Method and device for defluorination by electrocoagulation

By using a metal anode plate doped with rare earth elements in electrocoagulation technology, the synergistic precipitation of rare earth ions and fluoride ions is achieved, solving the problems of high energy consumption and limited floc adsorption capacity in electrocoagulation technology under low concentration conditions, and improving the fluoride ion removal efficiency and stability.

CN122403587APending Publication Date: 2026-07-17GRINM RESOURCES & ENVIRONMENT TECH CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
GRINM RESOURCES & ENVIRONMENT TECH CO LTD
Filing Date
2026-06-11
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Electrocoagulation technology is inefficient in removing fluoride ions, especially under low concentration conditions, requiring high energy consumption and strict pH control. Furthermore, the adsorption capacity of flocs for fluoride ions is limited, making it difficult to adapt to complex water qualities.

Method used

Using a metal anode plate doped with rare earth elements, rare earth ions are precipitated in situ during electrocoagulation. Through the synergistic effect of rare earth ions and fluoride ions, rare earth fluoride precipitates are formed, which enhances adsorption selectivity and optimizes the pH range to reduce energy consumption.

Benefits of technology

It improves the removal efficiency and stability of fluoride ions, reduces energy consumption and electrode wear, expands the application potential of electrocoagulation technology in complex water quality, and achieves deep removal of low-concentration fluoride ions.

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Abstract

本申请公开了一种电絮凝除氟的方法及装置,阳极板由掺杂稀土元素的金属材料组成,实现在操作过程中在电极表面区域原位析出稀土离子,实现稀土离子的沉淀与絮体的吸附协同作用,大幅提高氟离子的去除效率和稳定性,尤其在低浓度条件下无需过度依赖高能耗操作,能够降低电絮凝除氟对电流密度、pH精确控制和反应时间的苛刻要求,减少能耗和电极损耗,提升整体经济性;同时,稀土元素的引入借助其离子与氟离子极强的结合能力,增强了整个电絮凝体系对氟离子的吸附选择性,避免复杂水质中其他共存阴离子的竞争干扰,突破了传统电絮凝技术在复杂废水处理中效果不稳定的瓶颈,拓展了电絮凝技术在含氟废水深度处理领域的应用潜力。
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