An environmentally friendly washing machine and an environmentally friendly washing machine

By introducing a trioxide generator into the washing machine and using trioxide water for sterilization and disinfection, the problems of sewage discharge and resource consumption in existing washing machines are solved, efficient and environmentally friendly washing effects are achieved, and environmental pollution and resource waste are reduced.

CN119243441BActive Publication Date: 2025-09-26GUANGDONG YIKANG BIOTECHNOLOGY CO LTD
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Patent Information

Application Number
CN202411610643.8
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-11-12
Publication Date
2025-09-26
Estimated Expiration
2044-11-12

AI Technical Summary

Technical Problem

Existing washing machines rely on detergents and disinfectants, which lead to large amounts of sewage discharge and environmental pollution. The high phosphorus content in detergents causes eutrophication of water bodies and harms human skin. Commercial washing consumes a lot of resources, putting pressure on businesses and the environment.

Method used

An ozone generator is used, and oxygen cylinders, pressure reducing valves, flow meters, ozone generators, ozone concentration monitors, control systems, water inlet mechanisms, and dehydration mechanisms are used to generate ozone for sterilization and disinfection, avoiding the use of detergents and disinfectants. Efficient sterilization and decontamination are achieved through trioxide water, and the trioxide dissolves in water to become trioxide water for disinfection.

Benefits of technology

It achieves efficient sterilization and disinfection without the need for detergents and disinfectants, reduces sewage discharge and resource consumption, reduces pollution and energy consumption. Water trioxide is safe and residue-free, has a significant sterilization effect, reduces clothing shrinkage and oil stains, and improves clothing durability.

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Abstract

The present invention relates to the technical field of environmentally friendly washing machines and provides an ozone generator for environmentally friendly washing machines and an environmentally friendly washing machine. The ozone generator for environmentally friendly washing machines is applied to a washing machine and comprises: an oxygen cylinder, a pressure reducing valve, a flow meter, an ozone generator, an ozone concentration monitor, a control system, a water inlet mechanism, and a dehydration mechanism. The input end of the pressure reducing valve is connected to the output end of the oxygen cylinder, the input end of the flow meter is connected to the output end of the pressure reducing valve, the input end of the ozone generator is connected to the output end of the flow meter, and the input end of the ozone concentration monitor is connected to the output end of the ozone generator. The above technical solution solves the problems in the prior art of laundry reliance on detergents and disinfectants, which generate a large amount of wastewater every day, causing environmental pollution and wasting energy in wastewater treatment. The high phosphorus content in detergents causes eutrophication of water bodies, harms human skin, especially infant underwear and women's underwear, and may also cause disease.
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Description

Technical Field

[0001] The present invention relates to the technical field of environmentally friendly washing machines, and in particular to a tri-oxygen generating device for an environmentally friendly washing machine and an environmentally friendly washing machine. Background Art

[0002] With the continuous improvement of living standards, washing machines have entered thousands of households and become one of the indispensable household appliances in people's daily lives. Existing washing machine washing technology must add detergents such as laundry liquid and washing powder. If you want to sterilize and disinfect clothes, washing machines without high-temperature disinfection must also add disinfectant. Based on a conservative calculation of washing clothes once a day and using 50 liters of water each time (drum washing machine: about 40L-70L, pulsator washing machine: about 100L-130L), the annual sewage generated is as high as 2.555 billion tons, especially in large-scale specialized washing places (washing hospital sheets, clothes; hotels, school sheets). The large amount of detergents and disinfectants used in these places are at higher concentrations. The residual chemical detergents are discharged into the nature along with the sewage, causing environmental pollution and wasting energy consumption in treating sewage. In addition, waste packaging such as detergents, washing powders, disinfectants, etc. requires a lot of energy to process to reduce pollution to the environment.

[0003] Most detergents are artificially synthesized organic compounds, such as laundry detergent and dishwashing liquid, which contain high levels of phosphorus (sodium phosphate). After washing, the phosphorus-containing wastewater flows into rivers and lakes, causing eutrophication of water bodies, resulting in vigorous reproduction of algae in the water bodies, causing fish and other aquatic organisms to die due to lack of oxygen. At the same time, it also causes great harm to human skin, especially infants' and young children's underwear, and even causes disease. If clothes and bed sheets in public places are not thoroughly disinfected, there is a risk of virus cross-infection.

[0004] The main active ingredients of detergents are surfactants and cleaning agents. In addition, there are auxiliary ingredients such as bleach, fluorescent brighteners, corrosion inhibitors, foam regulators, enzymes, etc. Commercial detergents generally contain one or several surfactants and several cleaning agents due to their large usage and the wide variety of fabric sources. Commercial washing not only requires a large amount of detergent, but also a large amount of gas, washing water and electricity consumption, which puts great pressure on large-scale specialized laundry businesses and the environment. Summary of the Invention

[0005] This invention proposes an environmentally friendly ozone generator for washing machines and an environmentally friendly washing machine. This solves the existing problem of washing machines relying on detergents and disinfectants for daily laundry, generating large amounts of wastewater. This problem is particularly severe in large, specialized laundry facilities, where residual chemicals are discharged into the environment along with the wastewater, causing environmental pollution and wasted energy in wastewater treatment. Furthermore, the high phosphorus content in detergents causes eutrophication of water bodies, harming human skin, particularly infant and toddler underwear and women's underwear, and potentially causing illness. Furthermore, commercial laundry consumes large amounts of detergent, gas, water, and electricity, placing significant pressure on businesses and the environment.

[0006] The technical solution of the present invention is as follows: an environmentally friendly ozone generator for a washing machine, applied to a washing machine, comprising: an oxygen cylinder, a pressure reducing valve, a flow meter, an ozone generator, an ozone concentration monitor, a control system, a water inlet mechanism, and a dehydration mechanism;

[0007] The input end of the pressure reducing valve is communicated with the output end of the oxygen cylinder;

[0008] The input end of the flow meter is communicated with the output end of the pressure reducing valve;

[0009] The input end of the ozone generator is connected to the output end of the flow meter;

[0010] The input end of the ozone concentration monitor is connected to the output end of the ozone generator;

[0011] The control system is used to control the operation of the equipment;

[0012] The water inlet mechanism is connected to the washing machine and is used to fill water into the washing machine;

[0013] The dehydration mechanism is arranged on the washing machine and is used for discharging sewage.

[0014] Preferably, the control system includes: a 24V power supply, a human-machine interface and a main control circuit board;

[0015] The human-machine interface is electrically connected to a 24V power supply;

[0016] The main control circuit board is electrically connected to the human-machine interface, and the main control circuit board is electrically connected to the 24V power supply.

[0017] Furthermore, the water inlet mechanism includes: a water-air mixing pump and a tap water inlet valve;

[0018] The output end of the water-gas mixing pump is connected to the output end of the ozone concentration monitor;

[0019] The output end of the tap water inlet valve is communicated with the output end of the water-gas mixing pump.

[0020] Furthermore, the dehydration mechanism includes: a drain valve, a drying device and a tri-oxygen degrader;

[0021] The drain valve is connected to the washing machine;

[0022] The drying device is arranged on the washing machine;

[0023] The three-oxygen degrader is arranged on the washing machine.

[0024] In the aforementioned solution, the environmentally friendly washing machine includes the ozone generator for an environmentally friendly washing machine as described in any one of the above solutions.

[0025] The working principle and beneficial effects of the present invention are:

[0026] 1. In the present invention, there is no need to add any detergent or disinfectant. The unique sterilization, disinfection and decontamination capabilities of ozone are utilized, and the washing effect is better than that of existing washing machines. The sterilization rate can reach 99.99%. The discharged water is not only pollution-free, but also has the effect of sterilization and deodorization on the sewer pipes.

[0027] 2. In the present invention, there are 140 million washing machines in China; 2.555 billion tons of sewage are generated each year. Based on the electricity consumption of 0.2 kWh per ton (Internet source: sewage treatment power consumption is 0.2-0.3 kWh / m3), 510 million kWh of electricity can be saved each year. Every kWh (kilowatt-hour) of electricity saved saves 0.4 kg of standard coal, and at the same time reduces pollution emissions by 0.272 kg of carbon and 0.785 kg of carbon dioxide, which means that carbon emissions can be reduced by 138.7 million kg and carbon dioxide emissions by 400 million kg each year.

[0028] 3. In the present invention, based on the 1.4 billion population in China and the average annual per capita laundry detergent consumption of 3 kg, the online price of a 3 kg bottle of laundry detergent is about RMB 40. If a 20% discount is applied to the number of people who use laundry detergent (1.12 billion), 1.12 billion × RMB 40 = RMB 44.8 billion, which means RMB 44.8 billion can be saved annually.

[0029] 4. In the present invention, trioxygen is generated through the cooperation between the oxygen cylinder, the pressure reducing valve, the flow meter, the trioxygen generator, the trioxygen concentration monitor, the control system, the water inlet mechanism and the dehydration mechanism. Trioxygen is a strong oxidant that can decompose dirt and separate it from clothing fibers in a short period of time. Trioxygen can also effectively decompose oil stains and remove oil stains that cannot be removed by general detergents. Trioxygen can increase the nutrients in water and make clothes more naturally soft. In addition, washing clothes with trioxygen water can also reduce the shrinkage of clothes and increase the durability of clothes. The bactericidal ability of trioxygen is 150 times that of chlorine, and the bactericidal speed is 3000 times that of chlorine. The bactericidal effect of trioxygen dissolved in water to become trioxide water is more significant. Trioxide water can replace bleach and most liquid disinfectant chemicals. Therefore, trioxygen disinfection is safer than other disinfection methods, will not leave any residue, and will not cause secondary pollution. It is a more environmentally friendly disinfection method. BRIEF DESCRIPTION OF THE DRAWINGS

[0030] The present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments.

[0031] Figure 1 It is a schematic structural diagram of the present invention as a whole;

[0032] Figure 2 This is a schematic diagram of the overall structure of the second embodiment of the present invention;

[0033] Figure 3 This is a schematic diagram of the overall structure of the third embodiment of the present invention;

[0034] Figure 4 It is a schematic structural diagram of the interior of the box of the present invention;

[0035] Figure 5 This is a structural schematic diagram of the interior of the box of the present invention from another angle;

[0036] Figure 6 For the present invention Figure 5 A schematic diagram of the partially enlarged structure at point A in the middle;

[0037] Figure 7 For the present invention Figure 5 Schematic diagram of the locally enlarged structure at point B in the middle.

[0038] In the figure: 1. washing machine; 2. oxygen cylinder; 3. pressure reducing valve; 4. flow meter; 5. ozone generator; 6. ozone concentration monitor; 7. 24V power supply; 8. human-machine interface; 9. main control circuit board; 10. water-gas mixing pump; 11. tap water inlet valve; 12. drain valve; 13. drying device; 14. ozone degrader; 15. water inlet valve; 16. electrolysis module; 17. circulating water solenoid valve; 18. degrader solenoid valve; 19. degradation device; 20. drying equipment; 21. drain pump; 22. drain pipe; 23. interactive interface; 24. main control board; 25. constant current power supply; 26. box; 27. slide; 28. guide box; 29. ​​guide rail; 30. toothed belt; 31. moving frame; 32. moving gear; 33. first motor; 34. slide rod. DETAILED DESCRIPTION

[0039] The following will be combined with the embodiments of the present invention to clearly and completely describe the technical solutions in the embodiments of the present invention. Obviously, the embodiments described are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without making any creative efforts are within the scope of protection of the present invention.

[0040] Example 1, as Figure 1 As shown, this solution is applicable to a washing machine 1 weighing more than 25 kg and is applicable to large washing places. This embodiment proposes an environmentally friendly three-oxygen generating device for a washing machine, which is applied to the washing machine 1, including: an oxygen cylinder 2, a pressure reducing valve 3, a flow meter 4, a three-oxygen generator 5, a three-oxygen concentration monitor 6, a control system, a water inlet mechanism and a dehydration mechanism. The input end of the pressure reducing valve 3 is connected to the output end of the oxygen cylinder 2, the input end of the flow meter 4 is connected to the output end of the pressure reducing valve 3, the input end of the three-oxygen generator 5 is connected to the output end of the flow meter 4, and the input end of the three-oxygen concentration monitor 6 is connected to the output end of the three-oxygen generator 5. Through the oxygen cylinder 2, the pressure reducing valve 3, the flow meter 4, the three-oxygen generator 5, the three-oxygen concentration monitor 6, the control system, the water inlet mechanism and the dehydration mechanism, The cooperation between water bodies produces trioxygen, which is a strong oxidant that can decompose dirt in a short time and separate it from clothing fibers. Trioxygen can also effectively decompose oil stains and remove oil stains that ordinary detergents cannot remove. Trioxygen can increase the nutrients in water and make clothes more naturally soft. In addition, washing clothes with trioxygen water can also reduce the shrinkage of clothes and increase the durability of clothes. The bactericidal ability of trioxygen is 150 times that of chlorine, and the bactericidal speed is 3000 times that of chlorine. The bactericidal effect of trioxygen dissolved in water to become trioxide water is more significant. Trioxide water can replace bleach and most liquid disinfectant chemicals, so trioxygen disinfection is safer than other disinfection methods, there will be no residue, no secondary pollution, and it is a more environmentally friendly disinfection method.

[0041] It should also be added that the oxygen cylinder 2 can be purchased from outside and placed directly next to the washing machine 1 for use.

[0042] Among them, the control system is used to control the operation of the equipment. The control system includes: a 24V power supply 7, a human-machine interface 8 and a main control circuit board 9. The human-machine interface 8 is electrically connected to the 24V power supply 7, the main control circuit board 9 is electrically connected to the human-machine interface 8, and the main control circuit board 9 is electrically connected to the 24V power supply 7. Specifically, by connecting the 24V power supply 7 to provide power for the equipment, the operator controls the main control circuit board 9 through the human-machine interface 8 to issue instructions for operation.

[0043] Among them, the water inlet mechanism is connected to the washing machine 1 and is used to fill water into the washing machine 1. The water inlet mechanism includes: a water-gas mixing pump 10 and a tap water inlet valve 11. The output end of the water-gas mixing pump 10 is connected to the output end of the three-oxygen concentration monitor 6, and the output end of the tap water inlet valve 11 is connected to the output end of the water-gas mixing pump 10. Specifically, the tap water inlet valve 11 is connected to the faucet, and the water enters the washing machine 1 through the tap water inlet valve 11.

[0044] Among them, the dehydration mechanism is provided on the washing machine 1 for discharging sewage. The dehydration mechanism includes: a drain valve 12, a drying device 13 and a tri-oxygen degrader 14. The drain valve 12 is connected to the washing machine 1, the drying device 13 is provided on the washing machine 1, and the tri-oxygen degrader 14 is provided on the washing machine 1. Specifically, after washing is completed, the drain valve 12 is opened to drain the water, and then the clothes are dehydrated. At this time, the drying device 13 is started to dry the clothes. The residual tri-oxygen odor on the clothes is degraded into oxygen by the tri-oxygen degrader 14 and discharged.

[0045] The environmentally friendly washing machine 1 includes an ozone generator for an environmentally friendly washing machine according to any one of the above solutions.

[0046] In this embodiment, when the washing machine 1 is washing clothes, the 24V power supply 7 is turned on and the human-machine interface 8 displays the machine standby state;

[0047] Open oxygen cylinder 2 and adjust the oxygen pressure (0.1-0.15 MPa) and flow rate (0.8-1.5 m³ / h). The internal program for the three oxygen concentrations and flow rates has been preset and will automatically adjust according to the weight of the clothes.

[0048] Put in clothes (clothes that are easy to discolor should not be washed together with clothes of natural color. The washing machine 1 has a special washing program for clothes that are easy to discolor. You can select this function to wash such clothes). Press the start button. The washing machine 1 automatically detects the weight of the clothes and automatically selects the amount of water. The water inlet valve 11 opens and starts to fill the washing machine 1 with water.

[0049] At this time, the ozone generator 5 enters the preheating state and starts to produce ozone. The ozone enters the water-gas mixing pump 10. After the preset water level is reached, the water-gas mixing pump 10 starts to mix the ozone into the tap water for circulation.

[0050] The washing machine 1 washes clothes for 8 to 20 minutes. After each wash, the drain valve 12 is opened to drain the clothes (the drained water can be sent to the sewer for sterilization and deodorization). Generally, the clothes are washed three times. During the washing process, the trioxygen that is not dissolved in the water is degraded into oxygen by the trioxygen degrader 14 and discharged.

[0051] After washing is completed and dehydration is carried out, the drying device 13 is started to dry the clothes, and the residual three-oxygen odor on the clothes is degraded into oxygen by the three-oxygen degrader 14 and discharged.

[0052] After the whole process is completed, take out the clothes, which are now dry and sterile.

[0053] Embodiment 2: This solution is applicable to a household washing machine 1 weighing 3 to 20 kg. Figure 2 As shown, based on the first embodiment, this embodiment further proposes an environmentally friendly ozone generator for a washing machine, which is applied to a washing machine 1 and further includes: a water inlet valve 15, an electrolysis module 16, a circulating water solenoid valve 17, a gas-liquid mixing pump 35, a degrader solenoid valve 18, a degradation device 19, a drying device 20, a drain pump 21, a drain pipe 22 and a control mechanism. The input end of the electrolysis module 16 is connected to the water inlet valve 15, the output end of the electrolysis module 16 is connected to the washing machine 1, the output end of the circulating water solenoid valve 17 is connected to the electrolysis module 16, the output end of the gas-liquid mixing pump 35 is connected to the circulating water solenoid valve 17, the output end of the gas-liquid mixing pump 35 is connected to the washing machine 1, the output end of the gas-liquid mixing pump 35 is connected to the input end of the degrader solenoid valve 18, the input end of the degradation device 19 is connected to the output end of the degrader solenoid valve 18, the drying device 20 is provided on the washing machine 1, the drain pump 21 is provided on the washing machine 1, the input end of the drain pump 21 is connected to the washing machine 1, and the drain pipe 22 is connected to the output end of the drain pump 21;

[0054] The control mechanism is used to control the operation of the device, and the control mechanism includes: a constant current power supply 25, a main control board 24 and an interactive interface 23. The main control board 24 is electrically connected to the constant current power supply 25, and the interactive interface 23 is electrically connected to the main control board 24.

[0055] When the present embodiment is in use, the interactive interface 23 displays the standby state when the power is turned on;

[0056] Turn on the faucet, put in clothes (clothes that are easy to discolor should not be washed together with clothes of natural color. The washing machine 1 has a special washing program for clothes that are easy to discolor. This function can be selected to wash such clothes). Press the start button. The washing machine 1 automatically selects the amount of water according to the weight of the clothes. The water inlet valve 15 opens and starts to fill with water.

[0057] Tap water enters the electrolysis module 16, the constant current power supply 25 is energized, the electrolysis module 16 starts working, generates hydrogen and trioxide water, and enters the washing machine 1. When the water level reaches the set water level, the water inlet valve 15 is closed and washing begins;

[0058] After entering the washing state, hydrogen and trioxide react rapidly with organic matter (dirt) on the clothes, and the concentration of hydrogen and trioxide is consumed and reduced. At this time, the circulating water solenoid valve 17 opens, and the gas-liquid mixing pump 35 draws water from the washing machine 1 tub and the hydrogen and trioxide that have not dissolved in the water into the electrolysis module 16. The electrolysis module 16 continues to operate, generating new hydrogen and trioxide water and returning them to the washing machine 1.

[0059] The electrolysis module 16 and the gas-liquid mixing pump 35 work until the washing is completed; after each washing, the drainage pump 21 is turned on to dehydrate, and the sewage is discharged from the drain pipe 22 (the discharged water can be used to sterilize and deodorize the sewer). The washing time is 8 to 10 minutes, and generally three washings are performed;

[0060] After washing and dehydration, the drying device 20 is started to dry the clothes, the degrader solenoid valve 18 is opened, and the residual tri-oxygen on the clothes is degraded into oxygen through the degradation device 19 and discharged;

[0061] After the whole process is completed, take out the clothes. The clothes are now dry and sterile.

[0062] Example 3, as Figures 3 to 7 As shown, on the basis of the first and second embodiments, in order to facilitate the maintenance of the above-mentioned equipment, the third embodiment continues to propose a moving mechanism for driving the above-mentioned equipment to move out of the washing machine 1, which also includes: a box 26, a slide 27 and a slide-out assembly. Two guide boxes 28 are fixedly connected in the box 26, and two guide rails 29 are fixedly connected on the slide 27. The two guide rails 29 are respectively slidably arranged in the two guide boxes 28. The box 26 is set on the washing machine 1, and an operation port is opened on the box 26. The slide 27 is slidably arranged in the box 26. Both the first and second embodiments are arranged in the slide 27, and the slide-out assembly is arranged in the box 26 for driving the slide. 27 moves out of the box body 26, and the sliding-out assembly includes a toothed belt 30, a moving frame 31, a moving gear 32, and a first motor 33. Two slide rods 34 are fixedly connected to the box body 26, and two slide holes are provided on the moving frame 31. The two slide rods 34 are slidably set in the two slide holes, and two toothed belts 30 are provided. The two toothed belts 30 are respectively fixedly connected to the slide 27 and the box body 26, and the moving frame 31 is slidably set in the box body 26. The moving gear 32 is rotatably connected to the moving frame 31, and the moving gear 32 is engaged with the two toothed belts 30. The first motor 33 is provided on the moving frame 31, and the output end of the first motor 33 passes through the moving frame 31 and is fixedly connected to the moving gear 32.

[0063] When the third embodiment of the present invention is in use, the first motor 33 provided on the movable frame 31 drives the movable gear 32 to rotate on the two toothed belts 30, which in turn drives the movable frame 31 to move in the box body 26, thereby driving the slide 27 and the equipment installed on the slide 27 to slide out of the box body 26, thereby facilitating maintenance of the equipment.

[0064] The above are only preferred embodiments of the present invention and are not intended to limit the present invention. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention should be included in the scope of protection of the present invention.

Claims

1. An environmentally friendly ozone generator for a washing machine, applied to a washing machine (1), characterized in that: include: The water inlet valve (15), the electrolysis module (16), the circulating water solenoid valve (17), the gas-liquid mixing pump (35), the degrader solenoid valve (18), the degradation device (19), the drying equipment (20), the drainage pump (21), the drainage pipe (22) and the control mechanism, the input end of the electrolysis module (16) is connected to the water inlet valve (15), the output end of the electrolysis module (16) is connected to the washing machine (1), the output end of the circulating water solenoid valve (17) is connected to the electrolysis module (16), the output end of the gas-liquid mixing pump (35) is connected to the circulating water solenoid valve (17), and the output end of the gas-liquid mixing pump (35) is connected to the circulating water solenoid valve (17). The output end is connected to the washing machine (1), the output end of the gas-liquid mixing pump (35) is connected to the input end of the degrader electromagnetic valve (18), the input end of the degradation device (19) is connected to the output end of the degrader electromagnetic valve (18), the drying device (20) is provided on the washing machine (1), the drainage pump (21) is provided on the washing machine (1), the input end of the drainage pump (21) is connected to the washing machine (1), and the drainage pipe (22) is connected to the output end of the drainage pump (21); further comprising: a box (26), a slide (27) and a slide-out assembly, wherein two guide boxes (28) are fixedly connected in the box (26), the slide (27) ) is fixedly connected to two guide rails (29), and the two guide rails (29) are respectively slidably arranged in two guide boxes (28). The box (26) is arranged on the washing machine (1), and an operation port is opened on the box (26). The slide (27) is slidably arranged in the box (26). The three-oxygen generating device for the environmentally friendly washing machine is arranged in the slide (27). The slide-out assembly is arranged in the box (26) and is used to drive the slide (27) to move out of the box (26). The slide-out assembly includes a toothed belt (30), a moving frame (31), a moving gear (32), and a first motor (33). The box (26) is fixedly connected to two A slide rod (34) is provided on the movable frame (31), and two slide holes are provided on the movable frame (31). The two slide rods (34) are respectively slidably arranged in the two slide holes. Two toothed belts (30) are provided. The two toothed belts (30) are respectively fixedly connected to the slide rod (27) and the box body (26). The movable frame (31) is slidably arranged in the box body (26). The movable gear (32) is rotatably connected to the movable frame (31). The movable gear (32) is engaged with the two toothed belts (30). The first motor (33) is provided on the movable frame (31). The output end of the first motor (33) passes through the movable frame (31) and is fixedly connected to the movable gear (32).

2. An environmentally friendly washing machine, characterized in that: The environmentally friendly washing machine (1) uses the ozone generator for the environmentally friendly washing machine according to claim 1.

Citation Information

Patent Citations

  • Detergent and disinfectant-free ozone washing machine

    CN117144637A