Thermoplastic compositions comprising recycled polycarbonate having improved water aging properties

Abstract

The thermoplastic composition includes: (a) about 5 wt % to about 95 wt % of at least one recycled polycarbonate, which includes post-consumer recycled (PCR) polycarbonate; and (b) about 0.01 wt % to about 2 wt % of an acid component. The post-consumer recycled (PCR) polycarbonate includes at least 10 mol % of -OH end group content. In certain aspects, the acid component includes monozinc phosphate (MZP), a liquid solution including phosphorous acid, or a combination thereof. The composition has improved water aging properties compared to conventional compositions including recycled polycarbonate.

Description

Technical Field

[0001] The present disclosure relates to thermoplastic compositions including recycled polycarbonate (PC) having improved hydro-aging properties. Background Art

[0002] The consumer electronics market is seeking a more sustainable (i.e., "greener") footprint in its products. The use of recycled plastics, such as post-consumer recycled (PCR) plastics, provides a straightforward solution in this market. The demand for PCR plastics is increasing, at least in part due to regulations such as the U.S. Federal Acquisition Regulation (FAR), which incorporates the use of the Electronic Product Environmental Assessment Tool (EPEAT). Unfortunately, almost all available PCR products are black or dark in color, which limits their desirability in certain applications that require white or bright colors. This color limitation is caused by the source of PCR resins, such as PCR-polycarbonate (PC), which are recycled from water bottles, which have a dark blue color.

[0003] Recently, consumer electronics (CE) customers are demanding colorable requirements in products. Sources of light-colored PCR-PC include, but are not limited to, automotive lamps, PC sheets, and discs (e.g., CD-Rom, DVD, etc.). Such PCR-PC sources have color properties (e.g., L, a, b values) comparable to original PC. Unfortunately, however, it has been found that clarified (transparent, clear) PCR-PC has water aging problems, as evidenced by the spots / flecks in clarified samples. Examples of water aging failures (destruction, failure, failure) are shown in Figures 1A and 1B. The water aging problem will cause a risk of long-term use failure in products that include such components, especially for unfilled PC components. Therefore, product developers need to find a solution to the water aging problem.

[0004] These and other disadvantages are addressed by aspects of the present disclosure. Summary of the invention

[0005] Aspects of the present disclosure relate to thermoplastic compositions comprising: (a) from about 5 wt % to about 95 wt % of at least one recycled polycarbonate, comprising post-consumer recycled (PCR) polycarbonate; and (b) from about 0.01 wt % to about 2 wt % of an acid component. The post-consumer recycled (PCR) polycarbonate comprises at least 10 mol % -OH end group content. In certain aspects, the acid component comprises monozinc phosphate (MZP), a liquid solution comprising phosphorous acid, or a combination thereof. The composition has improved water aging properties compared to conventional compositions comprising recycled polycarbonate. BRIEF DESCRIPTION OF THE DRAWINGS

[0006] In the accompanying drawings (which are not necessarily drawn to scale), like numbers may describe similar components in different views. Like numbers with different letter suffixes may represent different instances of similar components. The accompanying drawings generally illustrate various aspects discussed in this document by way of example and not limitation.

[0007] 1A and 1B are photographs showing samples of conventional PCR-PC compositions having poor water aging stability.

[0008] 2A-2E are photographs showing reference plaques used in quantifying the water aging stability of comparative and example compositions according to aspects of the present disclosure. DETAILED DESCRIPTION

[0009] After evaluating polycarbonate recycling processes, and in particular the use of alkaline soaking to remove coatings and washing steps using sulfuric acid (vitriol) as a neutralizing agent, various additives were included in the recycled PC formulations in an attempt to address water aging performance issues. In the present disclosure, it was discovered that the water aging issues can be significantly improved by including certain quenchers and / or chain extenders, either alone or in combination, thereby allowing for colorable recycled PC products that meet the cosmetic and other needs of CE consumers.

[0010] The present disclosure may be more readily understood by reference to the following detailed description of the disclosure and the examples included therein. In various aspects, the present disclosure relates to a thermoplastic composition comprising: (a) about 5 wt % to about 95 wt % of at least one recycled polycarbonate, the recycled polycarbonate comprising post-consumer recycled (PCR) polycarbonate; and (b) about 0.01 wt % to about 2 wt % of an acid component. The post-consumer recycled (PCR) polycarbonate comprises at least 10 mol % of -OH end group content. In certain aspects, the acid component comprises monozinc phosphate (MZP), a liquid solution comprising phosphorous acid, or a combination thereof. The composition has improved water aging properties compared to conventional compositions comprising recycled polycarbonate.

[0011] Before disclosing and describing the compounds, compositions, articles, systems, devices and / or methods of the present invention, it is to be understood that they are not limited to specific synthetic methods unless otherwise specified, or to specific reagents unless otherwise specified, as this can of course vary. It is also to be understood that the terminology used herein is for the purpose of describing specific aspects only and is not intended to be limiting.

[0012] The present disclosure covers various combinations of elements of the present disclosure, for example, combinations of elements from dependent claims that depend on the same independent claim.

[0013] Furthermore, it should be understood that, unless otherwise expressly stated, it is not intended that any method described herein be interpreted as requiring that its steps be performed in a particular order. Therefore, in the event that a method claim does not actually recite the order in which its steps are to be followed or that the steps are not otherwise specifically stated in the claims or specification to be limited to a particular order, no order is intended to be inferred in any respect. This applies to any possible non-express basis for interpretation, including: logical issues regarding the arrangement of steps or operational flows; ordinary meaning derived from grammatical organization or punctuation; and the number or type of aspects described in the specification.

[0014] All publications mentioned herein are incorporated herein by reference to disclose and describe the methods and / or materials in connection with which the publications are cited.

[0015] definition

[0016] It should also be understood that the terminology used herein is for the purpose of describing specific aspects only and is not intended to be limiting. As used in the specification and in the claims, the term "comprising" may include the aspects "consisting of" and "consisting essentially of". Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which the present disclosure belongs. In this specification and in the appended claims, reference will be made to a number of terms that will be defined herein.

[0017] As used in the specification and the appended claims, the singular forms "a," "an," and "the" include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to "an acid component" includes a mixture of two or more acid components.

[0018] As used herein, the term "combination" is inclusive of blends, mixtures, alloys, reaction products, and the like.

[0019] Ranges may be expressed herein as from a value (first value) to another value (second value). When such a range is expressed, the range includes one or both of the first value and the second value in some aspects. Similarly, when a value is expressed as an approximation by using the antecedent "about", it will be understood that the specific value forms another aspect. It will be further understood that the endpoints of each range are significant relative to the other endpoints and are independent of the other endpoints. It is also understood that many values ​​are disclosed herein, and in addition to the value itself, each value is also disclosed herein as "about" the specific value. For example, if the value "10" is disclosed, "about 10" is also disclosed. It is also understood that each unit between two specific units is also disclosed. For example, if 10 and 15 are disclosed, 11, 12, 13 and 14 are also disclosed.

[0020] As used herein, the terms "about" and "at or about" mean that the amount or value in question can be a specified value, approximately the specified value, or about the same as the specified value. As used herein, it is generally understood that, unless otherwise indicated or inferred, nominal values ​​represent ±10% variations. The term is intended to convey that similar values ​​promote equivalent results or effects listed in the claims. That is, it is understood that amounts, dimensions, formulations, parameters, and other quantities and features are not and need not be exact, but may be approximate and / or larger or smaller as needed, reflecting tolerances, conversion factors, rounding, measurement errors, etc., as well as other factors known to those skilled in the art. Typically, amounts, dimensions, formulations, parameters, or other quantities or features are "about" or "approximate", whether or not explicitly stated as such. It is understood that, in the case of using "about" before a quantitative value, unless otherwise specifically stated, the parameter also includes the specific quantitative value itself.

[0021] Disclosed are components to be used to prepare the compositions of the present disclosure and the compositions themselves to be used in the methods disclosed herein. These and other materials are disclosed herein, and it is understood that when the combinations, subsets, interactions, groups, etc. of these materials are disclosed, although it is not possible to explicitly disclose specific reference to each different individual and set combination and arrangement of these compounds, each is specifically considered and described herein. For example, if a specific compound is disclosed and discussed, and many modifications that can be made to many molecules including the compound are discussed, then each combination and arrangement of the compound and possible modifications are specifically considered, unless explicitly indicated to the contrary. Therefore, if a class of molecules A, B and C and a class of molecules D, E and F are disclosed and an example AD of the combined molecule is disclosed, then even if each is not listed separately, each is also considered individually and collectively, meaning that the combination AE, AF, BD, BE, BF, CD, CE and CF are considered to be disclosed. Similarly, any subset or combination of these is also disclosed. Therefore, for example, the subgroups of AE, BF and CE will be considered to be disclosed. This concept applies to all aspects of the application, including but not limited to the steps in the method for preparing and using the composition of the present disclosure. Thus, if there are a variety of additional steps that can be performed it is understood that each of these additional steps can be performed with any specific aspect or combination of aspects of the methods of the present disclosure.

[0022] References in the specification and the appended claims to parts by weight of a particular element or component in a composition or article represent the weight relationship between said element or component and any other elements or components in the composition or article expressed in parts by weight. Thus, in a compound containing 2 parts by weight of component X and 5 parts by weight of component Y, X and Y are present in a weight ratio of 2:5, and are present in this ratio regardless of whether additional components are present in the compound.

[0023] Unless expressly stated to the contrary, the weight percentage of a component is based on the total weight of the formulation or composition in which the component is included.

[0024] As used herein, the terms "BisA," "BPA," or "bisphenol A," which may be used interchangeably, refer to a compound having a structure represented by the following formula:

[0025]

[0026] BisA may also be referred to by the name 4,4'-(propane-2,2-diyl)diphenol; p,p'-isopropylidene bisphenol; or 2,2-bis(4-hydroxyphenyl)propane. BisA has CAS# 80-05-7.

[0027] As used herein, "polycarbonate" refers to an oligomer or polymer comprising the residues of one or more dihydroxy compounds, such as dihydroxy aromatic compounds, connected by carbonate bonds; it also encompasses homopolycarbonates, copolycarbonates and (co)polyester carbonates.

[0028] The terms "residue" and "structural unit" used with respect to components of a polymer are synonymous throughout the specification.

[0029] As used herein, the terms "weight percent," "weight % (wt%)," and "weight % (wt.%)," which may be used interchangeably unless otherwise indicated, represent the weight percent of a given component based on the total weight of the composition. That is, all weight % values ​​are based on the total weight of the composition, unless otherwise indicated. It should be understood that the sum of the weight % values ​​of all components in a disclosed composition or formulation equals 100.

[0030] Unless otherwise indicated herein to the contrary, all test standards are the most recent standards in effect at the time this application is filed.

[0031] Each of the materials disclosed herein is either commercially available and / or methods for preparing the same are known to those skilled in the art.

[0032] It is understood that the compositions disclosed herein have certain functions. Certain structural requirements for performing the disclosed functions are disclosed herein, and it is understood that there are multiple structures related to the disclosed structures that can perform the same function, and these structures will generally achieve the same results.

[0033] Thermoplastic composition

[0034] Aspects of the present disclosure relate to: (a) about 5 wt % to about 95 wt % of at least one recycled polycarbonate (PC); and (b) about 0.01 wt % to about 2 wt % of an acid component. The at least one recycled PC comprises post-consumer recycled (PCR) polycarbonate. The PCR polycarbonate comprises at least 10 mol % -OH end group content. The -OH end group content can be determined according to conventional methods known to those skilled in the art.

[0035] The combined weight percent values ​​of all components do not exceed 100 weight percent, and all weight percent values ​​are based on the total weight of the composition.

[0036] As described, the at least one recycled PC comprises post-consumer recycled (PCR) polycarbonate. The recycled (e.g., PCR) polycarbonate can be distinguished from virgin polycarbonate by including at least 10 mol % of -OH end group content in the polycarbonate. In some aspects, the PCR polycarbonate includes 10 mol % to 35 mol % of -OH end group content in the polycarbonate. The recycled PC can be clear or colored. Clear recycled PC can be derived from, for example, water bottles, recycled PC sheets, automotive headlights, and optical discs (e.g., one or more of compact discs (compact discs) (CDs), digital versatile discs (DVDs), and Blu-ray discs). An exemplary source of colored PC is a water bottle.

[0037] In certain aspects, the composition further comprises from greater than 0 wt % to about 90 wt % of a non-recycled PC component. Examples of non-recycled PC include virgin PC, PC homopolymers, PC copolymers, and combinations thereof. Virgin PC and other PC products are available from SABIC.

[0038] In specific aspects, the composition further includes a polycarbonate-siloxane (PC-Si) copolymer. In some aspects, the PC-Si copolymer can have a siloxane content of about 5 wt % to about 35 wt %. In other aspects, the PC-Si copolymer has a siloxane content of about 10-30 wt %, or about 15 wt % to about 25 wt %, or about 20 wt %. Exemplary PC-Si copolymers include SABIC EXL copolymers.

[0039] In some aspects, the acid component can include monozinc phosphate (MZP), a liquid solution including phosphorous acid, or a combination thereof.

[0040] In a further aspect, the composition includes greater than 0 wt % to about 5 wt % of an epoxy stabilizer.Exemplary epoxy stabilizers include, but are not limited to, epoxy chain extenders such as Joncryl ADR 4368CS available from BASF.

[0041] In yet a further aspect, the composition includes greater than 0 wt % to about 5 wt % of at least one additional stabilizer. The additional stabilizer may include, but is not limited to, a UV stabilizer or a thermal stabilizer.

[0042] In specific aspects, the composition includes both monozinc phosphate (as the acid component) and an epoxy stabilizer. In other aspects, the composition includes a liquid solution comprising phosphorous acid (as the acid component), but does not include an epoxy stabilizer.

[0043] Properties of the thermoplastic composition

[0044] Compared to a comparative composition not including the acid component, the thermoplastic composition according to aspects of the present disclosure has improved water aging stability after exposure to 85°C and 85% relative humidity (RH) for 3 days. The improved water aging stability can be visually observed according to the method described herein and can be characterized by at least one grade improvement compared to a comparative composition not including the acid component.

[0045] In some aspects, the composition includes monozinc phosphate and an epoxy stabilizer and has an improved L* color value compared to a comparative composition not including the epoxy stabilizer, as tested with a 10 degree (°) observer and a D65 illuminant according to ASTM 2244. In certain aspects, the L* color value is improved by at least 3%, or at least 4%, or at least 5%, or at least 6%, or at least 7%, or at least 8%, or at least 9%, or at least 10%, or up to 15%, or up to 20%, or 3-20%, or 3-15%, or 3-10% compared to a comparative composition not including the epoxy stabilizer.

[0046] In a further aspect, the composition includes monozinc phosphate and an epoxy stabilizer and has improved transmittance as tested according to ASTM D 1003 compared to a comparative composition not including the epoxy stabilizer. In a specific aspect, the transmittance is improved by at least 10%, or at least 15%, or at least 20%, or at least 30%, or at least 35%, or at least 40%, or up to 50%, or 10-50%, or 10-40%, or 10-35% compared to a comparative composition not including the epoxy stabilizer.

[0047] In some aspects, the composition includes monozinc phosphate and an epoxy stabilizer and has a reduced yellowness index (YI) as tested according to ASTM D2244 compared to a comparative composition not including the epoxy stabilizer. In other aspects, the YI is reduced by at least 10%, or at least 15%, or at least 20%, or at least 25%, or at least 30%, or at least 35%, or at least 40%, or at least 45%, or at least 50%, or up to 60%, or up to 75%, or 10-75%, or 10-60%, or 15-75%, or 15-60%, compared to a comparative composition not including the epoxy stabilizer.

[0048] Manufacturing method

[0049] One or more of the foregoing components described herein may first be dry blended with each other, or with any combination of the foregoing components, and then fed into the extruder from one or more feeders, or fed into the extruder individually from one or more feeders. Fillers used in the composition, if included, may also first be processed into a masterbatch and then fed into the extruder. The components may be fed into the extruder from a throat hopper or any side feeder.

[0050] The extruder used in the present disclosure can have a single screw, multiple screws, intermeshing co-rotating or counter-rotating screws, non-intermeshing co-rotating or counter-rotating screws, a reciprocating screw, a pinned screw, a screen screw, a pinned barrel, a roller, a ram, a helical rotor, a co-kneader, a disc-pack processor, various other types of extrusion equipment, or a combination comprising at least one of the foregoing.

[0051] The components may also be mixed together and then melt blended to form the thermoplastic composition. Melt blending of the components involves the use of shear forces, extensional forces, compression forces, ultrasonic energy, electromagnetic energy, thermal energy, or a combination comprising at least one of the foregoing forces or energy forms.

[0052] The barrel temperature on the extruder during compounding can be set at a temperature at which at least a portion of the polymer has reached a temperature greater than or equal to about the melting temperature if the resin is a semi-crystalline organic polymer, or at the flow point (e.g., glass transition temperature) if the resin is an amorphous resin.

[0053] If desired, the mixture including the aforementioned components can be subjected to multiple blending and molding steps. For example, the thermoplastic composition can be first extruded and molded into pellets. The pellets can then be fed into a molding machine where it can be molded into any desired shape or product. Alternatively, the thermoplastic composition issued from a single melt blender can be formed into sheets or strands and subjected to post-extrusion processes such as annealing, uniaxial or biaxial orientation.

[0054] In some aspects, the temperature of the melt in the present method can be kept as low as possible to avoid excessive thermal degradation of the components. In some aspects, the melt temperature is maintained between about 230°C and about 350°C, although higher temperatures can be used, provided that the residence time of the resin in the processing equipment is kept relatively short. In some aspects, the melt-processed composition leaves the processing equipment such as an extruder through a small exit hole in the die. The resulting strands of molten resin can be cooled by passing the strands through a water bath. The cooled strands can be cut into pellets for packaging and further processing (transportation, handling).

[0055] Manufacturing of products

[0056] In certain aspects, the present disclosure relates to shaped, formed or molded articles comprising the thermoplastic composition. The thermoplastic composition can be molded into useful shaped articles by various means such as injection molding, extrusion, rotational molding, blow molding and thermoforming to form articles and structural parts such as: personal or commercial electronic devices, including but not limited to cellular phones, tablet computers, personal computers, notebook and portable computers and other such devices, medical applications, RFID applications, automotive applications, etc. In a further aspect, the article is extrusion molded. In a further aspect, the article is injection molded.

[0057] The present disclosure covers various combinations of elements of the present disclosure, such as combinations of elements from dependent claims that depend on the same independent claim.

[0058] Aspects of Public Content

[0059] In various aspects, the present disclosure relates to and includes at least the following aspects.

[0060] Aspect 1. A thermoplastic composition comprising, consisting of, or consisting essentially of:

[0061] (a) from about 5 weight percent to about 95 weight percent of at least one recycled polycarbonate; and

[0062] (b) from about 0.01% to about 2% by weight of an acid component,

[0063] The combined weight percentage values ​​of all components do not exceed 100 weight %, and all weight percentage values ​​are based on the total weight of the composition.

[0064] Aspect 2. The thermoplastic composition of aspect 1, wherein the at least one recycled polycarbonate comprises post-consumer recycled (PCR) polycarbonate.

[0065] Aspect 3. The thermoplastic composition of aspect 2, wherein the PCR polycarbonate is clear or colored.

[0066] Aspect 4. The thermoplastic composition of any one of aspects 1 to 3, wherein the composition further comprises greater than 0 wt % to about 90 wt % of a non-recycled polycarbonate component.

[0067] Aspect 5. The thermoplastic composition of aspect 4, wherein the non-recycled polycarbonate component comprises virgin polycarbonate, a polycarbonate homopolymer, a polycarbonate copolymer, or a combination thereof.

[0068] Aspect 6. The thermoplastic composition according to any one of aspects 1 to 5, wherein the composition further comprises a polycarbonate-siloxane copolymer.

[0069] Aspect 7. The thermoplastic composition of aspect 6, wherein the polycarbonate-siloxane copolymer has a siloxane content of about 15 wt % to about 25 wt %.

[0070] Aspect 8. The thermoplastic composition according to any one of aspects 1 to 7, wherein the acid component comprises monozinc phosphate (MZP), a liquid solution comprising phosphorous acid, or a combination thereof.

[0071] Aspect 9. The thermoplastic composition according to any one of aspects 1 to 8, wherein the composition further comprises greater than 0 wt % to about 5 wt % of an epoxy stabilizer.

[0072] Aspect 10. The thermoplastic composition of any one of aspects 1 to 9, wherein the composition further comprises greater than 0 wt % to about 5 wt % of at least one additional stabilizer.

[0073] Aspect 11. The thermoplastic composition of aspect 10, wherein the at least one additional stabilizer comprises a UV stabilizer or a thermal stabilizer.

[0074] Aspect 12. The thermoplastic composition according to any one of aspects 1 to 11, wherein the composition comprises monozinc phosphate and an epoxy stabilizer.

[0075] Aspect 13. The thermoplastic composition of any one of aspects 1 to 12, wherein the composition has improved water aging stability after exposure to 85° C. and 85% relative humidity (RH) for 3 days compared to a comparative composition not comprising the acid component.

[0076] Aspect 14. The thermoplastic composition of any one of Aspects 1 to 13, wherein the composition comprises monozinc phosphate and an epoxy stabilizer and has an improved L* color value as tested according to ASTM 2244 with a 10 degree (°) observer and a D65 illuminant, compared to a comparative composition not comprising the epoxy stabilizer.

[0077] Aspect 15. The thermoplastic composition of any one of aspects 1 to 14, wherein the composition comprises monozinc phosphate and an epoxy stabilizer and has improved transmittance as tested according to ASTM D1003 compared to a comparative composition not comprising the epoxy stabilizer.

[0078] Aspect 16. The thermoplastic composition of any one of aspects 1 to 15, wherein the composition comprises monozinc phosphate and an epoxy stabilizer and has a reduced yellowness index as tested according to ASTM D2244 compared to a comparative composition not comprising the epoxy stabilizer.

[0079] Aspect 17. A thermoplastic composition comprising, consisting of, or consisting essentially of:

[0080] (a) from about 5 weight percent to about 95 weight percent of at least one recycled polycarbonate, the recycled polycarbonate comprising post-consumer recycled (PCR) polycarbonate; and

[0081] (b) from about 0.01% to about 2% by weight of an acid component,

[0082] wherein the PCR polycarbonate comprises at least 10 mol % -OH end group content, and

[0083] The combined weight percentage values ​​of all components do not exceed 100 weight %, and all weight percentage values ​​are based on the total weight of the composition.

[0084] Aspect 18. The thermoplastic composition of aspect 17, wherein the PCR polycarbonate comprises 10 mol % to 35 mol % -OH end group content.

[0085] Aspect 19. The thermoplastic composition of aspect 17 or 18, wherein the PCR polycarbonate is recycled from one or more of a water bottle, a compact disc, an automobile headlight, or a sheet film.

[0086] Aspect 20. The thermoplastic composition of any one of aspects 17 to 19, wherein the composition further comprises greater than 0 wt % to about 90 wt % of a non-recycled polycarbonate component.

[0087] Aspect 21. The thermoplastic composition of aspect 20, wherein the non-recycled polycarbonate component comprises virgin polycarbonate, a polycarbonate homopolymer, a polycarbonate copolymer, or a combination thereof.

[0088] Aspect 22. The thermoplastic composition according to any one of aspects 17 to 21, wherein the composition further comprises a polycarbonate-siloxane copolymer.

[0089] Aspect 23. The thermoplastic composition of aspect 22, wherein the polycarbonate-siloxane copolymer has a siloxane content of about 15 wt % to about 25 wt %.

[0090] Aspect 24. The thermoplastic composition of any one of aspects 17 to 23, wherein the acid component comprises monozinc phosphate (MZP), a liquid solution comprising phosphorous acid, or a combination thereof.

[0091] Aspect 25. The thermoplastic composition of any one of Aspects 17 to 24, wherein the composition further comprises greater than 0 wt % to about 5 wt % of an epoxy stabilizer.

[0092] Aspect 26. The thermoplastic composition of any one of Aspects 17 to 25, wherein the composition further comprises greater than 0 wt % to about 5 wt % of at least one additional stabilizer.

[0093] Aspect 27. The thermoplastic composition of aspect 26, wherein the at least one additional stabilizer comprises a UV stabilizer or a thermal stabilizer.

[0094] Aspect 28. The thermoplastic composition according to any one of aspects 17 to 27, wherein the composition comprises monozinc phosphate and an epoxy stabilizer.

[0095] Aspect 29. The thermoplastic composition of any one of Aspects 17 to 28, wherein the composition has improved water aging stability after exposure to 85° C. and 85% relative humidity (RH) for 3 days compared to a comparative composition not comprising the acid component.

[0096] Aspect 30. The thermoplastic composition of any one of Aspects 17 to 29, wherein the composition comprises monozinc phosphate and an epoxy stabilizer and has an improved L* color value as tested according to ASTM 2244 with a 10 degree (°) observer and a D65 illuminant compared to a comparative composition not comprising the epoxy stabilizer.

[0097] Aspect 31. The thermoplastic composition of any one of Aspects 17 to 30, wherein the composition comprises monozinc phosphate and an epoxy stabilizer and: (1) has improved transmittance as tested according to ASTM D1003 compared to a comparative composition not comprising the epoxy stabilizer; or (2) has a reduced yellowness index as tested according to ASTM D2244 compared to a comparative composition not comprising the epoxy stabilizer.

[0098] Example

[0099] The following examples are given to provide a person of ordinary skill in the art with a complete disclosure and description of how to prepare and evaluate the compounds, compositions, articles, devices and / or methods claimed herein, and are intended to be purely exemplary and not intended to limit the present disclosure. Efforts have been made to ensure accuracy with respect to numbers (e.g., amounts, temperatures, etc.), but some errors and deviations should be considered. Unless otherwise stated, parts are by weight, temperatures are in ° C or are ambient temperatures, and pressures are at or near atmospheric pressure. Unless otherwise stated, percentages relating to compositions are expressed in % by weight.

[0100] There are many variations and combinations of reaction conditions such as component concentrations, desired solvents, solvent mixtures, temperature, pressure and other reaction ranges and conditions that can be used to optimize the product purity and yield obtained from the described methods. Only reasonable and routine experimentation will be required to optimize such process conditions.

[0101] The materials used in the comparative compositions and example compositions described herein are listed in Table 1:

[0102] Table 1 – Materials

[0103]

[0104] The granules were compounded from the composition according to conventional techniques. PCR-PC was fed into the throat separately from the other components. The composition was compounded using an output of 40 kg / hr, a screw speed of 400 RPM, a vacuum of 0.08 MPa, a barrel temperature of 260-270°C, and a die temperature of 270°C.

[0105] The pellets were injection molded according to the conditions given in Table 2:

[0106] Table 2 – Injection molding parameters

[0107]

[0108] Tensile strength was measured according to ASTM D638 at a test speed of 5 mm / min. Impact testing was performed according to ASTM D256 and ASTM D4812 at room temperature and with a pendulum energy of 5 lbf / ft. Flexural properties were tested according to ASTM 790 at a test speed of 1.27 mm / min and a part thickness of 3.2 mm. Melt volume rate (MVR) was measured according to ASTM D1238 using pellet samples dried at 80°C for 4 hours (hr). Color (L*, a*, b*) was measured using method ASTM 2244 with a 10° observer and a D65 light source.

[0109] Water aging performance was observed visually with the naked eye. Performance was qualitatively evaluated by visually observing the aged injection molded plates and applying a 1-5 grade based on the reference aged plates; the reference aged plates are shown in Figures 2A (Grade 1), 2B (Grade 2), 2C (Grade 3), 2D (Grade 4), and 2E (Grade 5). Before visual inspection, the injection molded plates were placed in a water aging oven at 85 degrees Celsius (°C) and 85% relative humidity (RH) for 72 hours. The water aging performance of the aged plates was evaluated by having 3 to 5 operators apply the rating scale to each sample, where Grade 1 represents the worst water stability (more aging spots) and Grade 5 represents the best water stability (fewer aging spots). The ratings of all samples of each composition were then averaged to obtain an average water aging grade.

[0110] Table 3 lists the comparative compositions and example compositions formed. All values ​​in Table 3 and other tables describing the formed compositions are provided in weight % (wt %):

[0111] Table 3 - Comparative and Example Compositions

[0112] Components C1 Ex1 Ex2 C3 Ex3 Ex4 C2 PCR-PC 90 89.9 89.7 89.5 89.4 89.2 89.9 PC (original) 10 10 10 10 10 10 10 ZGar 0.1 0.3 0.1 0.3 Joncryl ADR(Epoxy) 0.5 0.5 0.5 DHT-4T, hydrotalcite 0.1

[0113] Composition C1 is a control composition including 90% PCR-PC. Ex1 and Ex2 include MZP (which is a weak acid) as a stabilizer. C3 includes epoxy as a chain extender. Ex3 and Ex4 combine both the stabilizer (acid component) and epoxy. C2 is a control composition including hydrotalcite, which is a weakly basic component.

[0114] The color properties of the compositions are provided in Table 4:

[0115] Table 4 - Properties of the compositions of Table 3

[0116]

[0117] Comparing C1, C2, Ex1 and Ex2, it is observed that water aging performance is highly improved by adding an acid component (e.g., MZP) instead of hydrotalcite. These results indicate that post-consumer recycled components are more sensitive to alkaline additives and cause water aging spots. Keeping the formulation weakly acidic greatly improves this problem. However, the introduction of acid, especially at high loadings (e.g., Ex2 with 0.3 wt. % MZP), introduces yellowness issues to the samples, which is unacceptable for applications requiring light or transparent colors. This is observed in the YI values ​​in Table 3.

[0118] Potential solutions to address the yellowness issue were considered. First, epoxy was added. Comparing compositions C1 and C3, L* increased from 91 to 92, transmittance increased from 80% to 83%, and YI decreased from 5.3 to 4.2. Comparing Ex1 and Ex3, the addition of epoxy improved L* (88 to 91), transmittance (74% to 82%), and YI (decreased from 15.3 to 7.5). Further, even with high MZP loading (Ex4), including epoxy helped improve L* and transmittance as well as reduce YI. And notably, including epoxy also improved the problem of water aging spots.

[0119] Further comparative compositions and example compositions were formed according to Table 5:

[0120] Table 5 - Comparative and Example Compositions

[0121] Components C4 Ex5 Ex6 Ex7 Ex8 PCR-PC 90 89.95 89.9 89.95 89.9 PC (original) 10 10 10 10 10 ZGar 0.05 0.1 Phosphorous acid, 45% 0.05 0.1

[0122] The properties of these compositions are provided in Table 6:

[0123] Table 6 - Properties of the compositions of Table 5

[0124]

[0125] Note that compositions C4 and Ex6 have the same composition as C1 and Ex1, respectively. The different water aging rating values ​​can be attributed to different batches of PCR-PC, because there may be quality differences between batches. Phosphorous acid liquid solutions were studied as substitutes for MZP (which is solid) in Ex7 and Ex8. Phosphorous acid liquid solutions not only improve the color (yellowness problem), but also improve physical properties. Comparing Ex5 and Ex6 (which include MZP) with Ex7 and Ex8 (including phosphorous acid liquid solutions), the color performance of Ex7 and Ex8 is improved, with higher L*, transmittance, lower b*, lower YI and lower haze - which is comparable to the control composition C4. The color after water aging also shows similar performance. In addition, as observed from the MFR change data, liquid phosphorous acid helps to improve the thermal stability of PCR compounds. Finally, as shown in the water aging rating, the use of liquid phosphorous acid can - like MZP - improve the problem of water aging spots (compare Ex7 and Ex8 with C4).

[0126] Based on this data, it appears that the water aging performance of PCR based components can be improved by combining a solid acid component (eg, MZP) with an epoxy or by using a liquid acid component.

[0127] Further compositions have been prepared to evaluate the effect of including a PC-siloxane copolymer (e.g., EXL from SABIC) on the composition. The compositions are shown in Table 7:

[0128] Table 7 - PC-Si copolymer compositions

[0129]

[0130] Evaluation of the properties of the compositions of Table 7 is ongoing. It is believed that example compositions Ex9 and Ex10 will have even further improved water aging stability properties.

[0131] The above description is intended to be illustrative rather than restrictive. For example, the examples described above (or one or more aspects thereof) can be used in combination with each other. For example, those of ordinary skill in the art can use other aspects after reading the above description. An abstract is provided to comply with 37C.FR§1.72(b) to allow readers to quickly determine the essence of the technical disclosure. According to this understanding, it is believed that it will not be used to interpret or limit the scope or meaning of the claims. In addition, in the above-mentioned specific embodiments, various features can be classified together to simplify the present disclosure. This should not be interpreted as an intention that the disclosed features that are not claimed for protection are essential to any claim. On the contrary, the subject matter of the present invention may be less than all the features of the specific disclosed aspects. Therefore, the attached claims are thus incorporated into the specific embodiments as examples or aspects, wherein each claim is independently used as a separate aspect, and it is expected that such aspects can be combined with each other in various combinations or arrangements. The scope of the present disclosure should be determined with reference to the attached claims and the full scope of the equivalents given by these claims.

Claims

1. A thermoplastic composition comprising: (a) 5 to 95 wt. % of at least one recycled polycarbonate comprising post-consumer recycled PCR polycarbonate; (b) 0.01% to 2% by weight of monozinc phosphate; and (c) greater than 0 wt % to 5 wt % of an epoxy stabilizer, wherein the epoxy stabilizer is an epoxy chain extender, wherein the PCR polycarbonate comprises at least 10 mol % -OH end group content, and The combined weight percentage values ​​of all components do not exceed 100 weight %, and all weight percentage values ​​are based on the total weight of the composition.

2. The thermoplastic composition of claim 1, wherein the PCR polycarbonate comprises a -OH end group content of 10 to 35 mol%.

3. The thermoplastic composition of claim 1, wherein the PCR polycarbonate is recycled from one or more of a water bottle, a compact disc, an automobile headlight, or a sheet film.

4. The thermoplastic composition of claim 1, wherein the composition further comprises greater than 0 wt% to 90 wt% of a non-recycled polycarbonate component.

5. The thermoplastic composition of claim 4, wherein the non-recycled polycarbonate component comprises virgin polycarbonate, a polycarbonate homopolymer, a polycarbonate copolymer, or a combination thereof.

6. The thermoplastic composition of claim 1, wherein the composition further comprises a polycarbonate-siloxane copolymer.

7. The thermoplastic composition of claim 6, wherein the polycarbonate-siloxane copolymer has a siloxane content of 15 to 25 weight percent.

8. The thermoplastic composition of claim 1, wherein the composition further comprises greater than 0 wt% to 5 wt% of at least one additional stabilizer.

9. The thermoplastic composition of claim 8, wherein the at least one additional stabilizer comprises a UV stabilizer or a heat stabilizer.

10. The thermoplastic composition of any one of claims 1 to 9, wherein the composition has improved water aging stability after exposure to 85°C and 85% relative humidity (RH) for 3 days compared to a comparative composition not comprising monozinc phosphate.

11. The thermoplastic composition of any one of claims 1 to 9, wherein the composition has an improved L* color value as tested according to ASTM 2244 with a 10 degree (°) observer and a D65 illuminant compared to a comparative composition not comprising the epoxy stabilizer.

12. The thermoplastic composition of any one of claims 1 to 9, wherein (1) the composition has improved transmittance as compared to a comparative composition not comprising the epoxy stabilizer, as tested according to ASTM D1003; or (2) the composition has a reduced yellowness index as compared to a comparative composition not comprising the epoxy stabilizer, as tested according to ASTM D2244.

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