A ternary synergistic calcium silicate board special additive, a preparation method and application thereof

By grafting calcium lignosulfonate onto nanocellulose, a ternary synergistic calcium silicate board additive is formed, which solves the problems of single function of flocculants and lack of reinforcement of nanocellulose in the existing technology, realizes the synergistic effect of flocculation and reinforcement, and improves the mechanical properties and dehydration efficiency of calcium silicate board.

CN122404718APending Publication Date: 2026-07-17FOSHAN SANLE BUILDING MATERIALS IND CO LTD
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Patent Information

Application Number
CN202610580917.6
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-04-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the existing technology, anionic polyacrylamide, as a flocculant, has a single function in the preparation of calcium silicate boards and cannot improve mechanical properties. Furthermore, lignin sulfonate, as a water treatment flocculant, has failed to play a multifunctional role in calcium silicate boards, and nanocellulose has failed to effectively enhance the properties.

Method used

Using nanocellulose as the backbone, anionic polyacrylamide side chains are covalently grafted, and calcium lignosulfonate is grafted at the end of the side chain. By utilizing the electrostatic coordination of -SO3- and Ca2+ in calcium lignosulfonate, a dynamic ionic cross-linking network is formed, realizing the synergistic triple function of flocculation, nano-reinforcement and calcium ion response.

Benefits of technology

It achieves synergistic effects of flocculation and reinforcement, shortens dehydration time by 33%-46%, increases the flexural strength of finished boards by 74%, and improves wet blank strength by 3.7 times. The intelligent response of the calcium ion crosslinking network avoids the negative interference of lignin sulfonate.

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Abstract

本发明公开了一种三元协同型硅酸钙板专用添加剂及其制备方法和应用。该硅酸钙板专用添加剂是以纳米纤维素(CNF)为骨架,共价接枝阴离子聚丙烯酰胺(APAM)支链,并在支链末端接枝木质素磺酸钙获得。该专用添加剂在加入含Ca2+的硅酸钙板浆料后,木质素磺酸钙中的‑SO3‑与Ca2+静电配位,原位形成动态离子交联网络,实现“离子桥联‑絮凝吸附‑纳米增强”三重功能协同,可作为絮凝及增强剂用于硅酸钙板生产方面。
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