A method and device for measuring adiabatic temperature rise data and an adiabatic accelerating calorimeter

Abstract

The application provides a kind of adiabatic temperature rise data measurement method, device and adiabatic accelerating calorimeter, when measuring the adiabatic temperature rise data of high viscosity system material, colloid material or solid material, by adding intermediate material in the original measurement system, the intermediate material mixes with the measured material, the viscosity of the original measured high viscosity system material is low or the colloid and solid become continuous phase, eliminate the temperature gradient of the measured material in the original measurement system, the temperature inside and outside the ball is uniform, the measurement result of uniform mixture is more accurate and reliable, then the adiabatic temperature rise test result of uniform mixture is corrected according to the thermal parameter information of intermediate material, measured material and test ball, the adiabatic temperature rise test data of measured material is obtained, after actual test verification, the adiabatic temperature rise test data of measured material obtained after correction has the precision meeting the demand.

Description

Technical Field

[0001] This application relates to the field of chemical testing technology, and in particular to a method, apparatus and adiabatic accelerated calorimeter for measuring adiabatic temperature rise data. Background Technology

[0002] Currently, adiabatic accelerated calorimeters are commonly used to measure the adiabatic temperature rise of substances. However, situations frequently arise where the tested substances are highly viscous systems, colloidal substances, or solid substances. Because adiabatic accelerated calorimeters often lack stirring or cannot achieve ideal mixing results for highly viscous systems, colloidal substances, or solid substances, and because these substances have limited heat transfer during testing (i.e., a temperature gradient exists within the measurement system, with different temperatures on the outside and inside of the substance), the measured data contains errors compared to the actual situation.

[0003] Taking a certain polyether polyol as the test substance as an example, following the experimental procedure of the adiabatic accelerated calorimeter described above, a certain amount of the polyether polyol is loaded into a test sphere. This test sphere is a special type configured in the adiabatic accelerated calorimeter, with a thermocouple slot at the bottom. An internal insertion tube is inserted into the center of the test substance. After connecting the test sphere to the internal insertion tube, the thermocouple of the adiabatic accelerated calorimeter is connected to the thermocouple slot, and an external thermocouple is connected. This external thermocouple is inserted into the center of the test substance through the internal insertion tube. Then, the top cover, insulation cavity, etc., are installed. After completing the above operations, the test software compatible with the adiabatic accelerated calorimeter is opened to conduct the experiment. The experimental results are as follows: Figure 1 As shown: The experiment will stop between 600 and 700 minutes because the set pressure limit has been exceeded to ensure experimental safety.

[0004] During the experiment, the inventors discovered that when using the adiabatic accelerated calorimeter, the outer temperature of the test sphere was 250°C, while the inner temperature was 260°C, a 10°C difference that severely affected the accuracy of the test results. Using the outer temperature for data processing resulted in unconservative results; using the inner temperature for data processing resulted in overly conservative results.

[0005] Given the problems in the above example, how to eliminate this influence and accurately measure the adiabatic temperature rise data of the system is an urgent problem to be solved. Summary of the Invention

[0006] The technical problem to be solved by this application is that there are large errors in the existing data for measuring the adiabatic temperature rise of high-viscosity substances, colloidal substances or solid substances. To this end, this application proposes a method, device and adiabatic accelerating calorimeter for measuring adiabatic temperature rise data.

[0007] To address the aforementioned technical problems, this application provides the following technical solution:

[0008] In a first aspect, this application provides a method for measuring adiabatic temperature rise data, used to measure the adiabatic temperature rise data of high-viscosity substances, colloidal substances, or solid substances, including:

[0009] Obtain the property information of the substance to be tested;

[0010] An intermediate substance is determined based on the property information of the analyte. The intermediate substance meets the following conditions: if the analyte is a high-viscosity system, the intermediate substance is used to reduce the viscosity of the analyte when mixed with it; if the analyte is a colloidal or solid substance, the intermediate substance is used to transform the analyte into a continuous phase when mixed with it; the intermediate substance does not react with the analyte, and the intermediate substance has stable chemical properties within the measurement temperature range.

[0011] The homogeneous mixture obtained by mixing the intermediate substance and the substance to be tested is placed in the test sphere of an adiabatic accelerated calorimeter to obtain the adiabatic temperature rise test result of the homogeneous mixture.

[0012] The adiabatic temperature rise test results of the homogeneous mixture are corrected based on the thermal parameter information of the intermediate substance, the substance to be tested, and the test ball to obtain the adiabatic temperature rise test data of the substance to be tested.

[0013] In this invention, the high-viscosity system generally refers to a system with a viscosity greater than 800 cp at 25°C; the intermediate substance having stable chemical properties within the measurement temperature range mainly means that the intermediate substance will not decompose and will not react with the test substance and the test ball within the measurement temperature range.

[0014] Some methods for measuring adiabatic temperature rise data, wherein the adiabatic temperature rise test results of the homogeneous mixture are corrected based on the thermal parameter information of the intermediate substance, the substance to be tested, and the test sphere to obtain the adiabatic temperature rise test data of the substance to be tested, include:

[0015] Obtain the mass and specific heat capacity of the intermediate substance;

[0016] Obtain the mass and specific heat capacity of the test ball;

[0017] Obtain the mass and specific heat capacity of the substance to be tested;

[0018] The thermal inertia correction value of the test substance is determined based on the mass and specific heat capacity of the intermediate substance, the mass and specific heat capacity of the test ball, and the mass and specific heat capacity of the test substance.

[0019] The adiabatic temperature rise test results of the homogeneous mixture are multiplied by the thermal inertia correction value to obtain the adiabatic temperature rise test data.

[0020] Some methods for measuring adiabatic temperature rise data, wherein determining the thermal inertia correction value of the test substance based on the mass and specific heat capacity of the intermediate substance, the mass and specific heat capacity of the test sphere, and the mass and specific heat capacity of the test substance, includes:

[0021] Phi'=1+f(m b C b m w C w m s C s );

[0022] Where, f(m) b C b m w C w m s C s ) indicates that it contains parameter m b C b m w C w m s C s The function, where m b C represents the mass of the test ball. b The specific heat capacity of the test sphere is represented by m. w C represents the mass of the intermediate substance. w m represents the specific heat capacity of the intermediate substance. s C represents the mass of the substance being tested. s This indicates the specific heat capacity of the substance being tested.

[0023] The method for measuring adiabatic temperature rise data described in some schemes, wherein f(m) b， C b m w C w m s C s The result is inversely proportional to the product of the mass of the test substance and the specific heat capacity of the test substance, directly proportional to the product of the mass of the test ball and the specific heat capacity of the test ball, and directly proportional to the product of the mass of the intermediate substance and the specific heat capacity of the intermediate substance.

[0024] In some schemes, the method for measuring adiabatic temperature rise data includes a formula for the thermal inertia correction value:

[0025]

[0026] Some of the methods for measuring adiabatic temperature rise data describe substances that can be measured, including polyether polyols, isocyanates, polymeric monomers, or isobutylene; wherein:

[0027] When the substance to be tested is a polyether polyol, the intermediate substance is water;

[0028] When the substance to be tested is an isocyanate, the intermediate substance is ethyl acetate;

[0029] When the substance to be tested is a polymeric monomer, the intermediate substance is a solvent corresponding to the polymeric monomer;

[0030] When the substance to be tested is isobutylene, the intermediate substance is n-hexane.

[0031] Secondly, this application provides a device for measuring adiabatic temperature rise data, used to measure the adiabatic temperature rise data of high-viscosity substances, colloidal substances, or solid substances, including:

[0032] The information acquisition module is configured to acquire the property information of the substance to be tested;

[0033] An intermediate substance determination module is configured to determine an intermediate substance based on the property information of the analyte; the intermediate substance satisfies the following conditions: if the analyte is a high-viscosity system, the intermediate substance is used to reduce the viscosity of the analyte when mixed with it; if the analyte is a colloidal or solid substance, the intermediate substance is used to transform the analyte into a continuous phase when mixed with it; the intermediate substance does not react with the analyte, and the intermediate substance has stable chemical properties within the measurement temperature range;

[0034] The initial result test module is configured to place the homogeneous mixture obtained by mixing the intermediate substance and the test substance into the test ball of the adiabatic accelerated calorimeter, and obtain the adiabatic temperature rise test result of the homogeneous mixture.

[0035] The correction module is configured to correct the adiabatic temperature rise test results of the homogeneous mixture based on the thermal parameter information of the intermediate substance, the substance to be tested, and the test ball, so as to obtain the adiabatic temperature rise test data of the substance to be tested.

[0036] Thirdly, the present application provides an electronic device, which includes at least one processor and at least one memory, wherein at least one memory stores program information, and at least one processor reads the program information and executes the method for measuring adiabatic temperature rise data as described in any one of the first aspects.

[0037] Fourthly, the present application provides a computer-readable storage medium storing program information, wherein a computer reads the program information and executes the method for measuring adiabatic temperature rise data as described in any one of the first aspects.

[0038] Fifthly, the present application provides an adiabatic accelerated calorimeter, which is equipped with the electronic equipment described in the third aspect or the storage medium described in the fourth aspect.

[0039] The technical solution of this application has the following technical advantages over the prior art:

[0040] The adiabatic temperature rise measurement method, apparatus, and adiabatic accelerating calorimeter provided in this application, when measuring the adiabatic temperature rise data of high-viscosity systems, colloidal substances, or solid substances, add an intermediate substance to the original measurement system. The intermediate substance mixes with the substance to be measured, thereby reducing the viscosity of the high-viscosity system or making the colloid and solid a continuous phase. This eliminates the temperature gradient of the substance to be measured in the original measurement system, and ensures uniform temperature inside and outside the measuring sphere. The measurement results for homogeneous mixtures are more accurate and reliable. Then, the adiabatic temperature rise test results of the homogeneous mixture are corrected based on the thermal parameters of the intermediate substance, the substance to be measured, and the test sphere, to obtain the adiabatic temperature rise test data of the substance to be measured. After actual experimental verification, the adiabatic temperature rise test data of the substance to be measured obtained after correction has the required accuracy. Attached Figure Description

[0041] The preferred embodiments of this application will be described in detail below with reference to the accompanying drawings, which will help to understand the purpose and advantages of this application, wherein:

[0042] Figure 1 The curve showing the change in test temperature over time for a 100% content polyether polyol.

[0043] Figure 2 This is a flowchart of a method for measuring adiabatic temperature rise data according to one embodiment of this application;

[0044] Figure 3 This is a curve showing the change in test temperature over time for a certain polyether polyol with a 50% content as described in the embodiments of this application;

[0045] Figure 4 This is a curve showing the change in test temperature over time for a certain polyether polyol with a content of 60% as described in the embodiments of this application;

[0046] Figure 5 This is a curve showing the change in test temperature over time for a certain polyether polyol with a content of 70% as described in the embodiments of this application;

[0047] Figure 6This is a comparison of the AKTS software-processed curves of a certain polyether polyol measured by DSC at different heating rates, as described in the embodiments of this application, with the measurement results of this method;

[0048] Figure 7 This is a structural block diagram of a device for measuring adiabatic temperature rise data according to an embodiment of this application.

[0049] Figure 8 This is a schematic diagram of the hardware connections of the electronic device used to perform the method for measuring the adiabatic temperature rise data according to an embodiment of this application. Detailed Implementation

[0050] The technical solutions of this application will now be clearly and completely described with reference to the accompanying drawings. Obviously, the described embodiments are only some, not all, of the embodiments of this application. Based on the embodiments of this application, all other embodiments obtained by those skilled in the art without creative effort are within the scope of protection of this application.

[0051] In the description of this application, it should be noted that the terms "center," "upper," "lower," "left," "right," "vertical," "horizontal," "inner," and "outer," etc., indicate the orientation or positional relationship based on the orientation or positional relationship shown in the accompanying drawings. They are used only for the convenience of describing this application and simplifying the description, and do not indicate or imply that the device or element referred to must have a specific orientation, or be constructed and operated in a specific orientation. Therefore, they should not be construed as limitations on this application. Furthermore, the terms "first," "second," and "third" are used for descriptive purposes only and should not be construed as indicating or implying relative importance.

[0052] In the description of this application, it should be noted that, unless otherwise expressly specified and limited, the terms "installation," "connection," and "joining" should be interpreted broadly. For example, they can refer to a fixed connection, a detachable connection, or an integral connection; they can refer to a direct connection or an indirect connection through an intermediate medium; and they can refer to the internal communication between two components. Those skilled in the art can understand the specific meaning of the above terms in this application based on the specific circumstances.

[0053] Furthermore, the technical features involved in the different embodiments of this application described below can be combined with each other as long as they do not conflict with each other.

[0054] This embodiment provides a method for measuring adiabatic temperature rise data, applicable to application scenarios where an adiabatic accelerated calorimeter is used to measure the adiabatic temperature rise data of high-viscosity systems, colloidal substances, or solid substances; wherein, for example... Figure 1 As shown, the method includes the following steps:

[0055] S10: Obtain the property information of the substance to be tested.

[0056] Among them, attribute information is used to determine the material properties and chemical properties of the substance to be tested, such as whether it is a high-viscosity system, a colloidal substance, or a solid substance, and solvents that will not react chemically with the substance to be tested.

[0057] S20: Determine the intermediate substance based on the property information of the substance to be tested.

[0058] The intermediate substance satisfies the following conditions: if the analyte is a high-viscosity system, the intermediate substance is used to reduce the viscosity of the analyte when mixed with it; if the analyte is a colloidal or solid substance, the intermediate substance is used to transform the analyte into a continuous phase when mixed with it; the intermediate substance does not react with the analyte, and the intermediate substance has stable chemical properties within the measurement temperature range.

[0059] Because the intermediate substance is also placed in the test sphere and heated by a thermocouple, the intermediate substance must have stable chemical properties within the test temperature range. This is to prevent the intermediate substance from undergoing decomposition reactions or producing other substances during the test, which could adversely affect the properties of the test substance and thus ensure the accuracy of the test results.

[0060] For example, when the analyte is a polyether polyol, the intermediate substance is water; when the analyte is an isocyanate, the intermediate substance is ethyl acetate; when the analyte is a monomer, the intermediate substance is a solvent corresponding to the monomer; when the analyte is isobutylene, the intermediate substance is n-hexane.

[0061] As shown in the example above, the intermediate substance and the analyte do not react. The intermediate substance merely reduces the viscosity of the analyte or makes it a continuous phase, making it more suitable for uniform mixing and eliminating the adverse effects of its heat transfer gradient.

[0062] S30: The homogeneous mixture obtained by mixing the intermediate substance and the substance to be tested is placed in the test ball of the adiabatic accelerated calorimeter to obtain the adiabatic temperature rise test result of the homogeneous mixture.

[0063] After the intermediate substance and the substance to be tested are mixed, as mentioned above, they have become a low-viscosity or continuous phase substance, so a homogeneous mixture can be obtained by stirring. After the homogeneous mixture is placed in the test sphere and the sealing operation is completed, the test result can be obtained using the software application corresponding to the adiabatic accelerated calorimeter, just like the test method in the prior art. This result is the adiabatic temperature rise test result of the homogeneous mixture.

[0064] Adiabatic heating refers to the temperature increase that can be achieved when a material undergoes complete exothermic reaction and the heat released during the reaction. In this specific experiment, the heat released by the test substance is absorbed not only by the test substance itself but also by the test sphere and intermediate substances; therefore, the results need to be corrected.

[0065] S40: Correct the adiabatic temperature rise test results of the homogeneous mixture based on the thermal parameter information of the intermediate substance, the substance to be tested, and the test ball, to obtain the adiabatic temperature rise test data of the substance to be tested.

[0066] Because the intermediate substance, the substance to be tested, and the material of the test sphere are all determined, the thermal parameters of these three substances are also determined, such as specific heat capacity and thermal inertia. Therefore, during the test, the temperature changes of the intermediate substance, the substance to be tested, and the test sphere can all be determined based on their respective thermal parameters. This allows us to determine how much of the heat released by the substance to be tested was absorbed by the intermediate substance and the test sphere, and how much was absorbed by the substance itself. Thus, we can determine the adiabatic temperature rise test data of the substance to be tested.

[0067] In the above embodiments, when measuring the adiabatic temperature rise data of high-viscosity substances, colloidal substances, or solid substances, an intermediate substance is added to the original measurement system. The intermediate substance is mixed with the substance to be measured, which reduces the viscosity of the high-viscosity substance or makes the colloid and solid become a continuous phase, eliminating the temperature gradient of the substance to be measured in the original measurement system. The temperature inside and outside the measuring sphere is uniform, and the measurement results for homogeneous mixtures are more accurate and reliable. Then, the adiabatic temperature rise test results of the homogeneous mixture are corrected based on the thermal parameter information of the intermediate substance, the substance to be measured, and the test sphere, to obtain the adiabatic temperature rise test data of the substance to be measured. After actual experimental verification, the adiabatic temperature rise test data of the substance to be measured obtained after correction has the required accuracy.

[0068] Specifically, step S40 may include the following steps: obtaining the mass and specific heat capacity of the intermediate substance; obtaining the mass and specific heat capacity of the test ball; obtaining the mass and specific heat capacity of the substance to be tested; determining the thermal inertia correction value of the substance to be tested based on the mass and specific heat capacity of the intermediate substance, the mass and specific heat capacity of the test ball, and the mass and specific heat capacity of the substance to be tested; and multiplying the adiabatic temperature rise test result of the homogeneous mixture with the thermal inertia correction value to obtain the adiabatic temperature rise test data of the substance to be tested.

[0069] Regarding the heat absorption and release of a substance and temperature changes, the specific heat capacity has the greatest impact. Therefore, this method obtains the mass and specific heat capacity of the intermediate substance, the substance to be tested, and the test sphere to determine the influence of the test sphere and the intermediate substance on the adiabatic temperature rise data of the substance to be tested. The aforementioned influence relationship or influence function can be determined through calibration experiments. The adiabatic temperature rise test data of the substance to be tested is obtained by multiplying the adiabatic temperature rise test results of the homogeneous mixture by the thermal inertia correction value.

[0070] In this application, the thermal inertia correction value of the substance under test is determined by the following function, including:

[0071] Phi'=1+f(m b， C b m w C w m s C s );

[0072] Where, f(m) b C b m w C w m s C s ) indicates that it contains parameter m b C b m w C w m s C s The function can be determined through calibration experiments. Where m... b C represents the mass of the test ball. b The specific heat capacity of the test sphere is represented by m. w C represents the mass of the intermediate substance. w m represents the specific heat capacity of the intermediate substance. s C represents the mass of the substance being tested. s This indicates the specific heat capacity of the substance being tested.

[0073] Furthermore, the f(m) b C b m w C w m s C sThe result is inversely proportional to the product of the mass and specific heat capacity of the test substance, directly proportional to the product of the mass and specific heat capacity of the test sphere, and directly proportional to the product of the mass and specific heat capacity of the intermediate substance. That is, the product of the mass and specific heat capacity of the test substance is used as the denominator, and the products of the mass and specific heat capacity of the test sphere and the intermediate substance are used as the numerators. Preferably, the formula for the thermal inertia correction value is expressed as:

[0074]

[0075] The final adiabatic temperature rise test data of the substance to be tested are as follows:

[0076] δT (Phi＝1) =δT (Phi>1) ×Phi';

[0077] δT (Phi＝1) This represents the adiabatic temperature rise test data of the substance under test, δT. (Phi>1) This represents the adiabatic temperature rise test result of a homogeneous mixture, where Phi' represents the correction value for the thermal inertia of the substance being tested.

[0078] In the above scheme, the unit of thermal inertia is "1", the unit of mass is "g", the unit of specific heat capacity is "J / gK", and the unit of adiabatic temperature rise test data is "K", where K represents Kelvin.

[0079] The above method was used to test a certain polyether polyol. Water was chosen as the intermediate substance. Solutions of different concentrations were prepared by mixing the test substance with water, and the experiments were conducted following the same steps. As shown in Table 1, three experimental samples were obtained by mixing water and the polyether polyol, corresponding to concentrations of 50%, 60%, and 70%. The test results are as follows: Figure 3-5 As shown in the table below, the corrected adiabatic temperature rise is approximately 250-260℃. This temperature value can be calculated using Kelvin. Assuming the specific heat capacity of the substance being tested is 2 J / g·K, the total heat release is approximately 500-520 J / g.

[0080] Table 1. Experimental data and results of a certain polyether polyol at different concentrations.

[0081]

[0082] When testing a pure polyether polyol, DSC was used at different heating rates, and the test results were processed using AKTS software. The results are as follows: Figure 6As shown in the figure, the heat release is in the range of 507±12J / g. The result of the correction using the adiabatic calorimeter method coincides with this result, thus verifying the accuracy of the proposed solution.

[0083] This application also provides a device for measuring adiabatic temperature rise data, used to measure the adiabatic temperature rise data of high-viscosity substances, colloidal substances, or solid substances, such as... Figure 7 As shown, it includes:

[0084] The information acquisition module 10 is configured to acquire the property information of the substance to be tested.

[0085] The intermediate substance determination module 20 is configured to determine an intermediate substance based on the property information of the analyte; the intermediate substance satisfies the following conditions: if the analyte is a high-viscosity system, the intermediate substance is used to reduce the viscosity of the analyte when mixed with the analyte; if the analyte is a colloidal or solid substance, the intermediate substance is used to transform the analyte into a continuous phase when mixed with the analyte; the intermediate substance does not react with the analyte, and the intermediate substance has stable chemical properties within the measurement temperature range.

[0086] The initial result test module 30 is configured to place the homogeneous mixture obtained by mixing the intermediate substance and the test substance into the test sphere of the adiabatic accelerated calorimeter, and obtain the adiabatic temperature rise test result of the homogeneous mixture.

[0087] The correction module 40 is configured to correct the adiabatic temperature rise test results of the homogeneous mixture based on the thermal parameter information of the intermediate substance, the substance to be tested, and the test ball, so as to obtain the adiabatic temperature rise test data of the substance to be tested.

[0088] In some embodiments, the correction module 40 is configured to: acquire the mass and specific heat capacity of the intermediate substance; acquire the mass and specific heat capacity of the test sphere; acquire the mass and specific heat capacity of the substance to be tested; determine the thermal inertia correction value of the substance to be tested based on the mass and specific heat capacity of the intermediate substance, the test sphere, and the substance to be tested; and multiply the adiabatic temperature rise test result of the homogeneous mixture by the thermal inertia correction value to obtain the adiabatic temperature rise test data of the substance to be tested. Preferably, in the correction module 40, the formula for the thermal inertia correction value is expressed as: In some embodiments, the analyte includes polyether polyol, isocyanate, monomer, or isobutylene; wherein: when the analyte is a polyether polyol, the intermediate is water; when the analyte is an isocyanate, the intermediate is ethyl acetate; when the analyte is a monomer, the intermediate is a solvent corresponding to the monomer; and when the analyte is isobutylene, the intermediate is n-hexane.

[0089] In some embodiments of this application, a storage medium is also provided, wherein the storage medium stores program information, and after the computer reads the program information, it executes the adiabatic temperature rise data measurement method described in any of the above claims.

[0090] Some embodiments also provide a device for determining the location of ground surface measuring points. The device includes at least one processor and at least one memory. The at least one memory stores program information, and the at least one processor reads the program information and executes the adiabatic temperature rise data measurement method described above. For example... Figure 8The electronic device includes at least one processor 81 and at least one memory 82. The memory 82 stores program information, and the processor 81 reads the program information and executes the adiabatic temperature rise data measurement method described in any of the above embodiments. The device may further include an input device 83 and an output device 84. The processor 81, memory 82, input device 83, and output device 84 are communicatively connected. The memory 82, as a non-volatile computer-readable storage medium, can be used to store non-volatile software programs, non-volatile computer-executable programs, and modules. The processor 81 executes various functional applications and data processing by running the non-volatile software programs, instructions, and modules stored in the memory 82, thereby implementing the adiabatic temperature rise data measurement method provided in any of the above embodiments. The memory 82 may include a program storage area and a data storage area. The program storage area may store the operating system and at least one application program required for a function; the data storage area may store data created based on the use of the adiabatic temperature rise data measurement method. Furthermore, memory 82 may include high-speed random access memory and non-volatile memory, such as at least one disk storage device, flash memory device, or other non-volatile solid-state storage device. In some embodiments, memory 82 may optionally include memory remotely located relative to processor 81, and these remote memories may be connected via a network to the apparatus performing the adiabatic temperature rise data measurement method. Examples of such networks include, but are not limited to, the Internet, intranets, local area networks, mobile communication networks, and combinations thereof. Input device 83 may receive user clicks and generate signal inputs related to user settings and function control of the adiabatic temperature rise data measurement method. Output device 84 may include a display device such as a display screen. When the one or more modules are stored in memory 82 and are run by the one or more processors 81, the adiabatic temperature rise data measurement method in any of the above method embodiments is executed.

[0091] This application also provides an adiabatic accelerated calorimeter, which is equipped with the aforementioned electronic equipment or storage medium.

[0092] Obviously, the above embodiments are merely illustrative examples for clear explanation and are not intended to limit the implementation. Those skilled in the art will recognize that other variations or modifications can be made based on the above description. It is neither necessary nor possible to exhaustively list all possible implementations here. However, obvious variations or modifications derived therefrom are still within the scope of protection of this application.

Claims

1. A method for measuring adiabatic temperature rise data, characterized in that, Data used to measure the adiabatic temperature rise of highly viscous substances, colloidal substances, or solid substances, including: Obtain the property information of the substance to be tested; An intermediate substance is determined based on the property information of the analyte. The intermediate substance meets the following conditions: if the analyte is a high-viscosity system, the intermediate substance is used to reduce the viscosity of the analyte when mixed with it; if the analyte is a colloidal or solid substance, the intermediate substance is used to transform the analyte into a continuous phase when mixed with it; the intermediate substance does not react with the analyte, and the intermediate substance has stable chemical properties within the measurement temperature range. The homogeneous mixture obtained by mixing the intermediate substance and the substance to be tested is placed in the test sphere of an adiabatic accelerated calorimeter to obtain the adiabatic temperature rise test result of the homogeneous mixture. The adiabatic temperature rise test results of the homogeneous mixture are corrected based on the thermal parameter information of the intermediate substance, the substance to be tested, and the test ball to obtain the adiabatic temperature rise test data of the substance to be tested.

2. The method for measuring adiabatic temperature rise data according to claim 1, characterized in that, The step of correcting the adiabatic temperature rise test results of the homogeneous mixture based on the thermal parameter information of the intermediate substance, the substance to be tested, and the test ball to obtain the adiabatic temperature rise test data of the substance to be tested includes: Obtain the mass and specific heat capacity of the intermediate substance; Obtain the mass and specific heat capacity of the test ball; Obtain the mass and specific heat capacity of the substance to be tested; The thermal inertia correction value of the test substance is determined based on the mass and specific heat capacity of the intermediate substance, the mass and specific heat capacity of the test ball, and the mass and specific heat capacity of the test substance. The adiabatic temperature rise test results of the homogeneous mixture are multiplied by the thermal inertia correction value to obtain the adiabatic temperature rise test data of the substance under test.

3. The method for measuring adiabatic temperature rise data according to claim 2, characterized in that, The step of determining the thermal inertia correction value of the test substance based on the mass and specific heat capacity of the intermediate substance, the mass and specific heat capacity of the test ball, and the mass and specific heat capacity of the test substance includes: Phi’= ; in, Indicates that parameters are included. The function, where, Indicates the mass of the test ball. This indicates the specific heat capacity of the test ball. Indicates the mass of the intermediate substance. This indicates the specific heat capacity of the intermediate substance. Indicates the mass of the substance being tested. This indicates the specific heat capacity of the substance being tested.

4. The method for measuring adiabatic temperature rise data according to claim 3, characterized in that: The The result is inversely proportional to the product of the mass of the test substance and its specific heat capacity, and directly proportional to the sum of the product of the mass of the test ball and its specific heat capacity, and the product of the mass of the intermediate substance and its specific heat capacity.

5. The method for measuring adiabatic temperature rise data according to claim 4, characterized in that, The formula for the thermal inertia correction value is expressed as follows: Phi’= 。 6. The method for measuring adiabatic temperature rise data according to any one of claims 1-5, characterized in that, The analyte includes polyether polyols, isocyanates, polymeric monomers, or isobutylene; wherein: When the substance to be tested is a polyether polyol, the intermediate substance is water; When the substance to be tested is an isocyanate, the intermediate substance is ethyl acetate; When the substance to be tested is a polymeric monomer, the intermediate substance is a solvent corresponding to the polymeric monomer; When the substance to be tested is isobutylene, the intermediate substance is n-hexane.

7. A device for measuring adiabatic temperature rise data, characterized in that, Data used to measure the adiabatic temperature rise of highly viscous substances, colloidal substances, or solid substances, including: The information acquisition module is configured to acquire the property information of the substance to be tested; An intermediate substance determination module is configured to determine an intermediate substance based on the property information of the analyte; the intermediate substance satisfies the following conditions: if the analyte is a high-viscosity system, the intermediate substance is used to reduce the viscosity of the analyte when mixed with it; if the analyte is a colloidal or solid substance, the intermediate substance is used to transform the analyte into a continuous phase when mixed with it; the intermediate substance does not react with the analyte, and the intermediate substance has stable chemical properties within the measurement temperature range; The initial result test module is configured to place the homogeneous mixture obtained by mixing the intermediate substance and the test substance into the test ball of the adiabatic accelerated calorimeter, and obtain the adiabatic temperature rise test result of the homogeneous mixture. The correction module is configured to correct the adiabatic temperature rise test results of the homogeneous mixture based on the thermal parameter information of the intermediate substance, the substance to be tested, and the test ball, so as to obtain the adiabatic temperature rise test data of the substance to be tested.

8. An electronic device, characterized in that, The electronic device includes at least one processor and at least one memory, wherein at least one memory stores program information, and at least one processor reads the program information and executes the method for measuring adiabatic temperature rise data according to any one of claims 1-6.

9. A computer-readable storage medium, characterized in that, The storage medium stores program information, and after the computer reads the program information, it executes the method for measuring adiabatic temperature rise data as described in any one of claims 1-6.

10. An adiabatic accelerated calorimeter, wherein the adiabatic accelerated calorimeter is equipped with the electronic device of claim 8 or the storage medium of claim 9.

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