Bactericidal, antibacterial and preservative compositions

Abstract

The present invention relates to a composition for antibacterial and preservative purposes and products including the same such as cosmetics, sanitary products, household chemical products, etc., the above-mentioned composition being used for water-containing products such as laundry or dishware, cleaning agents or fragrance products for living spaces, wet wipes, cosmetics, etc., for the purpose of preventing spoilage and maintaining physical properties. The composition for antibacterial and preservative purposes of the present invention includes a compound of Chemical Formula 1 and any one of compounds of Chemical Formula 2, Chemical Formula 3, Chemical Formula 4, or Chemical Formula 5, thereby being able to solve problems such as harmfulness to the human body, skin irritation, etc., and enhance antibacterial power.

Description

TECHNICAL FIELD

[0001] The present application relates to a composition for antibacterial and preservation and a product comprising the same, the composition being used for laundry or dish, cleaning agent or fragrance product for living space, wet tissue, shampoo, cosmetic (cream, lipstick, etc.) and the like, water-containing product and non-water-containing product (cosmetic powder) for the purpose of preventing spoilage and maintaining physical properties. BACKGROUND

[0002] All water-containing products must use an antibacterial agent because microorganisms are easily propagated. The antibacterial agent refers to an agent that inhibits the growth of bacteria or kills bacteria.

[0003] In particular, a cleaning agent product containing a large amount of water must contain a preservative for preventing the proliferation of microorganisms and spoilage and an antibacterial agent for eliminating microorganisms as a source of contamination to maintain quality for a long time. Such a product is very long in shelf life, has a very high possibility of contact with microorganisms in the process of use and storage method, has various carbon and nitrogen sources combined, and also has a high moisture content required for the growth of microorganisms, so the antibacterial agent component is essential.

[0004] Recently, the harmfulness of antibacterial agents to the human body has been controversial, but when a product does not use an antibacterial agent or has weak antibacterial power, not only the product deteriorates and the risk of infectious pathogenic bacteria is high, but also it becomes a cause of skin problems and diseases due to microbial metabolism, so the use of an antibacterial agent is inevitable.

[0005] Methylisothiazolinone, chloromethylisothiazolinone, benzisothiazolinone (1,2-benzisothiazol-3(2H)-one), and the like, toxic chemicals such as isothiazolinone components, are still used as a purpose of preserving cleaning agents or fragrance products for laundry or dish, living space, wet tissues, shampoos, cosmetics (cream, lipstick, etc.).

[0006] Isothiazolinone components, which are toxic chemicals, are widely used because they are inexpensive and potent, but since they can act as carcinogenic substances, regulations thereon are being strengthened.

[0007] In recent years, since antibacterial agents can affect public health, Korea is strengthening regulations on each product group. Although regulations on antibacterial agents are being accelerated, such as classifying wet tissues as other sanitary products in the Sanitary Products Management Act, strengthening relevant regulations by the Food and Drug Safety Administration's notice designating raw materials that can be used in kitchen cleaners, the use of safe and excellent antibacterial agents is being narrowed due to the improper use of antibacterial agents.

[0008] Therefore, there is a need for an antibacterial agent that can be safely used in products including cosmetics, hygiene products, and daily chemical products and exhibits excellent antibacterial activity.

[0009] Existing technical documents

[0010] Patent documents

[0011] Patent Document 1: Korean Patent No. 10-2233825 Summary of the Invention

[0012] Technical issues

[0013] Therefore, in the process of researching and developing a method to inhibit microorganisms through other means without using existing antibacterial agents that harm the human body through various pathways, the inventors of this invention discovered that when a compound with a surfactant structure as shown in Formula 1 is mixed with any one of the preservative compounds shown in Formula 2, Formula 3, Formula 4 or Formula 5, the microbial inhibitory material can be easily mixed into the product dosage form. Compared with using it alone, it can provide a synergistic effect of antibacterial, bactericidal and preservative effects, and also has the effect of counteracting the reduction of antibacterial, bactericidal and preservative functions caused by the ionicity of the product substrate. Therefore, it was determined that it can inhibit microorganisms more effectively, thus completing this invention.

[0014] Therefore, specifically, the specific technical solution of the present invention is to provide a composition for antibacterial and preservation comprising a compound as shown in Chemical Formula 1 and any one of the compounds shown in Chemical Formula 2, Chemical Formula 3, Chemical Formula 4 or Chemical Formula 5.

[0015] Furthermore, a special technical solution of the present invention is to provide products comprising the above-mentioned composition for antibacterial and preservation purposes in various forms.

[0016] Furthermore, a special technical solution of the present invention is to provide an antibacterial method for treating bacteria with the above-mentioned composition for antibacterial and preservation.

[0017] Solution to the problem

[0018] To address the aforementioned problems, the following solutions are disclosed in this invention.

[0019] Specifically, the present invention discloses a composition for antibacterial and preservation purposes, comprising: (a) a compound as shown in Formula 1; and (b) any one of the compounds shown in Formula 2, Formula 3, Formula 4 or Formula 5.

[0020] The antibacterial and preservation compositions of the present invention have the advantages of exhibiting broad-spectrum microbial inhibition capabilities and solving problems such as the harmfulness of preservatives to the human body and skin irritation.

[0021] This invention discloses a product comprising the above-described composition for antibacterial and preservation purposes.

[0022] The present invention discloses an antibacterial method, the method comprising the step of treating bacteria with the composition described above for antibacterial and preservation purposes.

[0023] The effects of the invention

[0024] The antibacterial activity can be synergistically expressed by combining the ingredients invented by the inventors.

[0025] Furthermore, when the antibacterial and preservation composition invented by the inventors is included in various products such as cosmetics, hygiene products, and daily chemical products, it can help emulsify and solubilize according to the properties of the surfactant, and exhibits excellent antibacterial activity and a broad antibacterial spectrum.

[0026] Furthermore, the antibacterial and preservation compositions of the present invention can exhibit a wide range of applications because they achieve broad efficacy in anionic and nonionic surfactant-based compositions and cationic surfactant-based compositions.

[0027] The effects of the present invention are not limited to those described above. Various effects may be included within the scope that will be obvious to those skilled in the art based on the following description. Detailed Implementation

[0028] The following is a more detailed description of this instruction manual.

[0029] The specific details are as follows. On the other hand, each description and embodiment disclosed in this invention can also be applied to every other description and embodiment. That is, all combinations of the various elements disclosed in this invention fall within the scope of this invention. Furthermore, the scope of this invention should not be considered limited by the following specific description.

[0030] As used in this specification, expressions such as “comprising” should be understood as open-ended terms implying the possibility of including other embodiments, unless otherwise stated in the sentence or text containing such expression.

[0031] The terms or words used in the description of this invention and the scope of the claims should not be construed as limited to their conventional or dictionary meanings. Based on the principle that inventors can appropriately define the concepts of terms to best describe their inventions, they should be interpreted as meanings and concepts consistent with the technical ideas of this invention.

[0032] Compositions for antimicrobial and preservation

[0033] This invention provides a composition for antibacterial and preservation purposes, comprising: (a) a compound as shown in Formula 1; and (b) any one of the compounds shown in Formula 2, Formula 3, Formula 4, or Formula 5.

[0034] Chemical Formula 1:

[0035]

[0036] Chemical formula 2:

[0037]

[0038] Chemical formula 3:

[0039]

[0040] Chemical formula 4:

[0041] H3C-L3-R6·X;

[0042] Chemical formula 5:

[0043]

[0044] In the above chemical formula 1,

[0045] R1 is hydrogen.

[0046] R2 represents substituted or unsubstituted C6 to C6. 18 Alkyl or substituted or unsubstituted C6 to C 18 alkenyl,

[0047] In the above chemical formula 2,

[0048] L1 is -CH2-, -O-, -C(=O)-, or -OC(=O)-.

[0049] R3 represents substituted or unsubstituted C1 to C2. 15 Alkyl or substituted or unsubstituted C2 to C3 15 alkenyl,

[0050] In the above chemical formula 3,

[0051] L2 is -(CH=CH)- or -(CH2). m -、-C=O- or -O-,

[0052] R4 is -C(=O)-R a -OH, -O-Na + -(CH2) n -OH, substituted or unsubstituted C1 to C2 15 Alkyl or substituted or unsubstituted C2 to C315 alkenyl,

[0053] R5 represents hydrogen, halogen, -OH, or -OR. b or -(C=O)-OR c ,

[0054] R a To R c Each of the following is independently hydrogen, substituted or unsubstituted C1 to C2. 15 Alkyl or substituted or unsubstituted C2 to C3 15 alkenyl,

[0055] m and n are independent integers from 1 to 5.

[0056] In the above chemical formula 4,

[0057] L3 can be -C(=O)-, -(CH=CH)-(CH2)o-, -C(CH3)2-CH2-CH(CH3)-CH2-, or -(CH2). p -,

[0058] o and p are independent integers from 1 to 15.

[0059] -(CH2) p -Can be C1 to C 15 Alkyl substitution,

[0060] R6 is -C(=O)-NH-OH、

[0061] X is NH2-CH2-CH2-OH or does not exist (Null).

[0062] In the above chemical formula 5,

[0063] R7 represents substituted or unsubstituted C1 to C2. 15 Alkyl, -COOH, -OR d or -COO - Na + ,

[0064] R8 represents substituted or unsubstituted C1 to C8. 15 Alkyl, -OH or -O - Na + ,

[0065] L4 can be substituted or unsubstituted -(CH2). q -, substituted or unsubstituted -(CH2) r -N(R e )-(CH2) s-Or substituted or unsubstituted phenylene (-C6H4-),

[0066] R d C1 to C1, whether substituted or not 15 alkyl,

[0067] R e C1 to C1, whether substituted or not 15 Alkyl or -(CH2) t -N[(CH2) u -CO2 - )]2,

[0068] q, r, s, t, and u are each an independent integer from 1 to 5.

[0069] In this invention, the term "composition for antibacterial and preservation" can refer to a preservative composition, which may contain all additives that can prevent the composition to which they are added from deteriorating, spoiling, discoloring, or undergoing chemical changes, and may also contain functional antibiotics that inhibit the growth of spoilage microorganisms or have a bactericidal effect by inhibiting the proliferation of microorganisms such as bacteria, molds, and yeasts.

[0070] In this invention, the above-mentioned antibacterial and preservation compositions may have antibacterial or antifungal effects on bacteria or fungi, but are not limited thereto.

[0071] In this invention, the term "antibacterial" refers to the ability to inhibit or control the growth and proliferation of bacteria.

[0072] In this invention, the term "antifungal" refers to the ability to inhibit or control the growth and proliferation of fungi.

[0073] In this invention, the above-mentioned antibacterial and preservation compositions may have antibacterial activity against Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, Klebsiella pneumoniae, methicillin-resistant Staphylococcus aureus, Bacillus subtilis, Vibrio parahaemolyticus, Salmonella typhimurium, Listeria monocytogenes, and Shigella flexneri, and antifungal activity against Candida albicans and Aspergillus niger, but are not limited thereto.

[0074] In this invention, compounds represented by chemical formulas 2 to 5 are preservative compounds. The term "preservative" refers to a chemical substance added to control the quality of processed foods, beverages, cosmetics, pharmaceuticals, hygiene products, and daily chemical products produced and distributed in the industry, used to prevent spoilage due to microorganisms or quality degradation or deterioration due to the decomposition of chemical components. That is, because it can exhibit antimicrobial activity against at least one of bacteria, molds, and yeasts, it is intended to function as an antimicrobial and / or antibacterial and / or antifungal agent.

[0075] In this invention, the composition for antibacterial and preservation purposes can be used to inhibit at least one microorganism selected from the group consisting of Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, Klebsiella pneumoniae, methicillin-resistant Staphylococcus aureus, Bacillus subtilis, Vibrio parahaemolyticus, Salmonella typhimurium, Listeria monocytogenes, Shigella flexneri, Candida albicans, and Aspergillus niger, but is not limited thereto.

[0076] In this invention, the weight ratio of the compound represented by chemical formula 1 to any one of the compounds represented by chemical formula 2, chemical formula 3, chemical formula 4 or chemical formula 5 can be from 0.01:9.99 to 9.99:0.01. Specifically, the weight ratio of the compound represented by chemical formula 1 to any one of the compounds represented by chemical formula 2, chemical formula 3, chemical formula 4 or chemical formula 5 can be 6:4, 7:3 and / or 8:2, but is not limited thereto.

[0077] Specifically, the content of any one of the compounds shown in Chemical Formula 1 and Chemical Formula 2, Chemical Formula 3, Chemical Formula 4 or Chemical Formula 5 is within the above-mentioned range, thereby having the advantage of enhancing the microbial inhibition effect.

[0078] In this invention, the compound represented by Chemical Formula 1 may be 3-(dodecylamino)propane-1,2-diol represented by Chemical Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol represented by Chemical Formula 1-2, but is not limited thereto.

[0079] Chemical formula 1-1:

[0080]

[0081] Chemical formula 1-2:

[0082]

[0083] Specifically, the compounds shown in Chemical Formula 1-1 or Chemical Formula 1-2, as compounds with excellent emulsifying and solubilizing effects, can be mixed with any one of the compounds shown in Chemical Formula 2, Chemical Formula 3, Chemical Formula 4, or Chemical Formula 5 to form an antibacterial composition, thereby inhibiting bacteria such as Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, Klebsiella pneumoniae, methicillin-resistant Staphylococcus aureus, Bacillus subtilis, Vibrio parahaemolyticus, Salmonella typhimurium, Listeria monocytogenes, and Shigella flexneri. Microorganisms such as *Flexneri*, *Candida albicans*, and *Aspergillus niger* can be used to make it antibacterial and antifungal, thus giving it the advantage of being applicable to various products in liquid and solid forms, such as cosmetics, hygiene products, and daily chemical products.

[0084] In this invention, in the above chemical formula 2, L1 can be -CH2-, -O-, or -OC(=O)-, and R3 can be substituted or unsubstituted C2 to C3. 10 Alkyl groups, but not limited to them.

[0085] Specifically, in the above chemical formula 2, L1 can be -CH2-, and R3 can be a substituted or unsubstituted C2 to C8 alkyl group, but is not limited thereto.

[0086] Furthermore, in the above chemical formula 2, L1 can be -O-, and R3 can be a substituted or unsubstituted C3 to C9 alkyl group, but is not limited thereto.

[0087] Furthermore, in the above chemical formula 2, L1 can be -OC (=O)-, and R3 can be a substituted or unsubstituted C8 to C3 group. 10 Alkyl groups, but not limited to them.

[0088] In this invention, the compound represented by Chemical Formula 2 may be one or more selected from the group consisting of hexane-1,2-diol, octane-1,2-diol, decane-1,2-diol, hexyl glycerin, octyl glycerin, ethylhexylglycerin, and glyceryl monocaprylate, but is not limited thereto.

[0089] Specifically, hexane-1,2-diol has The structure of octane-1,2-diol has The structure of decane-1,2-diol has The structure of hexylglycerin has... The structure of octyl glycerin has The structure of ethylhexylglycerin has... The structure of glyceryl monocaprylate has The structure.

[0090] In this invention, in the compounds shown in Chemical Formula 3 above, L2 can be -(CH=CH)- or -(CH2). m -, -C = O- or -O-, R4 can be -C(=O)-R a -OH, -O - Na + -(CH2) n -OH, substituted or unsubstituted C1 to C6 alkyl groups, and R5 can be hydrogen, -OH, or -OR. b R a and R b Each can be independently hydrogen, substituted or unsubstituted C1 to C6 alkyl, and m and n can be independently integers from 2 to 4, but are not limited thereto.

[0091] Specifically, in the compounds shown in Chemical Formula 3 above, L2 can be -(CH=CH)-, and R4 can be -C(=O)-R. a R a R5 can be -hydrogen or substituted or unsubstituted C1 to C3 alkyl groups, and R5 can be hydrogen, -OH or -OR.b R b It can be hydrogen or substituted or unsubstituted C1 to C3 alkyl, but is not limited thereto.

[0092] Furthermore, in the compounds shown in Chemical Formula 3 above, L2 can be -(CH2). m -, R4 can be -(CH2) n -OH, -C(=O)-R a or -OH, R a It can be hydrogen or a substituted or unsubstituted C1 to C3 alkyl group, and R5 can be -OH, hydrogen or a substituted or unsubstituted C1 to C3 alkyl group. 15 Alkyl group, where m can be an integer from 2 to 4 and n can be an integer from 1 to 3, but is not limited thereto.

[0093] Furthermore, in the compounds shown in Formula 3 above, L2 can be -C=O-, and R4 can be a substituted or unsubstituted C1 to C3 alkyl group or -O. - Na + R5 can be hydrogen or -OH, but is not limited to these.

[0094] Furthermore, in the compounds shown in Formula 3 above, L2 can be -O- and R4 can be -(CH2). n -OH, n can be an integer from 1 to 3, R5 can be hydrogen, but is not limited to this.

[0095] In this invention, the compound represented by chemical formula 3 may be one or more selected from the group consisting of cinnamaldehyde, 2-methoxychinnamaldhide, raspberryketone, 3-phenyl-1-propanol, 4-hydroxyacetophenone, sodium benzoate, and phenoxyethanol, but is not limited thereto.

[0096] Specifically, cinnamaldehyde has The structure of 2-methoxychinnamaldhide has The structure of raspberry ketone has The structure of 3-phenyl-1-propanol has The structure of 4-hydroxyacetophenone has The structure of sodium benzoate has The structure of phenoxyethanol (Phenoxy EtOH) has The structure.

[0097] In this invention, in the compounds shown in Formula 4 above, L3 can be -C(=O)-, -C(CH3)2-CH2-CH(CH3)-CH2-, or -(CH2). p -, p can be an integer from 5 to 12, R6 can be -C(=O)-NH-OH、 X can be NH2-CH2-CH2-OH or it may not exist (Null), but it is not limited to these.

[0098] Specifically, in the compounds shown in Chemical Formula 4 above, L3 can be -C(=O)-, and R6 can be... X can be non-existent (Null), but is not limited to this.

[0099] Furthermore, in the compounds shown in Chemical Formula 4 above, L3 can be -(CH2). p -,-(CH2) p - Can be substituted with C1 to C3 alkyl groups, p can be an integer from 3 to 11, and R6 can be -C(=O)-NH-OH or X can be non-existent (Null), but is not limited to this.

[0100] Furthermore, in the compounds shown in Chemical Formula 4 above, L3 can be -C(CH3)2-CH2-CH(CH3)-CH2-, and R6 can be... X can be NH2-CH2-CH2-OH, but is not limited to this.

[0101] In this invention, the compound represented by chemical formula 4 may be one or more selected from the group consisting of sodium dehydroacetate, caprylhydroxamic acid, piroctoneolamine, and lauroyl arginine ethyl ester, but is not limited thereto.

[0102] Specifically, sodium dehydroacetate has The structure of caprylhydroxamic acid has The structure of pyroxone olamine has... The structure of lauroyl arginine ethyl ester has The structure.

[0103] In this invention, in the compounds shown in Formula 5 above, R7 can be -COOH, -OR d or -COO - Na + R8 can be an unsubstituted C1 to C3 alkyl group, -OH, or -O. - Na + L4 can be -(CH2) substituted or unsubstituted by one or more substituents selected from the group consisting of hydroxyl, unsubstituted C1 to C3 alkyl, and carboxyl groups. q -, substituted or unsubstituted -(CH2) r -N(R e )-(CH2) s -or unsubstituted phenylene (-C6H4-), R d R is an unsubstituted C1 to C3 alkyl group. e It can be -(CH2) t -N[(CH2) u -CO2 - )]2, q, r, s, t, u can be independent integers from 1 to 3, but are not limited to these.

[0104] In this invention, the compounds shown in Formula 5 can be in the form of hydrates or salts, but are not limited thereto.

[0105] In this invention, the compound represented by chemical formula 5 may be one or more selected from the group consisting of levopropionic acid, citric acid, sodium anisate, disodium EDTA, and tetrasodium EDTA, but is not limited thereto.

[0106] Specifically, levulinic acid has The structure of citric acid has The structure of sodium anisate has The structure of disodium ethylenediaminetetraacetate (EDTA) has... The structure of tetrasodium ethylenediaminetetraacetate (EDTA) has... The structure.

[0107] A specific compound represented by any of the compounds shown in Formula 2, Formula 3, Formula 4 or Formula 5, together with a surfactant-type compound shown in Formula 1, is used as a component of a composition for antibacterial and preservation purposes. Thus, compared with using them separately, it can prevent the development of spoilage microorganisms by inhibiting the proliferation of microorganisms such as bacteria, molds, and yeasts, and can exhibit a synergistic effect by improving bactericidal power.

[0108] Products comprising compositions for antimicrobial and preservation

[0109] The present invention provides a product comprising the above-described composition for antibacterial and preservation purposes.

[0110] In this invention, the above-mentioned products can be cosmetics, hygiene products or daily chemical products, but are not limited to these.

[0111] In this invention, the term "cosmetics" refers to an item applied to the human body by means of smearing, rubbing or spraying, etc., to enhance attractiveness and brighten appearance by cleaning and beautifying the human body, or to maintain or promote the health of skin and hair, with negligible effect on the human body.

[0112] In this invention, the term "hygiene products" refers to products that require special hygiene supervision to ensure health and hygiene.

[0113] In this invention, the term "daily chemical product" refers to a chemical product used in everyday living spaces such as homes, offices, and public facilities, which may result in exposure of chemical substances to people or the environment.

[0114] In this invention, the aforementioned cosmetics can be prepared in any dosage form commonly prepared in the field of cosmetics, and can be formulated as any of the following: solutions, suspensions, emulsions, pastes, gels, creams, pressed powders, loose powders, liquid foundations, foundation sticks, sprays, soaps, facial cleansers, shower gels, shampoos, and conditioners, but are not limited thereto. More specifically, they can be prepared as toners, nourishing lotions, creams, nourishing face creams, massage creams, lipsticks, pressed powders, serums, eye creams, makeup removers, facial cleansers, makeup remover waters, sheet masks, or sprays, etc.

[0115] In this invention, according to the Hygiene Products Management Act, the aforementioned hygiene products may be selected from the group consisting of dishwashing liquid cleaners, dishwasher cleaners, and wet wipes, but are not limited thereto.

[0116] In this invention, in accordance with the relevant laws on the safety management of daily chemical products and biocides, the aforementioned daily chemical products may be selected from the group consisting of laundry detergents, living space cleaners, deodorizers, air purifiers, indoor fragrances, hair fragrances, fabric softeners, multi-functional cleaning products, bactericidal products, antibacterial products, disinfectant products, and disinfectants, but are not limited thereto.

[0117] In this invention, the content of the composition for antibacterial and preservation can be from 0.01% by weight to 10% by weight, relative to the above-mentioned cosmetics, hygiene products or daily chemical products, but is not limited thereto.

[0118] Specifically, the above-mentioned products may be selected from the group consisting of liquid cleaning compositions for clothing, kitchen cleaning compositions, wet wipes concentrate compositions, shampoo concentrate compositions, cosmetic face cream concentrate compositions, and cosmetic powder compositions, but are not limited thereto.

[0119] Laundry liquid detergent composition

[0120] Specifically, when the product containing the composition for antibacterial and preservation purposes is a liquid laundry detergent composition, it contains 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2, and hexane-1,2-diol, octane-1,2-diol, decane-1,2-diol, hexyl glycerin, octyl glycerin, ethylhexylglycerin, and glyceryl monocaprylate as shown in Formula 2. Compositions for antibacterial and preservation purposes, consisting of any combination of compounds from monoCaprylate, can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger, and Candida albicans.

[0121] Furthermore, when the product containing the composition for antibacterial and preservation is a liquid laundry detergent composition, it contains a compound selected from 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2, and a compound selected from cinnamaldehyde, 2-methoxychinnamaldhide, raspberryketone, 3-phenyl-1-propanol, 4-hydroxyacetophenone, sodium benzoate, and phenoxyethanol as shown in Formula 3. A composition for antibacterial and preservation purposes consisting of compounds from the group consisting of EtOH, which can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger and Candida albicans.

[0122] Furthermore, when the product containing the composition for antibacterial and preservation is a liquid laundry detergent composition, the composition containing any one of the following compounds for antibacterial and preservation—sodium dehydroacetate, caprylhydroxamic acid, piroctoneolamine, and lauroyl arginine ethyl ester—as shown in Formula 1-1 or Formula 1-2—can effectively inhibit Escherichia coli, Staphylococcus aureus, P. aeruginosa, Aspergillus niger, and Candida albicans.

[0123] Furthermore, when the product containing the composition for antibacterial and preservation is a liquid laundry detergent composition, the composition containing any one of the following compounds for antibacterial and preservation—such as 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2, levulinic acid, citric acid, sodium anisate, disodium EDTA, and tetrasodium EDTA as shown in Formula 5—can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger, and Candida albicans.

[0124] Kitchen cleaner composition

[0125] Specifically, when the product containing the composition for antibacterial and preservation purposes is a kitchen cleaner composition, it contains 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2, and hexane-1,2-diol, octane-1,2-diol, decane-1,2-diol, hexyl glycerin, octyl glycerin, ethylhexylglycerin, and glyceryl monocaprylate as shown in Formula 2. Compositions for antibacterial and preservation purposes, consisting of any combination of compounds from monoCaprylate, can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger, and Candida albicans.

[0126] Furthermore, when the product containing the composition for antibacterial and preservation purposes is a kitchen cleaning composition, it contains a 3-(dodecylamino)propane-1,2-diol compound selected as shown in Formula 1-1 or a 3-(tetradecylamino)propane-1,2-diol compound selected as shown in Formula 1-2 and a cinnamaldehyde, 2-methoxychinnamaldhide, raspberryketone, 3-phenyl-1-propanol, 4-hydroxyacetophenone, sodium benzoate, and phenoxyethanol selected as shown in Formula 3. A composition for antibacterial and preservation purposes consisting of compounds from the group consisting of EtOH, which can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger and Candida albicans.

[0127] Furthermore, when the product containing the composition for antibacterial and preservation is a kitchen cleaning composition, the composition containing any one of the following compounds for antibacterial and preservation, such as 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2, sodium dehydroacetate, caprylhydroxamic acid, piroctoneolamine, and lauroyl arginine ethyl ester as shown in Formula 4, can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger, and Candida albicans.

[0128] Furthermore, when the product containing the composition for antibacterial and preservation is a kitchen cleaning composition, the composition containing any one of the following compounds for antibacterial and preservation, such as 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2, levulinic acid, citric acid, sodium anisate, disodium EDTA, and tetrasodium EDTA as shown in Formula 5, can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger, and Candida albicans.

[0129] Wet wipe concentrate composition

[0130] Specifically, when the product containing the composition for antibacterial and preservation purposes is a wet wipe concentrate composition, it contains 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2, and hexane-1,2-diol, octane-1,2-diol, decane-1,2-diol, hexylglycerin, octylglycerin, ethylhexylglycerin, and glyceryl monocaprylate as shown in Formula 2. Compositions for antibacterial and preservation purposes, consisting of any combination of compounds from monoCaprylate, can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger, and Candida albicans.

[0131] Furthermore, when the product containing the composition for antibacterial and preservation purposes is a wet wipe concentrate composition, it contains a compound selected from 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2, and a compound selected from cinnamaldehyde, 2-methoxychinnamaldhide, raspberryketone, 3-phenyl-1-propanol, 4-hydroxyacetophenone, sodium benzoate, and phenoxyethanol as shown in Formula 3. A composition for antibacterial and preservation purposes consisting of compounds from the group consisting of EtOH, which can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger and Candida albicans.

[0132] Furthermore, when the product containing the composition for antibacterial and preservation is a wet wipe concentrate composition, the composition containing any one of the following compounds for antibacterial and preservation—sodium dehydroacetate, caprylhydroxamic acid, piroctone olamine, and lauroyl arginine ethyl ester—as shown in Formula 1-1 or Formula 1-2—can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger, and Candida albicans.

[0133] Furthermore, when the product containing the composition for antibacterial and preservation is a wet wipe concentrate composition, it comprises a composition for antibacterial and preservation consisting of a compound such as 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or a compound such as 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2 and any one of the following compounds such as levulinic acid, citric acid, sodium anisate, disodium EDTA, and tetrasodium EDTA as shown in Formula 5, thereby effectively inhibiting Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger, and Candida albicans.

[0134] Shampoo concentrate composition

[0135] Specifically, when the product containing the composition for antibacterial and preservation purposes is a shampoo concentrate composition, it contains 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2, and hexane-1,2-diol, octane-1,2-diol, decane-1,2-diol, hexyl glycerin, octyl glycerin, ethylhexylglycerin, and glyceryl monocaprylate as shown in Formula 2. Compositions for antibacterial and preservation purposes, consisting of any combination of compounds from monoCaprylate, can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger, and Candida albicans.

[0136] Furthermore, when the product containing the composition for antibacterial and preservation purposes is a shampoo concentrate composition, it contains a compound selected from 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2, and a compound selected from cinnamaldehyde, 2-methoxychinnamaldhide, raspberryketone, 3-phenyl-1-propanol, 4-hydroxyacetophenone, sodium benzoate, and phenoxyethanol as shown in Formula 3. A composition for antibacterial and preservation purposes consisting of compounds from the group consisting of EtOH, which can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger and Candida albicans.

[0137] Furthermore, when the product containing the composition for antibacterial and preservation is a shampoo concentrate composition, the composition containing any one of the following compounds for antibacterial and preservation—sodium dehydroacetate, caprylhydroxamic acid, piroctoneolamine, and lauroyl arginine ethyl ester—as shown in Formula 1-1 or Formula 1-2—can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger, and Candida albicans.

[0138] Furthermore, when the product containing the composition for antibacterial and preservation purposes is a shampoo concentrate composition, the composition containing any one of the following compounds for antibacterial and preservation purposes—such as 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2, levulinic acid, citric acid, sodium anisate, disodium EDTA, and tetrasodium EDTA as shown in Formula 5—can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger, and Candida albicans.

[0139] Cosmetic cream concentrate composition

[0140] Specifically, when the product containing the composition for antibacterial and preservation purposes is a cosmetic cream essence composition, it contains 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol compound as shown in Formula 1-2, and hexane-1,2-diol, octane-1,2-diol, decane-1,2-diol, hexyl glycerin, octyl glycerin, ethylhexylglycerin, and glyceryl monocaprylate as shown in Formula 2. Compositions for antibacterial and preservation purposes, consisting of any combination of compounds from monoCaprylate, can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger, and Candida albicans.

[0141] Furthermore, when the product containing the composition for antibacterial and preservation purposes is a cosmetic cream concentrate composition, it contains a compound selected from 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2, and a compound selected from cinnamaldehyde, 2-methoxychinnamaldhide, raspberryketone, 3-phenyl-1-propanol, 4-hydroxyacetophenone, sodium benzoate, and phenoxyethanol as shown in Formula 3. A composition for antibacterial and preservation purposes consisting of compounds from the group consisting of EtOH, which can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger and Candida albicans.

[0142] Furthermore, when the product containing the composition for antibacterial and preservation purposes is a cosmetic cream essence composition, the composition containing any one of the following compounds for antibacterial and preservation purposes—sodium dehydroacetate, caprylhydroxamic acid, piroctoneolamine, and lauroyl arginine ethyl ester—as shown in Formula 1-1 or Formula 1-2, can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger, and Candida albicans.

[0143] Furthermore, when the product containing the composition for antibacterial and preservation is a cosmetic cream essence composition, the composition containing any one of the following compounds for antibacterial and preservation purposes—such as 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2, levulinic acid, citric acid, sodium anisate, disodium EDTA, and tetrasodium EDTA as shown in Formula 5—can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger, and Candida albicans.

[0144] Cosmetic powder compact composition

[0145] Specifically, when the product containing the composition for antibacterial and preservation purposes is a cosmetic powder composition, it contains 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2, and hexane-1,2-diol, octane-1,2-diol, decane-1,2-diol, hexyl glycerin, octyl glycerin, ethylhexylglycerin, and glyceryl monocaprylate as shown in Formula 2. Compositions for antibacterial and preservation purposes, consisting of any combination of compounds from monoCaprylate, can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger, and Candida albicans.

[0146] Furthermore, when the product containing the composition for antibacterial and preservation purposes is a cosmetic powder composition, it contains a compound selected from 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2, and a compound selected from cinnamaldehyde, 2-methoxychinnamaldhide, raspberryketone, 3-phenyl-1-propanol, 4-hydroxyacetophenone, sodium benzoate, and phenoxyethanol as shown in Formula 3. A composition for antibacterial and preservation purposes consisting of compounds from the group consisting of EtOH, which can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger and Candida albicans.

[0147] Furthermore, when the product containing the composition for antibacterial and preservation is a cosmetic powder composition, the composition containing any one of the following compounds for antibacterial and preservation, such as 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2, sodium dehydroacetate, caprylhydroxamic acid, piroctoneolamine, and lauroyl arginine ethyl ester as shown in Formula 4, can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger, and Candida albicans.

[0148] Furthermore, when the product containing the composition for antibacterial and preservation is a cosmetic powder composition, the composition contains a combination of any one of the following compounds for antibacterial and preservation: 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2, levulinic acid, citric acid, sodium anisate, disodium EDTA, and tetrasodium EDTA as shown in Formula 5. This combination can effectively inhibit Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Aspergillus niger, and Candida albicans.

[0149] Antimicrobial method

[0150] The present invention provides an antibacterial method, the method comprising the step of treating bacteria with the composition described above for antibacterial and preservation purposes.

[0151] The method of treating bacteria with the above-described composition for antibacterial and preservation purposes may be appropriately applied according to conventional methods known to those skilled in the art in various fields where antibacterial action is required. The amount of the composition used for antibacterial and preservation purposes may be appropriately determined according to the intended use.

[0152] Unless there are contradictions, the matters mentioned in the antibacterial and preservation compositions, products containing antibacterial and preservation compositions, and antibacterial methods of the present invention also apply.

[0153] Hereinafter, the invention will be evaluated by applying it to various products with reference to preferred embodiments, so that those skilled in the art can easily implement it. However, the invention can be implemented in various different forms and is not limited to the embodiments described below.

[0154] Preparation example: Preparation of compositions for antibacterial and preservation purposes

[0155] Preparation Examples 1-7. Compositions for antibacterial and preservation purposes were prepared using 3-(dodecylamino)propane-1,2-diol compounds as shown in Formula 1-1 and compounds as shown in Formula 2.

[0156] Preparation Example 1.

[0157] Compositions for antibacterial and preservation purposes are prepared by combining 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and hexane-1,2-diol compound as shown in Formula 2 in a weight ratio of 7:3.

[0158] Preparation Example 2.

[0159] Compositions for antibacterial and preservation purposes are prepared by combining 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and octane-1,2-diol compound as shown in Formula 2 in a weight ratio of 7:3.

[0160] Preparation Example 3.

[0161] Compositions for antibacterial and preservation purposes were prepared by combining 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and decane-1,2-diol compound as shown in Formula 2 in a weight ratio of 7:3.

[0162] Preparation Example 4.

[0163] Compositions for antibacterial and preservation purposes are prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and a hexylglycerol compound as shown in Formula 2 in a weight ratio of 7:3.

[0164] Preparation Example 5.

[0165] Compositions for antibacterial and preservation purposes are prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and an octylglycerol compound as shown in Formula 2 in a weight ratio of 7:3.

[0166] Preparation Example 6.

[0167] Compositions for antibacterial and preservation purposes are prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and an ethylhexylglycerol compound as shown in Formula 2 in a weight ratio of 7:3.

[0168] Preparation Example 7.

[0169] Compositions for antibacterial and preservation purposes were prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and a glyceryl monooctanoate compound as shown in Formula 2 in a weight ratio of 7:3.

[0170] Preparation Examples 8-14. Compositions for antibacterial and preservation purposes were prepared using 3-(dodecylamino)propane-1,2-diol compounds as shown in Formula 1-1 and compounds as shown in Formula 3.

[0171] Preparation Example 8.

[0172] Compositions for antibacterial and preservation purposes were prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and a cinnamaldehyde compound as shown in Formula 3 in a weight ratio of 7:3.

[0173] Preparation Example 9.

[0174] Compositions for antibacterial and preservation purposes were prepared by combining 3-(dodecylamino)propane-1,2-diol (as shown in Formula 1-1) and 2-methoxycinnamonaldehyde (as shown in Formula 3) in a weight ratio of 7:3.

[0175] Preparation Example 10.

[0176] Compositions for antibacterial and preservation purposes were prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and a raspberry ketone compound as shown in Formula 3 in a weight ratio of 7:3.

[0177] Preparation Example 11.

[0178] Compositions for antibacterial and preservation purposes are prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and a 3-phenyl-1-propanol compound as shown in Formula 3 in a weight ratio of 7:3.

[0179] Preparation Example 12.

[0180] Compositions for antibacterial and preservation purposes were prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and a 4-hydroxyacetophenone compound as shown in Formula 3 in a weight ratio of 7:3.

[0181] Preparation Example 13.

[0182] Compositions for antibacterial and preservation purposes are prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and a sodium benzoate compound as shown in Formula 3 in a weight ratio of 7:3.

[0183] Preparation Example 14.

[0184] Compositions for antibacterial and preservation purposes are prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and a phenoxyethanol compound as shown in Formula 3 in a weight ratio of 7:3.

[0185] Preparation Examples 15-18. Compositions for antibacterial and preservation purposes were prepared using 3-(dodecylamino)propane-1,2-diol compounds as shown in Formula 1-1 and compounds as shown in Formula 4.

[0186] Preparation Example 15.

[0187] Compositions for antibacterial and preservation purposes are prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and a sodium dehydroacetate compound as shown in Formula 4 in a weight ratio of 7:3.

[0188] Preparation Example 16.

[0189] Compositions for antibacterial and preservation purposes were prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and an octyl isohydroxamic acid compound as shown in Formula 4 in a weight ratio of 7:3.

[0190] Preparation Example 17.

[0191] Compositions for antibacterial and preservation purposes were prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and a pyrrolidone ethanolamine compound as shown in Formula 4 in a weight ratio of 7:3.

[0192] Preparation Example 18.

[0193] Compositions for antibacterial and preservation purposes were prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and a lauroyl arginine ethyl ester compound as shown in Formula 4 in a weight ratio of 7:3.

[0194] Preparation Examples 19-23. Compositions for antibacterial and preservation purposes were prepared using 3-(dodecylamino)propane-1,2-diol compounds as shown in Formula 1-1 and compounds as shown in Formula 5.

[0195] Preparation Example 19.

[0196] Compositions for antibacterial and preservation purposes are prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and an levulinic acid compound as shown in Formula 5 in a weight ratio of 7:3.

[0197] Preparation Example 20.

[0198] Compositions for antibacterial and preservation purposes are prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and a citric acid compound as shown in Formula 5 in a weight ratio of 7:3.

[0199] Preparation Example 21.

[0200] Compositions for antibacterial and preservation purposes were prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and a sodium anisinate compound as shown in Formula 5 in a weight ratio of 7:3.

[0201] Preparation Example 22.

[0202] Compositions for antibacterial and preservation purposes were prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and a disodium ethylenediaminetetraacetate compound as shown in Formula 5 in a weight ratio of 7:3.

[0203] Preparation Example 23.

[0204] Compositions for antibacterial and preservation purposes were prepared by combining a 3-(dodecylamino)propane-1,2-diol compound as shown in Formula 1-1 and a tetrasodium ethylenediaminetetraacetate compound as shown in Formula 5 in a weight ratio of 7:3.

[0205] Comparative Examples 1-8

[0206] Comparative Example 1.

[0207] The compound used is 3-(dodecylamino)propane-1,2-diol, as shown in Formula 1.

[0208] Compare Example 2.

[0209] Hexane-1,2-diol, as shown in Formula 2, is used.

[0210] Comparative Example 3.

[0211] The octane-1,2-diol compound, as shown in Formula 2, is used.

[0212] Comparative Example 4.

[0213] The compound used is decane-1,2-diol, as shown in Formula 2.

[0214] Comparative Example 5.

[0215] Use a compound such as hexylglycerin as shown in Formula 2.

[0216] Comparative Example 6.

[0217] Use octylglycerin, as shown in Formula 2.

[0218] Compare Example 7.

[0219] The compound ethylhexylglycerin, as shown in formula 2, is used.

[0220] Compare Example 8.

[0221] Use glyceryl monocaprylate, as shown in formula 2.

[0222] Comparative Examples 9-15

[0223] Comparative Example 9.

[0224] Use cinnamaldehyde, a compound represented by chemical formula 3.

[0225] Comparative Example 10.

[0226] The compound 2-methoxychinnamaldhide, as shown in formula 3, is used.

[0227] Comparative Example 11.

[0228] Use the raspberry ketone compound as shown in formula 3.

[0229] Comparative Example 12.

[0230] The compound 3-phenyl-1-propanol, as shown in Formula 3, is used.

[0231] Comparative Example 13.

[0232] The compound used is 4-hydroxyacetophenone, as shown in Formula 3.

[0233] Comparative Example 14.

[0234] Sodium benzoate, as shown in chemical formula 3, is used.

[0235] Comparative Example 15.

[0236] Use phenoxyethanol (Phenoxy EtOH) as shown in chemical formula 3.

[0237] Comparative Examples 16–19

[0238] Comparative Example 16.

[0239] Sodium dehydroacetate, as shown in chemical formula 4, is used.

[0240] Comparative Example 17.

[0241] The compound used is caprylhydroxamic acid, as shown in chemical formula 4.

[0242] Comparative Example 18.

[0243] The compound used is pyroxone olamine, as shown in formula 4.

[0244] Comparative Example 19.

[0245] The compound used is lauroyl arginine ethyl ester, as shown in chemical formula 4.

[0246] Comparative Examples 20-24

[0247] Comparative Example 20.

[0248] Use levulinic acid, as shown in chemical formula 5.

[0249] Comparative Example 21.

[0250] Use citric acid compounds as shown in chemical formula 5.

[0251] Comparative Example 22.

[0252] Sodium anisate, as shown in chemical formula 5, is used.

[0253] Comparative Example 23.

[0254] The compound used is disodium ethylenediaminetetraacetate (EDTA) as shown in formula 5.

[0255] Comparative Example 24.

[0256] Tetrasodium EDTA, as shown in Formula 5, is used.

[0257] Example

[0258] All products used in the following examples were purchased from Sigma-Aldrich Korea and TCI, among others.

[0259] Examples 1-23: Liquid detergent compositions for laundry

[0260] Example 1.

[0261] A liquid detergent composition for clothing is prepared, comprising 6% by weight lauryl ether-7, 3% by weight alkylbenzene sulfonate, 5% by weight sodium lauryl ether-2 sulfate, 0.3% by weight protease, 0.3% by weight lipase, 1% by weight coconut oil fatty acid soap, 2% by weight salt, 0.2% by weight fragrance, 81.7% by weight purified water, and 0.5% by weight the composition for antibacterial and preservation prepared according to Preparation Example 1.

[0262] Example 2.

[0263] Except that the antibacterial and preservative composition prepared according to Preparation Example 2 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 1, the liquid detergent composition for clothing was prepared by the same method as in Example 1.

[0264] Example 3.

[0265] Except that the antibacterial and preservative composition prepared according to Preparation Example 3 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 1, the liquid detergent composition for clothing was prepared by the same method as in Example 1.

[0266] Example 4.

[0267] Except that the antibacterial and preservative composition prepared according to Preparation Example 4 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 1, the liquid detergent composition for clothing was prepared by the same method as in Example 1.

[0268] Example 5.

[0269] Except that the antibacterial and preservative composition prepared according to Preparation Example 5 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 1, the liquid detergent composition for clothing was prepared by the same method as in Example 1.

[0270] Example 6.

[0271] Except that the antibacterial and preservative composition prepared according to Preparation Example 6 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 1, the liquid detergent composition for clothing was prepared by the same method as in Example 1.

[0272] Example 7.

[0273] Except that the antibacterial and preservative composition prepared according to Preparation Example 7 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 1, the liquid detergent composition for clothing was prepared by the same method as in Example 1.

[0274] Example 8.

[0275] A liquid detergent composition for clothing is prepared, comprising 6% by weight lauryl ether-7, 3% by weight alkylbenzene sulfonate, 5% by weight sodium lauryl ether-2 sulfate, 0.3% by weight protease, 0.3% by weight lipase, 1% by weight coconut oil fatty acid soap, 2% by weight salt, 0.2% by weight fragrance, 81.7% by weight purified water, and 0.5% by weight the composition for antibacterial and preservation prepared according to Preparation Example 8.

[0276] Example 9.

[0277] Except that the antibacterial and preservative composition prepared according to Preparation Example 9 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 8, the liquid detergent composition for clothing was prepared by the same method as in Example 8.

[0278] Example 10.

[0279] Except that the antibacterial and preservative composition prepared according to Preparation Example 10 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 8, the liquid detergent composition for clothing was prepared by the same method as in Example 8.

[0280] Example 11.

[0281] Except that the antibacterial and preservative composition prepared according to Preparation Example 11 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 8, the liquid detergent composition for clothing was prepared by the same method as in Example 8.

[0282] Example 12.

[0283] Except that the antibacterial and preservative composition prepared according to Preparation Example 12 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 8, the liquid detergent composition for clothing was prepared by the same method as in Example 8.

[0284] Example 13.

[0285] Except that the antibacterial and preservative composition prepared according to Preparation Example 13 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 8, the liquid detergent composition for clothing was prepared by the same method as in Example 8.

[0286] Example 14.

[0287] Except that the antibacterial and preservative composition prepared according to Preparation Example 14 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 8, the liquid detergent composition for clothing was prepared by the same method as in Example 8.

[0288] Example 15.

[0289] A liquid detergent composition for clothing is prepared, comprising 6% by weight lauryl ether-7, 3% by weight alkylbenzene sulfonate, 5% by weight sodium lauryl ether-2 sulfate, 0.3% by weight protease, 0.3% by weight lipase, 1% by weight coconut oil fatty acid soap, 2% by weight salt, 0.2% by weight fragrance, 81.7% by weight purified water, and 0.5% by weight the composition for antibacterial and preservation prepared according to Preparation Example 15.

[0290] Example 16.

[0291] Except that the antibacterial and preservative composition prepared according to Preparation Example 16 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 15, the liquid detergent composition for clothing was prepared by the same method as in Example 15.

[0292] Example 17.

[0293] Except that the antibacterial and preservative composition prepared according to Preparation Example 17 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 15, the liquid detergent composition for clothing was prepared by the same method as in Example 15.

[0294] Example 18.

[0295] Except that the antibacterial and preservative composition prepared according to Preparation Example 18 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 15, the liquid detergent composition for clothing was prepared by the same method as in Example 15.

[0296] Example 19.

[0297] A liquid detergent composition for clothing is prepared, comprising 6% by weight lauryl ether-7, 3% by weight alkylbenzene sulfonate, 5% by weight sodium lauryl ether-2 sulfate, 0.3% by weight protease, 0.3% by weight lipase, 1% by weight coconut oil fatty acid soap, 2% by weight salt, 0.2% by weight fragrance, 81.7% by weight purified water, and 0.5% by weight the composition for antibacterial and preservation prepared according to Preparation Example 19.

[0298] Example 20.

[0299] Except that the antibacterial and preservative composition prepared according to Preparation Example 20 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 19, the liquid detergent composition for clothing was prepared by the same method as in Example 19.

[0300] Example 21.

[0301] Except that the antibacterial and preservative composition prepared according to Preparation Example 21 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 19, the liquid detergent composition for clothing was prepared by the same method as in Example 19.

[0302] Example 22.

[0303] Except that the antibacterial and preservative composition prepared according to Preparation Example 22 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 19, the liquid detergent composition for clothing was prepared by the same method as in Example 19.

[0304] Example 23.

[0305] Except that the antibacterial and preservative composition prepared according to Preparation Example 23 was used instead of the antibacterial and preservative composition prepared according to Preparation Example 19, the liquid detergent composition for clothing was prepared by the same method as in Example 19.

[0306] Examples 24-46: Kitchen Cleaning Compositions

[0307] Example 24.

[0308] A kitchen cleaning composition is prepared comprising 5% by weight sodium lauryl ether-2 sulfate, 4% by weight α-alkenyl sulfonate, 2% by weight amine oxide, 2% by weight alkyl glycoside, 2% by weight alkylbenzene sulfonate, 2% by weight glycerin, 0.2% by weight fragrance, 82.5% by weight purified water, and 0.3% by weight of the composition for antibacterial and preservation prepared according to Preparation Example 1.

[0309] Example 25.

[0310] Except that the composition for antibacterial and preservation prepared according to Preparation Example 2 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1, the kitchen cleaning composition was prepared by the same method as in Example 24.

[0311] Example 26.

[0312] Except that the composition for antibacterial and preservation prepared according to Preparation Example 3 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1, the kitchen cleaning composition was prepared by the same method as in Example 24.

[0313] Example 27.

[0314] Except that the composition for antibacterial and preservation prepared according to Preparation Example 4 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1, the kitchen cleaning composition was prepared by the same method as in Example 24.

[0315] Example 28.

[0316] Except that the composition for antibacterial and preservation prepared according to Preparation Example 5 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1, the kitchen cleaning composition was prepared by the same method as in Example 24.

[0317] Example 29.

[0318] Except that the composition for antibacterial and preservation prepared according to Preparation Example 6 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1, the kitchen cleaning composition was prepared by the same method as in Example 24.

[0319] Example 30.

[0320] Except that the composition for antibacterial and preservation prepared according to Preparation Example 7 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1, the kitchen cleaning composition was prepared by the same method as in Example 24.

[0321] Example 31.

[0322] A kitchen cleaner composition is prepared comprising 5% by weight sodium lauryl ether-2 sulfate, 4% by weight α-alkenyl sulfonate, 2% by weight amine oxide, 2% by weight alkyl glycoside, 2% by weight alkylbenzene sulfonate, 2% by weight glycerin, 0.2% by weight fragrance, 82.5% by weight purified water, and 0.3% by weight of the composition for antibacterial and preservation prepared according to Preparation Example 8.

[0323] Example 32.

[0324] Except that the composition for antibacterial and preservation prepared according to Preparation Example 9 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the kitchen cleaning composition was prepared by the same method as in Example 31.

[0325] Example 33.

[0326] Except that the composition for antibacterial and preservation prepared according to Preparation Example 10 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the kitchen cleaning composition was prepared by the same method as in Example 31.

[0327] Example 34.

[0328] Except that the composition for antibacterial and preservation prepared according to Preparation Example 11 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the kitchen cleaning composition was prepared by the same method as in Example 31.

[0329] Example 35.

[0330] Except that the composition for antibacterial and preservation prepared according to Preparation Example 12 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the kitchen cleaning composition was prepared by the same method as in Example 31.

[0331] Example 36.

[0332] Except that the composition for antibacterial and preservation prepared according to Preparation Example 13 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the kitchen cleaning composition was prepared by the same method as in Example 31.

[0333] Example 37.

[0334] Except that the composition for antibacterial and preservation prepared according to Preparation Example 14 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the kitchen cleaning composition was prepared by the same method as in Example 31.

[0335] Example 38.

[0336] A kitchen cleaning composition is prepared comprising 5% by weight sodium lauryl ether-2 sulfate, 4% by weight α-alkenyl sulfonate, 2% by weight amine oxide, 2% by weight alkyl glycoside, 2% by weight alkylbenzene sulfonate, 2% by weight glycerin, 0.2% by weight fragrance, 82.5% by weight purified water, and 0.3% by weight of the composition for antibacterial and preservation prepared according to Preparation Example 15.

[0337] Example 39.

[0338] Except that the composition for antibacterial and preservation prepared according to Preparation Example 16 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 15, the kitchen cleaning composition was prepared by the same method as in Example 38.

[0339] Example 40.

[0340] Except that the composition for antibacterial and preservation prepared according to Preparation Example 17 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 15, the kitchen cleaning composition was prepared by the same method as in Example 38.

[0341] Example 41.

[0342] Except that the composition for antibacterial and preservation prepared according to Preparation Example 18 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 15, the kitchen cleaning composition was prepared by the same method as in Example 38.

[0343] Example 42.

[0344] A kitchen cleaner composition is prepared comprising 5% by weight sodium lauryl ether-2 sulfate, 4% by weight α-alkenyl sulfonate, 2% by weight amine oxide, 2% by weight alkyl glycoside, 2% by weight alkylbenzene sulfonate, 2% by weight glycerin, 0.2% by weight fragrance, 82.5% by weight purified water, and 0.3% by weight of the composition for antibacterial and preservation prepared according to Preparation Example 19.

[0345] Example 43.

[0346] Except that the composition for antibacterial and preservation prepared according to Preparation Example 20 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 19, the kitchen cleaning composition was prepared by the same method as in Example 42.

[0347] Example 44.

[0348] Except that the composition for antibacterial and preservation prepared according to Preparation Example 21 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 19, the kitchen cleaning composition was prepared by the same method as in Example 42.

[0349] Example 45.

[0350] Except that the composition for antibacterial and preservation prepared according to Preparation Example 22 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 19, the kitchen cleaning composition was prepared by the same method as in Example 42.

[0351] Example 46.

[0352] Except that the composition for antibacterial and preservation prepared according to Preparation Example 23 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 19, the kitchen cleaning composition was prepared by the same method as in Example 42.

[0353] Examples 47-69: Wet Wipes Stock Solution Composition

[0354] Example 47.

[0355] Prepare a wet wipe stock solution composition comprising 1% by weight of a natural extract, 98.7% by weight of purified water, and 0.3% by weight of the antibacterial and preservation composition prepared according to Preparation Example 1.

[0356] Example 48.

[0357] Except that the composition for antibacterial and preservation prepared according to Preparation Example 2 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1, the wet wipe stock solution composition was prepared by the same method as in Example 47.

[0358] Example 49.

[0359] Except that the composition for antibacterial and preservation prepared according to Preparation Example 3 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1, the wet wipe stock solution composition was prepared by the same method as in Example 47.

[0360] Example 50.

[0361] Except that the composition for antibacterial and preservation prepared according to Preparation Example 4 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1, the wet wipe stock solution composition was prepared by the same method as in Example 47.

[0362] Example 51.

[0363] Except that the composition for antibacterial and preservation prepared according to Preparation Example 5 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1, the wet wipe stock solution composition was prepared by the same method as in Example 47.

[0364] Example 52.

[0365] Except that the composition for antibacterial and preservation prepared according to Preparation Example 6 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1, the wet wipe stock solution composition was prepared by the same method as in Example 47.

[0366] Example 53.

[0367] Except that the composition for antibacterial and preservation prepared according to Preparation Example 7 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1, the wet wipe stock solution composition was prepared by the same method as in Example 47.

[0368] Example 54.

[0369] Prepare a wet wipe stock solution composition comprising 1% by weight of a natural extract, 98.7% by weight of purified water, and 0.3% by weight of the composition for antibacterial and preservation prepared according to Preparation Example 8.

[0370] Example 55.

[0371] Except that the composition for antibacterial and preservation prepared according to Preparation Example 9 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the wet wipe stock solution composition was prepared by the same method as in Example 54.

[0372] Example 56.

[0373] Except that the composition for antibacterial and preservation prepared according to Preparation Example 10 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the wet wipe stock solution composition was prepared by the same method as in Example 54.

[0374] Example 57.

[0375] Except that the composition for antibacterial and preservation prepared according to Preparation Example 11 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the wet wipe stock solution composition was prepared by the same method as in Example 54.

[0376] Example 58.

[0377] Except that the composition for antibacterial and preservation prepared according to Preparation Example 12 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the wet wipe stock solution composition was prepared by the same method as in Example 54.

[0378] Example 59.

[0379] Except that the composition for antibacterial and preservation prepared according to Preparation Example 13 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the wet wipe stock solution composition was prepared by the same method as in Example 54.

[0380] Example 60.

[0381] Except that the composition for antibacterial and preservation prepared according to Preparation Example 14 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the wet wipe stock solution composition was prepared by the same method as in Example 54.

[0382] Example 61.

[0383] Prepare a wet wipe stock solution composition comprising 1% by weight of a natural extract, 98.7% by weight of purified water, and 0.3% by weight of the composition for antibacterial and preservation prepared according to Preparation Example 15.

[0384] Example 62.

[0385] Except that the composition for antibacterial and preservation prepared according to Preparation Example 16 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 15, the wet wipe stock solution composition was prepared by the same method as in Example 61.

[0386] Example 63.

[0387] Except that the composition for antibacterial and preservation prepared according to Preparation Example 17 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 15, the wet wipe stock solution composition was prepared by the same method as in Example 61.

[0388] Example 64.

[0389] Except that the composition for antibacterial and preservation prepared according to Preparation Example 18 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 15, the wet wipe stock solution composition was prepared by the same method as in Example 61.

[0390] Example 65.

[0391] Prepare a wet wipe stock solution composition comprising 1% by weight of a natural extract, 98.7% by weight of purified water, and 0.3% by weight of the composition for antibacterial and preservation prepared according to Preparation Example 19.

[0392] Example 66.

[0393] Except that the composition for antibacterial and preservation prepared according to Preparation Example 20 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 19, the wet wipe stock solution composition was prepared by the same method as in Example 65.

[0394] Example 67.

[0395] Except that the composition for antibacterial and preservation prepared according to Preparation Example 21 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 19, the wet wipe stock solution composition was prepared by the same method as in Example 65.

[0396] Example 68.

[0397] Except that the composition for antibacterial and preservation prepared according to Preparation Example 22 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 19, the wet wipe stock solution composition was prepared by the same method as in Example 65.

[0398] Example 69.

[0399] Except that the composition for antibacterial and preservation prepared according to Preparation Example 23 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 19, the wet wipe stock solution composition was prepared by the same method as in Example 65.

[0400] Examples 70-92: Shampoo concentrate compositions

[0401] Example 70.

[0402] A shampoo stock solution composition was prepared comprising 0.05% by weight of disodium EDTA, 0.1% by weight of panthenol, 1% by weight of glycerin, 1% by weight of tocopheryl acetate, 0.5% by weight of polyquaternium-7, 8% by weight of sodium lauryl sulfate, 5% by weight of cocamidopropyl betaine, 2% by weight of sodium cocoyl sarcosinate, 0.5% by weight of polyquaternium-10, 1% by weight of fragrance, 80.55% by weight of purified water, and 0.3% by weight of the composition prepared according to Preparation Example 1 for antibacterial and preservation purposes.

[0403] Example 71.

[0404] Except that the antibacterial and preservation composition prepared according to Preparation Example 2 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 1, the shampoo stock composition was prepared by the same method as in Example 70.

[0405] Example 72.

[0406] Except that the antibacterial and preservation composition prepared according to Preparation Example 3 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 1, the shampoo stock composition was prepared by the same method as in Example 70.

[0407] Example 73.

[0408] Except that the antibacterial and preservation composition prepared according to Preparation Example 4 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 1, the shampoo stock composition was prepared by the same method as in Example 70.

[0409] Example 74.

[0410] Except that the antibacterial and preservation composition prepared according to Preparation Example 5 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 1, the shampoo stock composition was prepared by the same method as in Example 70.

[0411] Example 75.

[0412] Except that the antibacterial and preservation composition prepared according to Preparation Example 6 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 1, the shampoo stock composition was prepared by the same method as in Example 70.

[0413] Example 76.

[0414] Except that the antibacterial and preservation composition prepared according to Preparation Example 7 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 1, the shampoo stock composition was prepared by the same method as in Example 70.

[0415] Example 77.

[0416] A shampoo stock solution composition was prepared comprising 0.05% by weight of disodium EDTA, 0.1% by weight of panthenol, 1% by weight of glycerin, 1% by weight of tocopheryl acetate, 0.5% by weight of polyquaternium-7, 8% by weight of sodium lauryl sulfate, 5% by weight of cocamidopropyl betaine, 2% by weight of sodium cocoyl sarcosinate, 0.5% by weight of polyquaternium-10, 1% by weight of fragrance, 80.55% by weight of purified water, and 0.3% by weight of the composition prepared according to Preparation Example 8 for antibacterial and preservation purposes.

[0417] Example 78.

[0418] Except that the antibacterial and preservation composition prepared according to Preparation Example 9 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 8, the shampoo stock composition was prepared by the same method as in Example 77.

[0419] Example 79.

[0420] Except that the antibacterial and preservation composition prepared according to Preparation Example 10 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 8, the shampoo stock composition was prepared by the same method as in Example 77.

[0421] Example 80.

[0422] Except that the antibacterial and preservation composition prepared according to Preparation Example 11 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 8, the shampoo stock composition was prepared by the same method as in Example 77.

[0423] Example 81.

[0424] Except that the antibacterial and preservation composition prepared according to Preparation Example 12 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 8, the shampoo stock composition was prepared by the same method as in Example 77.

[0425] Example 82.

[0426] Except that the antibacterial and preservation composition prepared according to Preparation Example 13 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 8, the shampoo stock composition was prepared by the same method as in Example 77.

[0427] Example 83.

[0428] Except that the antibacterial and preservation composition prepared according to Preparation Example 14 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 8, the shampoo stock composition was prepared by the same method as in Example 77.

[0429] Example 84.

[0430] A shampoo stock solution composition was prepared comprising 0.05% by weight of disodium EDTA, 0.1% by weight of panthenol, 1% by weight of glycerin, 1% by weight of tocopheryl acetate, 0.5% by weight of polyquaternium-7, 8% by weight of sodium lauryl sulfate, 5% by weight of cocamidopropyl betaine, 2% by weight of sodium cocoyl sarcosinate, 0.5% by weight of polyquaternium-10, 1% by weight of fragrance, 80.55% by weight of purified water, and 0.3% by weight of the composition prepared according to Preparation Example 15 for antibacterial and preservation purposes.

[0431] Example 85.

[0432] Except that the antibacterial and preservation composition prepared according to Preparation Example 16 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 15, the shampoo stock composition was prepared by the same method as in Example 84.

[0433] Example 86.

[0434] Except that the antibacterial and preservation composition prepared according to Preparation Example 17 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 15, the shampoo stock composition was prepared by the same method as in Example 84.

[0435] Example 87.

[0436] Except that the antibacterial and preservation composition prepared according to Preparation Example 18 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 15, the shampoo stock composition was prepared by the same method as in Example 84.

[0437] Example 88.

[0438] A shampoo stock solution composition is prepared comprising 0.05% by weight of disodium EDTA, 0.1% by weight of panthenol, 1% by weight of glycerin, 1% by weight of tocopheryl acetate, 0.5% by weight of polyquaternium-7, 8% by weight of sodium lauryl sulfate, 5% by weight of cocamidopropyl betaine, 2% by weight of sodium cocoyl sarcosinate, 0.5% by weight of polyquaternium-10, 1% by weight of fragrance, 80.55% by weight of purified water, and 0.3% by weight of the composition prepared according to Preparation Example 19 for antibacterial and preservation purposes.

[0439] Example 89.

[0440] Except that the antibacterial and preservation composition prepared according to Preparation Example 20 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 19, the shampoo stock composition was prepared by the same method as in Example 88.

[0441] Example 90.

[0442] Except that the antibacterial and preservation composition prepared according to Preparation Example 21 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 19, the shampoo stock composition was prepared by the same method as in Example 88.

[0443] Example 91.

[0444] Except that the antibacterial and preservation composition prepared according to Preparation Example 22 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 19, the shampoo stock composition was prepared by the same method as in Example 88.

[0445] Example 92.

[0446] Except that the antibacterial and preservation composition prepared according to Preparation Example 23 was used instead of the antibacterial and preservation composition prepared according to Preparation Example 19, the shampoo stock composition was prepared by the same method as in Example 88.

[0447] Examples 93-115: Cosmetic face cream concentrate composition

[0448] Example 93.

[0449] A face cream stock composition was prepared comprising 2.5 wt% cetearyl alcohol, 1.5 wt% glyceryl stearate, 5.0 wt% glyceryl tricaprylate, 1.2 wt% polysorbate 60, 0.5 wt% sorbitan stearate, 5.0 wt% squalane, 3.0 wt% liquid paraffin, 3.0 wt% cyclomethicone, 0.2 wt% δ-tocopherol, 4.0 wt% glycerin, 2.0 wt% 1,3-butanediol, 0.2 wt% xanthan gum, 0.05 wt% disodium ethylenediaminetetraacetate (EDTA-2Na), 0.1 wt% fragrance, 71.55 wt% purified water, and 0.2 wt% of the composition prepared according to Preparation Example 1 for antibacterial and preservation purposes.

[0450] Example 94.

[0451] The cosmetic cream stock solution composition was prepared by the same method as in Example 93, except that the composition for antibacterial and preservation prepared according to Preparation Example 2 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1.

[0452] Example 95.

[0453] The cosmetic cream stock solution composition was prepared by the same method as in Example 93, except that the composition for antibacterial and preservation prepared according to Preparation Example 3 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1.

[0454] Example 96.

[0455] The cosmetic cream stock composition was prepared by the same method as in Example 93, except that the composition for antibacterial and preservation prepared according to Preparation Example 4 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1.

[0456] Example 97.

[0457] The cosmetic cream stock solution composition was prepared by the same method as in Example 93, except that the composition for antibacterial and preservation prepared according to Preparation Example 5 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1.

[0458] Example 98.

[0459] The cosmetic cream stock solution composition was prepared by the same method as in Example 93, except that the composition for antibacterial and preservation prepared according to Preparation Example 6 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1.

[0460] Example 99.

[0461] The cosmetic cream stock solution composition was prepared by the same method as in Example 93, except that the composition for antibacterial and preservation prepared according to Preparation Example 7 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1.

[0462] Example 100.

[0463] A face cream stock composition was prepared comprising 2.5 wt% cetearyl alcohol, 1.5 wt% glyceryl stearate, 5.0 wt% glyceryl tricaprylate, 1.2 wt% polysorbate 60, 0.5 wt% sorbitan stearate, 5.0 wt% squalane, 3.0 wt% liquid paraffin, 3.0 wt% cyclomethicone, 0.2 wt% δ-tocopherol, 4.0 wt% glycerin, 2.0 wt% 1,3-butanediol, 0.2 wt% xanthan gum, 0.05 wt% disodium ethylenediaminetetraacetate (EDTA-2Na), 0.1 wt% fragrance, 71.55 wt% purified water, and 0.2 wt% of the composition prepared according to Preparation Example 8 for antibacterial and preservation purposes.

[0464] Example 101.

[0465] Except that the composition for antibacterial and preservation prepared according to Preparation Example 9 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the cosmetic cream stock composition was prepared by the same method as in Example 100.

[0466] Example 102.

[0467] Except that the composition for antibacterial and preservation prepared according to Preparation Example 10 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the cosmetic cream stock composition was prepared by the same method as in Example 100.

[0468] Example 103.

[0469] Except that the composition for antibacterial and preservation prepared according to Preparation Example 11 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the cosmetic cream stock composition was prepared by the same method as in Example 100.

[0470] Example 104.

[0471] Except that the composition for antibacterial and preservation prepared according to Preparation Example 12 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the cosmetic cream stock composition was prepared by the same method as in Example 100.

[0472] Example 105.

[0473] Except that the composition for antibacterial and preservation prepared according to Preparation Example 13 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the cosmetic cream stock composition was prepared by the same method as in Example 100.

[0474] Example 106.

[0475] Except that the composition for antibacterial and preservation prepared according to Preparation Example 14 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8, the cosmetic cream stock composition was prepared by the same method as in Example 100.

[0476] Example 107.

[0477] A face cream stock composition was prepared comprising 2.5 wt% cetearyl alcohol, 1.5 wt% glyceryl stearate, 5.0 wt% glyceryl tricaprylate, 1.2 wt% polysorbate 60, 0.5 wt% sorbitan stearate, 5.0 wt% squalane, 3.0 wt% liquid paraffin, 3.0 wt% cyclomethicone, 0.2 wt% δ-tocopherol, 4.0 wt% glycerin, 2.0 wt% 1,3-butanediol, 0.2 wt% xanthan gum, 0.05 wt% disodium ethylenediaminetetraacetate (EDTA-2Na), 0.1 wt% fragrance, 71.55 wt% purified water, and 0.2 wt% of the composition prepared according to Preparation Example 15 for antibacterial and preservation purposes.

[0478] Example 108.

[0479] The cosmetic cream stock solution composition was prepared by the same method as in Example 107, except that the composition for antibacterial and preservation prepared according to Preparation Example 16 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 15.

[0480] Example 109.

[0481] Except that the composition for antibacterial and preservation prepared according to Preparation Example 17 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 15, the cosmetic cream stock composition was prepared by the same method as in Example 107.

[0482] Example 110.

[0483] Except that the composition for antibacterial and preservation prepared according to Preparation Example 18 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 15, the cosmetic cream stock composition was prepared by the same method as in Example 107.

[0484] Example 111.

[0485] A face cream stock composition was prepared comprising 2.5 wt% cetearyl alcohol, 1.5 wt% glyceryl stearate, 5.0 wt% glyceryl tricaprylate, 1.2 wt% polysorbate 60, 0.5 wt% sorbitan stearate, 5.0 wt% squalane, 3.0 wt% liquid paraffin, 3.0 wt% cyclomethicone, 0.2 wt% δ-tocopherol, 4.0 wt% glycerin, 2.0 wt% 1,3-butanediol, 0.2 wt% xanthan gum, 0.05 wt% disodium ethylenediaminetetraacetate (EDTA-2Na), 0.1 wt% fragrance, 71.55 wt% purified water, and 0.2 wt% of the composition prepared according to Preparation Example 19 for antibacterial and preservation purposes.

[0486] Example 112.

[0487] Except that the composition for antibacterial and preservation prepared according to Preparation Example 20 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 19, the cosmetic cream stock composition was prepared by the same method as in Example 111.

[0488] Example 113.

[0489] Except that the composition for antibacterial and preservation prepared according to Preparation Example 21 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 19, the cosmetic cream stock composition was prepared by the same method as in Example 111.

[0490] Example 114.

[0491] Except that the composition for antibacterial and preservation prepared according to Preparation Example 22 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 19, the cosmetic cream stock composition was prepared by the same method as in Example 111.

[0492] Example 115.

[0493] Except that the composition for antibacterial and preservation prepared according to Preparation Example 23 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 19, the cosmetic cream stock composition was prepared by the same method as in Example 111.

[0494] Examples 116-138: Cosmetic Powder Compact (Solid Makeup) Compositions

[0495] Example 116.

[0496] A powder compact (solid makeup) composition was prepared comprising 25% by weight of spherical powder (Silica-HDI), 10% by weight of calcium aluminum borosilicate, 20% by weight of oily binder silicone oil (dimethicone), 0.2% by weight of fragrance, 5% by weight of pigment, 20% by weight of ethanol, 19.4% by weight of plate-shaped talc (Talc JA 46R), and 0.4% by weight of the composition for antibacterial and preservation prepared according to Preparation Example 1.

[0497] Example 117.

[0498] The cosmetic powder composition was prepared by the same method as in Example 116, except that the composition for antibacterial and preservation prepared according to Preparation Example 2 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1.

[0499] Example 118.

[0500] The cosmetic powder composition was prepared by the same method as in Example 116, except that the composition for antibacterial and preservation prepared according to Preparation Example 3 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1.

[0501] Example 119.

[0502] The cosmetic powder composition was prepared by the same method as in Example 116, except that the composition for antibacterial and preservation prepared according to Preparation Example 4 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1.

[0503] Example 120.

[0504] The cosmetic powder composition was prepared by the same method as in Example 116, except that the composition for antibacterial and preservation prepared according to Preparation Example 5 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1.

[0505] Example 121.

[0506] The cosmetic powder composition was prepared by the same method as in Example 116, except that the composition for antibacterial and preservation prepared according to Preparation Example 6 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1.

[0507] Example 122.

[0508] The cosmetic powder composition was prepared by the same method as in Example 116, except that the composition for antibacterial and preservation prepared according to Preparation Example 7 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 1.

[0509] Example 123.

[0510] A powder compact (solid makeup) composition is prepared comprising 25% by weight of spherical powder (Silica-HDI), 10% by weight of calcium aluminum borosilicate, 20% by weight of oily binder silicone oil (dimethicone), 0.2% by weight of fragrance, 5% by weight of pigment, 20% by weight of ethanol, 19.4% by weight of plate-shaped talc (Talc JA 46R), and 0.4% by weight of the composition for antibacterial and preservation prepared according to Preparation Example 8.

[0511] Example 124.

[0512] The cosmetic powder composition was prepared by the same method as in Example 123, except that the composition for antibacterial and preservation prepared according to Preparation Example 9 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8.

[0513] Example 125.

[0514] The cosmetic powder composition was prepared by the same method as in Example 123, except that the composition for antibacterial and preservation prepared according to Preparation Example 10 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8.

[0515] Example 126.

[0516] The cosmetic powder composition was prepared by the same method as in Example 123, except that the composition for antibacterial and preservation prepared according to Preparation Example 11 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8.

[0517] Example 127.

[0518] The cosmetic powder composition was prepared by the same method as in Example 123, except that the composition for antibacterial and preservation prepared according to Preparation Example 12 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8.

[0519] Example 128.

[0520] The cosmetic powder composition was prepared by the same method as in Example 123, except that the composition for antibacterial and preservation prepared according to Preparation Example 13 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8.

[0521] Example 129.

[0522] The cosmetic powder composition was prepared by the same method as in Example 123, except that the composition for antibacterial and preservation prepared according to Preparation Example 14 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 8.

[0523] Example 130.

[0524] A powder compact (solid makeup) composition is prepared comprising 25% by weight of spherical powder (Silica-HDI), 10% by weight of calcium aluminum borosilicate, 20% by weight of oily binder silicone oil (dimethicone), 0.2% by weight of fragrance, 5% by weight of pigment, 20% by weight of ethanol, 19.4% by weight of plate-shaped talc (Talc JA 46R), and 0.4% by weight of the composition for antibacterial and preservation prepared according to Preparation Example 15.

[0525] Example 131.

[0526] The cosmetic powder composition was prepared by the same method as in Example 130, except that the composition for antibacterial and preservation prepared according to Preparation Example 16 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 15.

[0527] Example 132.

[0528] The cosmetic powder composition was prepared by the same method as in Example 130, except that the composition for antibacterial and preservation prepared according to Preparation Example 17 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 15.

[0529] Example 133.

[0530] The cosmetic powder composition was prepared by the same method as in Example 130, except that the composition for antibacterial and preservation prepared according to Preparation Example 18 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 15.

[0531] Example 134.

[0532] A powder compact (solid makeup) composition is prepared comprising 25% by weight of spherical powder (Silica-HDI), 10% by weight of calcium aluminum borosilicate, 20% by weight of oily binder silicone oil (dimethicone), 0.2% by weight of fragrance, 5% by weight of pigment, 20% by weight of ethanol, 19.4% by weight of plate-shaped talc (Talc JA 46R), and 0.4% by weight of the composition for antibacterial and preservation prepared according to Preparation Example 19.

[0533] Example 135.

[0534] The cosmetic powder composition was prepared by the same method as in Example 134, except that the composition for antibacterial and preservation prepared according to Preparation Example 20 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 19.

[0535] Example 136.

[0536] The cosmetic powder composition was prepared by the same method as in Example 134, except that the composition for antibacterial and preservation prepared according to Preparation Example 21 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 19.

[0537] Example 137.

[0538] The cosmetic powder composition was prepared by the same method as in Example 134, except that the composition for antibacterial and preservation prepared according to Preparation Example 22 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 19.

[0539] Example 138.

[0540] The cosmetic powder composition was prepared by the same method as in Example 134, except that the composition for antibacterial and preservation prepared according to Preparation Example 23 was used instead of the composition for antibacterial and preservation prepared according to Preparation Example 19.

[0541] Experimental Example

[0542] Antimicrobial tests were conducted on each composition for antibacterial and preservation prepared according to the components of the comparative examples and preparation examples, as well as on each daily chemical product composition prepared according to the examples, against bacteria, fungi, and yeasts using the following methods.

[0543] method

[0544] Antibacterial test

[0545] The antibacterial activity of the test solution was determined using the broth dilution method. Test solutions were diluted to concentrations ranging from a maximum of 5% to a minimum of 0.0001%. Turbidity of the test tubes was confirmed after incubating the test solution and the bacterial strain together. In this case, the concentration of the test solution in tubes where no bacterial growth was observed, compared to the turbidity observed in tubes where only the bacterial strain was inoculated in the culture medium without treatment, was set as the minimum inhibitory concentration (MIC). After the first test as described above, a second test was conducted by further subdividing the treatment concentrations of the test solution to obtain the correct MIC.

[0546] 1) Pre-culture test bacteria

[0547] Escherichia coli, Staphylococcus aureus, and Pseudomonas aeruginosa, used as test strains, were inoculated into tryptic soy broth and cultured at 35±2℃ for 16–24 hours. Candida albicans was inoculated into Sabouraud dextrose broth and cultured at 35℃ for 24 hours. Aspergillus niger was spread onto potato dextrose agar and cultured at (25±1)℃ for 7 days. Sterile physiological saline was dispensed onto the solid culture medium containing bacteria, and spores were scraped off using a spreader and diluted in sterile physiological saline.

[0548] 2) Preparation of test solution

[0549] The antibacterial and preservation compositions of Preparation Examples 1 to 23 were dissolved in dipropylene glycol to be used as test solutions.

[0550] Comparative Examples 1 to 24 were used as comparative solutions.

[0551] 3) Mixed bacterial strains and compositions (test solutions) for antibacterial and preservation purposes.

[0552] After adding liquid culture medium to the test tubes, add test solutions diluted to a maximum concentration from 5% to a minimum concentration of 0.0001%. Tryptic Soy Broth was used as the liquid culture medium for Escherichia coli, Staphylococcus aureus, and Pseudomonas aeruginosa (bacteria), while Sabouraud Dextrose Broth was used as the liquid culture medium for Candida albicans and Aspergillus niger (fungi).

[0553] 4) Inoculate with test bacterial solution

[0554] Escherichia coli (E. coli), Staphylococcus aureus (S. aureus), and Pseudomonas aeruginosa (P. aeruginosa) were inoculated to achieve a bacterial concentration of 1 × 10⁻⁶ in the test tube. 5CFU / mL. The test tubes treated with the test solution were incubated at 35±2℃ for 16–24 hours. Candida albicans and Aspergillus niger were inoculated to achieve a bacterial concentration of 1×10⁻⁶ CFU / mL. 4 CFU / mL. After treatment with the test solution, *Candida albicans* was cultured at 35°C for 24–48 hours, and *Aspergillus niger* was cultured at 25°C for 46–50 hours. Tubes containing no bacterial culture were used as a negative control, and tubes inoculated only with bacterial culture but without the test solution were used as a growth control. Furthermore, to confirm the antibacterial activity of dipropylene glycol used as the solvent, the MIC of the test bacteria against the solvent was determined by applying the same test conditions as the sample.

[0555] Test results

[0556] The test results are shown in Tables 1 to 32. The evaluation of the test results shows that the antibacterial and preservation composition of the present invention, and cosmetic, hygiene and daily chemical product compositions containing the antibacterial and preservation composition of the present invention, effectively inhibit bacteria, fungi and yeast.

[0557] Specifically, Tables 1 to 4 show the antibacterial effects of comparative examples, and Tables 5 to 8 show the antibacterial test results of the compositions prepared according to the preparation examples of the present invention for antibacterial and preservation against bacteria, fungi, and yeasts.

[0558] Table 1

[0559]

[0560] Table 2

[0561]

[0562] Table 3

[0563]

[0564]

[0565] Table 4

[0566]

[0567] Table 5

[0568]

[0569] Table 6

[0570]

[0571] Table 7

[0572]

[0573] Table 8

[0574]

[0575] Referring to Tables 1 and 5, compared with the individual compounds in Table 1, all the compositions prepared according to the present invention for antibacterial and preservation purposes exhibit excellent antibacterial effects against bacteria, fungi, and yeasts. In particular, it was confirmed that the composition for antibacterial and preservation of Preparation Example 3, which combines 3-(dodecylamino)propane-1,2-diol and decane-1,2-diol compounds, can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans).

[0576] Referring to Tables 1, 2, and 6, compared with the individual compounds in Tables 1 and 2, all the compositions prepared according to the present invention for antibacterial and preservation purposes exhibit excellent antibacterial effects against bacteria, fungi, and yeasts. In particular, it was confirmed that the composition for antibacterial and preservation of Preparation Example 13, which combines 3-(dodecylamino)propane-1,2-diol and sodium benzoate, can effectively inhibit bacteria (Escherichia coli, Staphylococcus aureus, and Pseudomonas aeruginosa).

[0577] Referring to Tables 1, 3, and 7, compared with the individual compounds in Tables 1 and 3, all the compositions prepared according to the present invention for antibacterial and preservation purposes exhibit excellent antibacterial effects against bacteria, fungi, and yeasts. In particular, it was confirmed that the composition for antibacterial and preservation of Preparation Example 18, which combines 3-(dodecylamino)propane-1,2-diol and lauroylarginine ethyl ester, can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans).

[0578] Referring to Tables 1, 4, and 8, compared with the individual compounds in Tables 1 and 4, all the compositions prepared according to the present invention for antibacterial and preservation purposes exhibit excellent antibacterial effects against bacteria, fungi, and yeasts. In particular, it was confirmed that the composition for antibacterial and preservation of Preparation Example 20, which combines 3-(dodecylamino)propane-1,2-diol and citric acid, can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans).

[0579] Tables 9 to 12: Antimicrobial test results of liquid laundry detergent compositions

[0580] Table 9 below shows the antimicrobial test results of the liquid laundry detergent compositions of Examples 1 to 7 against bacteria, fungi, and yeast.

[0581] Table 9

[0582]

[0583] Referring to Table 9, it was confirmed that the liquid detergent compositions for clothing according to Examples 1 to 7 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0584] Table 10 below shows the antimicrobial test results of the liquid laundry detergent compositions of Examples 8 to 14 against bacteria, fungi, and yeast.

[0585] Table 10

[0586]

[0587] Referring to Table 10, it was confirmed that the liquid detergent compositions for clothing according to Examples 8 to 14 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0588] Table 11 below shows the antimicrobial test results of the liquid laundry detergent compositions of Examples 15 to 18 against bacteria, fungi, and yeast.

[0589] Table 11

[0590]

[0591] Referring to Table 11, it was confirmed that the liquid detergent compositions for clothing according to Examples 15 to 18 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0592] Table 12 below shows the antimicrobial test results of the liquid laundry detergent compositions of Examples 19 to 23 against bacteria, fungi, and yeast.

[0593] Table 12

[0594]

[0595] Referring to Table 12, it was confirmed that the liquid detergent compositions for clothing according to Examples 19 to 23 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0596] Tables 13 to 16: Antimicrobial test results of kitchen cleaning agent compositions

[0597] Table 13 below shows the antimicrobial test results of the kitchen cleaning compositions of Examples 24 to 30 against bacteria, fungi, and yeast.

[0598] Table 13

[0599]

[0600] Referring to Table 13, it was confirmed that the kitchen cleaning compositions according to Examples 24 to 30 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0601] Table 14 below shows the antimicrobial test results of the kitchen cleaning compositions of Examples 31 to 37 against bacteria, fungi, and yeast.

[0602] Table 14

[0603]

[0604] Referring to Table 14, it was confirmed that the kitchen cleaning compositions according to Examples 31 to 37 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0605] Table 15 below shows the antimicrobial test results of the kitchen cleaning compositions of Examples 38 to 41 against bacteria, fungi, and yeast.

[0606] Table 15

[0607]

[0608] Referring to Table 15, it was confirmed that the kitchen cleaning compositions according to Examples 38 to 41 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0609] Table 16 below shows the antimicrobial test results of the kitchen cleaning compositions of Examples 42 to 46 against bacteria, fungi, and yeast.

[0610] Table 16

[0611]

[0612] Referring to Table 16, it was confirmed that the kitchen cleaning compositions according to Examples 42 to 46 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0613] Tables 17 to 20: Antibacterial test results of wet wipe stock solution compositions

[0614] Table 17 below shows the antibacterial test results of the wet wipe stock compositions of Examples 47 to 53 against bacteria, fungi, and yeast.

[0615] Table 17

[0616]

[0617]

[0618] Referring to Table 17, it was confirmed that the wet wipe stock solution compositions according to Examples 47 to 53 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0619] Table 18 below shows the antibacterial test results of the wet wipe stock compositions of Examples 54 to 60 against bacteria, fungi, and yeast.

[0620] Table 18

[0621]

[0622] Referring to Table 18, it was confirmed that the wet wipe stock solution compositions according to Examples 54 to 60 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0623] Table 19 below shows the antibacterial test results of the wet wipe stock compositions of Examples 61 to 64 against bacteria, fungi, and yeast.

[0624] Table 19

[0625]

[0626] Referring to Table 19, it was confirmed that the wet wipe stock solution compositions according to Examples 61 to 64 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0627] Table 20 below shows the antibacterial test results of the wet wipe stock compositions of Examples 65 to 69 against bacteria, fungi, and yeast.

[0628] Table 20

[0629]

[0630] Referring to Table 20, it was confirmed that the wet wipe stock solution compositions according to Examples 65 to 69 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0631] Tables 21 to 24: Antibacterial test results of shampoo concentrate compositions

[0632] Table 21 below shows the antibacterial test results of the shampoo stock compositions of Examples 70 to 76 against bacteria, fungi, and yeast.

[0633] Table 21

[0634]

[0635] Referring to Table 21, it was confirmed that the shampoo stock compositions according to Examples 70 to 76 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0636] Table 22 below shows the antibacterial test results of the shampoo stock compositions of Examples 77 to 83 against bacteria, fungi, and yeast.

[0637] Table 22

[0638]

[0639] Referring to Table 22, it was confirmed that the shampoo stock compositions according to Examples 77 to 83 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0640] Table 23 below shows the antibacterial test results of the shampoo stock compositions of Examples 84 to 87 against bacteria, fungi, and yeast.

[0641] Table 23

[0642]

[0643] According to Table 23, it was confirmed that the shampoo stock compositions according to Examples 84 to 87 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0644] Table 24 below shows the antibacterial test results of the shampoo stock compositions of Examples 88 to 92 against bacteria, fungi, and yeast.

[0645] Table 24

[0646]

[0647] Referring to Table 24, it was confirmed that the shampoo stock compositions according to Examples 88 to 92 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0648] Tables 25 to 28: Antibacterial Test Results of Cosmetic Face Cream Essence Compositions

[0649] Table 25 below shows the antibacterial test results of the cosmetic cream concentrate compositions of Examples 93 to 99 against bacteria, fungi, and yeast.

[0650] Table 25

[0651]

[0652] Referring to Table 25, it was confirmed that the cosmetic cream concentrate compositions according to Examples 93 to 99 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0653] Table 26 below shows the antibacterial test results of the cosmetic cream concentrate compositions of Examples 100 to 106 against bacteria, fungi, and yeast.

[0654] Table 26

[0655]

[0656]

[0657] Referring to Table 26, it was confirmed that the cosmetic cream concentrate compositions according to Examples 100 to 106 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0658] Table 27 below shows the antibacterial test results of the cosmetic cream concentrate compositions of Examples 107 to 110 against bacteria, fungi, and yeast.

[0659] Table 27

[0660]

[0661] Referring to Table 27, it was confirmed that the cosmetic cream concentrate compositions according to Examples 107 to 110 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0662] Table 28 below shows the antibacterial test results of the cosmetic cream concentrate compositions of Examples 111 to 115 against bacteria, fungi, and yeast.

[0663] Table 28

[0664]

[0665]

[0666] Referring to Table 28, it was confirmed that the cosmetic cream concentrate compositions according to Examples 111 to 115 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0667] Tables 29 to 32: Antibacterial Test Results of Cosmetic Powder Compositions

[0668] Table 29 below shows the antibacterial test results of the cosmetic powder compositions of Examples 116 to 122 against bacteria, fungi, and yeast.

[0669] Table 29

[0670]

[0671] Referring to Table 29, it was confirmed that the cosmetic powder compositions according to Examples 116 to 122 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0672] Table 30 below shows the antibacterial test results of the cosmetic powder compositions of Examples 123 to 129 against bacteria, fungi, and yeast.

[0673] Table 30

[0674]

[0675]

[0676] Referring to Table 30, it was confirmed that the cosmetic powder compositions according to Examples 123 to 129 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0677] Table 31 below shows the antibacterial test results of the cosmetic powder compositions of Examples 130 to 133 against bacteria, fungi, and yeast.

[0678] Table 31

[0679]

[0680] Referring to Table 31, it was confirmed that the cosmetic powder compositions according to Examples 130 to 133 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

[0681] Table 32 below shows the antimicrobial test results of the cosmetic powder compositions of Examples 134 to 138 against bacteria, fungi, and yeast.

[0682] Table 32

[0683]

[0684] Referring to Table 32, it was confirmed that the cosmetic powder compositions according to Examples 134 to 138 can effectively inhibit all bacteria (Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa), fungi (Aspergillus niger), and yeasts (Candida albicans) used in the antibacterial test.

Claims

1. A composition for antibacterial and preservation purposes, characterized in that, Include: (a) a compound as shown in chemical formula 1; and (b) Compounds as shown in chemical formula 3 Chemical Formula 1: Chemical formula 3: In the above chemical formula 1, R1 is hydrogen. R2 is C6 to C 18 alkyl, In the above chemical formula 3, When L2 is -(CH2) m When -, R4 is -(CH2). n -OH, -C(=O)-R a or -OH, R a It is hydrogen or a C1 to C6 alkyl group, and R5 is hydrogen, halogen or -OH; When L2 is -C=O-, R4 is a C1 to C6 alkyl group or -O. - Na + R5 is hydrogen, halogen, or -OH; When L2 is -O-, R4 is -(CH2). n -OH, R5 is hydrogen, halogen or -OH; m and n are independent integers from 1 to 5.

2. The composition for antibacterial and preservation according to claim 1, characterized in that, The above-mentioned compositions for antibacterial and preservation purposes have antibacterial or antifungal effects against bacteria or fungi.

3. The composition for antibacterial and preservation according to claim 2, characterized in that, The above-mentioned antibacterial and preservation compositions have antibacterial activity against Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, Klebsiella pneumoniae, methicillin-resistant Staphylococcus aureus, Bacillus subtilis, Vibrio parahaemolyticus, Salmonella typhimurium, Listeria monocytogenes, and Shigella flexneri, and antifungal activity against Candida albicans and Aspergillus niger.

4. The composition for antibacterial and preservation according to claim 1, characterized in that, The weight ratio of the compound shown in Formula 1 to the compound shown in Formula 3 is from 0.01:9.99 to 9.99:0.

01.

5. The composition for antibacterial and preservation according to claim 1, characterized in that, The compound shown in Formula 1 is 3-(dodecylamino)propane-1,2-diol as shown in Formula 1-1 or 3-(tetradecylamino)propane-1,2-diol as shown in Formula 1-2: Chemical formula 1-1: Chemical formula 1-2:

6. The composition for antibacterial and preservation according to claim 1, characterized in that, In the compounds shown in chemical formula 3 above, When L2 is -(CH2) m When -, R4 is -(CH2). n -OH, -C(=O)-R a or -OH, R a It is a C1 to C3 alkyl group, and R5 is hydrogen or -OH; When L2 is -C=O-, R4 is a C1 to C3 alkyl group or -O. - Na + R5 is hydrogen or -OH; When L2 is -O-, R4 is -(CH2). n -OH, R5 is hydrogen; m is an integer from 2 to 4, and n is an integer from 1 to 3.

7. The composition for antibacterial and preservation according to claim 1, characterized in that, The compound shown in Formula 3 is selected from one or more of the group consisting of raspberry ketone, 3-phenyl-1-propanol, 4-hydroxyacetophenone, sodium benzoate and phenoxyethanol.

8. A product characterized in that, It includes the composition for antibacterial and preservation as described in claim 1.

9. The product according to claim 8, characterized in that, The above products are cosmetics, hygiene products, or daily chemical products.

10. The product according to claim 9, characterized in that, The aforementioned cosmetics are selected from any one of the following groups: solutions, suspensions, emulsions, pastes, gels, creams, pressed powders, loose powders, liquid foundations, foundation sticks, sprays, soaps, facial cleansers, shower gels, shampoos, and hair conditioners.

11. The product according to claim 9, characterized in that, The above-mentioned hygiene products are selected from the group consisting of dishwashing liquid cleaner, dishwasher cleaner, and wet wipes.

12. The product according to claim 9, characterized in that, The above-mentioned daily chemical products are selected from the group consisting of laundry detergents, living space cleaners, deodorizers, air purifiers, indoor fragrances, hair fragrances, fabric softeners, multi-functional cleaning products, bactericidal products, antibacterial products, disinfectant products, and disinfectants.

13. The product according to claim 9, characterized in that, The content of the above-mentioned antibacterial and preservation composition is from 0.01% to 10% by weight, relative to cosmetics, hygiene products or daily chemical products.

14. An antibacterial method, characterized in that, The step includes treating bacteria with the composition for antibacterial and preservation as described in claim 1.

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