METHOD FOR DETERMINING THE WATER-SOLUBLE ACIDITY OF HYDROCARBON MIXTURES

The analytical method using a pH-sensitive electrode and controlled pH adjustment effectively measures water-soluble acidity in hydrocarbon mixtures, addressing the limitations of existing methods by accurately determining the potential corrosiveness of acids extracted into water.

BR102025004931B1Active Publication Date: 2026-07-07PETROLEO BRASILEIRO SA PETROBRAS
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Patent Information

Application Number
BR102025004931
Authority / Receiving Office
BR · BR
Patent Type
Patents
Current Assignee / Owner
Filing Date
2025-03-14
Publication Date
2026-07-07
Estimated Expiration
2045-03-14

AI Technical Summary

Technical Problem

Existing methods for determining the total acidity of hydrocarbon mixtures, such as ASTM D664, are inadequate for measuring the acidity of components that can be extracted into an aqueous phase, as they are dominated by naphthenic acids that remain in the oil phase, failing to account for the potential corrosiveness of acids that migrate into water.

Method used

An analytical method involving a pH-sensitive electrode and controlled pH adjustment with a base solution to measure the water-soluble acidity by equimolar reaction, ensuring complete extraction of acids from the hydrocarbon mixture into the aqueous phase.

Benefits of technology

Enables accurate determination of water-soluble acidity, allowing for the prediction of corrosiveness and enabling protective measures for equipment and proper disposal of hydrocarbon-contaminated waters.

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