Environment-friendly stain-resistant antiskid preparation and preparation method thereof

Abstract

The invention relates to the technical field of anti-skid preparations, in particular to an environment-friendly stain-resistant anti-skid preparation and a preparation method thereof.The calcium carbonate is modified through sodium stearate, the adhesive force between the calcium carbonate and a base material can be improved, and meanwhile the surface roughness of a material is improved; the dispersity and the stability of the coating in water can be improved, and meanwhile, the binding force of the coating and a base material is enhanced; the modified titanium dioxide, the modified calcium carbonate and the modified fly ash are added into the base liquid component, so that the surface roughness of the material can be improved, and the anti-skid performance of the material is improved; the main components of the preparation, such as the polyurethane, the waterborne epoxy resin, the modified titanium dioxide, the modified calcium carbonate and the modified fly ash, are all environment-friendly materials and are environment-friendly, so that the pollution to the environment is reduced to a certain extent.

Description

Technical Field

[0001] The present invention relates to the technical field of anti-slip preparations, and particularly relates to an environment-friendly anti-fouling and anti-slip preparation and a preparation method thereof. Background Art

[0002] Although traditional concrete floors are suitable for a large number of floor projects in terms of hardness and anti-slip performance, in modern construction projects and interior decoration projects, due to the ugly appearance of concrete, easy mildew, and poor appearance caused by poor construction process control, it has gradually been replaced by smooth building materials such as marble, artificial stone, and terrazzo. However, when these smooth stone surfaces encounter water, a uniform water film will form on their surfaces, resulting in a decrease in the friction coefficient between the stone surface and the feet, making people very prone to slipping and falling.

[0003] Traditional anti-slip processes include anti-slip coatings, anti-slip mats, and making the surfaces of anti-slip tiles serrated or uneven. However, the applicability of anti-slip mats is not wide and they cannot be used in large-scale construction projects; applying an anti-slip agent on the surface of finished floor tiles can increase the friction coefficient by using the anti-slip agent attached to the brick surface, but the applied anti-slip layer will gradually be worn with the extension of the use time and the anti-slip performance will also disappear; treating floor tiles with a corrosive liquid can make the brick surface into a structure with uneven ups and downs, and use this structure and the suction cup effect generated by the sole under pressure to increase the friction coefficient and prevent slipping and falling, but the anti-slip agents on the market generally have poor penetration, and the uneven structure on the brick surface will become smooth again due to friction. Therefore, it is particularly important to develop a safe anti-slip preparation that can effectively increase the anti-slip coefficient of floor tiles. Summary of the Invention

[0004] The object of the present invention can be achieved by the following technical solutions:

[0005] An environment-friendly anti-fouling and anti-slip preparation, which is composed of the following components: a base liquid component, modified titanium dioxide, modified calcium carbonate, modified fly ash, a dispersant, an antifoaming agent, a curing agent, and deionized water;

[0006] The base liquid component is prepared by copolymerizing polyurethane and waterborne epoxy resin;

[0007] The modified titanium dioxide is prepared by modifying nano-titanium dioxide with a silane coupling agent KH-570;

[0008] The modified calcium carbonate is prepared by modifying calcium carbonate with sodium stearate;

[0009] The modified fly ash is prepared by modifying fly ash with ethylene glycol.

[0010] Furthermore, the preparation steps of the base liquid component are:

[0011] Step 1: Weigh 30 g of polytetrahydrofuran ether glycol and pour it into a flask. Dehydrate it under a vacuum pump at 100 °C for 30 min, then cool it down to 70 °C. Add 6.66 g of isophorone diisocyanate and heat it up to 90 °C, and react for 3 h. The obtained product is denoted as the polyurethane prepolymer component.

[0012] Step 2: Weigh 23 g of epoxy resin and melt it in an oven at 100 °C. Pour it into the flask, then reheat it to 70 °C. Add 8 g of dipropylene glycol dimethyl ether and dissolve it at 85 °C for 30 min. Then add 2.8 g of sodium 2-aminoethanesulfonate and heat it up to 66 °C and react for 1 h. The obtained product is denoted as the epoxy resin prepolymer component.

[0013] Step 3: Add the polyurethane prepolymer component to the epoxy resin prepolymer component and add 4 g of piperazine. React at 60 °C for 6 h, then cool down and discharge. Add 4 g of glacial acetic acid to neutralize for 10 min, and then pour it into an emulsifier together with 60 g of deionized water and emulsify at a rotation speed of 1200 r / min for 30 min. The obtained product is the base liquid component.

[0014] Furthermore, the preparation steps of the modified titanium dioxide are as follows:

[0015] Step 1: Add 2 g of silane coupling agent KH-570, 30 g of absolute ethanol, and 70 g of deionized water into a flask. After mixing evenly, adjust the pH value to 3 - 4, and then perform ultrasonic treatment at room temperature. The obtained product is denoted as the modifier component.

[0016] Step 2: Place the nano-titanium dioxide in an oven at 110 °C and dry it for 12 h. Then weigh 6 g and add it into the flask, and add 20 g of absolute ethanol. Disperse it by ultrasonic wave at a frequency of 28 kHz for 30 min. The obtained product is denoted as the component to be modified.

[0017] Step 3: Under the water bath condition of 78 °C, drop the modifier component into the component to be modified at a dropping speed of 1 drop / s. Adjust the pH value to 9 - 10, then perform mechanical stirring for reaction. After centrifugation, extract with acetone, and after drying treatment, grind it through a 200-mesh sieve. The obtained product is the modified titanium dioxide.

[0018] Furthermore, the specific operation of mixing evenly in Step 1 is to stir at a stirring speed of 500 r / min for 30 min. In Step 1, glacial acetic acid is used to adjust the pH value. The specific operation of ultrasonic treatment in Step 1 is to disperse by ultrasonic wave at a frequency of 26 kHz for 2 h.

[0019] Further, in Step 3, ammonia water is used to adjust the pH value. The specific operation of mechanical stirring in Step 3 is to stir at a stirring speed of 300 r / min for 5 h. The specific operation of centrifugation in Step 3 is to centrifuge at a rotation speed of 5000 r / min for 5 min. The specific operation of drying in Step 3 is to dry in an oven at 75 °C for 6 h.

[0020] Further, the preparation method of the modified calcium carbonate is as follows:

[0021] Mix 5 g of calcium carbonate and 50 g of deionized water, stir at a stirring speed of 300 r / min for 10 min, then add 2 g of sodium stearate, and continue to stir at the original stirring speed for 2 h for reaction. After the reaction is completed, centrifuge at a rotation speed of 5000 r / min for 5 min to obtain a precipitate. Extract the precipitate with acetone and then dry it in an oven at 68 °C for 6 h. What is obtained is the modified calcium carbonate.

[0022] Further, the preparation method of the modified fly ash is as follows:

[0023] Weigh 5 g of ethylene glycol, add it to 100 g of deionized water, stir at a stirring speed of 400 r / min for 10 min, then add 200 g of fly ash and stir at a stirring speed of 100 r / min for 10 min. Disperse at a stirring speed of 600 r / min for 40 min, then dry in a blast box at 40 °C for 24 h, and grind through a 200-mesh sieve. What is obtained is the modified fly ash.

[0024] Further, the dispersant is cetyltrimethylammonium bromide, the defoamer is polydimethylsiloxane, and the curing agent is an isocyanate curing agent.

[0025] A preparation method of an environment-friendly stain-resistant and non-slip preparation, and the preparation method is as follows:

[0026] S1. Weigh 8 - 10 parts by weight of deionized water, 0.2 - 0.3 parts by weight of dispersant, 8 - 9 parts by weight of modified titanium dioxide, 3 - 5 parts by weight of modified calcium carbonate, and 5 - 6 parts by weight of modified fly ash, pour them into a ball mill, add ball milling beads according to a ball-to-material ratio of 1:3, and then ball mill at a rotation speed of 300 r / min for 1 h. After passing through a 400-mesh sieve, what is obtained is denoted as the filler component;

[0027] S2. Weigh 50 - 55 parts by weight of the base liquid component and 0.3 - 0.4 parts by weight of defoamer, mix them, perform high-speed dispersion, then add the filler component in S1, continue to disperse, and then add 4 - 5 parts by weight of curing agent. What is obtained after uniform dispersion is the environment-friendly stain-resistant and non-slip preparation.

[0028] Further, in S2, the specific operation of high-speed dispersion is to stir at a stirring speed of 1200 r / min for 10 min, the specific operation of continuous dispersion is to stir at a stirring speed of 1000 r / min for 5 min, and the specific operation of uniform dispersion is to stir at a stirring speed of 500 r / min for 5 min.

[0029] Beneficial effects of the present invention:

[0030] 1. The polyurethane prepolymer component in the present invention is prepared by the reaction of polytetrahydrofuran glycol and isophorone diisocyanate, and has excellent elasticity and wear resistance. The epoxy resin prepolymer component is prepared by the reaction of epoxy resin with dipropylene glycol dimethyl ether and sodium 2-(2-aminoethylamino)ethanesulfonate, which can improve the water dispersibility and stability of waterborne epoxy resin. The polyurethane prepolymer component and the epoxy resin prepolymer component are used to prepare the base liquid component through the cross-linking reaction of piperazine, which can improve the stability and performance of the base liquid component, making the whole preparation more stable and reliable. Secondly, nano-titanium dioxide in the present invention reacts with silane coupling agent KH-570 under specific conditions. Through chemical bonding, the dispersibility and stability of titanium dioxide can be improved, and at the same time, its anti-fouling performance can be enhanced.

[0031] 2. Calcium carbonate in the present invention is modified by sodium stearate, which can improve its adhesion to the substrate and at the same time improve the surface roughness of the material. Fly ash is modified by ethylene glycol, which can improve its dispersibility and stability in water and at the same time enhance its binding force with the substrate. By adding modified titanium dioxide, modified calcium carbonate and modified fly ash to the base liquid component, the surface roughness of the material can be improved, thereby improving the anti-slip performance of the material. The main components of the preparation in the present invention, such as polyurethane, waterborne epoxy resin, modified titanium dioxide, modified calcium carbonate and modified fly ash, are all environmentally friendly materials, friendly to the environment, and reduce environmental pollution to a certain extent. Specific embodiments

[0032] Next, the technical solutions in the embodiments of the present invention will be clearly and completely described in conjunction with the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, rather than all the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts belong to the protection scope of the present invention.

[0033] Example 1

[0034] An environmentally friendly anti-fouling and anti-slip preparation in this example is composed of the following components: base liquid component, modified titanium dioxide, modified calcium carbonate, modified fly ash, dispersant, defoaming agent, curing agent and deionized water;

[0035] The base liquid component is prepared by copolymerizing and modifying polyurethane with waterborne epoxy resin. The preparation steps of the base liquid component are as follows:

[0036] Step 1: Weigh 30 g of polytetrahydrofuran ether glycol and pour it into a flask. After dehydrating under a vacuum pump at 100 °C for 30 min, cool it down to 70 °C, add 6.66 g of isophorone diisocyanate, and raise the temperature to 90 °C and react for 3 h. The obtained product is denoted as the polyurethane prepolymer component.

[0037] Step 2: Weigh 23 g of epoxy resin and melt it in an oven at 100 °C. Pour it into the flask, re-raise the temperature to 70 °C, add 8 g of dipropylene glycol dimethyl ether, dissolve it under the condition of 85 °C for 30 min, then add 2.8 g of sodium 2-aminoethanesulfonate and raise the temperature to 66 °C and react for 1 h. The obtained product is denoted as the epoxy resin prepolymer component.

[0038] Step 3: Add the polyurethane prepolymer component to the epoxy resin prepolymer component and add 4 g of piperazine. React under the condition of 60 °C for 6 h, then cool down and discharge. Add 4 g of glacial acetic acid to neutralize for 10 min, and then pour it into an emulsifier together with 60 g of deionized water and emulsify at a rotation speed of 1200 r / min for 30 min. The obtained product is the base liquid component.

[0039] The modified titanium dioxide is prepared by modifying nano-titanium dioxide with silane coupling agent KH-570. The preparation steps of the modified titanium dioxide are as follows:

[0040] Step 1: Add 2 g of silane coupling agent KH-570, 30 g of absolute ethanol, and 70 g of deionized water into a flask. Stir at a stirring speed of 500 r / min for 30 min, then use glacial acetic acid to adjust the pH value to 3, and ultrasonically disperse at a frequency of 26 kHz at room temperature for 2 h. The obtained product is denoted as the modifier component.

[0041] Step 2: Place the nano-titanium dioxide in an oven at 110 °C and dry it for 12 h. Then weigh 6 g and add it into the flask, add 20 g of absolute ethanol, and ultrasonically disperse at a frequency of 28 kHz for 30 min. The obtained product is denoted as the component to be modified.

[0042] Step 3: Under the water bath condition of 78 °C, drop the modifier component into the component to be modified at a dropping speed of 1 drop / s. Use ammonia water to adjust the pH value to 9, then stir at a stirring speed of 300 r / min for 5 h for reaction. Centrifuge at a rotation speed of 5000 r / min for 5 min, then extract with acetone, place it in an oven at 75 °C and dry for 6 h, and then grind it through a 200-mesh sieve. The obtained product is the modified titanium dioxide.

[0043] The modified calcium carbonate is prepared by modifying calcium carbonate with sodium stearate. The preparation method of the modified calcium carbonate is as follows:

[0044] Mix 5 g of calcium carbonate and 50 g of deionized water, stir at a stirring speed of 300 r / min for 10 min, then add 2 g of sodium stearate, and continue to stir at the original stirring speed for 2 h for reaction. After the reaction is completed, centrifuge at a speed of 5000 r / min for 5 min to obtain a precipitate. Extract the precipitate with acetone and then dry it in an oven at 68 °C for 6 h. The obtained product is the modified calcium carbonate.

[0045] The modified fly ash is prepared by modifying fly ash with ethylene glycol. The preparation method of the modified fly ash is as follows:

[0046] Weigh 5 g of ethylene glycol, add it to 100 g of deionized water, stir at a stirring speed of 400 r / min for 10 min, then add 200 g of fly ash and stir at a stirring speed of 100 r / min for 10 min. Disperse at a stirring speed of 600 r / min for 40 min, then dry it in a blast box at 40 °C for 24 h. After grinding through a 200-mesh sieve, the obtained product is the modified fly ash.

[0047] Among them, the dispersant is cetyltrimethylammonium bromide, the defoamer is polydimethylsiloxane, and the curing agent is isocyanate curing agent.

[0048] A preparation method of an environmentally friendly stain-resistant and anti-slip preparation. The preparation method is as follows:

[0049] S1. Weigh 8 parts by weight of deionized water, 0.2 parts by weight of dispersant, 8 parts by weight of modified titanium dioxide, 3 parts by weight of modified calcium carbonate, and 5 parts by weight of modified fly ash, pour them into a ball mill, add ball milling beads according to a material-to-ball ratio of 1:3, and ball mill at a speed of 300 r / min for 1 h. After passing through a 400-mesh sieve, the obtained product is recorded as the filler component;

[0050] S2. Weigh 50 parts by weight of the base liquid component and 0.3 parts by weight of defoamer and mix them. Stir at a stirring speed of 1200 r / min for 10 min, then add the filler component in S1, stir at a stirring speed of 1000 r / min for 5 min, then add 4 parts by weight of curing agent, and stir at a stirring speed of 500 r / min for 5 min. The obtained product is the environmentally friendly stain-resistant and anti-slip preparation.

[0051] Example 2

[0052] An environmentally friendly stain-resistant and anti-slip preparation in this example. The environmentally friendly stain-resistant and anti-slip preparation is composed of the following components: base liquid component, modified titanium dioxide, modified calcium carbonate, modified fly ash, dispersant, defoamer, curing agent, and deionized water;

[0053] The base liquid component is prepared by copolymerizing and modifying waterborne epoxy resin with polyurethane. The preparation steps of the base liquid component are as follows:

[0054] Step 1: Weigh 30 g of polytetrahydrofuran ether glycol and pour it into a flask. Dehydrate it under a vacuum pump at 100 °C for 30 min, then cool it down to 70 °C. Add 6.66 g of isophorone diisocyanate and heat it up to 90 °C and react for 3 h. The obtained product is denoted as the polyurethane prepolymer component;

[0055] Step 2: Weigh 23 g of epoxy resin and melt it in an oven at 100 °C. Pour it into the flask, reheat it to 70 °C, add 8 g of dipropylene glycol dimethyl ether and dissolve it under the condition of 85 °C for 30 min. Then add 2.8 g of sodium 2-aminoethanesulfonate and heat it up to 66 °C and react for 1 h. The obtained product is denoted as the epoxy resin prepolymer component;

[0056] Step 3: Add the polyurethane prepolymer component to the epoxy resin prepolymer component and add 4 g of piperazine. React under the condition of 60 °C for 6 h, then cool it down and discharge. Add 4 g of glacial acetic acid to neutralize for 10 min, then pour it into an emulsifier together with 60 g of deionized water and emulsify at a rotation speed of 1200 r / min for 30 min. The obtained product is the base liquid component.

[0057] The modified titanium dioxide is prepared by modifying nano-titanium dioxide with silane coupling agent KH-570. The preparation steps of the modified titanium dioxide are as follows:

[0058] Step 1: Add 2 g of silane coupling agent KH-570, 30 g of absolute ethanol and 70 g of deionized water into a flask. Stir at a stirring speed of 500 r / min for 30 min, then use glacial acetic acid to adjust the pH value to 4, and ultrasonically disperse at a frequency of 26 kHz at room temperature for 2 h. The obtained product is denoted as the modifier component;

[0059] Step 2: Place the nano-titanium dioxide in an oven at 110 °C and dry it for 12 h. Then weigh 6 g and add it into the flask and add 20 g of absolute ethanol. Ultrasonically disperse at a frequency of 28 kHz for 30 min. The obtained product is denoted as the component to be modified;

[0060] Step 3: Under the water bath condition of 78 °C, drop the modifier component into the component to be modified at a dropping speed of 1 drop / s. Use ammonia water to adjust the pH value to 10, then stir at a stirring speed of 300 r / min for 5 h for reaction. Centrifuge at a rotation speed of 5000 r / min for 5 min, then extract with acetone, place it in an oven at 75 °C and dry for 6 h, and then grind it through a 200-mesh sieve. The obtained product is the modified titanium dioxide.

[0061] The modified calcium carbonate is prepared by modifying calcium carbonate with sodium stearate. The preparation method of the modified calcium carbonate is as follows:

[0062] Mix 5 g of calcium carbonate and 50 g of deionized water, stir at a stirring speed of 300 r / min for 10 min, then add 2 g of sodium stearate, and continue to stir at the original stirring speed for 2 h for reaction. After the reaction is completed, centrifuge at a speed of 5000 r / min for 5 min to obtain a precipitate. Extract the precipitate with acetone and then dry it in an oven at 68 °C for 6 h. The obtained product is the modified calcium carbonate.

[0063] The modified fly ash is prepared by modifying fly ash with ethylene glycol. The preparation method of the modified fly ash is as follows:

[0064] Weigh 5 g of ethylene glycol, add it to 100 g of deionized water, stir at a stirring speed of 400 r / min for 10 min, then add 200 g of fly ash and stir at a stirring speed of 100 r / min for 10 min. Disperse at a stirring speed of 600 r / min for 40 min, then dry in a blast box at 40 °C for 24 h. After grinding through a 200-mesh sieve, the obtained product is the modified fly ash.

[0065] Among them, the dispersant is cetyltrimethylammonium bromide, the defoamer is polydimethylsiloxane, and the curing agent is isocyanate curing agent.

[0066] A preparation method of an environmentally friendly stain-resistant and non-slip preparation. The preparation method is as follows:

[0067] S1. Weigh 10 parts by weight of deionized water, 0.3 parts by weight of dispersant, 9 parts by weight of modified titanium dioxide, 5 parts by weight of modified calcium carbonate, and 6 parts by weight of modified fly ash, pour them into a ball mill, add ball milling beads according to a ball-to-material ratio of 1:3, and ball mill at a speed of 300 r / min for 1 h. After passing through a 400-mesh sieve, the obtained product is recorded as the filler component;

[0068] S2. Weigh 55 parts by weight of the base liquid component and 0.4 parts by weight of defoamer for mixing, stir at a stirring speed of 1200 r / min for 10 min, then add the filler component in S1, stir at a stirring speed of 1000 r / min for 5 min, then add 5 parts by weight of curing agent, and stir at a stirring speed of 500 r / min for 5 min. The obtained product is the environmentally friendly stain-resistant and non-slip preparation.

[0069] Example 3

[0070] An environmentally friendly stain-resistant and non-slip preparation of this example. The environmentally friendly stain-resistant and non-slip preparation consists of the following components: base liquid component, modified titanium dioxide, modified calcium carbonate, modified fly ash, dispersant, defoamer, curing agent, and deionized water;

[0071] The base liquid component is prepared by copolymerizing and modifying waterborne epoxy resin with polyurethane. The preparation steps of the base liquid component are as follows:

[0072] Step 1: Weigh 30 g of polytetrahydrofuran ether glycol and pour it into a flask. Dehydrate it under a vacuum pump at 100 °C for 30 min, then cool it down to 70 °C. Add 6.66 g of isophorone diisocyanate and heat it up to 90 °C and react for 3 h. The obtained product is denoted as the polyurethane prepolymer component;

[0073] Step 2: Weigh 23 g of epoxy resin and melt it in an oven at 100 °C. Pour it into the flask, then reheat it to 70 °C. Add 8 g of dipropylene glycol dimethyl ether and dissolve it under the condition of 85 °C for 30 min. Then add 2.8 g of sodium 2-aminoethanesulfonate and heat it up to 66 °C and react for 1 h. The obtained product is denoted as the epoxy resin prepolymer component;

[0074] Step 3: Add the polyurethane prepolymer component to the epoxy resin prepolymer component and add 4 g of piperazine. React under the condition of 60 °C for 6 h, then cool down and discharge. Add 4 g of glacial acetic acid to neutralize for 10 min, then pour it into an emulsifier together with 60 g of deionized water and emulsify at a rotation speed of 1200 r / min for 30 min. The obtained product is the base liquid component.

[0075] The modified titanium dioxide is prepared by modifying nano-titanium dioxide with silane coupling agent KH-570. The preparation steps of the modified titanium dioxide are as follows:

[0076] Step 1: Add 2 g of silane coupling agent KH-570, 30 g of absolute ethanol and 70 g of deionized water into a flask. Stir at a stirring speed of 500 r / min for 30 min, then use glacial acetic acid to adjust the pH value to 4, and ultrasonically disperse at a frequency of 26 kHz at room temperature for 2 h. The obtained product is denoted as the modifier component;

[0077] Step 2: Place the nano-titanium dioxide in an oven at 110 °C and dry it for 12 h. Then weigh 6 g and add it into the flask and add 20 g of absolute ethanol. Ultrasonically disperse at a frequency of 28 kHz for 30 min. The obtained product is denoted as the component to be modified;

[0078] Step 3: Under the water bath condition of 78 °C, drop the modifier component into the component to be modified at a dropping speed of 1 drop / s. Use ammonia water to adjust the pH value to 10, then stir at a stirring speed of 300 r / min for 5 h for reaction. Centrifuge at a rotation speed of 5000 r / min for 5 min, then extract with acetone, place it in an oven at 75 °C and dry for 6 h, and then grind it through a 200-mesh sieve. The obtained product is the modified titanium dioxide.

[0079] The modified calcium carbonate is prepared by modifying calcium carbonate with sodium stearate. The preparation method of the modified calcium carbonate is as follows:

[0080] Mix 5 g of calcium carbonate and 50 g of deionized water, stir at a stirring speed of 300 r / min for 10 min, then add 2 g of sodium stearate, and continue to stir at the original stirring speed for 2 h for reaction. After the reaction is completed, centrifuge at a speed of 5000 r / min for 5 min to obtain a precipitate. Extract the precipitate with acetone and then dry it in an oven at 68 °C for 6 h. The obtained product is the modified calcium carbonate.

[0081] The modified fly ash is prepared by modifying fly ash with ethylene glycol. The preparation method of the modified fly ash is as follows:

[0082] Weigh 5 g of ethylene glycol, add it to 100 g of deionized water, stir at a stirring speed of 400 r / min for 10 min, then add 200 g of fly ash and stir at a stirring speed of 100 r / min for 10 min. Disperse at a stirring speed of 600 r / min for 40 min, then dry in a blast box at 40 °C for 24 h. After grinding through a 200-mesh sieve, the obtained product is the modified fly ash.

[0083] Among them, the dispersant is cetyltrimethylammonium bromide, the defoamer is polydimethylsiloxane, and the curing agent is isocyanate curing agent.

[0084] A preparation method of an environmentally friendly stain-resistant and anti-slip preparation. The preparation method is as follows:

[0085] S1. Weigh 9 parts by weight of deionized water, 0.3 parts by weight of dispersant, 9 parts by weight of modified titanium dioxide, 4 parts by weight of modified calcium carbonate, and 5 parts by weight of modified fly ash, pour them into a ball mill, add ball milling beads according to a material-ball ratio of 1:3, and then ball mill at a speed of 300 r / min for 1 h. After passing through a 400-mesh sieve, the obtained product is recorded as the filler component;

[0086] S2. Weigh 53 parts by weight of the base liquid component and 0.3 parts by weight of defoamer and mix them. Stir at a stirring speed of 1200 r / min for 10 min, then add the filler component in S1, stir at a stirring speed of 1000 r / min for 5 min, then add 5 parts by weight of curing agent, and stir at a stirring speed of 500 r / min for 5 min. The obtained product is the environmentally friendly stain-resistant and anti-slip preparation.

[0087] Comparative Example 1

[0088] An environmentally friendly stain-resistant and anti-slip preparation and its preparation method provided in this comparative example are generally the same as those in Example 1. The main difference is that in this Comparative Example 1, the base liquid component in Example 1 is replaced with water-based epoxy resin.

[0089] Comparative Example 2

[0090] An environmentally friendly stain-resistant and anti-slip preparation provided in this comparative example and its preparation method are generally the same as those in Example 1, and the main difference is that in this Comparative Example 2, the modified titanium dioxide in Example 1 is replaced with unmodified nano-titanium dioxide.

[0091] Comparative Example 3

[0092] An environmentally friendly stain-resistant and anti-slip preparation provided in this comparative example and its preparation method are generally the same as those in Example 1, and the main difference is that in this Comparative Example 3, the modified calcium carbonate in Example 1 is replaced with unmodified calcium carbonate.

[0093] Comparative Example 4

[0094] An environmentally friendly stain-resistant and anti-slip preparation provided in this comparative example and its preparation method are generally the same as those in Example 1, and the main difference is that in this Comparative Example 4, the modified fly ash in Example 1 is replaced with unmodified fly ash.

[0095] Performance Test

[0096] The environmentally friendly stain-resistant and anti-slip preparations prepared in Examples 1-3 and Comparative Examples 1-4 are respectively marked as Example 1, Example 2, Example 3, Comparative Example 1, Comparative Example 2, Comparative Example 3 and Comparative Example 4, and then the performances of Examples 1-3 and Comparative Examples 1-4 are detected. The specific detection methods and detection items are as follows:

[0097] 1. Refer to the standard of ASTM-D4518 to detect the friction coefficients of Examples 1-3 and Comparative Examples 1-4, and the obtained data are recorded in the following table;

[0098] 2. Refer to the standard of GB / T 6739-86 to detect the pencil hardness of Examples 1-3 and Comparative Examples 1-4, and the obtained data are recorded in the following table;

[0099] 3. Refer to the standard of GB / T 1720-89 to detect the adhesion of Examples 1-3 and Comparative Examples 1-4, and the obtained data are recorded in the following table;

[0100] 4. Refer to the standard of GB / T1768-89 to detect the wear resistance of Examples 1-3 and Comparative Examples 1-4, and the obtained data are recorded in the following table;

[0101] Coefficient of friction Pencil hardness / H Adhesion Wear amount / g Example 1 0.81 2 2 0.003 Example 2 0.79 2 1 0.002 Example 3 0.78 2 1 0.003 Comparative example 1 0.76 1 1 0.008 Comparative example 2 0.71 1 2 0.051 Comparative example 3 0.73 2 1 0.064 Comparative example 4 0.72 1 1 0.047

[0102] It can be seen from the data in the above table that the friction coefficients of the environmentally friendly stain-resistant and anti-slip preparations in Examples 1-3 are significantly higher than those in Comparative Examples 1-4, indicating that the base liquid components, modified titanium dioxide, modified calcium carbonate and modified fly ash added in the present invention can play a role in improving the anti-slip performance of the material after being combined with each other. Therefore, the environmentally friendly stain-resistant and anti-slip preparation in the present invention has good application prospects.

[0103] The above content is only an example and illustration of the present invention. Those skilled in the art of the present technology can make various modifications or supplements to the described specific embodiments or use similar methods for substitution. As long as they do not deviate from the invention or exceed the scope defined by this claims, they shall fall within the protection scope of the present invention.

Claims

1. An environmentally friendly stain-resistant and anti-slip preparation, characterized in that, The environment-friendly stain-resistant and anti-slip preparation is composed of the following components: a base liquid component, modified titanium dioxide, modified calcium carbonate, modified fly ash, a dispersant, an antifoaming agent, a curing agent, and deionized water; The base liquid component is prepared by copolymerizing polyurethane and waterborne epoxy resin; The modified titanium dioxide is prepared by modifying nano-titanium dioxide with silane coupling agent KH-570; The modified calcium carbonate is prepared by modifying calcium carbonate with sodium stearate; The modified fly ash is prepared by modifying fly ash with ethylene glycol; 2. An environment-friendly stain-resistant and anti-slip preparation according to claim 1, characterized in that, The preparation steps of the base liquid component are as follows: Step 1: Weigh 30 g of polytetrahydrofuran ether glycol and pour it into a flask. Dehydrate it under a vacuum pump at 100 °C for 30 min, then cool it to 70 °C. Add 6.66 g of isophorone diisocyanate and heat it to 90 °C and react for 3 h. The obtained product is denoted as the polyurethane prepolymer component; Step 2: Weigh 23 g of epoxy resin and melt it in an oven at 100 °C. Pour it into the flask, then reheat it to 70 °C. Add 8 g of dipropylene glycol dimethyl ether and dissolve it at 85 °C for 30 min. Then add 2.8 g of ethylenediaminoethanesulfonic acid sodium salt and heat it to 66 °C and react for 1 h. The obtained product is denoted as the epoxy resin prepolymer component; Step 3: Add the polyurethane prepolymer component to the epoxy resin prepolymer component and add 4 g of piperazine. React at 60 °C for 6 h, then cool and discharge. Add 4 g of glacial acetic acid and neutralize for 10 min, then pour it into an emulsifier together with 60 g of deionized water and emulsify at a rotation speed of 1200 r / min for 30 min. The obtained product is the base liquid component.

3. An environment-friendly stain-resistant and anti-slip preparation according to claim 1, characterized in that, The preparation steps of the modified titanium dioxide are as follows: Step 1: Add 2 g of silane coupling agent KH-570, 30 g of absolute ethanol, and 70 g of deionized water to a flask. After mixing evenly, adjust the pH value to 3-4 and perform ultrasonic treatment at room temperature. The obtained product is denoted as the modifier component; Step 2: Place the nano-titanium dioxide in an oven at 110 °C and dry it for 12 h. Then weigh 6 g and add it to the flask, and add 20 g of absolute ethanol. Ultrasonically disperse it at a frequency of 28 kHz for 30 min. The obtained product is denoted as the component to be modified; Step 3: Under the water bath condition of 78 °C, drop the modifier component into the component to be modified at a dropping speed of 1 drop / s. Adjust the pH value to 9-10 and perform mechanical stirring for reaction. After centrifugation, extract with acetone, perform drying treatment, and then grind it through a 200-mesh sieve. The obtained product is the modified titanium dioxide.

4. An environment-friendly stain-resistant and anti-slip preparation according to claim 3, characterized in that, The specific operation of mixing evenly in Step 1 is to stir at a stirring speed of 500 r / min for 30 min. In Step 1, the pH value is adjusted with glacial acetic acid. The specific operation of ultrasonic treatment in Step 1 is to ultrasonically disperse at a frequency of 26 kHz for 2 h.

5. An environment-friendly stain-resistant and anti-slip preparation according to claim 3, characterized in that, In Step 3, the pH value is adjusted with ammonia water. The specific operation of mechanical stirring in Step 3 is to stir at a stirring speed of 300 r / min for 5 h. The specific operation of centrifugation in Step 3 is to centrifuge at a rotation speed of 5000 r / min for 5 min. The specific operation of drying treatment in Step 3 is to dry in an oven at 75 °C for 6 h.

6. An environment-friendly stain-resistant and anti-slip preparation according to claim 1, characterized in that, The preparation method of the modified calcium carbonate is as follows: Mix 5 g of calcium carbonate and 50 g of deionized water, stir at a stirring speed of 300 r / min for 10 min, then add 2 g of sodium stearate, and continue to stir for 2 h at the original stirring speed for reaction. After the reaction is completed, centrifuge at a speed of 5000 r / min for 5 min to obtain a precipitate. Extract the precipitate with acetone and then dry it in an oven at 68 °C for 6 h. The obtained product is the modified calcium carbonate.

7. An environmentally friendly stain-resistant and anti-slip preparation according to claim 1, characterized in that, The preparation method of the modified fly ash is as follows: Weigh 5 g of ethylene glycol, add it to 100 g of deionized water, stir at a stirring speed of 400 r / min for 10 min, then add 200 g of fly ash and stir at a stirring speed of 100 r / min for 10 min. Disperse at a stirring speed of 600 r / min for 40 min, then place it in a blast dryer at 40 °C for 24 h. After grinding through a 200-mesh sieve, the obtained product is the modified fly ash.

8. An environmentally friendly stain-resistant and anti-slip preparation according to claim 1, characterized in that, The dispersant is cetyltrimethylammonium bromide, the defoamer is polydimethylsiloxane, and the curing agent is isocyanate curing agent.

9. The preparation method of an environment-friendly stain-resistant and anti-slip preparation according to any one of claims 1-8, characterized in that, The preparation method is as follows: S1. Weigh 8 - 10 parts by weight of deionized water, 0.2 - 0.3 parts by weight of dispersant, 8 - 9 parts by weight of modified titanium dioxide, 3 - 5 parts by weight of modified calcium carbonate, and 5 - 6 parts by weight of modified fly ash, pour them into a ball mill, add ball milling beads according to a ball-to-material ratio of 1:3, and then ball mill at a speed of 300 r / min for 1 h. After passing through a 400-mesh sieve, the obtained product is denoted as the filler component; S2. Weigh 50 - 55 parts by weight of the base liquid component and 0.3 - 0.4 parts by weight of defoamer, mix them, add the filler component in S1 after high-speed dispersion, continue to disperse, then add 4 - 5 parts by weight of curing agent. After uniform dispersion, the obtained product is the environmentally friendly stain-resistant and anti-slip preparation.

10. The preparation method of an environment-friendly stain-resistant and anti-slip preparation according to claim 9, characterized in that, In S2, the specific operation of high-speed dispersion is to stir at a stirring speed of 1200 r / min for 10 min, the specific operation of continuous dispersion is to stir at a stirring speed of 1000 r / min for 5 min, and the specific operation of uniform dispersion is to stir at a stirring speed of 500 r / min for 5 min.