Resin composition and molded article

By using a phosphorus-based flame retardant composition of Mn+(diethylphosphonic acid)-n and ammonium polyphosphate in the resin composition, a metallic supramolecular structure is formed, which solves the problem that ABS copolymers are difficult to self-carbonize without the addition of a carbonizing agent, achieving high flame retardancy and thermal stability, and is suitable for vehicle interior and exterior trim materials and electrical/electronic products.

CN115427504BActive Publication Date: 2026-06-05LG CHEM LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
LG CHEM LTD
Filing Date
2021-08-06
Publication Date
2026-06-05

AI Technical Summary

Technical Problem

In the existing technology, ABS copolymers are difficult to form char with phosphorus-based flame retardants without the addition of charring agents, resulting in insufficient flame retardancy and thermal stability. In addition, the charring agents are expensive, which affects productivity.

Method used

A phosphorus-based flame retardant composition comprising 30% to 70% by weight of Mn+(diethylphosphonic acid)-n and 30% to 70% by weight of ammonium polyphosphate is used to achieve self-charring by forming metal supramolecular structures in the resin composition, thereby imparting flame retardancy and thermal stability.

Benefits of technology

Without the addition of a charring agent, the resin composition can self-char, exhibiting excellent flame retardancy and thermal stability, meeting the high flame retardancy requirements of the UL-94V test, and is suitable for a variety of products.

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Abstract

The present invention provides a resin composition and a molded product molded from the resin composition, the resin composition comprising: 25 to 50 parts by weight of a phosphorus-based flame retardant composition with respect to 100 parts by weight of a base resin comprising a graft copolymer containing a rubber polymer and a styrene-based copolymer, wherein the phosphorus-based flame retardant composition comprises 30 to 70% by weight of M n+ (diethylphosphinic acid) ‑ n (M is a metal having an oxidation number of 2 to 5, n is an integer selected from 2 to 5) and 30 to 70% by weight of ammonium polyphosphate.
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