Herbicidal composition comprising cyproconazole and acetochlor or pretilachlor

Abstract

The present invention relates to a herbicidal composition comprising at least one chloroacetamide selected from acetochlor and pretilachlor. The present invention also relates to a method and use for controlling undesirable plants, especially a method and use for controlling undesirable plants in crops.

Description

[0001] The present invention relates to a herbicidal composition comprising at least one chloroacetamide selected from acetochlor and pretilachlor. The present invention also relates to a method and use for controlling undesirable plants, especially a method and use for controlling undesirable plants in crops. Background of the Invention

[0003] In crop protection, it is generally desirable to increase the specific activity of active compounds and the reliability of the effect. In particular, it is desirable that crop protection products effectively control harmful plants, but at the same time be compatible with the useful plants. A broad activity spectrum is also desirable, allowing simultaneous control of harmful plants. This cannot usually be achieved with a single herbicidal active compound.

[0004] In addition, the situation of herbicide resistant weeds is becoming more and more common. These biotypes survive the application of herbicides at doses that are usually effective in controlling these varieties. Resistant weed biotypes are the result of a basic evolutionary process. Individuals within the variety that are most suitable for a particular practice are selected and will increase in the population. Once a weed population is exposed to an herbicide to which one or more plants are naturally resistant, the herbicide kills susceptible individuals but allows resistant individuals to survive and reproduce. Under repeated use of herbicides, resistant weeds that initially appear as isolated plants or small plots in the field may quickly expand and dominate in the population and soil seed bank.

[0005] For example, herbicide resistance in weeds, especially grass weeds such as Alopecurus myosuroides (ALOMY), Apera spica-venti (APESV) or Lolium species (LOLSS) has become a major concern for farmers, leading to dramatic weed control problems, for example in cereal crops. Herbicides from the class of ACCase- and ALS-inhibitors are most affected by resistance evolution, but also by various other types of herbicides.

[0006] Therefore, there is also a need to develop practices to prevent, delay or manage herbicide resistance in weeds.

[0007] Acetochlor is the common name for the herbicidal compound with the IUPAC name 2-chloro-N-ethoxymethyl-6'-ethylacetyl-o-toluidine and the Chemical Abstracts name 2-chloro-N-ethoxymethyl-N-(2-ethyl-6-methylphenyl)acetamide (CAS RN 34256-82-1), described in The Pesticide Manual, 14th edition, editor: CDS Tomlin, British Crop Production Council, 2006, item 5, pages 9-10. Acetochlor can be used for pre-emergence or pre-planting control of annual grass weeds, certain annual broadleaf weeds and Cyperus esculentus in corn, peanuts, soybeans, cotton, potatoes and sugarcane.

[0008] Pretilachlor is the common name for the herbicidal compound with the IUPAC name 2-chloro-2',6'-diethyl-N-(2-propoxyethyl)acetanilide and the Chemical Abstracts name 2-chloro-N-(2,6-diethylphenyl)-N-(2-propoxyethyl)acetamide (CAS RN51218-49-6), described in The Pesticide Manual, 14th edition, editor: CDS Tomlin, British Crop Production Council, 2006, entry 677, pages 856-857. Pretilachlor can be used to control major annual grass weeds, broadleaf weeds and sedges in transplanted and sown rice.

[0009] WO 2009 / 010475 discloses a method for controlling aquatic weeds by applying a herbicidally effective amount of a VLCFA inhibitor to a water body of aquatic weeds and / or to a water habitat containing seeds or other reproductive organs of the aquatic weeds. The VLCFA inhibitor can be an acetamide, a chloroacetamide, a hydroxyacetamide, a tetrazolinone, or selected from anilofos, cafenstrole, indanofan, and piperophos. Acetochlor and pretilachlor are both mentioned as examples of chloroacetamides. The VLCFA inhibitor can also be applied in combination with one or more other herbicides selected from various active compounds.

[0010] WO 88 / 02598 describes herbicidal mixtures comprising oxabicycloheptane compounds, in particular 2-exo-(2-methylbenzyloxy)-1-methyl-4-(1-methylethyl)-7-oxabicyclo[2.2.1]heptane (referred to as "Compound 1"), and various other herbicidal compounds, in particular alachlor and metolachlor (referred to as "Compound 19" and "Compound 20", respectively).

[0011] WO 2013 / 040163 describes synergistic herbicidal mixtures comprising herbicidally effective amounts of (a) penoxsulam and (b) pretilachlor.

[0012] US 2014 / 0243200 describes a herbicidal composition comprising synergistically herbicidally effective amounts of (a) penoxsulam and (b) acetochlor.

[0013] However, there is still room for improvement, for example with regard to activity, spectrum of activity, application rates, compatibility with useful plants and control of resistant weed biotypes. SUMMARY OF THE INVENTION

[0015] It was an object of the present invention to provide herbicidal compositions which exhibit an enhanced herbicidal action against unwanted harmful plants and / or have an improved compatibility with useful plants, in particular crops.

[0016] It is an object of the present invention in particular to provide herbicidal compositions which provide comparable weed control to the individual compounds at significantly reduced application rates. It is also an object of the present invention to provide herbicidal compositions which provide significantly increased weed control at application rates comparable to the application rates of the individual compounds.

[0017] Furthermore, it was an object of the present invention to provide herbicidal compositions which maintain or improve the level of weed control compared to the individual compounds while showing less damage in the cultivated crops.

[0018] Furthermore, the compositions according to the invention should have a broad spectrum of activity.

[0019] Another object of the present invention is to effectively control herbicide-resistant weed biotypes, especially among herbicide-resistant grass weeds.

[0020] These and other objects are achieved by the following herbicidal compositions, uses and methods.

[0021] Therefore, in one aspect of the present invention, there is provided a herbicidal composition comprising a herbicidally effective amount of (a) (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane, any of its individual enantiomers or any of its non-racemic mixtures (herbicide A) and (b) at least one chloroacetamide selected from acetochlor and pretilachlor (herbicide B).

[0022] The term "herbicide A" as used herein refers to a racemic mixture comprising (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane (also referred to herein as the "exo-(±)-isomer", CAS RN 87818-31-3):

[0023]

[0024] Any of its individual enantiomers or any of its non-racemic mixtures. The racemic mixture contains equal parts of the two enantiomers (+)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane (also referred to herein as the "exo-(+)-isomer", CAS RN 87818-61-9) and (-)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane (also referred to herein as the "exo-(-)-isomer", CAS RN 87819-60-1). Exo-(±)-isomers, exo-(+)-isomers and exo-(-)-isomers (including their preparation and herbicidal properties) are disclosed in EP 0 081 893 A2 (see Examples 29, 34, 35 and 62). Other methods for the preparation of these compounds are described in US Pat. No. 4,487,945 (see Examples 46 and 48). The racemic mixture (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane is also known by its common name cyproconazole, its IUPAC name (1RS,2SR,4SR)-1,4-oxo-p-butyl -2-yl 2-methylbenzyl ether and its Chemical Abstracts name exo-(±)-1-methyl-4-(1-methylethyl)-2-[(2-methylphenyl)methoxy]-7-oxabicyclo[2.2.1]heptane are described in The Pesticide Manual, 14th edition, editor: CDS Tomlin, British Crop Production Council, 2006, entry 157, pages 195-196.

[0025] In a preferred embodiment, the herbicide A is (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane.

[0026] In another embodiment, the herbicide A is (+)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane.

[0027] In another embodiment, the herbicide A is (-)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane.

[0028] In another embodiment, herbicide A is a non-racemic mixture of (+)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane and (-)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane. The non-racemic mixture contains unequal parts of exo-(+)-isomers and exo-(-)-isomers. The weight ratio of exo-(+)-isomers to exo-(-)-isomers in the non-racemic mixture can vary widely.

[0029] In another preferred embodiment, the herbicide B is acetochlor (hereinafter also referred to as "herbicide B.1" or "B.1").

[0030] In another preferred embodiment, the herbicide B is pretilachlor (hereinafter also referred to as "herbicide B.2" or "B.2").

[0031] The term "herbicidally effective amount" means an amount of active ingredient sufficient to control unwanted vegetation, especially in cultivated plants, without causing significant damage to the treated plants. This amount can vary within wide limits and depends on various factors, such as the plants to be controlled, the cultivated plants or materials to be treated, climatic conditions and the specific composition of the invention used.

[0032] The composition according to the invention may further comprise at least one herbicide C different from the herbicides A and B (as defined below).

[0033] The compositions according to the invention may further comprise at least one safener D (as defined below).

[0034] The compositions according to the invention may further comprise one or more auxiliaries customary in crop protection (as defined below).

[0035] In a further aspect, the present invention relates to the use of a composition as defined herein for controlling undesirable vegetation.

[0036] As used herein, the terms "plant" and "vegetation" include germinating seeds, emerging seedlings, plants emerging from asexual propagules, and established plants.

[0037] As used herein, the terms "control" and "controlling" are synonymous.

[0038] As used herein, the terms "undesirable plants," "harmful plants," "unwanted plant growth," "weeds," and "weed species" are synonymous.

[0039] In another aspect, the present invention relates to a method for controlling undesirable plants, which comprises applying to the plants or the locus thereof or the soil or water a herbicidally effective amount of (a) (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane, any of its individual enantiomers or any of its non-racemic mixtures (herbicide A) and (b) at least one chloroacetamide selected from acetochlor and pretilachlor (herbicide B) to prevent the emergence or growth of undesirable plants.

[0040] The method according to the invention may further comprise the application of at least one herbicide C (as defined below) which is different from the herbicides A and B. The method according to the invention may further comprise the application of at least one safener D. The method according to the invention may further comprise the application of one or more adjuvants customary in crop protection.

[0041] As used herein, the term "locus" refers to an area, typically a field, where plants are growing or are to be grown.

[0042] In yet another aspect, the present invention relates to a method for controlling undesirable vegetation, comprising applying a composition of the present invention to the vegetation or the locus thereof or to the soil or water to prevent the emergence or growth of the undesirable vegetation.

[0043] Further embodiments of the invention are apparent from the description, the examples and the claims. It is understood that the features of the subject matter of the invention mentioned above and still to be explained below can be used not only in the combination given in each specific case but also in other combinations without departing from the scope of the invention. DETAILED DESCRIPTION OF THE INVENTION

[0045] Surprisingly, it has been found that the combination of (a) a herbicide A and (b) at least one chloroacetamide selected from acetochlor and pretilachlor (herbicide B) can provide a synergistic herbicidal effect.

[0046] Therefore, in a preferred embodiment of the compositions, uses and methods of the present invention, herbicide A and herbicide B are each present or applied in an amount sufficient to provide a synergistic herbicidal effect.

[0047] The term "synergistic herbicidal effect" relates to the herbicidal effect of a given combination of two herbicides, wherein the herbicidal activity of the combination exceeds the sum of the individual herbicidal activities of the herbicides when applied separately. For this reason, these compositions can be used at a lower application rate based on the individual components to achieve a herbicidal effect comparable to that of the individual components.

[0048] In some embodiments of the invention, Colby's equation is used to determine whether the combination of herbicide A and herbicide B exhibits a synergistic effect (see SR Colby, "Calculating Synergistic and Antagonistic Responses of Herbicide Combinations," Weeds 1967, 15, pp. 20-22).

[0049] E=X+Y-(X·Y / 100)

[0050] Where X = the percentage effect of using herbicide A at application rate a;

[0051] Y = the percentage effect of herbicide B at application rate b;

[0052] E = expected effect (%) of herbicide A + herbicide B at application rate a + b.

[0053] For a three-way combination (herbicide A + herbicide B + herbicide C), a modified Colby equation can be used:

[0054] E=X+Y+Z-(X·Y+X·Z+Y·Z) / 100]-X·Y·Z / 10000

[0055] wherein E, X and Y are as defined above and Z is the percentage herbicidal effect of herbicide C (as defined herein) at application rate c.

[0056] In the Colby equation, the E value corresponds to the expected effect (plant damage or injury) if the activities of the individual compounds are additive. If the observed effect is higher than the E value calculated according to the Colby equation, a synergistic effect is present.

[0057] In one embodiment of the present invention, the compositions, uses and methods disclosed herein are synergistic as determined by the Colby equation. Specifically, the synergistic herbicidal effect is determined according to the Colby equation.

[0058] Furthermore, the compositions, uses and methods of the invention provide excellent pre- and post-emergence weed control.These compositions and methods can be used in particular for controlling undesirable vegetation before it emerges (pre-emergence).

[0059] The compositions, uses and methods of the invention also show good crop compatibility, ie the combined application of (a) herbicide A and (b) herbicide B in crops does not lead to increased crop damage compared to the individual application of herbicide A or herbicide B.

[0060] In addition, the compositions, uses and methods of the present invention provide effective control of herbicide-resistant or tolerant weed varieties, especially herbicide-resistant weed biotypes. For example, the compositions, uses and methods of the present invention can effectively control herbicide-resistant grass weeds, such as Alopecurus alopecurus (ALOMY), Apegrass (APESV), Phalaris species (PHASS) or Lolium species (LOLSS). The compositions, uses and methods of the present invention are also suitable for controlling herbicide-resistant broadleaf weeds, such as Papaver rhoeas (PAPRH, Papaver rhoeas), which have evolved resistance, especially to ALS-inhibiting herbicides.

[0061] Furthermore, the compositions, uses and methods of the invention can effectively control weed biotypes with target resistance and can also effectively control weed biotypes with non-target resistance. A particular advantage is that the compositions, uses and methods of the invention also provide effective control of weed biotypes with both target resistance and non-target resistance, such as resistant populations of Alopecurus alopecurus (ALOMY) or Lolium rigidum (LOLRI).

[0062] As used herein, "target resistance" occurs either through mutations within the gene encoding the herbicide target enzyme (limiting herbicide binding) or through overproduction of the target enzyme (gene overexpression or amplification).

[0063] As used herein, "non-target resistance" relates to mechanisms that minimize the amount of active herbicide that reaches the target (eg, reduced herbicide uptake or transport, increased herbicide sequestration, or enhanced herbicide metabolism).

[0064] In the composition of the present invention, the weight ratio of herbicide A (especially (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane) to herbicide B (especially sethoxydim (B.1) or pretilachlor (B.2)) is generally 1:0.1-1:100, preferably 1:0.3-1:40, and more preferably 1:0.8-1:20.

[0065] In addition to the herbicide A and the herbicide B, the composition of the present invention may further contain at least one herbicide C different from the herbicides A and B.

[0066] Therefore, in one embodiment, the composition of the present invention comprises a herbicide A (especially (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane), at least one chloroacetamide (herbicide B) selected from acetochlor and pretilachlor (especially acetochlor (B.1) or pretilachlor (B.2)) and at least one herbicide C.

[0067] Preferably, the herbicide C is selected from aclonifen (C.1), amicarbazine (C.2), amidosulfuron (C.3), aminopyralid (C.4), amitrole (C.5), asulam (C.6), atrazine (C.7), azimsulfuron (C.8), beflubutamid (C.9), benfluralin (C.10), bensulfuron (C.11), C.11), bensulide (C.12), bentazone (C.13), bicyclopyrone (C.14), bifenox (C.15), bispyribac (C.16), bromoxynil (C.17), carbetamide (C.18), carfentrazone (C.19), chloridazon (C.20), chlorpropham (C.21), chlorsulfuron (C.22), ulfuron) (C.22), chlorthal (C.23), chlortoluron (C.24), clethodim (C.25), clodinafop (C.26), clomazone (C.27), clopyralid (C.28), cycloxydim (C.29), cyclopyrimorate (C.30), cyhalofop (C.31), 2,4-D (C.32), dazomet )(C.33), 2,4-DB (C.34), desmedipham (C.35), dicamba (C.36), dichlorprop (C.37), dichlorprop-P (C.38), diclofop (C.39), diflufenican (C.40), diflufenzopyr (C.41), dimethachlor (C.42), dimethenamid (C.43), dimethenamid-P (C.44), diquat (C.45), dithiopyr (C.46), diuron (C.47), ethametsulfuron (C.48), ethofumesate (C.49), Fenoxaprop (C.50), high Fenoxaprop-P (C.51), fenquinotrione (C.52), flazasulfuron (C.53), florasulam (C.54), fluazifop (C.55), fluazifop-P (C.56), flufenacet (C.57), fluorine Flumioxazin (C.58), fluometuron (C.59), flupyrsulfuron (C.60), flurochloridone (C.61), fluroxypyr (C.62), flurtamone (C.63), foramsulfuron (C.64), glufosinate (C.65), glufosinate-P (C.66), glyphosate (C.67), halauxifen (C.68), chlorpyrifosinate (C.69), chlorpyrifosinate (C.70), chlorpyrifosinate (C.71), chlorpyrifosinate (C.72), chlorpyrifosinate (C.73), chlorpyrifosinate (C.74), chlorpyrifosinate (C.75), chlorpyrifosinate-P (C.76), chlorpyrifosinate (C.77), chlorpyrifosinate (C.78), chlorpyrifosinate (C.79), chlorpyrifosinate (C.80), chlorpyrifosinate (C.81), chlorpyrifosinate (C.82), chlorpyrifosinate (C.83), chlorpyrifosinate (C.84), chlorpyrifosinate (C.85), chlorpyrifosinate-P (C.86), chlorpyrifosinate (C.87), chlorpyrifosinate (C.88), chlorpyrifosinate (C.89), chlorpyrifosinate (C.90), chlorpyrifosinate (C.91), chlorpyrifosinate (C.92), chlorpyrifosinate (C.93), chlorpyrifosinate (C.94), chlorpyrifosinate (C.95), chlorpyrifosinate-P (C.96), chlorpyrifosinate (C.97), chlorpyrifosinate ( .68), halosulfuron (C.69), haloxyfop-P (C.70), indaziflam (C.71), imazamox (C.72), imazaquin (C.73), imazosulfuron (C.74), iodosulfuron (C.75), iofensulfuron (C.76), ioxynil (C.77), isoproturon (C.78), isoxaben (C.79), isoxaben (C.80), Isoxaflutole (C.80), lenacil (C.81), linuron (C.82), 2-methyl-4-chloropropane (MCPA) (C.83), 2-methyl-4-chlorobutyric acid (MCPB) (C.84), 2-methyl-4-chloropropane (mecoprop) (C.85), mecoprop-P (mecoprop-P) (C.86), mesosulfuron (C.87), mesotrione (C.88), metam (C.89), metamitron (C.90), metazachlor (C.91), methiozoline (C.92), metob romuron) (C.93), isopropyl metolachlor (C.94), S-metolachlor (C.95), metosulam (C.96), metribuzin (C.97), metsulfuron (C.98), molinate (C.99), monosodium methyl arsenate (MSMA) (C.100), napropamide (C.101), napropamide-M (C.102), nicosulfuron (C.103), orthosulfamuron (C.104), oryzalin (C.105), propargyl Oxadiargyl (C.106), oxadiazon (C.107), oxasulfuron (C.108), oxyfluorfen (C.109), pendimethalin (C.110), penoxsulam (C.111), pethoxamid (C.112), phenmedipham (C.113), picloram (C.114), picolinafen (C.115), pinoxaden (C.116), oxadiargyl (C.117), oxadiazon (C.118), oxadiazon (C.119), oxadiazon (C.200), oxadiazon (C.210), oxadiazon (C.211), oxadiazon (C.212), oxadiazon (C.213), oxadiazon (C.214), picolinafen (C.215), pinoxaden (C.216), oxadiazon (C.217), oxadiazon (C.218), oxadiazon (C.219), oxadiazon (C.220), oxadiazon (C.221), oxadiazon (C.222), oxadiazon (C.223), oxadiazon (C.224), oxadiazon (C.225), oxadiazon (C.226), oxadiazon (C.227), oxadiazon (C.228), oxadiazon (C.229), oxadiazon (C.23 ... 116), aminopropydim (C.117), profoxydim (C.118), prometryne (C.119), propaquizafop (C.120), propoxycarbazone (C.121), propyzamide (C.122), prosulfocarb (C.123), prosulfuron (C.124), pyraflufen (C.125), pyridate (C.126), 6), pyroxasulfone (C.127), pyroxsulam (C.128), quinclorac (C.129), quinmerac (C.130), quinoclamine (C.131), quizalofop (C.132), quizalofop-P (C.133), rimsulfuron (C.134), saflufenacil (C.135), sethoxydim (C.136), quinacrazol (C.137), quinacrazol (C.138), quinacrazol (C.139), quinacrazol (C.140), quinacrazol (C.141), quinacrazol (C.142), quinacrazol (C.143), quinacrazol (C.144), quinacrazol (C.145), quinacrazol (C.146), quinacrazol (C.147), quinacrazol (C.148), quinacrazol (C.149), quinacrazol (C.150), quinacrazol (C.151), quinacrazol (C.152), quinacrazol (C.153), quinacrazol (C.154), quinacrazol (C.155), quinacrazol (C.156), quinacrazol (C.157), quinacrazol (C.158), quinacrazol (C.159), quinacrazol (C.160), quinacrazol (C.161), quinacrazol (C.162), quinacrazol (C.163), quinacrazol (C.164), quinacrazol (C.165), quinacrazol (C.166), quinacrazol (C.167), quinacrazol (C.168), 36), siduron (C.137), simazine (C.138), sulcotrione (C.139), sulfentrazone (C.140), sulfosulfuron (C.141), tembotrione (C.142), tepraloxydim (C.143), terbuthylazine (C.144), thiencarbazone (C.145), thifensulfuron (C.146), thifensulfuron (C.147), thifensulfuron (C.148), thifensulfuron (C.149), thifensulfuron (C.200), thifensulfuron (C.201), thifensulfuron (C.202), thifensulfuron (C.203), thifensulfuron (C.204), thifensulfuron (C.205), thifensulfuron (C.206), thifensulfuron (C.207), thifensulfuron (C.208), thifensulfuron (C.209), thifensulfuron (C.210), thifensulfuron (C.211), thifensulfuron (C.212), thifensulfuron (C.213), thifensulfuron (C.214), thifensulfuron (C.215), thifensulfuron (C.216), thifensulfuron (C.217), thifensulfuron (C.218), thifensulfuron (C.219), thifensulfuron (C.221), thifensulfuron (C.223), thifensulfuron (C.224), thifensulfuron (C.225), th146), tolpyralate (C.147), topramezone (C.148), tralkoxydim (C.149), tri-allate (C.150), triasulfuron (C.151), tribenuron (C.152), triclopyr (C.153), trifloxysulfuron (C.154), trifludimoxazin (C.155), trifluralin (C.156), triflusulfuron (C.157), tritosulfuron (C.158), 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)-5-fluoropyridine-2-carboxylic acid (C.159), 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)-5-fluoropyridine-2-carboxylic acid benzyl ester (CAS 1390661-72-9, C.160), cyclosulfamuron (C.161), benzobicyclon (C.162), halosuflamuron (C.163), propanil (C.164), butachlor (C.165), butralin (C.166), piperophos (C.167), pyrazosulfuron (C.168), thiobencarb (C.169), flucarbazone (C.170), imazapic (C.171), imazapyr (C.172), imazethapyr (C.173) and their agriculturally acceptable salts, esters or amides.

[0068] More preferably, the herbicide C is selected from the group consisting of bennitroprop-butyl (C.1), aminopyralid (C.4), atrazine (C.7), tetrazosulfuron (C.8), fluazifop-butyl (C.9), benzylsulfuron (C.11), thiamethoxam (C.13), flupyralid (C.14), cypermethrin (C.15), bispyribac (C.16), long-kill grass (C.18), cypermethrin (C.20), chlorotoluron (C.24), clethodim (C.25), clofabutin (C.26), isothiocarb (C.27), dichloro Picolinic acid (C.28), cypermethrin (C.29), cyclopyrimorate (C.30), cyhalofop-butyl (C.31), 2,4-D (C.32), dicamba (C.36), chlorfenapyr (C.39), fluazifop-butyl (C.40), diflupyr (C.41), chlorfenapyr (C.42), dimethenamid (C.43), dimethenamid-P (C.44), fluthiopyralid (C.46), ethametsulfuron (C.48), ethoxysulfuron (C.49), Fenpyraclostrobin (C.50), high Fenpyraclostrobin (C.51), phenoxyquinoxaline (C.52), fluazifop-butyl (C.53), fluazifop-butyl (C.55), fluazifop-butyl (C.56), flufenacet (C.57), fluorine oxazolidinone (C.58), fluazifop-butyl (C.60), fluchloridone (C.61), furazolidinone (C.63), foramsulfuron (C.64), glufosinate (C.65), glufosinate (C.66), glyphosate (C.67), pyralidone (C.69), pyralidone (C.70), indazine fluazifop-butyl (C.71), imazamox (C.72), iodinesulfuron (C.75), isoproturon (C.78), isoxadiazon (C.79), isoproturon Fluorosulfuron (C.80), 2-methyl-4-chloropropionic acid (C.83), 2-methyl-4-chloropropionic acid (C.85), high 2-methyl-4-chloropropionic acid (C.86), methyl disulfone (C.87), mesotrione (C.88), metazachlor (C.91), isopropyl metolachlor (C.94), S-isopropyl metolachlor (C.95), sulfamethoxam (C.96), metribuzin (C.97), sulfamethoxam (C.98), chlorpyrifos (C.99), naphthamide (C.101), naphthamide (C.102), nicosulfuron (C.103), chlorpyrifos (C.105), propargyl Azoles (C.106), oxadiazine (C.107), oxyfluorfen (C.109), pendimethalin (C.110), penfloxacin (C.111), pethoxamid (C.112), piclopidine (C.114), fluazifop (C.115), pinoxaden (C.116), aminopropane (C.117), cypermethrin (C.118), cyfluthrin (C.119), chlorpyrifos (C.200), chloranil (C.210), chloranil (C.211), chloranil (C.212), chloranil (C.213), chloranil (C.214), chloranil (C.215), chloranil (C.216), chloranil (C.217), chloranil (C.218), chloranil (C.219), chloranil (C.221), chloranil (C.222), chloranil (C.223), chloranil (C.224), chloranil (C.225), chloranil (C.226), chloranil (C.227), chloranil (C.228), chloranil (C.229), chloranil (C.230), chloranil (C.231), chloranil (C.232), chloranil (C.233), chloranil (C.234), chloranil (C.235), chloranil (C.236), chloranil (C.237), chloranil (C.238), chloranil (C.239), chloranil (C.240), chloranil (C.241), chloranil (C.242), chloranil (C.243), 120), propansulfuron-methyl (C.121), naclofoate (C.122), bensulfuron (C.123), pyroxensulfuron (C.127), foramsulfuron (C.128), quinclorac (C.129), quinclorac (C.130), quizalofop-p-butyl (C.132), quizalofop-p-butyl (C.133), pyrazosulfuron (C.134), bensulfuron (C.135), Simazine (C.138), sulcotrione (C.139), ethyl yellow yellow sulfonate (C.141), tampron (C.142), quinone oxime grass (C.143), terbuthyl azine (C.144), thiocarbamide (C.145), tolpyralate (C.147), benzylpyraclostrobin (C.148), oxime oxadione (C.149), wild wheat chlorpyrifos (C.150), trifludimoxazin (C.155), trifluralin (C.156), trifluorosulfuron (C.158), 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)-5-fluoropyridine-2-carboxylic acid (C.159), 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)-5-fluoropyridine-2-carboxylic acid benzyl ester (CAS 1390661-72-9, C.160), cyprosulfuron (C.161), bicyclonyl (C.162), halosuflamuron (C.163), propanil (C.164), butachlor (C.165), disulfiram (C.166), pyraclostrobin (C.167), pyrazosulfuron (C.168), carbofuran (C.169) and their agriculturally acceptable salts, esters or amides.

[0069] The herbicide C is particularly selected from benitobutyl (C.1), atrazine (C.7), thiamethoxam (C.13), bispyribac (C.16), dicamba (C.36), diflupyrone (C.41), fluazifop (C.61), imazamox (C.72), isoflurane (C.73), chlorpyrifos (C.74), chlorpyrifos (C.76), chlorpyrifos (C.77), chlorpyrifos (C.78), chlorpyrifos (C.79), chlorpyrifos (C.80), chlorpyrifos (C.81), chlorpyrifos (C.82), chlorpyrifos (C.83), chlorpyrifos (C.84), chlorpyrifos (C.85), chlorpyrifos (C.86), chlorpyrifos (C.87), Fluorothiocarb (C.80), Mesotrione (C.88), Nicosulfuron (C.103), Propargyl Azoresulphate (C.106), pendimethalin (C.110), penoxsulam (C.111), cypermethrin (C.118), carbendazim (C.123), quinclorac (C.129), bensulfuron (C.135), cypermethrin (C.142), terbuthion (C.144), benzopyrazone (C.148), cyprosulfuron (C.161), bicyclonyl (C.162), halosuflamuron (C.163), propanil (C.164), butachlor (C.165), pyrazosulfuron (C.168) and their agriculturally acceptable salts, esters or amides.

[0070] In another preferred embodiment, the herbicide C is selected from benitobutyl (C.1), cyclathione (C.29), fluazifop (C.61), imazamox (C.72), propargyl C.106, C.110 and their agriculturally acceptable salts, esters or amides. The above herbicide C is particularly suitable for use in sunflowers.

[0071] In another preferred embodiment, the herbicide C is selected from atrazine (C.7), dicamba (C.36), diflupyrron (C.41), isoflurane (C.54), isoflurane (C.63), isoflurane (C.77), isoflurane (C.38), isoflurane (C.49), isoflurane (C.50), isoflurane (C.61), isoflurane (C.62), isoflurane (C Fluorosulfuron (C.80), mesotrione (C.88), nicosulfuron (C.103), pendimethalin (C.110), tampoxone (C.142), terbuthion (C.144), pyraclostrobin (C.148) and their agriculturally acceptable salts, esters or amides. The above herbicide C is particularly suitable for use in corn.

[0072] In another preferred embodiment, the herbicide C is selected from benitobutyl (C.1), cypermethrin (C.29), imazamox (C.72), metribuzin (C.97), pendimethalin (C.110), carbofuran (C.123) and their agriculturally acceptable salts, esters or amides. The above herbicide C is particularly suitable for use in leguminous plants.

[0073] In another preferred embodiment, the herbicide C is selected from thiamethoxam (C.13), bispyribac (C.16), cypermethrin (C.29), imazamox (C.72), pendimethalin (C.110), cypermethrin (C.118), dichloroquinoline (C.129), benzylpyridin (C.135), cyproconazole (C.161), bicyclonazole (C.162), pyrazosulfuron (C.168) and its agriculturally acceptable salts, esters or amides. The above-mentioned herbicide C is particularly suitable for use in rice.

[0074] Besides the herbicide A, the herbicide B and optionally the herbicide C, the composition according to the invention may further comprise at least one safener D.

[0075] Safeners are compounds which prevent or reduce damage to useful plants without having a significant effect on the herbicidal action of the herbicidal active ingredients on unwanted plants. Safeners can be applied before sowing (e.g. seed treatment), on shoots or seedlings, and in pre- or post-emergence treatments of useful plants and in the habitat.

[0076] In one embodiment, the composition according to the invention therefore comprises a herbicide A, a herbicide B, in particular acetochlor (B.1) or pretilachlor (B.2), at least one safener D and optionally at least one herbicide C.

[0077] In a further embodiment, the composition according to the invention comprises a herbicide A, a herbicide B, in particular acetochlor (B.1) or pretilachlor (B.2), at least one herbicide C and at least one safener D.

[0078] Exemplary safeners D include benoxacor (D.1), cloquintocet (D.2), cyometrinil (D.3), cyprosulfamide (D.4), dichlormid (D.5), dicyclonon (D.6), dietholate (D.7), fenchlorazole (D.8), fenclorim (D.9), flurazole (D.10), fluxofenim (D.11), furilazole (D.12), diphenyl isoxadifen (D.13), mefenpyr (D.14), mephenate (D.15), naphthylacetic acid (D.16), naphthalic anhydride (naphthalicanhydride) (D.17), oxabetrinil (D.18), 4-dichloroacetyl-1-oxa-4-azaspiro[4.5]decane (MON4660, CAS 71526-07-3) (D.19), 2,2,5-trimethyl-3-dichloroacetyl-1,3- Oxazolidine (R-29148, CAS 52836-31-4) (D.20), N-(2-methoxybenzoyl)-4-[(methylaminocarbonyl)amino]benzenesulfonamide (CAS 129531-12-0) (D.21) and agriculturally acceptable salts, esters or amides thereof.

[0079] Preferably, the safener D is selected from the group consisting of chlorpyrifos (D.1), quinoxyacetic acid (D.2), cyproconazole (D.4), chlorfenapyr (D.5), bicyclazole (D.6), chlorfenapyr (D.8), chlorpyrifos (D.9), chlorfenapyr (D.10), chlorfenapyr (D.12), diphenylamine (D.13), chlorpyrifos (D.14), chlorfenapyr (D.15), chlorfenapyr (D.16), chlorfenapyr (D.17), chlorfenapyr (D.18), chlorfenapyr (D.19), chlorfenapyr (D.20), chlorfenapyr (D.21), chlorfenapyr (D.22), chlorfenapyr (D.23), chlorfenapyr (D.24), chlorfenap Azoles acid (D.13), pyrrole dicarboxylic acid (D.14), 4-dichloroacetyl-1-oxa-4-azaspiro[4.5]decane (MON4660, CAS71526-07-3) (D.19), 2,2,5-trimethyl-3-dichloroacetyl-1,3- Oxazolidine (R-29148, CAS 52836-31-4) (D.20) and its agriculturally acceptable salts, esters or amides.

[0080] More preferably, the safener D is selected from the group consisting of chlorpyrifos (D.1), cloquintocet-mexyl (D.2a), cyproconazole (D.4), chlorfenapyr (D.5), bicyclol (D.6), fenclorazole-ethyl (D.8a), chlorpyrifos (D.9), chlorfenapyr (D.10), chlorpyrifos (D.12), biphenyl isoxadifen-ethyl (D.13a), mefenpyr-diethyl (D.14a), 4-dichloroacetyl-1-oxa-4-azaspiro[4.5]decane (MON4660, CAS 71526-07-3) (D.19) and 2,2,5-trimethyl-3-dichloroacetyl-1,3- Oxazolidine (R-29148, CAS 52836-31-4) (D.20).

[0081] Even more preferably, the safener D is selected from the group consisting of chlorpyrifos (D.1), quinoxyacetic acid (D.2), cyproconazole (D.4), chlorfenapyr (D.5), fenclorazole (D.8), chlorpyrifos (D.9), diphenylamine (D.10), chlorpyrifos (D.11), chlorpyrifos (D.12), chlorpyrifos (D.13), chlorpyrifos (D.14), chlorpyrifos (D.15), chlorpyrifos (D.16), chlorpyrifos (D.17), chlorpyrifos (D.18), chlorpyrifos (D.19), chlorpyrifos (D.20), chlorpyrifos (D.21), chlorpyrifos (D.22), chlorpyrifos (D.23), chlorpyrifos (D.24 Azoles acid (D.13), pyrrole dicarboxylic acid (D.14) and agriculturally acceptable salts, esters or amides thereof.

[0082] Still more preferably, the safener D is selected from the group consisting of chlorpyrifos (D.1), quinoxaline (D.2a), cyproconazole (D.4), chlorpyrifos ethyl (D.5), chlorpyrifos ethyl (D.8a), chlorpyrifos thiocarb (D.9), diphenylamine (D.10), chlorpyrifos ethyl (D.11), chlorpyrifos thiocarb (D.12), chlorpyrifos thiocarb (D.13), chlorpyrifos thiocarb (D.14), chlorpyrifos thiocarb (D.15), chlorpyrifos thiocarb (D.16), chlorpyrifos thiocarb (D.17), chlorpyrifos thiocarb (D.18), chlorpyrifos thiocarb (D.19), chlorpyrifos Ethyl oxadiazole (D.13a) and diethyl pyrrole (D.14a).

[0083] The safener D is particularly selected from the group consisting of chlorpyrifos (D.1), quinoxyacetic acid (D.2), cyproconazole (D.4), diphenyl The safener D is most preferably selected from the group consisting of chlorpyrifos (D.1), quinoxyacetyl isoheptyl (D.2a), cyproconazole (D.4), diphenylamine (D.5), chlorpyrifos (D.6), chlorpyrifos (D.7), chlorpyrifos (D.8), chlorpyrifos (D.9), chlorpyrifos (D.10), chlorpyrifos (D.11), chlorpyrifos (D.12), chlorpyrifos (D.13), chlorpyrifos (D.14), and chlorpyrifos (D.15). Ethyl oxadiazole (D.13a) and diethyl pyrrole (D.14a).

[0084] Herbicide C and safener D are known herbicides and safeners, see, for example, The Pesticide Manual, British Crop Protection Council, 16th edition, 2012; The Compendium of Pesticide Common Names (http: / / www.alanwood.net / pesticides / ); Farm Chemicals Handbook 2000, Vol. 86, Meister Publishing Company, 2000; B. Hock, C. Fedtke, RR Schmidt, Herbizide [Herbicide], Georg Thieme Verlag, Stuttgart 1995; WH Hrens, Herbicide Handbook, 7th edition, Weed Science Society of America, 1994; and KK Hatzios, Herbicide Handbook, Supplement to the 7th edition, Weed Science Society of America, 1998. 2,2,5-trimethyl-3-dichloroacetyl-1,3- Oxazolidine [CAS No. 52836-31-4] is also known as R-29148. 4-Dichloroacetyl-1-oxa-4-azaspiro[4.5]decane [CAS No. 71526-07-3] is also known as AD-67 and MON 4660.

[0085] If the herbicides C and / or safeners D described herein are capable of forming geometrical isomers, for example E / Z isomers, both the pure isomers and mixtures thereof can be used in the compositions, uses and methods according to the invention.

[0086] If the herbicides C and / or safeners D described herein have one or more chiral centers and therefore exist as enantiomers or diastereomers, both the pure enantiomers and diastereomers and mixtures thereof can be used in the compositions, uses and methods according to the invention.

[0087] If the herbicides C and / or safeners D described herein have ionizable functional groups, they can also be used in the form of their agriculturally acceptable salts. The term "agriculturally acceptable salts" is used herein to generally refer to salts of those cations and acid addition salts of those acids whose cations and anions, respectively, have no adverse effect on the herbicidal activity of the active compound.

[0088] Preferred cations are ions of alkali metals, preferably lithium, sodium and potassium, ions of alkaline earth metals, preferably calcium and magnesium, and ions of transition metals, preferably manganese, copper, zinc and iron, furthermore ammonium and substituted ammonium in which 1 to 4 hydrogen atoms are replaced by C1-C4-alkyl, hydroxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkyl, hydroxy-C1-C4-alkoxy-C1-C4-alkyl, phenyl or benzyl, preferably ammonium, methylammonium, isopropylammonium, dimethyl ... Isopropylammonium, trimethylammonium, heptylammonium, dodecylammonium, tetradecylammonium, tetramethylammonium, tetraethylammonium, tetrabutylammonium, 2-hydroxyethylammonium (alcoholamine salt), 2-(2-hydroxyeth-1-oxy)eth-1-ylammonium (diglycolamine salt), di(2-hydroxyeth-1-yl)ammonium (diolamine salt), tri(2-hydroxyethyl)ammonium (triolamine salt), tri(2-hydroxypropyl)ammonium, benzyltrimethylammonium, benzyltriethylammonium, N,N,N-trimethylethanolammonium (choline salt), in addition ions, sulfonium ions, preferably tri(C1-C4-alkyl)sulfonium, such as trimethylsulfonium, and sulfoxide ions, preferably tri(C1-C4-alkyl)sulfoxide, and finally salts of polyamines, such as N,N-di(3-aminopropyl)methylamine and diethylenetriamine.

[0089] Anions of useful acid addition salts are primarily chloride, bromide, fluoride, iodide, hydrogensulfate, methylsulfate, sulfate, dihydrogenphosphate, hydrogenphosphate, nitrate, hydrogencarbonate, carbonate, hexafluorosilicate, hexafluorophosphate, benzoate and also the anions of C1-C4-alkanoic acids, preferably formate, acetate, propionate and butyrate.

[0090] The herbicides C and / or safeners D described herein having carboxyl, hydroxyl and / or amino groups may be in the form of acids, in the form of agriculturally suitable salts as described above or in the form of agriculturally acceptable derivatives, for example as amides, such as mono- and di-C1-C6-alkylamides or arylamides, as esters, for example as allyl esters, propargyl esters, C1-C6-alkylamide ... 10 Alkyl esters, alkoxyalkyl esters, tetrahydrofuranylmethyl (tefuryl) ((tetrahydrofuran-2-yl)methyl) esters and also as thioesters, for example as C1-C 10Alkylthio esters are used. Preferred mono- and di-C1-C6 alkylamides are methyl and dimethylamides. Preferred arylamides are, for example, benzamide and 2-chlorobenzamide. Preferred alkyl esters are, for example, methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, methylhexyl (mexyl) (1-methylhexyl), methylheptyl (meptyl) (1-methylheptyl), heptyl, octyl or isooctyl (2-ethylhexyl) esters. Preferred C1-C4 alkoxy-C1-C4 alkyl esters are straight-chain or branched C1-C4 alkoxyethyl esters, for example 2-methoxyethyl esters, 2-ethoxyethyl esters, 2-butoxyethyl (butotyl) esters, 2-butoxypropyl esters or 3-butoxypropyl esters. Straight-chain or branched C1-C 10 An example of an alkylthio ester is ethylthio ester.

[0091] Exemplary agriculturally acceptable salts or esters of aminopyralid (C.4) include aminopyralid-dimethylammonium (C.4a), aminopyralid-potassium (C.4b), aminopyralid-tris(2-hydroxypropyl)ammonium (C.4c), and mixtures thereof.

[0092] Exemplary agriculturally acceptable salts or esters of cypermethrin (C.6) include cypermethrin potassium (C.6a), cypermethrin sodium (C.6b), and mixtures thereof.

[0093] Exemplary agriculturally acceptable salts or esters of bensulfuron-methyl (C.11) include bensulfuron-methyl (C.11a).

[0094] Exemplary agriculturally acceptable salts or esters of methicillin (C.13) include methicillin sodium (C.13a).

[0095] Exemplary agriculturally acceptable salts or esters of bispyribac (C.16) include bispyribac sodium (C.16a).

[0096] Exemplary agriculturally acceptable salts or esters of bromoxynil (C.17) include bromoxynil butyrate (C.17a), bromoxynil heptanoate (C.17b), bromoxynil octanoate (C.17c), bromoxynil potassium (C.17d), and mixtures thereof.

[0097] Exemplary agriculturally acceptable salts or esters of carfentrazone (C.19) include carfentrazone-ethyl (C.19a).

[0098] Exemplary agriculturally acceptable salts or esters of dichlorvos (C.23) include dichlorvos dimethyl ester (DCPA) (C.23a), dichlorvos monomethyl ester (C.23b), and mixtures thereof.

[0099] Exemplary agriculturally acceptable salts or esters of clodinafop-propargyl (C.26) include clodinafop-propargyl (C.26a).

[0100] Exemplary agriculturally acceptable salts or esters of clopyralid (C.28) include potassium clopyralid (C.28a), clopyralid-olamine (C.28b), clopyralid-tris(2-hydroxypropyl)ammonium (C.28c), clopyralid-methyl (C.28d) and mixtures thereof. In some embodiments, clopyralid is provided as an amine salt, such as clopyralid-olamine (C.28b, see above), dimethylamine (DMA) salt (C.28e), monoethanolamine (MEA) salt (C.28f), triisopropanolamine (TIPA) salt (C.28g) and mixtures thereof.

[0101] Exemplary agriculturally acceptable salts or esters of cyhalofop-butyl (C.31) include cyhalofop-butyl (C.31a).

[0102] Exemplary agriculturally acceptable salts or esters of 2,4-D (C.32) include 2,4-D ammonium (C.32a), 2,4-D butoxyethyl ester (C.32b), 2,4-D-2-butoxypropyl ester (C.32c), 2,4-D-3-butoxypropyl ester (C.32d), 2,4-D butyl ester (C.32e), 2,4-D diethylammonium (C.32f), 2,4-D dimethylammonium (C.32g), 2,4-D diethanolammonium (C.32h), 2,4-D dodecylammonium (C.32i), 2,4-D ethyl ester (C.32j), 2,4-D ethylhexyl ester (C.32k), 2,4-D heptyl ammonium (C.32l), 2,4-D isobutyl ester (C.32m), 2,4-D isobutyl ester (C.32m), 2,4-D isobutyl ester (C.32e), 2,4-D isobutyl ester (C.32f), 2,4-D dimethylammonium (C.32g), 2,4-D diethanolammonium (C.32h), 2,4-D dodecyl ammonium (C.32i), 2,4-D ethyl ester (C.32j), 2,4-D ethylhexyl ester (C.32k), 2,4-D heptyl ammonium (C.32l), 2,4-D isobutyl ester (C.32m), 2,4-D isobutyl ester (C.32e), 2,4-D isobutyl ester (C.32e), 2,4-D isobutyl ester (C.32f), 2,4-D di Octyl ester (C.32n), 2,4-drop isopropyl ester (C.32o), 2,4-drop isopropylammonium (C.32p), 2,4-drop lithium (C.32q), 2,4-drop methylheptyl ester (C.32r), 2,4-drop methyl ester (C.32s), 2,4-drop octyl ester (C.32t), 2,4-drop pentyl ester (C.32u), 2,4-drop propyl ester (C.32v), 2,4-drop sodium (C.32w), 2,4-drop tetrahydrofuranyl methyl ester (C.32x), 2,4-drop tetradecyl ammonium (C.32y), 2,4-drop triethylammonium (C.32z), 2,4-drop tri(2-hydroxypropyl)ammonium (C.32zx), 2,4-drop triethanolamine (C.32zy) and mixtures thereof.

[0103] Exemplary agriculturally acceptable salts or esters of dazomethon (C.33) include sodium dazomethon (C.33a).

[0104] Exemplary agriculturally acceptable salts or esters of 2,4-D butyric acid (C.34) include 2,4-D butyl butyrate (C.34a), 2,4-D dimethylammonium butyrate (C.34b), 2,4-D isooctyl butyrate (C.34c), 2,4-D potassium butyrate (C.34d), 2,4-D sodium butyrate (C.34e), and mixtures thereof.

[0105] Exemplary agriculturally acceptable salts or esters of dicamba (C.36) include sodium dicamba (C.36a), potassium dicamba (C.36b), dicamba methylammonium (C.36c), dimethyl dicamba (C.36d), isopropyl dicamba (C.36e), diglycolamine (C.36f), dicamba ethanolamine (C.36g), diethanolamine (C.36h), triethanolamine (C.36i), dicamba-N,N-di(3-aminopropyl)methylamine (C.36j), dicamba-diethylenetriamine (C.36k), dicamba methyl ester (C.36l), dicamba butoxyethyl ester (C.36m) and mixtures thereof.

[0106] Exemplary agriculturally acceptable salts or esters of 2,4-dichlorpropionic acid include butoxyethyl 2,4-dichlorprop (C.37a), dimethylammonium 2,4-dichlorprop (C.37b), ethylammonium 2,4-dichlorprop (C.37c), 2-ethylhexyl 2,4-dichlorprop (C.37d), isooctyl 2,4-dichlorprop (C.37e), methyl 2,4-dichlorprop (C.37f), potassium 2,4-dichlorprop (C.37g), sodium 2,4-dichlorprop (C.37h), and mixtures thereof.

[0107] Exemplary agriculturally acceptable salts or esters of 2,4-dichlorprop include dimethylammonium 2,4-dichlorprop (C.38a), 2-ethylhexyl 2,4-dichlorprop (C.38b), potassium 2,4-dichlorprop (C.38c), sodium 2,4-dichlorprop (C.38d), and mixtures thereof.

[0108] Exemplary agriculturally acceptable salts or esters of chlorothalonil (C.39) include chlorothalonil methyl (C.39a).

[0109] Exemplary agriculturally acceptable salts or esters of diflupyrone (C.41) include diflupyrone sodium (C.41a).

[0110] Exemplary agriculturally acceptable salts or esters of the diquat cation (C.45) include diquat dibromide (C.45a).

[0111] Exemplary agriculturally acceptable salts or esters of ethametsulfuron (C.48) include ethametsulfuron methyl (C.48a).

[0112] Exemplary agriculturally acceptable salts or esters of oxadiazon (C.50) include Ethyl thiocarb (C.50a).

[0113] high Exemplary agriculturally acceptable salts or esters of oxadiazon-ethyl (C.51) include high Ethyl thiamethoxam (C.51a).

[0114] Exemplary agriculturally acceptable salts or esters of fluazifop-butyl (C.55) include fluazifop-butyl methyl ester (C.55a), fluazifop-butyl ester (C.55b), and mixtures thereof.

[0115] Exemplary agriculturally acceptable salts or esters of fluazifop-P-ethyl (C.56) include fluazifop-P-butyl ester (C.56a).

[0116] Exemplary agriculturally acceptable salts or esters of fluazifop-sodium (C.60) include fluazifop-sodium methyl ester (C.60a), fluazifop-sodium methyl ester (C.60b), and mixtures thereof.

[0117] Exemplary agriculturally acceptable salts or esters of fluroxypyr (C.62) include fluroxypyr-butomethyl (C.62a), fluroxypyr-methylheptyl (C.62b), and mixtures thereof.

[0118] Exemplary agriculturally acceptable salts or esters of glufosinate (C.65) include glufosinate-ammonium (C.65a).

[0119] Exemplary agriculturally acceptable salts or esters of glufosinate-ammonium (C.66) include glufosinate-P-ammonium (C.66a), glufosinate-sodium (C.66b), and mixtures thereof.

[0120] Exemplary agriculturally acceptable salts or esters of glyphosate (C.67) include glyphosate-ammonium (C.67a), glyphosate diammonium (C.67b), glyphosate dimethyl ammonium (C.67c), glyphosate isopropyl ammonium (C.67d), glyphosate potassium (C.67e), glyphosate sodium (C.67f), glyphosate sesquisodium salt (C.67g), glyphosate-trimesium (C.67h), glyphosate ethanolamine (C.67i), glyphosate diethanolamine (C.67j) and mixtures thereof.

[0121] Exemplary agriculturally acceptable salts or esters of halauxifen (C.68) include halauxifen-methyl (C.68a).

[0122] Exemplary agriculturally acceptable salts or esters of pyridoxal (C.69) include pyridoxal methyl ester (C.69a).

[0123] Exemplary agriculturally acceptable salts or esters of haloxyfop-P-etotyl (C.70) include haloxyfop-P-etotyl (C.70a), haloxyfop-P-methyl ester (C.70b), and mixtures thereof.

[0124] Exemplary agriculturally acceptable salts or esters of imazamox (C.72) include imazamox ammonium (C.72a).

[0125] Exemplary agriculturally acceptable salts or esters of quinaquin (C.73) include quinaquin ammonium (C.73a), quinaquin methyl (C.73b), quinaquin sodium (C.73c), and mixtures thereof.

[0126] Exemplary agriculturally acceptable salts or esters of iodiosulfuron (C.75) include iodiosulfuron methyl ester (C.75a), iodiosulfuron methyl sodium ester (C.75b), and mixtures thereof.

[0127] Exemplary agriculturally acceptable salts or esters of iodosulfuron (C.76) include iodosulfuron sodium (C.76a).

[0128] Exemplary agriculturally acceptable salts or esters of ioxonil (C.77) include lithium ioxonil (C.77a), ioxonil octanoate (C.77b), sodium ioxonil (C.77c), and mixtures thereof.

[0129] Exemplary agriculturally acceptable salts or esters of 2-methyl-4-chlorobutoxyethyl ester (C.83a), 2-methyl-4-chlorobutyl ester (C.83b), 2-methyl-4-chlorodimethylammonium (C.83c), 2-methyl-4-chlorodiethanolamine (C.83d), 2-methyl-4-chloroethyl ester (C.83e), 2-methyl-4-chloro-2-ethylhexyl ester (C.83f), 2-methyl-4-chloroisobutyl ester (C.83g), 2-methyl-4-chloroisooctyl ester (C.83h), 2-methyl-4-chloroisopropyl ester (C.83i), 2-methyl-4-chloromethyl ester (C.83j), 2-methyl-4-chloroethanolamine (C.83k), 2-methyl-4-chloropotassium (C.83l), 2-methyl-4-chlorosodium (C.83m), 2-methyl-4-chlorotriethanolamine (C.83n) and mixtures thereof.

[0130] Exemplary agriculturally acceptable salts or esters of 2-methyl-4-chlorobutyric acid (C.84) include ethyl 2-methyl-4-chlorobutyrate (C.84a), methyl 2-methyl-4-chlorobutyrate (C.84b), sodium 2-methyl-4-chlorobutyrate (C.84c), and mixtures thereof.

[0131] Exemplary agriculturally acceptable salts or esters of 2-methyl-4-chloropropionic acid (C.85) include dimethylammonium 2-methyl-4-chloropropionic acid (C.85a), diethanolamine 2-methyl-4-chloropropionic acid (C.85b), mecoprop-ethadyl (C.85c), 2-ethylhexyl 2-methyl-4-chloropropionic acid ester (C.85d), isooctyl 2-methyl-4-chloropropionic acid ester (C.85e), methyl 2-methyl-4-chloropropionic acid ester (C.85f), potassium 2-methyl-4-chloropropionic acid (C.85g), sodium 2-methyl-4-chloropropionic acid (C.85h), triethanolamine 2-methyl-4-chloropropionic acid (C.85i) and mixtures thereof.

[0132] Exemplary agriculturally acceptable salts or esters of 2-methyl-4-chloropropionic acid (C.86) include dimethylammonium 2-methyl-4-chloropropionic acid (C.86a), 2-ethylhexyl 2-methyl-4-chloropropionic acid ester (C.86b), isobutyl 2-methyl-4-chloropropionic acid ester (C.86c), potassium 2-methyl-4-chloropropionic acid (C.86d) and mixtures thereof.

[0133] Exemplary agriculturally acceptable salts or esters of mesosulfuron (C.87) include mesosulfuron methyl ester (C.87a).

[0134] Exemplary agriculturally acceptable salts or esters of metamex (C.89) include ammonium metamex (C.89a), potassium metamex (C.89b), sodium metamex (C.89c), and mixtures thereof.

[0135] Exemplary agriculturally acceptable salts or esters of metsulfuron (C.98) include metsulfuron-methyl (C.98a).

[0136] Exemplary agriculturally acceptable salts or esters of benzapropazone (C.113) include benzapropazone ethyl (C.113a).

[0137] Exemplary agriculturally acceptable salts or esters of picloram (C.114) include picloram dimethylammonium (C.114a), picloram 2-ethylhexyl ester (C.114b), picloram isooctyl ester (C.114c), picloram methyl ester (C.114d), picloram ethanolamine (C.114e), picloram potassium (C.114f), picloram triethylammonium (C.114g), picloram tri(2-hydroxypropyl)ammonium (C.114h), picloram triethanolamine (C.114i) and mixtures thereof.

[0138] Exemplary agriculturally acceptable salts or esters of propoxycarb-methyl (C.121) include propoxycarb-methyl sodium (C.121a).

[0139] Exemplary agriculturally acceptable salts or esters of pyraflufen-butyl (C.125) include pyraflufen-ethyl (C.125a).

[0140] Exemplary agriculturally acceptable salts or esters of quinclorac (C.129) include quinclorac dimethylammonium (C.129a).

[0141] Exemplary agriculturally acceptable salts or esters of quizalofop-p-ethyl (C.132) include quizalofop-p-ethyl ester (C.132a).

[0142] Exemplary agriculturally acceptable salts or esters of quizalofop-p-ethyl (C.133) include quizalofop-p-ethyl ethyl ester (C.133a), quizalofop-p-ethyl tetrahydrofuranyl methyl ester (C.133b), and mixtures thereof.

[0143] Exemplary agriculturally acceptable salts or esters of thiathionsulfuron-methyl (C.145) include thiathionsulfuron-methyl ester (C.145a).

[0144] Exemplary agriculturally acceptable salts or esters of thifensulfuron (C.146) include thifensulfuron methyl (C.146a).

[0145] Exemplary agriculturally acceptable salts or esters of tobambucil (C.148) include tobambucil sodium (C.148a).

[0146] Exemplary agriculturally acceptable salts or esters of bensulfuron (C.152) include bensulfuron-methyl (C.152a).

[0147] Exemplary agriculturally acceptable salts or esters of triclopyr-butotyl (C.153) include triclopyr-butotyl (C.153a), triclopy-ethyl (C.153b), triclopyr-butotyl triethylammonium (C.153c), and mixtures thereof.

[0148] Exemplary agriculturally acceptable salts or esters of trifloxysulfuron (C.154) include trifloxysulfuron sodium (C.154a).

[0149] Exemplary agriculturally acceptable salts or esters of trifloxysulfuron (C.157) include trifloxysulfuron methyl (C.157a).

[0150] Exemplary agriculturally acceptable salts or esters of pyrazosulfuron (C.168) include pyrazosulfuron ethyl ester (C.168a).

[0151] Exemplary agriculturally acceptable salts or esters of flucarbazone (C.170) include flucarbazone sodium (C.170a).

[0152] Exemplary agriculturally acceptable salts or esters of imazapic-methyl (C.171) include imazapic-ammonium (C.171a).

[0153] Exemplary agriculturally acceptable salts or esters of mefenacet (C.172) include mefenacet isopropylammonium (C.172a).

[0154] Exemplary agriculturally acceptable salts or esters of imazethapyr (C.173) include imazethapyr ammonium (C.173a).

[0155] Exemplary agriculturally acceptable salts or esters of cloquintocet (D.2) include cloquintocet isoheptyl (D.2a).

[0156] Exemplary agriculturally acceptable salts or esters of fenthiocarb (D.8) include fenthiocarb ethyl ester (D.8a).

[0157] Bis(phenyl)benzene Exemplary agriculturally acceptable salts or esters of oxadiazole acid (D.13) include diphenyl Ethyl oxadiazole (D.13a).

[0158] Exemplary agriculturally acceptable salts or esters of pyrrole dicarboxylic acid (D.14) include diethyl pyrrole dicarboxylate (D.14a).

[0159] In a particular embodiment of the invention, the composition comprises the herbicide A (especially (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane) and the herbicide B (especially sethoxydim (B.1) or pretilachlor (B.2)) as the only active ingredients.

[0160] In another specific embodiment of the present invention, the composition comprises as the only active ingredients a herbicide A (especially (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane), a herbicide B (especially acetochlor (B.1) or pretilachlor (B.2)) and at least one (preferably 1 to 3, more preferably 1 or 2, most preferably one) safener D selected from safeners D.1 to D.21 and their agriculturally acceptable salts, esters or amides (preferably selected from chlorpyrifos (D.1), quinoxyacetic acid (D.2), cyprodinil (D.4), chlorfenapyr (D.5), bicyclazole (D.6), chlorpyrifos (D.8), chlorpyrifos (D.9), chlorfenapyr (D.10), chlorpyrifos (D.12), biphenyl Azoles acid (D.13), pyrrole dicarboxylic acid (D.14), 4-dichloroacetyl-1-oxa-4-azaspiro[4.5]decane (MON4660, CAS 71526-07-3) (D.19), 2,2,5-trimethyl-3-dichloroacetyl-1,3- Oxazolidine (R-29148, CAS 52836-31-4) (D.20) and its agriculturally acceptable salts, esters or amides, more preferably selected from chlorpyrifos (D.1), quinoxyacetyl isoheptyl (D.2a), cyproconazole (D.4), chlorfenapyr (D.5), bicyclazole (D.6), chlorpyrifos ethyl (D.8a), chlorpyrifos (D.9), chlorfenapyr (D.10), chlorpyrifos furoate (D.12), diphenylamine (D.13), chlorpyrifos acetic acid (D.14), chlorpyrifos acetic acid (D.15), chlorpyrifos acetic acid (D.16), chlorpyrifos acetic acid (D.17), chlorpyrifos acetic acid (D.18), chlorpyrifos acetic acid (D.19), chlorpyrifos acetic acid (D.20), chlorpyrifos acetic acid (D.21), chlorpyrifos acetic acid (D.23), chlorpyrifos acetic acid (D.24), chlorpyrifos acetic acid (D.25), chlorpyrifos acetic acid (D.26), chlorpyrifos acetic acid (D.27), chlorpyrifos acetic acid (D.28), chlorpyrifos acetic acid (D.29), chlorpyrifos acetic acid (D.30), chlorpyrifos acetic acid (D.31), chlorpyrifos acetic acid (D.32), chlorpyrifos acetic acid (D.33), chlorpyrifos acetic acid (D.34), chlorpyrifos acetic acid (D.35), chlorpyri Ethyl oxadiazole (D.13a), diethyl pyrrole (D.14a), 4-dichloroacetyl-1-oxa-4-azaspiro[4.5]decane (MON4660, CAS71526-07-3) (D.19) and 2,2,5-trimethyl-3-dichloroacetyl-1,3- Oxazolidine (R-29148, CAS52836-31-4) (D.20), and even more preferably selected from chlorpyrifos (D.1), quinoxyacetyl isoheptyl (D.2a), cyproconazole (D.4), chlorfenapyr (D.5), chlorpyrifos ethyl (D.8a), chlorpyrifos (D.9), diphenyl Ethyl oxadiazole (D.13a) and diethylpyrrole (D.14a), especially selected from chlorpyrifos (D.1), quinoxaline (D.2a), cyproconazole (D.4), diphenyl Ethyl pyrrolidine (D.13a) and diethyl pyrrole (D.14a)).

[0161] In another specific embodiment of the present invention, the composition comprises as the only active ingredients a herbicide A (especially (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane), a herbicide B (especially sethoxydim (B.1) or pretilachlor (B.2)) and at least one (preferably 1-3, more preferably 1 or 2, most preferably one) herbicide C selected from the herbicides C.1-C.173 and their agriculturally acceptable salts, esters or amides (preferably selected from benzaclostrobin (C.1), aminopyralid (C.4), atrazine (C.7), tetrazosulfuron (C.8), fluazifop-butyl (C.9), benzylsulfuron (C.11), thiamethoxam (C.13), fluazifop-butyl (C.14), cypermethrin (C.15), chlorpyrifos (C.16), chlorpyrifos (C.17), chlorpyrifos (C.18), chlorpyrifos (C.19), chlorpyrifos (C.20), chlorpyrifos (C.21), chlorpyrifos (C.22), chlorpyrifos (C.23), chlorpyrifos (C.24), chlorpyrifos (C.25), chlorpyrifos (C.26), chlorpyrifos (C.27), chlorpyrifos (C.28), chlorpyrifos (C.29), chlorpyrifos (C.30), chlorpyrifos (C.31), chlorpyrifos (C.32), chlorpyrifos (C.33), chlorpyrifos (C.34), chlorpyrifos (C.35), chlorpyrifos (C.36), (C.15), bispyribac (C.16), long grass (C.18), cypermethrin (C.20), chlorotoluron (C.24), clethodim (C.25), clodinafop-butyl (C.26), isothiocarb (C.27), diclopicolinic acid (C.28), cypermethrin (C.29), cyclopyrimorate (C.30), cyfluthrin (C.31), 2,4-D (C.32), dicamba (C.36), chlorfenapyr (C.39), fluazifop-butyl (C.40), diflupyr (C.41), chlorfenapyr (C.42), dimethenamid (C.43), dimethenamid (C.44), fluthiopyralid (C.46), ethametsulfuron (C.48), cyfluthrin (C.49), Fenpyraclostrobin (C.50), high Fenpyraclostrobin (C.51), phenoxyquinoxaline (C.52), fluazifop-butyl (C.53), fluazifop-butyl (C.55), fluazifop-butyl (C.56), flufenacet (C.57), fluorine oxazolidinone (C.58), fluazifop-butyl (C.60), fluchloridone (C.61), furazolidinone (C.63), foramsulfuron (C.64), glufosinate (C.65), glufosinate (C.66), glyphosate (C.67), pyralidone (C.69), pyralidone (C.70), indazine fluazifop-butyl (C.71), imazamox (C.72), iodinesulfuron (C.75), isoproturon (C.78), isoxadiazon (C.79), isoproturon Fluorosulfuron (C.80), 2-methyl-4-chloropropionic acid (C.83), 2-methyl-4-chloropropionic acid (C.85), high 2-methyl-4-chloropropionic acid (C.86), methyl disulfone (C.87), mesotrione (C.88), metazachlor (C.91), isopropyl metolachlor (C.94), S-isopropyl metolachlor (C.95), sulfamethoxam (C.96), metribuzin (C.97), sulfamethoxam (C.98), chlorpyrifos (C.99), naphthamide (C.101), naphthamide (C.102), nicosulfuron (C.103), chlorpyrifos (C.105), propargyl Azoles (C.106), oxadiazine (C.107), oxyfluorfen (C.109), pendimethalin (C.110), penfloxacin (C.111), pethoxamid (C.112), piclopidine (C.114), fluazifop (C.115), pinoxaden (C.116), aminopropane (C.117), cypermethrin (C.118), cyfluthrin (C.119), chlorpyrifos (C.200), chloranil (C.210), chloranil (C.211), chloranil (C.212), chloranil (C.213), chloranil (C.214), chloranil (C.215), chloranil (C.216), chloranil (C.217), chloranil (C.218), chloranil (C.219), chloranil (C.221), chloranil (C.222), chloranil (C.223), chloranil (C.224), chloranil (C.225), chloranil (C.226), chloranil (C.227), chloranil (C.228), chloranil (C.229), chloranil (C.230), chloranil (C.231), chloranil (C.232), chloranil (C.233), chloranil (C.234), chloranil (C.235), chloranil (C.236), chloranil (C.237), chloranil (C.238), chloranil (C.239), chloranil (C.240), chloranil (C.241), chloranil (C.242), chloranil (C.243), 120), propansulfuron-methyl (C.121), naclofoate (C.122), bensulfuron (C.123), pyroxensulfuron (C.127), foramsulfuron (C.128), quinclorac (C.129), quinclorac (C.130), quizalofop-p-butyl (C.132), quizalofop-p-butyl (C.133), pyrazosulfuron (C.134), bensulfuron (C.135), Simazine (C.138), sulcotrione (C.139), ethyl yellow yellow sulfonate (C.141), tampron (C.142), quinone oxime grass (C.143), terbuthyl azine (C.144), thiocarbamide (C.145), tolpyralate (C.147), benzylpyraclostrobin (C.148), oxime oxadione (C.149), wild wheat chlorpyrifos (C.150), trifludimoxazin (C.155), trifluralin (C.156), trifluorosulfuron (C.158), 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)-5-fluoropyridine-2-carboxylic acid (C.159), 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)-5-fluoropyridine-2-carboxylic acid benzyl ester (CAS 1390661-72-9, C.160), cyprosulfuron (C.161), bicyclonazole (C.162), halosuflamuron (C.163), propanil (C.164), butachlor (C.165), dimethoate (C.166), pyraclostrobin (C.167), pyrazosulfuron (C.168), cypermethrin (C.169) and their agriculturally acceptable salts, esters or amides, more preferably selected from benitobutyl (C.1), atrazine (C.7), thiamethoxam (C.13), bispyribac (C.16), dicamba (C.36), diflupyrone (C.41), fluazifop (C.61), imazamox (C.72), isothiocarb (C.14), chlorpyrifos (C.15), chlorpyrifos (C.16), chlorpyrifos (C.17), chlorpyrifos (C.18), chlorpyrifos (C.19), chlorpyrifos (C.20), chlorpyrifos (C.21), chlorpyrifos (C.22), chlorpyrifos (C.23), chlorpyrifos (C.24), chlorpyrifos (C.25), chlorpyrifos (C.26), chlorpyrifos (C.27), chlorpyrifos (C.28), chlorpyrifos (C.29), chlorpyrifos (C.30), chlorpyrifos (C.31), chlorpyrifos (C.32), chlorpyrifos (C.33), chlorpyrifos (C.34), chlorpyrifos (C.35), chlorpyrifos (C.36), chlorpyrifos (C Fluorothiocarb (C.80), Mesotrione (C.88), Nicosulfuron (C.103), Propargyl Azoresulphate (C.106), pendimethalin (C.110), penoxsulam (C.111), cypermethrin (C.118), carbendazim (C.123), quinclorac (C.129), bensulfuron (C.135), cypermethrin (C.142), terbuthion (C.144), benzopyrazone (C.148), cyprosulfuron (C.161), bicyclonyl (C.162), halosuflamuron (C.163), propanil (C.164), butachlor (C.165), pyrazosulfuron (C.168) and their agriculturally acceptable salts, esters or amides).

[0162] In another specific embodiment of the present invention, the composition comprises as the only active ingredients a herbicide A (especially (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane), a herbicide B (especially sethoxydim (B.1) or pretilachlor (B.2)), at least one (preferably 1-3, more preferably 1 or 2, most preferably one) herbicide C selected from the herbicides C.1-C.173 and their agriculturally acceptable salts, esters or amides (preferably selected from benzaclostrobin (C.1), aminopyralid (C.4), atrazine (C.7), tetrazosulfuron (C.8), fluazifop-butyl (C.9), benzylsulfuron (C.11), thiamethoxam (C.13), fluazifop-butyl (C.14), cypermethrin (C.15), chlorpyrifos (C.16), chlorpyrifos (C.17), chlorpyrifos (C.18), chlorpyrifos (C.19), chlorpyrifos (C.20), chlorpyrifos (C.21), chlorpyrifos (C.22), chlorpyrifos (C.23), chlorpyrifos (C.24), chlorpyrifos (C.25), chlorpyrifos (C.26), chlorpyrifos (C.27), chlorpyrifos (C.28), chlorpyrifos (C.29), chlorpyrifos (C.30), chlorpyrifos (C.31), chlorpyrifos (C.32), chlorpyrifos (C.33), chlorpyrifos (C.34), chlorpyrifos (C.35), chlorpyrifos (C.36), chlor (C.15), bispyribac (C.16), long grass (C.18), cypermethrin (C.20), chlorotoluron (C.24), clethodim (C.25), clodinafop-butyl (C.26), isothiocarb (C.27), diclopicolinic acid (C.28), cypermethrin (C.29), cyclopyrimorate (C.30), cyfluthrin (C.31), 2,4-D (C.32), dicamba (C.36), chlorfenapyr (C.39), fluazifop-butyl (C.40), diflupyr (C.41), chlorfenapyr (C.42), dimethenamid (C.43), dimethenamid (C.44), fluthiopyralid (C.46), ethametsulfuron (C.48), cyfluthrin (C.49), Fenpyraclostrobin (C.50), high Fenpyraclostrobin (C.51), phenoxyquinoxaline (C.52), fluazifop-butyl (C.53), fluazifop-butyl (C.55), fluazifop-butyl (C.56), flufenacet (C.57), fluorine oxazolidinone (C.58), fluazifop-butyl (C.60), fluchloridone (C.61), furazolidinone (C.63), foramsulfuron (C.64), glufosinate (C.65), glufosinate (C.66), glyphosate (C.67), pyralidone (C.69), pyralidone (C.70), indazine fluazifop-butyl (C.71), imazamox (C.72), iodinesulfuron (C.75), isoproturon (C.78), isoxadiazon (C.79), isoproturon Fluorosulfuron (C.80), 2-methyl-4-chloropropionic acid (C.83), 2-methyl-4-chloropropionic acid (C.85), high 2-methyl-4-chloropropionic acid (C.86), methyl disulfone (C.87), mesotrione (C.88), metazachlor (C.91), isopropyl metolachlor (C.94), S-isopropyl metolachlor (C.95), sulfamethoxam (C.96), metribuzin (C.97), sulfamethoxam (C.98), chlorpyrifos (C.99), naphthamide (C.101), naphthamide (C.102), nicosulfuron (C.103), chlorpyrifos (C.105), propargyl Azoles (C.106), oxadiazine (C.107), oxyfluorfen (C.109), pendimethalin (C.110), penfloxacin (C.111), pethoxamid (C.112), piclopidine (C.114), fluazifop (C.115), pinoxaden (C.116), aminopropane (C.117), cypermethrin (C.118), cyfluthrin (C.119), chlorpyrifos (C.200), chloranil (C.210), chloranil (C.211), chloranil (C.212), chloranil (C.213), chloranil (C.214), chloranil (C.215), chloranil (C.216), chloranil (C.217), chloranil (C.218), chloranil (C.219), chloranil (C.221), chloranil (C.222), chloranil (C.223), chloranil (C.224), chloranil (C.225), chloranil (C.226), chloranil (C.227), chloranil (C.228), chloranil (C.229), chloranil (C.230), chloranil (C.231), chloranil (C.232), chloranil (C.233), chloranil (C.234), chloranil (C.235), chloranil (C.236), chloranil (C.237), chloranil (C.238), chloranil (C.239), chloranil (C.240), chloranil (C.241), chloranil (C.242), chloranil (C.243), 120), propansulfuron-methyl (C.121), naclofoate (C.122), bensulfuron (C.123), pyroxensulfuron (C.127), foramsulfuron (C.128), quinclorac (C.129), quinclorac (C.130), quizalofop-p-butyl (C.132), quizalofop-p-butyl (C.133), pyrazosulfuron (C.134), bensulfuron (C.135), Simazine (C.138), sulcotrione (C.139), ethyl yellow yellow sulfonate (C.141), tampron (C.142), quinone oxime grass (C.143), terbuthyl azine (C.144), thiocarbamide (C.145), tolpyralate (C.147), benzylpyraclostrobin (C.148), oxime oxadione (C.149), wild wheat chlorpyrifos (C.150), trifludimoxazin (C.155), trifluralin (C.156), trifluorosulfuron (C.158), 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)-5-fluoropyridine-2-carboxylic acid (C.159), 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)-5-fluoropyridine-2-carboxylic acid benzyl ester (CAS 1390661-72-9, C.160), cyprosulfuron (C.161), bicyclonazole (C.162), halosuflamuron (C.163), propanil (C.164), butachlor (C.165), dimethoate (C.166), pyraclostrobin (C.167), pyrazosulfuron (C.168), cypermethrin (C.169) and their agriculturally acceptable salts, esters or amides, more preferably selected from benitobutyl (C.1), atrazine (C.7), thiamethoxam (C.13), bispyribac (C.16), dicamba (C.36), diflupyrone (C.41), fluazifop (C.61), imazamox (C.72), isothiocarb (C.14), chlorpyrifos (C.15), chlorpyrifos (C.16), chlorpyrifos (C.17), chlorpyrifos (C.18), chlorpyrifos (C.19), chlorpyrifos (C.20), chlorpyrifos (C.21), chlorpyrifos (C.22), chlorpyrifos (C.23), chlorpyrifos (C.24), chlorpyrifos (C.25), chlorpyrifos (C.26), chlorpyrifos (C.27), chlorpyrifos (C.28), chlorpyrifos (C.29), chlorpyrifos (C.30), chlorpyrifos (C.31), chlorpyrifos (C.32), chlorpyrifos (C.33), chlorpyrifos (C.34), chlorpyrifos (C.35), chlorpyrifos (C.36), chlorpyrifos (C Fluorothiocarb (C.80), Mesotrione (C.88), Nicosulfuron (C.103), Propargyl Azoles(C.106), Pendimethalin(C.110), Penoxsulam(C.111), Cyclohexanil(C.118), Benthiocarb(C.123), Quinclorac(C.129), Bensulfuron(C.135), Cyproconazole(C.142), Terbuthylazine(C.144), Benpyraclostrobin(C.148), Cyprosulfuron(C.161), Bicyclonylsulfuron(C.162), Halosuflamuron(C.163), Dipyridamole(C.164), Butachlor( C.165), pyrazosulfuron (C.168) and its agriculturally acceptable salts, esters or amides) and at least one (preferably 1-3, more preferably 1 or 2, most preferably one) selected from safeners D.1-D.21 and their agriculturally acceptable salts, esters or amides of safeners D (preferably selected from chlorpyrifos (D.1), quinoxyacetic acid (D.2), cyprodinil (D.4), chlorfenapyr (D.5), dicyclopentadione (D.6), chlorfenapyr (D.8), chlorpyrifos (D.9), chloranil (D.10), chlorpyrifos (D.12), diphenylamine (D.13), chlorpyrifos (D.14), chloranil (D.15), chloranil (D.16), chloranil (D.17), chloranil (D.18), chloranil (D.19), chloranil (D.20), chloranil (D.21), chloranil (D.22), chloranil (D.23), chloranil (D.24), chloranil (D.25), chloranil (D.26), chloranil (D.27), chloranil (D.28), chloranil (D.29), chloranil (D.30), chloranil (D.31), chloranil (D.32), chloranil (D.33), chloranil (D.34), chloranil (D.35), chloranil (D.36), chloranil (D.37), chloranil (D.38), chloranil (D.39), chloranil (D.40), chloranil (D.41), chloranil (D.42), chloranil (D.43), chloran Azoles acid (D.13), pyrrole dicarboxylic acid (D.14), 4-dichloroacetyl-1-oxa-4-azaspiro[4.5]decane (MON4660, CAS 71526-07-3) (D.19), 2,2,5-trimethyl-3-dichloroacetyl-1,3- Oxazolidine (R-29148, CAS 52836-31-4) (D.20) and its agriculturally acceptable salts, esters or amides, more preferably selected from chlorpyrifos (D.1), quinoxyacetyl isoheptyl (D.2a), cyproconazole (D.4), chlorfenapyr (D.5), bicyclazole (D.6), chlorpyrifos ethyl (D.8a), chlorpyrifos (D.9), chlorfenapyr (D.10), chlorpyrifos furoate (D.12), diphenylamine (D.13), chlorpyrifos acetic acid (D.14), chlorpyrifos acetic acid (D.15), chlorpyrifos acetic acid (D.16), chlorpyrifos acetic acid (D.17), chlorpyrifos acetic acid (D.18), chlorpyrifos acetic acid (D.19), chlorpyrifos acetic acid (D.20), chlorpyrifos acetic acid (D.21), chlorpyrifos acetic acid (D.23), chlorpyrifos acetic acid (D.24), chlorpyrifos acetic acid (D.25), chlorpyrifos acetic acid (D.26), chlorpyrifos acetic acid (D.27), chlorpyrifos acetic acid (D.28), chlorpyrifos acetic acid (D.29), chlorpyrifos acetic acid (D.30), chlorpyrifos acetic acid (D.31), chlorpyrifos acetic acid (D.32), chlorpyrifos acetic acid (D.33), chlorpyrifos acetic acid (D.34), chlorpyrifos acetic acid (D.35), chlorpyri Ethyl oxadiazole (D.13a), diethyl pyrrole (D.14a), 4-dichloroacetyl-1-oxa-4-azaspiro[4.5]decane (MON4660, CAS 71526-07-3) (D.19) and 2,2,5-trimethyl-3-dichloroacetyl-1,3- Oxazolidine (R-29148, CAS 52836-31-4) (D.20), and even more preferably selected from chlorpyrifos (D.1), quinoxyacetate isoheptyl (D.2a), cyproconazole (D.4), chlorfenapyr (D.5), chlorpyrifos ethyl (D.8a), chlorpyrifos (D.9), diphenyl Ethyl oxadiazole (D.13a) and diethylpyrrole (D.14a), especially selected from chlorpyrifos (D.1), quinoxaline (D.2a), cyproconazole (D.4), diphenyl Ethyl pyrrolidine (D.13a) and diethyl pyrrole (D.14a)).

[0163] Of particular interest are the herbicidal compositions of the invention comprising the following combinations of three active ingredients (herbicide A + herbicide B + herbicide C): A+B.1 (or B.2) + C.1, A+B.1 (or B.2) + C.2, A+B.1 (or B.2) + C.3, A+B.1 (or B.2) + C.4, A+B.1 (or B.2) + C.4a, A+B.1 (or B.2) + C.4b, A+B.1 (or B.2) + C.4c, A+B.1 (or B.2) + C.5, A+B.1 (or B.2) + C.6, A+B.1 (or B.2) + C.6a, A+B.1 (or B.2) + C.6b, A+B.1 (or B.2) + C.7, A+B.1 (or B.2) + C.8 .1(or B.2)+C.8, A+B.1(or B.2)+C.9, A+B.1(or B.2)+C.10, A+B.1(or B.2)+C.11, A+B.1(or B.2)+C.11a, A+B.1(or B.2)+C.12, A+B.1(or B.2)+C.13, A+B.1(or B.2 )+C.13a, A+B.1(or B.2)+C.14, A+B.1(or B.2)+C.15, A+B.1(or B.2)+C.16, A+B.1(or B.2)+C.16a, A+B.1(or B.2)+C.17, A+B.1(or B.2)+C.17a, A+B.1(or B.2)+C .17b, A+B.1(or B.2)+C.17c, A+B.1(or B.2)+C.17d, A+B.1(or B.2)+C.18, A+B.1(or B.2)+C.19, A+B.1(or B.2)+C.19a, A+B.1(or B.2)+C.20, A+B.1(or B.2)+C. 21, A+B.1(or B.2)+C.22, A+B.1(or B.2)+C.23, A+B.1(or B.2)+C.23a, A+B.1(or B.2)+C.23b, A+B.1(or B.2)+C.24, A+B.1(or B.2)+C.25, A+B.1(or B.2)+C.26, A +B.1(or B.2)+C.26a, A+B.1(or B.2)+C.27, A+B.1(or B.2)+C.28, A+B.1(or B.2)+C.28a, A+B.1(or B.2)+C.28b, A+B.1(or B.2)+C.28c, A+B.1(or B.2)+C.28d, A+ B.1 (or B.2) + C.28e, A + B.1 (or B.2) + C.28f, A + B.1 (or B.2) + C.28g, A + B.1 (or B.2) + C.29, A + B.1 (or B.2) + C.30, A + B.1 (or B.2) + C.31, A + B.1 (or B.2) + C.31a, A + B.1(or B.2)+C.32, A+B.1(or B.2)+C.32a, A+B.1(or B.2)+C.32b, A+B.1(or B.2)+C.32c, A+B.1(or B.2)+C.32d, A+B.1(or B.2)+C.32e, A+B.1(or B.2)+C.32f, A+B .1(or B.2)+C.32g, A+B.1(or B.2)+C.32h, A+B.1(or B.2)+C.32i, A+B.1(or B.2)+C.32j, A+B.1(or B.2)+C.32k, A+B.1(or B.2)+C.32l, A+B.1(or B.2)+C.32m, A+ B.1(or B.2)+C.32n, A+B.1(or B.2)+C.32o, A+B.1(or B.2)+C.32p, A+B.1(or B.2)+C.32q, A+B.1(or B.2)+C.32r, A+B.1(or B.2)+C.32s, A+B.1(or B.2)+C.32t, A+B.1(or B.2)+C.32u, A+B.1(or B.2)+C.32v, A+B.1(or B.2)+C.32w, A+B.1(or B.2)+C.32x, A+B.1(or B.2)+C.32y, A+B.1(or B.2)+C.32z, A+B.1(or B.2)+C.32z x, A+B.1(or B.2)+C.32zy, A+B.1(or B.2)+C.33, A+B.1(or B.2)+C.33a, A+B.1(or B.2)+C.34, A+B.1(or B.2)+C.34a, A+B.1(or B.2)+C.34b, A+B.1(or B.2)+C.3 4c, A+B.1(or B.2)+C.34d, A+B.1(or B.2)+C.34e, A+B.1(or B.2)+C.35, A+B.1(or B.2)+C.36, A+B.1(or B.2)+C.36a, A+B.1(or B.2)+C.36b, A+B.1(or B.2)+C.36 c, A+B.1(or B.2)+C.36d, A+B.1(or B.2)+C.36e, A+B.1(or B.2)+C.36f, A+B.1(or B.2)+C.36g, A+B.1(or B.2)+C.36h, A+B.1(or B.2)+C.36i, A+B.1(or B.2)+C. 36j, A+B.1(or B.2)+C.36k, A+B.1(or B.2)+C.36l, A+B.1(or B.2)+C.36m, A+B.1(or B.2)+C.37, A+B.1(or B.2)+C.37a, A+B.1(or B.2)+C.37b, A+B.1(or B.2)+C.37c, A+B.1(or B.2)+C.37d, A+B.1(or B.2)+C.37e, A+B.1(or B.2)+C.37f, A+B.1(or B.2)+C.37g, A+B.1(or B.2)+C.37h, A+B.1(or B.2)+C.38, A+B.1(or B.2)+C .38a, A+B.1(or B.2)+C.38b, A+B.1(or B.2)+C.38c, A+B.1(or B.2)+C.38d, A+B.1(or B.2)+C.39, A+B.1(or B.2)+C.39a, A+B.1(or B.2)+C.40, A+B.1(or B.2)+C. 41, A+B.1(or B.2)+C.41a, A+B.1(or B.2)+C.42, A+B.1(or B.2)+C.43, A+B.1(or B.2)+C.44, A+B.1(or B.2)+C.45, A+B.1(or B.2)+C.45a, A+B.1(or B.2)+C.46, A+B.1(or B.2)+C.47, A+B.1(or B.2)+C.48, A+B.1(or B.2)+C.48a, A+B.1(or B.2)+C.49, A+B.1(or B.2)+C.50, A+B.1(or B.2)+C.50a, A+B.1(or B.2)+C.51, A+B. 1(or B.2)+C.51a, A+B.1(or B.2)+C.52, A+B.1(or B.2)+C.53, A+B.1(or B.2)+C.54, A+B.1(or B.2)+C.55, A+B.1(or B.2)+C.55a, A+B.1(or B.2)+C.55b, A+B.1( or B.2)+C.56, A+B.1(or B.2)+C.56a, A+B.1(or B.2)+C.57, A+B.1(or B.2)+C.58, A+B.1(or B.2)+C.59, A+B.1(or B.2)+C.60, A+B.1(or B.2)+C.60a, A+B.1(or B.2 )+C.60b, A+B.1(or B.2)+C.61, A+B.1(or B.2)+C.62, A+B.1(or B.2)+C.62a, A+B.1(or B.2)+C.62b, A+B.1(or B.2)+C.63, A+B.1(or B.2)+C.64, A+B.1(or B.2)+ C.65, A+B.1(or B.2)+C.65a, A+B.1(or B.2)+C.66, A+B.1(or B.2)+C.66a, A+B.1(or B.2)+C.66b, A+B.1(or B.2)+C.67, A+B.1(or B.2)+C.67a, A+B.1(or B.2)+C.67b, A+B.1(or B.2)+C.67c, A+B.1(or B.2)+C.67d, A+B.1(or B.2)+C.67e, A+B.1(or B.2)+C.67f, A+B.1(or B.2)+C.67g, A+B.1(or B.2)+C.67h, A+B.1(or B.2)+ C.67i, A+B.1(or B.2)+C.67j, A+B.1(or B.2)+C.68, A+B.1(or B.2)+C.68a, A+B.1(or B.2)+C.69, A+B.1(or B.2)+C.69a, A+B.1(or B.2)+C.70, A+B.1(or B.2)+C. 70a, A+B.1(or B.2)+C.70b, A+B.1(or B.2)+C.71, A+B.1(or B.2)+C.72, A+B.1(or B.2)+C.72a, A+B.1(or B.2)+C.73, A+B.1(or B.2)+C.73a, A+B.1(or B.2)+C.73 b, A+B.1(or B.2)+C.73c, A+B.1(or B.2)+C.74, A+B.1(or B.2)+C.75, A+B.1(or B.2)+C.75a, A+B.1(or B.2)+C.75b, A+B.1(or B.2)+C.76, A+B.1(or B.2)+C.76a, A+B.1(or B.2)+C.77, A+B.1(or B.2)+C.77a, A+B.1(or B.2)+C.77b, A+B.1(or B.2)+C.77c, A+B.1(or B.2)+C.78, A+B.1(or B.2)+C.79, A+B.1(or B.2)+C.80, A+B .1(or B.2)+C.81, A+B.1(or B.2)+C.82, A+B.1(or B.2)+C.83, A+B.1(or B.2)+C.83a, A+B.1(or B.2)+C.83b, A+B.1(or B.2)+C.83c, A+B.1(or B.2)+C.83d, A+B.1 (or B.2)+C.83e, A+B.1(or B.2)+C.83f, A+B.1(or B.2)+C.83g, A+B.1(or B.2)+C.83h, A+B.1(or B.2)+C.83i, A+B.1(or B.2)+C.83j, A+B.1(or B.2)+C.83k, A+B. 1(or B.2)+C.83l, A+B.1(or B.2)+C.83m, A+B.1(or B.2)+C.83n, A+B.1(or B.2)+C.84, A+B.1(or B.2)+C.84a, A+B.1(or B.2)+C.84b, A+B.1(or B.2)+C.84c, A+B.1(or B.2)+C.85, A+B.1(or B.2)+C.85a, A+B.1(or B.2)+C.85b, A+B.1(or B.2)+C.85c, A+B.1(or B.2)+C.85d, A+B.1(or B.2)+C.85e, A+B.1(or B.2)+C.85f, A+B. 1(or B.2)+C.85g, A+B.1(or B.2)+C.85h, A+B.1(or B.2)+C.85i, A+B.1(or B.2)+C.86, A+B.1(or B.2)+C.86a, A+B.1(or B.2)+C.86b, A+B.1(or B.2)+C.86c, A+B. 1(or B.2)+C.86d, A+B.1(or B.2)+C.87, A+B.1(or B.2)+C.87a, A+B.1(or B.2)+C.88, A+B.1(or B.2)+C.89, A+B.1(or B.2)+C.89a, A+B.1(or B.2)+C.89b, A+B.1( or B.2)+C.89c, A+B.1(or B.2)+C.90, A+B.1(or B.2)+C.91, A+B.1(or B.2)+C.92, A+B.1(or B.2)+C.93, A+B.1(or B.2)+C.94, A+B.1(or B.2)+C.95, A+B.1(or B.2) +C.96, A+B.1(or B.2)+C.97, A+B.1(or B.2)+C.98, A+B.1(or B.2)+C.98a, A+B.1(or B.2)+C.99, A+B.1(or B.2)+C.100, A+B.1(or B.2)+C.101, A+B.1(or B.2)+C. 102, A+B.1(or B.2)+C.103, A+B.1(or B.2)+C.104, A+B.1(or B.2)+C.105, A+B.1(or B.2)+C.106, A+B.1(or B.2)+C.107, A+B.1(or B.2)+C.108, A+B.1(or B.2)+C .109, A+B.1(or B.2)+C.110, A+B.1(or B.2)+C.111, A+B.1(or B.2)+C.112, A+B.1(or B.2)+C.113, A+B.1(or B.2)+C.113a, A+B.1(or B.2)+C.114, A+B.1(or B.2) +C.114a, A+B.1(or B.2)+C.114b, A+B.1(or B.2)+C.114c, A+B.1(or B.2)+C.114d, A+B.1(or B.2)+C.114e, A+B.1(or B.2)+C.114f, A+B.1(or B.2)+C.114g, A+B.1(or B.2)+C.114h, A+B.1(or B.2)+C.114i, A+B.1(or B.2)+C.115, A+B.1(or B.2)+C.116, A+B.1(or B.2)+C.117, A+B.1(or B.2)+C.118, A+B.1(or B.2)+C.119, A+B.1(or B.2)+C.120, A+B.1(or B.2)+C.121, A+B.1(or B.2)+C.121a, A+B.1(or B.2)+C.122, A+B.1(or B.2)+C.123, A+B.1(or B.2)+C.124, A+B.1(or B.2)+C.12 5, A+B.1(or B.2)+C.125a, A+B.1(or B.2)+C.126, A+B.1(or B.2)+C.127, A+B.1(or B.2)+C.128, A+B.1(or B.2)+C.129, A+B.1(or B.2)+C.129a, A+B.1(or B.2)+ C.130, A+B.1(or B.2)+C.131, A+B.1(or B.2)+C.132, A+B.1(or B.2)+C.132a, A+B.1(or B.2)+C.133, A+B.1(or B.2)+C.133a, A+B.1(or B.2)+C.133b, A+B.1(or B.2)+C.133 .2)+C.134, A+B.1(or B.2)+C.135, A+B.1(or B.2)+C.136, A+B.1(or B.2)+C.137, A+B.1(or B.2)+C.138, A+B.1(or B.2)+C.139, A+B.1(or B.2)+C.140, A+B.1( or B.2)+C.141, A+B.1(or B.2)+C.142, A+B.1(or B.2)+C.143, A+B.1(or B.2)+C.144, A+B.1(or B.2)+C.145, A+B.1(or B.2)+C.145a, A+B.1(or B.2)+C.146, A+B. 1(or B.2)+C.146a, A+B.1(or B.2)+C.147, A+B.1(or B.2)+C.148, A+B.1(or B.2)+C.148a, A+B.1(or B.2)+C.149, A+B.1(or B.2)+C.150, A+B.1(or B.2)+C.151, A +B.1(or B.2)+C.152, A+B.1(or B.2)+C.152a, A+B.1(or B.2)+C.153, A+B.1(or B.2)+C.153a, A+B.1(or B.2)+C.153b, A+B.1(or B.2)+C.153c, A+B.1(or B.2)+C.154, A+B.1(or B.2)+C.154a, A+B.1(or B.2)+C.155, A+B.1(or B.2)+C.156, A+B.1(or B.2)+C.157, A+B.1(or B.2)+C.157a, A+B.1(or B.2)+C.158, A+B.1(or B.2)+C.159, A+B.1(or B.2)+C.160, A+B.1(or B.2)+C.161, A+B.1(or B.2)+C.162, A+B.1(or B.2)+C.163, A+B.1(or B.2)+C.164, A+B.1(or B.2)+C.165 , A+B.1(or B.2)+C.166, A+B.1(or B.2)+C.167, A+B.1(or B.2)+C.168, A+B.1(or B.2)+C.168a, A+B.1(or B.2)+C.169, A+B.1(or B.2)+C.170, A+B.1(or B.2)+C.170a, A+B.1(or B.2)+C.171, A+B.1(or B.2)+C.171a, A+B.1(or B.2)+C.172, A+B.1(or B.2)+C.172a, A+B.1(or B.2)+C.173, A+B.1(or B.2)+C.173a. .

[0164] Of particular interest are also the herbicidal compositions of the invention comprising the following combinations of three active ingredients (herbicide A + herbicide B + safener D): A+B.1 (or B.2) + D.1, A+B.1 (or B.2) + D.2, A+B.1 (or B.2) + D.2a, A+B.1 (or B.2) + D.3, A+B.1 (or B.2) + D.4, A+B.1 (or B.2) + D.5, A+B.1 (or B.2) + D.6, A+B.1 (or B.2) + D.7, A+B.1 (or B.2) + D.8, A+B.1 (or B.2) + D.8a, A+B.1 (or B.2) + D.9, A+B.1 (or B.2) + D.10, A+B.1 (or B.2) + D.11, A+B.1 (or B.2) + D.12, A+B.1 (or B.2) + D.13, A+B.1 (or B.2) + D.14, A+B.1 (or B.2) + D.15, A+B.1 (or B.2) + D.16, A+B.1 (or B.2) + D.17, A+B.1 (or B.2) + D.18, A+B.1 (or B.2) + D.19, A+B.1 (or B.2) + (or B.2) + D.10, A+B.1(or B.2) + D.11, A+B.1(or B.2) + D.12, A+B.1(or B.2) + D.13, A+B.1(or B.2) + D.13a, A+B.1(or B.2) + D.14, A+B.1(or B.2) + D.14a, A+B.1(or B.2) + D.15, A+B.1(or B.2) + D.16, A+B.1(or B.2) + D.17, A+B.1(or B.2) + D.18, A+B.1(or B.2) + D.19, A+B.1(or B.2) + D.20, A+B.1(or B.2) + D.21.

[0165] Of particular interest are the herbicidal compositions of the invention comprising the following combinations of four active ingredients (herbicide A + herbicide B + herbicide C + safener D): A+B.1 (or B.2) + C.1 + D.1, A+B.1 (or B.2) + C.2 + D.1, A+B.1 (or B.2) + C.3 + D.1, A+B.1 (or B.2) + C.4 + D.1, A+B.1 (or B.2) + C.4a + D.1, A+B.1 (or B.2) + C.4b + D.1, A+B.1 (or B.2) + C.4c + D.1, A+B.1 (or B.2) + C.5 + D.1, A+B.1 (or B.2) + C.6 + D.1, A+B.1 (or B.2) + C.7+ D.1 .6a+D.1, A+B.1(or B.2)+C.6b+D.1, A+B.1(or B.2)+C.7+D.1, A+B.1(or B.2)+C.8+D.1, A+B.1(or B.2)+C.9+D.1, A+B.1(or B.2)+C.10+D.1, A+B.1(or B.2)+C.1 1+D.1,A+B.1(or B.2)+C.11a+D.1,A+B.1(or B.2)+C.12+D.1,A+B.1(or B.2)+C.13+D.1,A+B.1(or B.2)+C.13a+D.1,A+B.1(or B.2)+C.14+D.1,A+B.1(or B.2)+ C.15+D.1, A+B.1(or B.2)+C.16+D.1, A+B.1(or B.2)+C.16a+D.1, A+B.1(or B.2)+C.17+D.1, A+B.1(or B.2)+C.17a+D.1, A+B.1(or B.2)+C.17b+D.1, A+B.1(or B.2) .2)+C.17c+D.1,A+B.1(or B.2)+C.17d+D.1,A+B.1(or B.2)+C.18+D.1,A+B.1(or B.2)+C.19+D.1,A+B.1(or B.2)+C.19a+D.1,A+B.1(or B.2)+C.20+D.1,A+B. 1(or B.2)+C.21+D.1,A+B.1(or B.2)+C.22+D.1,A+B.1(or B.2)+C.23+D.1,A+B.1(or B.2)+C.23a+D.1,A+B.1(or B.2)+C.23b+D.1,A+B.1(or B.2)+C.24+D.1,A +B.1(or B.2)+C.25+D.1, A+B.1(or B.2)+C.26+D.1, A+B.1(or B.2)+C.26a+D.1, A+B.1(or B.2)+C.27+D.1, A+B.1(or B.2)+C.28+D.1, A+B.1(or B.2)+C.28a+D.1, A+B.1(or B.2)+C.28b+D.1, A+B.1(or B.2)+C.28c+D.1, A+B.1(or B.2)+C.28d+D.1, A+B.1(or B.2)+C.28e+D.1, A+B.1(or B.2)+C.28f+D.1, A+B.1(or B.2)+ C.28g+D.1, A+B.1(or B.2)+C.29+D.1, A+B.1(or B.2)+C.30+D.1, A+B.1(or B.2)+C.31+D.1, A+B.1(or B.2)+C.31a+D.1, A+B.1(or B.2)+C.32+D.1, A+B.1(or B.2) 2)+C.32a+D.1,A+B.1(or B.2)+C.32b+D.1,A+B.1(or B.2)+C.32c+D.1,A+B.1(or B.2)+C.32d+D.1,A+B.1(or B.2)+C.32e+D.1,A+B.1(or B.2)+C.32f+D.1,A +B.1(or B.2)+C.32g+D.1,A+B.1(or B.2)+C.32h+D.1,A+B.1(or B.2)+C.32i+D.1,A+B.1(or B.2)+C.32j+D.1,A+B.1(or B.2)+C.32k+D.1,A+B.1(or B.2)+C.32 l+D.1,A+B.1(or B.2)+C.32m+D.1,A+B.1(or B.2)+C.32n+D.1,A+B.1(or B.2)+C.32o+D.1,A+B.1(or B.2)+C.32p+D.1,A+B.1(or B.2)+C.32q+D.1,A+B.1(or B.2) .2)+C.32r+D.1,A+B.1(or B.2)+C.32s+D.1,A+B.1(or B.2)+C.32t+D.1,A+B.1(or B.2)+C.32u+D.1,A+B.1(or B.2)+C.32v+D.1,A+B.1(or B.2)+C.32w+D.1,A +B.1(or B.2)+C.32x+D.1,A+B.1(or B.2)+C.32y+D.1,A+B.1(or B.2)+C.32z+D.1,A+B.1(or B.2)+C.32zx+D.1,A+B.1(or B.2)+C.32zy+D.1,A+B.1(or B.2)+C. 33+D.1,A+B.1(or B.2)+C.33a+D.1,A+B.1(or B.2)+C.34+D.1,A+B.1(or B.2)+C.34a+D.1,A+B.1(or B.2)+C.34b+D.1,A+B.1(or B.2)+C.34c+D.1,A+B.1(or B.2)+C.2)+C.34d+D.1,A+B.1(or B.2)+C.34e+D.1,A+B.1(or B.2)+C.35+D.1,A+B.1(or B.2)+C.36+D.1,A+B.1(or B.2)+C.36a+D.1,A+B.1(or B.2)+C.36b+D.1,A+B .1(or B.2)+C.36c+D.1,A+B.1(or B.2)+C.36d+D.1,A+B.1(or B.2)+C.36e+D.1,A+B.1(or B.2)+C.36f+D.1,A+B.1(or B.2)+C.36g+D.1,A+B.1(or B.2)+C.36h+ D.1, A+B.1(or B.2)+C.36i+D.1, A+B.1(or B.2)+C.36j+D.1, A+B.1(or B.2)+C.36k+D.1, A+B.1(or B.2)+C.36l+D.1, A+B.1(or B.2)+C.36m+D.1, A+B.1(or B.2 )+C.37+D.1,A+B.1(or B.2)+C.37a+D.1,A+B.1(or B.2)+C.37b+D.1,A+B.1(or B.2)+C.37c+D.1,A+B.1(or B.2)+C.37d+D.1,A+B.1(or B.2)+C.37e+D.1,A+B. 1(or B.2)+C.37f+D.1,A+B.1(or B.2)+C.37g+D.1,A+B.1(or B.2)+C.37h+D.1,A+B.1(or B.2)+C.38+D.1,A+B.1(or B.2)+C.38a+D.1,A+B.1(or B.2)+C.38b+D. .1, A+B.1(or B.2)+C.38c+D.1, A+B.1(or B.2)+C.38d+D.1, A+B.1(or B.2)+C.39+D.1, A+B.1(or B.2)+C.39a+D.1, A+B.1(or B.2)+C.40+D.1, A+B.1(or B.2)+C. 41+D.1,A+B.1(or B.2)+C.41a+D.1,A+B.1(or B.2)+C.42+D.1,A+B.1(or B.2)+C.43+D.1,A+B.1(or B.2)+C.44+D.1,A+B.1(or B.2)+C.45+D.1,A+B.1(or B.2)+ C.45a+D.1, A+B.1(or B.2)+C.46+D.1, A+B.1(or B.2)+C.47+D.1, A+B.1(or B.2)+C.48+D.1, A+B.1(or B.2)+C.48a+D.1, A+B.1(or B.2)+C.49+D.1, A+B.1(or B.2)+C.50+D.1,A+B.1(or B.2)+C.50a+D.1,A+B.1(or B.2)+C.51+D.1,A+B.1(or B.2)+C.51a+D.1,A+B.1(or B.2)+C.52+D.1,A+B.1(or B.2)+C.53+D.1,A+B.1 (or B.2)+C.54+D.1,A+B.1(or B.2)+C.55+D.1,A+B.1(or B.2)+C.55a+D.1,A+B.1(or B.2)+C.55b+D.1,A+B.1(or B.2)+C.56+D.1,A+B.1(or B.2)+C.56a+D.1,A +B.1(or B.2)+C.57+D.1,A+B.1(or B.2)+C.58+D.1,A+B.1(or B.2)+C.59+D.1,A+B.1(or B.2)+C.60+D.1,A+B.1(or B.2)+C.60a+D.1,A+B.1(or B.2)+C.60b+D .1, A+B.1(or B.2)+C.61+D.1, A+B.1(or B.2)+C.62+D.1, A+B.1(or B.2)+C.62a+D.1, A+B.1(or B.2)+C.62b+D.1, A+B.1(or B.2)+C.63+D.1, A+B.1(or B.2)+C.6 4+D.1,A+B.1(or B.2)+C.65+D.1,A+B.1(or B.2)+C.65a+D.1,A+B.1(or B.2)+C.66+D.1,A+B.1(or B.2)+C.66a+D.1,A+B.1(or B.2)+C.66b+D.1,A+B.1(or B.2 )+C.67+D.1,A+B.1(or B.2)+C.67a+D.1,A+B.1(or B.2)+C.67b+D.1,A+B.1(or B.2)+C.67c+D.1,A+B.1(or B.2)+C.67d+D.1,A+B.1(or B.2)+C.67e+D.1,A+B. 1(or B.2)+C.67f+D.1,A+B.1(or B.2)+C.67g+D.1,A+B.1(or B.2)+C.67h+D.1,A+B.1(or B.2)+C.67i+D.1,A+B.1(or B.2)+C.67j+D.1,A+B.1(or B.2)+C.68+D .1, A+B.1(or B.2)+C.68a+D.1, A+B.1(or B.2)+C.69+D.1, A+B.1(or B.2)+C.69a+D.1, A+B.1(or B.2)+C.70+D.1, A+B.1(or B.2)+C.70a+D.1, A+B.1(or B.2)+C.70b+D.1,A+B.1(or B.2)+C.71+D.1,A+B.1(or B.2)+C.72+D.1,A+B.1(or B.2)+C.72a+D.1,A+B.1(or B.2)+C.73+D.1,A+B.1(or B.2)+C.73a+D.1,A+B.1(or B.2)+C. 2)+C.73b+D.1,A+B.1(or B.2)+C.73c+D.1,A+B.1(or B.2)+C.74+D.1,A+B.1(or B.2)+C.75+D.1,A+B.1(or B.2)+C.75a+D.1,A+B.1(or B.2)+C.75b+D.1,A+B. 1(or B.2)+C.76+D.1,A+B.1(or B.2)+C.76a+D.1,A+B.1(or B.2)+C.77+D.1,A+B.1(or B.2)+C.77a+D.1,A+B.1(or B.2)+C.77b+D.1,A+B.1(or B.2)+C.77c+D. 1, A+B.1(or B.2)+C.78+D.1, A+B.1(or B.2)+C.79+D.1, A+B.1(or B.2)+C.80+D.1, A+B.1(or B.2)+C.81+D.1, A+B.1(or B.2)+C.82+D.1, A+B.1(or B.2)+C.83+D .1, A+B.1(or B.2)+C.83a+D.1, A+B.1(or B.2)+C.83b+D.1, A+B.1(or B.2)+C.83c+D.1, A+B.1(or B.2)+C.83d+D.1, A+B.1(or B.2)+C.83e+D.1, A+B.1(or B.2) +C.83f+D.1,A+B.1(or B.2)+C.83g+D.1,A+B.1(or B.2)+C.83h+D.1,A+B.1(or B.2)+C.83i+D.1,A+B.1(or B.2)+C.83j+D.1,A+B.1(or B.2)+C.83k+D.1,A+B. 1(or B.2)+C.83l+D.1,A+B.1(or B.2)+C.83m+D.1,A+B.1(or B.2)+C.83n+D.1,A+B.1(or B.2)+C.84+D.1,A+B.1(or B.2)+C.84a+D.1,A+B.1(or B.2)+C.84b+D. 1, A+B.1(or B.2)+C.84c+D.1, A+B.1(or B.2)+C.85+D.1, A+B.1(or B.2)+C.85a+D.1, A+B.1(or B.2)+C.85b+D.1, A+B.1(or B.2)+C.85c+D.1, A+B.1(or B.2)+C.85d+D.1,A+B.1(or B.2)+C.85e+D.1,A+B.1(or B.2)+C.85f+D.1,A+B.1(or B.2)+C.85g+D.1,A+B.1(or B.2)+C.85h+D.1,A+B.1(or B.2)+C.85i+D.1,A+B.1(or B.2)+C.86+D.1,A+B.1(or B.2)+C.86a+D.1,A+B.1(or 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A+B.1(or B.2)+C.36l+D.2a, A+B.1(or B.2)+C.36m+D.2a, A+B.1(or B.2)+C.37+D.2a, A+B.1 (or B.2)+C.37a+D.2a, A+B.1(or B.2)+C.37b+D.2a, A+B.1(or B.2)+C.37c+D.2a, A+B.1(or B.2)+C.37d+D.2a, A+B.1(or B.2)+C.37e+D.2a, A+B.1(or B.2)+C.37e+D.2a 7f+D.2a,A+B.1(or B.2)+C.37g+D.2a,A+B.1(or B.2)+C.37h+D.2a,A+B.1(or B.2)+C.38+D.2a,A+B.1(or B.2)+C.38a+D.2a,A+B.1(or B.2)+C.38b+D.2a,A+ B.1(or B.2)+C.38c+D.2a, A+B.1(or B.2)+C.38d+D.2a, A+B.1(or B.2)+C.39+D.2a, A+B.1(or B.2)+C.39a+D.2a, A+B.1(or B.2)+C.40+D.2a, A+B.1(or B.2)+C. 41+D.2a, A+B.1(or B.2)+C.41a+D.2a, A+B.1(or B.2)+C.42+D.2a, A+B.1(or B. 2)+C.43+D.2a, A+B.1(or B.2)+C.44+D.2a, A+B.1(or B.2)+C.45+D.2a, A+B.1( or B.2)+C.45a+D.2a, A+B.1(or B.2)+C.46+D.2a, A+B.1(or B.2)+C.47+D.2a, A+B.1(or B.2)+C.48+D.2a, A+B.1(or B.2)+C.48a+D.2a, A+B.1(or B.2)+C.49+D.2a, A+B.1(or B.2)+C.50+D.2a, A+B.1(or B.2)+C.50a+D.2a, A+B.1(or B.2)+C.51+D.2a, A+B.1(or B.2)+C.51a+D.2a, A+B.1(or B.2)+C.52+D.2a, A+B.1(or B.2)+C.53+D.2a 2)+C.53+D.2a,A+B.1(or B.2)+C.54+D.2a,A+B.1(or 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B.2)+C.70b+D.2a, A+B.1(or B.2)+C.71+D.2a, A+B.1(or B.2)+C.72+D.2a, A+B.1(or B.2)+C.72 a+D.2a, A+B.1(or B.2)+C.73+D.2a, A+B.1(or B.2)+C.73a+D.2a, A+B.1(or B.2)+C.73b+D.2a, A+B.1(or B.2)+C.73c+D.2a, A+B.1(or B.2)+C.74+D.2a, A+B.1 (or B.2)+C.75+D.2a, A+B.1(or B.2)+C.75a+D.2a, A+B.1(or B.2)+C.75b+D.2a, A+B.1(or B.2)+C.76+D.2a, A+B.1(or B.2)+C.76a+D.2a, A+B.1(or B.2)+C.77 +D.2a, A+B.1(or B.2)+C.77a+D.2a, A+B.1(or B.2)+C.77b+D.2a, A+B.1(or B.2)+C.77c+D.2a, A+B.1(or B.2)+C.78+D.2a, A+B.1(or B.2)+C.79+D.2a, A+B.1( or B.2)+C.80+D.2a, A+B.1(or B.2)+C.81+D.2a, A+B.1(or B.2)+C.82+D.2a, A+B.1(or B.2)+C.83+D.2a, A+B.1(or B.2)+C.83a+D.2a, A+B.1(or B.2)+C.83b+D. .2a, A+B.1(or B.2)+C.83c+D.2a, A+B.1(or B.2)+C.83d+D.2a, A+B.1(or B.2)+C.83e+D.2a, A+B.1(or B.2)+C.83f+D.2a, A+B.1(or B.2)+C.83g+D.2a, A+B.1( or B.2)+C.83h+D.2a, A+B.1(or B.2)+C.83i+D.2a, A+B.1(or B.2)+C.83j+D.2a, A+B.1(or B.2)+C.83k+D.2a, A+B.1(or B.2)+C.83l+D.2a, A+B.1(or B.2)+C.83 m+D.2a, A+B.1(or B.2)+C.83n+D.2a, A+B.1(or B.2)+C.84+D.2a, A+B.1(or B.2)+C.84a+D.2a, A+B.1(or B.2)+C.84b+D.2a, A+B.1(or B.2)+C.84c+D.2a, A+B.1(or B.2)+C.85+D.2a, A+B.1(or B.2)+C.85a+D.2a, A+B.1(or B.2)+C.85b+D.2a, A+B.1(or B.2)+C.85c+D.2a, A+B.1(or B.2)+C.85d+D.2a, A+B.1(or B.2)+C. 85e+D.2a,A+B.1(or B.2)+C.85f+D.2a,A+B.1(or B.2)+C.85g+D.2a,A+B.1(or B.2)+C.85h+D.2a,A+B.1(or B.2)+C.85i+D.2a,A+B.1(or B.2)+C.86+D.2a,A+ B.1(or B.2)+C.86a+D.2a, A+B.1(or B.2)+C.86b+D.2a, A+B.1(or B.2)+C.86c+D.2a, A+B.1(or B.2)+C.86d+D.2a, A+B.1(or B.2)+C.87+D.2a, A+B.1(or B.2)+ C.87a+D.2a, A+B.1(or B.2)+C.88+D.2a, A+B.1(or B.2)+C.89+D.2a, A+B.1(or B.2)+C.89a+D.2a, A+B.1(or B.2)+C.89b+D.2a, A+B.1(or B.2)+C.89c+D.2a, A +B.1(or B.2)+C.90+D.2a, A+B.1(or B.2)+C.91+D.2a, A+B.1(or B.2)+C.92+D. 2a, A+B.1(or B.2)+C.93+D.2a, A+B.1(or B.2)+C.94+D.2a, A+B.1(or B.2)+C.9 5+D.2a, A+B.1(or B.2)+C.96+D.2a, A+B.1(or B.2)+C.97+D.2a, A+B.1(or B.2)+C.98+D.2a, A+B.1(or B.2)+C.98a+D.2a, A+B.1(or B.2)+C.99+D.2a, A+B.1(or B.2)+C.91+D.2a B.2)+C.100+D.2a, A+B.1(or B.2)+C.101+D.2a, A+B.1(or B.2)+C.102+D.2a, A+B.1(or B.2)+C.103+D.2a, A+B.1(or B.2)+C.104+D.2a, A+B.1(or B.2)+C.105 +D.2a, A+B.1(or B.2)+C.106+D.2a, A+B.1(or B.2)+C.107+D.2a, A+B.1(or B.2 )+C.108+D.2a, A+B.1(or B.2)+C.109+D.2a, A+B.1(or B.2)+C.110+D.2a, A+B.1(or B.2)+C.111+D.2a,A+B.1(or B.2)+C.112+D.2a,A+B.1(or B.2)+C.113+D.2a,A+B.1(or B.2)+C.113a+D.2a,A+B.1(or B.2)+C.114+D.2a,A+B.1(or B.2)+ C.114a+D.2a, A+B.1(or B.2)+C.114b+D.2a, A+B.1(or B.2)+C.114c+D.2a, A+B.1(or B.2)+C.114d+D.2a, A+B.1(or B.2)+C.114e+D.2a, A+B.1(or B.2)+C.114 f+D.2a,A+B.1(or B.2)+C.114g+D.2a,A+B.1(or B.2)+C.114h+D.2a,A+B.1(or B.2)+C.114i+D.2a,A+B.1(or B.2)+C.115+D.2a,A+B.1(or B.2)+C.116+D.2a, A+B.1(or B.2)+C.117+D.2a, A+B.1(or B.2)+C.118+D.2a, A+B.1(or B.2)+C.11 9+D.2a, A+B.1(or B.2)+C.120+D.2a, A+B.1(or B.2)+C.121+D.2a, A+B.1(or B.2 )+C.121a+D.2a, A+B.1(or B.2)+C.122+D.2a, A+B.1(or B.2)+C.123+D.2a, A+B.1(or B.2)+C.124+D.2a, A+B.1(or B.2)+C.125+D.2a, A+B.1(or B.2)+C.125a +D.2a, A+B.1(or B.2)+C.126+D.2a, A+B.1(or B.2)+C.127+D.2a, A+B.1(or B.2)+C.128+D.2a, A+B.1(or B.2)+C.129+D.2a, A+B.1(or B.2)+C.129a+D.2a, A+B .1(or B.2)+C.130+D.2a, A+B.1(or B.2)+C.131+D.2a, A+B.1(or B.2)+C.132+D.2a, A+B.1(or B.2)+C.132a+D.2a, A+B.1(or B.2)+C.133+D.2a, A+B.1(or B.2)+ C.133a+D.2a, A+B.1(or B.2)+C.133b+D.2a, A+B.1(or B.2)+C.134+D.2a, A+B.1(or B.2)+C.135+D.2a, A+B.1(or B.2)+C.136+D.2a, A+B.1(or B.2)+C.137+D.2a, A+B.1(or B.2)+C.138+D.2a, A+B.1(or B.2)+C.139+D.2a, A+B.1(or B.2)+C .140+D.2a, A+B.1(or B.2)+C.141+D.2a, A+B.1(or B.2)+C.142+D.2a, A+B.1( or B.2)+C.143+D.2a, A+B.1(or B.2)+C.144+D.2a, A+B.1(or B.2)+C.145+D.2a, A+B.1(or B.2)+C.145a+D.2a, A+B.1(or B.2)+C.146+D.2a, A+B.1(or B.2)+C.1 46a+D.2a,A+B.1(or B.2)+C.147+D.2a,A+B.1(or B.2)+C.148+D.2a,A+B.1(or B.2)+C.148a+D.2a,A+B.1(or B.2)+C.149+D.2a,A+B.1(or B.2)+C.150+D.2a, A+B.1(or B.2)+C.151+D.2a, A+B.1(or B.2)+C.152+D.2a, A+B.1(or B.2)+C.152a+D.2a, A+B.1(or B.2)+C.153+D.2a, A+B.1(or B.2)+C.153a+D.2a, A+B.1(or B.2)+C.153a+D.2a .2)+C.153b+D.2a, A+B.1(or B.2)+C.153c+D.2a, A+B.1(or B.2)+C.154+D.2a, A+B.1(or B.2)+C.154a+D.2a, A+B.1(or B.2)+C.155+D.2a, A+B.1(or B.2)+C.1 56+D.2a, A+B.1(or B.2)+C.157+D.2a, A+B.1(or B.2)+C.157a+D.2a, A+B.1(or B.2)+C.158+D.2a, A+B.1(or B.2)+C.159+D.2a, A+B.1(or B.2)+C.160+D.2a, A +B.1(or B.2)+C.161+D.2a, A+B.1(or B.2)+C.162+D.2a, A+B.1(or B.2)+C.163 +D.2a, A+B.1(or B.2)+C.164+D.2a, A+B.1(or B.2)+C.165+D.2a, A+B.1(or B.2) +C.166+D.2a, A+B.1(or B.2)+C.167+D.2a, A+B.1(or B.2)+C.168+D.2a, A+B.1(or B.2)+C.168a+D.2a, A+B.1(or B.2)+C.169+D.2a, A+B.1(or B.2)+C.170+D.2a, A+B.1(or B.2)+C.170a+D.2a, A+B.1(or B.2)+C.171+D.2a, A+B.1(or B.2)+C.171a+D.2a, A+B.1(or B.2)+C.172+D.2a, A+B.1(or B.2)+C.172a+D.2a, A+B .1(or B.2)+C.173+D.2a, A+B.1(or B.2)+C.173a+D.2a, A+B.1(or B.2)+C.1+D.4, A+B.1(or B.2)+C.2+D.4, A+B.1(or B.2)+C.3+D.4, A+B.1(or B.2)+C.4+D.4, A +B.1(or B.2)+C.4a+D.4, A+B.1(or B.2)+C.4b+D.4, A+B.1(or B.2)+C.4c+D.4, A+B.1(or B.2)+C.5+D.4, A+B.1(or B.2)+C.6+D.4, A+B.1(or B.2)+C.6a+D.4, A +B.1(or B.2)+C.6b+D.4,A+B.1(or B.2)+C.7+D.4,A+B.1(or B.2)+C.8+D.4,A+B.1(or B.2)+C.9+D.4,A+B.1(or B.2)+C.10+D.4,A+B.1(or B.2)+C.11+D.4,A+B .1(or B.2)+C.11a+D.4, A+B.1(or B.2)+C.12+D.4, A+B.1(or B.2)+C.13+D.4, A+B.1(or B.2)+C.13a+D.4, A+B.1(or B.2)+C.14+D.4, A+B.1(or B.2)+C.15+D.4 , A+B.1(or B.2)+C.16+D.4, A+B.1(or B.2)+C.16a+D.4, A+B.1(or B.2)+C.17+D.4, A+B.1(or B.2)+C.17a+D.4, A+B.1(or B.2)+C.17b+D.4, A+B.1(or B.2)+C.17 c+D.4, A+B.1(or B.2)+C.17d+D.4, A+B.1(or B.2)+C.18+D.4, A+B.1(or B.2)+C.19+D.4, A+B.1(or B.2)+C.19a+D.4, A+B.1(or B.2)+C.20+D.4, A+B.1(or B.2)+ C.21+D.4, A+B.1(or B.2)+C.22+D.4, A+B.1(or B.2)+C.23+D.4, A+B.1(or B.2)+C.23a+D.4, A+B.1(or B.2)+C.23b+D.4, A+B.1(or B.2)+C.24+D.4, A+B.1(or B.2)+C.25+D.42)+C.25+D.4,A+B.1(or B.2)+C.26+D.4,A+B.1(or B.2)+C.26a+D.4,A+B.1(or B.2)+C.27+D.4,A+B.1(or B.2)+C.28+D.4,A+B.1(or B.2)+C.28a+D.4,A+B.1( or B.2)+C.28b+D.4, A+B.1(or B.2)+C.28c+D.4, A+B.1(or B.2)+C.28d+D.4, A+B.1(or B.2)+C.28e+D.4, A+B.1(or B.2)+C.28f+D.4, A+B.1(or B.2)+C.28g+D.4 , A+B.1(or B.2)+C.29+D.4, A+B.1(or B.2)+C.30+D.4, A+B.1(or B.2)+C.31+D.4, A+B.1(or B.2)+C.31a+D.4, A+B.1(or B.2)+C.32+D.4, A+B.1(or B.2)+C.32a+ D.4, A+B.1(or B.2)+C.32b+D.4, A+B.1(or B.2)+C.32c+D.4, A+B.1(or B.2)+C.32d+D.4, A+B.1(or B.2)+C.32e+D.4, A+B.1(or B.2)+C.32f+D.4, A+B.1(or B.2) +C.32g+D.4,A+B.1(or B.2)+C.32h+D.4,A+B.1(or B.2)+C.32i+D.4,A+B.1(or B.2)+C.32j+D.4,A+B.1(or B.2)+C.32k+D.4,A+B.1(or B.2)+C.32l+D.4,A+B. 1(or B.2)+C.32m+D.4, A+B.1(or B.2)+C.32n+D.4, A+B.1(or B.2)+C.32o+D.4, A+B.1(or B.2)+C.32p+D.4, A+B.1(or B.2)+C.32q+D.4, A+B.1(or B.2)+C.32r+D .4, A+B.1(or B.2)+C.32s+D.4, A+B.1(or B.2)+C.32t+D.4, A+B.1(or B.2)+C.32u+D.4, A+B.1(or B.2)+C.32v+D.4, A+B.1(or B.2)+C.32w+D.4, A+B.1(or B.2)+ C.32x+D.4, A+B.1(or B.2)+C.32y+D.4, A+B.1(or B.2)+C.32z+D.4, A+B.1(or B.2)+C.32zx+D.4, A+B.1(or B.2)+C.32zy+D.4, A+B.1(or B.2)+C.33+D.4, A+B.1(or B.2)+C.33a+D.4, A+B.1(or B.2)+C.34+D.4, A+B.1(or B.2)+C.34a+D.4, A+B.1(or B.2)+C.34b+D.4, A+B.1(or B.2)+C.34c+D.4, A+B.1(or B.2)+C.34d+D. 4, A+B.1(or B.2)+C.34e+D.4, A+B.1(or B.2)+C.35+D.4, A+B.1(or B.2)+C.36+D.4, A+B.1(or B.2)+C.36a+D.4, A+B.1(or B.2)+C.36b+D.4, A+B.1(or B.2)+C.3 6c+D.4, A+B.1(or B.2)+C.36d+D.4, A+B.1(or B.2)+C.36e+D.4, A+B.1(or B.2)+C.36f+D.4, A+B.1(or B.2)+C.36g+D.4, A+B.1(or B.2)+C.36h+D.4, A+B.1(or B.2)+C.36h+D.4 .2)+C.36i+D.4,A+B.1(or B.2)+C.36j+D.4,A+B.1(or B.2)+C.36k+D.4,A+B.1(or B.2)+C.36l+D.4,A+B.1(or B.2)+C.36m+D.4,A+B.1(or B.2)+C.37+D.4,A+ B.1(or B.2)+C.37a+D.4, A+B.1(or B.2)+C.37b+D.4, A+B.1(or B.2)+C.37c+D.4, A+B.1(or B.2)+C.37d+D.4, A+B.1(or B.2)+C.37e+D.4, A+B.1(or B.2)+C.37f +D.4, A+B.1(or B.2)+C.37g+D.4, A+B.1(or B.2)+C.37h+D.4, A+B.1(or B.2)+C.38+D.4, A+B.1(or B.2)+C.38a+D.4, A+B.1(or B.2)+C.38b+D.4, A+B.1(or B.2) +C.38c+D.4, A+B.1(or B.2)+C.38d+D.4, A+B.1(or B.2)+C.39+D.4, A+B.1(or B.2)+C.39a+D.4, A+B.1(or B.2)+C.40+D.4, A+B.1(or B.2)+C.41+D.4, A+B.1(or B.2)+C.41a+D.4, A+B.1(or B.2)+C.42+D.4, A+B.1(or B.2)+C.43+D.4, A+B.1(or B.2)+C.44+D.4, A+B.1(or B.2)+C.45+D.4, A+B.1(or B.2)+C.45a+D.4, A+B.1(or B.2)+C.46+D.4,A+B.1(or 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A+B.1(or B.2)+C.67h+D.4, A+B.1(or B.2)+C.67i+D.4, A+B.1(or B.2)+C.67j+D.4, A+B.1(or B.2)+C.68+D.4, A+B.1(or B.2)+C.68a+D.4, A+B.1(or B.2)+C.69+D.4, A+B.1(or B.2)+C.69a+D.4, A+B.1(or B.2)+C.70+D.4, A+B.1(or B.2)+C.70a+D.4, A+B.1(or B.2)+C.70b+D.4, A+B.1(or B.2)+C. .2)+C.71+D.4,A+B.1(or B.2)+C.72+D.4,A+B.1(or B.2)+C.72a+D.4,A+B.1(or B.2)+C.73+D.4,A+B.1(or B.2)+C.73a+D.4,A+B.1(or B.2)+C.73b+D.4,A+B. 1(or B.2)+C.73c+D.4, A+B.1(or B.2)+C.74+D.4, A+B.1(or B.2)+C.75+D.4, A+B.1(or B.2)+C.75a+D.4, A+B.1(or B.2)+C.75b+D.4, A+B.1(or B.2)+C.76+D.4 , A+B.1(or B.2)+C.76a+D.4, A+B.1(or B.2)+C.77+D.4, A+B.1(or B.2)+C.77a+D.4, A+B.1(or B.2)+C.77b+D.4, A+B.1(or B.2)+C.77c+D.4, A+B.1(or B.2)+C.7 8+D.4, A+B.1(or B.2)+C.79+D.4, A+B.1(or B.2)+C.80+D.4, A+B.1(or B.2)+C.81+D.4, A+B.1(or B.2)+C.82+D.4, A+B.1(or B.2)+C.83+D.4, A+B.1(or B.2)+C .83a+D.4, A+B.1(or B.2)+C.83b+D.4, A+B.1(or B.2)+C.83c+D.4, A+B.1(or B.2)+C.83d+D.4, A+B.1(or B.2)+C.83e+D.4, A+B.1(or B.2)+C.83f+D.4, A+B.1( or B.2)+C.83g+D.4, A+B.1(or 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A+B.1(or B.2)+C.98+D.4, A+B.1(or B.2)+C.99+D.4, A+B.1(or B.2)+C.91+D.4, A+B.1(or B.2)+C.92+D.4, A+B.1(or B.2)+C. 2)+C.96+D.4,A+B.1(or B.2)+C.97+D.4,A+B.1(or B.2)+C.98+D.4,A+B.1(or B.2)+C.98a+D.4,A+B.1(or B.2)+C.99+D.4,A+B.1(or B.2)+C.100+D.4,A+B.1( or B.2)+C.101+D.4, A+B.1(or B.2)+C.102+D.4, A+B.1(or B.2)+C.103+D.4, A+B.1(or B.2)+C.104+D.4, A+B.1(or B.2)+C.105+D.4, A+B.1(or B.2)+C.106+D.4 , A+B.1(or B.2)+C.107+D.4, A+B.1(or B.2)+C.108+D.4, A+B.1(or B.2)+C.109+D.4, A+B.1(or B.2)+C.110+D.4, A+B.1(or B.2)+C.111+D.4, A+B.1(or B.2)+C.112+D.4, A+B.1(or B.2)+C.113+D.4, A+B.1(or B.2)+C.113a+D.4, A+B.1(or B.2)+C.114+D.4, A+B.1(or B.2)+C.114a+D.4, A+B.1(or B.2)+C.114b+D.4, A+B. 1(or B.2)+C.114c+D.4, A+B.1(or B.2)+C.114d+D.4, A+B.1(or B.2)+C.114e+D.4, A+B.1(or B.2)+C.114f+D.4, A+B.1(or B.2)+C.114g+D.4, A+B.1(or B.2)+C. 114h+D.4,A+B.1(or B.2)+C.114i+D.4,A+B.1(or B.2)+C.115+D.4,A+B.1(or B.2)+C.116+D.4,A+B.1(or B.2)+C.117+D.4,A+B.1(or B.2)+C.118+D.4,A+B.1 (or B.2)+C.119+D.4, A+B.1(or B.2)+C.120+D.4, A+B.1(or B.2)+C.121+D.4, A+B.1(or B.2)+C.121a+D.4, A+B.1(or B.2)+C.122+D.4, A+B.1(or B.2)+C.123+D .4, A+B.1(or B.2)+C.124+D.4, A+B.1(or B.2)+C.125+D.4, A+B.1(or B.2)+C.125a+D.4, A+B.1(or B.2)+C.126+D.4, A+B.1(or B.2)+C.127+D.4, A+B.1(or B.2) +C.128+D.4,A+B.1(or B.2)+C.129+D.4,A+B.1(or B.2)+C.129a+D.4,A+B.1(or B.2)+C.130+D.4,A+B.1(or B.2)+C.131+D.4,A+B.1(or B.2)+C.132+D.4,A+B .1(or B.2)+C.132a+D.4,A+B.1(or B.2)+C.133+D.4,A+B.1(or B.2)+C.133a+D.4,A+B.1(or B.2)+C.133b+D.4,A+B.1(or B.2)+C.134+D.4,A+B.1(or B.2)+C.1 35+D.4, A+B.1(or B.2)+C.136+D.4, A+B.1(or B.2)+C.137+D.4, A+B.1(or B.2)+C.138+D.4, A+B.1(or B.2)+C.139+D.4, A+B.1(or B.2)+C.140+D.4, A+B.1(or B.2)+C.2)+C.141+D.4,A+B.1(or B.2)+C.142+D.4,A+B.1(or B.2)+C.143+D.4,A+B.1(or B.2)+C.144+D.4,A+B.1(or B.2)+C.145+D.4,A+B.1(or B.2)+C.145a+D.4, A+B.1(or B.2)+C.146+D.4, A+B.1(or B.2)+C.146a+D.4, A+B.1(or B.2)+C.147+D.4, A+B.1(or B.2)+C.148+D.4, A+B.1(or B.2)+C.148a+D.4, A+B.1(or B.2)+C .149+D.4, A+B.1(or B.2)+C.150+D.4, A+B.1(or B.2)+C.151+D.4, A+B.1(or B.2)+C.152+D.4, A+B.1(or B.2)+C.152a+D.4, A+B.1(or B.2)+C.153+D.4, A+B.1 (or B.2)+C.153a+D.4, A+B.1(or B.2)+C.153b+D.4, A+B.1(or B.2)+C.153c+D.4, A+B.1(or B.2)+C.154+D.4, A+B.1(or B.2)+C.154a+D.4, A+B.1(or B.2)+C.15 5+D.4, A+B.1(or B.2)+C.156+D.4, A+B.1(or B.2)+C.157+D.4, A+B.1(or B.2)+C.157a+D.4, A+B.1(or B.2)+C.158+D.4, A+B.1(or B.2)+C.159+D.4, A+B.1(or A+B.1(or B.2)+C.160+D.4, A+B.1(or B.2)+C.161+D.4, A+B.1(or B.2)+C.162+D.4, A+B.1(or B.2)+C.163+D.4, A+B.1(or B.2)+C.164+D.4, A+B.1(or B.2)+C.165+D.4, A+B.1(or B.2)+C.166+D.4, A+B.1(or B.2)+C.167+D.4, A+B.1(or B.2)+C.168+D.4, A+B.1(or B.2)+C.168a+D.4, A+B.1(or B.2)+C.169+D.4, A+B.1(or B.2)+C. 170+D.4, A+B.1(or B.2)+C.170a+D.4, A+B.1(or B.2)+C.171+D.4, A+B.1(or B.2)+C.171a+D.4, A+B.1(or B.2)+C.172+D.4, A+B.1(or B.2)+C.172a+D.4, A+B.1(or B.2)+C.173+D.4, A+B.1(or B.2)+C.173a+D.4, A+B.1(or B.2)+C.1+D.5, A+B.1(or B.2)+C.2+D.5, A+B.1(or B.2)+C.3+D.5, A+B.1(or B.2)+C.4+D.5, A+B .1(or B.2)+C.4a+D.5, A+B.1(or 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A+B.1(or B.2)+C.146a+D.5, A+B.1(or B.2)+C.147+D.5, A+B.1(or B.2)+C.148+D.5, A+B.1(or B.2)+C.148a+D.5, A+B.1(or B.2) +C.149+D.5,A+B.1(or B.2)+C.150+D.5,A+B.1(or B.2)+C.151+D.5,A+B.1(or B.2)+C.152+D.5,A+B.1(or B.2)+C.152a+D.5,A+B.1(or B.2)+C.153+D.5,A+B .1(or B.2)+C.153a+D.5, A+B.1(or B.2)+C.153b+D.5, A+B.1(or B.2)+C.153c+D.5, A+B.1(or B.2)+C.154+D.5, A+B.1(or B.2)+C.154a+D.5, A+B.1(or B.2)+C. 155+D.5, A+B.1(or B.2)+C.156+D.5, A+B.1(or B.2)+C.157+D.5, A+B.1(or B.2)+C.157a+D.5, A+B.1(or B.2)+C.158+D.5, A+B.1(or B.2)+C.159+D.5, A+B.1( or B.2)+C.160+D.5, A+B.1(or B.2)+C.161+D.5, A+B.1(or B.2)+C.162+D.5, A+B.1(or B.2)+C.163+D.5, A+B.1(or B.2)+C.164+D.5, A+B.1(or B.2)+C.165+D.5 , A+B.1(or B.2)+C.166+D.5, A+B.1(or B.2)+C.167+D.5, A+B.1(or B.2)+C.168+D.5, A+B.1(or B.2)+C.168a+D.5, A+B.1(or B.2)+C.169+D.5, A+B.1(or B.2)+C .170+D.5, A+B.1(or B.2)+C.170a+D.5, A+B.1(or B.2)+C.171+D.5, A+B.1(or B.2)+C.171a+D.5, A+B.1(or B.2)+C.172+D.5, A+B.1(or B.2)+C.172a+D.5, A+B .1(or B.2)+C.173+D.5, A+B.1(or B.2)+C.173a+D.5, A+B.1(or B.2)+C.1+D.6, A+B.1(or B.2)+C.2+D.6, A+B.1(or B.2)+C.3+D.6, A+B.1(or B.2)+C.4+D.6, A+B.1(or B.2)+C.4a+D.6,A+B.1(or B.2)+C.4b+D.6,A+B.1(or B.2)+C.4c+D.6,A+B.1(or B.2)+C.5+D.6,A+B.1(or B.2)+C.6+D.6,A+B.1(or B.2)+C.6a+D.6,A+B.1 (or B.2)+C.6b+D.6, A+B.1(or B.2)+C.7+D.6, A+B.1(or B.2)+C.8+D.6, A+B.1(or B.2)+C.9+D.6, A+B.1(or B.2)+C.10+D.6, A+B.1(or B.2)+C.11+D.6, A+B.1(or B.2)+C.11a+D.6, A+B.1(or B.2)+C.12+D.6, A+B.1(or B.2)+C.13+D.6, A+B.1(or B.2)+C.13a+D.6, A+B.1(or B.2)+C.14+D.6, A+B.1(or B.2)+C.15+D.6, A+B. 1(or B.2)+C.16+D.6, A+B.1(or B.2)+C.16a+D.6, A+B.1(or B.2)+C.17+D.6, A+B.1(or B.2)+C.17a+D.6, A+B.1(or B.2)+C.17b+D.6, A+B.1(or B.2)+C.17c+D.6 ,A+B.1(or B.2)+C.17d+D.6,A+B.1(or B.2)+C.18+D.6,A+B.1(or B.2)+C.19+D.6,A+B.1(or B.2)+C.19a+D.6,A+B.1(or B.2)+C.20+D.6,A+B.1(or B.2)+C.21+ D.6, A+B.1(or B.2)+C.22+D.6, A+B.1(or B.2)+C.23+D.6, A+B.1(or B.2)+C.23a+D.6, A+B.1(or B.2)+C.23b+D.6, A+B.1(or B.2)+C.24+D.6, A+B.1(or B.2)+C. 25+D.6, A+B.1(or B.2)+C.26+D.6, A+B.1(or B.2)+C.26a+D.6, A+B.1(or B.2)+C.27+D.6, A+B.1(or B.2)+C.28+D.6, A+B.1(or B.2)+C.28a+D.6, A+B.1(or B.2) +C.28b+D.6, A+B.1(or B.2)+C.28c+D.6, A+B.1(or B.2)+C.28d+D.6, A+B.1(or B.2)+C.28e+D.6, A+B.1(or B.2)+C.28f+D.6, A+B.1(or B.2)+C.28g+D.6, A+B.1(or B.2)+C.29+D.6,A+B.1(or B.2)+C.30+D.6,A+B.1(or B.2)+C.31+D.6,A+B.1(or B.2)+C.31a+D.6,A+B.1(or B.2)+C.32+D.6,A+B.1(or B.2)+C.32a+D.6,A +B.1(or B.2)+C.32b+D.6, A+B.1(or B.2)+C.32c+D.6, A+B.1(or B.2)+C.32d+D.6, A+B.1(or B.2)+C.32e+D.6, A+B.1(or B.2)+C.32f+D.6, A+B.1(or B.2)+C.32 g+D.6, A+B.1(or B.2)+C.32h+D.6, A+B.1(or B.2)+C.32i+D.6, A+B.1(or B.2)+C.32j+D.6, A+B.1(or B.2)+C.32k+D.6, A+B.1(or B.2)+C.32l+D.6, A+B.1(or B.2)+C.32i+D.6, A+B.1(or B.2)+C.32j+D.6, A+B.1(or B.2)+C.32k+D.6, A+B.1(or B.2)+C.32l+D.6, A+B.1(or B. 2)+C.32m+D.6,A+B.1(or B.2)+C.32n+D.6,A+B.1(or B.2)+C.32o+D.6,A+B.1(or B.2)+C.32p+D.6,A+B.1(or B.2)+C.32q+D.6,A+B.1(or B.2)+C.32r+D.6,A+ B.1(or B.2)+C.32s+D.6, A+B.1(or B.2)+C.32t+D.6, A+B.1(or B.2)+C.32u+D.6, A+B.1(or B.2)+C.32v+D.6, A+B.1(or B.2)+C.32w+D.6, A+B.1(or B.2)+C.32x +D.6, A+B.1(or B.2)+C.32y+D.6, A+B.1(or B.2)+C.32z+D.6, A+B.1(or B.2)+C.32zx+D.6, A+B.1(or B.2)+C.32zy+D.6, A+B.1(or B.2)+C.33+D.6, A+B.1(or B.2)+C.33+D.6 2)+C.33a+D.6,A+B.1(or B.2)+C.34+D.6,A+B.1(or B.2)+C.34a+D.6,A+B.1(or B.2)+C.34b+D.6,A+B.1(or B.2)+C.34c+D.6,A+B.1(or B.2)+C.34d+D.6,A+B .1(or B.2)+C.34e+D.6, A+B.1(or B.2)+C.35+D.6, A+B.1(or B.2)+C.36+D.6, A+B.1(or B.2)+C.36a+D.6, A+B.1(or B.2)+C.36b+D.6, A+B.1(or B.2)+C.36c+D.6, A+B.1(or B.2)+C.36d+D.6, A+B.1(or B.2)+C.36e+D.6, A+B.1(or B.2)+C.36f+D.6, A+B.1(or B.2)+C.36g+D.6, A+B.1(or B.2)+C.36h+D.6, A+B.1(or B.2)+C .36i+D.6, A+B.1(or B.2)+C.36j+D.6, A+B.1(or B.2)+C.36k+D.6, A+B.1(or B.2)+C.36l+D.6, A+B.1(or B.2)+C.36m+D.6, A+B.1(or B.2)+C.37+D.6, A+B.1(or A+B.1(or B.2)+C.37a+D.6, A+B.1(or B.2)+C.37b+D.6, A+B.1(or B.2)+C.37c+D.6, A+B.1(or B.2)+C.37d+D.6, A+B.1(or B.2)+C.37e+D.6, A+B.1(or B.2)+C.37f+D.6, A+B.1(or B.2)+C.37g+D.6, A+B.1(or B.2)+C.37h+D.6, A+B.1(or B.2)+C.38+D.6, A+B.1(or B.2)+C.38a+D.6, A+B.1(or B.2)+C.38b+D.6, A+B.1(or B.2)+C.38 c+D.6, A+B.1(or B.2)+C.38d+D.6, A+B.1(or B.2)+C.39+D.6, A+B.1(or B.2)+C.39a+D.6, A+B.1(or B.2)+C.40+D.6, A+B.1(or B.2)+C.41+D.6, A+B.1(or B.2)+ C.41a+D.6, A+B.1(or B.2)+C.42+D.6, A+B.1(or B.2)+C.43+D.6, A+B.1(or B.2)+C.44+D.6, A+B.1(or B.2)+C.45+D.6, A+B.1(or B.2)+C.45a ... 2)+C.46+D.6, A+B.1(or B.2)+C.47+D.6, A+B.1(or B.2)+C.48+D.6, A+B.1(or B.2)+C.48a+D.6, A+B.1(or B.2)+C.49+D.6, A+B.1(or B.2)+C.50+D.6, A+B.1(or B.2)+C.50a+D.6, A+B.1(or B.2)+C.51+D.6, A+B.1(or B.2)+C.51a+D.6, A+B.1(or B.2)+C.52+D.6, A+B.1(or B.2)+C.53+D.6, A+B.1(or B.2)+C.54+D.6, A+B.1(or B.2)+C.55+D.6, A+B.1(or B.2)+C.55a+D.6, A+B.1(or B.2)+C.55b+D.6, A+B.1(or B.2)+C.56+D.6, A+B.1(or B.2)+C.56a+D.6, A+B.1(or B.2)+C.57+D.6 , A+B.1(or B.2)+C.58+D.6, A+B.1(or B.2)+C.59+D.6, A+B.1(or B.2)+C.60+D.6, A+B.1(or B.2)+C.60a+D.6, A+B.1(or B.2)+C.60b+D.6, A+B.1(or B.2)+C.61+ D.6, A+B.1(or B.2)+C.62+D.6, A+B.1(or B.2)+C.62a+D.6, A+B.1(or B.2)+C.62b+D.6, A+B.1(or B.2)+C.63+D.6, A+B.1(or B.2)+C.64+D.6, A+B.1(or B.2)+C. 65+D.6, A+B.1(or B.2)+C.65a+D.6, A+B.1(or B.2)+C.66+D.6, A+B.1(or B.2)+C.66a+D.6, A+B.1(or B.2)+C.66b+D.6, A+B.1(or B.2)+C.67+D.6, A+B.1(or B.2 )+C.67a+D.6,A+B.1(or B.2)+C.67b+D.6,A+B.1(or B.2)+C.67c+D.6,A+B.1(or B.2)+C.67d+D.6,A+B.1(or B.2)+C.67e+D.6,A+B.1(or B.2)+C.67f+D.6,A+ B.1(or B.2)+C.67g+D.6, A+B.1(or B.2)+C.67h+D.6, A+B.1(or B.2)+C.67i+D.6, A+B.1(or B.2)+C.67j+D.6, A+B.1(or B.2)+C.68+D.6, A+B.1(or B.2)+C.68a+ D.6, A+B.1(or B.2)+C.69+D.6, A+B.1(or B.2)+C.69a+D.6, A+B.1(or B.2)+C.70+D.6, A+B.1(or B.2)+C.70a+D.6, A+B.1(or B.2)+C.70b+D.6, A+B.1(or B.2)+C .71+D.6, A+B.1(or B.2)+C.72+D.6, A+B.1(or B.2)+C.72a+D.6, A+B.1(or B.2)+C.73+D.6, A+B.1(or B.2)+C.73a+D.6, A+B.1(or B.2)+C.73b+D.6, A+B.1(or B.2)+C.73a+D.6, A+B.1(or B.2)+C.73b+D.6, A+B.1(or B.2)+C.73a+D.6, A+B.1(or B.2)+C.73b+D.6, A+B.1(or B.2)+C.73c+D.6,A+B.1(or B.2)+C.74+D.6,A+B.1(or B.2)+C.75+D.6,A+B.1(or B.2)+C.75a+D.6,A+B.1(or B.2)+C.75b+D.6,A+B.1(or B.2)+C.76+D.6,A+B. 1(or B.2)+C.76a+D.6, A+B.1(or B.2)+C.77+D.6, A+B.1(or B.2)+C.77a+D.6, A+B.1(or B.2)+C.77b+D.6, A+B.1(or B.2)+C.77c+D.6, A+B.1(or B.2)+C.78+D.6 , A+B.1(or B.2)+C.79+D.6, A+B.1(or B.2)+C.80+D.6, A+B.1(or B.2)+C.81+D.6, A+B.1(or B.2)+C.82+D.6, A+B.1(or B.2)+C.83+D.6, A+B.1(or B.2)+C.83a+D .6, A+B.1(or B.2)+C.83b+D.6, A+B.1(or B.2)+C.83c+D.6, A+B.1(or B.2)+C.83d+D.6, A+B.1(or B.2)+C.83e+D.6, A+B.1(or B.2)+C.83f+D.6, A+B.1(or B.2)+ C.83g+D.6, A+B.1(or B.2)+C.83h+D.6, A+B.1(or B.2)+C.83i+D.6, A+B.1(or B.2)+C.83j+D.6, A+B.1(or B.2)+C.83k+D.6, A+B.1(or B.2)+C.83l+D.6, A+B.1 (or B.2)+C.83m+D.6, A+B.1(or B.2)+C.83n+D.6, A+B.1(or B.2)+C.84+D.6, A+B.1(or B.2)+C.84a+D.6, A+B.1(or B.2)+C.84b+D.6, A+B.1(or B.2)+C.84c+D.6 , A+B.1(or B.2)+C.85+D.6, A+B.1(or B.2)+C.85a+D.6, A+B.1(or B.2)+C.85b+D.6, A+B.1(or B.2)+C.85c+D.6, A+B.1(or B.2)+C.85d+D.6, A+B.1(or B.2)+C.8 5e+D.6,A+B.1(or B.2)+C.85f+D.6,A+B.1(or B.2)+C.85g+D.6,A+B.1(or B.2)+C.85h+D.6,A+B.1(or B.2)+C.85i+D.6,A+B.1(or B.2)+C.86+D.6,A+B.1(or B.2)+C.86+D.62)+C.86a+D.6,A+B.1(or B.2)+C.86b+D.6,A+B.1(or B.2)+C.86c+D.6,A+B.1(or B.2)+C.86d+D.6,A+B.1(or B.2)+C.87+D.6,A+B.1(or B.2)+C.87a+D.6,A+ B.1(or B.2)+C.88+D.6, A+B.1(or B.2)+C.89+D.6, A+B.1(or B.2)+C.89a+D.6, A+B.1(or B.2)+C.89b+D.6, A+B.1(or B.2)+C.89c+D.6, A+B.1(or B.2)+C.90+D. 6, A+B.1(or B.2)+C.91+D.6, A+B.1(or B.2)+C.92+D.6, A+B.1(or B.2)+C.93+D.6, A+B.1(or B.2)+C.94+D.6, A+B.1(or B.2)+C.95+D.6, A+B.1(or B.2)+C.96+ D.6, A+B.1(or B.2)+C.97+D.6, A+B.1(or B.2)+C.98+D.6, A+B.1(or B.2)+C.98a+D.6, A+B.1(or B.2)+C.99+D.6, A+B.1(or B.2)+C.100+D.6, A+B.1(or B.2)+C. 101+D.6, A+B.1(or B.2)+C.102+D.6, A+B.1(or B.2)+C.103+D.6, A+B.1(or B.2)+C.104+D.6, A+B.1(or B.2)+C.105+D.6, A+B.1(or B.2)+C.106+D.6, A+B.1( or B.2)+C.107+D.6, A+B.1(or B.2)+C.108+D.6, A+B.1(or B.2)+C.109+D.6, A+B.1(or B.2)+C.110+D.6, A+B.1(or B.2)+C.111+D.6, A+B.1(or B.2)+C.112+D.6 , A+B.1(or B.2)+C.113+D.6, A+B.1(or B.2)+C.113a+D.6, A+B.1(or B.2)+C.114+D.6, A+B.1(or 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B.2)+C.4+D.10, A+B.1(or B.2)+C.4a ...2)+C.4b+D.10,A+B.1(or B.2)+C.4c+D.10,A+B.1(or B.2)+C.5+D.10,A+B.1(or B.2)+C.6+D.10,A+B.1(or B.2)+C.6a+D.10,A+B.1(or B.2)+C.6b+D.10,A+B .1(or B.2)+C.7+D.10,A+B.1(or B.2)+C.8+D.10,A+B.1(or B.2)+C.9+D.10,A+B.1(or B.2)+C.10+D.10,A+B.1(or B.2)+C.11+D.10,A+B.1(or B.2)+C.11a+D.1 0, A+B.1(or B.2)+C.12+D.10, A+B.1(or B.2)+C.13+D.10, A+B.1(or B.2)+C.13a+D.10, A+B.1(or B.2)+C.14+D.10, A+B.1(or B.2)+C.15+D.10, A+B.1(or B.2) +C.16+D.10,A+B.1(or B.2)+C.16a+D.10,A+B.1(or B.2)+C.17+D.10,A+B.1(or B.2)+C.17a+D.10,A+B.1(or B.2)+C.17b+D.10,A+B.1(or B.2)+C.17c+D.10, A+B.1(or B.2)+C.17d+D.10, A+B.1(or B.2)+C.18+D.10, A+B.1(or B.2)+C.19+D.10, A+B.1(or B.2)+C.19a+D.10, A+B.1(or B.2)+C.20+D.10, A+B.1(or B.2)+ C.21+D.10, A+B.1(or B.2)+C.22+D.10, A+B.1(or B.2)+C.23+D.10, A+B.1(or B .2)+C.23a+D.10, A+B.1(or B.2)+C.23b+D.10, A+B.1(or B.2)+C.24+D.10, A+B .1(or B.2)+C.25+D.10,A+B.1(or B.2)+C.26+D.10,A+B.1(or B.2)+C.26a+D.10,A+B.1(or B.2)+C.27+D.10,A+B.1(or B.2)+C.28+D.10,A+B.1(or 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A+B.1(or B.2)+C.32i+D.12, A+B.1(or B.2)+C.32j+D.12, A+B.1(or B.2)+C.32k+D.12 .2)+C.32l+D.12,A+B.1(or B.2)+C.32m+D.12,A+B.1(or B.2)+C.32n+D.12,A+B.1(or B.2)+C.32o+D.12,A+B.1(or B.2)+C.32p+D.12,A+B.1(or B.2)+C.32q+ D.12, A+B.1(or B.2)+C.32r+D.12, A+B.1(or B.2)+C.32s+D.12, A+B.1(or B.2)+C.32t+D.12, A+B.1(or B.2)+C.32u+D.12, A+B.1(or B.2)+C.32v+D.12, A+B.1 (or B.2)+C.32w+D.12, A+B.1(or B.2)+C.32x+D.12, A+B.1(or B.2)+C.32y+D.12, A+B.1(or B.2)+C.32z+D.12, A+B.1(or B.2)+C.32zx+D.12, A+B.1(or B.2)+C.32zy+D.12,A+B.1(or B.2)+C.33+D.12,A+B.1(or B.2)+C.33a+D.12,A+B.1(or B.2)+C.34+D.12,A+B.1(or B.2)+C.34a+D.12,A+B.1(or B.2)+C.34b+D.12,A +B.1(or B.2)+C.34c+D.12, A+B.1(or B.2)+C.34d+D.12, A+B.1(or B.2)+C.34e+D.12, A+B.1(or B.2)+C.35+D.12, A+B.1(or B.2)+C.36+D.12, A+B.1(or B.2)+C .36a+D.12, A+B.1(or B.2)+C.36b+D.12, A+B.1(or B.2)+C.36c+D.12, A+B.1(or B.2)+C.36d+D.12, A+B.1(or B.2)+C.36e+D.12, A+B.1(or B.2)+C.36f+D.12, A+B.1(or B.2)+C.36g+D.12, A+B.1(or B.2)+C.36h+D.12, A+B.1(or B.2)+C.36i+D.12, A+B.1(or B.2)+C.36j+D.12, A+B.1(or B.2)+C.36k+D.12, A+B.1(or B.2 )+C.36l+D.12, A+B.1(or B.2)+C.36m+D.12, A+B.1(or B.2)+C.37+D.12, A+B.1(or B.2)+C.37a+D.12, A+B.1(or B.2)+C.37b+D.12, A+B.1(or B.2)+C.37c+D. 12, A+B.1(or B.2)+C.37d+D.12, A+B.1(or B.2)+C.37e+D.12, A+B.1(or B.2)+C.37f+D.12, A+B.1(or B.2)+C.37g+D.12, A+B.1(or B.2)+C.37h+D.12, A+B.1(or B.2)+C.37h+D.12 B.2)+C.38+D.12, A+B.1(or B.2)+C.38a+D.12, A+B.1(or B.2)+C.38b+D.12, A+B.1(or B.2)+C.38c+D.12, A+B.1(or B.2)+C.38d+D.12, A+B.1(or B.2)+C.39+D .12, A+B.1(or B.2)+C.39a+D.12, A+B.1(or B.2)+C.40+D.12, A+B.1(or B.2)+C.41+D.12, A+B.1(or B.2)+C.41a+D.12, A+B.1(or B.2)+C.42+D.12, A+B.1(or B.2)+C.43a+D.122)+C.43+D.12,A+B.1(or B.2)+C.44+D.12,A+B.1(or B.2)+C.45+D.12,A+B.1(or B.2)+C.45a+D.12,A+B.1(or B.2)+C.46+D.12,A+B.1(or B.2)+C.47+D.12, A+B.1(or B.2)+C.48+D.12, A+B.1(or B.2)+C.48a+D.12, A+B.1(or B.2)+C.49+D.12, A+B.1(or B.2)+C.50+D.12, A+B.1(or B.2)+C.50a+D.12, A+B.1(or B.2)+C .51+D.12, A+B.1(or B.2)+C.51a+D.12, A+B.1(or B.2)+C.52+D.12, A+B.1(or B .2)+C.53+D.12, A+B.1(or B.2)+C.54+D.12, A+B.1(or B.2)+C.55+D.12, A+B.1 (or B.2)+C.55a+D.12, A+B.1(or B.2)+C.55b+D.12, A+B.1(or B.2)+C.56+D.12, A+B.1(or B.2)+C.56a+D.12, A+B.1(or B.2)+C.57+D.12, A+B.1(or B.2)+C.58+ D.12, A+B.1(or B.2)+C.59+D.12, A+B.1(or B.2)+C.60+D.12, A+B.1(or B.2)+C.60a+D.12, A+B.1(or B.2)+C.60b+D.12, A+B.1(or B.2)+C.61+D.12, A+B.1(or B.2)+C.62+D.12 B.2)+C.62+D.12, A+B.1(or B.2)+C.62a+D.12, A+B.1(or B.2)+C.62b+D.12, A+B.1(or B.2)+C.63+D.12, A+B.1(or B.2)+C.64+D.12, A+B.1(or B.2)+C.65+D.1 2, A+B.1(or B.2)+C.65a+D.12, A+B.1(or B.2)+C.66+D.12, A+B.1(or B.2)+C.66a+D.12, A+B.1(or B.2)+C.66b+D.12, A+B.1(or B.2)+C.67+D.12, A+B.1(or B.2 )+C.67a+D.12, A+B.1(or B.2)+C.67b+D.12, A+B.1(or B.2)+C.67c+D.12, A+B.1(or B.2)+C.67d+D.12, A+B.1(or B.2)+C.67e+D.12, A+B.1(or B.2)+C.67f+D.12, A+B.1(or B.2)+C.67g+D.12, A+B.1(or B.2)+C.67h+D.12, A+B.1(or B.2)+C.67i+D.12, A+B.1(or B.2)+C.67j+D.12, A+B.1(or B.2)+C.68+D.12, A+B.1(or B.2)+C.68a+D.12, A+B.1(or B.2)+C.69+D.12, A+B.1(or B.2)+C.69a+D.12, A+B.1(or B.2)+C.70+D.12, A+B.1(or B.2)+C.70a+D.12, A+B.1(or B.2)+C.70b+D .12, A+B.1(or B.2)+C.71+D.12, A+B.1(or B.2)+C.72+D.12, A+B.1(or B.2)+C.72a+D.12, A+B.1(or B.2)+C.73+D.12, A+B.1(or B.2)+C.73a+D.12, A+B.1(or B.2)+C.73a+D.12, A+B.1(or B.2)+C.73a+D.12 .2)+C.73b+D.12, A+B.1(or B.2)+C.73c+D.12, A+B.1(or B.2)+C.74+D.12, A+B.1(or B.2)+C.75+D.12, A+B.1(or B.2)+C.75a+D.12, A+B.1(or B.2)+C.75b+D. 12, A+B.1(or B.2)+C.76+D.12, A+B.1(or B.2)+C.76a+D.12, A+B.1(or B.2)+C.77+D.12, A+B.1(or B.2)+C.77a+D.12, A+B.1(or B.2)+C.77b+D.12, A+B.1(or B.2)+C.77a+D.12 .2)+C.77c+D.12,A+B.1(or B.2)+C.78+D.12,A+B.1(or B.2)+C.79+D.12,A+B.1(or B.2)+C.80+D.12,A+B.1(or B.2)+C.81+D.12,A+B.1(or B.2)+C.82+D.12, A+B.1(or B.2)+C.83+D.12, A+B.1(or B.2)+C.83a+D.12, A+B.1(or B.2)+C.83b+D.12, A+B.1(or B.2)+C.83c+D.12, A+B.1(or B.2)+C.83d+D.12, A+B.1(or B.2 )+C.83e+D.12, A+B.1(or B.2)+C.83f+D.12, A+B.1(or B.2)+C.83g+D.12, A+B.1(or B.2)+C.83h+D.12, A+B.1(or B.2)+C.83i+D.12, A+B.1(or B.2)+C.83j+D.12, A+B.1(or B.2)+C.83k+D.12, A+B.1(or B.2)+C.83l+D.12, A+B.1(or B.2)+C.83m+D.12, A+B.1(or B.2)+C.83n+D.12, A+B.1(or B.2)+C.84+D.12, A+B.1(or B.2)+C.84a+D.12, A+B.1(or B.2)+C.84b+D.12, A+B.1(or B.2)+C.84c+D.12, A+B.1(or B.2)+C.85+D.12, A+B.1(or B.2)+C.85a+D.12, A+B.1(or B.2)+C.85b+ D.12, A+B.1(or B.2)+C.85c+D.12, A+B.1(or B.2)+C.85d+D.12, A+B.1(or B.2)+C.85e+D.12, A+B.1(or B.2)+C.85f+D.12, A+B.1(or B.2)+C.85g+D.12, A+B. 1(or B.2)+C.85h+D.12, A+B.1(or B.2)+C.85i+D.12, A+B.1(or B.2)+C.86+D.12, A+B.1(or B.2)+C.86a+D.12, A+B.1(or B.2)+C.86b+D.12, A+B.1(or B.2)+C.8 6c+D.12, A+B.1(or B.2)+C.86d+D.12, A+B.1(or B.2)+C.87+D.12, A+B.1(or B.2)+C.87a+D.12, A+B.1(or B.2)+C.88+D.12, A+B.1(or B.2)+C.89+D.12, A+B. 1(or B.2)+C.89a+D.12, A+B.1(or B.2)+C.89b+D.12, A+B.1(or B.2)+C.89c+D.12, A+B.1(or B.2)+C.90+D.12, A+B.1(or B.2)+C.91+D.12, A+B.1(or B.2)+C.92 +D.12, A+B.1(or B.2)+C.93+D.12, A+B.1(or B.2)+C.94+D.12, A+B.1(or B.2)+C.95+D.12, A+B.1(or B.2)+C.96+D.12, A+B.1(or B.2)+C.97+D.12, A+B.1(or B.2)+C.98+D.12, A+B.1(or B.2)+C.99+D.12, A+B.1(or B.2)+C.91 .2)+C.98+D.12, A+B.1(or B.2)+C.98a+D.12, A+B.1(or B.2)+C.99+D.12, A+B.1(or B.2)+C.100+D.12, A+B.1(or B.2)+C.101+D.12, A+B.1(or B.2)+C.102+D.12, A+B.1(or B.2)+C.103+D.12, A+B.1(or B.2)+C.104+D.12, A+B.1(or B.2)+C.105+D.12, A+B.1(or B.2)+C.106+D.12, A+B.1(or B.2)+C.107+D.12, A+B.1( or B.2)+C.108+D.12, A+B.1(or B.2)+C.109+D.12, A+B.1(or B.2)+C.110+D.12, A+B.1(or B.2)+C.111+D.12, A+B.1(or B.2)+C.112+D.12, A+B.1(or B.2)+C.11 3+D.12, A+B.1(or B.2)+C.113a+D.12, A+B.1(or B.2)+C.114+D.12, A+B.1(or B.2)+C.114a+D.12, A+B.1(or B.2)+C.114b+D.12, A+B.1(or B.2)+C.114c+D.1 2, A+B.1(or B.2)+C.114d+D.12, A+B.1(or B.2)+C.114e+D.12, A+B.1(or B.2)+C.114f+D.12, A+B.1(or B.2)+C.114g+D.12, A+B.1(or B.2)+C.114h+D.12, A+B .1(or B.2)+C.114i+D.12,A+B.1(or B.2)+C.115+D.12,A+B.1(or B.2)+C.116+D.12,A+B.1(or B.2)+C.117+D.12,A+B.1(or B.2)+C.118+D.12,A+B.1(or B.2) +C.119+D.12, A+B.1(or B.2)+C.120+D.12, A+B.1(or B.2)+C.121+D.12, A+B.1(or B.2)+C.121a+D.12, A+B.1(or B.2)+C.122+D.12, A+B.1(or B.2)+C.123+D. 12, A+B.1(or B.2)+C.124+D.12, A+B.1(or B.2)+C.125+D.12, A+B.1(or B.2)+C.125a+D.12, A+B.1(or B.2)+C.126+D.12, A+B.1(or B.2)+C.127+D.12, A+B.1 (or B.2)+C.128+D.12, A+B.1(or B.2)+C.129+D.12, A+B.1(or B.2)+C.129a+D.12, A+B.1(or B.2)+C.130+D.12, A+B.1(or B.2)+C.131+D.12, A+B.1(or B.2)+C.132+D.12, A+B.1(or B.2)+C.132a+D.12, A+B.1(or B.2)+C.133+D.12, A+B.1(or B.2)+C.133a+D.12, A+B.1(or B.2)+C.133b+D.12, A+B.1(or B.2)+C.134+D.1 2, A+B.1(or B.2)+C.135+D.12, A+B.1(or B.2)+C.136+D.12, A+B.1(or B.2)+C.137+D.12, A+B.1(or B.2)+C.138+D.12, A+B.1(or B.2)+C.139+D.12, A+B.1(or B.2)+C.140+D.141 .2)+C.140+D.12,A+B.1(or B.2)+C.141+D.12,A+B.1(or B.2)+C.142+D.12,A+B.1(or B.2)+C.143+D.12,A+B.1(or B.2)+C.144+D.12,A+B.1(or B.2)+C.145+ D.12, A+B.1(or B.2)+C.145a+D.12, A+B.1(or B.2)+C.146+D.12, A+B.1(or B.2)+C.146a+D.12, A+B.1(or B.2)+C.147+D.12, A+B.1(or B.2)+C.148+D.12, A+B .1(or B.2)+C.148a+D.12,A+B.1(or B.2)+C.149+D.12,A+B.1(or B.2)+C.150+D.12,A+B.1(or B.2)+C.151+D.12,A+B.1(or B.2)+C.152+D.12,A+B.1(or B.2)+ C.152a+D.12, A+B.1(or B.2)+C.153+D.12, A+B.1(or B.2)+C.153a+D.12, A+B.1(or B.2)+C.153b+D.12, A+B.1(or B.2)+C.153c+D.12, A+B.1(or B.2)+C.154+ D.12, A+B.1(or B.2)+C.154a+D.12, A+B.1(or B.2)+C.155+D.12, A+B.1(or B.2)+C.156+D.12, A+B.1(or B.2)+C.157+D.12, A+B.1(or B.2)+C.157a+D.12, A+B .1(or B.2)+C.158+D.12, A+B.1(or B.2)+C.159+D.12, A+B.1(or B.2)+C.160+D.12, A+B.1(or B.2)+C.161+D.12, A+B.1(or B.2)+C.162+D.12, A+B.1(or B.2)+C.163+D.12, A+B.1(or B.2)+C.164+D.12, A+B.1(or B.2)+C.165+D.12, A+B.1(or B.2)+C.166+D.12, A+B.1(or B.2)+C.167+D.12, A+B.1(or B.2)+C.168+D.12, A+B.1(or B.2)+C.168a+D.12, A+B.1(or B.2)+C.169+D.12, A+B.1(or B.2)+C.170+D.12, A+B.1(or B.2)+C.170a+D.12, A+B.1(or B.2)+C.171+D.12, A+B.1(or B.2)+C.172a+D.12 .2)+C.171a+D.12, A+B.1(or B.2)+C.172+D.12, A+B.1(or B.2)+C.172a+D.12, A+B.1(or B.2)+C.173+D.12, A+B.1(or B.2)+C.173a+D.12, A+B.1(or B.2)+C. 1+D.13a, A+B.1(or B.2)+C.2+D.13a, A+B.1(or B.2)+C.3+D.13a, A+B.1(or B.2)+C.4+D.13a, A+B.1(or B.2)+C.4a+D.13a, A+B.1(or B.2)+C.4b+D.13a, A+B.1 (or B.2)+C.4c+D.13a, A+B.1(or B.2)+C.5+D.13a, A+B.1(or B.2)+C.6+D.13a, A+B.1(or B.2)+C.6a+D.13a, A+B.1(or B.2)+C.6b+D.13a, A+B.1(or B.2)+C.7+ D.13a, A+B.1(or B.2)+C.8+D.13a, A+B.1(or B.2)+C.9+D.13a, A+B.1(or B.2)+C.10+D.13a, A+B.1(or B.2)+C.11+D.13a, A+B.1(or B.2)+C.11a+D.13a, A+B.1 (or B.2)+C.12+D.13a, A+B.1(or B.2)+C.13+D.13a, A+B.1(or B.2)+C.13a+D.13a, A+B.1(or B.2)+C.14+D.13a, A+B.1(or B.2)+C.15+D.13a, A+B.1(or B.2)+C .16+D.13a, A+B.1(or B.2)+C.16a+D.13a, A+B.1(or B.2)+C.17+D.13a, A+B.1(or B.2)+C.17a+D.13a, A+B.1(or B.2)+C.17b+D.13a, A+B.1(or B.2)+C.17c+D.13a, A+B.1(or B.2)+C.17d+D.13a, A+B.1(or B.2)+C.18+D.13a, A+B.1(or B.2)+C.19+D.13a, A+B.1(or B.2)+C.19a+D.13a, A+B.1(or B.2)+C.20+D.13a, A+B. 1(or B.2)+C.21+D.13a, A+B.1(or B.2)+C.22+D.13a, A+B.1(or B.2)+C.23+D.13a, A+B.1(or B.2)+C.23a+D.13a, A+B.1(or B.2)+C.23b+D.13a, A+B.1(or B.2)+ C.24+D.13a, A+B.1(or B.2)+C.25+D.13a, A+B.1(or B.2)+C.26+D.13a, A+B.1(or B.2)+C.26a+D.13a, A+B.1(or B.2)+C.27+D.13a, A+B.1(or B.2)+C.28+D.13 a, A+B.1(or B.2)+C.28a+D.13a, A+B.1(or B.2)+C.28b+D.13a, A+B.1(or B.2)+C.28c+D.13a, A+B.1(or B.2)+C.28d+D.13a, A+B.1(or B.2)+C.28e+D.13a, A+B .1(or B.2)+C.28f+D.13a,A+B.1(or B.2)+C.28g+D.13a,A+B.1(or B.2)+C.29+D.13a,A+B.1(or B.2)+C.30+D.13a,A+B.1(or B.2)+C.31+D.13a,A+B.1(or B.2) +C.31a+D.13a, A+B.1(or B.2)+C.32+D.13a, A+B.1(or B.2)+C.32a+D.13a, A+B.1(or B.2)+C.32b+D.13a, A+B.1(or B.2)+C.32c+D.13a, A+B.1(or B.2)+C.32d +D.13a, A+B.1(or B.2)+C.32e+D.13a, A+B.1(or B.2)+C.32f+D.13a, A+B.1(or B.2)+C.32g+D.13a, A+B.1(or B.2)+C.32h+D.13a, A+B.1(or B.2)+C.32i+D.13 a,A+B.1(or B.2)+C.32j+D.13a,A+B.1(or B.2)+C.32k+D.13a,A+B.1(or B.2)+C.32l+D.13a,A+B.1(or B.2)+C.32m+D.13a,A+B.1(or B.2)+C.32n+D.13a,A+B.1(or B.2)+C.32o+D.13a, A+B.1(or B.2)+C.32p+D.13a, A+B.1(or B.2)+C.32q+D.13a, A+B.1(or B.2)+C.32r+D.13a, A+B.1(or B.2)+C.32s+D.13a, A+B.1(or B.2) .2)+C.32t+D.13a,A+B.1(or B.2)+C.32u+D.13a,A+B.1(or B.2)+C.32v+D.13a,A+B.1(or 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A+B.1(or B.2)+C.73b+D.14a, A+B.1(or B.2)+C.73c+D.14a, A+B.1(or B.2)+C.74+D.14a, A+B.1(or B.2)+C.75+D.14a, A+B.1( or B.2)+C.75a+D.14a, A+B.1(or B.2)+C.75b+D.14a, A+B.1(or B.2)+C.76+D.14a, A+B.1(or B.2)+C.76a+D.14a, A+B.1(or B.2)+C.77+D.14a, A+B.1(or B.2)+ C.77a+D.14a, A+B.1(or B.2)+C.77b+D.14a, A+B.1(or B.2)+C.77c+D.14a, A+B.1(or B.2)+C.78+D.14a, A+B.1(or B.2)+C.79+D.14a, A+B.1(or B.2)+C.80+D. 14a, A+B.1(or B.2)+C.81+D.14a, A+B.1(or B.2)+C.82+D.14a, A+B.1(or B.2)+C.83+D.14a, A+B.1(or B.2)+C.83a+D.14a, A+B.1(or B.2)+C.83b+D.14a, A+B. 1(or B.2)+C.83c+D.14a, A+B.1(or B.2)+C.83d+D.14a, A+B.1(or B.2)+C.83e+D.14a, A+B.1(or B.2)+C.83f+D.14a, A+B.1(or B.2)+C.83g+D.14a, A+B.1(or B.2)+C.83g+D.14a, A+B.1(or B.2)2)+C.83h+D.14a,A+B.1(or B.2)+C.83i+D.14a,A+B.1(or B.2)+C.83j+D.14a,A+B.1(or B.2)+C.83k+D.14a,A+B.1(or B.2)+C.83l+D.14a,A+B.1(or B.2)+C .83m+D.14a, A+B.1(or B.2)+C.83n+D.14a, A+B.1(or B.2)+C.84+D.14a, A+B.1(or B.2)+C.84a+D.14a, A+B.1(or B.2)+C.84b+D.14a, A+B.1(or B.2)+C.84c+D .14a, A+B.1(or 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A+B.1(or B.2)+C.129+D.14a, A+B.1(or B.2)+C.129a+D.14a, A+B.1(or B.2)+C.130+D.14a, A+B.1(or B.2)+C.131+D.14a ,A+B.1(or B.2)+C.132+D.14a,A+B.1(or B.2)+C.132a+D.14a,A+B.1(or B.2)+C.133+D.14a,A+B.1(or B.2)+C.133a+D.14a,A+B.1(or B.2)+C.133b+D.14a,A +B.1(or B.2)+C.134+D.14a, A+B.1(or B.2)+C.135+D.14a, A+B.1(or B.2)+C.136+D.14a, A+B.1(or B.2)+C.137+D.14a, A+B.1(or B.2)+C.138+D.14a, A+B.1 (or B.2)+C.139+D.14a, A+B.1(or B.2)+C.140+D.14a, A+B.1(or B.2)+C.141+D.14a, A+B.1(or B.2)+C.142+D.14a, A+B.1(or B.2)+C.143+D.14a, A+B.1(or B.2 )+C.144+D.14a,A+B.1(or B.2)+C.145+D.14a,A+B.1(or B.2)+C.145a+D.14a,A+B.1(or B.2)+C.146+D.14a,A+B.1(or B.2)+C.146a+D.14a,A+B.1(or B.2)+ C.147+D.14a, A+B.1(or B.2)+C.148+D.14a, A+B.1(or B.2)+C.148a+D.14a, A+B.1(or B.2)+C.149+D.14a, A+B.1(or B.2)+C.150+D.14a, A+B.1(or B.2)+C.15 1+D.14a,A+B.1(or B.2)+C.152+D.14a,A+B.1(or B.2)+C.152a+D.14a,A+B.1(or B.2)+C.153+D.14a,A+B.1(or B.2)+C.153a+D.14a,A+B.1(or B.2)+C.153b +D.14a, A+B.1(or B.2)+C.153c+D.14a, A+B.1(or B.2)+C.154+D.14a, A+B.1(or B.2)+C.154a+D.14a, A+B.1(or B.2)+C.155+D.14a, A+B.1(or B.2)+C.156+D.14a, A+B.1(or B.2)+C.157+D.14a, A+B.1(or B.2)+C.157a+D.14a, A+B.1(or B.2)+C.158+D.14a, A+B.1(or B.2)+C.159+D.14a, A+B.1(or B.2)+C.160+D.14a , A+B.1(or B.2)+C.161+D.14a, A+B.1(or B.2)+C.162+D.14a, A+B.1(or B.2)+C.163+D.14a, A+B.1(or B.2)+C.164+D.14a, A+B.1(or B.2)+C.165+D.14a, A+B. 1(or B.2)+C.166+D.14a, A+B.1(or B.2)+C.167+D.14a, A+B.1(or B.2)+C.168+D.14a, A+B.1(or B.2)+C.168a+D.14a, A+B.1(or B.2)+C.169+D.14a, A+B.1(or B.2) .2)+C.170+D.14a,A+B.1(or B.2)+C.170a+D.14a,A+B.1(or B.2)+C.171+D.14a,A+B.1(or B.2)+C.171a+D.14a,A+B.1(or B.2)+C.172+D.14a,A+B.1(or B.2) +C.172a+D.14a, A+B.1(or B.2)+C.173+D.14a, A+B.1(or B.2)+C.173a+D.14a, A+B.1(or B.2)+C.1+D.19, A+B.1(or B.2)+C.2+D.19, A+B.1(or B.2)+C.3+D.19 , A+B.1(or B.2)+C.4+D.19, A+B.1(or B.2)+C.4a+D.19, A+B.1(or B.2)+C.4b+D.19, A+B.1(or B.2)+C.4c+D.19, A+B.1(or B.2)+C.5+D.19, A+B.1(or B.2)+C.6+ D.19, A+B.1(or B.2)+C.6a+D.19, A+B.1(or B.2)+C.6b+D.19, A+B.1(or 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A+B.1(or B.2)+C.39+D.19, A+B.1(or B.2)+C.39a+D.19, A+B.1(or B.2)+C.40+D.19, A+B.1(or B.2)+C.41+D.19, A+B.1(or B.2)+C.41a+D.19, A+B.1(or B.2)+C.42+D.19, A+ B.1(or B.2)+C.43+D.19, A+B.1(or B.2)+C.44+D.19, A+B.1(or B.2)+C.45+D.19 , A+B.1(or B.2)+C.45a+D.19, A+B.1(or B.2)+C.46+D.19, A+B.1(or B.2)+C.47+D.19, A+B.1(or B.2)+C.48+D.19, A+B.1(or B.2)+C.48a+D.19, A+B.1(or B.2)+ C.49+D.19, A+B.1(or B.2)+C.50+D.19, A+B.1(or B.2)+C.50a+D.19, A+B.1(or B.2)+C.51+D.19, A+B.1(or B.2)+C.51a+D.19, A+B.1(or B.2)+C.52+D.19, A+B .1(or B.2)+C.53+D.19, A+B.1(or B.2)+C.54+D.19, A+B.1(or B.2)+C.55+D.19, A+B.1(or B.2)+C.55a+D.19, A+B.1(or B.2)+C.55b+D.19, A+B.1(or B.2)+C.56 +D.19, A+B.1(or B.2)+C.56a+D.19, A+B.1(or B.2)+C.57+D.19, A+B.1(or B.2)+C.58+D.19, A+B.1(or B.2)+C.59+D.19, A+B.1(or B.2)+C.60+D.19, A+B.1(or B.2)+C.61+D.192)+C.60a+D.19,A+B.1(or B.2)+C.60b+D.19,A+B.1(or B.2)+C.61+D.19,A+B.1(or B.2)+C.62+D.19,A+B.1(or B.2)+C.62a+D.19,A+B.1(or B.2)+C.62b+D.1 9, A+B.1(or B.2)+C.63+D.19, A+B.1(or B.2)+C.64+D.19, A+B.1(or B.2)+C.65+D.19, A+B.1(or B.2)+C.65a+D.19, A+B.1(or B.2)+C.66+D.19, A+B.1(or B.2)+ C.66a+D.19, A+B.1(or B.2)+C.66b+D.19, A+B.1(or B.2)+C.67+D.19, A+B.1(or B.2)+C.67a+D.19, A+B.1(or B.2)+C.67b+D.19, A+B.1(or B.2)+C.67c+D.19, A+B.1(or B.2)+C.67d+D.19, A+B.1(or B.2)+C.67e+D.19, A+B.1(or B.2)+C.67f+D.19, A+B.1(or B.2)+C.67g+D.19, A+B.1(or B.2)+C.67h+D.19, A+B.1(or B.2 )+C.67i+D.19,A+B.1(or B.2)+C.67j+D.19,A+B.1(or B.2)+C.68+D.19,A+B.1(or B.2)+C.68a+D.19,A+B.1(or B.2)+C.69+D.19,A+B.1(or B.2)+C.69a+D.19 , A+B.1(or B.2)+C.70+D.19, A+B.1(or B.2)+C.70a+D.19, A+B.1(or B.2)+C.70b+D.19, A+B.1(or B.2)+C.71+D.19, A+B.1(or B.2)+C.72+D.19, A+B.1(or B.2)+ C.72a+D.19, A+B.1(or B.2)+C.73+D.19, A+B.1(or B.2)+C.73a+D.19, A+B.1(or B.2)+C.73b+D.19, A+B.1(or B.2)+C.73c+D.19, A+B.1(or B.2)+C.74+D.19, A +B.1(or B.2)+C.75+D.19, A+B.1(or B.2)+C.75a+D.19, A+B.1(or B.2)+C.75b+D.19, A+B.1(or B.2)+C.76+D.19, A+B.1(or B.2)+C.76a+D.19, A+B.1(or B.2)+C.77+D.19, A+B.1(or B.2)+C.77a+D.19, A+B.1(or B.2)+C.77b+D.19, A+B.1(or B.2)+C.77c+D.19, A+B.1(or B.2)+C.78+D.19, A+B.1(or B.2)+C.79+D.19, A+B. 1(or B.2)+C.80+D.19, A+B.1(or B.2)+C.81+D.19, A+B.1(or B.2)+C.82+D.19, A+B.1(or B.2)+C.83+D.19, A+B.1(or B.2)+C.83a+D.19, A+B.1(or B.2)+C.83b+ D.19, A+B.1(or B.2)+C.83c+D.19, A+B.1(or B.2)+C.83d+D.19, A+B.1(or B.2)+C.83e+D.19, A+B.1(or B.2)+C.83f+D.19, A+B.1(or B.2)+C.83g+D.19, A+B.1 (or B.2)+C.83h+D.19, A+B.1(or B.2)+C.83i+D.19, A+B.1(or B.2)+C.83j+D.19, A+B.1(or B.2)+C.83k+D.19, A+B.1(or B.2)+C.83l+D.19, A+B.1(or B.2)+C.8 3m+D.19,A+B.1(or B.2)+C.83n+D.19,A+B.1(or B.2)+C.84+D.19,A+B.1(or B.2)+C.84a+D.19,A+B.1(or B.2)+C.84b+D.19,A+B.1(or B.2)+C.84c+D.19,A+B .1(or B.2)+C.85+D.19, A+B.1(or B.2)+C.85a+D.19, A+B.1(or B.2)+C.85b+D.19, A+B.1(or B.2)+C.85c+D.19, A+B.1(or B.2)+C.85d+D.19, A+B.1(or B.2)+C. 85e+D.19,A+B.1(or B.2)+C.85f+D.19,A+B.1(or B.2)+C.85g+D.19,A+B.1(or B.2)+C.85h+D.19,A+B.1(or B.2)+C.85i+D.19,A+B.1(or B.2)+C.86+D.19,A+ B.1(or B.2)+C.86a+D.19, A+B.1(or B.2)+C.86b+D.19, A+B.1(or B.2)+C.86c+D.19, A+B.1(or B.2)+C.86d+D.19, A+B.1(or B.2)+C.87+D.19, A+B.1(or B.2)+C.87a+D.19, A+B.1(or B.2)+C.88+D.19, A+B.1(or B.2)+C.89+D.19, A+B.1(or B.2)+C.89a+D.19, A+B.1(or B.2)+C.89b+D.19, A+B.1(or B.2)+C.89c+D.19, A+B .1(or B.2)+C.90+D.19, A+B.1(or B.2)+C.91+D.19, A+B.1(or B.2)+C.92+D.19, A+B.1(or B.2)+C.93+D.19, A+B.1(or B.2)+C.94+D.19, A+B.1(or B.2)+C.95+D .19, A+B.1(or B.2)+C.96+D.19, A+B.1(or B.2)+C.97+D.19, A+B.1(or B.2)+C.98+D.19, A+B.1(or B.2)+C.98a+D.19, A+B.1(or B.2)+C.99+D.19, A+B.1(or B.2)+C.98a+D.19 )+C.100+D.19, A+B.1(or B.2)+C.101+D.19, A+B.1(or B.2)+C.102+D.19, A+B.1(or B.2)+C.103+D.19, A+B.1(or B.2)+C.104+D.19, A+B.1(or B.2)+C.105+D. 19, A+B.1(or B.2)+C.106+D.19, A+B.1(or B.2)+C.107+D.19, A+B.1(or B.2)+C.108+D.19, A+B.1(or B.2)+C.109+D.19, A+B.1(or B.2)+C.110+D.19, A+B.1(or B.2)+C.111+D.19, A+B.1(or B.2)+C.112+D.19, A+B.1(or B.2)+C.113+D.19, A+B.1(or B.2)+C.113a+D.19, A+B.1(or B.2)+C.114+D.19, A+B.1(or B.2)+C.11 4a+D.19, A+B.1(or B.2)+C.114b+D.19, A+B.1(or B.2)+C.114c+D.19, A+B.1(or B.2)+C.114d+D.19, A+B.1(or B.2)+C.114e+D.19, A+B.1(or B.2)+C.114f+D. 19, A+B.1(or B.2)+C.114g+D.19, A+B.1(or B.2)+C.114h+D.19, A+B.1(or B.2)+C.114i+D.19, A+B.1(or B.2)+C.115+D.19, A+B.1(or B.2)+C.116+D.19, A+B.1(or B.2)+C.117+D.19, A+B.1(or B.2)+C.118+D.19, A+B.1(or B.2)+C.119+D.19, A+B.1(or B.2)+C.120+D.19, A+B.1(or B.2)+C.121+D.19, A+B.1(or B.2)+C .121a+D.19, A+B.1(or B.2)+C.122+D.19, A+B.1(or B.2)+C.123+D.19, A+B.1(or B.2)+C.124+D.19, A+B.1(or B.2)+C.125+D.19, A+B.1(or B.2)+C.125a+D.1 9, A+B.1(or B.2)+C.126+D.19, A+B.1(or B.2)+C.127+D.19, A+B.1(or B.2)+C.128+D.19, A+B.1(or B.2)+C.129+D.19, A+B.1(or B.2)+C.129a+D.19, A+B.1(or B.2)+C.130+D.19, A+B.1(or B.2)+C.131+D.19, A+B.1(or B.2)+C.132+D.19, A+B.1(or B.2)+C.132a+D.19, A+B.1(or B.2)+C.133+D.19, A+B.1(or B.2)+C.13 3a+D.19, A+B.1(or B.2)+C.133b+D.19, A+B.1(or B.2)+C.134+D.19, A+B.1(or B.2)+C.135+D.19, A+B.1(or B.2)+C.136+D.19, A+B.1(or B.2)+C.137+D.19, A+B.1(or B.2)+C.138+D.19, A+B.1(or B.2)+C.139+D.19, A+B.1(or B.2)+C.140+D.19, A+B.1(or B.2)+C.141+D.19, A+B.1(or B.2)+C.142+D.19, A+B.1(or B.2)+C.143+D.19 )+C.143+D.19,A+B.1(or B.2)+C.144+D.19,A+B.1(or B.2)+C.145+D.19,A+B.1(or B.2)+C.145a+D.19,A+B.1(or B.2)+C.146+D.19,A+B.1(or B.2)+C.146a+ D.19, A+B.1(or B.2)+C.147+D.19, A+B.1(or B.2)+C.148+D.19, A+B.1(or B.2)+C.148a+D.19, A+B.1(or B.2)+C.149+D.19, A+B.1(or B.2)+C.150+D.19, A+B.1(or B.2)+C.151+D.19, A+B.1(or B.2)+C.152+D.19, A+B.1(or B.2)+C.152a+D.19, A+B.1(or B.2)+C.153+D.19, A+B.1(or B.2)+C.153a+D.19, A+B.1(or B.2)+ C.153b+D.19, A+B.1(or B.2)+C.153c+D.19, A+B.1(or B.2)+C.154+D.19, A+B.1(or B.2)+C.154a+D.19, A+B.1(or B.2)+C.155+D.19, A+B.1(or B.2)+C.156+D .19, A+B.1(or B.2)+C.157+D.19, A+B.1(or B.2)+C.157a+D.19, A+B.1(or B.2)+C.158+D.19, A+B.1(or B.2)+C.159+D.19, A+B.1(or B.2)+C.160+D.19, A+B.1 (or B.2)+C.161+D.19, A+B.1(or B.2)+C.162+D.19, A+B.1(or B.2)+C.163+D.19, A+B.1(or B.2)+C.164+D.19, A+B.1(or B.2)+C.165+D.19, A+B.1(or B.2)+C.1 66+D.19,A+B.1(or B.2)+C.167+D.19,A+B.1(or B.2)+C.168+D.19,A+B.1(or B.2)+C.168a+D.19,A+B.1(or B.2)+C.169+D.19,A+B.1(or B.2)+C.170+D.19,A +B.1(or B.2)+C.170a+D.19, A+B.1(or B.2)+C.171+D.19, A+B.1(or B.2)+C.171a+D.19, A+B.1(or B.2)+C.172+D.19, A+B.1(or B.2)+C.172a+D.19, A+B.1(or B.2) .2)+C.173+D.19,A+B.1(or B.2)+C.173a+D.19,A+B.1(or B.2)+C.1+D.20,A+B.1(or B.2)+C.2+D.20,A+B.1(or B.2)+C.3+D.20,A+B.1(or B.2)+C.4+D.20,A+ B.1(or B.2)+C.4a+D.20, A+B.1(or B.2)+C.4b+D.20, A+B.1(or B.2)+C.4c+D.20, A+B.1(or B.2)+C.5+D.20, A+B.1(or B.2)+C.6+D.20, A+B.1(or B.2)+C.6a+D.20, A+B.1(or B.2)+C.6b+D.20, A+B.1(or B.2)+C.7+D.20, A+B.1(or B.2)+C.8+D.20, A+B.1(or B.2)+C.9+D.20, A+B.1(or B.2)+C.10+D.20, A+B.1(or B.2)+C.1 1+D.20, A+B.1(or B.2)+C.11a+D.20, A+B.1(or B.2)+C.12+D.20, A+B.1(or B.2)+C.13+D.20, A+B.1(or B.2)+C.13a+D.20, A+B.1(or B.2)+C.14+D.20, A+B.1( or B.2)+C.15+D.20, A+B.1(or B.2)+C.16+D.20, A+B.1(or B.2)+C.16a+D.20, A+B.1(or B.2)+C.17+D.20, A+B.1(or B.2)+C.17a+D.20, A+B.1(or B.2)+C.17b+D. .20, A+B.1(or B.2)+C.17c+D.20, A+B.1(or B.2)+C.17d+D.20, A+B.1(or B.2)+C.18+D.20, A+B.1(or B.2)+C.19+D.20, A+B.1(or B.2)+C.19a+D.20, A+B.1(or B.2)+C.19d+D.20 .2)+C.20+D.20, A+B.1(or B.2)+C.21+D.20, A+B.1(or B.2)+C.22+D.20, A+B.1(or B.2)+C.23+D.20, A+B.1(or B.2)+C.23a+D.20, A+B.1(or B.2)+C.23b+D.20 , A+B.1(or B.2)+C.24+D.20, A+B.1(or B.2)+C.25+D.20, A+B.1(or B.2)+C.26+D.20, A+B.1(or B.2)+C.26a+D.20, A+B.1(or B.2)+C.27+D.20, A+B.1(or B.2)+C .28+D.20, A+B.1(or B.2)+C.28a+D.20, A+B.1(or B.2)+C.28b+D.20, A+B.1(or B.2)+C.28c+D.20, A+B.1(or B.2)+C.28d+D.20, A+B.1(or B.2)+C.28e+D.20, A +B.1(or B.2)+C.28f+D.20, A+B.1(or B.2)+C.28g+D.20, A+B.1(or B.2)+C.29+D.20, A+B.1(or B.2)+C.30+D.20, A+B.1(or B.2)+C.31+D.20, A+B.1(or B.2)+C.31a+D.20, A+B.1(or B.2)+C.32+D.20, A+B.1(or B.2)+C.32a+D.20, A+B.1(or B.2)+C.32b+D.20, A+B.1(or B.2)+C.32c+D.20, A+B.1(or B.2)+C.32d+D.20, A +B.1(or B.2)+C.32e+D.20,A+B.1(or B.2)+C.32f+D.20,A+B.1(or B.2)+C.32g+D.20,A+B.1(or B.2)+C.32h+D.20,A+B.1(or B.2)+C.32i+D.20,A+B.1(or B.2) +C.32j+D.20,A+B.1(or B.2)+C.32k+D.20,A+B.1(or B.2)+C.32l+D.20,A+B.1(or B.2)+C.32m+D.20,A+B.1(or B.2)+C.32n+D.20,A+B.1(or B.2)+C.32o+D.2 0, A+B.1(or B.2)+C.32p+D.20, A+B.1(or B.2)+C.32q+D.20, A+B.1(or B.2)+C.32r+D.20, A+B.1(or B.2)+C.32s+D.20, A+B.1(or B.2)+C.32t+D.20, A+B.1(or B.2)+C.32r+D.20 .2)+C.32u+D.20,A+B.1(or B.2)+C.32v+D.20,A+B.1(or B.2)+C.32w+D.20,A+B.1(or B.2)+C.32x+D.20,A+B.1(or B.2)+C.32y+D.20,A+B.1(or B.2)+C.32z+ D.20, A+B.1(or B.2)+C.32zx+D.20, A+B.1(or B.2)+C.32zy+D.20, A+B.1(or B.2)+C.33+D.20, A+B.1(or B.2)+C.33a+D.20, A+B.1(or B.2)+C.34+D.20, A+B.1 (or B.2)+C.34a+D.20, A+B.1(or B.2)+C.34b+D.20, A+B.1(or B.2)+C.34c+D.20, A+B.1(or B.2)+C.34d+D.20, A+B.1(or B.2)+C.34e+D.20, A+B.1(or B.2)+C.3 5+D.20, A+B.1(or B.2)+C.36+D.20, A+B.1(or B.2)+C.36a+D.20, A+B.1(or B.2)+C.36b+D.20, A+B.1(or B.2)+C.36c+D.20, A+B.1(or B.2)+C.36d+D.20, A+B.1(or B.2)+C.36e+D.20, A+B.1(or B.2)+C.36f+D.20, A+B.1(or B.2)+C.36g+D.20, A+B.1(or B.2)+C.36h+D.20, A+B.1(or B.2)+C.36i+D.20, A+B.1(or B.2)+C. 36j+D.20,A+B.1(or B.2)+C.36k+D.20,A+B.1(or B.2)+C.36l+D.20,A+B.1(or B.2)+C.36m+D.20,A+B.1(or B.2)+C.37+D.20,A+B.1(or B.2)+C.37a+D.20,A+ B.1(or B.2)+C.37b+D.20, A+B.1(or B.2)+C.37c+D.20, A+B.1(or B.2)+C.37d+D.20, A+B.1(or B.2)+C.37e+D.20, A+B.1(or B.2)+C.37f+D.20, A+B.1(or B.2)+ C.37g+D.20, A+B.1(or B.2)+C.37h+D.20, A+B.1(or B.2)+C.38+D.20, A+B.1(or B.2)+C.38a+D.20, A+B.1(or B.2)+C.38b+D.20, A+B.1(or B.2)+C.38c+D.20, A+B.1(or B.2)+C.38d+D.20, A+B.1(or B.2)+C.39+D.20, A+B.1(or B.2)+C.39a+D.20, A+B.1(or B.2)+C.40+D.20, A+B.1(or B.2)+C.41+D.20, A+B.1(or B.2)+C .41a+D.20, A+B.1(or B.2)+C.42+D.20, A+B.1(or B.2)+C.43+D.20, A+B.1(or B.2)+C.44+D.20, A+B.1(or B.2)+C.45+D.20, A+B.1(or B.2)+C.45a+D.20, A+B. 1(or B.2)+C.46+D.20, A+B.1(or B.2)+C.47+D.20, A+B.1(or B.2)+C.48+D.20, A+B.1(or B.2)+C.48a+D.20, A+B.1(or B.2)+C.49+D.20, A+B.1(or B.2)+C.50+D .20, A+B.1(or B.2)+C.50a+D.20, A+B.1(or B.2)+C.51+D.20, A+B.1(or B.2)+C.51a+D.20, A+B.1(or B.2)+C.52+D.20, A+B.1(or B.2)+C.53+D.20, A+B.1(or B.2)+C.54+D.202)+C.54+D.20,A+B.1(or B.2)+C.55+D.20,A+B.1(or B.2)+C.55a+D.20,A+B.1(or B.2)+C.55b+D.20,A+B.1(or B.2)+C.56+D.20,A+B.1(or B.2)+C.56a+D.2 0, A+B.1(or B.2)+C.57+D.20, A+B.1(or B.2)+C.58+D.20, A+B.1(or B.2)+C.59+D.20, A+B.1(or B.2)+C.60+D.20, A+B.1(or B.2)+C.60a+D.20, A+B.1(or B.2)+ C.60b+D.20, A+B.1(or B.2)+C.61+D.20, A+B.1(or B.2)+C.62+D.20, A+B.1(or B.2)+C.62a+D.20, A+B.1(or B.2)+C.62b+D.20, A+B.1(or B.2)+C.63+D.20, A+ B.1(or B.2)+C.64+D.20, A+B.1(or B.2)+C.65+D.20, A+B.1(or B.2)+C.65a+D.20, A+B.1(or B.2)+C.66+D.20, A+B.1(or B.2)+C.66a+D.20, A+B.1(or B.2)+C.6 6b+D.20,A+B.1(or B.2)+C.67+D.20,A+B.1(or B.2)+C.67a+D.20,A+B.1(or B.2)+C.67b+D.20,A+B.1(or B.2)+C.67c+D.20,A+B.1(or B.2)+C.67d+D.20,A+ B.1(or B.2)+C.67e+D.20,A+B.1(or B.2)+C.67f+D.20,A+B.1(or B.2)+C.67g+D.20,A+B.1(or B.2)+C.67h+D.20,A+B.1(or B.2)+C.67i+D.20,A+B.1(or B.2)+ C.67j+D.20, A+B.1(or B.2)+C.68+D.20, A+B.1(or B.2)+C.68a+D.20, A+B.1(or B.2)+C.69+D.20, A+B.1(or B.2)+C.69a+D.20, A+B.1(or B.2)+C.70+D.20, A+ B.1(or B.2)+C.70a+D.20, A+B.1(or B.2)+C.70b+D.20, A+B.1(or B.2)+C.71+D.20, A+B.1(or B.2)+C.72+D.20, A+B.1(or B.2)+C.72a+D.20, A+B.1(or B.2)+C.73+D.20, A+B.1(or B.2)+C.73a+D.20, A+B.1(or B.2)+C.73b+D.20, A+B.1(or B.2)+C.73c+D.20, A+B.1(or B.2)+C.74+D.20, A+B.1(or B.2)+C.75+D.20, A+B .1(or B.2)+C.75a+D.20, A+B.1(or B.2)+C.75b+D.20, A+B.1(or B.2)+C.76+D.20, A+B.1(or B.2)+C.76a+D.20, A+B.1(or B.2)+C.77+D.20, A+B.1(or B.2)+C.7 7a+D.20, A+B.1(or B.2)+C.77b+D.20, A+B.1(or B.2)+C.77c+D.20, A+B.1(or B.2)+C.78+D.20, A+B.1(or B.2)+C.79+D.20, A+B.1(or B.2)+C.80+D.20, A+B.1 (or B.2)+C.81+D.20, A+B.1(or B.2)+C.82+D.20, A+B.1(or B.2)+C.83+D.20, A+B.1(or B.2)+C.83a+D.20, A+B.1(or B.2)+C.83b+D.20, A+B.1(or B.2)+C.83c+ D.20, A+B.1(or B.2)+C.83d+D.20, A+B.1(or B.2)+C.83e+D.20, A+B.1(or B.2)+C.83f+D.20, A+B.1(or B.2)+C.83g+D.20, A+B.1(or B.2)+C.83h+D.20, A+B.1 (or B.2)+C.83i+D.20, A+B.1(or B.2)+C.83j+D.20, A+B.1(or B.2)+C.83k+D.20, A+B.1(or B.2)+C.83l+D.20, A+B.1(or B.2)+C.83m+D.20, A+B.1(or B.2)+C.8 3n+D.20, A+B.1(or B.2)+C.84+D.20, A+B.1(or B.2)+C.84a+D.20, A+B.1(or B.2)+C.84b+D.20, A+B.1(or B.2)+C.84c+D.20, A+B.1(or B.2)+C.85+D.20, A+B. 1(or B.2)+C.85a+D.20, A+B.1(or B.2)+C.85b+D.20, A+B.1(or B.2)+C.85c+D.20, A+B.1(or B.2)+C.85d+D.20, A+B.1(or B.2)+C.85e+D.20, A+B.1(or B.2)+C.85f+D.20,A+B.1(or B.2)+C.85g+D.20,A+B.1(or B.2)+C.85h+D.20,A+B.1(or B.2)+C.85i+D.20,A+B.1(or B.2)+C.86+D.20,A+B.1(or B.2)+C.86a+D.20,A+ B.1(or B.2)+C.86b+D.20, A+B.1(or B.2)+C.86c+D.20, A+B.1(or B.2)+C.86d+D.20, A+B.1(or B.2)+C.87+D.20, A+B.1(or B.2)+C.87a+D.20, A+B.1(or B.2)+C .88+D.20, A+B.1(or B.2)+C.89+D.20, A+B.1(or B.2)+C.89a+D.20, A+B.1(or B.2)+C.89b+D.20, A+B.1(or B.2)+C.89c+D.20, A+B.1(or B.2)+C.90+D.20, A+B .1(or B.2)+C.91+D.20, A+B.1(or B.2)+C.92+D.20, A+B.1(or B.2)+C.93+D.20, A+B.1(or B.2)+C.94+D.20, A+B.1(or B.2)+C.95+D.20, A+B.1(or B.2)+C.96+D .20, A+B.1(or B.2)+C.97+D.20, A+B.1(or B.2)+C.98+D.20, A+B.1(or B.2)+C.98a+D.20, A+B.1(or B.2)+C.99+D.20, A+B.1(or B.2)+C.100+D.20, A+B.1(or B.2)+C.97+D.20, A+B.1(or B.2)+C.98+D.20, A+B.1(or B.2)+C.98a+D.20, A+B.1(or B.2)+C.99+D.20, A+B.1(or B.2)+C.97+D.20, A+B.1(or B.2)+C.98 2)+C.101+D.20, A+B.1(or B.2)+C.102+D.20, A+B.1(or B.2)+C.103+D.20, A+B.1(or B.2)+C.104+D.20, A+B.1(or B.2)+C.105+D.20, A+B.1(or B.2)+C.106+D .20, A+B.1(or B.2)+C.107+D.20, A+B.1(or B.2)+C.108+D.20, A+B.1(or B.2)+C.109+D.20, A+B.1(or B.2)+C.110+D.20, A+B.1(or B.2)+C.111+D.20, A+B.1( or B.2)+C.112+D.20, A+B.1(or B.2)+C.113+D.20, A+B.1(or B.2)+C.113a+D.20, A+B.1(or B.2)+C.114+D.20, A+B.1(or B.2)+C.114a+D.20, A+B.1(or B.2)+C.114b+D.20, A+B.1(or B.2)+C.114c+D.20, A+B.1(or B.2)+C.114d+D.20, A+B.1(or B.2)+C.114e+D.20, A+B.1(or B.2)+C.114f+D.20, A+B.1(or B.2)+C.114g +D.20, A+B.1(or B.2)+C.114h+D.20, A+B.1(or B.2)+C.114i+D.20, A+B.1(or B.2)+C.115+D.20, A+B.1(or B.2)+C.116+D.20, A+B.1(or B.2)+C.117+D.20, A+ B.1(or B.2)+C.118+D.20, A+B.1(or B.2)+C.119+D.20, A+B.1(or B.2)+C.120+D.20, A+B.1(or B.2)+C.121+D.20, A+B.1(or B.2)+C.121a+D.20, A+B.1(or B.2) +C.122+D.20, A+B.1(or B.2)+C.123+D.20, A+B.1(or B.2)+C.124+D.20, A+B.1(or B.2)+C.125+D.20, A+B.1(or B.2)+C.125a+D.20, A+B.1(or B.2)+C.126+D. 20, A+B.1(or B.2)+C.127+D.20, A+B.1(or B.2)+C.128+D.20, A+B.1(or B.2)+C.129+D.20, A+B.1(or B.2)+C.129a+D.20, A+B.1(or B.2)+C.130+D.20, A+B.1 (or B.2)+C.131+D.20, A+B.1(or B.2)+C.132+D.20, A+B.1(or B.2)+C.132a+D.20, A+B.1(or B.2)+C.133+D.20, A+B.1(or B.2)+C.133a+D.20, A+B.1(or B.2)+C .133b+D.20, A+B.1(or B.2)+C.134+D.20, A+B.1(or B.2)+C.135+D.20, A+B.1(or B.2)+C.136+D.20, A+B.1(or B.2)+C.137+D.20, A+B.1(or B.2)+C.138+D.20 , A+B.1(or B.2)+C.139+D.20, A+B.1(or B.2)+C.140+D.20, A+B.1(or B.2)+C.141+D.20, A+B.1(or B.2)+C.142+D.20, A+B.1(or B.2)+C.143+D.20, A+B.1(or B.2)+C.144+D.202)+C.144+D.20,A+B.1(or B.2)+C.145+D.20,A+B.1(or B.2)+C.145a+D.20,A+B.1(or B.2)+C.146+D.20,A+B.1(or B.2)+C.146a+D.20,A+B.1(or B.2)+C.14 7+D.20,A+B.1(or B.2)+C.148+D.20,A+B.1(or B.2)+C.148a+D.20,A+B.1(or B.2)+C.149+D.20,A+B.1(or B.2)+C.150+D.20,A+B.1(or B.2)+C.151+D.20,A+ B.1(or B.2)+C.152+D.20, A+B.1(or B.2)+C.152a+D.20, A+B.1(or B.2)+C.153+D.20, A+B.1(or B.2)+C.153a+D.20, A+B.1(or B.2)+C.153b+D.20, A+B.1(or B.2) .2)+C.153c+D.20,A+B.1(or B.2)+C.154+D.20,A+B.1(or B.2)+C.154a+D.20,A+B.1(or B.2)+C.155+D.20,A+B.1(or B.2)+C.156+D.20,A+B.1(or B.2)+C.15 7+D.20,A+B.1(or B.2)+C.157a+D.20,A+B.1(or B.2)+C.158+D.20,A+B.1(or B.2)+C.159+D.20,A+B.1(or B.2)+C.160+D.20,A+B.1(or B.2)+C.161+D.20,A +B.1(or B.2)+C.162+D.20,A+B.1(or B.2)+C.163+D.20,A+B.1(or B.2)+C.164+D.20,A+B.1(or B.2)+C.165+D.20,A+B.1(or B.2)+C.166+D.20,A+B.1(or B.2) +C.167+D.20,A+B.1(or B.2)+C.168+D.20,A+B.1(or B.2)+C.168a+D.20,A+B.1(or B.2)+C.169+D.20,A+B.1(or B.2)+C.170+D.20,A+B.1(or B.2)+C.170a+D .20, A+B.1(or B.2)+C.171+D.20, A+B.1(or B.2)+C.171a+D.20, A+B.1(or B.2)+C.172+D.20, A+B.1(or B.2)+C.172a+D.20, A+B.1(or B.2)+C.173+D.20, A+B.1(or B.2)+C.173a+D.20. .

[0166] In the composition of the present invention, the weight ratio of herbicide A (especially (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane) to herbicide C is generally 1:0.002-1:160, preferably 1:0.0026-1:107, more preferably 1:0.004-1:80, wherein each herbicide C which is an ester or salt of an acid is calculated as an acid.

[0167] In another embodiment, the weight ratio of herbicide A (especially (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane) to herbicide C is 1:0.002-1:48, preferably 1:0.002-1:32, more preferably 1:0.004-1:24, wherein each herbicide C which is an ester or salt of an acid is calculated as an acid. The above weight ratios are particularly suitable for controlling undesirable plants in sunflowers.

[0168] In another embodiment, the weight ratio of herbicide A (especially (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane) to herbicide C is 1:0.005-1:48, preferably 1:0.006-1:32, more preferably 1:0.01-1:24, wherein each herbicide C which is an ester or salt of an acid is calculated as an acid. The above weight ratios are particularly suitable for controlling undesirable plants in corn.

[0169] In another embodiment, the weight ratio of herbicide A (especially (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane) to herbicide C is 1:0.002-1:160, preferably 1:0.0026-1:107, more preferably 1:0.004-1:80, wherein each herbicide C which is an ester or salt of an acid is calculated as an acid. The above weight ratios are particularly suitable for controlling undesirable plants in leguminous plants.

[0170] In another embodiment, the weight ratio of herbicide A (especially (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane) to herbicide C is 1:0.002-1:160, preferably 1:0.0026-1:107, more preferably 1:0.004-1:80, wherein each herbicide C which is an ester or salt of an acid is calculated as an acid. The above weight ratios are particularly suitable for controlling undesirable plants in rice.

[0171] In the composition of the present invention, the weight ratio of herbicide B (especially acetochlor (B.1) or pretilachlor (B.2)) to herbicide C is generally 1:0.0004-1:160, preferably 1:0.0006-1:80, more preferably 1:0.001-1:53, wherein each herbicide C which is an ester or salt of an acid is calculated as an acid.

[0172] In another embodiment, the weight ratio of herbicide B (especially acetochlor (B.1) or pretilachlor (B.2)) to herbicide C is 1:0.0004-1:48, preferably 1:0.0006-1:24, more preferably 1:0.001-1:16, wherein each herbicide C which is an ester or salt of an acid is calculated as an acid. The above weight ratios are particularly suitable for controlling undesirable plants in sunflowers.

[0173] In another embodiment, the weight ratio of herbicide B (especially acetochlor (B.1) or pretilachlor (B.2)) to herbicide C is 1:0.001-1:48, preferably 1:0.0016-1:24, more preferably 1:0.0025-1:16, wherein each herbicide C that is an ester or salt of an acid is calculated as an acid. The above weight ratio is particularly suitable for controlling undesirable plants in corn.

[0174] In another embodiment, the weight ratio of herbicide B (especially acetochlor (B.1) or pretilachlor (B.2)) to herbicide C is 1:0.0004-1:160, preferably 1:0.0006-1:80, more preferably 1:0.001-1:53, wherein each herbicide C which is an ester or salt of an acid is calculated as an acid. The above weight ratio is particularly suitable for controlling undesirable plants in leguminous plants or rice.

[0175] The composition contains the safener D in an effective amount of generally at least 0.1% by weight, in particular at least 0.2% by weight or at least 0.5% by weight, based on the total amount of herbicide A, herbicide B and, if present, herbicide C.

[0176] The weight ratio of herbicide A (especially (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane) to safener D is generally 1:0.002-1:24, preferably 1:0.004-1:12, more preferably 1:0.012-1:5, wherein each safener D which is an ester or salt of an acid is calculated as an acid.

[0177] The weight ratio of herbicide B to safener D is usually 1:0.0005-1:5, preferably 1:0.001-1:3, more preferably 1:0.0025-1:1, wherein each safener D which is an ester or salt of an acid is calculated as an acid.

[0178] In the methods and uses according to the invention, herbicide A and herbicide B are preferably applied in the same weight ratios as defined herein for the compositions according to the invention.

[0179] In the methods and uses according to the invention, herbicide A and herbicide C are preferably applied in the same weight ratios as defined herein for the compositions according to the invention.

[0180] In the methods and uses according to the invention, herbicide B and herbicide C are preferably applied in the same weight ratios as defined herein for the compositions according to the invention.

[0181] In the methods and uses according to the invention, the herbicide A and the safener D are preferably applied in the same weight ratios as defined herein for the compositions according to the invention.

[0182] In the methods and uses according to the invention, the herbicide B and the safener D are preferably applied in the same weight ratios as defined herein for the compositions according to the invention.

[0183] In the methods and uses according to the invention, the herbicide A, the herbicide B and, if present, the herbicide C and / or the safener D can be applied jointly or separately.

[0184] In the methods and uses according to the invention, the herbicide A, the herbicide B and, if present, the herbicide C and / or the safener D can be applied simultaneously or sequentially.

[0185] Preferably, herbicide A, herbicide B and, if present, herbicide C and / or safener D are applied to the undesirable plants simultaneously. In another embodiment, herbicide A, herbicide B and, if present, herbicide C and / or safener D are provided as a herbicide composition of the invention (e.g., a tank mix containing herbicide A, herbicide B and, if present, herbicide C and / or safener D) applied to the undesirable plants. Thus, in some embodiments of the methods of the invention, the herbicidal composition of the invention is applied to the undesirable plants or their locus or to the soil or water to prevent the emergence or growth of the undesirable plants.

[0186] In the case of separate or sequential application, the order of application of the herbicide A, the herbicide B and, if present, the herbicide C and / or the safener D is of little importance. It is only necessary that the herbicide A, the herbicide B and, if present, the herbicide C and / or the safener D are applied within a time frame that allows the active ingredients to act simultaneously on the plants to be controlled and / or safened, preferably within a time frame of at most 14 days, in particular at most 7 days.

[0187] In the methods and uses according to the invention, the herbicide A, the herbicide B and, if present, the herbicide C and / or the safener D (or the composition according to the invention) can be applied pre-emergence (before the emergence of the unwanted plants) or post-emergence (ie during and / or after the emergence of the unwanted plants).

[0188] Preferably, the herbicide A, the herbicide B and, if present, the herbicide C and / or the safener D (or the composition according to the invention) are applied before the emergence of the undesired plants (pre-emergence).

[0189] More preferably, the herbicide A, the herbicide B and, if present, the herbicide C and / or the safener D (or the composition according to the invention) are applied before or during the emergence of the undesired plants (pre-emergence or early-postemergence).

[0190] In a further embodiment, the herbicide A, the herbicide B and, if present, the herbicide C and / or the safener D (or the composition according to the invention) are applied after the emergence of the undesired plants.

[0191] In the case of post-emergence treatment, the herbicide A, the herbicide B and, if present, the herbicide C and / or the safener D (or the composition according to the invention) are preferably applied after the undesirable plants have emerged and have developed up to 6 leaves.

[0192] The compositions and methods according to the invention are suitable for controlling a large number of undesirable plants (harmful plants), including monocotyledonous and dicotyledonous weeds.

[0193] In one embodiment, the undesirable plants are selected from monocotyledonous weed varieties. Preferably, the undesirable plants are selected from the Poaceae. More preferably, the undesirable plants are selected from the Aveneae, Bromeae, Paniceae and Poeae. In one embodiment, the undesirable plants are selected from the Aveneae. In another embodiment, the undesirable plants are selected from the Bromeae. In yet another embodiment, the undesirable plants are selected from the Panicae. In yet another embodiment, the undesirable plants are selected from the Poa.

[0194] The compositions and methods of the present invention are particularly useful for controlling annual weeds such as grass weeds, including, but not limited to, Aegilops such as Aegilops cylindrical (AEGCY, Aegilops cylindrical); Agropyron such as Agropyron repens (AGRRE, common wheatgrass); Alopecurus such as ALOMY, Alopecurus aequalis (ALOAE, foxtail grass); Apera such as Apecurus aequalis (APESV, Apera); Avena such as Avena fatua (AVEFA, wild oats) or Avena sterilis subsp.Sterilis (AVEST, false oats); Brachiaria such as Brachiaria plantaginea (BRAPL, Alexander grass) or Brachiaria decumbens (BRADC, Surinam grass); Bromus such as Bromus inermis (BROIN, Bromus inermis), Bromus sterilis (BROST, Bromus sterilis), Bromus tectorum (BROTE, Bromus tectorum), Bromus arvensis (BROAV, Bromus arvensis), Bromus secalinus (BROSE, Black Bromus) or Bromus hordeacus (BROMO, Lop grass); Cenchrus such as Cenchrus serrata (Cenchrus echinatus (CCHEC, Mossman River Grass); Cynodon such as Cynodon dactylon (CYNDA, Cynodon); Digitaria such as Digitaria ciliaris (DIGAD, Cricket Grass), Digitaria sanguinalis (DIGSA, Hairy Crabgrass), Digitaria insularis (TRCIN, Two Ear Grass) or Digitaria ischaemum (DIGIS, Hemostatic Digitaria); Echinochloa such as Echinochloa colonum (ECHCO, Barnyardgrass), Echinochloacrus-galli (ECHCG, Common Barnyardgrass), Echinochloa spp. crus-pavonis)(ECHCV, peacock barnyard grass), Echinochloa oryzoides(ECHOR, early barnyard grass) or Echinochloa phyllogogon(ECHPH, evening barnyard grass);. Eleusine such as Eleusine indica (ELEIN, Indian goose grass); Ischaemum such as Ischaemum rugusom (ISCRU, duckbill grass); Leptochloa such as Leptochloa chinensis (LEFCH, lemon fruit), Leptochloa fascicularis (LEFFA, salt-meadow grass), Leptochloa afiliformis (LEFPC, spiral Leptochloa), Leptochloa mucronata (LEFFI, red Leptochloa), Leptochloa panicoides (LEFPA, tighthead sprangletop), Leptochloa gentiana (Leptochloa chinensis), Leptochloa fascicularis (LEFFA, salt-meadow grass), Leptochloa afiliformis (LEFPC, spiral Leptochloa), Leptochloa mucronata (LEFFI, red Leptochloa), Leptochloa panicoides (LEFPA, tighthead sprangletop), Leptochloa gentiana (Leptochloa chinensis), Leptochloa chinensis (LEFCH, tighthead sprangletop), Leptochloa chinensis (LEFPA ... scabra (LEFSC) or tropical Leptochloavirgata (LEFVI, tropical Leptochloavirgata); Lolium such as Lolium multiflorum (LOLMU, Italian ryegrass), Lolium perenne (LOLPE, perennial ryegrass) or Swiss ryegrass (LOLRI, annual ryegrass); Panicum such as Panicum capillare (PANCA, woolen millet), Panicum dichotomiflorum (PANDI, smooth woolen millet), Panicum laevifolium (PANLF, sweet millet grass) or Panicum miliaceum (PANMI, millet); Phalaris such as Phalaris minor (PHAMI, small canary grass), Phalaris mirabilis (PHALARIS minor) (PHAMI, small canary grass), Phalaris serrata ... paradoxa (PHAPA, mildew grass), Phalaris canariensis (PHACA, Canary grass) or Phalaris brachystachys (PHABR, short-spiked grass); Poa species such as Poa annua (POAAN, annual bluegrass), Poa pratensis (POAPR, meadow bluegrass) or Poa trivialis (POATR, common bluegrass); Rottboellia species such as Rottboellia exaltata (ROOEX, guinea fowl grass);Setaria, such as Setaria faberi (SETFA, Big Setaria), Setaria glauca (PESGL, Pearl Millet), Setaria italic (SETIT, Millet), Setaria pumila (SETPU, Foxtail), Setaria verticillata (SETVE, Whorled Setaria) or Setaria viridis (SETVI, Setaria); and Sorghum, such as Sorghum halepense (SORHA, Sorghum). ;

[0195] Preferably, the undesirable plants are selected from the group consisting of Agropyron, Alopecurus, Apera, Avena, Brachiaria, Bromus, Bermuda grass, Digitaria, Echinochloa, More preferably, the undesirable plants are selected from the group consisting of Agropyron, Alopecurus, Apera, Avena, Brachiaria, Bromus, Cynodon, Digitaria, Echinochloa, The monocotyledonous weed varieties of the genus Alopecurus, Apira, Avena, Digitaria, Echinochloa, Leptochloa, Lolium, Phalaris, Poa and Setaria are even more preferably selected from the genus Alopecurus, Apira, Avena, Digitaria, Echinochloa, Leptochloa, Lolium, Phalaris, Poa and Setaria. The undesirable plants are especially selected from the genus Alopecurus, Apira, Avena, Echinochloa, Leptochloa, Lolium, Phalaris and Poa. The most preferred undesirable plants are selected from the genus Alopecurus, Avena, Lolium and Phalaris.

[0196] In another embodiment, the undesirable plant is a monocotyledonous weed species selected from the genera Alopecurus, Avena, Echinochloa, Lolium, Setaria, and Sorghum.

[0197] In yet another embodiment, the undesirable plants are monocotyledonous weed species selected from the genera Alopecurus, Avena and Lolium.

[0198] In yet another embodiment, the undesirable plant is a monocotyledonous weed species selected from the genera Alopecurus, Apera, Lolium and Poa.

[0199] In another embodiment, the undesirable plants are selected from the group consisting of Elytium wilfordii, Alopecurus paniculatus, Alopecurus paniculatus, Apiraea serrata, Oats australis, Brachiaria plantaine, Brachiaria serrata, Bromus serrata, Bromus australis, Bromus serrata, Bromus serrata, Bromus serrata, Bromus serrata, Bromus serrata, Bromus serrata, Bromus serrata, Bromus serrata, Digitaria ischemum, Echinochloa colona, ​​Echinochloa colona, ​​Echinochloa serrata, Echinochloa erecta, Echinochloa serrata ... filliformis), Leptochloa filliformis, Gentiana, Leptochloa tropicalis, Lolium multiflorum, Perennial ryegrass, Swiss ryegrass, Woolen millet, Panicum foetida, Sweet millet, Panicum sphaerocephalum, Small-seeded mangrove, Miraculous mangrove, Canary mangrove, Short-spiked mangrove, Poa annua, Poa pratensis, Common bluegrass, Coleus sphaerocephalum, French foxtail, Golden foxtail, Millet (Setaria italica), Little foxtail, Whorled foxtail, Setaria, and Sorghum chinense.

[0200] Preferably, the undesirable plants are selected from the group consisting of: Elytium wilfordii, Alopecurus paniculatus, Alopecurus paniculatus, Apiraea serrata, Oats serrata, Brachiaria plantaine, Brachiaria serrata, Bromus serrata, Bromus serrata, Bromus serrata, Bromus serrata, Bromus serrata, Bromus serrata, Bromus serrata, Bermuda grass, Digitaria serrata, Digitaria serrata, Digitaria serrata, Barley serrata, Barnyard grass, Echinochloa crusgalli ... , clustered Leptothamnus, nit grass, millet-like Leptothamnus, gentian, tropical Leptothamnus, multiflora ryegrass, perennial ryegrass, Swiss ryegrass, wooly millet, foreign wild millet, sweet millet, pangolin, small-seeded mangrove, exotic mangrove, canary mangrove, short-spiked mangrove, bluegrass, meadow bluegrass, common bluegrass, cylindrical axis grass, French foxtail, golden foxtail, millet, little dogtail, whorled foxtail and foxtail monocotyledonous weed varieties.

[0201] The monocotyledonous weed species are especially selected from the group consisting of Alopecurus macrostachya, Alopecurus australis, Apira, Oats, Oats, Echinochloa grus-galli, Echinochloa grus-galli, Leptochloa chinensis, Lolium multiflorum, Lolium perenne, Lolium swiss, Echinochloa grus-galli, Echinochloa grus-galli, Leptochloa chinensis, Lolium multiflorum, Lolium perenne, Lolium swiss, Echinochloa grus-galli, Echinochloa grus-galli, and Poa annua, more preferably Alopecurus macrostachya, Alopecurus australis, Apira, Oats, Echinochloa grus-galli, Echinochloa grus-galli, Leptochloa chinensis, Lolium multiflorum, Lolium swiss, Echinochloa grus-galli and Poa annua, most preferably selected from the group consisting of Alopecurus macrostachya, Oats, Echinochloa grus-galli, Echinochloa grus-galli, Leptochloa chinensis, Lolium multiflorum, Lolium swiss, Echinochloa grus-galli and Echinochloa grus.

[0202] In another embodiment, the monocot weed species is selected from the group consisting of Alopecurus macrostachya, Avena sativa, Echinochloa crusgalli, Lolium multiflorum, Setaria viridis, and Sorghum chinense.

[0203] In another embodiment, the monocot weed species is selected from Alopecurus australis, Avena sativa and Lolium multiflorum.

[0204] In yet another embodiment, the monocot weed species is selected from the group consisting of Alopecurus macrostachya, Apera grass, Lolium multiflorum and Poa annua.

[0205] The compositions and methods of the present invention are also suitable for controlling a large number of dicotyledonous weeds, especially broadleaf weeds, including but not limited to Polygonum species such as Polygonum convolvolus (POLCO, golden buckwheat), Amaranthus species such as Amaranthus albus (AMAAL, tumbleweed), Amaranthus blitoides (AMABL, cluster amaranth), Amaranthus hybridus (AMACH, green amaranth), Amaranthus palmeri (AMAPA, long palm amaranth), Amaranthus powellii (AMAPO, Bowie's amaranth), Amaranthus retroflexus (Amaranthus oleraceus) (AMABL, cluster amaranth), Amaranthus oleraceus ... retroflexus (AMARE, redroot amaranth), Amaranthus tuberculatus (AMATU, rough amaranth), Amaranthus rudis (AMATA, tall amaranth) or Amaranthus viridis (AMAVI, green amaranth), Chenopodium species such as Chenopodium album (CHEAL, common chenopodium), Chenopodium ficifolium (CHEFI, fig-leaf chenopodium), Chenopodium polyspermum (CHEPO, multi-seed chenopodium) or Chenopodium hybridum (CHEHY, maple-leaf chenopodium), Sida species such as Sida spinosa L. (SIDSP, spiny yellow chenopodium), Ambrosia species such as Ambrosia ragweed (Ambrosia artemisiifolia (AMBEL, ragweed), Acanthospermum species, Anthemis species such as Anthemis arvensis (ANTAR, field chamomile), Atriplex species, Cirsium species, Convolvulus species, Conyza species such as Conyza bonariensis (ERIBO, fragrant silk grass) or Conyza canadensis (ERICA, Canadian fleabane), Cassia species, Commelina species, Datura species, Euphorbia species,Geranium species such as Geranium dissectum (GERDI), Geranium pusillium (GERPU) or Geranium rotundifolium (GERRT), Galinsoga species, Ipomoea species such as Ipomoea hederacea (IPOHE), Lamium species, Malva species, Matricaria species such as Matricaria chamomilla (MATCH), Matricaria discoidea (MATMT) or Matricaria chamomile (MATMT). inodora (MATIN, chamomile-shaped matricaria), Sysimbrium species, Solanum species, Xanthium species, Veronica species, Viola species, Stellaria species such as Stellaria media (STEME, chickweed), Abutilon theophrasti (ABUTH, velvety leaf), Hemp sesbania (Sesbaniaexaltata Cory, SEBEX, Colorado River hemp), Anoda cristata (ANVCR, mousetail), Bidens pilosa (BIDPI, common needle grass), Centaurea species such as Centaurea cyanus (CENCY, cornflower), Galeopsis tetrahit (GAETE, common weed flower), Galium aparine (GALAP, galium or goose grass), Galium spurium (GALSP, false galium), Galium tricornutum (GALTC, triangular galium), Helianthusannuus (HELAN, sunflower), Desmodium tortuosum (DEDTO, giant galium), Kochia scoparia (KCHSC, Kochia scoparia), Mercurialis annua (MERAN, indigo),Myosotis arvensis (MYOAR, field forget-me-not), corn poppy (PAPRH, corn poppy), Salsola kali (SASKA, potassium hogweed), Sonchus arvensis (SONAR, sowbread), Tagetes minuta (TAGMI, Mexican marigold), Richardia brasiliensis (RCHBR, Brazilian duck tongue), cruciferous weeds such as Raphanus raphanistrum (RAPRA, wild radish), Sinapis alba (SINAL, white mustard), Sinapis arvensis (SINAR, wild mustard), Thlaspi arvense (THLAR, blue mustard), Descurainia sophia)(DESSO, shepherd's purse), Capsella bursa-pastoris(CAPBP, shepherd's purse), Sisymbrium species such as Sisymbrium officinale(SSYOF, drill garlic mustard) or Sisymbrium orientale(SSYOR, Oriental mustard), Brassica kaber(SINAR, wild mustard).

[0206] Preferred undesirable plants are dicotyledonous weed species selected from the group consisting of Abutilon, Amaranth, Ambrosia, Anthemis, Capsella, Knapweed, Chenopodium, Descurainia, Galium, Geranium, Kochia, Matricaria, Papaver, Polygonum, Raphanus, Sinapis, Garlic mustard, Chickweed and Thlaspi.

[0207] More preferably, the undesirable plants are dicotyledonous weed species selected from the group consisting of Amaranth, Ambrosia, Anthemis, Shepherd's Purse, Cornflower, Chenopodium, Ligusticum, Descurainia, Galium, Geranium, Kochia, Matricaria, Papaver, Raphanus, Sinapsis, Garlic Mustard, Chickweed and Scutellaria, even more preferably selected from the group consisting of Anthemis, Cornflower, Geranium, Matricaria, Papaver, Garlic Mustard and Chickweed.

[0208] In another embodiment, the undesirable plant is a dicotyledonous weed species selected from the genera Abutilon, Anthemis, Chenopodium, Geranium, Polygonum and Stellaria.

[0209] Still more preferably, the dicotyledonous weed species are selected from the group consisting of abutilon, amaranth, amaranth, green-spiked amaranth, long-horned amaranth, powell amaranth, short-bracted amaranth, rough-fruited amaranth, western amaranth, wrinkled amaranth, ragweed, field chamomile, shepherd's purse, cornflower, quinoa, quinoa, quinoa, multi-seed quinoa, hybrid quinoa, sweet silk grass, small white wine grass, Descurania sophia, cleaver, creeping vine, wheat kernel pearl, deep-divided geranium, creeping geranium (Geranium pusillum), round-leaved geranium, Kochia, chamomile, matricaria, pale chamomile, poppy, wild buckwheat (Polygonum convolvulus), wild radish, European white mustard, wild European white mustard, drill-fruited garlic mustard, western garlic mustard, chickweed and bluegrass.

[0210] The dicotyledonous weed species are especially selected from the group consisting of Amaranth, Amaranthus annuus, Amaranthus sibiricus, Amaranthus palmatus, Amaranthus powellii, Amaranthus retroflexus, Amaranthus striata, Amaranthus truncatus, Amaranthus chinensis, Amaranthus rugosa, Amaranthus chinensis, Amaranthus rugosa, Amaranthus rugosa, Amaranthus ragweed, Amaranthus annuus, Amaranthus bursa-pastoris, Amaranthus chinensis ... Most preferably the dicot weed species is selected from the group consisting of Anthemis nobilis, Knapweed, Geranium lobata, Geranium prostrate, Geranium rotundifolium, Chamomile, Chamomile sempervivum, Corn Poppy, Garlic Mustard and Chickweed.

[0211] In another embodiment, the dicot weed species is selected from the group consisting of Abutilon, Anthemis nobilis, Chenopodium album, Geranium sphaerocephalum, Fagopyrum sphaerocephalum and Chickweed.

[0212] In another embodiment, the undesirable plants are selected from the group consisting of Agropyron, Alopecurus, Apera, Avena, Brachiaria, Bromus, Cynodon, Digitaria, Echinochloa, genus, duckbill grass, Leptochloa, ryegrass, millet, phragmites, bluegrass, cyperus, Setaria, sorghum, abutilon, chamomile, amaranth, ragweed, shepherd's purse, cornflower, quinoa, white wine grass, Artemisia, Galium, geranium, Kochia, Matricaria, poppy, Polygonum, Raphanus, Sinapsis, garlic mustard, Chickweed and bluegrass.

[0213] Preferably, the undesirable plants are selected from the group consisting of Agropyron, Alopecurus, Avena, Brachiaria, Bromus, Bermuda grass, Digitaria, Echinochloa, genus, duckbill grass, Leptochloa, ryegrass, millet, phragmites, bluegrass, sedge, Setaria, chamomile, amaranth, ragweed, shepherd's purse, cornflower, quinoa, white wine grass, artemisia, galium, kochia, matricaria, poppy, radish, mustard, garlic mustard, chickweed and indigo. More preferably, the undesirable plants are selected from the genera Alopecurus, Apera, Digitaria, Echinochloa, Leptochloa, Lolium, Phalaenopsis, Poa, Setaria, Amaranth, Anthemis, Shepherd's Purse, Knapweed, Chenopodium, Descurainia, Kochia, Matricaria, Papaver, Garlic Mustard, Chickweed and Bluegrass, still more preferably selected from the genera Alopecurus, Apera, Echinochloa, Leptochloa, Secale perenne, Phalaenopsis, Poa, Setaria, Amaranth, Anthemis, Shepherd's Purse, Knapweed, Chenopodium, Descurainia, Kochia, Matricaria, Papaver, Garlic Mustard, Chickweed and Bluegrass. The invention further comprises a plant selected from the genera Alopecurus, Echinochloa, Lolium, Phalaris, Poa, Amaranth, Chenopodium, Matricaria, Papaver and Chickweed, even more preferably selected from the genera Alopecurus, Echinochloa, Lolium, Phalaris, Poa, Amaranth, Chenopodium, Matricaria, Papaver and Chickweed, still more preferably selected from the genera Alopecurus, Echinochloa, Lolium, Phalaris, Poa and Papaver, in particular selected from the genera Alopecurus, Lolium, Phalaris and Papaver.

[0214] In another embodiment, the undesirable plants are selected from the genera Alopecurus, Avena, Echinochloa, Lolium, Setaria, Sorghum, Abutilon, Anthemis, Chenopodium, Geranium, Polygonum, and Chickweed.

[0215] In yet another embodiment, the undesirable plants are selected from the group consisting of: Aesculus vulgaris, Alopecurus macrostachya, Alopecurus serrata, Avena sativa ... Echinochloa erecta, Echinochloa chinensis, Echinochloa striata, Goosegrass, Wrinkled duckbill grass, Leptochloa chinensis, Leptochloa tuftica, Leptochloa spp., Gentiana, Leptochloa spp., Multiflora ryegrass, Perennial ryegrass, Swiss ryegrass, Woolen millet, Wild millet, Sweet millet, Millet, Small-seeded mangosteen, Strange mangosteen, Canary mangosteen, Short-spiked mangosteen, Poa annua, Poa pratensis, Common Poa annua, Amaranthus striata, French foxtail, golden foxtail, millet, foxtail, whorled foxtail, foxtail, stone grass sorghum, ramie, amaranth, North American amaranth, green spike amaranth, long-horned amaranth, Powell amaranth, short-bracted amaranth, rough fruit amaranth, western amaranth, wrinkled fruit amaranth, ragweed, field chamomile, shepherd's purse, cornflower, quinoa, small quinoa, multi-seed quinoa, hybrid quinoa, fragrant silk grass, small white wine grass, sowwort, The present invention comprises the following: cleaver, creeper, wheat kernel, deep-divided geranium, creeping geranium, round-leaved geranium, Kochia, chamomile, matricaria, light chamomile, poppy, wild buckwheat, wild radish, mustard, wild mustard, garlic mustard, garlic mustard, chickweed and blue vegetable, preferably selected from the group consisting of Alopecurus macrostachya, Alopecurus macrostachya, Avena sativa, wild oats, Avena sativa, Avena oleracea, Avena oleracea, Avena oleracea, Avena sativa ... sterilis), Brachiaria plantaine, Brachiaria pitching, Bromus perenne, Bromus sutchuenensis, Bromus sutchuenensis, Bromus sutchuenensis, Bromus sutchuenensis, Bromus sutchuenensis, Digitaria bald, Echinochloa crusgalli, Echinochloa pavo, Echinochloa erecta, Echinochloa sutchuenensis, Echinochloa sutchuenensis, Echinochloa sutchuenensis, Leptochloa chinensis, Leptochloa sutchuenensis, Tropical Leptochloa chinensis, Lolium multiflorum, Perennial ryegrass, Swiss ryegrass, Millet sutchuenensis, Panicum sutchuenensis, Phalaris brachystachyx), small-seeded mangosteen, strange mangosteen, bluegrass, meadow bluegrass, common bluegrass, cylindrical axis grass, French foxtail, golden foxtail, small dogtail, whorled foxtail, foxtail, white amaranth, North American amaranth, green spike amaranth, long-horned amaranth, Powell amaranth, short-bracted amaranth, rough-fruited amaranth, western amaranth, wrinkled amaranth, ragweed, field chamomile, shepherd's purse, cornflower, quinoa, small quinoa, multi-seeded quinoa, hybrid quinoa, fragrant silk grass, small white wine grass, sowworm, cleaver, creeper, wheat kernel, Kochia, chamomile, matricaria, pale chamomile, poppy, wild radish, European white mustard, wild European white mustard, drill fruit garlic mustard, West Asian garlic mustard, chickweed and bluegrass,Preferably, the present invention is selected from the group consisting of Alopecurus macrostachya, Alopecurus macrostachya, Apira grass, Digitaria styracifolia, Digitaria styracifolia, Echinochloa crusgalli, Leptochloa chinensis, Lolium multiflora, Perennial ryegrass, Swiss ryegrass, Short-spiked Manis serrata, Small-seeded Manis serrata, Miraculous Manis serrata, Poa annua, Common Poa annua, French foxtail, Golden foxtail, Setaria pumilla, Verticillata, Setaria, Powell amaranth, Short-bracted Amaranth, Rough-fruited Amaranth, Western Amaranth, Field chamomile, Shepherd's purse, Cornflower, Chenopodium album, Descurainia scabra, Kochia scoparia, Chamomile, Light chamomile, Corn poppy, Drill garlic mustard, Chickweed and Blueweed, more preferably selected from the group consisting of Alopecurus macrostachya, Alopecurus macrostachya, Apira grass, Echinochloa crusgalli, Echinochloa crusgalli, Leptochloa chinensis, Lolium multiflora, Perennial ryegrass, Swiss ryegrass, Short-spiked amaranth, small-seeded amaranth, miraculous amaranth, bluegrass, Poa, Powell amaranth, short-bracted amaranth, rough-fruited amaranth, western amaranth, quinoa, chamomile, light chamomile, corn poppy and chickweed, especially preferably selected from the group consisting of big-spiked alopecuroides, alopecuroides, apiaceae, barnyard grass, paddy field barnyard grass, lycopodium, multiflorum ryegrass, Swiss ryegrass, small-seeded amaranth and bluegrass, especially selected from the group consisting of big-spiked alopecuroides, multiflorum ryegrass, Swiss ryegrass and small-seeded amaranth. ,

[0216] In another embodiment, the undesirable plants are selected from Alopecurus macrostachya, Wild Oats, Echinochloa crusgalli, Lolium multiflorum, Setaria viridis, Sorghum chinense, Abutilon, Anthemis nobilis, Chenopodium album, Geranium sphaerocephalum, Fagopyrum serrata, and Chickweed.

[0217] In another embodiment, the undesirable plants are herbicide resistant or tolerant weed species.

[0218] Exemplary herbicide resistant or tolerant weed species include, but are not limited to, acetyl CoA carboxylase (ACCase) inhibitors (HRAC A class), acetolactate synthase (ALS) inhibitors (HRAC B class), photosystem II (PSII) inhibitors (HRAC C1, C2 and C3 classes), photosystem I (PS I) inhibitors (HRAC D class), protoporphyrinogen oxidase (PPO) inhibitors (HRAC E class), 4-hydroxyphenylpyruvate dioxygenase (HPPD) inhibitors (HRAC F1 class), phytoene desaturase (PDS) inhibitors (HRAC F2 class), carotenoid biosynthesis inhibitors (HRAC F3 class), DOXP synthase inhibitors (HRAC F4 class), 5-enolpyruvylshikimate 3-phosphate (EPSP) inhibitors (HRAC G class), glutamine synthetase inhibitors (HRAC H class), DHP synthase inhibitors (HRAC I class), microtubule assembly inhibitors (HRAC K1 class), mitosis / microtubule organization inhibitors (HRAC The invention also provides biotypes that are resistant or tolerant to herbicides selected from the group consisting of herbicides classified as HRAK (HRAC K2 class), very long chain fatty acid (VLCFA) inhibitors (HRAC K3 class), cell wall synthesis inhibitors (HRAC L class), decouplers (membrane disruption) (HRAC M class), lipid biosynthesis inhibitors (HRAC N class), synthetic auxins (HRAC O class), auxin transport inhibitors (HRAC P class), and herbicides with unknown mode of action (HRAC Z class).

[0219] Preferably, the herbicide-resistant or -tolerant weed species is selected from biotypes that are resistant or tolerant to herbicides selected from the group consisting of acetyl CoA carboxylase (ACCase) inhibitors (HRAC A class), acetolactate synthase (ALS) inhibitors (HRAC B class), photosystem II (PS II) inhibitors (HRACC1, C2 and C3 classes), protoporphyrinogen oxidase (PPO) inhibitors (HRAC E class), 4-hydroxyphenylpyruvate dioxygenase (HPPD) inhibitors (HRAC F1 class), phytoene desaturase (PDS) inhibitors (HRAC F2 class), 5-enolpyruvylshikimate 3-phosphate (EPSP) inhibitors (HRAC G class), microtubule assembly inhibitors (HRAC K1 class), very long chain fatty acids (VLCFA) inhibitors (HRAC K3 class), cell wall synthesis inhibitors (HRAC L class) and lipid synthesis inhibitors (HRAC N class).

[0220] More preferably, the herbicide resistant or tolerant weed species are selected from biotypes that are resistant or tolerant to herbicides selected from the group consisting of acetyl CoA carboxylase (ACCase) inhibitors (HRAC A class), acetolactate synthase (ALS) inhibitors (HRAC B class), photosystem II (PS II) inhibitors (HRACC1, C2 and C3 classes), microtubule assembly inhibitors (HRAC K1 class), very long chain fatty acids (VLCFA) inhibitors (HRAC K3 class) and lipid synthesis inhibitors (HRAC N class).

[0221] The herbicide-resistant or tolerant weed species are in particular selected from biotypes that are resistant or tolerant to at least one herbicide selected from the group consisting of acetyl CoA carboxylase (ACCase) inhibitors (HRAC class A), acetolactate synthase (ALS) inhibitors (HRAC class B) and photosystem II (PSII) inhibitors (HRAC classes C1, C2 and C3).

[0222] In another embodiment, the resistant or tolerant biotype is selected from the group consisting of Agropyron, Alopecurus, Apera, Avena, Brachiaria, Bromus, Cynodon, Digitaria, Echinochloa, genus, duckbill grass, Leptochloa, ryegrass, millet, phragmites, bluegrass, cyperus, Setaria, sorghum, abutilon, chamomile, amaranth, ragweed, shepherd's purse, cornflower, quinoa, white wine grass, Artemisia, Galium, geranium, Kochia, Matricaria, poppy, Polygonum, Raphanus, Sinapsis, garlic mustard, Chickweed and bluegrass.

[0223] Preferably, the resistant or tolerant biotype is selected from the group consisting of Agropyron, Alopecurus, Apera, Avena, Brachiaria, Bromus, Cynodon, Digitaria, Echinochloa, genus, duckbill grass, Leptochloa, ryegrass, millet, phragmites, bluegrass, sedge, Setaria, chamomile, amaranth, ragweed, shepherd's purse, cornflower, quinoa, white wine grass, artemisia, galium, kochia, matricaria, poppy, radish, mustard, garlic mustard, chickweed and indigo.

[0224] More preferably, the resistant or tolerant biotype is selected from the genera Alopecurus, Apira, Digitaria, Echinochloa, Leptochloa, Lolium, Phalaenopsis, Poa, Setaria, Amaranth, Anthemis, Shepherd's Purse, Knapweed, Chenopodium, Descurainia, Kochia, Matricaria, Papaver, Garlic Mustard, Chickweed and Bluegrass, still more preferably selected from the genera Alopecurus, Apira, Echinochloa, Leptochloa, The genus Lolium, Phalaenopsis, Poa, Amaranth, Chenopodium, Matricaria, Papaver and Chickweed, even more preferably selected from the genus Alopecurus, Echinochloa, Lolium, Phalaenopsis, Poa, Amaranth, Chenopodium, Matricaria, Papaver and Chickweed, still more preferably selected from the genus Alopecurus, Echinochloa, Lolium, Phalaenopsis, Poa and Papaver, in particular selected from the genus Alopecurus, Lolium, Phalaenopsis and Papaver.

[0225] In another embodiment, the resistant or tolerant biotype is selected from the group consisting of Alopecurus, Apera, Digitaria, Echinochloa, Leptochloa, Phalaenopsis, Poa, Setaria, Amaranthus, Anthemis, Shepherd's Purse, Knapweed, Chenopodium, Descurainia, Kochia, Matricaria, Papaver, Garlic Mustard, Chickweed and Indigofera, more preferably selected from the group consisting of Alopecurus, Apera, The invention further comprises the following genera: The genera are selected from the genera Alopecuroides, Echinochloa, Leptochloa, Phalaenopsis, Poa, Amaranth, Chenopodium, Matricaria, Papaver and Chickweed, even more preferably selected from the genera Alopecuroides, Echinochloa, Phalaenopsis, Poa, Amaranth, Chenopodium, Matricaria, Papaver and Chickweed, still more preferably selected from the genera Alopecuroides, Echinochloa, Phalaenopsis, Poa and Papaver, in particular selected from the genera Alopecuroides, Phalaenopsis and Papaver.

[0226] In another embodiment, the resistant or tolerant biotype is selected from the group consisting of Alopecurus, Avena, Echinochloa, Lolium, Setaria, Sorghum, Abutilon, Anthemis, Chenopodium, Geranium, Polygonum, and Chickweed.

[0227] In one embodiment, the resistant or tolerant biotype is selected from the genera of Alopecurus, Apera, Digitaria, Echinochloa, Leptochloa, Lolium, Phalaenopsis, Poa and Setaria, preferably selected from the genera of Alopecurus, Apera, Echinochloa, Leptochloa, Lolium, Phalaenopsis and Poa, more preferably selected from the genera of Alopecurus, Echinochloa, Lolium, Phalaenopsis and Poa, especially selected from the monocotyledonous weed varieties of Alopecurus, Lolium and Phalaenopsis.

[0228] In another embodiment, the resistant or tolerant biotype is a monocotyledonous weed variety, preferably selected from the genera Alopecurus, Apera, Digitaria, Echinochloa, Leptochloa, Phalaris, Poa and Setaria, preferably selected from the genera Alopecurus, Apera, Echinochloa, Leptochloa, Phalaris and Poa, more preferably selected from the genera Alopecurus, Echinochloa, Phalaris and Poa, especially selected from the monocotyledonous weed varieties of Alopecurus and Phalaris.

[0229] In another embodiment, the resistant or tolerant biotype is a dicotyledonous weed species, preferably selected from the genera Amaranth, Anthemis, Shepherd's purse, Centaurea, Chenopodium, Descurainia, Kochia, Matricaria, Papaver, Allium, Chickweed and Indigofera, more preferably selected from the genera Amaranth, Chenopodium, Matricaria, Papaver and Chickweed, in particular selected from the genera Papaver.

[0230] In another embodiment, the resistant or tolerant biotype is selected from the group consisting of: Agropyron sibiricum, Alopecurus macrostachya, Alopecurus australis, Wild oats, Oats, Brachiaria plantaine, Brachiaria sibiricum, Bromus ... Mango, bluegrass, meadow bluegrass, common bluegrass, cylindrical axis grass, French foxtail, golden foxtail, millet, small dogtail, whorled foxtail, foxtail, stone grass sorghum, ramie, amaranth, North American amaranth, green spike amaranth, long-horned amaranth, Powell amaranth, short-bracted amaranth, rough-fruited amaranth, western amaranth, wrinkled amaranth, ragweed, field chamomile, shepherd's purse, cornflower, quinoa, small quinoa, multi-seeded quinoa, hybrid quinoa, fragrant silk grass, small white wine grass, sowworm, cleaver, climbing vine, wheat kernel pearl, deep-divided geranium, creeping geranium, round-leaved geranium, Kochia, chamomile, matricaria, light chamomile, corn poppy, wild buckwheat, wild radish, European white mustard, wild European white mustard, drill-fruited garlic mustard, West Asian garlic mustard, chickweed and bluegrass.

[0231] The resistant or tolerant biotype is particularly selected from the group consisting of: Alopecurus macrostachya, Alopecurus macrostachya, Apiraea serrata, Oats australis, Brachiaria plantaine, Brachiaria serrata, Bromus serrata perenne, Bromus australis perenne, Bromus australis perenne, Bromus australis perenne, Digitaria pubescens, Digitaria serrata, Echinochloa crusgalli, Echinochloa baldii, Echinochloa serrata, Echinochloa serrata perenne ... Poa annua, common bluegrass, cypress, French foxtail, golden foxtail, little dogtail, whorled foxtail, foxtail, white amaranth, North American amaranth, green spike amaranth, long-horned amaranth, Powell amaranth, short-bracted amaranth, rough-fruited amaranth, western amaranth, wrinkled amaranth, ragweed, field chamomile, shepherd's purse, cornflower, quinoa, small quinoa, multi-seeded quinoa, hybrid quinoa, fragrant silk grass, small white wine grass, sowworm, cleaver, climbing vine, wheat kernel pearl, Kochia scoparia, chamomile, matricaria, light chamomile, corn poppy, wild radish, European white mustard, wild European white mustard, drill garlic mustard, West Asian garlic mustard, chickweed and curb Blue vegetables, preferably selected from the group consisting of large-eared alopecuroides, alopecuroides, Apira grass, hemostatic crabgrass, crabgrass, barnyard grass, paddy barnyard grass, lycopodium, multiflorum, perennial ryegrass, Swiss ryegrass, short-spiked mandarin grass, small-seeded mandarin grass, miraculous mandarin grass, bluegrass, common bluegrass, French foxtail, golden foxtail, small dogtail, whorled foxtail, foxtail, Powell amaranth, short-bracted amaranth, rough fruit amaranth, western amaranth, field chamomile, shepherd's purse, cornflower, quinoa, sophora japonica, kochia, chamomile, light chamomile, poppy, garlic mustard, chickweed and blue vegetables, more preferably selected from The present invention relates to a kind of grasshopper, alopecurus, apirass, barnyard grass, barnyard grass, lycopodium, multiflorum, perennial ryegrass, Swiss ryegrass, short-spiked mangrove, small-seeded mangrove, miraculous mangrove, bluegrass, Powell amaranth, short-bracted amaranth, rough-fruited amaranth, western amaranth, quinoa, chamomile, light chamomile, corn poppy and chickweed, and particularly preferably selected from alopecurus, alopecurus, apirass, barnyard grass, barnyard grass, barnyard grass, lycopodium, multiflorum, Swiss ryegrass, small-seeded mangrove and bluegrass, and particularly preferably selected from alopecurus, alopecurus, apirass, barnyard grass, barnyard grass, barnyard grass, lycopodium, multiflorum, Swiss ryegrass, small-seeded mangrove and bluegrass, and particularly preferably selected from alopecurus, multiflorum, Swiss ryegrass and small-seeded mangrove.

[0232] In another embodiment, the resistant or tolerant biotype is selected from the group consisting of Alopecurus macrostachya, Alopecurus macrostachya, Alopecurus serrata ... , bluegrass, meadow bluegrass, common bluegrass, cypress, French foxtail, golden foxtail, little dogtail, whorled foxtail, foxtail, white amaranth, North American amaranth, green spike amaranth, long-horned amaranth, Powell amaranth, short-bracted amaranth, rough amaranth, western amaranth, wrinkled amaranth, ragweed, field chamomile, shepherd's purse, cornflower, quinoa, small quinoa, multi-seed quinoa, hybrid quinoa, fragrant silk grass, small white wine grass, sowworm, pigweed, climbing vine, wheat kernel, Kochia scoparia, chamomile, matricaria, light chamomile, poppy, wild radish, European white mustard, wild European white mustard, garlic mustard, garlic mustard, chickweed and blue vegetables, preferably selected from the group consisting of big-eared foxtail, foxtail, apiaceae, hemostatic crabgrass, crabgrass, barnyard grass, paddy field barnyard grass, lycopodium, short-spiked mandarin grass, small-seeded mandarin grass, strange mandarin grass, bluegrass, common bluegrass, French foxtail, golden foxtail, small dogtail, whorled foxtail, foxtail, Powell amaranth, short-bracted amaranth, rough fruit amaranth, western amaranth, field chamomile, shepherd's purse, cornflower, quinoa, sophora japonica, kochia, chamomile, Light chamomile, corn poppy, garlic mustard, chickweed and bluegrass, more preferably selected from large-spiked alopecuroides, alopecuroides, apirassus, barnyard grass, paddy field barnyard grass, kiwifruit, short-spiked mantis grass, small-seeded mantis grass, miraculous mantis grass, bluegrass, Powell amaranth, short-bracted amaranth, rough-fruited amaranth, western amaranth, quinoa, chamomile, light chamomile, corn poppy and chickweed, especially preferably selected from large-spiked alopecuroides, alopecuroides, apirassus, barnyard grass, paddy field barnyard grass, kiwifruit, small-seeded mantis grass and bluegrass, especially large-spiked alopecuroides or small-seeded mantis grass.

[0233] In another embodiment, the resistant or tolerant biotype is selected from Alopecurus macrostachya, Oats, Echinochloa crusgalli, Lolium multiflorum, Setaria viridis, Sorghum chinense, Abutilon, Anthemis nobilis, Chenopodium album, Geranium sphaerocephalum, Fagopyrum serrata, and Chickweed.

[0234] In one embodiment, the resistant or tolerant biotype is selected from the group consisting of Alopecurus macrostachya, Alopecurus macrostachya, Apiraea serrata, Digitaria stagna, Digitaria stagna, Echinochloa crusgalli, Echinochloa chinensis, Leptochloa chinensis, Lolium multiflorum, Perennial ryegrass, Swiss ryegrass, Short-spiked Manis serrata, Small-seeded Manis serrata, Miraculous Manis serrata, Poa annua, Common Poa annua, French foxtail, Golden foxtail, Little foxtail, Whorled foxtail and Setaria, preferably selected from the group consisting of Alopecurus macrostachya, Alopecurus macrostachya, The weeds selected from the group consisting of Apira, Echinochloa crusgalli, Echinochloa chinensis, Leptochloa chinensis, Lolium multiflorum, perennial ryegrass, Swiss ryegrass, Short-spiked Manis grass, Small-seeded Manis grass, Miraculous Manis grass and Poa annua, more preferably selected from the group consisting of Alopecurus macrostachya, Alopecurus macrostachya, Apira, Echinochloa crusgalli, Echinochloa chinensis, Leptochloa chinensis, Lolium multiflorum, Swiss ryegrass, Small-seeded Manis grass and Poa annua, especially selected from the group consisting of monocotyledonous weed varieties of Alopecurus macrostachya, Lolium multiflorum, Swiss ryegrass and Small-seeded Manis grass.

[0235] In another embodiment, the resistant or tolerant biotype is a dicotyledonous weed variety selected from Powell's Amaranth, Short-bracted Amaranth, Rough-fruited Amaranth, Western Amaranth, Field Chamomile, Shepherd's Purse, Cornflower, Chenopodium album, Descurainia oleracea, Kochia scoparia, Chamomile, Light Chamomile, Poppy, Garlic Mustard, Chickweed and Bluegrass, preferably selected from Powell's Amaranth, Short-bracted Amaranth, Rough-fruited Amaranth, Western Amaranth, Chenopodium album, Chamomile, Light Chamomile, Poppy and Chickweed, more preferably Poppy.

[0236] The composition, use and method of the present invention are particularly suitable for controlling ACCase-resistant grass weeds, more specifically selected from the group consisting of large-eared foxtail, foxtail, apiaceae, wild oats, false oats, plantain brachii, pitching brachii, rye-like brome, false brome, early brome, hairy crabgrass, two-eared grass, hemostatic crabgrass, crabgrass, bald barnyard grass, barnyard grass, peacock barnyard grass, upright barnyard grass, paddy barnyard grass, water barnyard grass, cattle Tendon grass, wrinkled duckbill grass, lycopodium, millet lycopodium, gentian, tropical lycopodium, multiflora ryegrass, perennial ryegrass, Swiss ryegrass, woolly millet, foreign wild millet, short spiked lycopodium, small seeded lycopodium, miraculous lycopodium, bluegrass, meadow bluegrass, common bluegrass, cylindrical axis grass, French foxtail, golden foxtail, small foxtail, whorled foxtail and foxtail, preferably selected from large spiked alopecurus, bluegrass The present invention relates to a kind of grass selected from the group consisting of: grass, sedum, hemostatic crabgrass, crabgrass, barnyard grass, paddy barnyard grass, lycopodium, multiflorum, perennial ryegrass, Swiss ryegrass, short-spiked mandarin grass, small-seeded mandarin grass, miraculous mandarin grass, bluegrass, common bluegrass, French foxtail, golden foxtail, small foxtail, whorled foxtail and foxtail, more preferably selected from the group consisting of: big-spiked alopecurus, alopecurus, sedum ... Ryegrass, perennial ryegrass, Swiss ryegrass, short-spiked black grass, small-seeded black grass, miraculous black grass and bluegrass, particularly preferably selected from the group consisting of big-spiked black grass, black grass, apiaceae, barnyard grass, paddy field barnyard grass, lycopodiella, multiflora ryegrass, Swiss ryegrass, small-seeded black grass and bluegrass, especially ACCase-resistant grass weeds selected from the group consisting of big-spiked black grass, multiflora ryegrass, Swiss ryegrass and small-seeded black grass.

[0237] The composition, use and method of the present invention are also suitable for controlling ALS-resistant grass weeds, more specifically selected from the group consisting of large-eared foxtail, foxtail, apiaceae, wild oats, false oats, plantain brachii, pitching brachii, rye-like brome, false brome, early brome, hairy crabgrass, two-eared grass, hemostatic crabgrass, crabgrass, bald barnyard grass, barnyard grass, peacock barnyard grass, upright barnyard grass, paddy barnyard grass, water barnyard grass, and goosegrass. , wrinkled duckbill, lycopodium, millet lycopodium, gentian, tropical lycopodium, multiflora ryegrass, perennial ryegrass, Swiss ryegrass, woolly millet, foreign wild millet, short spiked mangosteen, small seeded mangosteen, strange mangosteen, bluegrass, meadow bluegrass, common bluegrass, cylindrical axis grass, French foxtail, golden foxtail, small foxtail, whorled foxtail and foxtail, preferably selected from large spiked alopecurus, alopecurus , Apira, hemostatic crabgrass, crabgrass, barnyard grass, paddy barnyard grass, Leptochloa chinensis, multiflora ryegrass, perennial ryegrass, Swiss ryegrass, short-spiked mandarin grass, small-seeded mandarin grass, miraculous mandarin grass, bluegrass, common bluegrass, French foxtail, golden foxtail, small foxtail, whorled foxtail and foxtail, more preferably selected from the group consisting of large-spiked alopecurus, alopecurus, Apira ... Flowering ryegrass, perennial ryegrass, Swiss ryegrass, short-spiked black grass, small-seeded black grass, miraculous black grass and bluegrass, particularly preferably selected from the group consisting of large-spiked black grass, black grass, apiaceae, barnyard grass, paddy field barnyard grass, Leptochloa chinensis, multi-flowered ryegrass, Swiss ryegrass, small-seeded black grass and bluegrass, especially ALS-resistant grass weeds selected from the group consisting of large-spiked black grass, multi-flowered ryegrass, Swiss ryegrass and small-seeded black grass.

[0238] The composition, use and method of the present invention are also suitable for controlling ALS-resistant dicotyledonous weeds, more specifically selected from amaranth, North American amaranth, green spike amaranth, long-horned amaranth, Powell amaranth, short-bracted retroflex amaranth, rough-fruited amaranth, western amaranth, wrinkled amaranth, ragweed, field chamomile, shepherd's purse, cornflower, quinoa, small quinoa, multi-seed quinoa, hybrid quinoa, fragrant silk grass, small white wine grass, sowworm, cleaver, creeping vine, wheat kernel pearl, Kochia scoparia, chamomile, matricaria, light chamomile, poppy, wild radish, European white mustard , wild European white mustard, garlic mustard, garlic mustard, chickweed and blue vegetable, preferably selected from Powell's amaranth, short-bracted amaranth, rough-fruited amaranth, western amaranth, field chamomile, shepherd's purse, cornflower, quinoa, sophora flavescens, kochia, chamomile, light chamomile, poppy, garlic mustard, chickweed and blue vegetable, more preferably selected from Powell's amaranth, short-bracted amaranth, rough-fruited amaranth, western amaranth, quinoa, chamomile, light chamomile, poppy and chickweed, especially ALS-resistant dicotyledonous weeds selected from poppy.

[0239] The composition, use and method of the present invention are particularly suitable for controlling PS II resistant grass weeds, more specifically selected from the group consisting of big-eared foxtail, foxtail, apiaceae, wild oats, false oats, plantain brachii, pitching brachii, rye-like brome, false brome, early brome, hairy crabgrass, two-eared grass, hemostatic crabgrass, crabgrass, bald barnyard grass, barnyard grass, peacock barnyard grass, upright barnyard grass, paddy field barnyard grass, water barnyard grass, goosegrass, wrinkled duckbill grass, Leptochloa chinensis, and similar The invention relates to the following: the gentian, the tropical gentian, the multiflora ryegrass, the perennial ryegrass, the Swiss ryegrass, the woolly millet, the foreign wild millet, the short-spiked mangrove, the small-seeded mangrove, the strange mangrove, the bluegrass, the meadow bluegrass, the common bluegrass, the cylindrical axis grass, the French foxtail, the golden foxtail, the little foxtail, the whorled foxtail and the foxtail, preferably selected from the large-spiked alopecurus, the alopecurus, the apiary grass , hemostatic crabgrass, crabgrass, barnyard grass, paddy barnyard grass, Leptochloa chinensis, multiflora ryegrass, perennial ryegrass, Swiss ryegrass, short-spiked mandarin grass, small-seeded mandarin grass, miraculous mandarin grass, bluegrass, common bluegrass, French foxtail, golden foxtail, small foxtail, whorled foxtail and foxtail, more preferably selected from the group consisting of large-spiked foxtail, foxtail, Apira, barnyard grass, paddy barnyard grass, Leptochloa chinensis , multiflora ryegrass, perennial ryegrass, Swiss ryegrass, short-spiked blackthorn grass, small-seeded blackthorn grass, miraculous blackthorn grass and bluegrass, particularly preferably selected from the group consisting of large-spiked blackthorn, blackthorn, apiaceae, barnyard grass, paddy field barnyard grass, lycopodiella, multiflora ryegrass, Swiss ryegrass, small-seeded blackthorn grass and bluegrass, especially selected from the group consisting of large-spiked blackthorn, multiflora ryegrass, Swiss ryegrass and small-seeded blackthorn grass PS II resistant grass weeds.

[0240] The composition, use and method of the present invention are also suitable for controlling PSII-resistant dicotyledonous weeds, more specifically selected from amaranth, North American amaranth, green spike amaranth, long-horned amaranth, Powell amaranth, short-bracted amaranth, rough-fruited amaranth, western amaranth, wrinkled amaranth, ragweed, field chamomile, shepherd's purse, cornflower, quinoa, small quinoa, multi-seed quinoa, hybrid quinoa, fragrant silk grass, small white wine grass, sowworm, cleaver, climbing vine, wheat kernel pearl, Kochia scoparia, chamomile, matricaria, light chamomile, poppy, wild radish, European white mustard , wild European white mustard, garlic mustard, garlic mustard, chickweed and blue vegetable, preferably selected from Powell's Amaranth, short-bracted Amaranth, rough-fruited Amaranth, western Amaranth, field chamomile, shepherd's purse, cornflower, quinoa, sophora flavescens, Kochia scoparia, chamomile, light chamomile, poppy, garlic mustard, chickweed and blue vegetable, more preferably selected from Powell's Amaranth, short-bracted Amaranth, rough-fruited Amaranth, western Amaranth, quinoa, chamomile, light chamomile, poppy and chickweed, especially PSII-resistant dicotyledonous weeds selected from poppy.

[0241] The compositions according to the invention are suitable as herbicides either directly or as appropriately formulated agrochemical compositions. The term "agrochemical composition" as used herein relates to a composition according to the invention which further comprises one or more auxiliaries customary in crop protection.

[0242] Therefore, the present invention also relates to an agrochemical composition comprising a herbicide A, a herbicide B (especially acetochlor (B.1) or pretilachlor (B.2)), optionally at least one herbicide C (as defined herein), optionally at least one safener D (as defined herein) and one or more adjuvants commonly used in crop protection in a herbicidally effective amount.

[0243] Herbicide A, herbicide B, optionally at least one herbicide C (as defined herein) and optionally at least one safener D (as defined herein) can be converted into the types commonly used in agricultural chemical compositions, such as solutions, emulsions, suspensions, dusts, powders, pastes, granules, molded products and mixtures thereof. These and other types of agricultural chemical compositions are defined in "Catalogue of pesticide formulation types and international coding system", Technical Monograph, No. 2, May 2008, 6th edition, CropLife International.

[0244] Agrochemical compositions can be prepared in a known manner, as described by Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001; or by Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005.

[0245] The invention therefore also relates to a process for preparing a composition as defined herein, more particularly an agrochemical composition, comprising mixing herbicide A, herbicide B, optionally herbicide C and / or safener D and one or more adjuvants customary in crop protection.

[0246] The term "adjuvants customary in crop protection" includes, but are not limited to, solvents, liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, wetting agents, adjuvants, solubilizers, penetration enhancers, protective colloids, adhesives, thickeners, humectants, repellents, attractants, feeding stimulants, compatibilizers, bactericides, antifreeze agents, defoamers, colorants, tackifiers and adhesives.

[0247] Suitable solvents and liquid carriers are water and organic solvents, such as medium to high boiling mineral oil fractions, for example kerosene, diesel; oils of vegetable or animal origin; aliphatic, cyclic and aromatic hydrocarbons, for example toluene, paraffin, tetralin, alkylated naphthalenes; alcohols, such as ethanol, propanol, butanol, benzyl alcohol, cyclohexanol; glycols; DMSO; ketones, for example cyclohexanone; esters, for example lactic acid esters, carbonates, fatty acid esters, γ-butyrolactone; fatty acids; phosphonates; amines; amides, for example N-methylpyrrolidone, fatty acid dimethylamides; and mixtures thereof.

[0248] Suitable solid carriers or fillers are mineral earths, for example silicates, silica gel, talc, kaolin, limestone, lime, chalk, clay, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide; polysaccharides, for example cellulose, starch; fertilizers, for example ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas; products of plant origin, for example cereal flour, bark flour, wood flour and nut shell flour, and mixtures thereof.

[0249] Suitable surfactants are surface-active compounds such as anionic, cationic, nonionic and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surfactants can be used as emulsifiers, dispersants, solubilizers, wetting agents, penetration enhancers, protective colloids or adjuvants. Examples of surfactants are listed in McCutcheon's, Volume 1: Emulsifiers & Detergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International Edition or North American Edition).

[0250] Suitable anionic surfactants are alkali metals, alkaline earth metals or ammonium salts of sulfonic acid, sulfuric acid, phosphoric acid, carboxylic acids and mixtures thereof. Examples of sulfonates are alkyl aryl sulfonates, diphenyl sulfonates, α-olefin sulfonates, lignin sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of alkoxylated arylphenols, sulfonates of condensed naphthalene, sulfonates of dodecyl- and tridecylbenzene, sulfonates of naphthalene and alkylnaphthalene, sulfosuccinates or sulfosuccinamates. Examples of sulfates are sulfates of fatty acids and oils, sulfates of ethoxylated alkylphenols, sulfates of alcohols, sulfates of ethoxylated alcohols or sulfates of fatty acid esters. Examples of phosphates are phosphate esters. Examples of carboxylates are alkyl carboxylates and carboxylated alcohols or alkylphenol ethoxylates.

[0251] Suitable nonionic surfactants are alkoxylates, N-substituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants and mixtures thereof. Examples of alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters that have been alkoxylated with 1 to 50 equivalents. Ethylene oxide and / or propylene oxide can be used for alkoxylation, preferably ethylene oxide. Examples of N-substituted fatty acid amides are fatty acid glucamides or fatty acid alkanolamides. Examples of esters are fatty acid esters, glycerides or monoglycerides. Examples of sugar-based surfactants are sorbitan, ethoxylated sorbitan, sucrose and glucose esters or alkyl polyglucosides. Examples of polymeric surfactants are homopolymers or copolymers of vinyl pyrrolidone, vinyl alcohol or vinyl acetate.

[0252] Suitable cationic surfactants are quaternary surfactants, for example quaternary ammonium compounds with 1 or 2 hydrophobic groups, or salts of long chain primary amines. Suitable amphoteric surfactants are alkyl betaines and imidazolines. Suitable block polymers are AB or ABA type block polymers comprising blocks of polyoxyethylene and polyoxypropylene, or ABC type block polymers comprising alkanol, polyoxyethylene and polyoxypropylene. Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are alkali metal salts of polyacrylic acid or polyacid comb polymers. Examples of polybases are polyvinylamine or polyvinylamine.

[0253] Suitable adjuvants are compounds which themselves have negligible or even no pesticidal activity and which improve the biological performance of compound I on the target. Examples are surfactants, mineral or vegetable oils and other adjuvants. Further examples are listed by Knowles, Adjuvants and additives, Agrow Reports DS256, T&F Informa UK, 2006, Chapter 5.

[0254] Suitable thickeners are polysaccharides (eg xanthan gum, carboxymethylcellulose), inorganic clays (organically modified or unmodified), polycarboxylates and silicates.

[0255] Suitable fungicides are bronopol and isothiazolinone derivatives such as alkylisothiazolinones and benzisothiazolinones.

[0256] Suitable antifreeze agents are ethylene glycol, propylene glycol, urea and glycerol.

[0257] Suitable defoamers are silicones, long-chain alcohols and fatty acid salts.

[0258] Suitable colorants (for example red, blue or green) are low water-soluble pigments and water-soluble dyes. Examples are inorganic colorants (for example iron oxide, titanium oxide, iron hexacyanoferrate) and organic colorants (for example alizarin colorants, azo colorants and phthalocyanine colorants).

[0259] Suitable tackifiers or adhesives are polyvinyl pyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylates, bio-waxes or synthetic waxes and cellulose ethers.

[0260] The agrochemical compositions generally comprise from 0.01 to 95% by weight, preferably from 0.1 to 90% by weight and in particular from 0.5 to 75% by weight of active substances. The active substances are employed in a purity of from 90 to 100%, preferably from 95 to 100% (according to NMR spectrum).

[0261] Various types of oils, wetting agents, adjuvants, fertilizers or micronutrients and other pesticides (e.g. herbicides, insecticides, fungicides, growth regulators, safeners) can be added to the active substances or compositions containing them as premixes or, if appropriate, added immediately before use (tank mix). These agents can be mixed with the composition of the invention in a weight ratio of 1:100-100:1, preferably 1:10-10:1.

[0262] The user usually uses the agricultural chemical composition of the present invention in a pre-dosing device, a small backpack sprayer, a spray can, a spray plane or an irrigation system. The agricultural chemical composition is usually formulated with water, a buffer and / or other adjuvants to the desired application concentration to obtain a ready-to-use spray liquid or an agricultural chemical composition of the present invention. 20-2000 liters, preferably 50-400 liters of ready-to-use spray liquid are usually applied per hectare of agricultural utilization area.

[0263] According to one embodiment, the user can mix the individual components or partially premixed components of the agrochemical composition of the present invention in a spray tank, for example an agrochemical composition comprising herbicide A, herbicide B, optionally at least one herbicide C (as defined herein) and optionally at least one safener D (as defined herein) and, if appropriate, other auxiliaries and additives.

[0264] In a further embodiment, the user can mix the components of the agrochemical composition according to the invention, for example the parts of a kit or the parts of a binary or ternary mixture, himself in a spray tank and, if appropriate, add further auxiliaries.

[0265] In another embodiment, the individual components or partially premixed components of the agrochemical composition of the present invention, for example a component comprising herbicide A, herbicide B, optionally at least one herbicide C (as defined herein) and optionally at least one safener D (as defined herein), can be applied jointly (e.g. after tank mixing) or sequentially.

[0266] Therefore, the agricultural chemical composition can be provided in the form of a single package formulation comprising herbicide A, herbicide B, optionally at least one herbicide C (as defined herein) and optionally at least one safener D (as defined herein) together with a liquid and / or solid carrier and one or more surfactants and other adjuvants common in one or more crop protections if needed. The formulation can be provided in the form of a double package formulation, wherein one package includes a formulation of herbicide A and herbicide B, and another package includes a formulation comprising at least one herbicide C and / or safener D, and wherein both formulations include at least one carrier material, one or more surfactants and other adjuvants common in one or more crop protections if needed. The formulation can also be provided in the form of a double package formulation, wherein one package includes a formulation of herbicide A and herbicide B and optionally safener D, and another package includes a formulation of at least one herbicide C, and wherein both formulations include at least one carrier material, one or more surfactants and other adjuvants common in one or more crop protections if needed. In the case of a double package formulation, the two formulations are preferably mixed before application. Preference is given to mixing being effected as a tank mix, ie the formulations are mixed immediately before or during dilution with water.

[0267] The compositions of the invention are very effective in controlling plants in non-crop areas, especially at high application rates. They act on broadleaf weeds and grass weeds in crops such as wheat, barley, rice, corn, sunflower, soybean and cotton without causing any significant damage to the crops. This effect is mainly observed at low application rates.

[0268] The composition of the present invention is mainly applied to plants by spraying. Here, for example, water can be used as a carrier by conventional spraying techniques using a spray liquid volume of about 50-1000 l / ha (e.g. 300-400 l / ha). The herbicidal composition can also be applied by a low-volume or ultra-low-volume method or in the form of microparticles.

[0269] The herbicidal compositions of the present invention can be applied before or after emergence, or together with the seeds of the crop. The compounds and compositions can also be applied by applying the seeds of the crop pretreated with the composition of the present invention. If the herbicides A and B and, if appropriate, the herbicide C are not well tolerated by certain crops, an application technique can be used in which the herbicidal compositions are sprayed with the aid of a spraying device so that they do not contact the leaves of sensitive crops as much as possible, but the active compound reaches the leaves of the undesirable plants growing below or the exposed soil surface (post-leading, final tillage procedure).

[0270] In another embodiment, the composition of the invention can be applied by treating seeds. Seed treatment essentially includes all procedures based on the composition of the invention that are well known to those skilled in the art (seed dressing, seed coating, seed dusting, seed soaking, seed coating, seed multilayer coating, seed shelling, seed dripping and seed pelleting). The herbicidal composition can be applied diluted or undiluted.

[0271] The term "seed" includes all types of seeds, such as corn, seeds, fruits, tubers, rice seedlings and similar forms. The preferred term seed here describes corn and seeds. The seeds used can be seeds of the above-mentioned useful plants, but can also be seeds of transgenic plants or plants obtained by conventional breeding methods.

[0272] Furthermore, it may be advantageous to apply the compositions according to the invention alone or in combination with other crop protection agents, for example agents for controlling pests or phytopathogenic fungi or bacteria, or growth-regulating active compounds. Also of interest is the miscibility with inorganic salt solutions for treating nutrient and trace element deficiencies. Non-phytotoxic oils and oil concentrates may also be added.

[0273] When used in plant protection, the application rates of the active substances without formulation auxiliaries, i.e. the herbicides A and B and, if appropriate, the herbicide C, are, depending on the desired effect, 0.1 to 10 000 grams per hectare (g / ha), preferably 10 to 7500 g / ha, more preferably 25 to 5000 g / ha and in particular 50 to 3000 g / ha.

[0274] In the method and use of the present invention, the application rate of herbicide A is generally 0.1-2000 g / ha, preferably 10-1000 g / ha, more preferably 10-750 g / ha, especially 10-500 g / ha. In another embodiment, the application rate of herbicide A is 50-1000 g / ha, preferably 75-750 g / ha, more preferably 100-500 g / ha.

[0275] In the method and use of the present invention, the application rate of the herbicide B (especially acetochlor (B.1) or pretilachlor (B.2)) is generally 0.1-10000 g / ha, preferably 10-5000 g / ha, more preferably 10-3000 g / ha, especially 10-2000 g / ha. In another embodiment, the application rate of the herbicide B (especially acetochlor (B.1) or pretilachlor (B.2)) is 50-5000 g / ha, preferably 100-3000 g / ha, more preferably 150-2000 g / ha.

[0276] In the methods and uses according to the invention, the application rate of the herbicide C (calculated as acid in the case of salts) is generally 0.1 to 10 000 g / ha, preferably 2 to 8000 g / ha.

[0277] In a further embodiment, the application rate of the herbicide C (calculated as acid in the case of salts) is 2 to 2400 g / ha. The abovementioned application rates are particularly suitable for controlling undesirable vegetation in sunflowers.

[0278] In a further embodiment, the application rate of the herbicide C (calculated as acid in the case of salts) is 5 to 2400 g / ha. The above application rates are particularly suitable for controlling undesirable vegetation in maize.

[0279] In a further embodiment, the application rate of the herbicide C (calculated as acid in the case of salts) is 2 to 8000 g / ha. The abovementioned application rates are particularly suitable for controlling undesirable vegetation in leguminous plants.

[0280] In the method and use according to the invention, the application rate of safener D (calculated as acid in the case of salts) is generally 1 to 2500 g / ha, preferably 2 to 2000 g / ha, more preferably 5 to 1500 g / ha.

[0281] In the treatment of plant propagation material such as seeds, for example by dusting, coating or impregnating seeds, the amount of active substance generally required is 0.1-5000 g, preferably 5-2500 g, more preferably 50-2000 g, especially 100-1500 g per 100 kg of plant propagation material (preferably seeds).

[0282] In a further embodiment of the invention, for the treatment of seed, the active substances, ie the herbicides A and B and, if appropriate, the herbicide C, are generally applied in amounts of from 0.001 to 10 kg per 100 kg of seed.

[0283] The compositions and methods of the present invention can be used to control undesirable vegetation in a variety of crops. Examples of suitable crops are as follows: onion (Allium cepa), garlic (Allium sativum), pineapple (Ananas comosus), peanut (Arachis hypogaea), asparagus (Asparagus officinalis), oats (Avena sativa), sugar beet (Betavulgaris spec.altissima), turnip (Beta vulgaris spec.rapa), rapeseed (Brassicanapus var.napus, Corolla), cabbage (Brassica napus var.napobrassica), winter rapeseed (Brassica rapa var.silvestris), kale (Brassica oleracea), black mustard (Brassicanigra), tea (Camellia sinensis), safflower (Carthamus tinctorius), pecan (Caryaillinoinensis), lemon (Citrus limon), sweet orange (Citrus sinensis), small fruit coffee (Coffea arabica) (Coffea canephora) canephora, coffee (Coffea liberica), cucumber (Cucumis isatis), bermudagrass (Cynodon dactylon), carrot (Daucus carotasubspec. sativa), oil palm (Elaeis guineensis), European strawberry (Fragaria vesca), soybean (Glycine max), upland cotton (Gossypium hirsutum) (tree cotton (Gossypium arboreum), grass cotton (Gossypium herbaceum), Gossypium vitifolium), sunflower (Helianthus annuus), Brazilian rubber (Hevea brasiliensis), barley (Hordeum vulgare), hops (Humulus lupulus), sweet potato (Ipomoea batatas), walnut (Juglans regia), lentil (Lens culinaris), flax (Linum usitatissimum), tomato (Lycopersicon lycopersicum), apple (Malus spec.), cassava (Manihot esculenta), alfalfa (Medicago sativa), banana (Musa spec.), tobacco (Nicotiana tabacum) (N. rustica), olive (Olea europaea), rice (Oryza sativa), golden bean (Phaseolus lunatus), snap bean (Phaseolus vulgaris, green bean, dry bean), European spruce (Picea abies), pine (Pinus spec.), pistachio (Pistacia vera), pea (Pisum sativum), European sweet cherry (Prunus avium), peach (Prunus persica), pear (Pyrus communis), apricot (Prunus armeniaca), European sour cherry (Prunus cerasus), almond (Prunus dulcis) and European plum (Prunus domestica), red currant (Ribes sylvestre), castor (Ricinus communis), sugarcane (Saccharum officinarum), rye (Secale cereale), mustard (Sinapis alba), potato (Solanum tuberosum), Sorghum bicolor (Sorghum vulgare), cocoa (Theobroma cacao), red clover (Trifoliumpratense), common wheat (Triticum aestivum), triticale (Triticale), durum wheat (Triticumdurum), bean (Vicia faba), grape (Vitis vinifera), and maize (Zea mays, sweet corn, corn).

[0284] Preferred crops are onion (Allium cepa), garlic (Allium sativum), peanut (Arachis hypogaea), sugar beet (Beta vulgaris spec. altissima), rapeseed (Brassica napus var. napus), kale (Brassica oleracea), bermudagrass (Cynodon dactylon), carrot (Daucus carota subspec. sativa), soybean (Glycine max), upland cotton (Gossypium hirsutum) (Gossypium arboreum, Gossypium herbaceum, Gossypium vitifolium), sunflower (Helianthus annuus), barley (Hordeum vulgare), lentil (Lens culinaris), flax (Linumus itatissimum), tomato (Lycopersicon lycopersicum), apple (Malus spec.), alfalfa (Medicago sativa), rice (Oryza sativa), sativa), Phaseolus lunatus, Phaseolus vulgaris, Pisum sativum, Saccharum officinarum, Secale cereale, Solanum tuberosum, Sorghum bicolor (Sorghum vulgare), Triticale, Triticum aestivum, Triticum durum, Vicia faba, Vitis vinifera, and Zea mays.

[0285] In another embodiment, the crop is selected from wheat, barley, rye, oats, triticale, corn, sunflower, rice, legumes (such as soybeans, peas, beans, green beans, adzuki beans, peanuts, chickpeas, lentils, alfalfa, lupines, etc.), oilseed rape, corolla, cotton, potatoes, sugar beets, sugar cane, bulb vegetables (such as onions, garlic, shallots, etc.), carrots, tomatoes, brassica vegetables (such as cabbage, cauliflower, broccoli, Brussels sprouts, kale, kohlrabi, etc.), leafy vegetables (such as salad, lettuce, endive, red lettuce, arugula, magnolia, etc.), bell peppers, cucumbers, eggplants, pumpkins, melons, , peppers, zucchini, celery, parsnips, radishes, horseradish, leeks, asparagus, celery, artichokes, tobacco, hops, citrus fruits (such as oranges, lemons, limon, pomelo, grapefruit, tangerines, nectarines, etc.), stone fruits (such as apricots, cherries, peaches, plums, etc.), pomelo (such as apples, pears, mandarin oranges, etc.), nuts (such as almonds, walnuts, etc.), grapes, oil palm, olives, and lawn grasses (such as American paspalum, bentgrass, bermudagrass, bluegrass, buffalo grass, carpet grass, centipede grass, fescue, pennisetum, ryegrass, blunt-leaved grass (St. Augustinegrass), zoysia grass).

[0286] In a preferred embodiment, the crop is selected from the group consisting of wheat, barley, rye, triticale, oats, corn, sunflower, rice, soybean, pea, bean, peanut, oilseed rape, corolla, cotton, potato, sugar beet, sugar cane, turf grass and vegetables.

[0287] In an even more preferred embodiment, the crop plant is selected from the group consisting of wheat, barley, rye, triticale, oats, corn, sunflower, rice, soybean, pea, bean, French bean, peanut, oilseed rape, corolla, cotton, potato, sugar beet, sugar cane, grass and vegetables.

[0288] In a particularly preferred embodiment, undesirable plants are controlled in cereals, rice, sunflower, corn and leguminous plants. The cereals are especially selected from the group consisting of wheat, barley, rye, oats and triticale.

[0289] In a particularly preferred embodiment, undesirable vegetation is controlled in rice.

[0290] In an especially preferred embodiment, undesirable vegetation is controlled in corn.

[0291] In a particularly preferred embodiment, undesirable vegetation is controlled in sunflowers.

[0292] In a particularly preferred embodiment, undesirable vegetation is controlled in leguminous plants.

[0293] The present composition, uses and methods can also be used in genetically modified plants. The term "genetically modified plant" is understood to be a plant whose genetic material is modified by using recombinant DNA technology to include an insertion sequence of non-natural DNA for the genome of the plant variety or to present a deletion of natural DNA for the genome of the variety, wherein the modification is not easily obtained by hybridization, mutation or natural recombination alone. Special genetically modified plants are usually plants whose genetic modifications are obtained by natural breeding or propagation methods from the hereditary plants whose genome is a genome directly processed by using recombinant DNA technology. One or more genes are usually integrated into the genetic material of the genetically modified plant to improve certain properties of the plant. This type of genetic modification also includes, but is not limited to, targeted post-translational modifications of proteins, oligopeptides or polypeptides, for example, by introducing amino acid mutations that allow, reduce or promote glycosylation or polymer addition such as isoprenylation, acetylation or farnesylation or PEG structure parts.

[0294] Plants modified by breeding, mutagenesis or genetic engineering are, for example, made tolerant by conventional breeding or genetic engineering methods to the application of particular classes of herbicides, such as auxin herbicides, such as dicamba or 2,4-D; bleach herbicides, such as 4-hydroxyphenylpyruvate dioxygenase (HPPD) inhibitors or phytoene desaturase (PDS) inhibitors; acetolactate synthase (ALS) inhibitors, such as sulfonylureas or imidazolinones; enolpyruvylshikimate 3-phosphate synthase (EPSPS) inhibitors, such as glycyrrhizin; phosphine; glutamine synthetase (GS) inhibitors, such as glufosinate; protoporphyrinogen-IX oxidase inhibitors; lipid biosynthesis inhibitors such as acetyl CoA carboxylase (ACCase) inhibitors; or oxynil (i.e., bromoxynil or ioxynil) herbicides; in addition, plants have been genetically modified multiple times to tolerate multiple classes of herbicides, such as tolerance to both glyphosate and glufosinate or tolerance to both glyphosate and another class of herbicides selected from ALS inhibitors, HPPD inhibitors, auxin inhibitors or ACCase inhibitors. These herbicide tolerance technologies are described, for example, in Pest Management Science 61, 2005, 246; 61, 2005, 258; 61, 2005, 277; 61, 2005, 269; 61, 2005, 286; 64, 2008, 326; 64, 2008, 332; Weed Science 57, 2009, 108; Australian Journal of Agricultural Research 58, 2007, 708; Science 316, 2007, 1185; and in the literature cited therein. Several cultivated plants have been made tolerant to herbicides by genetic mutation and conventional breeding methods, for example, tolerant to imidazolinones such as imazamox. Summer rapeseed (Canola, BASF SE, Germany) or tolerant to sulfonylureas, such as bensulfuron Sunflower (DuPont, USA). Genetic engineering methods have been used to confer tolerance to cultivated plants such as soybean, cotton, corn, sugar beet and rapeseed to herbicides such as glyphosate, imidazolinones and glufosinate, some of which are under development or available under the brand or trade name (glyphosate tolerant, Monsanto, USA), (Imidazolinone resistant, BASF SE, Germany) and (Glufosinate-tolerant, Bayer CropScience, Germany) is commercially available.

[0295] Furthermore, plants are also included which are capable of synthesizing one or more insecticidal proteins, in particular those known from Bacillus bacteria, in particular Bacillus thuringiensis, by the use of recombinant DNA technology, such as delta-endotoxins, for example CryIA(b), CryIA(c), CryIF, CryIF(a2), CryIIA(b), CryIIIA, CryIIIB(b1) or Cry9c; asexual insecticidal proteins (VIP), for example VIP1, VIP2, VIP3 or VIP3A; insecticidal proteins of nematode-colonizing bacteria, for example Photorhabdus or Xenorhabdus; toxins produced by animals, such as scorpion toxins, spider toxins, wasp toxins or other insect-specific neurotoxins; toxins produced by fungi, for example Streptomyces; cetes) toxins; plant lectins, such as pea or barley lectins; lectins; protease inhibitors, such as trypsin inhibitors, serine protease inhibitors, patatin, cysteine ​​protease inhibitors or papain inhibitors; ribosome inactivating proteins (RIPs), such as ricin, maize-RIP, abrin, luffa seed protein, saporin or bryodin; steroid metabolizing enzymes, such as 3-hydroxysteroid oxidase, ecdysteroid-IDP glycosyltransferase, cholesterol oxidase, ecdysone inhibitor or HMG-CoA reductase; ion channel blockers, such as sodium channel or calcium channel blockers; juvenile hormone esterase; helicokinin receptor; Synthetase, bibenzyl synthetase, chitinase or glucanase. In the context of the present invention, these insecticidal proteins or toxins are also specifically understood to include pretoxins, hybrid proteins, truncated or otherwise modified proteins. The feature of hybrid proteins is the novel combination of protein domains (for example, referring to WO 02 / 015701). Other examples of genetically modified plants of this type of toxin or capable of synthesizing these toxins are disclosed in EP-A 374753, WO 93 / 007278, WO 95 / 34656, EP-A 427 529, EP-A 451 878, WO03 / 18810 and WO 03 / 52073. The method for producing these genetically modified plants is known to those skilled in the art and is for example disclosed in the above-mentioned publications. These insecticidal proteins contained in the genetically modified plants confer tolerance to all taxonomic arthropod pests, in particular beetles (Coleoptera), dipterans (Diptera) and moths (Lepidoptera) as well as nematodes (Nematoda). Genetically modified plants capable of synthesizing one or more insecticidal proteins are described, for example, in the above-mentioned publications, some of which are commercially available, for example (corn varieties that produce the toxin Cry1Ab), Plus (corn varieties producing toxins Cry1Ab and Cry3Bb1), (corn varieties that produce the toxin Cry9c), RW (a corn variety that produces the toxins Cry34Ab1, Cry35Ab1, and the enzyme phosphinothricin-N-acetyltransferase [PAT]); 33B (cotton variety producing the toxin Cry1Ac), I (cotton variety producing the toxin Cry1Ac), II (cotton varieties producing toxins Cry1Ac and Cry2Ab2); (cotton varieties that produce VIP toxins); (potato varieties that produce the toxin Cry3A); Bt11 (e.g. CB) and Bt176 of Syngenta Seeds SAS, France (a corn variety producing toxin Cry1Ab and PAT enzyme), MIR604 of Syngenta Seeds SAS, France (a corn variety producing a modified version of toxin Cry3A, see WO03 / 018810), MON 863 of Monsanto Europe SA, Belgium (a corn variety producing toxin Cry3Bb1), IPC 531 of Monsanto Europe SA, Belgium (a cotton variety producing a modified version of toxin Cry1Ac) and 1507 of Pioneer Overseas Corporation, Belgium (a corn variety producing toxin Cry1F and PAT enzyme).

[0296] In addition, plants are also included that are able to synthesize one or more proteins that enhance resistance or tolerance to bacterial, viral or fungal pathogens by using recombinant DNA technology. Examples of such proteins are so-called "pathogenesis-related proteins" (PR proteins, see, for example, EP-A 392 225), plant disease resistance genes (e.g. potato varieties expressing resistance genes that act against Phytophthora infestans from the Mexican wild potato Solanum bulbocastanum) or T4 lysozyme (e.g. potato varieties that are able to synthesize these proteins that have enhanced resistance to bacteria such as Erwinia amylvora). Methods for producing these genetically modified plants are known to those skilled in the art and are disclosed, for example, in the above-mentioned publications.

[0297] Also included are plants that are capable of synthesizing one or more proteins through the use of recombinant DNA technology to increase yield (e.g., biomass production, grain yield, starch content, oil content, or protein content), tolerance to drought, salt, or other growth-limiting environmental factors, or tolerance to pests and fungal, bacterial, and viral pathogens.

[0298] In addition, plants are also included that contain altered amounts of ingredients or new ingredients, particularly to improve human or animal nutrition, by using recombinant DNA technology, such as oil crops that produce health-promoting long-chain ω-3 fatty acids or unsaturated ω-9 fatty acids (e.g. Rapeseed (DOW Agro Sciences, Canada).

[0299] Furthermore, plants are also included which contain altered or novel components by the use of recombinant DNA technology, in particular to improve raw material production, such as potatoes which produce increased amounts of amylopectin (e.g. potatoes, BASF SE, Germany).

[0300] The following examples illustrate the invention. Example

[0301] The effect of the herbicidal combination of the herbicides A and B according to the invention on the growth of undesirable plants compared with the individual herbicidally active compounds was demonstrated by the following greenhouse test:

[0302] Test plants were sown individually for each variety in plastic containers in sandy loam containing 5% organic matter.

[0303] For the pre-emergence treatment, the active compound suspended or emulsified in water is applied directly after sowing with the aid of a fine distribution nozzle. The containers are gently irrigated to promote germination and growth and then covered with a transparent plastic cover until the plants have taken root. This covering leads to uniform germination of the test plants, unless this is adversely affected by the active compound.

[0304] Depending on the individual requirements of the plants they are cultivated at 10-25° C. and 20-35° C. The plants are irrigated according to their necessity.

[0305] The racemic mixture (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane was used as herbicide A and formulated into emulsifiable concentrates having an active ingredient concentration of 50 g / l, 100 g / l or 750 g / l.

[0306] Acetochlor (herbicide B.1) was used in an encapsulated (CS) formulation with an active ingredient concentration of 400 g / l + 67 g / l of chlorfenapyr as safener.

[0307] Pretilachlor (herbicide B.2) was used as an emulsifiable concentrate (EC) formulation with an active ingredient concentration of 120 g / l.

[0308] In the following tests, the herbicidal activity of the individual herbicidal compositions (applied individually and in mixtures) was evaluated 20 days after the treatment (DAT).

[0309] The damage to undesirable weeds caused by the chemical composition compared to untreated control plants is assessed using a score of 0-100%, where 0 means no damage and 100 means complete damage of the plant.

[0310] The plants used in the greenhouse experiments were of the following species:

[0311]

[0312]

[0313] Colby's equation was used to determine whether the combination of herbicide A and herbicide B showed a synergistic effect (see SR Colby, "Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 1967, 15, pp. 20-22).

[0314] E=X+Y-(X·Y / 100)

[0315] Where X = the percentage effect of using herbicide A at application rate a;

[0316] Y = the percentage effect of herbicide B at application rate b;

[0317] E = expected effect of herbicide A + herbicide B at application rate a + b (%)

[0318] If the activities of the individual compounds are additive, the E value corresponds to the expected effect (damage or injury to the plants). If the observed effect is higher than the E value calculated according to Colby's equation, a synergistic effect is present.

[0319] Tables 1 and 2 below relate to the herbicidal activity of the individual actives and combinations in greenhouse tests applied at different application rates and ratios in pre-emergence applications 20 days after treatment (DAT).

[0320] Table 1: Pre-emergence application of herbicide A and herbicide B.1 (acetochlor)

[0321]

[0322]

[0323] Table 2: Pre-emergence application of herbicide A and herbicide B.2 (pretilachlor)

[0324]

[0325]

[0326] As can be seen from the data in Tables 1 and 2, the combination of Herbicide A and Herbicide B has an unexpected synergistic effect, as the herbicidal activity against various weed species in the pre-emergence treatment is significantly higher than would be expected based on the values ​​for each compound alone.

Claims

1. Use of a herbicidal composition for controlling undesirable plants, wherein the herbicidal composition comprises a herbicidally effective amount of (a) (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane, i.e., herbicide A, and (b) at least one chloroacetamide selected from acetochlor and pretilachlor, i.e., herbicide B, wherein the weight ratio of herbicide A to acetochlor is 1:0.8-1:20, or the weight ratio of herbicide A to pretilachlor is 1:1, And wherein the undesirable plants are selected from the genera Alopecurus, Echinochloa, Lolium, Setaria, Sorghum, Chenopodium and Polygonum.

2. A method for controlling undesirable plants, comprising applying the following herbicidal composition to the plants or their loci to prevent the emergence or growth of undesirable plants, wherein the herbicidal composition comprises a herbicidally effective amount of (a) (±)-2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane, i.e., herbicide A and (b) at least one chloroacetamide selected from acetochlor and pretilachlor, i.e., herbicide B, wherein the weight ratio of herbicide A to acetochlor is 1:0.8-1:20, or the weight ratio of herbicide A to pretilachlor is 1:1, And wherein the undesirable plants are selected from the genera Alopecurus, Echinochloa, Lolium, Setaria, Sorghum, Chenopodium and Polygonum.

3. A method according to claim 2, comprising applying the herbicidal composition to soil or water to prevent the emergence or growth of undesirable plants.

4. The use according to claim 1, or the method according to claim 2, wherein the herbicide A and the herbicide B are each present in an amount sufficient to provide a synergistic herbicidal effect.

5. The use according to claim 1, or the method according to claim 2, wherein the composition further comprises at least one herbicide C selected from the group consisting of: beniflox, amitriptyline, sulfamethoxam, aminopyralid, cypermethrin, chlorpyrifos, atrazine, tetrazosulfuron, flubutyric acid, fluazifop, benzylsulfuron, dithiocarb, thiamethoxam, fluazifop, chlorpyrifos, bispyribac, bromoxynil, long-term grass, fluazifop, chlorpyrifos, green yellow chlorpyrifos, chlortoluron, clethodim, clodinafop-butyl, isoclomazone, diclopicolinic acid, cypermethrin, cyclopyrimorate, cyhalofop-butyl, 2,4-D, dazomethane, 2,4-D butyric acid, isobenzothiocarb, dicamba, 2,4-D propionic acid, high 2,4-D propionic acid, chlorpyrifos, pyrifos, diflupyr, chlorpyrifos, dimethoate, dimethoate, dimethoate-prepared, diquat cation, dithiocarb, diuron, ethosulfuron, ethosulfuron, Fenpyraclostrobin, high Azofenac, phenoxyquinoxaline, fluazifop-butyl, bispyribac, fluazifop-butyl, flufenacet-butyl, fluazifop-butyl, fluphenazine Azofenac, fluazifop, fludioxon, flurochloridone, fluroxypyr, flurazepam, foramsulfuron, glufosinate, glyphosate, fluclopyralid, pyraclostrobin, pyraclostrobin, indazine fluazifop, imazamox, chloranil, pyrimidine, iodine, iodinesulfuron, iodinesulfuron, iodoxycycline, isoproturon, isoxazolidinone, isoproturon Fluorothioate, cypermethrin, linuron, 2-methyl-4-chloro-4-chloro-2-methyl-4-chloro-2-methyl-4-chloro-propionic acid, 2-methyl-4-chloro-propionic acid, high 2-methyl-4-chloro-propionic acid, mesotrione, mesotrione, metamifungus, metazachlor, methiocarb, sulfamethoxazole, sulfamethoxazole, isopropyl metolachlor, S-isopropyl metolachlor, sulfamethoxazole, metribuzin, metsulfuron, chloranil, monosodium methyl arsenate, naphthamide, naphthamide, nicotinamide, pyrimidinesulfuron, yellow grass, propargyl Azoles, oxadiazine, cyprosulfuron, oxyfluorfen, pendimethalin, penfosulam, pethodiamide, pyralid, fluazifop, pinoxaflor, aminofluanid, cyproconazole, promethazine, chlorfenapyr, propoxysulfone, chlorfenapyr, natoxydim, benzylcarb, fluprosulfuron, fluazifop-butyl, dazuridine, pyroxasulfone, sulfasulfuron, quinclorac, quinclorac, quinthiocarb, quinazolin, quinazolin, quinazolin, quizalofop-p-ethyl, quizalofop-p-ethyl, pyrasulfuron, benzylsulfuron, sethoxydim, cyproconazole, simazine, sulfosulfuron, sulfamethoxazole, cyproconazole, terbuthylazine, thiocarb, thiosulfuron, tolpyralate, pyrazoline, oxime, wild wheat Fear, bensulfuron-methyl, bensulfuron-methyl, oxazolidinone, trifloxysulfuron, trifludimoxazin, fluralin, flusulfuron-methyl, trifloxysulfuron, 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)-5-fluoropyridine-2-carboxylic acid, 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)-5-fluoropyridine-2-carboxylic acid benzyl ester, cyprosulfuron, bicyclosulfuron, halosuflamuron, propanil, butachlor, disulfuron, piperafophos, pyrazosulfuron, cypermethrin, fluazifop-methyl, imazapic, imazapic and their agriculturally acceptable salts, esters or amides.

6. The use according to claim 5, or the method according to claim 5, wherein the herbicide A and the herbicide B are each present in an amount sufficient to provide a synergistic herbicidal effect.

7. The use according to claim 1, or the method according to claim 2, wherein the composition further comprises at least one safener D selected from the group consisting of chlorpyrifos, quinoxyacetic acid, chlorpyrifos nitrile, cyproconazole, chlorpyrifos amine, bicyclazole, chlorpyrifos thiocarb ... Azoles, pyrrole dicarboxylic acid, mephenate, naphthylacetic acid, naphthalene dicarboxylic anhydride, oxalonitrile, 4-dichloroacetyl-1-oxa-4-azaspiro[4.5]decane, 2,2,5-trimethyl-3-dichloroacetyl-1,3- Oxazolidine, N-(2-methoxybenzoyl)-4-[(methylaminocarbonyl)amino]benzenesulfonamide and agriculturally acceptable salts, esters or amides thereof.

8. The use according to claim 1, or the method according to claim 2, wherein the composition further comprises one or more adjuvants customary in crop protection.

9. The method according to claim 1 , wherein the undesirable plants are controlled in a crop selected from the group consisting of wheat, barley, rye, triticale, oats, corn, sunflower, rice, soybean, pea, broad bean, French bean, peanut, oilseed rape, corolla, cotton, potato, sugar beet, sugar cane and turf grass.

10. The use according to claim 1 or the method according to claim 2, wherein the undesirable plants are controlled in vegetables.

11. The use according to claim 1 or the method according to claim 2, wherein the undesirable plants are herbicide-resistant or -tolerant weed species.

12. The use according to claim 4 or the method according to claim 4, wherein the undesirable plants are herbicide-resistant or -tolerant weed species.

13. The use according to claim 5 or the method according to claim 5, wherein the undesirable plants are herbicide-resistant or -tolerant weed species.

14. The use according to claim 6 or the method according to claim 6, wherein the undesirable plants are herbicide-resistant or -tolerant weed species.

15. The use according to claim 1 or the method according to claim 2, wherein the herbicide A and the herbicide B are applied before or during the emergence of the undesired vegetation.

16. The use according to claim 4 or the method according to claim 4, wherein the herbicide A and the herbicide B are applied before or during the emergence of the unwanted vegetation.

17. The use according to claim 5 or the method according to claim 5, wherein the herbicide A and the herbicide B are applied before or during the emergence of the undesired vegetation.

18. The use according to claim 6 or the method according to claim 6, wherein the herbicide A and the herbicide B are applied before or during the emergence of the undesired vegetation.

19. The use according to claim 11 or the method according to claim 11, wherein the herbicide A and the herbicide B are applied before or during the emergence of the undesired vegetation.

20. The use according to claim 1 or the method according to claim 2, wherein the herbicide A is applied in an amount of 10 to 1000 g / ha and the herbicide B is applied in an amount of 10 to 5000 g / ha.

21. The use according to claim 4 or the method according to claim 4, wherein the herbicide A is applied in an amount of 10 to 1000 g / ha and the herbicide B is applied in an amount of 10 to 5000 g / ha.

22. The use according to claim 5 or the method according to claim 5, wherein the herbicide A is applied in an amount of 10-1000 g / ha and the herbicide B is applied in an amount of 10-5000 g / ha.

23. The use according to claim 6 or the method according to claim 6, wherein the herbicide A is applied in an amount of 10-1000 g / ha and the herbicide B is applied in an amount of 10-5000 g / ha.

24. The use according to claim 11 or the method according to claim 11, wherein the herbicide A is applied in an amount of 10-1000 g / ha and the herbicide B is applied in an amount of 10-5000 g / ha.

25. The use according to claim 15 or the method according to claim 15, wherein the herbicide A is applied in an amount of 10-1000 g / ha and the herbicide B is applied in an amount of 10-5000 g / ha.

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