Composite solid electrolyte, preparation method thereof, and all-solid-state battery comprising composite solid electrolyte

By forming a composite solid electrolyte with a polymer coating on the sulfide-based solid electrolyte particles, the problem of high reactivity of the sulfide-based solid electrolyte to moisture is solved, the atmospheric stability and chemical resistance are significantly improved, the generation of harmful gases is reduced, and the safety and performance of the battery are ensured.

CN119654730APending Publication Date: 2025-03-18LG CHEM LTD
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Patent Information

Application Number
CN202380060095.3
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Priority Date
2022-08-30
Filing Date
2023-08-24
Publication Date
2025-03-18

AI Technical Summary

Technical Problem

The sulfide-based solid electrolyte is highly reactive to moisture, which leads to reaction with moisture in the air and moisture under low humidity conditions, producing harmful gas hydrogen sulfide, affecting safety and performance.

Method used

Using a composite solid electrolyte containing a polymer coating on sulfide-based solid electrolyte particles, the polymer coating contains repeating units represented by chemical formula I, and the coating is formed by heat treatment to improve atmospheric stability and chemical resistance.

Benefits of technology

It significantly improves the atmospheric stability and chemical resistance of the composite solid electrolyte, reduces the amount of hydrogen sulfide produced, ensures the safety of the process and improves the performance of the battery.

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Abstract

The present invention addresses the problem of improving the atmospheric stability of a conventional sulfide-based solid electrolyte, and relates to a composite solid electrolyte, a method for manufacturing the same, and an all-solid-state battery comprising the same. The composite solid electrolyte includes: sulfide-based solid electrolyte particles; and a polymer coating layer formed on the sulfide-based solid electrolyte particles, wherein a polymer in the polymer coating layer contains a repeating unit represented by chemical formula (I) described herein.
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