A process for the preparation of bis-hexylene triamine

By combining pre-distillation, light component removal tower, and heavy component removal tower, the problem of low purity of dihexanetriamine in hexanediamine production was solved, achieving high purity and high yield of dihexanetriamine separation and purification, thus enhancing its value utilization.

CN122404154APending Publication Date: 2026-07-17SHANGHAI JIEDA NYLON MATERIALS CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SHANGHAI JIEDA NYLON MATERIALS CO LTD
Filing Date
2026-04-07
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the existing technology, the bis(hexamethylenetriamine) produced during the production of hexamethylenediamine has low purity, which leads to its disposal as hazardous waste or its sale at low prices, resulting in its underutilization. In addition, the incineration process generates a large amount of pollutants.

Method used

A combined process of pre-distillation, light-weight removal tower, and heavy-weight removal tower was used to remove impurities such as hexamethylenediamine, N,N-diethylhexamethylenediamine, aminohexanonitrile, and 1,2-cyclohexamethylenediamine, finally obtaining high-purity and high-yield bis(hexamethylenediamine).

Benefits of technology

This method enables the separation and purification of bis(hexylenetriamine) with high purity and high yield, thereby enhancing the utilization value of bis(hexylenetriamine) and reducing pollution and costs associated with hazardous waste treatment.

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Abstract

本发明涉及一种制备双己撑三胺的方法,所述方法包括依次进行的以下步骤:(1)将己二胺副产物进行预蒸馏,得到第一分离产物,所述己二胺副产物包括N,N‑二乙基己二胺、双己撑三胺、己二胺、氨基己腈、水、1,2‑环己二胺和其他重组分;(2)将第一分离产物在脱轻塔中进行脱轻,从脱轻塔的塔底采集得到第二分离产物;(3)将第二分离产物在脱重塔中进行脱重,从脱重塔的塔顶采集得到双己撑三胺。
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