Dispersion of polyacrylate in epoxy resin and preparation method and application thereof

The polyacrylate dispersion is prepared by dispersing polymerization method using macromolecular RAFT reagent in epoxy resin, which solves the problems of high viscosity and difficulty in mixing of existing epoxy resin toughening agents, and achieves the effect of efficient toughening and convenient construction.

CN115651361BActive Publication Date: 2025-04-29TIANJIN UNIV
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Patent Information

Application Number
CN202211323360.6
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2022-10-27
Publication Date
2025-04-29
Estimated Expiration
2042-10-27

AI Technical Summary

Technical Problem

The existing epoxy resin toughening agents have problems such as high viscosity, difficulty in mixing and poor performance reproducibility, which affects their application in composite materials.

Method used

The polyacrylate dispersion is directly prepared in liquid epoxy resin by dispersion polymerization to control particle size and surface structure, and improve the stability and viscosity of the dispersion.

Benefits of technology

The dispersion has high solids content, good stability, low viscosity and easy construction properties, which significantly improves the toughening effect and application convenience of epoxy resin.

✦ Generated by Eureka AI based on patent content.

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Abstract

The invention belongs to the technical field of dispersions in epoxy resins, discloses a dispersion of polyacrylate in epoxy resins and its preparation method and application, with macromolecular RAFT agent as dispersant, epoxy resin as dispersion medium, acrylate monomers in epoxy resins are directly prepared by dispersion polymerization of polyacrylate in epoxy medium (labeled as DPA-EP), and the results show that the dispersion has the advantages of high dispersed particle content (also referred to as solid content), good dispersion stability, low viscosity, and easy regulation of particle size and particle surface chemical composition. The dispersion is used for toughening of epoxy resins, with convenient mixing, low system viscosity, easy construction, obvious toughening effect, and little influence on the heat resistance and modulus of epoxy cured products. It can be applied to various epoxy resins and curing systems.
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Citation Information

Patent Citations

  • Stable dispersions of polymers in polyepoxides

    US4708996A

  • Method for preparing polymer polyether polyol by semi-continuous dispersion polymerization process

    CN110437386A

  • Core-shell particle for toughening epoxy resin and preparation method thereof

    CN113831455A