Mirror-surface color-holding lip glaze and preparation method thereof

Abstract

A mirror-surface color-holding lip glaze and a preparation method thereof, belonging to the technical field of cosmetics, wherein the lip glaze comprises an emollient, a trimethylsiloxysilicate film-forming agent, a thickener, an antioxidant, a skin conditioner, a moisturizer, various composite modified colorants, etc. The lip glaze of the present invention is compounded with CI 77891 and polymethylsiloxane, CI 77492, CI 77491 and CI 77499 are respectively compounded with triethoxyoctylsilane, CI 15985, CI 15850 Red 6 and CI 15850 Red 7 are respectively copolymerized with polyvinyl pyrrolidone and rosin acrylate to form a copolymer of colorant / polyvinyl pyrrolidone / rosin acrylate; the treated colorant is used in combination with the film-forming agent, can have antistatic properties, the color holding ability of the colorant is improved, and can have a good gloss effect, and is not easy to decolor and stain the cup; it can also improve the makeup removal effect of the colorant, and does not stain the lips and is not sticky.

Description

Technical Field

[0001] The invention belongs to the technical field of cosmetics, and in particular relates to a mirror-finished color-holding lip glaze and a preparation method thereof. Background Art

[0002] In order to match the makeup, beautify the lips, please themselves and meet the needs of work, people usually use lipstick, lip gloss, lip glaze, etc. to improve the appearance of the lips. Among them, lipstick is generally solid and has a relatively dry texture. Lipstick has a strong concealing power, but the saturation is poor and it does not look real enough. Lipstick is easier to color, but it is also easy to fade and stain the cup; lip gloss is equivalent to the combination of lip gloss and lip glaze. The texture is liquid and moisturizing. It is very shiny when it is just applied, but the durability is average and it needs to be touched up frequently; lip glaze is equivalent to a viscous liquid lipstick with a high color rendering. The coloring effect of lip glaze is not as good as lipstick. It needs to be applied several times to achieve the desired makeup effect. In addition, due to the moist texture of lip glaze, it is particularly suitable for skin with dry lips and more lip lines. It can well relieve chapped lips and dryness, making the lips look fuller and more moisturized. From the comprehensive effect, lip glaze combines the saturated color of lipstick and the bright texture of lip gloss, and has relatively good color fixation. Lip glaze has obvious advantages.

[0003] However, the color retention effect of current lip gloss products is still uneven, and there are also fading and staining phenomena. In order to improve the long-term color retention, the dosage of film-forming agents, thickeners and colorants is generally increased, but there will be incomplete makeup removal, a lot of residue, lip staining, and a sticky and poor usage experience. Summary of the invention

[0004] The existing lip glaze products have the problems of fading and staining, but the problem of improving the color retention is that the makeup removal is incomplete, there is a lot of residue, the lip staining phenomenon, and the sticky feeling is poor. The present invention provides a mirror-finished color-retaining lip glaze and a preparation method thereof, CI 77891 and polymethylsiloxane are compounded, CI 77492, CI 77491 and CI 77499 are respectively compounded with triethoxyoctylsilane, CI 15985, CI 15850 Red 6 and CI 15850 Red 7 are respectively copolymerized with polyvinyl pyrrolidone and rosin acrylate to form a copolymer of colorant / polyvinyl pyrrolidone / rosin acrylate; the treated colorant is used in combination with a film-forming agent to have antistatic properties, improve the color retention ability of the colorant, and have a good gloss effect, and are not easy to decolorize and stain the cup; the makeup removal effect of the colorant can also be improved, and it will not stain the lips and will not be sticky; the user experience is very good. The specific technical scheme is as follows:

[0005] A mirror-finished color-holding lip glaze, the lip glaze is made of the following raw materials in parts by weight: 20 to 50 parts of emollient, 5 to 10 parts of film-forming agent, 20 to 30 parts of thickener, 0.1 to 0.5 parts of antioxidant, 10 to 25 parts of skin conditioner, 0.5 to 5 parts of moisturizer, 0.1 to 3 parts of fragrance, 0.1 to 0.8 parts of preservative and 8 to 15 parts of colorant;

[0006] The film former is trimethylsiloxysilicate;

[0007] The colorant is composed of colorant I, colorant II, colorant III, colorant IV, CI 15985, CI 15850 Red 6 (Red 6Ba Lake), CI 15850 Red 7 (Red 7Ca Lake), CI 45380 (RED 21Al Lake) and CI 45410 (RED 27Al Lake), and the mass ratio is colorant I: colorant II: colorant III: colorant IV: CI 15985: CI 15850 Red 6 (Red 6Ba Lake): CI 15850 Red 7 (Red 7Ca Lake): CI 45380 (RED 21Al Lake): CI 45410 (RED 27Al Lake) = (1-3): (0.5-3): (0.5-1): (1-5): (1-3): (1-5): (1-5): (0.5-1): (0.5-1);

[0008] The colorant I is a composite of CI 77891 and polymethylsiloxane, and the composite mass ratio is CI 77891: polymethylsiloxane = (1-5): (0.1-0.3);

[0009] The colorant II is a composite of CI 77492 and triethoxyoctylsilane, and the composite mass ratio is CI77492:triethoxyoctylsilane=(1-5):(0.2-0.4);

[0010] The colorant III is a composite of CI 77491 and triethoxyoctylsilane, and the composite mass ratio is CI77491:triethoxyoctylsilane=(1-5):(0.2-0.4);

[0011] The colorant IV is a composite of CI 77499 and triethoxyoctylsilane, and the composite mass ratio is CI77499:triethoxyoctylsilane=(1-5):(0.2-0.4);

[0012] The CI 15985, CI 15850 Red 6 (Red 6Ba Lake) and CI 15850 Red 7 (Red 7Ca Lake) are all modified colorants, and the modification method is as follows: according to the mass ratio, purified water: ethanol: CI 15985 or CI 15850 Red 6 (Red 6Ba Lake) or CI 15850 Red 7 (Red 7Ca Lake): polyvinyl pyrrolidone: rosin acrylate = (90-100): (20-30): (10-20): (2-5): (0.5-2), mixed, and then spray dried to remove ethanol and water to obtain the modified colorant.

[0013] In the above technical scheme, the emollient is composed of isododecane, polydimethylsiloxane, trimethylsiloxyphenyl polydimethylsiloxane and phenyl polytrimethylsiloxane, and the mass ratio is isododecane: polydimethylsiloxane: trimethylsiloxyphenyl polydimethylsiloxane: phenyl polytrimethylsiloxane = (2 to 5): (2 to 5): (0.5 to 1): (1 to 3).

[0014] In the above technical solution, the thickener is a hydrogenated (styrene / isoprene) copolymer.

[0015] In the above technical scheme, the skin conditioner is composed of olive (OLEA EUROPAEA) shell oil, macadamia (MACADAM IA TERNIFOLIA) seed oil and jojoba (SIMMONDSIA CHINENS IS) seed oil, and the mass ratio is olive (OLEA EUROPAEA) shell oil: macadamia (MACADAM IA TERN IFOL IA) seed oil: jojoba (SIMMONDSIA CHINENS IS) seed oil = (2-5): (2-5): (0.3-1).

[0016] In the above technical scheme, the moisturizer is composed of hydrolyzed sodium hyaluronate, Limnanthes alba seed oil, glyceryl behenate and ethylhexylglycerin, and the mass ratio is hydrolyzed sodium hyaluronate: Limnanthes alba seed oil: glyceryl behenate: ethylhexylglycerin = (2-5): (1-3): (0.5-1): (0.5-3).

[0017] In the above technical solution, the antioxidant is tocopherol acetate.

[0018] In the above technical solution, the aromatic agent is essence.

[0019] In the above technical solution, the preservative is phenoxyethanol.

[0020] The method for preparing the above-mentioned mirror-finished color-lasting lip glaze comprises the following steps:

[0021] The emollient, film former, thickener, fragrance and moisturizer are mixed evenly, and then antioxidants, skin conditioners and preservatives are added and mixed evenly, and then CI 45380 (RED 21Al Lake) and CI45410 (RED 27Al Lake) in the colorant are added and mixed evenly, and then colorant I, colorant II, colorant III and colorant IV in the colorant are added and mixed evenly, and finally CI 15985, CI 15850 Red 6 (Red 6Ba Lake) and CI 15850 Red 7 (Red 7Ca Lake) in the colorant are added and mixed evenly to obtain lip glaze.

[0022] In the above method, the mixing temperature is 65° C. to 75° C., and the mixing speed is 80 r / min to 120 r / min.

[0023] Compared with the prior art, the mirror-finished color-holding lip glaze and the preparation method thereof of the present invention have the following beneficial effects:

[0024] 1. The present invention is designed to compound CI 77891 and polymethylsiloxane. Polymethylsiloxane has the effects of softening, anti-foaming and film-forming. After CI 77891 and polymethylsiloxane are pre-compounded in a ratio of (1-5):(0.1-0.3), the spreadability and colorability of CI77891 can be improved, and it is not easy to fade; and the dispersion and color matching with other colorant components are uniform and good.

[0025] 2. The present invention is designed to compound CI 77492 and triethoxycaprylylsilane. Triethoxycaprylylsilane has bonding and emulsifying effects. After CI 77492 and triethoxycaprylylsilane are pre-compounded in a ratio of (1-5):(0.2-0.4), the adhesion of CI 77492 can be improved, as well as the workability of CI 77492 with other ingredients. The uniform color matching is good and the color is not easy to fade after application.

[0026] 3. The present invention is designed to compound CI 77491 and triethoxycaprylylsilane. Triethoxycaprylylsilane has bonding and emulsifying effects. After CI 77491 and triethoxycaprylylsilane are pre-compounded in a ratio of (1-5):(0.2-0.4), the adhesion of CI 77491 can be improved, as well as the workability of CI 77491 with other ingredients. The uniform color matching is good and the color is not easy to fade after application.

[0027] 4. The present invention is designed to compound CI 77499 and triethoxycaprylylsilane. Triethoxycaprylylsilane has bonding and emulsifying effects. After CI 77499 and triethoxycaprylylsilane are pre-compounded in a ratio of (1-5):(0.2-0.4), the adhesion of CI 77499 can be improved, as well as the workability of CI 77499 with other ingredients. The uniform color matching is good and the color is not easy to fade after application.

[0028] 5. The present invention is designed to modify CI 15985, CI 15850 Red 6 and CI 15850 Red 7 respectively, so that the colorant is copolymerized with polyvinyl pyrrolidone and rosin acrylate to form a copolymer of colorant / polyvinyl pyrrolidone / rosin acrylate, which can improve the properties of CI 15985, CI 15850 Red 6 and CI 15850 Red 7 colorants, have antistatic properties, composite film-forming gloss, and improved color retention of the colorant, and can have a good gloss effect, and is not easy to decolorize and stain the cup; in particular, polyvinyl pyrrolidone also has the color dispersion effect of the colorant, and also has good solubility, which can improve the makeup removal effect of the colorant, and does not stain the lips and is not sticky. CI 15985, CI 15850 Red 6 and CI 15850 Red 7 copolymerized with polyvinyl pyrrolidone / rosin acrylate have outstanding effects of color retention, gloss, no staining of the cup, and no staining of the lips after makeup removal.

[0029] 6. The trimethylsiloxysilicate film-forming agent designed by the present invention is used in combination with various composite and modified colorants, which has good compatibility, uniform and glossy coloring, good color retention and no fading; especially trimethylsiloxysilicate is used in combination with polyvinyl pyrrolidone and rosin acrylate to form a film, which can ensure thorough cleaning after removing makeup with lip glaze remover, without staining the lips and without stickiness.

[0030] 7. The present invention also adds emollients (isododecane, dimethicone, trimethylsiloxyphenyl dimethicone and phenyl trimethicone), skin conditioning agents (olive shell oil, macadamia seed oil and jojoba seed oil), humectants (hydrolyzed sodium hyaluronate, meadowfoam seed oil, glyceryl behenate and ethylhexylglycerin), which can be used in conjunction with film-forming agents and modified colorants to improve the emollient, moisturizing and skin conditioning properties of the lip glaze, maintain a moist luster for a long time, and not fade or stain the lips; and can promote easy removal of the lip glaze without residue, staining the lips, or being sticky.

[0031] In summary, the various raw materials of the present invention cooperate with each other and adopt a special colorant processing process, so that the lip glaze has good color durability, the gloss and moisture are maintained for a long time, and it is not easy to stain the lips. In addition, the composite and modified colorant can promote the lip glaze to be easy to remove, clean thoroughly, not stain the lips, and no sticky residue, and the use experience is very good. DETAILED DESCRIPTION

[0032] The present invention is further described below in conjunction with specific implementation cases, but the present invention is not limited to these embodiments.

[0033] Example 1

[0034] A mirror-finished color-holding lip glaze, the lip glaze being made of the following raw materials in parts by mass: 35 parts of an emollient, 6 parts of a trimethylsiloxysilicate film former, 25 parts of a hydrogenated (styrene / isoprene) copolymer thickener, 0.3 parts of a tocopherol acetate antioxidant, 20 parts of a skin conditioner, 3 parts of a moisturizer, 2 parts of a fragrance, 0.5 parts of a phenoxyethanol preservative, and 12 parts of a colorant;

[0035] Wherein, the colorant is composed of colorant I, colorant II, colorant III, colorant IV, CI 15985, CI 15850 Red 6 (Red 6Ba Lake), CI 15850 Red 7 (Red 7Ca Lake), CI 45380 (RED 21Al Lake) and CI 45410 (RED 27Al Lake), and the mass ratio is colorant I: colorant II: colorant III: colorant IV: CI 15985: CI15850 Red 6 (Red 6Ba Lake): CI 15850 Red 7 (Red 7Ca Lake): CI 45380 (RED 21Al Lake): CI45410 (RED 27Al Lake) = 2:1.5:0.6:3:2:3:2.5:0.8:0.6;

[0036] Colorant I is a complex of CI 77891 and polymethylsiloxane, and the composite mass ratio is CI 77891: polymethylsiloxane = 3:0.2. Colorant II is a complex of CI 77492 and triethoxycaprylylsilane, and the composite mass ratio is CI77492: triethoxycaprylylsilane = 3:0.25. Colorant III is a complex of CI 77491 and triethoxycaprylylsilane, and the composite mass ratio is CI 77491: triethoxycaprylylsilane = 3:0.35. Colorant IV is a complex of CI 77499 and triethoxycaprylylsilane, and the composite mass ratio is CI 77499: triethoxycaprylylsilane = 3:0.32. CI 15985, CI15850 Red 6 (Red 6Ba Lake) and CI 15850 Red 7 (Red 7Ca Lake) are all modified colorants. The modification method of CI 15985 is as follows: according to the mass ratio, purified water: ethanol: CI 15985: polyvinyl pyrrolidone: rosin acrylate = 95:25:15:3:1, mixed, and then spray dried to remove ethanol and water to obtain the modified CI 15985. The modification method of CI 15850 Red 6 (Red 6Ba Lake) is as follows: according to the mass ratio, purified water: ethanol: CI 15850 Red 6 (Red 6Ba Lake): polyvinyl pyrrolidone: rosin acrylate = 95:25:15:3:1, mixed, and then spray dried to remove ethanol and water to obtain the modified CI 15850 Red 6 (Red 6Ba Lake). The modification method of CI 15850 Red 7 (Red 7Ca Lake) is as follows: according to the mass ratio, purified water: ethanol: CI 15850 Red 7 (Red 7Ca Lake): polyvinyl pyrrolidone: rosin acrylate = 95:25:15:3:1, mixed, and then spray-dried to remove ethanol and water to obtain the modified CI 15850 Red 7 (Red 7Ca Lake).

[0037] The emollient is composed of isododecane, dimethicone, trimethylsiloxyphenyl dimethicone and phenyl trimethicone, and the mass ratio is isododecane: dimethicone: trimethylsiloxyphenyl dimethicone: phenyl trimethicone = 3:3:0.8:2.

[0038] The skin conditioning agent is composed of olive (OLEA EUROPAEA) shell oil, macadamia (MACADAM IA TERNIFOL IA) seed oil and jojoba (SIMMONDSIA CHINENSIS) seed oil, and the mass ratio is olive (OLEAEUROPAEA) shell oil: macadamia (MACADAM IA TERNIFOLIA) seed oil: jojoba (SIMMONDS IA CHINENSIS) seed oil = 3:3:0.5.

[0039] Among them, the moisturizer is composed of hydrolyzed sodium hyaluronate, Limnanthes alba seed oil, glyceryl behenate and ethylhexylglycerin, and the mass ratio is hydrolyzed sodium hyaluronate:Limnanthes alba seed oil:glyceryl behenate:ethylhexylglycerin=3:2:0.6:1.5.

[0040] Among them, the fragrance is rose fragrance essence.

[0041] The method for preparing the above-mentioned mirror-finished color-lasting lip glaze comprises the following steps:

[0042] According to the mass proportions, the emollient, film former, thickener, fragrance and moisturizer were mixed uniformly at 70°C at 100 r / min, and then the antioxidant, skin conditioner and preservative were added and mixed uniformly at 70°C at 100 r / min. Then, CI 45380 (RED 21Al Lake) and CI 45410 (RED 27Al Lake) in the colorant were added and mixed uniformly at 65°C-75°C at 80 r / min-120 r / min. Then, colorant I, colorant II, colorant III and colorant IV in the colorant were added and mixed uniformly at 70°C at 100 r / min. Finally, CI 15985, CI 15850 Red 6 (Red 6Ba Lake) and CI 15850 Red 7 (Red 7Ca Lake) in the colorant were added and mixed uniformly at 70°C at 100 r / min to obtain lip glaze.

[0043] Example 2

[0044] A mirror-finished color-holding lip glaze, the lip glaze being made of the following raw materials in parts by mass: 50 parts of an emollient, 10 parts of a trimethylsiloxysilicate film former, 30 parts of a hydrogenated (styrene / isoprene) copolymer thickener, 0.5 parts of a tocopherol acetate antioxidant, 25 parts of a skin conditioner, 5 parts of a moisturizer, 3 parts of a fragrance, 0.8 parts of a phenoxyethanol preservative, and 15 parts of a colorant;

[0045] Wherein, the colorant is composed of colorant I, colorant II, colorant III, colorant IV, CI 15985, CI 15850 Red 6 (Red 6Ba Lake), CI 15850 Red 7 (Red 7Ca Lake), CI 45380 (RED 21Al Lake) and CI 45410 (RED 27Al Lake), and the mass ratio is colorant I: colorant II: colorant III: colorant IV: CI 15985: CI15850 Red 6 (Red 6Ba Lake): CI 15850 Red 7 (Red 7Ca Lake): CI 45380 (RED 21Al Lake): CI45410 (RED 27Al Lake) = 3:3:1:5:3:5:5:1:1;

[0046] Colorant I is a complex of CI 77891 and polymethylsiloxane, and the composite mass ratio is CI 77891: polymethylsiloxane = 5:0.3. Colorant II is a complex of CI 77492 and triethoxycaprylylsilane, and the composite mass ratio is CI77492: triethoxycaprylylsilane = 5:0.4. Colorant III is a complex of CI 77491 and triethoxycaprylylsilane, and the composite mass ratio is CI 77491: triethoxycaprylylsilane = 5:0.4. Colorant IV is a complex of CI 77499 and triethoxycaprylylsilane, and the composite mass ratio is CI 77499: triethoxycaprylylsilane = 5:0.4. CI 15985, CI 15850 Red 6 (Red 6Ba Lake) and CI 15850 Red 7 (Red 7Ca Lake) are all modified colorants. The modification method of CI 15985 is as follows: according to the mass ratio, purified water: ethanol: CI 15985: polyvinyl pyrrolidone: rosin acrylate = 100:30:20:5:2, mixed, and then spray dried to remove ethanol and water to obtain the modified CI 15985. The modification method of CI 15850 Red 6 (Red6Ba Lake) is as follows: according to the mass ratio, purified water: ethanol: CI 15850 Red 6 (Red6Ba Lake): polyvinyl pyrrolidone: rosin acrylate = 100:30:20:5:2, mixed, and then spray dried to remove ethanol and water to obtain the modified CI 15850 Red 6 (Red 6Ba Lake). The modification method of CI 15850 Red 7 (Red 7Ca Lake) is as follows: according to the mass ratio, purified water: ethanol: CI 15850 Red 7 (Red 7Ca Lake): polyvinyl pyrrolidone: rosin acrylate = 100:30:20:5:2, mixed, and then spray-dried to remove ethanol and water to obtain the modified CI 15850 Red 7 (Red 7Ca Lake).

[0047] The emollient is composed of isododecane, dimethicone, trimethylsiloxyphenyl dimethicone and phenyl trimethicone, and the mass ratio is isododecane: dimethicone: trimethylsiloxyphenyl dimethicone: phenyl trimethicone = 5:5:1:3.

[0048] The skin conditioning agent is composed of olive (OLEA EUROPAEA) shell oil, macadamia (MACADAM IA TERNIFOL IA) seed oil and jojoba (SIMMONDSIA CHINENSIS) seed oil, and the mass ratio is olive (OLEAEUROPAEA) shell oil: macadamia (MACADAM IA TERNIFOLIA) seed oil: jojoba (SIMMONDS IA CHINENSIS) seed oil = 5:5:1.

[0049] The moisturizer is composed of hydrolyzed sodium hyaluronate, Limnanthes alba seed oil, glyceryl behenate and ethylhexylglycerin, and the mass ratio is hydrolyzed sodium hyaluronate:Limnanthes alba seed oil:glyceryl behenate:ethylhexylglycerin=5:3:1:3.

[0050] Among them, the fragrance is jasmine fragrance essence.

[0051] The method for preparing the above-mentioned mirror-finished color-lasting lip glaze comprises the following steps:

[0052] According to the mass proportion, the emollient, film former, thickener, fragrance and moisturizer were mixed uniformly at 75°C at 120 r / min, and then the antioxidant, skin conditioner and preservative were added and mixed uniformly at 75°C at 120 r / min. Then, CI 45380 (RED 21Al Lake) and CI 45410 (RED 27Al Lake) in the colorant were added and mixed uniformly at 65°C-75°C at 80 r / min-120 r / min. Then, colorant I, colorant II, colorant III and colorant IV in the colorant were added and mixed uniformly at 75°C at 120 r / min. Finally, CI 15985, CI 15850 Red 6 (Red 6Ba Lake) and CI 15850 Red 7 (Red 7Ca Lake) in the colorant were added and mixed uniformly at 75°C at 120 r / min to obtain lip glaze.

[0053] Example 3

[0054] A mirror-finished color-holding lip glaze, the lip glaze being made of the following raw materials in parts by mass: 20 parts of an emollient, 5 parts of a trimethylsiloxysilicate film former, 20 parts of a hydrogenated (styrene / isoprene) copolymer thickener, 0.1 parts of a tocopherol acetate antioxidant, 10 parts of a skin conditioner, 0.5 parts of a moisturizer, 0.1 parts of a fragrance, 0.1 parts of a phenoxyethanol preservative, and 8 parts of a colorant;

[0055] Wherein, the colorant is composed of colorant I, colorant II, colorant III, colorant IV, CI 15985, CI 15850 Red 6 (Red 6Ba Lake), CI 15850 Red 7 (Red 7Ca Lake), CI 45380 (RED 21Al Lake) and CI 45410 (RED 27Al Lake), and the mass ratio is colorant I: colorant II: colorant III: colorant IV: CI 15985: CI15850 Red 6 (Red 6Ba Lake): CI 15850 Red 7 (Red 7Ca Lake): CI 45380 (RED 21Al Lake): CI45410 (RED 27Al Lake) = 1:0.5:0.5:1:1:1:1:0.5:0.5;

[0056] Colorant I is a complex of CI 77891 and polymethylsiloxane, and the composite mass ratio is CI 77891: polymethylsiloxane = 1:0.1. Colorant II is a complex of CI 77492 and triethoxycaprylylsilane, and the composite mass ratio is CI77492: triethoxycaprylylsilane = 1:0.2. Colorant III is a complex of CI 77491 and triethoxycaprylylsilane, and the composite mass ratio is CI 77491: triethoxycaprylylsilane = 1:0.2. Colorant IV is a complex of CI 77499 and triethoxycaprylylsilane, and the composite mass ratio is CI 77499: triethoxycaprylylsilane = 1:0.2. CI 15985, CI 15850 Red 6 (Red 6Ba Lake) and CI 15850 Red 7 (Red 7Ca Lake) are all modified colorants. The modification method of CI 15985 is as follows: according to the mass ratio, purified water: ethanol: CI 15985: polyvinyl pyrrolidone: rosin acrylate = 90:20:10:2:0.5, mixed, and then spray dried to remove ethanol and water to obtain the modified CI 15985. The modification method of CI 15850 Red 6 (Red6Ba Lake) is as follows: according to the mass ratio, purified water: ethanol: CI 15850 Red 6 (Red6Ba Lake): polyvinyl pyrrolidone: rosin acrylate = 90:20:10:2:0.5, mixed, and then spray dried to remove ethanol and water to obtain the modified CI 15850 Red 6 (Red 6Ba Lake). The modification method of CI 15850 Red 7 (Red 7Ca Lake) is as follows: according to the mass ratio, purified water: ethanol: CI 15850 Red 7 (Red 7Ca Lake): polyvinyl pyrrolidone: rosin acrylate = 90:20:10:2:0.5, mixed, and then spray-dried to remove ethanol and water to obtain the modified CI 15850 Red 7 (Red 7Ca Lake).

[0057] The emollient is composed of isododecane, dimethicone, trimethylsiloxyphenyl dimethicone and phenyl trimethicone, and the mass ratio is isododecane: dimethicone: trimethylsiloxyphenyl dimethicone: phenyl trimethicone = 2:2:0.5:1.

[0058] The skin conditioning agent is composed of olive (OLEA EUROPAEA) shell oil, macadamia (MACADAM IA TERNIFOL IA) seed oil and jojoba (SIMMONDSIA CHINENSIS) seed oil, and the mass ratio is olive (OLEAEUROPAEA) shell oil: macadamia (MACADAM IA TERN IFOLIA) seed oil: jojoba (SIMMONDS IA CHINENSIS) seed oil = 2:2:0.3.

[0059] Among them, the moisturizer is composed of hydrolyzed sodium hyaluronate, Limnanthes alba seed oil, glyceryl behenate and ethylhexylglycerin, and the mass ratio is hydrolyzed sodium hyaluronate:Limnanthes alba seed oil:glyceryl behenate:ethylhexylglycerin=2:1:0.5:0.5.

[0060] Among them, the fragrance is orange blossom flavor essence.

[0061] The method for preparing the above-mentioned mirror-finished color-lasting lip glaze comprises the following steps:

[0062] According to the mass proportions, the emollient, film former, thickener, fragrance and moisturizer were mixed uniformly at 65°C for 80 r / min, and then the antioxidant, skin conditioner and preservative were added and mixed uniformly at 65°C for 80 r / min. Then, CI 45380 (RED 21Al Lake) and CI 45410 (RED 27Al Lake) in the colorant were added and mixed uniformly at 65°C-75°C for 80 r / min-120 r / min. Then, colorant I, colorant II, colorant III and colorant IV in the colorant were added and mixed uniformly at 65°C for 80 r / min. Finally, CI 15985, CI 15850 Red 6 (Red 6Ba Lake) and CI 15850 Red 7 (Red 7Ca Lake) in the colorant were added and mixed uniformly at 65°C for 80 r / min to obtain lip glaze.

[0063] Example 4

[0064] A mirror-finished color-holding lip glaze, the lip glaze being made of the following raw materials in parts by mass: 20 parts of an emollient, 10 parts of a trimethylsiloxysilicate film former, 20 parts of a hydrogenated (styrene / isoprene) copolymer thickener, 0.5 parts of a tocopherol acetate antioxidant, 10 parts of a skin conditioner, 5 parts of a moisturizer, 0.1 parts of a fragrance, 0.8 parts of a phenoxyethanol preservative, and 8 parts of a colorant;

[0065] Wherein, the colorant is composed of colorant I, colorant II, colorant III, colorant IV, CI 15985, CI 15850 Red 6 (Red 6Ba Lake), CI 15850 Red 7 (Red 7Ca Lake), CI 45380 (RED 21Al Lake) and CI 45410 (RED 27Al Lake), and the mass ratio is colorant I: colorant II: colorant III: colorant IV: CI 15985: CI15850 Red 6 (Red 6Ba Lake): CI 15850 Red 7 (Red 7Ca Lake): CI 45380 (RED 21Al Lake): CI45410 (RED 27Al Lake) = 3:0.5:1:1:3:1:5:0.5:1;

[0066] Colorant I is a complex of CI 77891 and polymethylsiloxane, and the composite mass ratio is CI 77891: polymethylsiloxane = 1:0.3. Colorant II is a complex of CI 77492 and triethoxycaprylylsilane, and the composite mass ratio is CI77492: triethoxycaprylylsilane = 1:0.4. Colorant III is a complex of CI 77491 and triethoxycaprylylsilane, and the composite mass ratio is CI 77491: triethoxycaprylylsilane = 1:0.4. Colorant IV is a complex of CI 77499 and triethoxycaprylylsilane, and the composite mass ratio is CI 77499: triethoxycaprylylsilane = 1:0.4. CI 15985, CI 15850 Red 6 (Red 6Ba Lake) and CI 15850 Red 7 (Red 7Ca Lake) are all modified colorants. The modification method of CI 15985 is as follows: according to the mass ratio, purified water: ethanol: CI 15985: polyvinyl pyrrolidone: rosin acrylate = 90:30:10:5:0.5, mixed, and then spray dried to remove ethanol and water to obtain the modified CI 15985. The modification method of CI 15850 Red 6 (Red6Ba Lake) is as follows: according to the mass ratio, purified water: ethanol: CI 15850 Red 6 (Red6Ba Lake): polyvinyl pyrrolidone: rosin acrylate = 100:20:20:2:1.2, mixed, and then spray dried to remove ethanol and water to obtain the modified CI 15850 Red 6 (Red 6Ba Lake). The modification method of CI 15850 Red 7 (Red 7Ca Lake) is as follows: according to the mass ratio, purified water: ethanol: CI 15850 Red 7 (Red 7Ca Lake): polyvinyl pyrrolidone: rosin acrylate = 90:30:10:5:0.5, mixed, and then spray-dried to remove ethanol and water to obtain the modified CI 15850 Red 7 (Red 7Ca Lake).

[0067] The emollient is composed of isododecane, dimethicone, trimethylsiloxyphenyl dimethicone and phenyl trimethicone, and the mass ratio is isododecane: dimethicone: trimethylsiloxyphenyl dimethicone: phenyl trimethicone = 5:2:1:1.

[0068] The skin conditioning agent is composed of olive (OLEA EUROPAEA) shell oil, macadamia (MACADAM IA TERNIFOL IA) seed oil and jojoba (SIMMONDSIA CHINENSIS) seed oil, and the mass ratio is olive (OLEAEUROPAEA) shell oil: macadamia (MACADAM IA TERN IFOLIA) seed oil: jojoba (SIMMONDS IA CHINENSIS) seed oil = 5:2:1.

[0069] The moisturizer is composed of hydrolyzed sodium hyaluronate, Limnanthes alba seed oil, glyceryl behenate and ethylhexylglycerin, and the mass ratio is hydrolyzed sodium hyaluronate:Limnanthes alba seed oil:glyceryl behenate:ethylhexylglycerin=2:3:0.5:3.

[0070] Among them, the fragrance is osmanthus fragrance essence.

[0071] The method for preparing the above-mentioned mirror-finished color-lasting lip glaze comprises the following steps:

[0072] According to the mass proportions, the emollient, film former, thickener, fragrance and moisturizer were mixed uniformly at 65°C at 120 r / min, and then the antioxidant, skin conditioner and preservative were added and mixed uniformly at 65°C at 120 r / min. Then, CI 45380 (RED 21Al Lake) and CI 45410 (RED 27Al Lake) in the colorant were added and mixed uniformly at 65°C-75°C at 80 r / min-120 r / min. Then, colorant I, colorant II, colorant III and colorant IV in the colorant were added and mixed uniformly at 65°C at 120 r / min. Finally, CI 15985, CI 15850 Red 6 (Red 6Ba Lake) and CI 15850 Red 7 (Red 7Ca Lake) in the colorant were added and mixed uniformly at 65°C at 120 r / min to obtain lip glaze.

[0073] Example 5

[0074] A mirror-finished color-holding lip glaze, the lip glaze being made of the following raw materials in parts by mass: 50 parts of an emollient, 5 parts of a trimethylsiloxysilicate film former, 30 parts of a hydrogenated (styrene / isoprene) copolymer thickener, 0.1 parts of a tocopherol acetate antioxidant, 25 parts of a skin conditioner, 0.5 parts of a moisturizer, 3 parts of a fragrance, 0.1 parts of a phenoxyethanol preservative, and 15 parts of a colorant;

[0075] Wherein, the colorant is composed of colorant I, colorant II, colorant III, colorant IV, CI 15985, CI 15850 Red 6 (Red 6Ba Lake), CI 15850 Red 7 (Red 7Ca Lake), CI 45380 (RED 21Al Lake) and CI 45410 (RED 27Al Lake), and the mass ratio is colorant I: colorant II: colorant III: colorant IV: CI 15985: CI15850 Red 6 (Red 6Ba Lake): CI 15850 Red 7 (Red 7Ca Lake): CI 45380 (RED 21Al Lake): CI45410 (RED 27Al Lake) = 1:3:0.5:5:1:5:1:1:0.5;

[0076] Colorant I is a complex of CI 77891 and polymethylsiloxane, and the composite mass ratio is CI 77891: polymethylsiloxane = 5:0.1. Colorant II is a complex of CI 77492 and triethoxycaprylylsilane, and the composite mass ratio is CI77492: triethoxycaprylylsilane = 5:0.2. Colorant III is a complex of CI 77491 and triethoxycaprylylsilane, and the composite mass ratio is CI 77491: triethoxycaprylylsilane = 5:0.2. Colorant IV is a complex of CI 77499 and triethoxycaprylylsilane, and the composite mass ratio is CI 77499: triethoxycaprylylsilane = 5:0.2. CI 15985, CI 15850 Red 6 (Red 6Ba Lake) and CI 15850 Red 7 (Red 7Ca Lake) are all modified colorants. The modification method of CI 15985 is as follows: according to the mass ratio, purified water: ethanol: CI 15985: polyvinyl pyrrolidone: rosin acrylate = 100:20:20:2:1.5, mixed, and then spray dried to remove ethanol and water to obtain the modified CI 15985. The modification method of CI 15850 Red 6 (Red6Ba Lake) is as follows: according to the mass ratio, purified water: ethanol: CI 15850 Red 6 (Red6Ba Lake): polyvinyl pyrrolidone: rosin acrylate = 90:30:10:5:0.5, mixed, and then spray dried to remove ethanol and water to obtain the modified CI 15850 Red 6 (Red 6Ba Lake). The modification method of CI 15850 Red 7 (Red 7Ca Lake) is as follows: according to the mass ratio, purified water: ethanol: CI 15850 Red 7 (Red 7Ca Lake): polyvinyl pyrrolidone: rosin acrylate = 100:20:20:2:1.5, mixed, and then spray-dried to remove ethanol and water to obtain the modified CI 15850 Red 7 (Red 7Ca Lake).

[0077] The emollient is composed of isododecane, dimethicone, trimethylsiloxyphenyl dimethicone and phenyl trimethicone, and the mass ratio is isododecane: dimethicone: trimethylsiloxyphenyl dimethicone: phenyl trimethicone = 2:5:0.5:3.

[0078] The skin conditioning agent is composed of olive (OLEA EUROPAEA) shell oil, macadamia (MACADAM IA TERNIFOL IA) seed oil and jojoba (SIMMONDSIA CHINENSIS) seed oil, and the mass ratio is olive (OLEAEUROPAEA) shell oil: macadamia (MACADAM IA TERNIFOLIA) seed oil: jojoba (SIMMONDS IA CHINENSIS) seed oil = 2:5:0.3.

[0079] Among them, the moisturizer is composed of hydrolyzed sodium hyaluronate, Limnanthes alba seed oil, glyceryl behenate and ethylhexylglycerin, and the mass ratio is hydrolyzed sodium hyaluronate:Limnanthes alba seed oil:glyceryl behenate:ethylhexylglycerin=5:1:1:0.5.

[0080] Among them, the fragrance is a fruity flavor.

[0081] The method for preparing the above-mentioned mirror-finished color-lasting lip glaze comprises the following steps:

[0082] According to the mass proportions, the emollient, film former, thickener, fragrance and moisturizer were mixed uniformly at 75°C for 80 r / min, and then the antioxidant, skin conditioner and preservative were added and mixed uniformly at 75°C for 80 r / min. Then, CI 45380 (RED 21Al Lake) and CI 45410 (RED 27Al Lake) in the colorant were added and mixed uniformly at 65°C-75°C for 80 r / min-120 r / min. Then, colorant I, colorant II, colorant III and colorant IV in the colorant were added and mixed uniformly at 75°C for 80 r / min. Finally, CI 15985, CI 15850 Red 6 (Red 6Ba Lake) and CI 15850 Red 7 (Red 7Ca Lake) in the colorant were added and mixed uniformly at 75°C for 80 r / min to obtain lip glaze.

[0083] Preparation Comparative Example 1

[0084] Colorant I only adds CI 77891, and does not compound with polymethylsiloxane (does not contain polymethylsiloxane); colorant II only adds CI 77492, and does not compound with triethoxycaprylylsilane (does not contain triethoxycaprylylsilane); colorant III only adds CI 77491, and does not compound with triethoxycaprylylsilane (does not contain triethoxycaprylysilane); colorant IV only adds CI77499, and does not compound with triethoxycaprylysilane (does not contain triethoxycaprylysilane). Other parameters and methods are the same as in Example 1.

[0085] Preparation Comparative Example 2

[0086] CI 15985, CI 15850 Red 6 (Red 6Ba Lake) and CI 15850 Red 7 (Red 7Ca Lake) were not modified, and pure products of CI 15985, CI 15850 Red 6 (Red 6Ba Lake) and CI 15850 Red 7 (Red 7Ca Lake) were directly added. Other parameters and methods were the same as in Example 1.

[0087] Preparation Comparative Example 3

[0088] Colorant I contains only CI 77891, colorant II contains only CI 77492, colorant III contains only CI 77491, and colorant IV contains only CI 77499; CI 15985, CI 15850 Red 6 (Red 6Ba Lake) and CI 15850 Red 7 (Red 7Ca Lake) are not modified. Other parameters and methods are the same as in Example 1.

[0089] Preparation Comparative Example 4

[0090] The trimethylsiloxysilicate film former was replaced by dimer linoleyl dimer linoleate.

[0091] The following experimental tests were performed on the lip glazes of Examples 1 to 5 and Comparative Examples 1 to 4.

[0092] 1. Toxicity test

[0093] According to the Horn method, 90 mice were selected and divided into 9 groups, half male and half female; the oral dose of lip glaze was 21.5g / (kg·bw), 10.0g / (kg·bw), 4.65g / (kg·bw), and 2.15g / (kg·bw), respectively, and the poisoning reaction and death of mice were observed within two weeks after oral administration. The test results of the lip glaze of each embodiment and comparative example were: negative, belonging to non-toxic substances. The raw materials used in the present invention are all in the catalogue of cosmetics allowed to be added.

[0094] 2. Color retention test

[0095] 90 female subjects (20 to 48 years old) were selected and divided into 9 groups. The subjects were respectively smeared with lip glazes of Examples 1 to 5 and Comparative Examples 1 to 4, and smeared evenly for 3 times. The subjects were photographed to record the color. After that, they drank water and ate normally. After a certain period of time, the subjects were photographed to observe the color of their lips, and the residual amount of lip glaze was measured and calculated. The test results are shown in Table 1 below:

[0096] Table 1 Color retention test results

[0097]

[0098] Color change rating: 1 - slightly lightened, moist; 2 - moderately lightened and moist luster; 3 - severely lightened and moist luster; 4 - severely lightened and dry and matte; 5 - color almost disappears and is dry and matte.

[0099] Residue grade evaluation: 100% ≥ A ≥ 80%, 80% > B ≥ 60%, 60% > C ≥ 40%, 40% > D ≥ 20%, 20% > E ≥ 0%.

[0100] From the above results, it can be seen that the lip glazes of Examples 1 to 5 have good color retention and a long time of moist gloss. From Comparative Example 1, it can be seen that the use of non-compounded colorants I, II and III has poor relative color retention. From Comparative Example 2, it can be seen that the use of unmodified CI 15985, CI 15850 Red 6 and CI 15850 Red 7 has poor relative color retention, and the color retention and moist gloss drop significantly after 3 hours in the later period. From Comparative Example 3, it can be seen that the use of non-compounded colorants I, II and III, and the use of unmodified CI 15985, CI 15850 Red 6 and CI 15850 Red 7, the color retention and moist gloss continue to drop significantly after 1 hour. From Comparative Example 4, it can be seen that the lip glaze with a film-forming agent has good color retention and moist gloss in the early stage, but the color retention and moist gloss drop significantly after 3 hours.

[0101] 3. Dyeing cup test

[0102] During the color holding test (experiment 2), after applying the lip glaze, the staining cup test was carried out at the same time. After 5 minutes, 1 hour, 2 hours, 3 hours, and 4 hours of application and absorption, the lips were placed on the wall of the white porcelain cup to keep pressing the lip print for 30 seconds, and then the wall of the white porcelain cup was observed to see if it was stained with the lip glaze color. The test results are shown in Table 2 below:

[0103] Table 2 Dyeing cup test results

[0104] Sample 5 minutes later 1 hour later 2h later 3h later 4h later Example 1 1 0 0 0 0 Example 2 1 0 0 0 0 Example 3 1 0 0 0 0 Example 4 1 0 0 0 0 Example 5 1 0 0 0 0 Comparative Example 1 2 1 1 0 0 Comparative Example 2 2 1 0 0 0 Comparative Example 3 2 2 1 1 0 Comparative Example 4 2 1 1 0 0

[0105] The lipstick staining rating is as follows: 0-no staining (colorless), 1-slight staining (slightly pink, almost no lip glaze staining), 2-moderate staining (red, a small amount of lip glaze staining), 3-severe staining (red, with a large amount of lip glaze staining).

[0106] From the above results, it can be seen that the lip glazes of Examples 1 to 5 have a very good effect of not staining the cup. From Comparative Example 1, it can be seen that the non-compounded colorant I, colorant II and colorant III are used, and the non-staining effect of the cup is relatively poor. From Comparative Example 2, it can be seen that the non-staining effect of the cup is relatively poor by using unmodified CI 15985, CI 15850 Red 6 and CI 15850 Red 7. From Comparative Example 3, it can be seen that the non-compounded colorant I, colorant II and colorant III, and the non-modified CI 15985, CI 15850 Red 6 and CI15850 Red 7 are used at the same time, and the lip glaze does not stain the cup. The effect is worse. From Comparative Example 4, it can be seen that the lip glaze with a film-forming agent replaced has a poor effect of not staining the cup.

[0107] 4. Lip staining test

[0108] 90 female subjects (22 to 42 years old) were selected and divided into 9 groups on average. The lip color was recorded by taking photos, and then the lip glazes of Examples 1 to 5 and Comparative Examples 1 to 4 were applied respectively. After repeated and even application for 3 times, the color was kept for 1 hour, and the lip glaze remover was used to remove the makeup, the lip glaze was washed off, and the lip color was recorded by taking photos. The lip color and the residual situation were observed and compared. The test results are shown in Table 3 below:

[0109] Table 3 Lip staining test results

[0110]

[0111] Lip staining rating: 0 - no change or almost no change, 1 - reddening.

[0112] From the above results, it can be seen that the lip glazes of Examples 1 to 5 and Comparative Example 1 have good makeup removal effects, no residue, and no staining. The colorants in Comparative Examples 2 and 3 do not contain polyvinyl pyrrolidone and rosin acrylate modification, and the makeup removal effect is poor. Comparative Example 4 replaces the film-forming agent, and the makeup removal effect is poor.

[0113] In summary, the results show that the lip glazes of Examples 1 to 5 have good color retention, do not stain the lips, are easy to remove, clean thoroughly, do not stain the lips, have no residue, are not sticky, and have a very good use experience.

Claims

1. A mirror-finished color-holding lip glaze, characterized in that: The lip glaze is made of the following raw materials in parts by weight: 20 to 50 parts of emollient, 5 to 10 parts of film former, 20 to 30 parts of thickener, 0.1 to 0.5 parts of antioxidant, 10 to 25 parts of skin conditioner, 0.5 to 5 parts of moisturizer, 0.1 to 3 parts of fragrance, 0.1 to 0.8 parts of preservative and 8 to 15 parts of colorant; The film former is trimethylsiloxysilicate; The emollient is composed of isododecane, dimethicone, trimethylsiloxyphenyl dimethicone and phenyl trimethicone, and the mass ratio is isododecane: dimethicone: trimethylsiloxyphenyl dimethicone: phenyl trimethicone = (2-5): (2-5): (0.5-1): (1-3); The colorant is composed of colorant I, colorant II, colorant III, colorant IV, CI 15985, CI 15850 Red 6, CI15850 Red 7, CI 45380 and CI 45410, and the mass ratio is colorant I: colorant II: colorant III: colorant IV: CI 15985: CI 15850 Red 6: CI 15850 Red 7: CI 45380: CI 45410=(1-3):(0.5-3):(0.5-1):(1-5):(1-3):(1-5):(1-5):(0.5-1):(0.5-1); The colorant I is a composite of CI 77891 and polymethylsiloxane, and the composite mass ratio is CI 77891: polymethylsiloxane = (1-5): (0.1-0.3); The colorant II is a composite of CI 77492 and triethoxyoctylsilane, and the composite mass ratio is CI 77492:triethoxyoctylsilane=(1-5):(0.2-0.4); The colorant III is a composite of CI 77491 and triethoxyoctylsilane, and the composite mass ratio is CI 77491:triethoxyoctylsilane=(1-5):(0.2-0.4); The colorant IV is a composite of CI 77499 and triethoxyoctylsilane, and the composite mass ratio is CI 77499:triethoxyoctylsilane=(1-5):(0.2-0.4); The CI 15985, CI 15850 Red 6 and CI 15850 Red 7 are all modified colorants, and the modification method is: according to the mass ratio, purified water: ethanol: CI 15985 or CI 15850 Red 6 or CI 15850 Red 7: polyvinyl pyrrolidone: rosin acrylate = (90-100): (20-30): (10-20): (2-5): (0.5-2), mix, and then spray dry to remove ethanol and water to obtain the modified colorant.

2. The mirror-finished color-holding lip glaze according to claim 1, characterized in that: The thickener is a hydrogenated (styrene / isoprene) copolymer.

3. The mirror-finished color-holding lip glaze according to claim 1, characterized in that: The skin conditioner is composed of olive shell oil, macadamia seed oil and jojoba seed oil, and the mass ratio is olive shell oil: macadamia seed oil: jojoba seed oil = (2-5): (2-5): (0.3-1).

4. The mirror-finished color-lasting lip glaze according to claim 1, characterized in that: The moisturizer is composed of hydrolyzed sodium hyaluronate, meadowfoam seed oil, glyceryl behenate and ethylhexylglycerin, and the mass ratio is hydrolyzed sodium hyaluronate: meadowfoam seed oil: glyceryl behenate: ethylhexylglycerin = (2-5): (1-3): (0.5-1): (0.5-3).

5. The mirror-finished color-lasting lip glaze according to claim 1, characterized in that: The antioxidant is tocopherol acetate.

6. The mirror-finished color-lasting lip glaze according to claim 1, characterized in that: The aromatic agent is essence.

7. The mirror-finished color-lasting lip glaze according to claim 1, characterized in that: The preservative is phenoxyethanol.

8. The method for preparing the mirror-finished color-lasting lip glaze according to claim 1, characterized in that: The steps include: Mix the emollient, film former, thickener, fragrance and moisturizer evenly, then add antioxidant, skin conditioner and preservative and continue to mix evenly, then add CI 45380 and CI 45410 in the colorant and continue to mix evenly, then add colorant I, colorant II, colorant III and colorant IV in the colorant and continue to mix evenly, finally add CI 15985, CI 15850 Red 6 and CI 15850 Red 7 in the colorant and mix evenly to obtain lip glaze.

9. The method for preparing a mirror-finished color-lasting lip glaze according to claim 8, characterized in that: The mixing temperature is 65° C. to 75° C., and the mixing rotation speed is 80 r / min to 120 r / min.

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