Powerful styling hair spray composition as well as preparation method and application thereof
By introducing nano-alumina sol and polysiloxane-modified cationic cellulose into the hair spray, the problem of shaping failure, white chip residue and insufficient flexibility of traditional hair spray in high temperature and high humidity environments is solved, and the effect of high-strength setting and natural flexibility is achieved.
Patent Information
- Application Number
- CN202510496522.3
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2025-04-21
- Publication Date
- 2025-07-11
AI Technical Summary
Traditional powerful hairspray has problems such as insufficient shaping effect in high temperature and high humidity environments, insufficient flexibility, and residual white shavings, which are difficult to meet consumers' comprehensive needs for high-strength shaping, natural texture and safety.
Polyurethane acrylate is used as the film forming agent, combined with the formulation design of nano-alumina sol, polysiloxane-modified cationic cellulose, reinforcement stable dispersion and natural polysaccharide modifier, and through controlling the stirring, dropping and ultrasonic treatment, a uniform and stable film forming network is formed, which enhances the shaping efficiency and flexibility and reduces white chip residues.
The finalization and maintenance time is extended to more than 8 hours in high temperature and high humidity environments, the tensile strength of the hair bundle is improved, the white shavings are retained, and the flexibility and natural texture of the hair are significantly improved, meeting consumers' needs for efficient and safe hair spray.
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Abstract
Description
Technical Field
[0001] The present invention relates to the technical field of daily chemical products, and particularly relates to a strong styling hairspray composition, a preparation method thereof, and an application thereof. Background Art
[0002] As a common hair styling product, hairspray is widely used in daily life for shaping and fixing hairstyles. Its main function is to form a uniform thin film on the hair surface through a film-forming substance, thereby achieving hair styling, smoothness, and gloss. With the continuous improvement of consumers' requirements for hairstyle durability and natural texture, the market demand for strong styling hairspray continues to grow. Traditional strong styling hairspray usually uses acrylate copolymers and vinyl pyrrolidone polymers as the main film-forming agents, and forms a rigid thin film on the hair surface through solvent evaporation to achieve styling. However, there are many deficiencies in the prior art in terms of formulation design and preparation process, and it is difficult to simultaneously meet the comprehensive requirements of high-strength styling, hair softness, environmental adaptability, and safety.
[0003] Short lasting styling time: Traditional hairspray compositions usually use polyurethane acrylate as the main film-forming substance, but the film-forming performance of a single component is limited, and it is easy to soften or break the film layer in a humid and hot environment, resulting in a rapid attenuation of the styling effect. Especially under high temperature and high humidity conditions, the lasting time of the hairspray is significantly shortened, and it cannot meet the needs of consumers for long-term styling.
[0004] Lack of softness: Traditional hairspray relies on film-forming agents with high glass transition temperatures to obtain strong styling effects, but the films formed by such components have poor flexibility, which easily causes the hair to be stiff, lack natural luster, and the film layer is prone to brittle fracture in a low-temperature environment, resulting in a decline in the anti-extrusion performance of the hairstyle. At the same time, the binding force between ordinary cationic conditioners and hair strands is insufficient, the hairspray is easy to fall off, and the styling effect is significantly attenuated after multiple combs.
[0005] White flake residue problem: Some hairspray products will leave white flakes on the hair after use. The main reason is that the film-forming substance precipitates unevenly under humid and hot conditions, forming tiny inorganic particles or unreacted solid substances. This not only affects the appearance but also may pose a potential threat to scalp health. Summary of the Invention
[0006] In view of this, the present invention provides a strong styling hairspray composition, a preparation method thereof, and an application thereof to solve the above problems.
[0007] The technical solution of the present invention is realized as follows: A strong styling hairspray composition: It contains components in the following mass percentages: 15-22% of polyurethane acrylate, 5-12% of nano-aluminum oxide sol, 3-7% of polysiloxane-modified cationic cellulose, 4-8% of enhancer stable dispersion liquid, 2-5% of natural polysaccharide modifier, 18-20% of solvent, and the balance is deionized water; the particle size of the nano-aluminum oxide sol is 10-30 nm, and the alumina content in the sol is 8-15 wt%.
[0008] Further, the polysiloxane-modified cationic cellulose is prepared by mixing hydroxyethyl cellulose with a sodium hydroxide solution with a mass concentration of 5-8% at a mass ratio of 1:8-10, swelling for 20-40 min, adding 3-aminopropyltriethoxysilane (KH550), controlling the amount of silane used so that the final product has a silicon content of 5-10%, reacting in a water bath at 50-70 °C for 3-5 hours, and after the reaction is completed, precipitating and purifying with ethanol and drying in vacuum for standby.
[0009] Further, the enhancer stable dispersion liquid is prepared by mixing hydroxyapatite nanowires and graphene oxide sheets at a mass ratio of 3-5:1, ultrasonically dispersing them in ethanol with a volume 1-3 times that of the mixture, with an ultrasonic power of 200-400 W and a time of 30-60 min to form a uniform dispersion liquid. The diameter of the hydroxyapatite nanowires is 5-20 nm, the aspect ratio is ≥50, and the number of layers of the graphene oxide sheets is ≤5.
[0010] Further, the natural polysaccharide modifier is prepared by dissolving xanthan gum in deionized water to form a 3-5 wt% solution, adding acrylate, purging with nitrogen to remove oxygen, reacting at 60-80 °C for 2-4 hours, controlling the grafting rate at 40-60%, centrifuging at high speed to remove unreacted monomers, and freeze-drying to obtain the modified product.
[0011] Further, the solvent is a mixture of polyglycerol-6 distearate and propylene glycol methyl ether acetate with a mass-to-volume ratio of g / mL of 3-5:10.
[0012] Further, a preparation method of a strong styling hairspray composition includes the following steps:
[0013] S1. Heat and stir the solvent at 40-60 °C until transparent, add polyurethane acrylate, control the stirring speed at 300-500 rpm, continue for 15-20 min, and slowly drop the nano-aluminum oxide sol under nitrogen protection while stirring to form a premixed liquid;
[0014] S2. Sequentially add polysiloxane-modified cationic cellulose and natural polysaccharide modifier to the premixed liquid, stir at 40-50 °C at 200-300 rpm for 20-30 min to ensure uniform dispersion, continue to add the enhancer stable dispersion liquid, and perform ultrasonic treatment for 10-15 minutes to prevent the settlement of nano materials;
[0015] S3. Slowly add deionized water to make the total system volume reach 100%, perform homogenization treatment, adjust the pH to 5.5 - 6.5 at room temperature after cooling, and sterilize and subpackage through a 0.20 - 0.30 μm filter membrane.
[0016] Furthermore, in step S1, the dropping rate is 1 - 2 mL / min, the stirring speed is 100 - 300 rpm, and the stirring is carried out for 8 - 15 min.
[0017] Furthermore, in step S2, the ultrasonic power is 200 - 400 W, and the ultrasonic frequency is 30 - 50 kHz.
[0018] Furthermore, in step S3, the homogenization pressure is 60 - 80 MPa, the feeding temperature is 35 - 40 °C, the discharging temperature is ≤ 45 °C, and it is circulated 3 - 5 times, with each time being 2 - 8 min.
[0019] Furthermore, the strong - setting hairspray composition is used for hairstyle setting in high - temperature and high - humidity environments, the setting duration is ≥ 8 hours, and the hair bundle tensile strength is ≥ 12 N / cm 2 。
[0020] Compared with the prior art, the beneficial effects of the present invention are as follows:
[0021] The present invention provides a hairspray composition with high - strength setting, natural and smooth texture, excellent environmental adaptability and safety through formula design and optimized preparation process, significantly improving the comprehensive performance of the hairspray, and solving the pain points of traditional hairsprays such as setting failure in humid and hot environments, white dandruff residue, and stiff hair.
[0022] Among them, polyurethane acrylate is used as the core film - forming agent, and nano - alumina sol is introduced to enhance the hardness and toughness of the film, effectively extending the setting duration. Polysiloxane - modified cationic cellulose and polyurethane acrylate jointly form a flexible film - forming network, improving the elasticity and anti - fracture performance of the hairspray, reducing the hair friction coefficient, and preventing frizzy hair. The enhanced properties of hydroxyapatite nanowires and graphene oxide sheets in the stabilizer dispersion liquid can be evenly dispersed, intertwined and synergistically interact with other components. The natural polysaccharide modifier obtained by grafting acrylate onto xanthan gum can form a hydrophilic and smooth protective film on the hair surface, significantly improving the hair smoothness, reducing the friction between hair strands, and making the hair maintain a natural hanging texture and smooth touch after setting.
[0023] In the preparation method, temperature control and stirring are carried out to fully dissolve the solvent and polyurethane acrylate to form a homogeneous system. Under nitrogen protection, nano-aluminum oxide sol is slowly added dropwise and stirring is continuously carried out to prevent agglomeration of nanoparticles, so as to achieve uniform dispersion of nano-components and release of enhanced efficacy. At an appropriate temperature and through a reasonable stirring speed, modified cellulose and natural polysaccharides are uniformly dispersed. After adding an enhancer, ultrasonic treatment is carried out to strengthen the dispersion of nano-materials, avoid sedimentation, and ensure the uniform and stable performance of the product. High-pressure homogenization treatment realizes deep mixing of components, precisely controls pressure, temperature and circulation parameters to form a stable colloid, adjusts the pH and sterilizes and sub-packages through a filter membrane to ensure the stable storage of the product and meet safety standards. The formula of the present invention has excellent practical value and promotion prospects, and can meet the needs of consumers for high-efficiency, safe and environmentally friendly hairspray products. Specific Embodiments
[0024] To better understand the technical content of the present invention, specific embodiments are provided below to further illustrate the present invention.
[0025] Unless otherwise specified, the experimental methods used in the embodiments of the present invention are all conventional methods.
[0026] Unless otherwise specified, the materials, reagents, etc. used in the embodiments of the present invention can all be obtained from commercial channels.
[0027] Example 1
[0028] The component ratio of the hairspray composition: 15% of polyurethane acrylate, 12% of nano-aluminum oxide sol, 3% of polysiloxane-modified cationic cellulose, 8% of enhancer stable dispersion liquid, 5% of natural polysaccharide modifier, 18% of solvent, and the balance of deionized water;
[0029] The particle size of the nano-aluminum oxide sol is 10 nm, and the alumina content in the sol is 8 wt%;
[0030] The polysiloxane-modified cationic cellulose is prepared by mixing hydroxyethyl cellulose and a sodium hydroxide solution with a mass concentration of 5% in a mass ratio of 1:8, swelling for 20 min, adding 3-aminopropyltriethoxysilane (KH550), controlling the amount of silane used so that the final product has a silicon content of 5%, reacting in a water bath at 50 °C for 3 hours, and after the reaction, precipitating and purifying with ethanol and drying in vacuum for standby;
[0031] The enhancer stable dispersion liquid is prepared by mixing hydroxyapatite nanowires and graphene oxide sheets in a mass ratio of 3-5:1, ultrasonically dispersing in ethanol with a volume 1 time that of the mixture, with an ultrasonic power of 200 W and a time of 30 min to form a uniform dispersion liquid. The diameter of the hydroxyapatite nanowires is 5 nm, the aspect ratio is ≥50, and the number of layers of the graphene oxide sheets is ≤5;
[0032] The natural polysaccharide modifier is prepared by dissolving xanthan gum in deionized water to form a 3 wt% solution, adding acrylate, purging with nitrogen to remove oxygen, reacting at 60 °C for 2 hours, controlling the grafting rate at 40%, removing unreacted monomers by ultracentrifugation, and freeze-drying to obtain the modified product;
[0033] The solvent is polyglycerol-6 distearate and propylene glycol methyl ether acetate with a mass-to-volume ratio of g / mL of 3:10.
[0034] Example 2
[0035] The composition ratio of the hairspray composition: 22% polyurethane acrylate, 5% nano-alumina sol, 7% polysiloxane-modified cationic cellulose, 4% enhancer stable dispersion, 2% natural polysaccharide modifier, 20% solvent, and the balance deionized water;
[0036] The particle size of the nano-alumina sol is 30 nm, and the alumina content in the sol is 15 wt%.
[0037] The polysiloxane-modified cationic cellulose is prepared by mixing hydroxyethyl cellulose with an 8% sodium hydroxide solution in a mass ratio of 1:10, swelling for 40 min, adding 3-aminopropyltriethoxysilane (KH550), controlling the amount of silane used so that the final product has a silicon content of 10%, reacting in a 70 °C water bath for 5 hours, precipitating and purifying with ethanol after the reaction, and drying in vacuo for standby;
[0038] The enhancer stable dispersion is prepared by mixing hydroxyapatite nanowires and graphene oxide sheets in a mass ratio of 5:1, ultrasonically dispersing in ethanol with a volume three times that of the mixture, with an ultrasonic power of 400 W and a time of 60 min to form a uniform dispersion. The diameter of the hydroxyapatite nanowires is 20 nm, the aspect ratio is ≥50, and the number of layers of the graphene oxide sheets is ≤5;
[0039] The natural polysaccharide modifier is prepared by dissolving xanthan gum in deionized water to form a 5 wt% solution, adding acrylate, purging with nitrogen to remove oxygen, reacting at 80 °C for 4 hours, controlling the grafting rate at 60%, removing unreacted monomers by ultracentrifugation, and freeze-drying to obtain the modified product;
[0040] The solvent is polyglycerol-6 distearate and propylene glycol methyl ether acetate with a mass-to-volume ratio of g / mL of 5:10.
[0041] Example 3
[0042] The composition ratio of the hairspray composition: 18% polyurethane acrylate, 8% nano-alumina sol, 5% polysiloxane-modified cationic cellulose, 6% enhancer stable dispersion, 3% natural polysaccharide modifier, 19% solvent, and the balance deionized water.
[0043] The particle size of the nano-alumina sol is 20 nm, and the alumina content in the sol is 12 wt%.
[0044] The polysiloxane-modified cationic cellulose is prepared by mixing hydroxyethyl cellulose and a sodium hydroxide solution with a mass concentration of 7% in a mass ratio of 1:9, swelling for 30 min, adding 3-aminopropyltriethoxysilane (KH550), controlling the amount of silane used so that the silicon content of the final product reaches 8%, reacting in a water bath at 60 °C for 4 hours, precipitating and purifying with ethanol after the reaction, and drying under vacuum for standby;
[0045] The enhancer stable dispersion is prepared by mixing hydroxyapatite nanowires and graphene oxide sheets in a mass ratio of 4:1, ultrasonically dispersing in ethanol with a volume twice that of the mixture, with an ultrasonic power of 300 W and a time of 5 min to form a uniform dispersion. The diameter of the hydroxyapatite nanowires is 15 nm, the aspect ratio is ≥50, and the number of layers of the graphene oxide sheets is ≤5;
[0046] The natural polysaccharide modifier is prepared by dissolving xanthan gum in deionized water to form a 4 wt% solution, adding acrylate, purging with nitrogen to remove oxygen, reacting at 70 °C for 3 hours, controlling the grafting rate at 50%, removing unreacted monomers by ultracentrifugation, and freeze-drying to obtain the modified product;
[0047] The solvent is polyglycerol-6 distearate and propylene glycol methyl ether acetate with a mass-to-volume ratio of g / mL of 4:10;
[0048] The above Examples 1-3 adopt the following preparation method:
[0049] S1. Heat and stir the solvent at 50 °C until transparent, add polyurethane acrylate, control the stirring speed at 400 rpm, continue for 18 min, slowly dropwise add nano-alumina sol under nitrogen protection at a dropping speed of 1 mL / min, stir while adding, with a stirring speed of 200 rpm, and stir for 12 min to form a premixed liquid;
[0050] S2. Sequentially add polysiloxane-modified cationic cellulose and natural polysaccharide modifier to the premixed liquid, stir at 250 rpm at 45 °C for 25 min to ensure uniform dispersion, continue to add the enhancer stable dispersion, perform ultrasonic treatment for 12 minutes, with an ultrasonic power of 300 W and an ultrasonic frequency of 40 kHz to prevent sedimentation of nano materials;
[0051] S3. Slowly supplement deionized water to make the total amount of the system 100%, perform homogenization treatment, with a homogenization pressure of 70 MPa, a feeding temperature of 38 °C, and a discharging temperature ≤45 °C, circulate 4 times, 5 min each time, adjust the pH to 6.0 at room temperature after cooling, and sterilize and package through a 0.25 μm filter membrane.
[0052] Comparative Example 1
[0053] The difference between this comparative example and Example 3 is that the hairspray composition does not add nano-alumina sol.
[0054] Ratio of components in the hairspray composition: 18% of polyurethane acrylate, 5% of polysiloxane-modified cationic cellulose, 6% of enhancer stable dispersion liquid, 3% of natural polysaccharide modifier, 19% of solvent, and the balance is deionized water.
[0055] The preparation method includes:
[0056] S1. Heat and stir the solvent at 50 °C until transparent, add polyurethane acrylate, control the stirring speed at 400 rpm, and continue for 18 min to form a premixed liquid.
[0057] S2. Sequentially add polysiloxane-modified cationic cellulose and natural polysaccharide modifier to the premixed liquid, stir at 250 rpm at 45 °C for 25 min to ensure uniform dispersion, then continue to add the enhancer stable dispersion liquid, perform ultrasonic treatment for 12 minutes, with an ultrasonic power of 300 W and an ultrasonic frequency of 40 kHz to prevent the settlement of nanomaterials.
[0058] S3. Slowly supplement deionized water to make the total system amount reach 100%, perform homogenization treatment, with a homogenization pressure of 70 MPa, a feed temperature of 38 °C, and a discharge temperature ≤ 45 °C, circulate 4 times, 5 min each time, adjust the pH to 6.0 at room temperature after cooling, and sterilize and package through a 0.25 μm filter membrane.
[0059] Comparative Example 2
[0060] The difference between this comparative example and Example 3 is that polysiloxane-modified cationic cellulose is not added to the hairspray composition.
[0061] Ratio of components in the hairspray composition: 18% of polyurethane acrylate, 8% of nano-aluminum oxide sol, 6% of enhancer stable dispersion liquid, 3% of natural polysaccharide modifier, 19% of solvent, and the balance is deionized water.
[0062] The preparation method includes
[0063] S1. Heat and stir the solvent at 50 °C until transparent, add polyurethane acrylate, control the stirring speed at 400 rpm, and continue for 18 min. Slowly drop the nano-aluminum oxide sol under nitrogen protection at a dropping speed of 1 mL / min, stir while adding, with a stirring speed of 200 rpm, and stir for 12 min to form a premixed liquid.
[0064] S2. Add the natural polysaccharide modifier to the premixed liquid, stir at 250 rpm at 45 °C for 25 min to ensure uniform dispersion, then continue to add the enhancer stable dispersion liquid, perform ultrasonic treatment for 12 minutes, with an ultrasonic power of 300 W and an ultrasonic frequency of 40 kHz to prevent the settlement of nanomaterials.
[0065] S3. Slowly add deionized water to make the total system volume reach 100%, perform homogenization treatment, with a homogenization pressure of 70 MPa, a feed temperature of 38 °C, and an outlet temperature ≤ 45 °C. Circulate 4 times, 5 minutes each time. After cooling, adjust the pH to 6.0 at room temperature, and sterilize and package through a 0.25 μm filter membrane.
[0066] Comparative Example 3
[0067] The difference between this comparative example and Example 3 is that the hairspray composition does not add an enhanced stabilizer dispersion liquid.
[0068] The component ratio of the hairspray composition: 18% polyurethane acrylate, 8% nano-aluminum oxide sol, 5% polysiloxane-modified cationic cellulose, 3% natural polysaccharide modifier, 19% solvent, and the balance is deionized water.
[0069] The preparation method includes:
[0070] S1. Heat and stir the solvent at 50 °C until transparent, add polyurethane acrylate, control the stirring speed at 400 rpm, continue for 18 minutes, slowly dropwise add nano-aluminum oxide sol under nitrogen protection at a dropping speed of 1 mL / min, stir while adding, with a stirring speed of 200 rpm, and stir for 12 minutes to form a premixed solution;
[0071] S2. Sequentially add polysiloxane-modified cationic cellulose and natural polysaccharide modifier to the premixed solution, stir at 250 rpm at 45 °C for 25 minutes to ensure uniform dispersion, continue to add an enhancer stable dispersion liquid, perform ultrasonic treatment for 12 minutes, with an ultrasonic power of 300 W and an ultrasonic frequency of 40 kHz to prevent the settlement of nano materials;
[0072] S3. Slowly add deionized water to make the total system volume reach 100%, perform homogenization treatment, with a homogenization pressure of 70 MPa, a feed temperature of 38 °C, and an outlet temperature ≤ 45 °C. Circulate 4 times, 5 minutes each time. After cooling, adjust the pH to 6.0 at room temperature, and sterilize and package through a 0.25 μm filter membrane.
[0073] Comparative Example 4
[0074] The difference between this comparative example and Example 3 is that the solvent is replaced with an equal amount of ethanol.
[0075] Comparative Example 5
[0076] The difference between this comparative example and Example 3 is that the hairspray composition does not add a natural polysaccharide modifier.
[0077] I. Physical and chemical property effect tests
[0078] (1) Tensile strength of hair bundle: Using an electronic universal testing machine, fix the hair bundle (10 hairs) on the fixture, apply hairspray and dry. Stretch it at a speed of 100 mm / min until it breaks, record the maximum tensile force value, and calculate the tensile strength (unit: N / mm 2 )
[0079] (2) Binding force with hair strands: Using the tape peeling method: Apply hairspray on the surface of the hair bundle, after drying, attach a standard tape, and quickly peel it at a 90° angle, record the force value during the peeling process (unit: N). Repeat 5 times and take the average value.
[0080] (3) Surface friction coefficient test: Using a friction tester, apply hairspray on the surface of the hair strands, and measure the sliding friction coefficient between the hair strands and other materials (glass plate). The test speed is 10 mm / s, the load is 100 g, repeat 5 times and take the average value.
[0081] Test results:
[0082] Table 1:
[0083]
[0084]
[0085] II. Styling effect test
[0086] (1) Styling duration: Adopt the three-point bending test or tensile test to measure the anti-deformation ability of the hair strands after styling. If the hair bending degree changes by more than 30% and the looseness of the hair bundle increases by more than 50%, it is regarded as the styling failure, and record the time at this moment as the styling duration.
[0087] (2) Softness test: Comb the styled hair bundle from the root to the tip with a standard comb, record the hair breakage situation and combing resistance, and score according to 1 - 5 points (5 points is the smoothest).
[0088] Test results:
[0089] Table 2:
[0090] Setting retention time (h) Softness (combing score, 1 - 5 points) Example 1 8.1 4.8 Example 2 8.2 4.7 Example 3 8.5 5.0 Comparative Example 1 6.2 3.8 Comparative Example 2 7.0 2.5 Comparative Example 3 5.5 3.5 Comparative Example 4 6.8 3.6 Comparative Example 5 6.2 3.1
[0091] III. Stability test
[0092] (1) Humid heat styling retention rate: Place the styled hair bundle in an environment of 40°C and RH85% for 2 hours, then measure the deformation degree of the hair bundle and calculate the styling retention rate;
[0093] Humid heat styling retention rate (%) = (Length after styling - Length after deformation) / Length after styling × 100%.
[0094] (2) White residue test: Observe whether there is white residue on the hair surface under the simulated humid and hot environment (40 °C / 85% RH).
[0095] Test results:
[0096] Table 3:
[0097] Moist heat setting retention rate White flake residue Example 1 95.1％ No white flake residue Example 2 95.2％ No white flake residue Example 3 95.5％ No white flake residue Comparative Example 1 71.5％ Significant increase in white flake residue Comparative Example 2 66.2％ Highest white flake residue Comparative Example 3 82.3％ Higher white flake residue Comparative Example 4 58.9％ Higher white flake residue Comparative Example 5 68.5％ Higher white flake residue
[0098] The results in the above Tables 1 - 3 show that the nano-aluminum oxide sol, polysiloxane-modified cationic cellulose, enhancer stable dispersion, and natural polysaccharide modifier in the formulation of the present invention have significant synergistic effects, improving the uniformity and stability of film formation. The introduction of nano-aluminum oxide sol acts synergistically with polyurethane acrylate to enhance the setting strength through the hard segment benzene ring structure, and the soft segment polyethylene glycol chain segment improves the flexibility. The enhanced stabilizer dispersion can be evenly dispersed, improving the lubricity and flexibility of the hairspray. The polysiloxane-modified cellulose reduces the combing resistance and improves the flexibility through cation adsorption and siloxane lubrication. The natural polysaccharide modifier adjusts the rheological properties to achieve a balance between strength and flexibility. The polysiloxane-modified cationic cellulose reduces the friction damage and white residue generation on the hair surface through lubrication and film formation.
[0099] The above are only the preferred embodiments of the present invention and are not intended to limit the present invention. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principle of the present invention shall be included in the protection scope of the present invention.
Claims
1. A strong styling hairspray composition, characterized in that: Components containing the following mass percentages: 15-22% of polyurethane acrylate, 5-12% of nano-aluminum oxide sol, 3-7% of polysiloxane-modified cationic cellulose, 4-8% of enhancer stable dispersion liquid, 2-5% of natural polysaccharide modifier, 18-20% of solvent, and the balance being deionized water; the particle size of the nano-aluminum oxide sol is 10-30 nm, and the alumina content in the sol is 8-15 wt%.
2. The strong styling hairspray composition according to claim 1, characterized in that: The polysiloxane-modified cationic cellulose is prepared by mixing hydroxyethyl cellulose with a sodium hydroxide solution with a mass concentration of 5-8% in a mass ratio of 1:8-10, swelling for 20-40 min, adding 3-aminopropyltriethoxysilane, controlling the amount of silane used so that the final product has a silicon content of 5-10%, reacting in a water bath at 50-70 °C for 3-5 hours, and after the reaction, precipitating and purifying with ethanol and drying in vacuum for standby.
3. The strong styling hairspray composition according to claim 1, wherein: The enhancer stable dispersion liquid is prepared by mixing hydroxyapatite nanowires and graphene oxide sheets in a mass ratio of 3-5:1, ultrasonically dispersing in ethanol with a volume 1-3 times that of the mixture, with an ultrasonic power of 200-400 W and a time of 30-60 min to form a uniform dispersion liquid. The diameter of the hydroxyapatite nanowires is 5-20 nm, the aspect ratio is ≥50, and the number of layers of the graphene oxide sheets is ≤5.
4. The strong styling hairspray composition according to claim 1, characterized in that: The natural polysaccharide modifier is prepared by dissolving xanthan gum in deionized water to form a 3-5 wt% solution, adding acrylate, purging with nitrogen to remove oxygen, reacting at 60-80 °C for 2-4 hours, controlling the grafting rate at 40-60%, centrifuging at high speed to remove unreacted monomers, and freeze-drying to obtain the modified product.
5. The strong setting hairspray composition according to claim 1, characterized in that: The solvent is polyglycerol-6 distearate and propylene glycol methyl ether acetate with a mass-volume ratio of g / mL of 3-5:
10.
6. The preparation method of a strong styling hairspray composition as described in claim 1, characterized in that: Including the following steps: S1. Heat and stir the solvent at 40-60 °C until transparent, add polyurethane acrylate, control the stirring speed at 300-500 rpm, continue for 15-20 min, and slowly dropwise add the nano-aluminum oxide sol under nitrogen protection while stirring to form a premixed liquid. S2. Sequentially add polysiloxane-modified cationic cellulose and natural polysaccharide modifier to the premixed liquid, stir at 200-300 rpm at 40-50 °C for 20-30 min, continue to add the enhancer stable dispersion liquid, and perform ultrasonic treatment for 10-15 minutes. S3. Slowly supplement deionized water to make the total amount of the system 100%, perform homogenization treatment, adjust the pH to 5.5-6.5 at room temperature after cooling, and sterilize and subpackage through a 0.20-0.30 μm filter membrane.
7. The preparation method of a strong styling hairspray composition according to claim 6, characterized in that: In step S1, the dropping speed is 1-2 mL / min, the stirring speed is 100-300 rpm, and the stirring is for 8-15 min.
8. The preparation method of a strong styling hairspray composition according to claim 6, characterized in that: In step S2, the ultrasonic power is 200-400 W, and the ultrasonic frequency is 30-50 kHz.
9. The preparation method of a strong styling hairspray composition according to claim 6, characterized in that: In step S3, the homogenization pressure is 60-80 MPa, the feeding temperature is 35-40 °C, the discharging temperature is ≤45 °C, and the cycle is 3-5 times, each time for 2-8 min.
10. Use of the composition according to any one of claims 1-5, characterized in that: For hair styling in high-temperature and high-humidity environments.