Nanocellulose ceramic hybrid coated separator

By modifying the acylhydrazone bonds of the nanocellulose ceramic-coated separator through grafting and dopamine coating, the problems of easy detachment and insufficient thermal stability of the ceramic-coated separator were solved, achieving high interfacial bonding and good ion transport, thus improving the safety and performance of the battery.

CN122291875APending Publication Date: 2026-06-26宁波大浦新材料科技有限公司 +1
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
宁波大浦新材料科技有限公司
Filing Date
2026-04-10
Publication Date
2026-06-26

AI Technical Summary

Technical Problem

Existing ceramic-coated separators are prone to microcracks and coating peeling during battery production and long-term cycling, affecting battery safety and performance, and it is difficult to balance flexibility and thermal stability.

Method used

A nanocellulose ceramic coating membrane is used. The carboxylated nanocellulose is modified by grafting with hydrazone bonds and biomimetic mineralization treatment. Combined with dopamine to coat inorganic ceramic particles, a strong interfacial bond is formed. The porous structure of nanocellulose improves ion transport channels and electrolyte wettability.

Benefits of technology

It significantly improves the interfacial bonding between the composite coating and the porous polymer base film, prevents coating peeling, improves the thermal stability and ion transport efficiency of the battery, and ensures battery safety and performance stability.

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Abstract

This application discloses a nanocellulose ceramic composite-coated separator, relating to the field of battery separator technology. It includes a porous polymer base membrane and a composite coating, wherein the composite coating covers at least one side of the porous polymer base membrane. The composite coating is obtained by coating and drying an aqueous ceramic slurry, and the aqueous ceramic slurry comprises 85-95 parts by weight of inorganic ceramic particles, 5-15 parts by weight of nanocellulose, 0.1-2 parts by weight of a crosslinking agent, and 200-500 parts by weight of deionized water. This application significantly improves flexibility, adhesion strength, and thermal stability.
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