Oil-in-water cosmetic material

Abstract

The present application provides an oil-in-water cosmetic material. The oil-in-water cosmetic material of the present application contains (A) a benzotriazole type ultraviolet absorber, (B) one or more selected from a silicone wax and silica, and (C) water, the average particle diameter of the silica of the above component (B) is 1 μm or more, and the content of the above component (C) is 50% by mass or more based on the total amount of the above oil-in-water cosmetic material.

Description

TECHNICAL FIELD

[0001] The present application relates to an oil-in-water cosmetic material. BACKGROUND

[0002] In order to protect the human body from ultraviolet rays in various situations in daily life, attempts have been made to incorporate ultraviolet absorbers in cosmetic materials. There are many challenges in achieving cosmetic materials that are excellent in terms of ultraviolet defense effect and use feeling.

[0003] Attempts have been made to enable the ultraviolet defense effect and good use feeling by making the total amount and the incorporation ratio of the higher alcohol and the surfactant be within a specific range (Patent Document 1), but if the higher alcohol is too much, the spread and stickiness of the application are generated, and thus the effect is insufficient.

[0004] PRIOR ART DOCUMENTS

[0005] PATENT DOCUMENTS

[0006] Patent Document 1: Japanese Patent Application Laid-Open No. 2010-189281 SUMMARY

[0007] An object of the present application is to provide an oil-in-water cosmetic material that is excellent in terms of quick-drying property, application property, use feeling.

[0008] The present inventors have provided an oil-in-water cosmetic material containing (A) a benzotriazole-type ultraviolet absorber, (B) one or more selected from the group consisting of silicone wax and silica, and (C) water,

[0009] The average particle diameter of the silica of the above component (B) is 1 μm or more, and the content of the above component (C) is 50% by mass or more, based on the total amount of the above oil-in-water cosmetic material.

[0010] It has been found that, according to the present application, an oil-in-water cosmetic material that is excellent in terms of quick-drying property, application property, use feeling, and emulsified state can be obtained. The present application has been completed based on these insights.

[0011] That is, the present application provides the following solutions:

[0012] [1] An oil-in-water cosmetic material containing (A) a benzotriazole-type ultraviolet absorber, (B) one or more selected from the group consisting of silicone wax and silica, and (C) water,

[0013] The average particle diameter of the silica of the above component (B) is 1 μm or more, and the content of the above component (C) is 50% by mass or more, based on the total amount of the above oil-in-water cosmetic material.

[0014] [2] The oil-in-water cosmetic material according to [1], which contains (D) a nonionic surfactant;

[0015] [3] The oil-in-water cosmetic material according to [1] or [2], which contains (E) an ultraviolet protecting agent (wherein the above-mentioned component (A) is excluded);

[0016] [4] The oil-in-water cosmetic material according to [1] to [3], which contains (F) an acrylic acid-based polymer;

[0017] [5] The oil-in-water cosmetic material according to [2], wherein the above-mentioned component (D) is one or more selected from the group consisting of polyglycerin fatty acid esters, sorbitan fatty acid esters, polyoxyethylene fatty acid esters, sucrose fatty acid esters, polysorbate esters, polyoxyethylene phytosteryl esters, and silicone-based surfactants;

[0018] [6] The oil-in-water cosmetic material according to [3], wherein the above-mentioned component (E) is one or more selected from the group consisting of 2-ethylhexyl-p-methoxycinnamate, dimethico-diethylbenzalmalonate, diethylamino hydroxybenzoyl hexyl benzoate, 2,4-bis{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine, 2,4,6-tris[4-(2-ethylhexyloxycarbonyl)anilino]-1,3,5-triazine, 4-tert-butyl-4'-methoxydibenzoylmethane, ethylhexyl salicylate, phenylbenzimidazole sulfonic acid, p-aminobenzoic acid, zinc oxide, and titanium oxide;

[0019] [7] The oil-in-water cosmetic material according to [4], wherein the above-mentioned component (F) is one or more selected from the group consisting of Carbomer, (acrylates / alkyl methacrylate (C10-30) crosspolymer, (hydroxyethyl acrylate / sodium acryloyldimethyl taurate) copolymer, (ammonium acryloyldimethyltaurate / vinylpyrrolidone) copolymer, and polyacrylamide;

[0020] [8] The oil-in-water cosmetic material according to [1] to [7], wherein the total content of the component (B) is 0.0001 parts by mass to 500 parts by mass, relative to 1 part by mass of the total content of the component (A);

[0021] [9] The oil-in-water cosmetic material according to [1] to [8], wherein the total content of the component (B) is 0.01 mass% to 10 mass%;

[0022]

[10] The oil-in-water cosmetic material according to [1] to [9], which is used for sun protection.

[0023] The oil-in-water cosmetic material of the present application contains (A) a benzotriazole type ultraviolet absorber, (B) one or more selected from the group consisting of silicone wax and silica, and (C) water 50% or more, the average particle diameter of the silica of the above component (B) is 1 μm or more, and the content of the above component (C) is 50% by mass or more based on the total amount of the above oil-in-water cosmetic material, and thus the quick-drying property, the application property, the use feeling, and the emulsified state are excellent. BRIEF DESCRIPTION OF DRAWINGS

[0024] Figure 1 The results of evaluating the application property of Test Example 1 using the compositions of Example 1 and Comparative Example 1 are shown. DETAILED DESCRIPTION

[0025] Hereinafter, the mode for carrying out the present application will be explained in detail. However, the present application is not limited to the following embodiments.

[0026] [1. Oil-in-water cosmetic material]

[0027] The oil-in-water cosmetic material of the present embodiment contains (A) a benzotriazole type ultraviolet absorber (also simply referred to as "(A) component"), (B) one or more selected from the group consisting of silicone wax and silica (also simply referred to as "(B) component"), and (C) water, the average particle diameter of the silica of the above component (B) is 1 μm or more, and the content of the above component (C) is 50% by mass or more based on the total amount of the above oil-in-water cosmetic material.

[0028] [(A) Component]

[0029] The benzotriazole type ultraviolet absorber is a methylenebis(hydroxyphenyl-benzotriazole) derivative, and preferably methylenebis-benzotriazolyl-tetramethylbutylphenol. Commercially available products such as TINOSORB M (manufactured by BASF Corporation) and Parsol MAX (manufactured by DSM Corporation) can be used. One kind can be used alone or two or more kinds can be used in combination.

[0030] The content of the (A) component in the oil-in-water cosmetic material of the present embodiment is not particularly limited, and can be appropriately set according to the kind of the (A) component, the kind and content of the other compounding components, the use and formulation form of the oil-in-water cosmetic material, and the like. From the viewpoint of more significantly exerting the effects brought by the present application, for example, the total content of the (A) component can be 0.01 to 20% by mass, preferably 0.01 to 10% by mass, more preferably 0.03 to 8% by mass, further preferably 0.05 to 6% by mass, further more preferably 0.08 to 5% by mass, particularly preferably 0.1 to 3% by mass, and most preferably 0.1 to 2% by mass, based on the total amount of the oil-in-water cosmetic material.

[0031] [(B) component]

[0032] The (B) component selected from one or more of silicone waxes and silica can be used alone or in combination of two or more.

[0033] In the (B) component, from the viewpoint of more further significantly exerting the effects brought about by the present application, the silicone wax is preferably a polyether-modified silicone wax, more preferably a water-soluble polyether-modified silicone wax, further preferably bis-PEG-18 methyl ether dimethicone, bis-PEG-15 methyl ether dimethicone, PEG-32 methyl ether dimethicone, and PEG-17 dimethicone, and most preferably bis-PEG-18 methyl ether dimethicone. The silicone wax can be used as a commercially available product, and examples include 2501 Cosmetic Wax (Dow Corning Toray Co., Ltd. manufacture, bis-PEG-18 methyl ether dimethicone, melting point 36°C to 42°C), DMC 6038 (Wacker manufacture, bis-PEG-15 methyl ether dimethicone, melting point about 30°C), KF-6004 (Shin-Etsu Chemical Co., Ltd. manufacture, PEG-32 methyl ether dimethicone, melting point 45°C), or Silsoft (registered trademark) 895 (MOMENTIVE manufacture, PEG-17 dimethicone), and the like.

[0034] In the (B) component, from the viewpoint of more further significantly exerting the effects brought about by the present application, the average particle diameter of the silica is 1 μm or more, preferably 1 μm to 20 μm, more preferably 1 μm to 15 μm, further preferably 2 μm to 10 μm, and particularly preferably 2 μm to 7 μm. The average particle diameter is the median particle diameter (D50) measured by a laser diffraction method. As the device used in the laser diffraction method, for example, LA960 (manufactured by HORIBA, Ltd.) is used. The silica can be hydrophobic or hydrophilic. The silica can be used as a commercially available product, and examples include SIRICA MICRO BEAD P-500, SIRICA MICRO BEAD P-4000, SILICA PEARL P-4M, SILICA PEARL 20CG, HCS 160M5, SILICA MICRO BEAD BA-1 (all manufactured by Showa Denko K.K.), Sylysia 320 (manufactured by Fuji Silysia Chemical Ltd.), SUNSPHERE H-31, SUNSPHERE H-51 (all manufactured by AGC Si-Tech Co., Ltd.), and the like. If the average particle diameter of the silica is less than 1 μm, the emulsified state is sometimes not ideal.

[0035] The content of the (B) component in the oil-in-water cosmetic material of the present embodiment is not particularly limited and can be appropriately set according to the kind of the (B) component, the kinds and contents of other compounding components, the use and formulation form of the oil-in-water cosmetic material, and the like. The content of the (B) component is preferably, for example, 0.01 to 10% by mass, more preferably 0.05 to 8% by mass, further preferably 0.1 to 6% by mass, further more preferably 0.1 to 5% by mass, and particularly preferably 0.1 to 4% by mass, based on the total amount of the oil-in-water cosmetic material, from the viewpoint of more significantly exerting the effects brought about by the present application.

[0036] [(C) component]

[0037] Water can be ion-exchanged water, distilled water, or the like. The content of water is not particularly limited and can be appropriately set according to the kinds and contents of other compounding components, the use and formulation form of the oil-in-water cosmetic material, and the like. The content of the (C) component is preferably 50% by mass or more, more preferably 55% by mass or more, further preferably 60% by mass or more, and particularly preferably 65% by mass or more, based on the total amount of the oil-in-water cosmetic material, from the viewpoint of more significantly exerting the effects brought about by the present application. For example, if it is around 45% by mass or less, the emulsified state is sometimes not ideal. The content of the (C) component is preferably 98% by mass or less, more preferably 96.5% by mass or less, and further more preferably 95% by mass or less, based on the total amount of the oil-in-water cosmetic material.

[0038] [(D) component]

[0039] The oil-in-water cosmetic material of the present embodiment can further contain a (D) nonionic surfactant (also simply referred to as a "(D) component"). By further containing the (D) component in the oil-in-water cosmetic material, the effects brought about by the present application can be more significantly exerted. The (D) component is not particularly limited as long as it is a compound that is generally used in cosmetic material compositions.

[0040] As the component (D), polyglyceryl fatty acid esters such as polyglyceryl monostearate, polyglyceryl monoisostearate, polyglyceryl diisostearate, and polyglyceryl penta- isostearate; sorbitan fatty acid esters such as sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, diglycerin sorbitan penta-2- ethylhexanoate, and diglycerin sorbitan tetra-2-ethylhexanoate; polyoxyethylene fatty acid esters such as polyethylene glycol monostearate, polyethylene glycol stearate, and polyethylene glycol isostearate; sucrose fatty acid esters; polysorbate esters such as polyoxyethylene sorbitan monolaurate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan tristearate, and polyoxyethylene sorbitan oleate; polyoxyethylene phytosteryl esters; silicone-based surfactants such as polyoxyethylene-methyl polysiloxane copolymer, silicone-13 (poly(oxyethylene / oxypropylene)-butene-methyl polysiloxane copolymer), lauryl PEG-9 polydimethylsiloxyethyl dimethicone, and PEG-9 polydimethylsiloxyethyl dimethicone; and the like can be exemplified. The HLB of the component (D) is preferably from 1 to 15, more preferably from 2 to 13, further preferably from 2 to 11, further more preferably from 2 to 10, and particularly preferably from 2 to 9. The HLB can be calculated by the Griffin method. The component (D) can be used as a commercially available product.

[0041] The content of the component (D) in the oil-in-water cosmetic material of the present embodiment is not particularly limited and can be appropriately set according to the kind of the component (D), the kinds and contents of other components, the use and formulation form of the oil-in-water cosmetic material, and the like. From the viewpoint of more significantly exerting the effects brought about by the present application, the total content of the component (D) is preferably from 0.01% by mass to 10% by mass, more preferably from 0.05% by mass to 8% by mass, further preferably from 0.05% by mass to 6% by mass, further more preferably from 0.05% by mass to 4% by mass, and particularly preferably from 0.1% by mass to 2% by mass, based on the total amount of the oil-in-water cosmetic material.

[0042] [(E) component]

[0043] The oil-in-water cosmetic material of the present embodiment can further contain an (E) ultraviolet protecting agent (also simply referred to as “component (E)”). By further containing the component (E) in the oil-in-water cosmetic material, the effects brought about by the present application can be more significantly exerted. The component (E) is not particularly limited as long as it is a compound generally used in cosmetic material compositions.

[0044] As the (E) component, one or more oil-soluble ultraviolet absorbers selected from the group consisting of p-methoxycinnamic acid 2-ethylhexyl ester, dimethicone diethyl silylene propanediolate, octocrylene, diethylamino hydroxybenzoyl hexyl benzoate, p-aminobenzoic acid, 2,4-bis{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine, 2,4,6-tris[4-(2-ethylhexyloxycarbonyl)anilino]-1,3,5-triazine, 4-tert-butyl-4'-methoxydibenzoylmethane, homomenthyl salicylate, ethylhexyl salicylate, and octyl salicylate; one or more water-soluble ultraviolet absorbers selected from the group consisting of phenyl benzimidazole sulfonic acid and terephthalylidene dicamphor sulfonic acid; and one or more metal oxides selected from the group consisting of zinc oxide, titanium oxide, cerium oxide, and zirconium oxide, and the like can be exemplified. The oil-soluble ultraviolet absorber preferably has a solubility in water of less than 0.01%. As for the metal oxide, there is no particular limitation as to the shape such as spherical, plate-like, needle-like, and the like, the particle diameter such as smoke-like, microparticles, pigment grade, and the like, the particle structure such as porous, non-porous, and the like, and surface treatment can be performed using a publicly known surface treatment method. The (E) component can be used as a commercially available product.

[0045] The content of the (E) component in the oil-in-water cosmetic material of the present embodiment is not particularly limited and can be appropriately set according to the type of the (E) component, the type and content of the other compounding components, the use and formulation form of the oil-in-water cosmetic material, and the like. As the content of the (E) component, from the viewpoint of more significantly exerting the effects brought about by the present application, for example, the total content of the (E) component is preferably 0.1 to 25 mass%, more preferably 0.5 to 20 mass%, further preferably 1 to 15 mass%, further more preferably 3 to 15 mass%, and particularly preferably 5 to 15 mass%, based on the total amount of the oil-in-water cosmetic material.

[0046] [(F) component]

[0047] The oil-in-water cosmetic material of the present embodiment can further contain a (F) acrylic polymer (also simply referred to as "(F) component"). By further containing the (F) component in the oil-in-water cosmetic material, the effects brought about by the present application can be more significantly exerted. The (F) component is not particularly limited as long as it is a compound generally used in cosmetic material compositions.

[0048] As the component (F), (sodium acrylate / sodium acryloyldimethyltaurate) copolymer, (hydroxyethyl acrylate / sodium acryloyldimethyltaurate) copolymer, (ammonium acryloyldimethyltaurate / vinylpyrrolidone) copolymer, (ammonium acryloyldimethyltaurate / Beheneth-25 methacrylate) crosspolymer, (ammonium acryloyldimethyltaurate / Steareth-25 methacrylate) crosspolymer, (ammonium acryloyldimethyltaurate / ammonium carboxyethyl acrylate) crosspolymer, acrylamide / ammonium acrylate copolymer, polyacrylate crosspolymer-6, polyacrylate crosspolymer-11, polyacrylate-13, (acrylic acid / acryloyldimethyltaurate / dimethyl acrylamide) crosspolymer, (sodium acrylate / acryloyldimethyltaurate / dimethyl acrylamide) crosspolymer, (acrylate / alkyl acrylate (C10-30)) crosspolymer, (acrylate / Steareth-20 methacrylate) copolymer, (acrylate / Beheneth-25 methacrylate) copolymer, (acrylate / Steareth-20 itaconate) copolymer, Steareth-10 allyl ether acrylate copolymer, carboxyvinyl polymer (carbomer), polyacrylamide, and the like can be exemplified. The component (F) can use a commercially available product.

[0049] The content of the component (F) in the oil-in-water cosmetic material of the present embodiment is not particularly limited and can be appropriately set according to the kind of the component (F), the kind and content of other compounding components, the use and formulation form of the oil-in-water cosmetic material, and the like. As the content of the component (F), from the viewpoint of more significantly exerting the effects brought by the present application, for example, the total content of the component (F) is preferably 0.01 to 5% by mass, more preferably 0.05 to 4% by mass, further preferably 0.05 to 3% by mass, further more preferably 0.1 to 3% by mass, and particularly preferably 0.1 to 2% by mass, based on the total amount of the oil-in-water cosmetic material.

[0050] The ratio of the (B) component to the (A) component in the oil-in-water cosmetic material of the present embodiment is not particularly limited and can be appropriately set according to the types of the (A) component and the (B) component, the types and amounts of other components, the use and formulation form of the oil-in-water cosmetic material, and the like. In terms of more significantly exerting the effects brought about by the present application, for example, with respect to 1 part by mass of the total amount of the (A) component contained in the oil-in-water cosmetic material of the present embodiment, the total amount of the (B) component is preferably from 0.0001 part by mass to 500 parts by mass, more preferably from 0.0001 part by mass to 300 parts by mass, further preferably from 0.0005 part by mass to 100 parts by mass, further more preferably from 0.0005 part by mass to 50 parts by mass, and particularly preferably from 0.001 part by mass to 10 parts by mass.

[0051] The oil-in-water cosmetic material of the present embodiment can contain publicly known components used in cosmetics or quasi-drugs, as long as the effects of the present application are not hindered. In addition to the above (A) to (F) components, for example, an appropriate amount of an antioxidant, a whitening component, a moisturizer, an anti-inflammatory component, an antibacterial agent, a vitamin, an amino acid, an extract from a living organism, various pharmacologically or physiologically active components can be contained in combination. In addition, an additive such as one of a surfactant (excluding the above (D)), a preservative, a pH adjustor, a chelating agent, a stabilizer, a buffer, a thickening agent (excluding the above (F)), a gelation agent, an irritation reliever, a preservative, a coloring agent, a perfume, a mineral, and the like can be added alone or two or more kinds can be added in combination. In addition, a base or a carrier can be contained alone or two or more kinds can be contained.

[0052] The oil-in-water cosmetic material of the present embodiment can be produced by mixing and stirring each component according to a conventional method, for example.

[0053] The formulation form of the oil-in-water cosmetic material of the present embodiment is not particularly limited and can adopt a publicly known form as a cosmetic or quasi-drug form. Among such publicly known forms, for example, there are liquid preparations, suspension preparations, emulsion preparations, cream preparations, gel preparations, liniment preparations, ointment preparations, emulsion preparations, aerosol preparations, powder preparations, poultice preparations, tablets in which a medicinal solution is impregnated in a sheet of non-woven fabric, stick preparations such as lipsticks, and the like. In addition, it can be used in the form of a base cosmetic such as a lotion, a cream, a body lotion, a body cream, a sunscreen cream, or the like, or in the form of a color cosmetic material such as a foundation, a lipstick, a blush, an eye makeup, a face powder, a nail polish, a pedicure, and the like. A sunscreen cosmetic material is preferred.

[0054] The application site of the oil-in-water cosmetic material of the present embodiment is not particularly limited, and any site such as the face, arms, hands, feet, neck, and the like can be applied.

[0055] Examples

[0056] Hereinafter, the present application will be specifically described based on test examples, but the present application is not limited to these test examples. In addition, the compounding amounts in the following examples and the like represent mass %.

[0057] [TEST EXAMPLE 1]

[0058] An oil-in-water composition having the composition shown in Table 1 below was prepared according to a conventional method, and the quick-drying property, tack-free property, and application uniformity were evaluated. Note that in the table, in the case where the amount indicated is 3 mass %, half of the amount, 1.5 mass %, of methylene bis-benzotriazolyl tetramethylbutylphenol is contained in the composition.

[0059] (Evaluation criteria for quick-drying property)

[0060] ◎: When the applied portion is touched after 30 seconds from the application to the skin, there is no feeling of moisture remaining, and the feeling of being close to the skin is felt.

[0061] O: When the applied portion is touched after 30 seconds from the application to the skin, there is almost no feeling of moisture remaining, and the feeling of being close to the skin is felt.

[0062] Δ: When the applied portion is touched after 30 seconds from the application to the skin, there is little feeling of moisture remaining, and the feeling of not being close to the skin is felt.

[0063] X: When the applied portion is touched after 30 seconds from the application to the skin, the feeling of moisture remaining is strong, and the feeling of not being close to the skin is felt.

[0064] (Evaluation criteria for tack-free property)

[0065] O: When the applied portion is touched after 30 seconds from the application to the skin, there is no feeling of tackiness.

[0066] X: When the applied portion is touched after 30 seconds from the application to the skin, there is a feeling of tackiness.

[0067] (Evaluation criteria for application uniformity)

[0068] The composition was weighed 3 g on artificial leather, and was uniformly applied using a bar coater. The applied portion was observed after 10 minutes from the application.

[0069] ◎: The concave-convex of the artificial leather was covered, and no unevenness was observed in the entire applied portion, and the application was uniform.

[0070] O: The unevenness of the artificial leather is covered, and unevenness is hardly observed in the entire application part, and the application is uniform.

[0071] Δ: The unevenness of the artificial leather is not covered, and unevenness is observed in part of the application part, and the application is not uniform.

[0072] X: The unevenness of the artificial leather is not covered, and unevenness is observed in the entire application part, and the application is not uniform.

[0073] [Table 1]

[0074] Ingredient name Example 1 Example 2 Comparative Example 1 Methylene bis-benzotriazolyl tetramethylbutylphenol 50% aqueous dispersion*1 3 3 3 Bis-PEG-18 methylether dimethyl silane*2 2 6 0 Polyoxyethylene-methylpolysiloxane copolymer*3 0.4 0.4 0.4 Purified water 94.6 90.6 96.6 Total amount 100 100 100 (B) / (A) 1.3 4 - Quick-drying property ○ ○ × Non-stickiness ○ ○ × Spreading property ◎ ◎ ×

[0075] *1 Tinosorb M (manufactured by BASF Corporation)

[0076] *2 2501 Cosmetic wax (manufactured by DOW CORNING TORAY CO., LTD.)

[0077] *3 SS-2804 (manufactured by DOW CORNING TORAY CO., LTD.)

[0078] As shown in Table 1, the composition containing the benzotriazole type ultraviolet absorber and the silicone wax is excellent in quick-drying property, tack-free property, and application uniformity compared with the composition not containing the silicone wax. As shown in Table 1, the application of the composition of the present application is uniform, and the composition is excellent in quick-drying property and tack-free property. Figure 1 As shown in Table 1, the composition containing the benzotriazole type ultraviolet absorber and the silicone wax is excellent in quick-drying property, tack-free property, and application uniformity compared with the composition not containing the silicone wax. As shown in Table 1, the application of the composition of the present application is uniform, and the composition is excellent in quick-drying property and tack-free property.

[0079] [Experimental Example 2]

[0080] An oil-in-water type composition having the composition shown in Table 2 below was prepared according to a conventional method, and the application uniformity and the application spreading easiness were evaluated. The evaluation criteria of the application uniformity were the same as those of Experimental Example 1.

[0081] (Evaluation Criteria of Application Spreading Easiness)

[0082] The composition was taken in an amount of 32.5 mg on a PMMA plate, and the application was spread.

[0083] O: The application can be smoothly spread, and no resistance is felt on the fingertips.

[0084] Δ: The application can be smoothly spread, and almost no resistance is felt on the fingertips.

[0085] X: The application cannot be smoothly spread, and resistance is felt on the fingertips.

[0086] [Table 2]

[0087] Ingredient name Example 3 Comparative Example 2 Methylene bis-benzotriazolyl tetramethylbutylphenol 50% aqueous dispersion*1 3 3 Silica*4 3.8 0 Polyoxyethylene-methylpolysiloxane copolymer*3 0.4 0.4 Purified water 92.8 96.6 Total amount 100 100 (B) / (A) 2.5 - Spreading property ○ × Ease of spreading ○ ×

[0088] *4 SIRICA MICRO BEAD P-500 (average particle diameter 2 μm, Lot: 048, manufactured by Nippon Shokubai Catalyst Co.)

[0089] As shown in Table 2, the composition containing the benzotriazole type ultraviolet absorber and the silica is excellent in application uniformity and application spreadability compared with the composition not containing the silica. The composition of the present application can be applied quickly because of easy application spreadability, and thus the ultraviolet absorber can exert the ultraviolet protection effect from immediately after the application, and can exert a high ultraviolet protection effect because of the application uniformity.

[0090] [Experimental Example 3]

[0091] An oil-in-water composition having the composition shown in Table 3 below was prepared according to a conventional method, and the quick-drying property, skin affinity, and emulsified state were evaluated. The evaluation criteria for the quick-drying property were the same as in Experimental Example 1.

[0092] (Evaluation Criteria for Skin Affinity)

[0093] The application part after the application with the fingers to the skin for 2 minutes and the surface of the skin not applied were compared in terms of the feeling of the fingers being caught.

[0094] ◎: The application part had no feeling of the fingers being caught compared with the surface of the skin not applied, and felt very smooth.

[0095] O: The application part had almost no feeling of the fingers being caught compared with the surface of the skin not applied, and felt smooth.

[0096] Δ: The application part felt the feeling of the fingers being caught compared with the surface of the skin not applied.

[0097] X: The application part strongly felt the feeling of the fingers being caught compared with the surface of the skin not applied.

[0098] (Evaluation Criteria 1 for Emulsified State: Smoothness)

[0099] The appearance of the emulsified state of the surface in contact with air of 80 g of the composition immediately after the preparation was observed by the naked eye.

[0100] ◎: No unevenness, very smooth.

[0101] O: No unevenness, smooth.

[0102] Δ: Slightly uneven.

[0103] X: unevenness

[0104] (Evaluation standard 2 for emulsified state: gloss)

[0105] The composition 80 g immediately after preparation was put in a 100 mL beaker, and the appearance of the emulsified state of the surface in contact with air was observed visually.

[0106] ◎: very glossy.

[0107] O: glossy.

[0108] Δ: slightly glossy.

[0109] X: not glossy.

[0110] [Table 3]

[0111]

[0112] *5 Decaglyn 5-ISV (manufactured by Shiseido Co., Ltd.)

[0113] *6 Tinosorb S (manufactured by BASF Co., Ltd.)

[0114] *7 Parsol MCX (manufactured by DSM Co., Ltd.)

[0115] *8 Parsol SLX (manufactured by DSM Co., Ltd.)

[0116] *9 Carbopol ETD2020 (manufactured by Lubrizol Co., Ltd.)

[0117] As shown in Table 3, the composition containing the benzotriazole type ultraviolet absorber and the silicone wax is excellent in the quick-drying property, the skin affinity, and the emulsified state, as compared with the composition not containing the silicone wax or containing a synthetic wax instead of the silicone wax as a non-silicone. The composition of the present application is high in the quick-drying property and the skin affinity, and therefore, the composition is less likely to adhere to clothes or skin from immediately after application, and a comfortable feeling of use can be given to the user.

[0118] [Experiment Example 4]

[0119] An oil-in-water type composition having the composition shown in Table 4 below was prepared according to a conventional method, and the skin affinity, the rubbing resistance, and the emulsified state were evaluated. The evaluation standards for the skin affinity and the emulsified state were the same as those of Experiment Example 3.

[0120] (Evaluation standard for rubbing resistance)

[0121] ◎: no change even when the applied part was rubbed back and forth 10 times with a finger after 2 minutes from the application to the skin.

[0122] O: After 2 minutes of application to the skin, no change was observed when the applied portion was rubbed back and forth 10 times with a finger.

[0123] Δ: After 2 minutes of application to the skin, lumps of the composition in the form of white stripes were observed when the applied portion was rubbed back and forth 10 times with a finger.

[0124] X: After 2 minutes of application to the skin, lumps of the composition in the form of large white stripes were observed when the applied portion was rubbed back and forth 10 times with a finger.

[0125] [Table 4]

[0126]

[0127] *10 Aerosil 200 (average particle diameter 12 nm, Lot: 616060881, manufactured by Aerosil Japan)

[0128] *11 SS-10V (manufactured by Nikko Chemicals)

[0129] *12 FZ-2233 (manufactured by DOW CORNING)

[0130] As shown in Table 4, the composition containing a benzotriazole-type ultraviolet absorber and silica having an average particle diameter of 2 μm was excellent in skin affinity, rubbing resistance, and emulsion state, as compared with the composition containing silica having an average particle diameter of 12 nm or the composition containing water at 45 mass%. The composition containing silica having an average particle diameter of 12 nm was very poor in emulsion state, and other evaluations could not be performed. The composition of the present application was high in skin affinity and rubbing resistance, and therefore, the composition was less likely to adhere to clothes or the skin from immediately after application, and a comfortable feeling of use could be given to the user, and these effects lasted for a long time.

[0131] [TEST EXAMPLE 5]

[0132] An oil-in-water composition having the composition shown in Table 5 below was prepared according to a conventional method, and the quick-drying property, skin affinity, secondary adhesion, and emulsion state were evaluated. The evaluation criteria for the quick-drying property were the same as in Test Example 1. The evaluation criteria for the skin affinity and emulsion state were the same as in Test Example 3.

[0133] (Evaluation Criteria for Secondary Adhesion)

[0134] One gram of the composition was applied to the central portion of the wrist to the elbow, and left to stand for 10 seconds. Fifty pieces of paper having a square shape with one side of 1 cm were dropped from a height of 10 cm from the applied portion. After the applied portion was temporarily pressed with a palm, the number of pieces of paper remaining on the applied portion was measured. Next, the applied portion was moved back and forth in the horizontal direction by a distance of 15 cm for 10 times with the applied portion kept facing upward, and the number of pieces of paper remaining on the applied portion was measured.

[0135] O: All of the paper sheets were peeled off from the application part when the arm was moved.

[0136] O: More than 90% of the paper sheets were peeled off from the application part when the arm was moved.

[0137] Δ: More than 90% of the paper sheets were peeled off from the application part when the arm was moved.

[0138] X: More than 90% of the paper sheets were peeled off from the application part when the arm was moved, and traces of the composition penetrating were observed in the attached paper sheets.

[0139] [Table 5]

[0140]

[0141] The following preparations were prepared according to the formulations described below. Formulation Examples 1 to 7 are all oil-in-water type cosmetic materials, and can be prepared by conventional methods. The numerical values indicate mass %.

[0142] Formulation Example 1 (Oil-in-water type UV gel)

[0143]

[0144] Formulation Example 2 (Oil-in-water type UV gel)

[0145]

[0146]

[0147] Formulation Example 3 (Oil-in-water type UV gel cream)

[0148]

[0149] Formulation Example 4 (Oil-in-water type UV gel cream)

[0150]

[0151]

[0152] Formulation Example 5 (Oil-in-water type colored UV cream)

[0153]

[0154]

[0155] Formulation Example 6 (Oil-in-water type UV cream)

[0156]

[0157]

[0158] Formulation Example 7 (Oil-in-water UV gel)

[0159]

Claims

1. A water-in-oil cosmetic material comprising (A) a benzotriazole type ultraviolet absorber, (B) one or more selected from polyether-modified silicone wax and silica, (C) water, and (D) one or more nonionic surfactants selected from polyglycerol fatty acids, sorbitan fatty acid esters, polyoxyethylene fatty acids, sucrose fatty acid esters, polysorbate esters, and polyoxyethylene phytosterols. The silica in component (B) has an average particle size of 1 μm or larger. Based on the total amount of the water-in-oil cosmetic material, the content of component (C) is 50% by mass or more.

2. The water-in-oil cosmetic material according to claim 1, comprising (E) an ultraviolet defense agent, wherein the ultraviolet defense agent does not include the ingredient (A).

3. The water-in-oil cosmetic material according to claim 1 or 2, wherein it contains (F) an acrylic polymer.

4. The water-in-oil cosmetic material according to claim 2, wherein, The component (E) is selected from one or more of the following: 2-ethylhexyl p-methoxycinnamate, dimethoxysiloxane diethyl benzoyl malonate, diethylaminohydroxybenzoyl benzoate, 2,4-bis{[4-(2-ethylhexoxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine, 2,4,6-tris[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazine, 4-tert-butyl-4'-methoxydibenzoylmethane, ethylhexyl salicylate, phenylbenzimidazole sulfonic acid, p-aminobenzoic acid, zinc oxide, and titanium oxide.

5. The water-in-oil cosmetic material according to claim 3, wherein, The component (F) is selected from one or more of carbomer, (acrylate / C10-30 alkyl acrylate) crosspolymer, (hydroxyethyl acrylate / sodium acryloyl dimethyl taurate) copolymer, (ammonium acryloyl dimethyl taurate / vinylpyrrolidone) copolymer and polyacrylamide.

6. The water-in-oil cosmetic material according to any one of claims 1 to 5, wherein, (B) The total content of component B is 0.01 to 10% by mass.

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