Method for industrial waste salt treatment and energy storage

By using a combination of ceramic electric heating rods and a moving platform inside the treatment tank, along with heat exchange water pipes for thermal energy storage, the problems of difficult industrial waste salt treatment and unstable clean energy utilization have been solved, achieving efficient waste salt treatment and energy utilization, and reducing the risk of environmental pollution.

CN115026106BActive Publication Date: 2025-10-21BEIJING TALENTMAN ENVIRONMENT SERVICES LTD
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Patent Information

Application Number
CN202210643701.1
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2022-06-09
Publication Date
2025-10-21
Estimated Expiration
2042-06-09

AI Technical Summary

Technical Problem

Existing technologies are difficult to effectively treat industrial waste salt, especially due to its complex composition and the presence of organic pollutants, which makes treatment difficult. Furthermore, unstable clean energy sources such as wind and solar power are difficult to utilize, resulting in low treatment efficiency and environmental pollution risks.

Method used

The industrial waste salt in the treatment tank is heated by ceramic electric heating rods, and the heating rods are moved horizontally and vertically by a mobile platform. Combined with heat exchange water pipes, heat energy is stored and utilized to achieve high-temperature treatment and energy storage of waste salt. The heating is carried out using unstable clean energy, and the waste gas is treated by desulfurization and denitrification spray tower and activated carbon adsorption device.

Benefits of technology

It has achieved efficient treatment of industrial waste salt and effective utilization of energy, completely removed organic pollutants, changed the energy structure, improved treatment efficiency and reduced environmental pollution risks.

✦ Generated by Eureka AI based on patent content.

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Abstract

The application discloses a kind of industrial waste salt processing and energy storage method, comprising: industrial waste salt is ground, uniformly arranged in processing tank;Step two: using discontinuous electric energy, industrial waste salt is locally heated to 1000 DEG C or more;All organic pollutants in waste salt are completely decomposed under anoxic condition, and the generated organic waste gas is discharged to atmosphere after treatment;Molten state industrial waste salt stores heat in processing tank for a long time, and the water in heating evaporation heat exchange pipe is evaporated by heating to drive steam turbine unit to generate electricity and output, or directly output high-temperature steam;Inorganic salt in processing tank is cooled and dissolved in water, and monovalent salt solution is obtained after filtration by nanofiltration membrane for industrial production.The application realizes the unstable electric energy generated by wind energy and solar energy to be directly converted into heat energy in the form of discontinuity or continuity, and stored in industrial waste salt.Industrial waste salt is kept in superhigh temperature state for a long time, organic pollutants are completely removed, and industrial waste salt is effectively treated and purified.
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Description

Technical Field

[0001] The invention relates to an industrial waste salt treatment method, in particular to an industrial waste salt treatment and energy storage method. Background Art

[0002] Industries such as petrochemicals, coal chemicals, pesticides, pharmaceuticals, and fine chemicals continuously generate large quantities of waste salts during their production processes. These waste salts primarily contain a variety of salts, including inorganic salts such as sodium, calcium, magnesium, iron, copper, aluminum, lead, zinc, chromium, cadmium, manganese, arsenic, nickel, silicon, and phosphorus. Furthermore, these industrial waste salts often contain organic pollutants, including complex components such as organic solvents, mineral oils, polymers, aromatic hydrocarbons, halogenated organic compounds, esters, ethers, alcohols, and aldehydes. Due to the highly complex composition of industrial waste salts, the presence of toxic organic compounds, and their high hardness and viscosity, their treatment is difficult, making them difficult to reuse as a resource. Consequently, they are often left in large quantities, posing a potential risk of soil and water pollution.

[0003] Advanced processing, recycling, purification, and reuse of industrial waste salt not only mitigates environmental hazards but also maximizes its economic value. Currently, only high-temperature processes are feasible for advanced processing and utilization of waste salt. Rotary kiln calcination, typically using coal or natural gas as the heat source, is commonly employed. High-temperature heating using plasma torches and arcs is also an option, but these methods consume significant amounts of electricity. Furthermore, clean, renewable energy sources such as wind and solar power, which are often unstable and intermittent, often prevent these facilities from utilizing them. Summary of the Invention

[0004] In view of the above-mentioned problems existing in the prior art, the purpose of the present invention is to provide a method for treating and storing industrial waste salt, which has good treatment effect, can use unstable clean energy and store energy, and can increase treatment efficiency.

[0005] In order to achieve the above-mentioned object, the present invention provides the following technical solution: a method for treating and storing industrial waste salt, wherein the device used in the method comprises:

[0006] The treatment tank is constructed as a cylindrical shell with an inner cavity. The top of the treatment tank is matched with a sealing cover. A gas outlet pipe is fixedly connected to one side of the upper end of the treatment tank. The outer fixed sleeve of the treatment tank is provided with an insulation sleeve. The surface of the insulation sleeve close to the treatment tank is provided with a serpentine groove. A heat exchange water pipe is fixedly arranged in the groove. The water inlet and outlet of the heat exchange water pipe both penetrate the insulation sleeve and extend to the outside.

[0007] A movable platform is horizontally arranged in the processing tank, and a plurality of heating rods are fixedly and evenly arranged vertically on the lower end surface of the movable platform; the movable platform is connected to the sealing cover through a movable assembly, and the sealing cover is provided with a driving assembly for driving the movable assembly to move;

[0008] The moving assembly includes a moving disk arranged in the sealing cover, the moving platform is connected to the moving disk, an annular limiting groove is provided on the inner wall of the sealing cover, the cross section of the annular limiting groove is set to a side T-shape, four sliding short columns are evenly arranged in the annular limiting groove, four elastic limiting rods are arranged around the moving disk, the four elastic limiting rods are all connected to the moving disk, and one end of the four elastic limiting rods away from the moving disk extends into the annular limiting groove and is fixedly connected to the four sliding short columns respectively;

[0009] The method for treating and storing industrial waste salt using the device includes the following steps:

[0010] Step 1: Use a multi-axis spiral crusher to crush the industrial waste salt and evenly arrange it in the processing tank. Then place the heating rod into the processing tank and insert it into the crushed industrial waste salt material;

[0011] Step 2: Intermittent electrical energy from wind or solar power plants is converted into thermal energy through a heating rod and passed into the treatment tank, locally heating the industrial waste salt to above 1000°C. The heating rod is then moved to another location in the treatment tank and continued to heat until all the industrial waste salt in the treatment tank is melted.

[0012] Step 3: After heating to above 1000°C, all organic pollutants in the waste salt are completely decomposed under oxygen-deficient conditions, and the waste gas generated is discharged from the gas outlet pipe;

[0013] Step 4: The exhaust gas is treated in a desulfurization and denitrification spray tower and an activated carbon adsorption device before being discharged into the atmosphere;

[0014] Step 5: The molten industrial waste salt stores heat in the treatment tank for a long time. During peak electricity demand periods, it heats and evaporates the water in the heat exchange water pipe to drive the steam turbine to generate electricity, or during peak thermal demand periods, it heats and evaporates the water in the heat exchange water pipe to output high-temperature steam.

[0015] Step 6: After the treated inorganic salts in the treatment tank are cooled, they are dissolved in water through a dissolution tank. After being filtered through a nanofiltration membrane, the monovalent salts and the polyvalent salts are separated to obtain a monovalent salt solution for industrial production.

[0016] Preferably, the driving assembly includes a frame-shaped member arranged on the upper side of the sealing cover, and a strip frame 1 and a strip frame 2 are horizontally arranged in the frame-shaped member, both ends of the strip frame 1 and the strip frame 2 are slidably connected to the frame-shaped member, the strip frame 1 and the strip frame 2 are arranged vertically and closely to each other, and a sliding block slides in the strip frame 1 and the strip frame 2 at the same time, and a fixed rod is vertically arranged on the upper side of the sealing cover, the upper end of the fixed rod is fixedly connected to the sliding block, and the lower end of the fixed rod is fixedly connected to an external disk connecting member, and the external disk connecting member is fixed to the upper surface of the movable disk, and two control components for driving the strip frame 1 and the strip frame 2 to move are provided on the frame-shaped member.

[0017] Preferably, adjacent sliding short columns are limited by a clamping spring arranged in an annular limiting groove.

[0018] Preferably, the control component includes two screws arranged in a frame-shaped member, the two screws are arranged perpendicular to each other, and a connecting block is provided on the threaded sleeve of the screw. The two connecting blocks are respectively fixedly connected to the strip frame one and the strip frame two. Both ends of the screw are rotatably connected to the frame-shaped member, and two servo motors are fixedly provided on the frame-shaped member to drive the two screws to rotate respectively.

[0019] Preferably, the mobile platform is fixedly connected to the mobile disk via two symmetrically arranged multi-stage telescopic rods. Preferably, a cleaning disk is provided on the underside of the mobile platform, the cleaning disk slidingly sleeved on a plurality of heating rods, and a plurality of telescopic rods are vertically and evenly arranged on the upper side of the mobile platform, each of the telescopic rods being fixedly sleeved with a limit spring to restrict its extension and contraction. The upper ends of the telescopic rods are fixedly connected to the mobile disk, and the lower ends of the telescopic rods are fixedly connected to the cleaning disk. The minimum length of the multi-stage telescopic rods is much smaller than the minimum length of the telescopic rods.

[0020] Preferably, the heating rod is a ceramic electric heating rod.

[0021] Preferably, the cylindrical shell is made of high-alumina refractory bricks, and the insulation sleeve is made of rock wool.

[0022] Preferably, the heat exchange water pipe is made of a high-temperature and high-pressure resistant metal pipe.

[0023] Preferably, a plurality of temperature and pressure sensors are evenly and fixedly arranged inside the processing tank, and a controller electrically connected to the plurality of temperature and pressure sensors is fixedly arranged outside the processing tank.

[0024] Compared with the prior art, the method for treating and storing industrial waste salt provided by the present invention heats the ceramic electric heating rod with unstable clean energy, and at the same time seals and insulates the treatment tank, which can keep the industrial waste salt in an ultra-high temperature state for a long time, effectively treating and purifying the waste salt, and the excess heat energy can be reused, thus achieving a change in the energy structure. The present invention realizes the direct conversion of unstable electric energy generated by wind and solar energy into heat energy in a discontinuous or continuous form, and stores it in industrial waste salt. At the same time, the industrial waste salt can be kept in an ultra-high temperature state for a long time, the organic pollutants therein can be completely removed, and the industrial waste salt is effectively treated and purified. While treating industrial waste salt, a change in the energy structure is achieved, which is of great significance.

[0025] The present invention proposes a new high-temperature treatment method, which further optimizes the use of energy. At the same time, in order to solve the problem that existing high-temperature treatment equipment lacks stirring or has poor stirring effect, the device drives several heating rods inside the treatment tank to move arbitrarily in the horizontal direction through a driving structure. The driving structure includes an external connecting member arranged on the outside of the movable disk. When the external driving structure drives the internal and external connecting members of the disk to move, the external connecting member is connected to the upper end face of the movable disk, and the movable platform is connected to the lower end face of the movable disk, thereby realizing the arbitrary movement of the movable platform in the horizontal direction, which can ensure that the heating rods fully contact the waste salt, and can use a certain moving speed and irregular moving position to play a certain stirring role on the waste salt. The device can also drive the heating rods to move in the vertical direction. The device can move vertically to achieve heating effects at different positions. First, the device realizes the stirring effect under the premise of ensuring high sealing and heat preservation of the treatment tank, and the waste salt inside the treatment tank can fully contact the heating rod to be heated, and the high-temperature treatment efficiency of the overall device is high. The device can also automatically clean several heating rods after the waste salt is treated. When the heating rod moves upward to a certain extent, the position of the cleaning disk is limited by the action of the tightening spring, and the cleaning disk can be used to scrape the heating rod to avoid the presence of waste salt impurities adhering to the heating rod and affecting the subsequent heating efficiency. The device has a high treatment effect on waste salt and has high sealing and can effectively utilize energy.

[0026] It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory only and are not restrictive of the present disclosure.

[0027] This application document provides an overview of various implementations or examples of the technology described in this disclosure, and is not a comprehensive disclosure of the full scope or all features of the disclosed technology. BRIEF DESCRIPTION OF THE DRAWINGS

[0028] Figure 1 This is a structural schematic diagram of an industrial waste salt treatment and energy storage device of the present invention.

[0029] Figure 2 This is a structural schematic diagram of another perspective of an industrial waste salt treatment and energy storage device of the present invention.

[0030] Figure 3 This is a structural schematic diagram of an industrial waste salt treatment and energy storage device from another perspective of the present invention.

[0031] Figure 4 This is a structural schematic diagram of an industrial waste salt treatment and energy storage device from another perspective of the present invention.

[0032] Figure 5 The present invention is a schematic cross-sectional structural diagram of a sealing cover of an industrial waste salt treatment and energy storage device.

[0033] Figure 6 This is a flow chart of an industrial waste salt treatment and energy storage device of the present invention.

[0034] Description of main reference numerals:

[0035] 1-processing tank, 2-moving platform, 11-sealing cover, 12-insulation sleeve, 13-heat exchange water pipe, 14-driving assembly, 15-gas outlet pipe, 16-controller, 21-heating rod, 22-multi-stage telescopic rod, 23-cleaning plate, 24-telescopic rod, 25-limiting spring, 31-moving plate, 32-sliding short column, 33-elastic limiting rod, 34-tightening spring, 131-heat exchange water pipe outlet, 141-frame part, 142-bar frame 1, 143-bar frame 2, 144-sliding block, 145-fixed rod, 146-disc external connection part, 148-control assembly, 1481-screw, 1482-connecting block, 1483-servo motor. DETAILED DESCRIPTION

[0036] In order to make the purpose, technical solutions and advantages of the embodiments disclosed in the present invention more clear, the technical solutions of the embodiments disclosed in the present invention will be clearly and completely described below in conjunction with the drawings of the embodiments disclosed in the present invention. Obviously, the described embodiments are part of the embodiments disclosed in the present invention, not all of the embodiments. Based on the described embodiments disclosed in the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection disclosed in the present invention.

[0037] Unless otherwise defined, the technical or scientific terms used in the present disclosure shall have the usual meanings understood by persons of ordinary skill in the field to which the present disclosure pertains. Words such as "include" or "comprise" and the like used in the present disclosure mean that the elements or objects preceding the word encompass the elements or objects listed following the word and their equivalents, without excluding other elements or objects. Words such as "connect" or "connected" and the like are not limited to physical or mechanical connections, but may also include electrical connections, whether direct or indirect. "Up", "down", "left", "right", etc. are only used to indicate relative positional relationships. When the absolute position of the object being described changes, the relative positional relationship may also change accordingly.

[0038] In order to keep the following description of the disclosed embodiments of the present invention clear and concise, the disclosed embodiments omit detailed descriptions of known functions and known components.

[0039] like Figure 1-6 As shown, an embodiment of the present invention provides an industrial waste salt treatment and energy storage device, comprising:

[0040] The treatment tank 1 is constructed as a cylindrical shell with an inner cavity. Currently, the treatment of waste salt by high-temperature calcination is a relatively common treatment process, which mainly uses high temperature to thermally decompose organic matter. When the waste salt is treated at high temperature, the principle of anaerobic cracking of organic matter is mainly used. Therefore, it is necessary to ensure the sealing of the entire treatment tank 1 during calcination. The upper end of the treatment tank 1 is provided with an opening for pouring the waste material to be treated. The upper side of the treatment tank 1 is matched with a sealing cover 11. A lifting control component (not shown) is provided between the sealing cover 11 and the treatment tank 1. The reactor or tank body currently uses an automatic lifting switch, which is widely used in actual production in this field. The lifting structure can adopt a variety of existing structures to realize the lifting action of the sealing cover 11. No specific statement will be made in this application.

[0041] It also includes a mobile platform 2, which is horizontally arranged in the processing tank 1. A number of heating rods 21 are fixedly arranged vertically and evenly on the lower end surface of the mobile platform 2. During the high-temperature treatment of waste salt, the waste gas generated needs to be discharged. Therefore, a gas outlet pipe 15 is fixedly connected to one side of the upper end of the processing tank 1, and the temperature inside the processing tank 1 needs to be detected to ensure the control of the temperature inside the processing tank 1. A number of temperature and pressure sensors are evenly fixed in the processing tank 1, and a controller 16 electrically connected to the number of temperature and pressure sensors is fixedly arranged outside the processing tank 1; but currently used When the electric heating rod realizes the heating effect, it needs to consume a large amount of electric energy. At present, my country's clean and renewable energy sources mainly include wind energy and solar energy, but these clean and renewable energy sources are unstable electric energy, which are all in the form of discontinuous or continuous. Therefore, the heating rod 21 in the device adopts a ceramic electric heating rod, and further, in order to ensure the full utilization of heat, the outer fixed sleeve of the treatment tank 1 is provided with an insulation sleeve 12. The device realizes the direct conversion into heat energy in the form of discontinuous or continuous, and stores it in industrial waste salt, which can keep the industrial waste salt in an ultra-high temperature state for a long time. At the same time, there will be problems when treating industrial waste salt. The heat energy that cannot be utilized can be utilized. A serpentine groove is provided on the end surface of the insulation sleeve 12 close to the treatment tank 1. A heat exchange water pipe 13 is fixedly arranged in the groove. Both ends of the heat exchange water pipe 13 pass through the insulation sleeve 12 and extend to the outside. The lower end of the heat exchange water pipe 13 is a heat exchange water pipe outlet 131. When the heat energy needs to be utilized, water is passed through the heat exchange water pipe 13 to carry away the heat energy and output steam. According to the existing waste salt high-temperature treatment process, the waste salt is generally calcined directly at high temperature in a container such as a reactor. After calcination, The waste gas is treated, but the current high-temperature treatment device either uses high-temperature gas to achieve the heating effect, which is not uniform for the heating of the waste salt and has a poor heating effect. The use of direct contact heating structures such as heating rods also has the problem of uneven contact. To address this problem, a stirring rod is generally used to achieve uniform heating. However, impurities generated during the stirring process are easy to adhere to the stirring rod, and vortices are easily formed during the rotating stirring process. Due to the centrifugal effect, a part of the solid waste salt is always attached to the inner wall of the container, and the contact with the direct heating structure is still not sufficient, resulting in poor overall heating effect.Therefore, in this device, the mobile platform 2 can move vertically, and at the same time, the mobile platform 2 can move arbitrarily in the horizontal position, and can change the heating position according to the needs, and has the function of stirring. At the same time, the heating will not be insufficient due to the single rotation action. In order to achieve the above needs and ensure the sealing of the processing tank 1, the mobile platform 2 is connected to the sealing cover 11 through a mobile component. The mobile component includes a mobile disk 31 arranged in the sealing cover 11, the mobile platform 2 is connected to the mobile disk 31, and the upper end surface of the mobile disk 31 is fixedly connected to the disk external connection member 146, and the inner wall of the sealing cover 11 is provided with a ring The limiting groove has a side T-shaped cross-section, with four sliding studs 32 evenly arranged within it. Four elastic limiting rods 33 are arranged around the movable disk 31 and connected to the movable disk 31. The ends of the four elastic limiting rods 33, which are away from the movable disk 31, extend into the limiting groove and are fixedly connected to the four sliding studs 32. In this structure, the four elastic limiting rods 33 and the sliding studs 32 can achieve a vertical limit and fixation of the movable disk, while ensuring horizontal movement of the movable disk 31 within the sealing cover 11.

[0042] In this device, it is also necessary to control the movement of the mobile platform 2, that is, to control the movement of the mobile disk 31. In order to achieve the control of the movement of the mobile disk 31 while ensuring the high sealing of the processing tank 1, the sealing cover 11 is provided with a driving assembly 14, which includes a frame 141 provided on the upper side of the sealing cover 11. The frame 141 is provided with a horizontal strip frame 142 and a strip frame 2 143. Both ends of the strip frame 142 and the strip frame 2 143 are slidably connected to the frame 141. 3 are arranged vertically and adjacent to each other, and the sliding block 144 slides simultaneously in the bar frame 142 and the bar frame 2 143. A fixing rod 145 is vertically provided on the upper side of the sealing cover 11. The upper end of the fixing rod 145 is fixedly connected to the sliding block 144, and the lower end of the fixing rod 145 is fixedly connected to the outer connecting member 146 of the connecting plate. Through the movement of the bar frame 142 and the bar frame 2 143, the sliding block 144 can be controlled to drive the fixing rod 145 to move to any position in the horizontal direction. Therefore, the frame-shaped member 141 is provided with two control components 148 for driving the bar frame 142 and the bar frame 2 143 to move. The control component 148 includes a screw 1481 arranged in the frame-shaped member 141. The two screws 1481 are arranged perpendicular to each other. A connecting block 1482 is threadedly sleeved on the screw 1481. The two connecting blocks 1482 are fixedly connected to the bar frame 142 and the bar frame 2 143 respectively. Both ends of the screw 1481 are rotatably connected to the frame-shaped member 141. Two servo motors 1483 are fixedly provided on the frame-shaped member 141 to drive the two screws 1481 to rotate respectively. When it is necessary to control the mobile platform 2 to move arbitrarily in the horizontal direction, the two servo motors 1483 are used to work, and the control bar The first-shaped frame 142 and the second-bar frame 143 respectively move within a certain stroke, which can realize the control of the movement of the fixed rod 145 to any position within the projection area of ​​the frame-shaped member 141, and then control the outer disk connection member 146 to move arbitrarily within the corresponding area. The outer disk connection member 146 drives the movable disk 31 to move horizontally within the range inside the sealing cover 11. Because the movable platform 2 is connected to the lower side of the movable disk 31, the effect of controlling the movable platform 2 to move arbitrarily is achieved. When the movable platform 2 moves, it can drive a number of heating rods 21 to move. When it moves irregularly at a certain rate, it can stir the waste salt, and can also ensure the sufficient heating effect of the waste salt, ensure the overall high waste salt treatment effect, and also ensure the sealing state of the treatment tank 1;

[0043] The heating rod 21 is easily adhered when inserted into the waste salt for heating operation. At the same time, if there are too many adhered impurities, it is easy to affect the heating effect of the heating rod 21 on the overall waste salt. A cleaning structure for the heating rod 21 is set in the device. Because the movable platform 2 in the device also needs to meet the vertical movement requirement, that is, the movable platform 2 is fixedly connected to the movable disk 31 through two symmetrically arranged multi-stage telescopic rods 22. Here, the multi-stage telescopic rod 22 adopts a telescopic rod structure that can be automatically extended and retracted. It can be driven and extended by hydraulic, pneumatic or electric means. It only needs to realize the telescopic action. This telescopic rod structure has many applications in this field and will not be elaborated here. In order to avoid high temperature affecting the telescopic effect, the telescopic rod should be subjected to high temperature resistant insulation treatment. Through the telescopic rod structure, the device realizes the function of allowing the movable platform 2 to drive several heating rods 21 to move in the vertical direction, and the vertical heating position can be controlled. In this device, the vertical direction of the movable platform 2 can be used The straight moving action realizes the cleaning effect of the heating rod 21, wherein a cleaning disc 23 is provided on the lower side of the movable platform 2, and the cleaning disc 23 is slidably sleeved on several heating rods 21, and several telescopic rods 24 are vertically and evenly provided on the upper side of the movable platform 2, and several of the telescopic rods 24 are fixedly sleeved with limit springs 25 that limit their extension and contraction. The upper end of the telescopic rod 24 is fixedly connected to the movable disc 21, and the lower end of the telescopic rod 24 is fixedly connected to the cleaning disc 23, wherein the minimum length of the multi-stage telescopic rod 22 is much smaller than the minimum length of the telescopic rod 24. When the high-temperature treatment of the waste salt inside the treatment tank 1 is completed and the treated material needs to be discharged, the heating rod 21 is moved out of the material by contracting the multi-stage telescopic rod 22. When the multi-stage telescopic rod 22 is shortened to less than the minimum length of the telescopic rod 24, the cleaning disc 23 and several heating rods 21 move relative to each other, thereby cleaning the material adhered to the heating rod 21. This cleaning structure does not affect the function of the heating rod 21 when it is inserted into the waste salt.

[0044] The method for treating and storing industrial waste salt using this device includes the following steps: first, using a multi-axis spiral pulverizer to crush the industrial waste salt and evenly distribute it in a treatment tank 1. Next, a heating rod 21 is placed in the treatment tank 1 and inserted into the crushed industrial waste salt. Intermittent electrical energy from a wind or solar power plant is converted into heat energy by the heating rod 21 and introduced into the treatment tank 1, locally heating the industrial waste salt to above 1000°C. The heating rod is then moved to another location in the treatment tank and continuously heated until all the industrial waste salt in the treatment tank is melted. During the heating process, because the treatment tank 1 is equipped with an insulation jacket 12, a discontinuous heating method can be used, allowing heating to be turned on and off at any time. The temperature can be maintained until it is output and used during peak power or heat periods. After heating to above 1000°C, all organic pollutants in the waste salt are completely decomposed under anoxic conditions. The resulting waste gas is discharged through a gas outlet pipe 15. The discharged waste gas is treated in a desulfurization and denitrification spray tower and an activated carbon adsorption device before being discharged into the atmosphere. Because the molten industrial waste salt can store heat for a long time in the heating kettle, it can be used to heat and evaporate the water in the heat exchange water pipe 13 during peak power periods to drive the steam turbine to generate electricity, or to output high-temperature steam during peak thermal periods. After cooling, the inorganic salt treated in the treatment tank 1 can be dissolved in water in a dissolution tank and then passed through a nanofiltration membrane to separate the monovalent salt from the polyvalent salt, obtaining a monovalent salt solution for industrial production.

[0045] Of course, the above is a preferred embodiment of the present invention. It should be pointed out that for ordinary technicians in this technical field, several improvements and modifications can be made without departing from the principles of the present invention. These improvements and modifications are also considered to be within the scope of protection of the present invention.

Claims

1. A method for treating and storing industrial waste salt, characterized in that: The apparatus used in this method includes: The treatment tank is constructed as a cylindrical shell with an inner cavity. The top of the treatment tank is matched with a sealing cover. A gas outlet pipe is fixedly connected to one side of the upper end of the treatment tank. The outer fixed sleeve of the treatment tank is provided with an insulation sleeve. The surface of the insulation sleeve close to the treatment tank is provided with a serpentine groove. A heat exchange water pipe is fixedly arranged in the groove. The water inlet and outlet of the heat exchange water pipe both penetrate the insulation sleeve and extend to the outside. A movable platform is horizontally arranged in the processing tank, and a plurality of heating rods are fixedly and evenly arranged vertically on the lower end surface of the movable platform; the movable platform is connected to the sealing cover through a movable assembly, and the sealing cover is provided with a driving assembly for driving the movable assembly to move; The moving assembly includes a moving plate arranged in a sealing cover, the moving platform is connected to the lower end surface of the moving plate, an annular limiting groove is provided on the inner wall of the sealing cover, the cross section of the annular limiting groove is set to a side T-shape, four sliding short columns are evenly arranged in the annular limiting groove, four elastic limiting rods are arranged around the moving plate, the four elastic limiting rods are all connected to the moving plate, and one end of the four elastic limiting rods away from the moving plate extends into the annular limiting groove and is fixedly connected to the four sliding short columns respectively; The method for treating and storing industrial waste salt using the device includes the following steps: Step 1: Use a multi-axis spiral crusher to crush the industrial waste salt and evenly arrange it in the processing tank. Then place the heating rod into the processing tank and insert it into the crushed industrial waste salt material; Step 2: Intermittent electrical energy from wind or solar power plants is converted into thermal energy through a heating rod and passed into the treatment tank, locally heating the industrial waste salt to above 1000°C. The heating rod is then moved to another location in the treatment tank and continued to heat until all the industrial waste salt in the treatment tank is melted. Step 3: After heating to above 1000°C, all organic pollutants in the waste salt are completely decomposed under oxygen-deficient conditions, and the waste gas generated is discharged from the gas outlet pipe; Step 4: The exhaust gas is treated in a desulfurization and denitrification spray tower and an activated carbon adsorption device before being discharged into the atmosphere; Step 5: The molten industrial waste salt stores heat in the treatment tank for a long time. During peak electricity demand periods, it heats and evaporates the water in the heat exchange water pipe to drive the steam turbine to generate electricity, or during peak thermal demand periods, it heats and evaporates the water in the heat exchange water pipe to output high-temperature steam. Step 6: After the treated inorganic salts in the treatment tank are cooled, they are dissolved in water through a dissolution tank. After being filtered through a nanofiltration membrane, the monovalent salts and the polyvalent salts are separated to obtain a monovalent salt solution for industrial production.

2. The method according to claim 1, wherein The driving assembly includes a frame-shaped member arranged on the upper side of the sealing cover, and a strip frame 1 and a strip frame 2 are horizontally arranged in the frame-shaped member, and both ends of the strip frame 1 and the strip frame 2 are slidably connected to the frame-shaped member, and the strip frame 1 and the strip frame 2 are arranged vertically and adjacent to each other, and a sliding block slides in the strip frame 1 and the strip frame 2 at the same time, and a fixed rod is vertically arranged on the upper side of the sealing cover, and the upper end of the fixed rod is fixedly connected to the sliding block, and the lower end of the fixed rod is fixedly connected to a disk external connecting member, and the disk external connecting member is fixed to the upper surface of the movable disk, and two control components that drive the strip frame 1 and the strip frame 2 to move are provided on the frame-shaped member.

3. The method according to claim 1, wherein The adjacent sliding short columns are limited by a pressing spring arranged in the annular limiting groove.

4. The method according to claim 2, wherein The control component includes two screws arranged in a frame-shaped member, the two screws are arranged perpendicular to each other, and a connecting block is provided on the screw thread sleeve. The two connecting blocks are fixedly connected to the strip frame 1 and the strip frame 2 respectively. Both ends of the screw are rotatably connected to the frame-shaped member, and two servo motors are fixedly provided on the frame-shaped member to drive the two screws to rotate respectively.

5. The method according to claim 1, wherein The mobile platform is fixedly connected to the mobile plate via two symmetrically arranged multi-stage telescopic rods.

6. The method according to claim 5, wherein A cleaning disk is provided on the lower side of the mobile platform, and the cleaning disk is slidably sleeved on a number of heating rods. A number of telescopic rods are vertically and evenly arranged on the upper side of the mobile platform. A number of the telescopic rods are fixedly sleeved with a limit spring for limiting their extension and retraction. The upper end of the telescopic rod is fixedly connected to the mobile disk, and the lower end of the telescopic rod is fixedly connected to the cleaning disk. The minimum length of the multi-stage telescopic rod is much smaller than the minimum length of the telescopic rod.

7. The method according to any one of claims 1 to 6, wherein: The heating rod is a ceramic electric heating rod.

8. The method according to any one of claims 1 to 6, characterized in that: The cylindrical shell is made of high-alumina refractory bricks, and the insulation sleeve is made of rock wool.

9. The method according to any one of claims 1 to 6, wherein the heat exchange water pipe is made of a high-temperature and high-pressure resistant metal pipe.

10. The method according to any one of claims 1 to 6, wherein a plurality of temperature and pressure sensors are evenly and fixedly arranged inside the processing tank, and a controller electrically connected to the plurality of temperature and pressure sensors is fixedly arranged outside the processing tank.

Citation Information

Patent Citations

  • Industrial waste salt treatment and energy storage device

    CN217451461U