一种改性锰酸锂正极材料及其制备方法

By coating the surface of lithium lanthanum titanium oxide solid electrolyte onto the lithium manganese oxide cathode material, the problem of poor cycle performance of lithium manganese oxide was solved, and the high rate performance and cycle stability of the material were improved, making it suitable for large-scale production.

CN116632189BActive Publication Date: 2026-07-17ANHUI BOSHI HIGH-TECH NEW MATERIAL CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
ANHUI BOSHI HIGH-TECH NEW MATERIAL CO LTD
Filing Date
2023-05-10
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The cycle performance of lithium manganese oxide cathode materials is poor, especially under high temperature conditions. The main reasons are the dissolution of manganese and the interfacial side reactions with the electrolyte.

Method used

A lithium lanthanum titanium oxide solid electrolyte is coated onto the surface of lithium manganese oxide. By forming a lithium lanthanum titanium oxide solid electrolyte layer on the surface of the lithium manganese oxide cathode material, the lithium ion migration rate is improved and internal stress is suppressed. This is achieved using a simple and controllable preparation method.

Benefits of technology

This improves the rate performance and cycle stability of lithium manganese oxide cathode materials, reduces production costs, and makes them suitable for large-scale industrial production.

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Abstract

本发明属于锂离子电池技术领域,具体涉及一种改性锰酸锂正极材料及其制备方法。本发明提供了一种改性锰酸锂正极材料,包括锰酸锂和包覆在所述锰酸锂表面的锂镧钛氧固态电解质;所述锂镧钛氧固态电解质的化学组成为Li1‑xLaxTiO3,其中0.1≤x≤0.8。本发明通过在锰酸锂正极材料的表面包覆锂镧钛氧固态电解质,可以避免锰酸锂正极材料与电解液的直接接触,还可以提高材料表面的锂离子迁移速率,提高材料的倍率性能;稳定的锂镧钛氧固态电解质包覆层还可以抑制正极材料循环过程中的内部应力,提高电池的循环性能和存储性能。
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