Pesticide composition containing pyrazolecarboxamide insecticide and application thereof

Abstract

The invention discloses a pesticide composition containing a pyrazolecarboxamide pesticide and application of the pesticide composition. The pesticide composition comprises an active component A which is the pyrazolecarboxamide pesticide and a component B which is at least one other pesticide defined in the specification, specifically, the invention relates to a pesticide composition for preventing and treating common lepidoptera, coleoptera, diptera, thysanoptera and homoptera pests of plants.

Description

[0001] This invention application is a divisional application with application number CN202011515865.3, application date December 21, 2020, and invention name "A pesticide composition containing pyrazolecarboxamide insecticides and its application". Technical Field

[0002] The present invention relates to a pesticide composition containing a pyrazolecarboxamide insecticide and a method for applying the composition. Background Art

[0003] Dimpropyridaz is a pyrazole carboxamide insecticide developed by BASF. Its chemical name is: 1-(1,2-dimethylpropyl)-N-ethyl-5-methyl-N-pyridazin-4-yl-pyrazole-4-carboxamide, CAS No. 1403615-77-9, and its structural formula is as follows:

[0004]

[0005] Dimpropyridaz is a pesticide that has a good control effect on aphids, whiteflies, thrips, leafhoppers and diamondback moths of the Homoptera, Coleoptera, Diptera, Thysanoptera and Lepidoptera orders.

[0006] International patent application WO2012143317 discloses pyrazolecarboxamide derivatives and their use as insecticides. The application document does not specifically mention possible insecticide compositions, nor does it mention the weight ratio of the pyrazolecarboxamide insecticide to other insecticide components in the composition.

[0007] International patent application WO2013189801 discloses pyrazole compounds and pesticide mixtures containing pyrazole compounds. The patent simply discloses the method and use of mixing the pyrazole compounds with some insecticides for controlling invertebrate pests, but does not mention the type of combined action of a specific composition for controlling a certain pest.

[0008] In the field of pesticides, new pesticide compositions with synergistic insecticide effects are often used to delay the development of pest resistance and minimize the impact of pesticides on the environment. Summary of the Invention

[0009] The present invention provides a pesticide composition containing a pyrazolecarboxamide insecticide. The pesticide composition contains the pyrazolecarboxamide insecticide and another known insecticide. The pesticide composition can be used to control common pests of the Homoptera, Coleoptera, Diptera, Thysanoptera, and Lepidoptera orders, such as aphids, whiteflies, leafhoppers, thrips, and diamondback moth, on fruit trees, vegetables, grain crops, and tea leaves. The pesticide composition exhibits synergistic insecticidal activity and can meet the needs of agricultural production.

[0010] The insecticide composition of the present invention comprises an active component A and an active component B.

[0011] Furthermore, the active component A is Dimpropyridaz, and the active component B is at least any one insecticide compound selected from B1-B17.

[0012] B1 Carbamates: benthiocarb, benfuracarb, propoxur, butasulfuron, bendiocarb, fenthiocarb, furamicarb, methiocarb, carbaryl, pirimicarb, carbofuran, cypermethrin, methomyl, oxamyl, aldicarb, aldisulfuron, ethiofencarb, isoprocarb, fenbutylcarb, triazolam, cypermethrin, pyraclostrobin, sulfamethoxam, cypermethrin, pyraclostrobin, chlorpyrifos, chlorpyrifos, chlorpyrifos, chlorpyrifos;

[0013] B2 organophosphates: trichlorfon, dichlorvos, chlorpyrifos, chlorpyrifos, parathion, diazinon, dibromophos, phosalone, methyl parathion, methyl pyrifos, methyl chlorpyrifos, methyl parathion, methyl glutamic acid, methyl pirimiphos, methyl demeton, methyl thiophos, monocrotophos, quinalphos, dimethoate, phosphamidon, cadusofos, Chlormethoate, chloroxyphos, malathion, ethoprophos, chloramidophos, triazophos, fenitrothion, fenitrothion, methiopromide, temephos, isocarbophos, mevinphos, terbufos, methoprene, phoxim, phosmet, sulfoxide, omethoate, disulfoton, azinphos-ethyl, ethion, acephate, methylpyraclofos, isoflurane, coumaphos, chlorpyrifos, azinphos-methyl, azinphos-ethyl, bromophos-ethyl, bromophenphos-ethyl, teramiphos, trisulfon, propylamidophos, pyrifos, isoflurane, methidathion;

[0014] B3 Pyrethroids: s-cypermethrin, θ-cypermethrin, β-cypermethrin, avermectin, phenothrin, tetrafluthrin, DDT, resmethrin, dichlorvos, allethrin, pyrethrin, fluvalinate, acralthrin, flutoxin, pentothrin, imidacloprid, thienthrin, flumethrin, flucythrin, flucythrin, beta-cypermethrin, triflumuron, fluvalinate, cyhalothrin, cypermethrin, phenothrin, metofluthrin, bromothrin, tetramethrin, beta-cyhalothrin Pyrethrin, cypermethrin, cypermethrin, methoprene, lambda-cyhalothrin, bifenthrin, cypermethrin, permethrin, cypermethrin, cypermethrin, tefluthrin, fenvalerate, allethrin, imiprothrin, thiophanate, flucythrin, bioresmethrin, bioallethrin, lambda-cypermethrin, cypermethrin, transfluthrin, transfluthrin, translomethrin, fenvalerate, cypermethrin, cypermethrin, cypermethrin, cyfluth ...

[0015] B4 neonicotinoids: imidacloprid, acetamiprid, dinotefuran, sulfoxaflor, clothianidin, thiacloprid, thiamethoxam, nitenpyram, nicotine, trifluanid, nithiazine, chlorothiazolin,

[0016] B5 Benzylurea: Diflubenzuron, Noviflumuron, Flufenoxuron, Flufluazuron, Flufluuron, Flupyuron, Flufenoxuron, Flufluuron, Triflumuron, Lufenuron, Bistriflumuron, Chlorofluanid, Flupyralid, Flufenoxuron ...

[0017] B6 Juvenile hormone mimetics: fenoxycarb, pyriproxyfen, methoprene, methoprene, fenpropathrin, fenpropathrin, fenpropathrin, fenpropathrin, and methoprene;

[0018] B7 Nereis toxin analogs: thiocarb, thiosulfuron, dimethoate, cartap hydrochloride;

[0019] B8 avermectins: avermectin, emamectin benzoate, lepidomectin, avermectin;

[0020] B9 Biological substances, hormones or pheromones: azadirachtin, Bacillus species, Beauveria species, Metarhizium species, Paecilomyces species, Bacillus thuringiensis, Verticillium species;

[0021] B10 Pyrazoles: butyronitrile, fipronil, ethiprole, acetoprole, ethioprole, flupyraclostrobin;

[0022] B11 Oxadiazines: indoxacarb;

[0023] B12 Organochlorine compounds: lindane, chlordane, endosulfan;

[0024] B13 diamides: flubendiamide, chlorantraniliprole, cyantraniliprole, flubendiamide, flufenamid, flufenamid, flufenamid;

[0025] B14 Diacylhydrazide: tebufenozide, chlorfenapyr, methoxyfenozide, chlorfenapyr;

[0026] B15 Other heterocyclics: pyrimidine, pyrifluanid, pymetrozine, butyronitrile, pyraclostrobin, fipronil, ethiprole, flonicamid, tolfenpyrad, indoxacarb, chlorfenapyr,

[0027] Cyclomethanil, pyrimethanil, and fluazifop;

[0028] B16 Biological insecticides: spinosad, spinosad;

[0029] B17 acaricides: acequinoxaline, fenpyroximate, benzyl cypermethrin, pyridabenzine, sulfamethoxam, bifenazate, mycomycin, cyproconazole, buprofezin, dicofol, dicofol sulfone, chlorpyrifos, bromopyralid, diclofenac, spirotetramat, spiromesifen, spirodiclofen, quinazaquin, pyridabenz, cypermethrin, fluazifop, pyrimidifen, hexythiazox, clofentezine, ivermectin, etoxazole, cyflumetofen, cyproconazole, fenbutatin, tricyclazone, triazotin.

[0030] When the active components in the insecticidal composition of the present invention are present in a specific mass ratio, the synergistic effect is very significant. The mass ratio of active component A to active component B is 0.1:100 to 100:0.1, preferably 1:12 to 100:0.1, and more preferably 1:4 to 100:1.

[0031] Furthermore, the mass ratio of active component A to abamectin is 25:1 to 100:1, the mass ratio of active component A to pyriproxyfen is 1:2 to 2:1, the mass ratio of active component A to imidacloprid is 2:5 to 50:1, the mass ratio of active component A to pymetrozine is 5:2 to 10:1, the mass ratio of active component A to profenofos is 1:1 to 50:1, the mass ratio of active component A to tebufenozide is 1:4 to 1:1, and the mass ratio of active component A to imidacloprid is 2:5 to 50:1. The mass ratio of active component A to diflubenzuron is 1:8-1:2, the mass ratio of active component A to butamethoxam is 5:2-10:1, the mass ratio of active component A to butyclomefone is 5:1-20:1, the mass ratio of active component A to acetamiprid is 25:3-100:3, the mass ratio of active component A to dinotefuran is 1:5-20:1, the mass ratio of active component A to flufenoxuron is 1:12-1:4, the mass ratio of active component A to sulfoxaflor ... The mass ratio of active component A to flubendiamide is 1:5 to 50:1, the mass ratio of active component A to flupyralid is 2:5 to 2:1, the mass ratio of active component A to fluflumuron is 10:1 to 50:1, the mass ratio of active component A to hexaflumuron is 10:1 to 40:1, the mass ratio of active component A to flufenacet is 100:0.5 to 100:0.1, the mass ratio of active component A to cyhalothrin is 25:4 to 25:1, the mass ratio of active component A to flufenacet ...:1 to 40:1, the mass ratio of active component A to flufenacet is 10:1 to 10 The mass ratio of active component A to emamectin benzoate is 50:1-100:0.5, the mass ratio of active component A to methoxyfenozide is 1:2-2:1, the mass ratio of active component A to cypermethrin is 25:0.2-50:0.1, the mass ratio of active component A to pirimicarb is 5:2-10:1, the mass ratio of active component A to bifenazate is 5:2-10:1, and the mass ratio of active component A to bifenthrin is 2:1-100:0.1. The mass ratio of the active component A to spirotetramat is 25:2-50:1, the mass ratio of the active component A to chlorantraniliprole is 25:1-100:1, the mass ratio of the active component A to propargyl is 5:2-10:1, the mass ratio of the active component A to clothianidin is 1:2-20:1, the mass ratio of the active component A to thiamethoxam is 5:1-20:1, the mass ratio of the active component A to triflumuron is 4:1-50:1, the mass ratio of the active component A to trifluoromethylpyrifos is 5:1-20:1, the mass ratio of the active component A to triazophos is 1:1-4:1, the mass ratio of the active component A to dimehypo is 1:1-4:1, and the mass ratio of the active component A to triflumuron is 5:1-20:1. The mass ratio of active component A to lufenuron is 5:2-10:1, the mass ratio of active component A to bistrifluan is 1:4-10:1, the mass ratio of active component A to nitenpyram is 2:1-20:1, the mass ratio of active component A to ethiprole is 2:1-10:1, the mass ratio of active component A to spinetoram is 25:2-50:1, the mass ratio of active component A to etoxazole is 25:1-100:1, the mass ratio of active component A to isoprocarb is 2:5-5:2, the mass ratio of active component A to indoxacarb is 5:2-50:1, the mass ratio of active component A to tolfenpyrad is 1:2-2:1, and the mass ratio of active component A to pyraclostrobin is 25:1-100:1.

[0032] Further, the mass ratio of the active component A to abamectin is 25:1 to 50:1, the mass ratio of the active component A to pyriproxyfen is 1:1 to 2:1, the mass ratio of the active component A to imidacloprid is 10:1 to 50:1, the mass ratio of the active component A to pymetrozine is 5:1 to 10:1, the mass ratio of the active component A to profenofos is 4:1 to 50:1, the mass ratio of the active component A to tebufenozide is 1:2 to 1:1, the mass ratio of the active component A to diflubenzuron is 1:8 to 1:2, the mass ratio of the active component A to butyronitrile is 5:1 to 10:1, the mass ratio of the active component A to butyclohexene is 10:1 to 20:1, the mass ratio of the active component A to acetamiprid is 50:3 to 100:3, and the mass ratio of the active component A to dinotefuran is 2:5 to 20: 1. The mass ratio of active component A to flufenoxuron is 1:12 to 1:6, the mass ratio of active component A to sulfoxaflor is 1:5 to 25:3, the mass ratio of active component A to flonicamid is 2:5 to 4:5, the mass ratio of active component A to chlorfluanid is 20:1 to 50:1, the mass ratio of active component A to hexaflumuron is 20:1 to 40:1, the mass ratio of active component A to flufenoxam is 100:0.5 to 100:0.1, the mass ratio of active component A to lambda-cyhalothrin is 25:2 to 25:1, the mass ratio of active component A to emamectin benzoate is 100:1 to 100:0.5, the mass ratio of active component A to methoxyfenozide is 1:1 to 2:1, and the mass ratio of active component A to cypermethrin is 50:0.2 to 50:0.1. The mass ratio of the active component A to pirimicarb is 5:2 to 5:1, the mass ratio of the active component A to bifenazate is 5:1 to 10:1, the mass ratio of the active component A to bifenthrin is 4:1 to 10:1, the mass ratio of the active component A to spirotetramat is 25:1 to 50:1, the mass ratio of the active component A to chlorantraniliprole is 50:1 to 100:1, the mass ratio of the active component A to propargite is 5:1 to 10:1, the mass ratio of the active component A to clothianidin is 1:2 to 1:1, the mass ratio of the active component A to thiamethoxam is 5:1 to 20:1, the mass ratio of the active component A to trifluralin is 4:1 to 50:1, the mass ratio of the active component A to trifluoromethylpyrifos is 10:1 to 20:1, the mass ratio of the active component A to triazophos is 1:1 to 4:1, and the mass ratio of the active component A to dimethoate is 1:2 to 1:1. The mass ratio of active component A to triflumuron is 2:1-4:1, the mass ratio of active component A to triflumuron is 5:1-10:1, the mass ratio of active component A to lufenuron is 5:1-10:1, the mass ratio of active component A to bistrifluanuron is 1:2-10:1, the mass ratio of active component A to nitenpyram is 2:1-10:1, the mass ratio of active component A to ethiprole is 2:1-5:1, the mass ratio of active component A to spinetoram is 25:2-50:1, the mass ratio of active component A to etoxazole is 25:1-100:1, the mass ratio of active component A to isoprocarb is 2:5-5:2, the mass ratio of active component A to indoxacarb is 5:2-20:1, the mass ratio of active component A to tolfenpyrad is 1:2-2:1, and the mass ratio of active component A to pyraclostrobin is 25:1-100:1.

[0033] Further, the mass ratio of active component A to abamectin is 50:1, 25:1, 100:1, and 50:1, the mass ratio of active component A to pyriproxyfen is 1:2 and 2:1, the mass ratio of active component A to imidacloprid is 10:1, 5:1, 20:1, 1:1, 2:5, 5:2, 25:1, 25:3, 50:1, and 50:3, the mass ratio of active component A to pymetrozine is 4:1, 2:1, 10:1, 5:1, and 5:2, and the mass ratio of active component A to profenofos is 5:1, 5:2, 25:4, 2:1, 1:1, 4:1, 2:1, 25:2, and 5 The mass ratios of active component A to tebufenozide were 1:2, 1:4, 1:1, and 50:1, the mass ratios of active component A to diflubenzuron were 1:8, 1:2, and 1:4, the mass ratios of active component A to butyronitrile were 5:2, 10:1, and 5:1, the mass ratios of active component A to cyflumetofen were 5:1, 20:1, and 10:1, the mass ratios of active component A to acetamiprid were 25:3, 100:1.5, and 50:3, the mass ratios of active component A to dinotefuran were 10:1, 5:1, 20:1, 2:5, 1:5, 1:1, 1:2, and 5:2, the mass ratios of active component A to The mass ratio of flubendiamide is 1:8, 1:12, 1:4, and 1:6, the mass ratio of active component A to sulfoxaflor is 1:1, 1:2, 2:1, 2:5, 1:5, 25:1, 25:2, 50:1, 25:3, 25:6, 50:3, and 4:5, the mass ratio of active component A to chlorpyrifos is 25:1, 10:1, 50:1, 40:1, and 20:1, the mass ratio of active component A to flufenoxam is 50:0.1, 100:1, 100:0.1, and 100:0.5, the mass ratio of active component A to lambda cyhalothrin is 25:4, 25:1, The mass ratios of active component A to emamectin benzoate were 50:1, 100:0.5, and 100:1, the mass ratios of active component A to methoxyfenozide were 1:2, 2:1, and 1:1, the mass ratios of active component A to cypermethrin were 25:0.1, 125:1, and 50:0.1, the mass ratios of active component A to pirimicarb were 5:1, 5:2, and 10:1, the mass ratios of active component A to bifenazate were 5:1, 5:2, and 10:1, and the mass ratios of active component A to bifenthrin were 5:1, 2:1, 10:1, 4:1, 50:0.1, 25:0.1, and 100:0.1, the mass ratio of active component A to spirotetramat is 25:1, 25:2, 50:1, the mass ratio of active component A to chlorantraniliprole is 50:1, 25:1, 100:1, 50:1, the mass ratio of active component A to propargyl is 5:1, 5:2, 10:1, the mass ratio of active component A to clothianidin is 1:1, 1:2, 5:2, 5:4, 20:1, 10:1, the mass ratio of active component A to thiamethoxam is 5:1, 20:1, 10:1, :1, 10:1, the mass ratio of active component A to triflumuron is 20:1, 4:1, 50:1, 10:1, the mass ratio of active component A to triflumuron is 5:1, 20:1, 10:1, the mass ratio of active component A to triazophos is 1:1, 4:1, 2:1, the mass ratio of active component A to dimehypo is 1:1, 4:1, 2:1, the mass ratio of active component A to triflumuron is 10:1, 5:1, 20:1, the mass ratio of active component A to triflumuron is The mass ratio of active component A to lufenuron is 5:1, 5:2, and 10:1, the mass ratio of active component A to bistrifluan is 1:2, 1:4, 1:1, 5:2, 10:1, and 5:1, the mass ratio of active component A to nitenpyram is 4:1, 2:1, 8:1, 2:1, 5:1, 20:1, and 10:1, the mass ratio of active component A to ethiprole is 4:1, 2:1, 10:1, and 5:1, and the mass ratio of active component A to spinetoram is 25 :2, 50:1, 25:1, the mass ratio of active component A to etoxazole is 25:1, 100:1, 50:1, the mass ratio of active component A to isoprocarb is 2:5, 5:2, 1:1, the mass ratio of active component A to indoxacarb is 10:1, 5:1, 20:1, 5:2, the mass ratio of active component A to tolfenpyrad is 1:2, 2:1, 1:1, and the mass ratio of active component A to pyraclostrobin is 25:1, 100:1, 50:1.

[0034] When the composition of the present invention is used to control green peach aphids, the mass ratio of active component A to pirimicarb is 5:1, 5:2, and 10:1, the mass ratio of active component A to lambda cyhalothrin is 25:4, 25:1, and 25:2, the mass ratio of active component A to bifenthrin is 25:0.1, 100:0.1, and 50:0.1, the mass ratio of active component A to imidacloprid is 25:1, 25:3, 50:1, and 50:3, the mass ratio of active component A to acetamiprid .... The mass ratio of active component A to dinotefuran is 50:3, 25:3, and 100:3, the mass ratio of active component A to sulfoxaflor is 50:1, 25:1, the mass ratio of active component A to clothianidin is 5:1, 20:1, and 10:1, the mass ratio of active component A to thiamethoxam is 5:1, 20:1, and 10:1, the mass ratio of active component A to nitenpyram is 5:1, 20:1, and 10:1. :1, the mass ratio of active component A to pymetrozine is 5:2, 10:1, 5:1, the mass ratio of active component A to sulfoxaflor is 25:6, 50:3, 25:3, preferably the mass ratio of active component A to high-efficiency chlorflucythrinate is 25:4, 25:1, 25:2, the mass ratio of active component A to bifenthrin is 25:0.1, 100:0.1, 50:0.1, 50:3, the mass ratio of active component A to acetamiprid is 50:3 , 25:3, the mass ratios of active component A to dinotefuran are 5:1, 20:1, and 10:1, the mass ratio of active component A to sulfoxaflor is 25:1, the mass ratio of active component A to clothianidin is 10:1, the mass ratio of active component A to thiamethoxam is 10:1, the mass ratio of active component A to nitenpyram is 20:1, the mass ratio of active component A to pymetrozine is 5:1, and the mass ratios of active component A to sulfoxaflor are 50:3 and 25:3;

[0035] When the composition of the present invention is used to control rice planthoppers, the mass ratio of the active component A to isoprocarb is 1:1, 2:5, and 5:2, the mass ratio of the active component A to profenofos is 5:1, 5:2, 25:2, and 25:4, the mass ratio of the active component A to imidacloprid is 2:5, 5:2, and 1:1, the mass ratio of the active component A to dinotefuran is 2:5, 1:5, 1:1, and 1:2, the mass ratio of the active component A to sulfoxaflor is 2:5, 1:5, 1:1, and 1:2, the mass ratio of the active component A to clothianidin is 1:1, 1:2, 5:2, and 5:4, the mass ratio of the active component A to nitenpyram is 4:1, 2:1, 10:1, and 5:1, and the mass ratio of the active component A to trifluanid is 2:5, 1:5, 1:1, and 1:2. The mass ratio of active component A to isoprocarb is 1:1, 2:5, the mass ratio of active component A to profenofos is 5:1, 25:2, the mass ratio of active component A to clothianidin is 1:1, the mass ratio of active component A to pymetrozine is 4:1, 2:1, 10:1, 5:1, the mass ratio of active component A to flonicamid is 4:5, 2:5, 2:1, 1:1; preferably, the mass ratio of active component A to isoprocarb is 1:1, 2:5, the mass ratio of active component A to profenofos is 5:1, 25:2, the mass ratio of active component A to clothianidin is 1:1, the mass ratio of active component A to pymetrozine is 4:1, 2:1, and the mass ratio of active component A to flonicamid is 4:5, 2:5, 2:1, 1:1;

[0036] When the composition of the present invention is used to control whiteflies, the mass ratios of the active component A to sulfoxaflor are 1:2, 2:1, and 1:1, the mass ratios of the active component A to bistrifluan are 1:4, 1:1, and 1:2, and the mass ratios of the active component A to pyriproxyfen are 1:2, 2:1, and 1:1; preferably, the mass ratios of the active component A to sulfoxaflor are 2:1 and 1:1, the mass ratios of the active component A to bistrifluan are 1:4 and 1:2, and the mass ratios of the active component A to pyriproxyfen are 2:1 and 1:1.

[0037] When the composition of the present invention is used to control Plutella xylostella, the mass ratio of the active component A to profenofos is 25:2, 50:1, and 25:1, the mass ratio of the active component A to diflubenzuron is 1:8, 1:2, and 1:4, the mass ratio of the active component A to chlorfluazuron is 10:1, 50:1, and 20:1, the mass ratio of the active component A to hexaflumuron is 10:1, 40:1, and 20:1, the mass ratio of the active component A to triflumuron is 5:1, 20:1, and 10:1, the mass ratio of the active component A to lufenuron is 5:2, 10:1, and 5:1, the mass ratio of the active component A to bistriflumuron is 5:2, 10:1, and 5:1, and the mass ratio of the active component A to chlorfluazuron is 10:1, 40:1, and 20:1. The mass ratios of active component A to abamectin were 25:1, 100:1, and 50:1, the mass ratios of active component A to emamectin benzoate were 10:1, 50:1, 50:0.1, and 100:1, the mass ratios of active component A to indoxacarb were 5:2, 10:1, and 5:1, the mass ratios of active component A to chlorantraniliprole were 25:1, 100:1, and 50:1, the mass ratios of active component A to flufenacet were 100:1, 100:0.1, and 20:0.1, the mass ratios of active component A to tebufenozide were 1:20, 1:4, 1:1, and 1:2, and the mass ratios of active component A to methoxyfenozide were 1:2, 2:1, and 2:1. 1:1, the mass ratio of active component A to tolfenpyrad is 1:2, 2:1, 1:1, the mass ratio of active component A to spinetoram is 25:2, 50:1, 25:1, the mass ratio of active component A to butyronitrile is 5:2, 10:1, 5:1, the mass ratio of active component A to trifluoromethylpyrifos is 5:1, 20:1, 10:1; preferably, the mass ratio of active component A to profenofos is 50:1, 25:1, the mass ratio of active component A to diflubenzuron is 1:2, 1:4, the mass ratio of active component A to chlorfluazuron is 50:1, 20:1, the mass ratio of active component A to hexaflumuron is 40:1, 20:1, the mass ratio of active component A to chlorpyrifos is 50:1, 25:1 The mass ratios of active component A to triflumuron were 20:1 and 10:1, the mass ratios of active component A to lufenuron were 5:2, 10:1, and 5:1, the mass ratios of active component A to bistrifluan were 10:1 and 5:1, the mass ratios of active component A to abamectin were 25:1, 100:1, and 50:1, the mass ratios of active component A to emamectin benzoate were 50:1, 50:0.1, and 100:1, the mass ratios of active component A to indoxacarb were 10:1 and 5:1, the mass ratios of active component A to chlorantraniliprole were 100:1 and 50:1, and the mass ratios of active component A to flufenacet were 100:0.1 and 20:0.1. The mass ratios of active component A to tebufenozide are 1:1 and 1:2; the mass ratios of active component A to methoxyfenozide are 2:1 and 1:1; the mass ratios of active component A to tolfenpyrad are 1:2, 2:1, and 1:1; the mass ratios of active component A to spinetoram are 50:1 and 25:1; the mass ratios of active component A to butyronitrile are 10:1 and 5:1; and the mass ratios of active component A to fluazifop are 5:1, 20:1, and 10:1.

[0038] When the composition of the present invention is used to control the striped stem borer, the mass ratio of the active component A to profenofos is 2:1, 1:1, and 4:1, the mass ratio of the active component A to triazophos is 2:1, 1:1, and 4:1, the mass ratio of the active component A to dinotefuran is 5:2, 10:1, and 5:1, the mass ratio of the active component A to dimehypo is 1:1, 4:1, and 2:1, the mass ratio of the active component A to butyronitrile is 5:2, 10:1, and 5:1, the mass ratio of the active component A to chlorfenapyr is 50:1, 25:1, 100:1, and 50:1, and the mass ratio of the active component A to flubendiamide is 50:0.1, 100:1, and 10:1. , 100:0.1, 20:0.1; preferably, the mass ratio of the active component A to profenofos is 2:1, 4:1, the mass ratio of the active component A to triazophos is 2:1, 4:1, the mass ratio of the active component A to dinotefuran is 5:2, 10:1, 5:1, the mass ratio of the active component A to dimehypo is 4:1, 2:1, the mass ratio of the active component A to butyronitrile is 10:1, 5:1, the mass ratio of the active component A to chlorfenapyr is 50:1, 25:1, 100:1, 50:1, and the mass ratio of the active component A to flubendiamide is 50:0.1, 100:1, 100:0.1, 20:0.1.

[0039] When the composition of the present invention is used to control tea green leafhoppers, the mass ratio of the active component A to bifenthrin is 5:1, 2:1, 10:1, and 4:1, the mass ratio of the active component A to imidacloprid is 10:1, 5:1, and 20:1, the mass ratio of the active component A to dinotefuran is 5:1, 20:1, and 10:1, the mass ratio of the active component A to nitenpyram is 2:1, 8:1, and 4:1, and the mass ratio of the active component A to indoxacarb is 5:1, 20:1, and 10:1; preferably, the mass ratio of the active component A to imidacloprid is 10:1 and 20:1, the mass ratio of the active component A to dinotefuran is 5:1, 20:1, and 10:1, the mass ratio of the active component A to nitenpyram is 4:1, and the mass ratio of the active component A to indoxacarb is 20:1.

[0040] When the composition of the present invention is used to control Tetranychus cinnabarinus, the mass ratio of active component A to flufenoxuron is 1:8, 1:12, 1:4, and 1:6, the mass ratio of active component A to pyraclostrobin is 50:1, 25:1, and 100:1, the mass ratio of active component A to bifenazate is 5:1, 5:2, 10:1, and 5:1, the mass ratio of active component A to propargyl is 5:2, 10:1, and 5:1, the mass ratio of active component A to etoxazole is 50:1, 25:1, and 100:1, the mass ratio of active component A to cyflumetofen is 5:1, 20:1, and 10:1, and the mass ratio of active component A to cypermethrin is 5:1, 20:1, and 10:1. The mass ratio of the active component A to pyroximate is 25:0.2, 50:0.1, and 25:0.1, and the mass ratio of the active component A to spirotetramat is 25:2, 50:1, and 25:1; preferably, the mass ratio of the active component A to pyroximate is 50:1 and 100:1, the mass ratio of the active component A to bifenazate is 10:1 and 5:1, the mass ratio of the active component A to propargyl is 5:1, the mass ratio of the active component A to cyflumetofen is 20:1 and 10:1, the mass ratio of the active component A to cypermethrin is 25:0.2, 50:0.1, and 25:0.1, and the mass ratio of the active component A to spirotetramat is 25:2, 50:1, and 25:1.

[0041] In the insecticidal composition of the present invention, the total amount of the active component A and the active component B accounts for 1% to 90% by mass, preferably 10% to 70%.

[0042] The insecticide composition of the present invention further contains pesticide preparation adjuvants and carriers.

[0043] The insecticide composition of the present invention can be used to prevent and control pests of the orders Lepidoptera, Coleoptera, Diptera, Thysanoptera and Homoptera.

[0044] The insecticide composition of the present invention is particularly useful for preventing and controlling Thysanoptera and Homoptera pests, especially Homoptera pests.

[0045] The insecticide composition of the present invention has the following significant advantages compared with the prior art:

[0046] 1. The insecticide composition of the present invention has significant synergistic effect, which can reduce the number of applications and the amount of single-dose application;

[0047] 2. The insecticidal composition of the present invention is active against all forms of pests;

[0048] 3. The insecticide composition of the present invention is composed of active ingredients with different mechanisms of action, which can effectively slow down the development of insecticide resistance in pests and greatly reduce the risk of resistance caused by the application of a single ingredient.

[0049] 4. The insecticide composition of the present invention can significantly improve the tolerance of crops, making the pesticide safer for crops. DETAILED DESCRIPTION

[0050] The biological activity examples are divided into indoor biological activity examples and field biological activity examples.

[0051] Indoor biological activity: The inventors selected the Bliss method to determine the synergistic effect of the combination of active component A and active component B on pests.

[0052] M t =1-(1-P A )(1-P B )

[0053] M e -M t =M e -(P A +P B -P A ×P B )

[0054] Where:

[0055] M e : Actual preventive effect of the composition

[0056] M t :Theoretical efficacy of the composition

[0057] P A 、P B : These are the measured control effects of component A and component B at corresponding concentrations.

[0058] M e -M t When >0, the synergistic effect is synergistic, M e -M t When <0, synergy is antagonism, M e -M t =0 is an additive effect.

[0059] The following tests can demonstrate the control effect of the pesticidal composition of the present invention on specific pests, but are not limited to the pest control method provided.

[0060] Example 1: Indoor activity of the insecticidal composition against green peach aphids

[0061] Select peach aphids of the same age, immerse them in the solution for 10 seconds, absorb the excess solution with filter paper, and transfer the test insects to normal conditions for rearing. Each treatment was repeated 4 times, with 10 insects in each repetition. After culturing for 24 hours, the mortality rate of peach aphids was evaluated. The results are shown in Table 1.

[0062] Table 1 Indoor activity results of the insecticide composition against green peach aphids

[0063]

[0064]

[0065] Example 2: Indoor activity of the insecticidal composition against rice planthoppers and whiteflies

[0066] The larvae selected were all 2-3 instars. The immersion method was used. The rice planthoppers were immersed in the liquid for about 10 seconds. The excess liquid was absorbed with filter paper, and the test insects were transferred to normal conditions for rearing. Each treatment was repeated 4 times, with 10 insects immersed in each repetition. The mortality rate was calculated after rearing for 24 hours. The results are shown in Table 2-3.

[0067] Table 2 Indoor test results of insecticide composition on rice planthopper

[0068]

[0069]

[0070] Table 3 Indoor test results of insecticide composition against whitefly

[0071]

[0072] Example 3: Indoor test of the insecticide composition against Plutella xylostella

[0073] A 1cm diameter leaf disc was punched out using a hole punch, placed in a culture dish, incubated with the test agent for 4 hours, and then placed in a tissue culture plate for later use. Two- to three-year-old diamondback moths were selected and starved for 4 hours. Sixty test insects were selected and placed in the culture plates for feeding. Four hours after inoculation, 20 test insects that had completely consumed the leaf disc were selected and incubated at room temperature for 24 hours. Mortality was observed and the mortality rate (control efficacy) was calculated. Each treatment was repeated four times. The test results are shown in Table 4.

[0074] Table 4 Indoor test results of insecticide composition against diamondback moth

[0075]

[0076]

[0077] Example 4: Indoor activity of the insecticide composition against Chilo suppressalis

[0078] A 1 cm diameter leaf disc was punched out using a cork borer, placed in a culture dish, incubated with the test agent for 4 hours, and then placed in a tissue culture plate for later use. Two- to three-year-old Chilo suppressalis (C. suppressalis) were selected and starved for 4 hours. Fifty test insects were selected and placed in the culture plate for feeding. Four hours after inoculation, 15 test insects that had completely consumed the leaf disc were selected and incubated at room temperature for 24 hours. Mortality was investigated and the mortality rate (control efficacy) was calculated. Each treatment was repeated four times. The test results are shown in Table 5.

[0079] Table 5 Indoor test results of insecticide composition against Chilo suppressalis

[0080]

[0081]

[0082] Example 5: Indoor activity test of the insecticide composition against tea green leafhopper

[0083] The larvae selected were all 2-3 instar larvae. The tea green leafhopper was immersed in the liquid medicine for about 10 seconds using the insect immersion method. The excess liquid was absorbed with filter paper, and the test insects were transferred to normal conditions for rearing. Each treatment was repeated 4 times, with 15 insects immersed in each repetition. The mortality rate was calculated after rearing for 24 hours. The results are shown in Table 6.

[0084] Table 6 Indoor activity results of the insecticide composition against tea green leafhopper

[0085]

[0086]

[0087] Example 6: Indoor Activity of the Insecticidal Composition Against Tetranychus cinnabarinus

[0088] Citrus leaves with growth inhibition were selected and leaf discs were made with a hole punch. The nymphs of Tetranychus cinnabarinus cultured indoors were inoculated onto the leaf discs. Twenty nymphs were inoculated per leaf disc. The leaves were sprayed using a Potter spray tower with a spray volume of 1 mL. After the solution settled for 1 minute, it was taken out and transferred to room temperature for feeding. After 48 hours, the number of dead test insects was checked and the mortality rate was calculated. The experiment is shown in Table 7.

[0089] Table 7 Indoor activity results of the insecticide composition against Tetranychus cinnabarinus

[0090]

[0091]

[0092] The results of indoor tests showed that the mixtures listed in Tables 1 to 7 had good indoor activity against peach aphids, rice planthoppers, whiteflies, diamondback moths, striped stem borers, tea leafhoppers, and spider mites.

[0093] Example 7: Field control effect of the insecticide composition on green peach aphid

[0094] This trial was conducted at the Jimo Experimental Base in Qingdao, using cabbage as the crop. A completely randomized block design was used, with a water dosage of 15 L per mu and four replicates per treatment. A baseline count was conducted before treatment and a live count was conducted after treatment. The reduction rate and control efficacy were calculated. The survey method used five sampling points, with five plants surveyed at each point. For each plant, a leaf with a sufficient number of aphids was marked and counted throughout the leaf. A baseline count of at least 500 aphids was obtained per plot.

[0095] Insect population reduction rate (%) = (insect population base - insect population after application) / base before test × 100

[0096] Control effect (%) = (pest population reduction rate in pesticide treatment - insect population reduction rate in blank control area) / (100 - insect population reduction rate in blank control area) × 100

[0097] Table 8 Field control effect of the insecticide composition on green peach aphids on cabbage

[0098]

[0099] The test results show that the insecticide compositions listed in Table 8 all achieved the expected control effects on green peach aphids on cruciferous cabbage, with control efficiencies ranging from 82.06% to 93.27%.

[0100] Example 8: Field control effect of the insecticide composition on rice planthoppers

[0101] The trial was conducted at the Changsha Rice Experimental Base in Hunan Province. Five treatments were set up, along with a water control. Each treatment area was 20 square meters, replicated three times, and the water consumption per mu was 15 liters. Live insect counts were conducted 14 days after application. The survey method involved surveying 25 rice clumps per treatment, shaking the clumps, and counting the number of rice planthoppers floating on the water surface between the clumps to calculate control efficacy.

[0102] Control effect (%) = [(number of live insects in the control area after control - number of live insects in the treatment area after control) / number of live insects in the control area after control] × 100

[0103] Table 9 Control effect of insecticide composition on rice planthopper

[0104]

[0105]

[0106] The test results show that the insecticide compositions listed in Table 9 have good control effects on rice planthoppers, with a control effect of 66.76%-84.62%.

[0107] Example 9: Field control effect of the insecticide composition on whiteflies

[0108] This experiment was conducted on greenhouse cucumbers, with each plot measuring 20 square meters and surrounded by protective plants. Four replicates were used per treatment, and 20 liters of water were used per mu. Six compound leaves from the same growing area of ​​10 cucumber plants were surveyed within each replicate. In the early morning, when adult insects are inactive, the leaves were gently turned, and the number of adults per leaf was counted. The baseline insect population was measured before application, and the number of live insects was counted seven days after application. The population reduction rate and control efficacy were calculated.

[0109] Insect population reduction rate (%) = (insect population base - insect population after application) / base before test × 100

[0110] Control effect (%) = (pest population reduction rate in pesticide treatment - insect population reduction rate in blank control area) / (100 - insect population reduction rate in blank control area) × 100

[0111] Table 10 Control effect of the insecticide composition on greenhouse whiteflies

[0112]

[0113] The test results show that the insecticide compositions listed in Table 10 have a control effect of more than 70% on cucumber whiteflies in greenhouses and do not cause any phytotoxicity to cucumbers.

[0114] Example 10: Field control effect of the insecticide composition on Plutella xylostella

[0115] This trial was conducted at the Jimo Experimental Base in Qingdao, using pakchoi as the crop. A completely randomized block design was used with four replicates per treatment. A baseline population was surveyed before treatment and live insect counts were calculated seven days after treatment. 15 L of water was used per mu (approximately 1 acre) of land. The reduction rate and control efficacy were calculated. Five sampling points were selected, with five plants surveyed at each point. The total number of Plutella xylostella larvae of each age was determined across the plant.

[0116] Insect population reduction rate (%) = (insect population base - insect population after application) / base before test × 100

[0117] Control effect (%) = (pest population reduction rate in pesticide treatment - insect population reduction rate in blank control area) / (100 - insect population reduction rate in blank control area) × 100

[0118] Table 11 Field control effect of the insecticide composition on Plutella xylostella

[0119]

[0120] The test results show that the insecticide compositions listed in Table 11 have good control effects on Plutella xylostella, with control effects ranging from 64.34% to 92.36%. No phytotoxicity was caused to Pakchoy during the test.

[0121] Example 11: Field control effect of the insecticide composition on the striped stem borer

[0122] Application was conducted during the tillering stage of rice when the sheath rate of the first-generation Chilo suppressalis borer was approximately 2%-3%. The water rate was 15 L per mu (approximately 1500 liters per acre). Each treatment was replicated three times, with each replicate covering 40 square meters. No pre-application population survey was conducted. Leaf curling was investigated 7 days after application. Twenty days after application, 25 rice clumps per plot were surveyed to calculate control efficacy.

[0123] Leaf curling rate (%) = number of curled leaves surveyed / total number of leaves surveyed × 100

[0124] Control effect (%) = (leaf curling rate in blank area after drug application - leaf curling rate in drug-treated area after drug application) / leaf curling rate in blank area × 100

[0125] Table 12 Field control effect of the insecticide composition on rice stem borer

[0126]

[0127] The test results show that the insecticide compositions listed in Table 12 have good control effects on the rice stem borer, with the leaf curl rate of each treatment being less than 11% and the control effect being 69.71%-78.91%. No adverse effects were caused to the rice during the test.

[0128] Example 12: Field control effect of the insecticide composition on tea green leafhopper

[0129] The experiment was conducted in Yangkou Tea Garden, Qingdao, Shandong Province. The experimental plot area was 40 square meters, repeated 4 times, and the water consumption per mu was 15L. Fixed points were set up in the plot. The number of nymphs on 50 young leaves was surveyed as the insect population base. The insect population was surveyed 7 days after application to calculate the insect population reduction rate and control effect.

[0130] Insect population reduction rate (%) = (insect population base - insect population after application) / base before test × 100

[0131] Control effect (%) = (pest population reduction rate in pesticide treatment - insect population reduction rate in blank control area) / (100 - insect population reduction rate in blank control area) × 100

[0132] Table 13 Field control effect of the insecticide composition on tea green leafhopper

[0133]

[0134]

[0135] The test results show that the different insecticide compositions listed in Table 13 have good control effects on tea green leafhoppers, with the reduction rate 7 days after application being higher than 70%, and the control effect is 79.95%-84.19%. In addition, during the test, the compositions did not cause any phytotoxicity to tea leaves and had no adverse effects on beneficial organisms.

[0136] Example 13 Field control effect of the insecticide composition on Tetranychus cinnabarinus

[0137] The experiment was conducted at an eggplant plantation in Jimo, Qingdao, Shandong Province, under good fertility and water conditions. Eggplants were cultivated outdoors in randomly arranged plots covering 20 square meters. Each treatment was replicated three times, with a single application. Twenty leaves were collected from each plot to count the number of mites (both adults and nymphs). Seven days after application, a survey was conducted to calculate control efficacy.

[0138] Mite reduction rate (%) = (insect population base - insect population after application) / base before test * 100

[0139] Control effect (%) = (mite reduction rate in the treatment area - mite reduction rate in the blank control area) / (100 - mite reduction rate in the blank control area) * 100

[0140] Table 14 Field control effect of the insecticide composition on Tetranychus cinnabarinus

[0141]

[0142] The test results showed that the different insecticide compositions listed in Table 14 had good control effects on Tetranychus cinnabarinus, with control rates ranging from 65.53% to 70.19% seven days after application. Furthermore, the insecticide compositions had no effect on eggplant growth and were harmless to beneficial organisms.

[0143] Preparation Example

[0144] The insecticide composition of the present invention can be prepared according to methods known to those skilled in the art.

[0145] When the insecticide composition is prepared into a suspension, in addition to the active ingredients, it also contains adjuvants such as dispersant 1% to 8% (preferably 2% to 7%), wetting agent 2% to 7% (preferably 2% to 4%), thickener 0 to 10% (preferably 1% to 5%), preservative 0 to 10% (preferably 1% to 2%), defoaming agent 1% to 10% (0.5% to 1%), antifreeze 1% to 10% (2% to 5%) and carrier deionized water to make up the balance.

[0146] Example 14: 51% A·avermectin (50:1) suspension concentrate: 50% A, 1% avermectin, 2.5% alkylnaphthalenesulfonic acid polycondensate anion sulfonate, 1.5% white carbon black, 0.5% xanthan gum, 5% ethylene glycol, 0.2% sodium benzoate, 0.5% organosilicon, and deionized water to make up the balance;

[0147] Example 15: 15% A·pyriproxyfen (2:1) suspension concentrate: 10% A, 5% pyriproxyfen, 5% alkylnaphthalenesulfonic acid condensate anion sulfonate, 0.5% silicone, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% white carbon black, 9% ethylene glycol, 0.2% sodium benzoate, and deionized water to make up the balance;

[0148] Example 16: 10% A·tebufenozide (1:1) suspension concentrate: 5% A, 5% tebufenozide, 0.6% xanthan gum, 4% alkylnaphthalenesulfonic acid condensate anion sulfonate, 0.5% silicone, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% white carbon black, 8% ethylene glycol, 0.2% sodium benzoate, and deionized water to make up the balance;

[0149] Example 17: 15% A·diflubenzuron (1:2) suspension concentrate: 5% A, 10% diflubenzuron, 5% FS3000, 1% TXC, 0.2% xanthan gum, 1% magnesium aluminum silicate, 4% ethylene glycol, 0.2% BIT, 0.3% organosilicon, and deionized water to make up the balance;

[0150] Example 18: 21% A·Cyclomef-1 (20:1) suspension concentrate: 20% A, 1% Cyclomef-1, 2% FS3000, 5% TXC, 0.2% xanthan gum, 1% magnesium aluminum silicate, 5% ethylene glycol, 0.2% BIT, 0.4% organosilicon, and deionized water to make up the balance;

[0151] Example 19: 53% A·Acetamiprid (50:3) suspension concentrate: 50% A, 3% Acetamiprid, 4% FS3000, 1% TXC, 0.5% xanthan gum, 1% magnesium aluminum silicate, 5% ethylene glycol, 0.2% 1,2-benzisothiazolin-3-one, 0.3% Silwet806, and deionized water to make up the balance;

[0152] Example 20: 15% A·sulfoxaflor (2:1) suspension concentrate: 10% A, 5% sulfoxaflor, 4% sodium salt of alkylnaphthalenesulfonic acid polycondensate, 2% Morwet EFW, 0.5% xanthan gum, 1% magnesium aluminum silicate, 5% ethylene glycol, 0.2% 1,2-benzisothiazolin-3-one, 0.3% silicone, and deionized water to make up the balance;

[0153] Example 21: 26% A·sulfoxaflor (25:1) suspension concentrate: 25% A, 1% sulfoxaflor, 0.6% xanthan gum, 4% alkylnaphthalenesulfonic acid polycondensate anion sulfonate, 0.5% silicone, 2% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% white carbon black, 9% ethylene glycol, 0.2% sodium benzoate, and deionized water to make up the balance;

[0154] Example 22: 53% A·sulfoxaflor (50:3) suspension concentrate: 50% A, 3% sulfoxaflor, 2% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% xanthan gum, 6% ethylene glycol, 3% alkylnaphthalenesulfonic acid condensate anion sulfonate, 1% organosilicon, 2% white carbon black, 0.2% sodium benzoate, and deionized water to make up the balance;

[0155] Example 23: 10% A·flunic acid slurry (1:1) suspension concentrate: 5% A, 5% flunic acid slurry, 3% alkylnaphthalenesulfonic acid polycondensate anion sulfonate, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% white carbon black, 0.2% xanthan gum, 5% ethylene glycol, 0.2% sodium benzoate, 0.5% silicone, and deionized water to make up the balance;

[0156] Example 24: 21% A·chlorfluazuron (20:1) suspension concentrate: 20% A, 1% chlorfluazuron, 4% alkylnaphthalenesulfonic acid condensate anion sulfonate, 0.3% xanthan gum, 2% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 0.5% silicone, 1.5% white carbon black, 6% ethylene glycol, 0.2% sodium benzoate, and deionized water to make up the balance;

[0157] Example 25: 15% A·Methoxyfenozide (2:1) suspension concentrate: 10% A, 5% methoxyfenozide, 4% alkylnaphthalenesulfonic acid polycondensate anion sulfonate, 1% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% white carbon black, 0.2% xanthan gum, 6% ethylene glycol, 0.2% sodium benzoate, 0.5% silicone, and deionized water to make up the balance;

[0158] Example 26: 50.2% A·cyprofenpyrad (250:1) suspension concentrate: 50% A, 0.2% cyprofenpyrad, 4% alkylnaphthalenesulfonic acid polycondensate anion sulfonate, 0.5% silicone, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% white carbon black, 9% ethylene glycol, 0.2% sodium benzoate, and 0.5% deionized water to make up the balance;

[0159] Example 27: 22% A·bifenazate (10:1) suspension concentrate: 20% A, 2% bifenazate, 5.5% alkylnaphthalenesulfonic acid condensate anion sulfonate, 0.5% xanthan gum, 0.5% silicone, 4% ethylene glycol, 2% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1.5% white carbon black, 0.2% sodium benzoate, and deionized water to make up the balance;

[0160] Example 28: 20.04% A·Bifenthrin (500:1) suspension concentrate: 20% A, 0.04% bifenthrin, 4% FS3000, 1% TXC, 0.18% xanthan gum, 1, 1% magnesium aluminum silicate, 5% ethylene glycol, 0.2% BIT, 0.3% Silwet806 synergist, and deionized water to make up the balance;

[0161] Example 29: 51% A·spirotetramat (50:1) suspension concentrate: 50% A, 1% spirotetramat, 0.6% gelatin, 4% alkylnaphthalenesulfonic acid condensate anion sulfonate, 0.5% silicone, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% white carbon black, 12% ethylene glycol, 0.2% sodium benzoate, and deionized water to make up the balance;

[0162] Example 30: 21% A·Fluoromethylpyrifos (20:1) suspension concentrate: 20% A, 1% fluoromethylpyrifos, 4% alkylnaphthalenesulfonic acid polycondensate anion sulfonate, 0.5% silicone, 2% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% white carbon black, 12% ethylene glycol, 0.2% potassium sorbate, and 1.5% deionized water to make up the balance;

[0163] Example 31: 20% A·metepid (4:1) suspension concentrate: 16% A, 4% metepid, 4% alkylnaphthalenesulfonic acid polycondensate anion sulfonate, 0.3% xanthan gum, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 0.5% silicone, 1.5% white carbon black, 6% ethylene glycol, 0.2% potassium sorbate, and deionized water to make up the balance;

[0164] Example 32: 21% A·thioflumuron (20:1) suspension concentrate: 20% A, 1% thioflumuron, 2% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% xanthan gum, 6% ethylene glycol, 3% alkylnaphthalenesulfonic acid condensate anion sulfonate, 1% organosilicon, 2% white carbon black, 0.2% sodium benzoate, and deionized water to make up the balance;

[0165] Example 33: 15% A·Bistriflumuron (1:2) suspension concentrate: 5% A, 10% bistriflumuron, 4% alkylnaphthalenesulfonic acid polycondensate anion sulfonate, 0.3% xanthan gum, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 0.5% silicone, 1.5% white carbon black, 6% ethylene glycol, 0.2% potassium sorbate, and deionized water to make up the balance;

[0166] Example 34: 22% A·Bistriflumuron (10:1) suspension concentrate: 20% A, 2% bistriflumuron, 4% alkylnaphthalenesulfonic acid polycondensate anion sulfonate, 0.3% xanthan gum, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1.5% white carbon black, 6% N, 0.2% potassium sorbate, and 1% deionized water to make up the balance;

[0167] Example 35: 18% A·Ethioxazole (5:1) suspension concentrate: 15% A, 3% etoxazole, 4% alkylnaphthalenesulfonic acid polycondensate anion sulfonate, 0.3% xanthan gum, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 0.5% silicone, 1.5% white carbon black, 6% N-methyl pyrrolidone, 0.2% sodium benzoate, and deionized water to make up the balance;

[0168] Example 36: 14% A·Isoprocarb (2:5) suspension concentrate: 4% A, 10% Isoprocarb, 4% FS3000, 1% TXC, 0.18% xanthan gum, 1% magnesium aluminum silicate, 5% ethylene glycol, 0.2% BIT, 0.3% Silwet 806 synergist, and deionized water to make up the balance;

[0169] Example 37: 22% A·Indoxacarb (10:1) suspension concentrate: 20% A, 2% indoxacarb, % urea-formaldehyde resin, 4% 0201B emulsifier, 15% S200# solvent, 15% SP682, 12% SP3262, 5% gelatin, 0.2% ethylene glycol, and deionized water to make up the balance;

[0170] Example 38: 21% A·Indoxacarb (20:1) suspension concentrate: 20% A, 1% indoxacarb, 2% Nongru 600, 8% xylene, 2% SP-682, 6% SP-326, 4% magnesium aluminum silicate, and deionized water to make up the balance;

[0171] Example 39: 10% A·tolfenpyrad (1:1) suspension concentrate: 5% A, 5% tolfenpyrad, 3% urea-formaldehyde resin, 4% 0201B emulsifier, 5% S200# solvent, 7% SP3262, 5% xanthan gum, 0.2% ethylene glycol, and deionized water to make up the balance;

[0172] Example 40: The content of each component of 20.2% A·fenpyroximate (100:1) suspension concentrate: 20% A, 0.2% fenpyroximate, 2% urea-formaldehyde resin, 5% 0201B emulsifier, 4% Nongru 600, 4% xylene, 10% SPSC29, 3% gelatin, 0.5% ethylene glycol, and deionized water to make up the balance.

[0173] When the insecticide composition is prepared into water-dispersible granules, in addition to the active ingredients, it also contains 1% to 10% (preferably 3% to 7%) of auxiliary dispersants, 1% to 10% (preferably 3% to 7%) of wetting agents, 0.5% to 10% (preferably 1% to 5%) of disintegrants, 0.5% to 10% (preferably 1% to 5%) of binders, and fillers to make up the balance.

[0174] Example 41: Formulation of 22% A·Imidacloprid (10:1) water dispersible granules: 20% A, 2% imidacloprid, 3% lignin sulfonate, 4% ammonium sulfate, and corn starch to make up the balance;

[0175] Example 42: Formulation of 53% A·Imidacloprid (50:3) water dispersible granules: 50% A, 3% imidacloprid, 5% lignin sulfonate, 5% sodium benzoate, 1% ammonium sulfate, and corn starch to make up the balance;

[0176] Example 43: Formulation of 15% A·pymetrozine (2:1) water dispersible granules: 10% A, 5% pymetrozine, 1% sodium salt of alkylnaphthalenesulfonate, 3% ammonium sulfate, and corn starch to make up the balance;

[0177] Example 44: Formulation of 18% A·pymetrozine (5:1) water dispersible granules: 15% A, 3% pymetrozine, 3% naphthalenesulfonate, 3.5% sodium benzoate, and corn starch to make up the balance;

[0178] Example 45: Formulation of 22% A·dinotefuran (10:1) water dispersible granules: 20% A, 2% dinotefuran, 4% lignin sulfonate, 4% sodium benzoate, and corn starch to make up the balance;

[0179] Example 46: Formulation of 21% A·dinotefuran (20:1) water dispersible granules: 20% A, 1% dinotefuran, 2% sodium salt of alkylnaphthalenesulfonate, 4% sodium benzoate, 1% ammonium sulfate, and corn starch to make up the balance;

[0180] Example 47: Formulation of 10.01% A·flufenacil (1000:1) water dispersible granules: 10% A, 0.01% flufenacil, 1.5% sodium naphthalenesulfonate, 2% sodium benzoate, 1% ammonium sulfate, and corn starch to make up the balance;

[0181] Example 48: Formulation of 40.2% A·Emamectin benzoate (200:1) water dispersible granules: 40% A, 0.2% emamectin benzoate, 5% sodium alkylnaphthalenesulfonate, 5% sodium benzoate, 1% ammonium sulfate, and corn starch to make up the balance;

[0182] Example 49: Formulation of 20.2% A·chlorantraniliprole (100:1) water dispersible granules: 20% A, 0.2% chlorantraniliprole, 2% lignin sulfonate, 4% ammonium sulfate, and corn starch to make up the balance;

[0183] Example 50: Formulation of 51% A·chlorantraniliprole (50:1) water dispersible granules: 50% A, 1% chlorantraniliprole, 5% sodium salt of alkylnaphthalenesulfonate, 6% ammonium sulfate, and corn starch to make up the balance;

[0184] Example 51: Formulation of 10% A·clothianidin (1:1) water dispersible granules: 5% A, 5% clothianidin, 2% lignin sulfonate, 2% ammonium sulfate, and corn starch to make up the balance;

[0185] Example 52: Formulation of 22% A·lufenuron (10:1) water dispersible granules: 20% A, 2% lufenuron, 4% lignin sulfonate, 4% ammonium sulfate, and corn starch to make up the balance;

[0186] Example 53: Formulation of 51% A·Spinetoram (50:1) water dispersible granules: 50% A, 1% spinetoram, 6% sodium salt of alkylnaphthalenesulfonate, 7% sodium benzoate, and corn starch makes up the balance.

[0187] When the insecticide composition is prepared into emulsifiable concentrate, in addition to the active ingredients, it also contains 1% to 20% (2% to 10%) of auxiliary emulsifier, and the solvent makes up the balance.

[0188] Example 52: Formula of 21% A·Profenofos (2:1) emulsifiable concentrate: 20% A, 1% Profenofos, 10% alkylphenyl polyethyl ether, and rapeseed oil to make up the balance;

[0189] Example 53: The formula of 21% A·Profenofos (2:5) emulsifiable concentrate is: 20% A, 1% Profenofos, 10% Agricultural Ru 0204, and rapeseed oil to make up the balance;

[0190] Example 54: Formula of 51% A·Profenofos (50:1) emulsifiable concentrate: 50% A, 1% Profenofos, 20% alkylphenyl polyethyl ether, and rapeseed oil to make up the balance;

[0191] Example 55: Formula of 22% A·butyronitrile (10:1) emulsifiable concentrate: 20% A, 2% butyronitrile, 10% Agricultural Ru 0204, and rapeseed oil to make up the balance;

[0192] Example 56: The formula of 18% A·butyronitrile (5:1) emulsifiable concentrate is: 15% A, 3% butyronitrile, 6% Nongru 0204, and rapeseed oil makes up the balance;

[0193] Example 57: The formula of 41% A·hexaflumuron (40:1) emulsifiable concentrate is: 40% A, 1% hexaflumuron, 15% Nongru 0204, and rapeseed oil makes up the balance;

[0194] Example 58: Formula of 20% A·triazophos (4:1) emulsifiable concentrate: 16% A, 4% triazophos, 7% alkylphenyl polyethyl ether, and rapeseed oil to make up the balance.

[0195] When the insecticide composition is prepared into a wettable powder, in addition to the active ingredients, it also contains 1% to 10% (3% to 7%) of an auxiliary dispersant, 1% to 10% (preferably 3% to 7%) of a wetting agent and fillers to make up the balance.

[0196] Example 59: Formulation of 52% A·Beta-cyhalothrin (50:2) wettable powder: 50% A, 2% Beta-cypermethrin, 2% sodium dodecylbenzenesulfonate, 10% white carbon black, 7% sodium ligninsulfonate, and light calcium carbonate to make up the balance;

[0197] Example 60: Formulation of 20% A·nitenpyram (4:1) wettable powder: 16% A, 4% nitenpyram, 3% sodium dodecylbenzenesulfonate, 15% white carbon black, 6% sodium ligninsulfonate, and light calcium carbonate to make up the balance.

Claims

1. A pesticide composition containing a pyrazolylamide insecticide, comprising component A and component B, wherein component A is Dimpropyridaz and component B is at least one active compound selected from Groups B1 to B17; B1 Carbamates: benthiocarb, benfuracarb, propoxur, butasulfuron, bendiocarb, fenthiocarb, furamicarb, methiocarb, carbaryl, pirimicarb, carbofuran, cypermethrin, methomyl, oxamyl, aldicarb, aldisulfuron, ethiofencarb, isoprocarb, fenbutylcarb, triazolam, cypermethrin, pyraclostrobin, sulfamethoxam, cypermethrin, pyraclostrobin, chlorpyrifos, chlorpyrifos, chlorpyrifos, chlorpyrifos; B2 organophosphates: trichlorfon, dichlorvos, chlorpyrifos, chlorpyrifos, parathion, diazinon, dibromophos, phosalone, methyl parathion, methyl pyrifos, methyl chlorpyrifos, methyl parathion, methyl glutamic acid, methyl pirimiphos, methyl demeton, methyl thiophos, monocrotophos, quinalphos, dimethoate, phosphamidon, cadusofos, Chlormethoate, chloroxyphos, malathion, ethoprophos, chloramidophos, triazophos, fenitrothion, fenitrothion, methiopromide, temephos, isocarbophos, mevinphos, terbufos, methoprene, phoxim, phosmet, sulfoxide, omethoate, disulfoton, azinphos-ethyl, ethion, acephate, methylpyraclofos, isoflurane, coumaphos, chlorpyrifos, azinphos-methyl, azinphos-ethyl, bromophos-ethyl, bromophenphos-ethyl, teramiphos, trisulfon, propylamidophos, pyrifos, isoflurane, methidathion; B3 Pyrethroids: s-cypermethrin, θ-cypermethrin, β-cypermethrin, phenothrin, tetrafluthrin, DDT, resmethrin, dichlorvos valerate, allethrin, pyrethrin, fluvalinate, acralthrin, flutoxin, pentothrin, iminothrin, thienthrin, flumethrin, flucythrin, flucythrin, beta-cypermethrin, triflumuron, fluvalinate, cyhalothrin, cypermethrin, phenothrin, metofluthrin, bromothrin, tetramethrin, beta-cyhalothrin, Methothrin, cypermethrin, methoprene, lambda-cyhalothrin, bifenthrin, lambda-cyhalothrin, permethrin, cypermethrin, cypermethrin, tefluthrin, fenvalerate, allethrin, imiprothrin, thiophanate, flucythrin, bioresmethrin, bioallethrin, lambda-cypermethrin, cypermethrin, transfluthrin, transfluthrin, translomethrin, fenvalerate, permethrin, cypermethrin, cypermethrin, cyfluthrin, fenfluthrin, cypermethrin, cypermethrin, fenfluthrin, cypermethrin, cypermethrin, fenfluthrin, cypermethrin, cypermethrin, pyrethrins; B4 Neonicotinoids: imidacloprid, acetamiprid, dinotefuran, sulfoxaflor, clothianidin, thiacloprid, thiamethoxam, nitenpyram, nicotine, trifluanid, nithiazine, chlorothiazolin; B5 Benzylurea: Diflubenzuron, Noviflumuron, Flufenoxuron, Flufluazuron, Fluflumuron, Flufenoxuron, Flufluuron, Triflumuron, Lufenuron, Bistriflumuron, Chlorofluanid, Flufenoxuron, Flufenoxuron, Flufenoxuron; B6 juvenile hormone analogs: fenoxycarb, pyriproxyfen, methoprene, methoprene, fenpropathrin, fenpropathrin, fenpropathrin, fenpropathrin, and methoprene; B7 Nereis toxin analogs: thiocarb, thiosulfuron, thiocarb, cartap hydrochloride; B8 avermectins: rapimectin, avermectin; B9 Biological substances, hormones or pheromones: azadirachtin, Bacillus species, Beauveria species, Metarhizium species, Paecilomyces species, Bacillus thuringiensis, Verticillium species; B10 Pyrazoles: butyronitrile, fipronil, ethiprole, acetoprole, ethioprole, flupyraclostrobin; B11 Oxadiazines: indoxacarb; B12 Organochlorine compounds: lindane, chlordane, endosulfan; B13 diamides: flubendiamide, chlorantraniliprole, cyantraniliprole, flubendiamide, fluchlorfenapyr, fluchlorfenapyr; B14 Diacylhydrazide: tebufenozide, chlorfenapyr, methoxyfenozide, chlorfenapyr; B15 Other heterocyclics: pyrimidine, pyrimethoxam, pyrimidine, pyraclostrobin, flonicamid, tolfenpyrad, chlorfenapyr, cyclafenamide, thiamethoxam, trifluoromethylpyrifos; B16 Biogenic insecticides: spinosad; B17 acaricides: acequinoxaline, fenpyroximate, benzyl cypermethrin, pyridabenzine, sulfamethoxam, bifenazate, mycomycin, cyproconazole, buprofezin, dicofol, dicofol sulfone, chlorpyrifos, bromopyralid, diclofenac, spirotetramat, spiromesifen, spirodiclofen, quinazaquin, pyridabenz, cypermethrin, fluazifop, pyrimidifen, hexythiazox, clofentezine, ivermectin, etoxazole, cyflumetofen, cyproconazole, fenbutatin, tricyclazone, triazotin.

2. The pesticide composition according to claim 1, characterized in that At least one component B of the composition is selected from B1 Carbamates: benfuracarb, carbosulfan, pirimicarb, carbofuran, chlorpyrifos, isoprocarb, fenbucarb, triazolam; B2 Organophosphates: prothiophos, profenofos, chlorpyrifos, triazophos, phoxim, and methidathion; B3 Pyrethroids: s-cypermethrin, β-cypermethrin, tetrafluthrin, pyrethrin, high-efficiency cyfluthrin, cyhalothrin, high-efficiency cyhalothrin, bifenthrin, cyfluthrin, cypermethrin, high-efficiency cypermethrin; B4 neonicotinoids: imidacloprid, acetamiprid, dinotefuran, sulfoxaflor, clothianidin, thiacloprid, thiamethoxam, nitenpyram, trifluanid; B5 benzoylureas: diflubenzuron, flufenoxuron, chlorfluazuron, hexaflumuron, triflumuron, lufenuron, bistriflumuron; B6 juvenile hormone mimetics: pyriproxyfen and methoprene; B7 Nereis toxin analogs: cypermethrin, dimethoate, cartap hydrochloride; B9 Biological substances, hormones or pheromones: Bacillus thuringiensis, Verticillium species; B10 Pyrazoles: butyronitrile, fipronil, ethiprole; B11 Oxadiazines: indoxacarb; B12 Organochlorine compounds: chlordane; B13 diamides: flubendiamide, chlorantraniliprole, cyantraniliprole, flubendiamide, flufenamid, flufenamid, flufenamid; B14 Diacylhydrazide: tebufenozide, chlorfenapyr, methoxyfenozide, chlorfenapyr; B15 Other heterocyclic compounds: pymetrozine, butyronitrile, fipronil, ethiprole, flonicamid, tolfenpyrad, chlorfenapyr, trifluoromethylpyrifos; B16 Biogenic insecticides: spinosad; B17 acaricides: cypermethrin, pyridabenz, bifenazate, cyproconazole, thiamethoxam, spirotetramat, spiromesifen, spirodiclofen, pyridabenz, etoxazole, butyrocyprodinil, and cyproconazole.

3. The pesticide composition according to claim 1, characterized in that At least one component B of the composition is selected from pyriproxyfen, imidacloprid, pymetrozine, profenofos, tebufenozide, diflubenzuron, butyronitrile, butyflumetofen, acetamiprid, dinotefuran, flufenoxuron, sulfoxaflor nitrile, flonicamid, chlorfluazuron, hexaflumuron, fluchlorfenuron, cyhalothrin, methoxyfenozide, cypermethrin, pirimicarb, bifenazate, bifenthrin, spirotetramat, chlorantraniliprole, chlorfenapyr, propargyl, clothianidin, thiamethoxam, triflubenzuron, trifluoromethylpyralid, triazophos, dimesulfuron, triflumuron, lufenuron, bistrifluan, nitenpyram, ethiprole, etoxazole, isoprocarb, indoxacarb, tolfenpyrad, and cypermethrin.

4. The pesticide composition according to claim 1, characterized in that The weight ratio of component A to component B is 0.1:100 to 100:0.1, preferably the mass ratio is 1:12 to 100:0.1, and more preferably 1:4 to 100:

1.

5. The pesticide composition according to any one of claims 1 to 3, characterized in that The mass ratio of the active component A to pyriproxyfen is 1:2 to 2:1, the mass ratio of the active component A to imidacloprid is 2:5 to 50:1, the mass ratio of the active component A to pymetrozine is 5:2 to 10:1, the mass ratio of the active component A to profenofos is 1:1 to 50:1, the mass ratio of the active component A to tebufenozide is 1:4 to 1:1, the mass ratio of the active component A to diflubenzuron is 1:8 to 1:2, the mass ratio of the active component A to butyronitrile is 5:2 to 10:1, the mass ratio of the active component A to butyclohexene is 5:1 to 20:1, the mass ratio of the active component A to acetamiprid is 25:3 to 100:3, the mass ratio of the active component A to dinotefuran is 1:5 to 20:1, and the mass ratio of the active component A to flufenoxuron is 1:

1. The mass ratio of the active component A to sulfoxaflor is 1:5-50:1, the mass ratio of the active component A to flonicamid is 2:5-2:1, the mass ratio of the active component A to chlorfluanid is 10:1-50:1, the mass ratio of the active component A to hexaflumuron is 10:1-40:1, the mass ratio of the active component A to flufenacet is 100:0.5-100:0.1, the mass ratio of the active component A to high-efficiency chlorflucythrinate is 25:4-25:1, the mass ratio of the active component A to methoxyfenozide is 1:2-2:1, the mass ratio of the active component A to cypermethrin is 25:0.2-50:0.1, the mass ratio of the active component A to pirimicarb is 5:2-10:1, the mass ratio of the active component A to biphenyl is 2:1-3:

1. The mass ratio of the active component A to chlorfenapyr is 2:1 to 100:0.1, the mass ratio of the active component A to spirotetramat is 25:2 to 50:1, the mass ratio of the active component A to chlorantraniliprole is 25:1 to 100:1, the mass ratio of the active component A to propargyl is 5:2 to 10:1, the mass ratio of the active component A to clothianidin is 1:2 to 20:1, the mass ratio of the active component A to thiamethoxam is 5:1 to 20:1, the mass ratio of the active component A to trifluralin is 4:1 to 50:1, the mass ratio of the active component A to trifluoromethylpyrifos is 5:1 to 20:1, the mass ratio of the active component A to triazophos is 1:1 to 4:1, and the mass ratio of the active component A to dimehypo is 1:2 to 20:

1. The mass ratio of the active component A to triflumuron is 1:1 to 4:1, the mass ratio of the active component A to triflumuron is 5:1 to 20:1, the mass ratio of the active component A to lufenuron is 5:2 to 10:1, the mass ratio of the active component A to bistrifluanyl is 1:4 to 10:1, the mass ratio of the active component A to nitenpyram is 2:1 to 20:1, the mass ratio of the active component A to ethiprole is 2:1 to 10:1, the mass ratio of the active component A to etoxazole is 25:1 to 100:1, the mass ratio of the active component A to isoprocarb is 2:5 to 5:2, the mass ratio of the active component A to indoxacarb is 5:2 to 50:1, the mass ratio of the active component A to tolfenpyrad is 1:2 to 2:1, and the mass ratio of the active component A to pyraclostrobin is 25:1 to 100:

1.

6. The pesticide composition according to claim 1, characterized in that The total weight of component A and component B accounts for 1% to 90% of the total weight of the composition, preferably 10% to 70%.

7. The pesticide composition according to claim 1, characterized in that The pesticide composition also contains pesticide-usable adjuvants and carriers.

8. A pesticide composition comprising the pyrazolecarboxamide insecticide according to any one of claims 1 to 7, which can be used in a method for curatively or preventively controlling pests.

9. The method according to claim 8, characterized in that The pesticide composition can be applied to seeds, plants and / or to plant fruits by seed treatment, foliar application, or drip irrigation.

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