A method for measuring the chloride diffusion coefficient of a composite material

Abstract

The application provides a method for measuring the chloride ion diffusion coefficient of a combined material. The method measures the chloride ion diffusion coefficients of old concrete and concrete repaired by new materials twice by using the RCM method, deduces the equivalent diffusion coefficient of the combined material based on the Fick law, and reversely calculates the chloride ion diffusion coefficient of the material. The method can efficiently and accurately obtain the chloride ion diffusion coefficient of the material by testing the mixed material.

Description

Technical Field

[0001] This invention relates to the field of concrete materials technology, and in particular to a method for determining the chloride ion diffusion coefficient of composite materials. Background Technology

[0002] Concrete is the most widely used and applied building material in recent years, with applications in the construction engineering field exceeding a century. However, building structures made primarily of concrete experience performance degradation over their service life. This degradation is mainly caused by physical forces, chemical corrosion, and climatic factors, leading to a decrease in load-bearing capacity and consequently reducing structural safety and durability. For aging, in-service concrete structures, attaching materials such as GO concrete, ECC, and UHPC to the existing concrete surface is an effective reinforcement method.

[0003] The chloride ion diffusion coefficient is an important indicator for evaluating the durability of concrete materials. Currently, the Rapid Chloride Migration Coefficient (RCM) method is commonly used to determine the chloride ion diffusion coefficient of concrete. However, due to the high processing requirements of high-performance materials and their small adhesion layer thickness, it is difficult to directly process them into standard-sized specimens for the RCM method. The RCM method faces two challenges in the application of composite materials: ① Because the aforementioned high-performance materials are in thin-layer form in reinforcement applications, their size cannot be processed into standard-sized specimens, making it impossible to directly measure their chloride ion diffusion coefficient using the traditional RCM method; ② The RCM method assumes that the material is homogeneous, making it impossible to directly measure the diffusion coefficient of each component in the composite material. In summary, the approach of using composite materials for testing is difficult, making it challenging to measure the chloride ion diffusion coefficient and hindering further durability evaluation and calculations.

[0004] Therefore, developing a method for determining the chloride ion diffusion coefficient of composite materials is of great significance. Summary of the Invention

[0005] The purpose of this invention is to provide a method for determining the chloride ion diffusion coefficient of composite materials, so as to solve the problems existing in the prior art.

[0006] The technical solution adopted to achieve the purpose of this invention is as follows: a method for determining the chloride ion diffusion coefficient of composite materials, measuring the chloride ion diffusion coefficient of in-service concrete and the chloride ion diffusion coefficient of concrete repaired with high-performance adhesive materials. The equivalent chloride ion diffusion coefficient of the composite material is derived based on Fick's law. The chloride ion diffusion coefficient of the high-performance adhesive material is then calculated by reverse calculation.

[0007] Furthermore, in-service concrete is marked as the original substrate. Concrete repaired with the high-performance adhesive is marked as the composite material. The diffusion coefficient of the high-performance adhesive is unknown. The diffusion coefficient of the original substrate is Three configuration specimens were prepared: Configuration I, Configuration II, and Configuration III.

[0008] The configuration I specimen is a composite material specimen. The configuration I specimen includes a thickness of The high-performance adhesion material has a top layer and a thickness of The original substrate layer below.

[0009] The configuration II specimen is a homogeneous equivalent material specimen. The diffusion coefficient of the configuration II specimen is... Thickness is The diffusion coefficient of the equivalent material The equivalent diffusion coefficient is given by [value]. The chloride ion concentration at the bottom surface of the specimen in configuration II and the specimen in configuration I exhibits the same function over time.

[0010] The configuration III specimen is an equivalent specimen of the homogeneous original substrate. The diffusion coefficient of the configuration III specimen is... The thickness of the specimen with configuration III is... The configuration III specimen comprises an upper layer of original substrate with a thickness of x3 and a lower layer of original substrate with a thickness of x2. The chloride ion concentration at the interface between the upper and lower layers of the configuration III specimen changes over time in the same manner as that at the interface between the upper and lower layers of the configuration I specimen.

[0011] Establishment was achieved by setting up specimens of configuration I, configuration II, and configuration III. , and The relationship is shown in equation (1).

[0012] (1)

[0013] The diffusion coefficient is accurate to [value missing]. .

[0014] Furthermore, the specific steps include:

[0015] 1) The diffusion coefficient of the specimen with configuration III was obtained by testing. .

[0016] 2) The diffusion coefficient of the specimen with configuration II was obtained by testing. .

[0017] 3) Solve for the value of D1 using equation (2).

[0018] (2)

[0019] The diffusion coefficient is accurate to [value missing]. .

[0020] Furthermore, specimens of configuration I and configuration III were prepared, and D2 and D3 were measured using the RCM method, and then the value of D1 was solved.

[0021] Furthermore, step S1) specifically includes the following sub-steps:

[0022] 1.1) Prepare and cure the configuration III specimen.

[0023] 1.2) The specimen was machined into a cylinder with a diameter of 100 mm and a height of 50 mm.

[0024] 1.3) Install the rubber bucket containing the test specimen in the test tank at a certain angle. The rubber bucket and the test tank are respectively labeled with... and containing The solution.

[0025] 1.4) Place the treated specimen into the test tank and apply the corresponding voltage as specified in the standard to force the chloride ions at the negative electrode to migrate into the specimen.

[0026] 1.5) After the specified time, remove the specimen, rinse it clean, and then split the specimen in half axially. Immediately spray 0.1 mol / L of [a specific disinfectant] onto the split specimen surface. Solution colorimetric indicator.

[0027] 1.6) After the indicator has been sprayed for 15 minutes, divide the specimen into 10 equal parts along its diameter section, and use a waterproof pen to draw the penetration outline. Measure the distance between the dividing line and the bottom of the specimen.

[0028] 1.7) Calculate the chloride ion diffusion coefficient of the specimen. .

[0029] Furthermore, in step S1.1), the curing period is 28 days. The curing conditions are 20℃ and 95% constant temperature and humidity.

[0030] Furthermore, step S2) specifically includes the following sub-steps:

[0031] 2.1) Prepare and cure the specimen of configuration I.

[0032] 2.1.1) Using a high-performance adhesive material layer as the prefabricated part, select a suitable mold according to the size of the specimen, and pour in the mixed concrete slurry for casting.

[0033] 2.1.2) Curing the precast parts together with the mold under standard conditions for 3 days.

[0034] 2.1.3) After the precast part reaches a certain strength, demold it and select a surface for manual roughening.

[0035] 2.1.4) Use the roughened surface of the precast part as one side of the new template to make the template for the post-cast part, and then pour the post-cast part.

[0036] 2.1.5) Cured under standard conditions for 28 days.

[0037] 2.2) D3 was obtained by using the RCM method.

[0038] Furthermore, the RCM method test was numerically simulated using the finite element method. After measuring D2 and D3, the value of D1 was solved.

[0039] The technical effects of this invention are beyond doubt:

[0040] A. It can quickly and accurately determine the chloride ion diffusion coefficient of high-performance materials, providing data support for judging durability and reinforcement effect;

[0041] B. To provide an effective monitoring method for the use of reinforcement techniques;

[0042] C. The finite element simulation method developed using the existing RCM method can avoid the need to manufacture standard-sized specimens. Attached Figure Description

[0043] Figure 1 Here is a flowchart for calculating the chloride ion diffusion coefficient of materials based on RCM;

[0044] Figure 2 This is a schematic diagram of the specimen with configuration I.

[0045] Figure 3 This is a schematic diagram of the specimen with configuration II.

[0046] Figure 4 This is a schematic diagram of the specimen with configuration III.

[0047] Figure 5 This is a schematic diagram of the model in Example 3;

[0048] Figure 6 This is a concentration distribution diagram of Model I in Example 3;

[0049] Figure 7 This is a concentration distribution diagram of Model II in Example 3;

[0050] Figure 8 This is a schematic diagram of the specimen with configuration III in Example 4;

[0051] Figure 9 This is a diagram showing the RCM concentration distribution of the specimen with configuration III in Example 4;

[0052] Figure 10 This is a schematic diagram of the specimen with configuration I in Example 4;

[0053] Figure 11 This is a diagram showing the RCM concentration distribution of specimen I in Example 4;

[0054] Figure 12 This is a diagram showing the RCM concentration distribution of the specimen with configuration III in Example 5;

[0055] Figure 13 This is a diagram showing the RCM concentration distribution of the specimen with configuration III in Example 6. Detailed Implementation

[0056] The present invention will be further described below with reference to embodiments, but it should not be construed that the scope of the present invention is limited to the following embodiments. Various substitutions and modifications made based on ordinary technical knowledge and common practices in the art without departing from the above-described technical concept of the present invention should be included within the scope of protection of the present invention.

[0057] Example 1:

[0058] This embodiment provides a method for rapid determination of chloride ion migration coefficient. See also... Figure 1 This embodiment provides a method for determining the chloride ion diffusion coefficient of composite materials, measuring the chloride ion diffusion coefficient of in-service concrete and the chloride ion diffusion coefficient of concrete repaired with a high-performance adhesive. The equivalent chloride ion diffusion coefficient of the composite material is derived based on Fick's law. The chloride ion diffusion coefficient of the high-performance adhesive is then calculated by reverse calculation.

[0059] It is worth noting that the basic equation for calculating the chloride ion diffusion coefficient is based on the diffusion coefficients of two combined materials. The equation for the diffusion coefficient of composite concrete blocks is derived. The derivation of the basic equation is as follows:

[0060] In this embodiment, in-service concrete is marked as the original substrate. Concrete repaired with the high-performance adhesive is marked as the composite material. The diffusion coefficient of the high-performance adhesive is unknown. The diffusion coefficient of the original substrate is Three configuration specimens were prepared: Configuration I, Configuration II, and Configuration III.

[0061] See Figure 2 The configuration I specimen is a composite material specimen. The configuration I specimen includes components with a thickness of... The high-performance adhesion material has a top layer and a thickness of The original substrate layer below.

[0062] Therefore, the upper layer of attached material can be considered equivalent to existing materials of varying thicknesses. See also Figure 3The configuration II specimen is a homogeneous equivalent material specimen. The diffusion coefficient of the configuration II specimen is... Thickness is The diffusion coefficient of the equivalent material The equivalent diffusion coefficient is given for specimen configuration I. The same chloride ion concentration is set at the top of both specimen configuration I and specimen configuration II. Based on Fick's law, the change function of chloride ion concentration at the bottom plane of the two specimens over time is calculated as follows: and When the chloride ion concentration on the bottom surface of the specimen of configuration II and the specimen of configuration I changes with time in the same functional manner, That is, the equivalent of configuration 1 The value (chloride ion diffusion coefficient) can be used to obtain the calculation equation for the chloride ion diffusion coefficient of the target material in the composite material. ).

[0063] Based on practical engineering applications, the diffusion of chloride ions in concrete is generally modeled using a semi-infinite approach. This means that one side of the concrete surface has a fixed chloride ion concentration, while the other side represents infinite space, thus treating it as a simple one-dimensional problem. According to Fick's Law:

[0064]

[0065] The chloride ion concentration at any thickness and any time under one-dimensional diffusion conditions can be obtained as follows:

[0066]

[0067] in, This is the Gaussian error function.

[0068] Because the composite material contains two materials with different chloride ion diffusion coefficients, the above solution cannot be directly applied to configuration 1. See also Figure 4 The configuration III specimen is an equivalent specimen of the homogeneous original substrate. The diffusion coefficient of the configuration III specimen is... The thickness of the specimen with configuration III is... The configuration III specimen comprises an upper layer of original substrate with a thickness of x3 and a lower layer of original substrate with a thickness of x2. The chloride ion concentration at the interface between the upper and lower layers of the configuration III specimen changes over time in the same manner as at the interface between the upper and lower layers of the configuration I specimen. Configuration I specimen, configuration II specimen, and configuration III specimen.

[0069] Chloride ion concentration at the interface of specimen type I:

[0070]

[0071] Chloride ion concentration at the interface of configuration III specimen:

[0072]

[0073] Solving the system of equations simultaneously, we get:

[0074]

[0075] At this point, the chloride ion concentration at the interface between configuration I and configuration III specimens is constant, and the materials below the interface are identical in thickness. Clearly, the chloride ion diffusion process is exactly the same, and the concentration distribution after diffusion is also identical. Therefore, configuration I and configuration III specimens can be considered completely equivalent. Configuration III specimen is a homogeneous concrete block with a diffusion coefficient of... Thickness is For the concrete block, the above solution can be directly applied to obtain the chloride ion concentration at the bottom of the configuration model:

[0076]

[0077] Similarly, for homogeneous specimens of configuration II, the above solution can be directly applied to obtain:

[0078]

[0079] Because ① the concentration function at the bottom is consistent, that is ② Specimens of configuration I and configuration III are equivalent, that is Therefore, it can be deduced that ,Right now:

[0080]

[0081] Solving for:

[0082]

[0083] Mode Established , and The relationship will Convert to a measurement method that is less difficult and , making The solution becomes possible.

[0084] This embodiment designs a method for measuring the diffusion coefficient of composite concrete materials using the RCM method. Its main purpose is to indirectly calculate the chloride ion diffusion coefficient of the material by measuring the diffusion coefficients of ordinary concrete specimens and composite concrete specimens through two RCM tests. This embodiment determines the chloride ion diffusion coefficients of existing old concrete and concrete repaired with new materials using the two RCM tests, derives the equivalent diffusion coefficient of the composite material based on Fick's law, and then calculates the chloride ion diffusion coefficient of the material. This embodiment can utilize the testing of mixed materials to efficiently and accurately obtain the chloride ion diffusion coefficient of the material.

[0085] Example 2:

[0086] The main content of this embodiment is the same as that of Embodiment 1. However, this embodiment is based on the relevant methods specified in the "Standard for Test Methods of Long-Term Performance and Durability of Ordinary Concrete" (GB / T 50082-2009). Configuration I and Configuration III specimens are prepared, and D2 and D3 are measured using the RCM method, then the value of D1 is calculated. This embodiment specifically includes the following steps:

[0087] 1) The diffusion coefficient of the specimen with configuration III was obtained by testing. Step S1) specifically includes the following sub-steps:

[0088] 1.1) Prepare and cure the specimens of configuration III. The curing period is 28 days. The curing conditions are 20℃ and 95% constant temperature and humidity.

[0089] 1.2) The specimen was machined into a cylinder with a diameter of 100 mm and a height of 50 mm.

[0090] 1.3) Install the rubber bucket containing the test specimen in the test tank at a certain angle. The rubber bucket and the test tank are respectively labeled with... and containing The solution.

[0091] 1.4) Place the treated specimen into the test tank and apply the corresponding voltage as specified in the standard to force the chloride ions at the negative electrode to migrate into the specimen.

[0092] 1.5) After the specified time, remove the specimen, rinse it clean, and then split the specimen in half axially. Immediately spray 0.1 mol / L of [a specific disinfectant] onto the split specimen surface. Solution colorimetric indicator.

[0093] 1.6) After the indicator has been sprayed for 15 minutes, divide the specimen into 10 equal parts along its diameter section, and use a waterproof pen to draw the penetration outline. Measure the distance between the dividing line and the bottom of the specimen.

[0094] 1.7) Calculate the chloride ion diffusion coefficient of the specimen. .

[0095] Chloride ion diffusion coefficient of the specimen Calculate using the following formula:

[0096]

[0097] In the formula: —Unsteady-state chloride ion migration coefficient in concrete, accurate to [value missing] ;

[0098] —The absolute value of the voltage used ( );

[0099] —The average of the initial and final temperatures of the anolyte solution ( );

[0100] —Specimen thickness ( );

[0101] —Average chloride ion penetration depth ( );

[0102] —Experiment duration ( )

[0103] 2) The diffusion coefficient of the specimen with configuration II was obtained by testing. Step S2) specifically includes the following sub-steps:

[0104] 2.1) Prepare and cure the specimen of configuration I.

[0105] 2.1.1) Using a high-performance adhesive material layer as the prefabricated part, select a suitable mold according to the size of the specimen, and pour in the mixed concrete slurry for casting.

[0106] 2.1.2) Curing the precast parts together with the mold under standard conditions for 3 days.

[0107] 2.1.3) After the precast part reaches a certain strength, demold it and select a surface for manual roughening.

[0108] 2.1.4) Use the roughened surface of the precast part as one side of the new template to make the template for the post-cast part, and then pour the post-cast part.

[0109] 2.1.5) Cured under standard conditions for 28 days.

[0110] 2.2) D3 was obtained by using the RCM method.

[0111] 3) Solve for the value of D1 using equation (2).

[0112]

[0113] In the formula: —The diffusion coefficient of the new material, accurate to the nearest centimeter. ;

[0114] —Thickness of new materials ( );

[0115] —Average chloride ion penetration depth ( );

[0116] —The diffusion coefficient of old materials, accurate to ;

[0117] —Equivalent diffusion coefficient of composite materials, accurate to .

[0118] Example 3:

[0119] This embodiment is largely the same as Embodiment 1. However, because the RCM method test is time-consuming, the finite element method is used to numerically simulate the RCM method test. After measuring D2 and D3, the value of D1 is solved. Since the actual RCM method test involves too many physical quantities to simulate all of them, this embodiment simplifies it to a certain extent. Referring to the empirical formula of the RCM method, the following constructor is constructed:

[0120]

[0121] In the formula: —Diffusion coefficient of new materials ( );

[0122] —Specimen thickness ( );

[0123] —Average chloride ion penetration depth ( );

[0124] —Undetermined coefficients;

[0125] Existing data indicates that, The critical concentration for color development of the colorimetric reagent is 0.2 mol / L. Based on this, the chloride ion penetration depth can be obtained from the concentration distribution calculated by numerical simulation. Two models were established, both with a thickness of 110 mm, and their diffusion coefficients were respectively... and ,like Figure 5 A boundary chloride ion concentration of 1.7 mol / L was set, and a numerical simulation of chloride ion diffusion was performed. The concentration distribution is shown below. Figure 6 and Figure 7 As shown. The chloride ion penetration depths were obtained to be 57.5 mm and 40.5 mm, respectively. Substituting these values ​​into the constructor, we can calculate... and Complete the simplified formula:

[0126]

[0127] In the formula: —Diffusion coefficient of new materials ( );

[0128] —Specimen thickness ( );

[0129] —Average chloride ion penetration depth ( );

[0130] — Coefficient, take ;

[0131] — Coefficient, take .

[0132] Take the diffusion coefficient as The model was verified, simulating a chloride ion penetration depth of 48.0 mm, using a substitution method. The diffusion coefficient is The result is close to the actual value, indicating that the above formula is quite accurate.

[0133] Example 4:

[0134] The main content of this embodiment is the same as that of embodiment 3, wherein, yes , It is 0.01m. yes , It is 0.1m, and the concentration of the aqueous solution in the boundary pores is 1.7mol / L.

[0135] The finite element software modeling of the RCM test of the configuration III specimen is as follows: Figure 8 To obtain the concentration distribution as follows Figure 9 The chloride ion penetration depth was found to be 57.5 mm. for The finite element software modeling of the RCM test for specimen configuration I is as follows: Figure 10 Concentration distribution as Figure 11 The chloride ion penetration depth was found to be 55.0 mm. for Substituting into equation 3.11, we get for The actual value is .

[0136] Example 5:

[0137] The main content of this embodiment is the same as that of embodiment 3, wherein, yes , It is 0.01m. yes , The concentration of the aqueous solution in the boundary pores is 1.7 mol / L, which is 0.1 m. The concentration distribution of the specimen in configuration I is as follows: Figure 12 The chloride ion penetration depth was found to be 56.5 mm. for Substituting into equation 3.11, we get for The actual value is .

[0138] Example 6:

[0139] The main content of this embodiment is the same as that of embodiment 3, wherein, yes , It is 0.005m. yes , The concentration of the aqueous solution in the boundary pores is 1.7 mol / L, which is 0.105 m. The concentration distribution of the RCM test for configuration I specimen is as follows: Figure 13 The chloride ion penetration depth was found to be 56.5 mm. for Substituting into equation 3.11, we get for The actual value is .

[0140] The numerical simulation results of Examples 4, 5 and 6 are close to the actual values ​​with small errors. These examples can efficiently and accurately obtain the chloride ion diffusion coefficient of the material.

Claims

1. A method for determining the chloride ion diffusion coefficient of a composite material, characterized in that: The chloride ion diffusion coefficient of in-service concrete and the chloride ion diffusion coefficient of concrete repaired with high-performance adhesive materials were determined. The equivalent chloride ion diffusion coefficient of the composite material is derived based on Fick's law; the chloride ion diffusion coefficient of the high-performance adhesion material is then calculated. The in-service concrete is marked as the original substrate; the concrete repaired with the high-performance adhesive is marked as the composite material; the diffusion coefficient of the high-performance adhesive is unknown. The diffusion coefficient of the original substrate is ; Set up configuration I specimens, configuration II specimens, and configuration III specimens; among which, The configuration I specimen is a composite material specimen; the configuration I specimen includes a thickness of The high-performance adhesion material has a top layer and a thickness of The original substrate layer below; The configuration II specimen is a homogeneous equivalent material specimen; the diffusion coefficient of the configuration II specimen is... Thickness is The diffusion coefficient of the equivalent material The equivalent diffusion coefficient is given by [value]; the chloride ion concentration on the bottom surface of the specimen of configuration II and the bottom surface of the specimen of configuration I changes with time in the same function. The configuration III specimen is a homogeneous equivalent specimen of the original substrate; the diffusion coefficient of the configuration III specimen is The thickness of the specimen of configuration III is The configuration III specimen includes an upper layer of original substrate with a thickness of x3 and a lower layer of original substrate with a thickness of x2; the chloride ion concentration at the interface between the upper and lower layers of the configuration III specimen changes with time in the same way as that at the interface between the upper and lower layers of the configuration I specimen. Establishment was achieved by setting up specimens of configuration I, configuration II, and configuration III. , and The relationship is shown in equation (1); (1) The diffusion coefficient is accurate to [value missing]. .

2. The method for determining the chloride ion diffusion coefficient of a composite material according to claim 1, characterized in that, Specifically, the following steps are included: S1) The diffusion coefficient of the configuration III specimen was obtained by testing. ; S2) The diffusion coefficient of the specimen with configuration II was obtained by testing. ; S3) Solve for the value of D1 using equation (2); (2) The diffusion coefficient is accurate to [value missing]. .

3. The method for determining the chloride ion diffusion coefficient of a composite material according to claim 2, characterized in that: Prepare specimens of configuration I and configuration III, determine D2 and D3 using the RCM method, and then solve for the value of D1.

4. The method for determining the chloride ion diffusion coefficient of a composite material according to claim 3, characterized in that, Step S1) specifically includes the following sub-steps: S1.1) Prepare and cure the specimen of configuration III; S1.2) The specimen is machined into a cylinder with a diameter of 100 mm and a height of 50 mm; S1.3) The rubber bucket containing the test specimen is installed in the test tank at a certain angle. The rubber bucket and the test tank are respectively labeled with... and containing The solution; S1.4) Place the treated specimen into the test tank and apply the corresponding voltage as specified in the specification to force the chloride ions at the negative electrode to migrate into the specimen; S1.5) After the specified time, remove the specimen, rinse it clean, and then split the specimen in half axially. Immediately spray 0.1 mol / L of [a specific chemical / treatment] onto the split specimen surface. Solution colorimetric indicator; S1.6) After the indicator has been sprayed for 15 minutes, divide the specimen into 10 equal parts along the diameter section, and use a waterproof pen to draw the penetration outline. Measure the distance between the dividing line and the bottom of the specimen. S1.7) Calculate the chloride ion diffusion coefficient of the specimen. .

5. The method for determining the chloride ion diffusion coefficient of a composite material according to claim 4, characterized in that: In step S1.1), the curing period is 28 days; the curing conditions are 20℃ and 95% constant temperature and humidity.

6. The method for determining the chloride ion diffusion coefficient of a composite material according to claim 3 or 4, characterized in that, Step S2) specifically includes the following sub-steps: S2.1) Prepare and cure the specimen of configuration I; S2.1.1) Using a high-performance adhesive material layer as the prefabricated part, select a suitable mold according to the size of the specimen, and pour in the mixed concrete slurry for casting; S2.1.2) Curing the precast part together with the mold under standard conditions for 3 days; S2.1.3) After the precast part reaches a certain strength, demold it and select one surface for manual roughening; S2.1.4) Use the roughened surface of the precast part as one side of the new template to make the template for the post-cast part, and then pour the post-cast part. S2.1.5) Cured for 28 days under standard conditions; S2.2) D3 was obtained by using the RCM method.

7. The method for determining the chloride ion diffusion coefficient of a composite material according to claim 2, characterized in that: The RCM method test was numerically simulated using the finite element method. After measuring D2 and D3, the value of D1 was solved.

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