Pesticide composition containing pyrazolecarboxamide insecticide and application thereof

Abstract

The invention discloses a pesticide composition containing a pyrazolecarboxamide pesticide and application of the pesticide composition. The pesticide composition comprises an active component A which is the pyrazolecarboxamide pesticide and a component B which is at least one other pesticide defined in the specification, specifically, the invention relates to a pesticide composition for preventing and treating common lepidoptera, coleoptera, diptera, thysanoptera and homoptera pests of plants.

Description

[0001] This invention application is a divisional application of application number CN202510719896.7, filed on December 21, 2020, entitled "A pesticide composition containing pyrazole carbamide insecticide and its application". Technical Field

[0002] This invention relates to pesticide compositions containing pyrazole carboxamide insecticides and methods for applying said compositions. Background Technology

[0003] Dimpropyridaz is a pyrazole carboxamide insecticide developed by BASF. Its chemical name is 1-(1,2-dimethylpropyl)-N-ethyl-5-methyl-N-pyridazin-4-yl-pyrazole-4-carboxamide, CAS number 1403615-77-9, and its structural formula is as follows: .

[0004] Dimpropyridaz is an effective pesticide against aphids, whiteflies, thrips, leafhoppers, and diamondback moths in the orders Hemiptera, Coleoptera, Diptera, Thysanoptera, and Lepidoptera.

[0005] International patent application WO2012143317 discloses pyrazole carboxamide derivatives and their use as insecticides. However, the application does not specifically mention possible insecticidal compositions or the weight ratio of pyrazole carboxamide insecticides to other insecticide components in the composition.

[0006] International patent application WO2013189801 discloses pyrazole compounds and pesticide mixtures containing pyrazole compounds. This patent simply discloses the method and use of mixing the pyrazole compound with a portion of an insecticide for the control of invertebrate pests, without mentioning the specific type of combined action of the composition on the control of a particular pest.

[0007] In the field of pesticides, novel pesticide compositions with synergistic insecticidal effects are frequently used to delay the development of pesticide resistance in pests while minimizing the environmental impact of pesticides. Summary of the Invention

[0008] This invention provides a pesticide composition containing a pyrazole carboxamide insecticide and another known insecticide. It can be used to control common pests of the orders Homoptera, Coleoptera, Diptera, Thysanoptera, and Lepidoptera, such as aphids, whiteflies, leafhoppers, thrips, and diamondback moths, on fruit trees, vegetables, grain crops, and tea plants. This insecticide composition exhibits synergistic insecticidal activity and can meet the needs of agricultural production.

[0009] The insecticidal composition of the present invention comprises active component A and active component B.

[0010] Furthermore, active component A is Dimpropyridaz, and active component B is at least one insecticidal compound selected from B1-B17.

[0011] B1 carbamates: benzothiocarb, carbofuran, propoxur, carbofuran, oxadiazon, imidacloprid, furazolidone, methyl thiocarb, carbofuran, pymetrozine, methomyl, thiamethoxam, aldicarb, aldicarb, ethylbenzylcarb, isopropylcarb, sec-butylcarb, azoxystrobin, fenvalerate, methylbenzyl, methamidophos, methamidophos, methamidophos, methamidophos, methamidophos, methamidophos, methamidophos, methamidophos, methamidophos, methamidophos, methamidophos, methamidophos.

[0012] B2 Organophosphates: Ammonium sulfadiazine, Phosphate, Fenthion, Benzoate, Phosphamidon, Pyrazophos, Propyrazophos, Propyrazophos, Phosphamidon, Pyrazazin, Dichlorvos, Dichlorvos, Chlorpyrifos, Parathion, Diazinon, Dibromophos, Phosphamidon, Methamidophos, Phosphamidon, Methylpyridinium phosphate, Methyl chlorpyrifos, Methyl parathion, Methyl glutamic acid, Methyl pyrimidinium phosphate, Methyl demeton-methyl, Methyl ethion, Monocrotophos, Quinalphos, Dimethoate, Phosphamidon, Thiophanate-methyl Phosphorus oxychloride, malathion, phosmet, phosmet, triazophos, fenitrothion, phosmet, chlorpyrifos, dimethoate, methamidophos, methamidophos, terbufos, phorate, phorate, phosmet, phosmet, sulfonylurea, dimethoate, phorate, ethyl glutathione, ethion, acephate, methyl pyrazophos, isofenphos, phosmet, phosmet, phosmet, ethyl bromide, bromophenylenephos, pyrimiphos, trithion, propionylphos, pyriflumethrin, isofenphos, phosmet, chlorpyrifos, chlorpyrifos, chlorpyrifos, chlorpyrifos, chlorpyrifos, chlorpyrifos, chlorpyrifos, chlorpyrifos.

[0013] B3 Pyrethroids: s-cypermethrin, θ-cypermethrin, β-cypermethrin, abamectin, deltamethrin, tetraflufenoxam, DDT, cypermethrin, dichlorvos, allethrin, pyrethrin, lambda-cyhalothrin, flufenoxuron, flufenoxuron, pendiflubenzuron, imidacloprid, thiamethoxam, flufenoxuron, deltamethrin, cypermethrin, lambda-cyhalothrin, triflufenoxuron, flufenoxuron, cypermethrin, pyrethroid, deltamethrin, methoxyfenozide, bromoflufenoxuron, methoxyfenozide, cypermethrin, cypermethrin Pyrethroids, methoxyfenozide, cypermethrin, methoxybenzylfenozide, high-efficiency cyhalothrin, bifenthrin, cyhalothrin, permethrin, cypermethrin, fenpyrethrin, cypermethrin, fenvalerate, fenvalerate, fenvalerate, fenvalerate, thiamethoxam, trifluralin, bio-benzylfenozide, bio-allethrin, high-efficiency cyhalothrin, cyclopentylfenozide, cypermethrin, tetrafluorobenzylfenozide, tetrafluoromethoxyfenozide, tetrabromopyrethrin, fenvalerate, bromopyrethrin, deltamethrin, cypermethrin, cypermethrin, pyrethrin, anti-pyrethroid, bromocypermethrin, pyrethrin.

[0014] B4 neonicotinoids: imidacloprid, acetamiprid, dinotefuran, flonicamid, thiamethoxam, thiamethoxam, acetamiprid, nicotine, trifluorophenylpyrimidine, nitenthiamethoxam, chlorothiazoline.

[0015] B5 Benzoylurea: Diflubenzuron, Polyfluorourea, Fipronil, Flufenoxuron, Flufenoxuron, Flufenoxuron, Flufenoxuron, Lufenuron, Diflubenzuron, Chlorflufenoxuron, Flufenoxuron, Flufenoxuron, Flufenoxuron.

[0016] B6 juvenile hormone mimics: phenoxycarb, pyriproxyfen, acetamiprid, acetamiprid ethyl ester, acetamiprid ester, acetamiprid ether, acetamiprid thiocyanate; B7 nereistoxin analogs: chlorfenapyr, chlorfenapyridine, chlorfenapyr hydrochloride.

[0017] B8 insecticides: abamectin, emamectin benzoate, ribavirin, emamectin benzoate.

[0018] B9 biological substances, hormones, or pheromones: azadirachtin, Bacillus species, Beauveria bassiana species, Metarhizium anisopliae species, Paecilomyces species, Bacillus thuringiensis, Verticillium species.

[0019] B10 pyrazoles: tebufenozide, fipronil, acetamiprid, thiophanate-methyl, flupyrazole.

[0020] B11 oxadiazines: indoxacarb.

[0021] B12 organochlorine compounds: lindane, chlordane, thiodine.

[0022] B13 diamides: flubendiamide, chlorantraniliprole, bromonitrile cyanamide, flubendiamide, flubendiamide, flubendiamide.

[0023] B14 dihydrazides: tebufenozide, cyclotebufenozide, methoxyfenozide, chlorfenapyr.

[0024] Other heterocyclic compounds in B15 include: pyridaben, pyrifluquinazon, pymetrozine, tebufenozide, pyridaben, fipronil, acetamiprid, flonicamid, acetamiprid, indoxacarb, bromfenac, cycloneprole, pyrimethanil, and trifluralin.

[0025] B16 biological insecticides: spinosad, ethyl spinosad.

[0026] B17 acaricides: Acaricides such as fenpropathrin, fenpropathrin, fenpropathrin, pyridaben, sulfadiazine, bifenazate, micaben, propargite, thiamethoxam, trichlorfon, trichlorfon sulfone, fenpropathrin, bromodifen, difenoconazole, spirotetramat, spirodiclofen, quinacrine, pyridaben, pyridaben, flufenoxuron, pyrimethanil, thiamethoxam, tetradifon, ivermectin, etoxazole, diflubenzuron, cyprodinil, fenbutatin, tricyclic tin, triazole tin.

[0027] When the active components in the insecticidal composition of the present invention are present in a specific mass ratio, the synergistic effect is very significant. The mass ratio of active component A to active component B is 0.1:100 to 100:0.1, preferably 1:12 to 100:0.1, and even more preferably 1:4 to 100:1.

[0028] Furthermore, the mass ratio of active component A to abamectin is 25:1 to 100:1, the mass ratio of active component A to pyriproxyfen is 1:2 to 2:1, the mass ratio of active component A to imidacloprid is 2:5 to 50:1, the mass ratio of active component A to pymetrozine is 5:2 to 10:1, the mass ratio of active component A to profenofos is 1:1 to 50:1, and the mass ratio of active component A to tebufenozide is 1:4 to 1:1. The mass ratio of active component A to diflubenzuron is 1:8 to 1:2; the mass ratio of active component A to tebufenozide is 5:2 to 10:1; the mass ratio of active component A to fenflurfen is 5:1 to 20:1; the mass ratio of active component A to acetamiprid is 25:3 to 100:3; the mass ratio of active component A to fipronil is 1:5 to 20:1; the mass ratio of active component A to flufenoxuron is 1:12 to 1:4; the mass ratio of active component A to flufenoxuron... The mass ratios are as follows: active component A to flupyradifurone is 1:5 to 50:1; active component A to flufenoxuron is 2:5 to 2:1; active component A to flufenoxuron is 10:1 to 50:1; active component A to flufenoxuron is 10:1 to 40:1; active component A to fluchlorfenapyr is 100:0.5 to 100:0.1; active component A to lambda-cyhalothrin is 25:4 to 25:1. The mass ratio of active ingredient A to abamectin is 50:1 to 100:0.5; the mass ratio of active ingredient A to methoxyfenozide is 1:2 to 2:1; the mass ratio of active ingredient A to cypermethrin is 25:0.2 to 50:0.1; the mass ratio of active ingredient A to pirimicarb is 5:2 to 10:1; the mass ratio of active ingredient A to bifenazate is 5:2 to 10:1; and the mass ratio of active ingredient A to bifenthrin is 2:1 to 100:0.1. The mass ratio of active ingredient A to spirotetramat is 25:2–50:1; the mass ratio of active ingredient A to chlorantraniliprole is 25:1–100:1; the mass ratio of active ingredient A to propargite is 5:2–10:1; the mass ratio of active ingredient A to thiamethoxam is 1:2–20:1; the mass ratio of active ingredient A to thiamethoxam is 5:1–20:1; the mass ratio of active ingredient A to trifluralin is 4:1–50:1; the mass ratio of active ingredient A to trifluralin is 5:1–20:1; the mass ratio of active ingredient A to triazophos is 1:1–4:1; the mass ratio of active ingredient A to cartap is 1:1–4:1; and the mass ratio of active ingredient A to chlorfenapyr is 5:1–20:1. The mass ratios of active component A to lufenuron are 5:2–10:1; the mass ratio of active component A to bispyribac-sodium is 1:4–10:1; the mass ratio of active component A to acetamiprid is 2:1–20:1; the mass ratio of active component A to acetamiprid is 2:1–10:1; the mass ratio of active component A to spinosad is 25:2–50:1; the mass ratio of active component A to etoxazole is 25:1–100:1; the mass ratio of active component A to isoprocarb is 2:5–5:2; the mass ratio of active component A to indoxacarb is 5:2–50:1; the mass ratio of active component A to acetamiprid is 1:2–2:1; and the mass ratio of active component A to azoxystrobin is 25:1–100:1.

[0029] Furthermore, the mass ratio of active component A to abamectin is 25:1–50:1; the mass ratio of active component A to pyriproxyfen is 1:1–2:1; the mass ratio of active component A to imidacloprid is 10:1–50:1; the mass ratio of active component A to pymetrozine is 5:1–10:1; the mass ratio of active component A to profenofos is 4:1–50:1; the mass ratio of active component A to tebufenozide is 1:2–1:1; the mass ratio of active component A to diflubenzuron is 1:8–1:2; the mass ratio of active component A to tebufenozide is 5:1–10:1; the mass ratio of active component A to fenflurfen is 10:1–20:1; the mass ratio of active component A to acetamiprid is 50:3–100:3; and the mass ratio of active component A to dinotefuran is 2:5–20:1. 1. The mass ratio of active component A to flufenoxuron is 1:12 to 1:6; the mass ratio of active component A to flonicamid is 1:5 to 25:3; the mass ratio of active component A to flonicamid is 2:5 to 4:5; the mass ratio of active component A to flonicamid is 20:1 to 50:1; the mass ratio of active component A to flufenoxuron is 20:1 to 40:1; the mass ratio of active component A to fluchlorfenapyr is 100:0.5 to 100:0.1; the mass ratio of active component A to lambda-cyhalothrin is 25:2 to 25:1; the mass ratio of active component A to abamectin is 100:1 to 100:0.5; the mass ratio of active component A to methoxyfenozide is 1:1 to 2:1; and the mass ratio of active component A to cypermethrin is 50:0.2 to 50:0.1. The mass ratio of active ingredient A to pirimicarb is 5:2 to 5:1; the mass ratio of active ingredient A to bifenazate is 5:1 to 10:1; the mass ratio of active ingredient A to bifenthrin is 4:1 to 10:1; the mass ratio of active ingredient A to spirotetramat is 25:1 to 50:1; the mass ratio of active ingredient A to chlorantraniliprole is 50:1 to 100:1; the mass ratio of active ingredient A to propargite is 5:1 to 10:1; the mass ratio of active ingredient A to thiamethoxam is 1:2 to 1:1; the mass ratio of active ingredient A to thiamethoxam is 5:1 to 20:1; the mass ratio of active ingredient A to trifluralin is 4:1 to 50:1; the mass ratio of active ingredient A to trifluralin is 10:1 to 20:1; the mass ratio of active ingredient A to triazophos is 1:1 to 4:1; the mass ratio of active ingredient A to chlorpyrifos is... The mass ratios of active components are as follows: 2:1 to 4:1; 5:1 to 10:1; 5:1 to 10:1; 1:2 to 10:1; 2:1 to acetamiprid; 2:1 to 5:1; 25:2 to 50:1; 25:1 to 100:1; 2:5 to 5:2; 5:2 to 20:1; 1:2 to 2:1; and 25:1 to 100:1.

[0030] Furthermore, the mass ratios of active component A to abamectin are 50:1, 25:1, 100:1, and 50:1; the mass ratios of active component A to pyriproxyfen are 1:2 and 2:1; the mass ratios of active component A to imidacloprid are 10:1, 5:1, 20:1, 1:1, 2:5, 5:2, 25:1, 25:3, 50:1, and 50:3; the mass ratios of active component A to pymetrozine are 4:1, 2:1, 10:1, 5:1, and 5:2; and the mass ratios of active component A to profenofos are 5:1, 5:2, 25:4, 2:1, 1:1, 4:1, 2:1, 25:2, and 5:5. 0:1, 25:1; the mass ratio of active component A to tebufenozide is 1:2, 1:4, 1:1, 50:1; the mass ratio of active component A to diflubenzuron is 1:8, 1:2, 1:4; the mass ratio of active component A to tebufenozide is 5:2, 10:1, 5:1; the mass ratio of active component A to fenflurfen is 5:1, 20:1, 10:1; the mass ratio of active component A to acetamiprid is 25:3, 100:1.5, 50:3; the mass ratio of active component A to dinotefuran is 10:1, 5:1, 20:1, 2:5, 1:5, 1:1, 1:2, 5:2; the mass ratio of active component A to dinotefuran is 1:2, 5:1, 2:5, 1:5, 1:1, 1:2, 5:2; the mass ratio of active component A to dinotefuran is 1:2, 5:1, 2:1, 2:5, 1:5, 1:1, 1:2, 5:2; the mass ratio of active component A to dinotefuran is 1:8, 1:2, 1:4 ...1, 1:2, 5:1; the mass ratio of active component A to dinotefuran is 1:8, 1:1, 1:2, 5:1; the mass ratio of The mass ratios of flufenoxuron are 1:8, 1:12, 1:4, and 1:6; the mass ratios of active component A to flonicamid are 1:1, 1:2, 2:1, 2:5, 1:5, 25:1, 25:2, 50:1, 25:3, 25:6, 50:3, and 4:5; the mass ratios of active component A to flufenoxuron are 25:1, 10:1, 50:1, 40:1, and 20:1; the mass ratios of active component A to flufenoxuron are 50:0.1, 100:1, 100:0.1, and 100:0.5; and the mass ratios of active component A to lambda-cyhalothrin are 25:4 and 25:1. The mass ratios of active component A to abamectin are 25:2, 50:1, 100:0.5, and 100:1; the mass ratios of active component A to methoxyfenozide are 1:2, 2:1, and 1:1; the mass ratios of active component A to cypermethrin are 25:0.1, 125:1, and 50:0.1; the mass ratios of active component A to pirimicarb are 5:1, 5:2, and 10:1; the mass ratios of active component A to bifenazate are 5:1, 5:2, and 10:1; and the mass ratios of active component A to bifenthrin are 5:1, 2:1, 10:1, 4:1, 50:0.1, 25:0.1, and 100:0.1. The mass ratio of active component A to spirotetramat is 25:1, 25:2, and 50:1; the mass ratio of active component A to chlorantraniliprole is 50:1, 25:1, 100:1, and 50:1; the mass ratio of active component A to propargite is 5:1, 5:2, and 10:1; the mass ratio of active component A to thiamethoxam is 1:1, 1:2, 5:2, 5:4, 20:1, and 10:1; the mass ratio of active component A to thiamethoxam is 5:1, 20... The mass ratios of active ingredient A to trifluoropyrimidine are 1, 10:1, 20:1, 4:1, 50:1, and 10:1; the mass ratios of active ingredient A to trifluralin are 5:1, 20:1, and 10:1; the mass ratios of active ingredient A to triazophos are 1:1, 4:1, and 2:1; the mass ratios of active ingredient A to cartap are 1:1, 4:1, and 2:1; the mass ratios of active ingredient A to chlorpyrifos are 10:1, 5:1, and 20:1. The mass ratios of active component A to lufenuron are 5:1, 5:2, and 10:1; the mass ratios of active component A to bispyribac-sodium are 1:2, 1:4, 1:1, 5:2, 10:1, and 5:1; the mass ratios of active component A to acetamiprid are 4:1, 2:1, 8:1, 2:1, 5:1, 20:1, and 10:1; the mass ratios of active component A to acetamiprid are 4:1, 2:1, 10:1, and 5:1; and the mass ratio of active component A to spinosad is 25. The mass ratios of active component A to etoxazole are 25:1, 100:1, and 50:1; the mass ratios of active component A to isoprocarb are 2:5, 5:2, and 1:1; the mass ratios of active component A to indoxacarb are 10:1, 5:1, 20:1, and 5:2; the mass ratios of active component A to acetamiprid are 1:2, 2:1, and 1:1; and the mass ratios of active component A to azoxystrobin are 25:1, 100:1, and 50:1.

[0031] When the composition of the present invention is used to control peach aphids, the mass ratio of active component A to pirimicarb is 5:1, 5:2, or 10:1; the mass ratio of active component A to lambda-cyhalothrin is 25:4, 25:1, or 25:2; the mass ratio of active component A to bifenthrin is 25:0.1, 100:0.1, or 50:0.1; the mass ratio of active component A to imidacloprid is 25:1, 25:3, 50:1, or 50:3; and the mass ratio of active component A to acetamiprid is... The mass ratios are 50:3, 25:3, and 100:3; the mass ratios of active component A to fipronil are 5:1, 20:1, and 10:1; the mass ratios of active component A to flonicamid are 50:1 and 25:1; the mass ratios of active component A to thiamethoxam are 5:1, 20:1, and 10:1; the mass ratios of active component A to thiamethoxam are 5:1, 20:1, and 10:1; and the mass ratios of active component A to acetamiprid are 5:1, 20:1, and 10:1. The mass ratio of active component A to pymetrozine is 5:2, 10:1, or 5:1; the mass ratio of active component A to flonicamid is 25:6, 50:3, or 25:3; preferably, the mass ratio of active component A to lambda-cyhalothrin is 25:4, 25:1, or 25:2; the mass ratio of active component A to bifenthrin is 25:0.1, 100:0.1, 50:0.1, or 50:3; and the mass ratio of active component A to acetamiprid is 50:3. The mass ratios of active component A to fipronil are 5:1, 20:1, and 10:1; the mass ratio of active component A to flonicamid is 25:1; the mass ratio of active component A to thiamethoxam is 10:1; the mass ratio of active component A to thiamethoxam is 10:1; the mass ratio of active component A to acetamiprid is 20:1; the mass ratio of active component A to pymetrozine is 5:1; and the mass ratio of active component A to flonicamid is 50:3 and 25:3.

[0032] When the composition of the present invention is used to control rice planthoppers, the mass ratio of active component A to isoprocarb is 1:1, 2:5, or 5:2; the mass ratio of active component A to profenofos is 5:1, 5:2, 25:2, or 25:4; the mass ratio of active component A to imidacloprid is 2:5, 5:2, or 1:1; the mass ratio of active component A to dinotefuran is 2:5, 1:5, 1:1, or 1:2; the mass ratio of active component A to flonicamid is 2:5, 1:5, 1:1, or 1:2; the mass ratio of active component A to thiamethoxam is 1:1, 1:2, 5:2, or 5:4; the mass ratio of active component A to acetamiprid is 4:1, 2:1, 10:1, or 5:1; and the mass ratio of active component A to trifluralin is... The mass ratios are 20:1, 4:1, 50:1, and 10:1; the mass ratios of active component A to acetamiprid are 4:1, 2:1, 10:1, and 5:1; the mass ratios of active component A to pymetrozine are 4:1, 2:1, 10:1, and 5:1; and the mass ratios of active component A to flonicamid are 4:5, 2:5, 2:1, and 1:1. Preferably, the mass ratios of active component A to isoprocarb are 1:1 and 2:5; the mass ratios of active component A to profenofos are 5:1 and 25:2; the mass ratio of active component A to thiamethoxam is 1:1; the mass ratios of active component A to pymetrozine are 4:1 and 2:1; and the mass ratios of active component A to flonicamid are 4:5, 2:5, 2:1, and 1:1.

[0033] When the composition of the present invention is used to control whiteflies, the mass ratio of active component A to flonicamid is 1:2, 2:1, or 1:1; the mass ratio of active component A to bis(triflufenoxuron) is 1:4, 1:1, or 1:2; and the mass ratio of active component A to pyriproxyfen is 1:2, 2:1, or 1:1. Preferably, the mass ratio of active component A to flonicamid is 2:1 or 1:1; the mass ratio of active component A to bis(triflufenoxuron) is 1:4 or 1:2; and the mass ratio of active component A to pyriproxyfen is 2:1 or 1:1.

[0034] When the composition of the present invention is used to control diamondback moth, the mass ratio of active component A to profenofos is 25:2, 50:1, and 25:1; the mass ratio of active component A to diflubenzuron is 1:8, 1:2, and 1:4; the mass ratio of active component A to flufenoxuron is 10:1, 50:1, and 20:1; the mass ratio of active component A to flufenoxuron is 10:1, 40:1, and 20:1; the mass ratio of active component A to chlorfenapyr is 5:1, 20:1, and 10:1; the mass ratio of active component A to dicofol is 5:2, 10:1, and 5:1; and the mass ratio of active component A to diflubenzuron is 5:2, 10:1, and 5:1. The mass ratios of active component A to abamectin are 25:1, 100:1, and 50:1; the mass ratios of active component A to emamectin benzoate are 10:1, 50:1, 50:0.1, and 100:1; the mass ratios of active component A to indoxacarb are 5:2, 10:1, and 5:1; the mass ratios of active component A to chlorantraniliprole are 25:1, 100:1, and 50:1; the mass ratios of active component A to fluchlorfenapyr are 100:1, 100:0.1, and 20:0.1; the mass ratios of active component A to tebufenozide are 1:20, 1:4, 1:1, and 1:2; and the mass ratios of active component A to methoxyfenozide are 1:2 and 2:1. The mass ratios of active component A to azoxystrobin are 1:1, 1:2, 2:1, and 1:1; the mass ratios of active component A to ethyl spinosad are 25:2, 50:1, and 25:1; the mass ratios of active component A to tebufenozide are 5:2, 10:1, and 5:1; and the mass ratios of active component A to trifluralin are 5:1, 20:1, and 10:1. Preferably, the mass ratios of active component A to profenofos are 50:1 and 25:1; the mass ratios of active component A to diflubenzuron are 1:2 and 1:4; the mass ratios of active component A to flufenoxuron are 50:1 and 20:1; and the mass ratios of active component A to flufenoxuron are 40:1 and 20:1. The mass ratios of active component A to chlorfenapyr are 20:1 and 10:1; the mass ratios of active component A to lufenuron are 5:2, 10:1, and 5:1; the mass ratios of active component A to bispyribac-sodium are 10:1 and 5:1; the mass ratios of active component A to abamectin are 25:1, 100:1, and 50:1; the mass ratios of active component A to emamectin benzoate are 50:1, 50:0.1, and 100:1; the mass ratios of active component A to indoxacarb are 10:1 and 5:1; the mass ratios of active component A to chlorantraniliprole are 100:1 and 50:1; and the mass ratios of active component A to fluchlorantraniliprole are 100:0.1 and 20:0.1. The mass ratio of active component A to tebufenozide is 1:1 and 1:2; the mass ratio of active component A to methoxyfenozide is 2:1 and 1:1; the mass ratio of active component A to azoxystrobin is 1:2, 2:1, and 1:1; the mass ratio of active component A to spinosad is 50:1 and 25:1; the mass ratio of active component A to tebufenozide is 10:1 and 5:1; and the mass ratio of active component A to trifluralin is 5:1, 20:1, and 10:1.

[0035] When the composition of the present invention is used to control rice stem borers, the mass ratio of active component A to profenofos is 2:1, 1:1, or 4:1; the mass ratio of active component A to triazophos is 2:1, 1:1, or 4:1; the mass ratio of active component A to dinotefuran is 5:2, 10:1, or 5:1; the mass ratio of active component A to cartap is 1:1, 4:1, or 2:1; the mass ratio of active component A to tebufenozide is 5:2, 10:1, or 5:1; the mass ratio of active component A to chlorantraniliprole is 50:1, 25:1, 100:1, or 50:1; and the mass ratio of active component A to flufenoxuron is 50:0.1 or 100:1. The preferred ratios are 100:0.1 and 20:0.1; the preferred ratios are as follows: active component A to profenofos at 2:1 and 4:1; active component A to triazophos at 2:1 and 4:1; active component A to fipronil at 5:2, 10:1, and 5:1; active component A to cartap at 4:1 and 2:1; active component A to tebufenozide at 10:1 and 5:1; active component A to chlorantraniliprole at 50:1, 25:1, 100:1, and 50:1; and active component A to fluchlorfenapyr at 50:0.1, 100:1, 100:0.1, and 20:0.1.

[0036] When the composition of the present invention is used to control the tea green leafhopper, the mass ratio of active component A to bifenthrin is 5:1, 2:1, 10:1, or 4:1; the mass ratio of active component A to imidacloprid is 10:1, 5:1, or 20:1; the mass ratio of active component A to dinotefuran is 5:1, 20:1, or 10:1; the mass ratio of active component A to acetamiprid is 2:1, 8:1, or 4:1; and the mass ratio of active component A to indoxacarb is 5:1, 20:1, or 10:1. Preferably, the mass ratio of active component A to imidacloprid is 10:1 or 20:1; the mass ratio of active component A to dinotefuran is 5:1, 20:1, or 10:1; the mass ratio of active component A to acetamiprid is 4:1; and the mass ratio of active component A to indoxacarb is 20:1.

[0037] When the composition of the present invention is used to control *Tetranychus carmine*, the mass ratio of active component A to flufenoxuron is 1:8, 1:12, 1:4, or 1:6; the mass ratio of active component A to abamectin is 50:1, 25:1, or 100:1; the mass ratio of active component A to bifenazate is 5:1, 5:2, 10:1, or 5:1; the mass ratio of active component A to propargite is 5:2, 10:1, or 5:1; the mass ratio of active component A to etoxazole is 50:1, 25:1, or 100:1; the mass ratio of active component A to diflubenzuron is 5:1, 20:1, or 10:1; and the mass ratio of active component A to cyprodinil is... The preferred ratios are: 25:0.2, 50:0.1, and 25:0.1; the mass ratio of active component A to spirotetramat is 25:2, 50:1, and 25:1; preferably, the mass ratio of active component A to abamectin is 50:1 and 100:1; the mass ratio of active component A to bifenazate is 10:1 and 5:1; the mass ratio of active component A to propargite is 5:1; the mass ratio of active component A to dicofol is 20:1 and 10:1; the mass ratio of active component A to cyprodinil is 25:0.2, 50:0.1, and 25:0.1; and the mass ratio of active component A to spirotetramat is 25:2, 50:1, and 25:1.

[0038] In the insecticidal composition of the present invention, the total amount of active component A and active component B, by mass percentage, is 1% to 90%, preferably 10% to 70%.

[0039] The insecticidal composition of the present invention also contains pesticide formulation adjuvants and carriers.

[0040] The insecticidal composition of the present invention can be used to control pests of the Lepidoptera, Coleoptera, Diptera, Thysanoptera, and Homoptera orders.

[0041] The insecticidal composition of the present invention is particularly useful for controlling pests of the Thysanoptera and Homoptera, especially Homoptera pests.

[0042] The insecticidal composition of the present invention has the following significant advantages compared with the prior art: 1. The insecticidal composition of the present invention has a significant synergistic effect, which can reduce the number of applications and the amount of a single agent required.

[0043] 2. The insecticidal composition of the present invention is active against all life stages of pests.

[0044] 3. The insecticidal composition of the present invention is composed of effective components with different mechanisms of action, which can effectively slow down the development of pesticide resistance in pests and greatly reduce the risk of resistance caused by applying the same component alone.

[0045] 4. The insecticidal composition of the present invention can significantly improve crop tolerance and make the agent safer for crops. Detailed Implementation

[0046] The bioactive examples are divided into indoor bioactive examples and field bioactive examples.

[0047] Indoor biological activity: The inventors used the Bliss method to determine the synergistic effect of the combination of active component A and active component B on pests.

[0048] M t =1-(1-P A )(1-P B ) M e -M t =M e -(P A +P B -P A ×P B ) In the formula: M e Actual measured efficacy of the composition M t Theoretical efficacy of the composition P A P B The values ​​represent the measured control effects of components A and B at their respective concentrations.

[0049] M e -M t When M > 0, the synergistic effect is synergistic. e -M t When <0, the synergistic effect is antagonistic, M e -M t The expression between 0 and 0 represents an additive effect.

[0050] The following tests can demonstrate the control effect of the insecticidal composition of the present invention on specific pests, but are not limited to the pest control methods provided.

[0051] Example 1: Indoor activity of the insecticidal composition against peach aphids.

[0052] Peach aphids of the same age were selected, and after immersing them in the pesticide solution for 10 seconds, excess pesticide solution was absorbed with filter paper. The test insects were then transferred to normal conditions for rearing. Each treatment was repeated 4 times, with 10 insects per repeat. After 24 hours of rearing, the mortality rate of the peach aphids was evaluated. The results are shown in Table 1.

[0053]

[0054] Example 2: Indoor activity of the insecticidal composition against rice planthoppers and whiteflies.

[0055] Rice planthoppers in their 2nd and 3rd instar larvae were selected and immersed in the pesticide solution for about 10 seconds using the immersion method. Excess pesticide solution was absorbed with filter paper, and the test insects were transferred to normal conditions for rearing. Each treatment was repeated 4 times, with 10 insects immersed in each repeated treatment. The mortality rate was calculated after 24 hours of rearing. The results are shown in Table 2-3.

[0056]

[0057]

[0058] Example 3: Indoor test of insecticidal composition against diamondback moth.

[0059] Leaf discs were punched using a 1cm diameter punch and placed in petri dishes. The test reagent was added and incubated for 4 hours. The resulting samples were then transferred to tissue culture plates for later use. Second- to third-instar diamondback moths were selected and starved for 4 hours. Sixty test moths were selected and placed in separate culture plates for feeding. Four hours after inoculation, 20 moths that had completely consumed the leaf discs were selected and incubated at room temperature for 24 hours. The mortality rate (control efficacy) was calculated. Each treatment was repeated four times. The results are shown in Table 4.

[0060]

[0061]

[0062] Example 4: Indoor activity of the insecticidal composition against rice stem borer.

[0063] Leaf discs were punched using a 1cm diameter punch and placed in petri dishes. The test reagent was added and incubated for 4 hours. The resulting samples were then transferred to tissue culture plates for later use. Rice stem borers in their 2nd-3rd instar were selected and starved for 4 hours. Fifty test insects were selected and placed in separate culture plates for feeding. Four hours after inoculation, 15 insects that had completely consumed the leaf discs were selected and incubated at room temperature for 24 hours. The mortality rate (control efficacy) was calculated. Each treatment was repeated four times. The results are shown in Table 5.

[0064]

[0065] Example 5: Indoor activity test of the insecticidal composition against the tea green leafhopper.

[0066] The larvae were selected in the 2nd to 3rd instar. The tea green leafhopper was immersed in the drug solution for about 10 seconds using the immersion method. The excess drug solution was absorbed with filter paper, and the test insects were transferred to normal conditions for rearing. Each treatment was repeated 4 times, with 15 insects immersed in each repeated treatment. The mortality rate was calculated after 24 hours of rearing. The results are shown in Table 6.

[0067]

[0068] Example 6: Indoor activity of the insecticidal composition against Tetranychus carmineus.

[0069] Select citrus leaves with growth inhibition, make leaf discs using a punch, and inoculate 20 nymphs of the carmine spider mite cultured indoors onto the leaf discs. Spray with a Potter spray tower, with a spray volume of 1 mL. After the solution settles for 1 minute, remove the leaf discs and transfer them to room temperature for rearing. Check the number of dead test insects after 48 hours and calculate the mortality rate. The results are shown in Table 7.

[0070]

[0071]

[0072] Indoor test results show that the mixtures listed in Tables 1-7 all have good indoor activity against peach aphid, rice planthopper, whitefly, diamondback moth, rice stem borer, tea green leafhopper, and spider mite.

[0073] Example 7: Field control efficacy of the insecticidal composition against peach aphids.

[0074] This experiment was conducted at an experimental base in Jimo City, Qingdao, using cabbage as the crop. A completely randomized block design was employed, with a water usage of 15 L per mu (approximately 0.067 hectares). Each treatment had four replicates. The baseline population was assessed before application, and the number of live aphids was assessed after application. The reduction rate and control efficacy were calculated separately. The survey method involved sampling at five points, with five plants surveyed at each point. One leaf with a sufficient number of aphids was marked on each plant, and the aphids on the entire leaf were counted. The baseline population in each plot was no less than 500 aphids.

[0075] Insect population reduction rate (%) = (Insect population base - Insect population after application) / Initial population before the experiment × 100 Control efficacy (%) = (Pest population reduction rate of pesticide treatment - Pest population reduction rate of blank control area) / (100 - Pest population reduction rate of blank control area) × 100

[0076] The test results showed that the insecticidal compositions listed in Table 8 all achieved the expected control effects against the peach aphid on cruciferous cabbage, with control efficacy ranging from 82.06% to 93.27%.

[0077] Example 8: Field control efficacy of the insecticidal composition against rice planthoppers.

[0078] The experiment was conducted at the Changsha Rice Experimental Base in Hunan Province. Five treatments were set up, including a water control. Each treatment covered an area of ​​20 square meters, with three replicates. The water usage per mu (approximately 0.067 hectares) was 15 L. The number of surviving planthoppers was assessed 14 days after application. The survey method involved surveying 25 rice clumps for each treatment, shaking the clumps, and counting the number of planthoppers floating on the water surface between the clumps to calculate the control effect.

[0079] Control efficacy (%) = [(Number of live insects in the control area after treatment - Number of live insects in the treatment area after treatment) / Number of live insects in the control area after treatment] × 100

[0080] The test results show that the insecticidal compositions listed in Table 9 have good control effects on rice planthoppers, with a control effect of 66.76%-84.62%.

[0081] Example 9: Field control efficacy of the insecticidal composition against whiteflies.

[0082] This experiment was conducted on cucumbers grown in greenhouses, with each plot measuring 20 square meters and protected by surrounding plants. Each treatment was replicated four times, and 20 L of water was used per acre. For each replicate, six compound leaves at the same growth site were examined from ten cucumber plants. The leaves were gently turned in the early morning when the adults were inactive, and the number of adults on each leaf was counted. The initial insect population was assessed before application, and the number of surviving insects was assessed seven days after application. The insect population reduction rate and control efficacy were calculated.

[0083] Insect population reduction rate (%) = (Insect population base - Insect population after application) / Initial population before the experiment × 100 Control efficacy (%) = (Pest population reduction rate of pesticide treatment - Pest population reduction rate of blank control area) / (100 - Pest population reduction rate of blank control area) × 100

[0084] The experimental results show that the insecticidal compositions listed in Table 10 are all more than 70% effective in controlling whiteflies on cucumbers in greenhouses, and do not cause phytotoxicity to cucumbers.

[0085] Example 10: Field control efficacy of the insecticidal composition against diamondback moth.

[0086] This experiment was conducted at an experimental base in Jimo City, Qingdao, using Chinese cabbage as the crop. A completely randomized block design was used, with four replicates per treatment. The baseline population was assessed before application, and the number of live insects was assessed seven days after application. 15 L of water was used per acre. The reduction rate and control efficacy were calculated. The survey method involved sampling at five points, with five plants at each point, to determine the total number of diamondback moth larvae of each instar on the entire plant.

[0087] Insect population reduction rate (%) = (Insect population base - Insect population after application) / Initial population before the experiment × 100 Control efficacy (%) = (Pest population reduction rate of pesticide treatment - Pest population reduction rate of blank control area) / (100 - Pest population reduction rate of blank control area) × 100

[0088] The experimental results showed that the insecticidal compositions listed in Table 11 had good control effects on diamondback moth on Chinese cabbage, with control effects ranging from 64.34% to 92.36%, and no phytotoxicity was caused to the Chinese cabbage during the experiment.

[0089] Example 11: Field control efficacy of the insecticidal composition against rice stem borer.

[0090] Apply pesticide when the first generation of rice stem borer has a sheathing rate of approximately 2%-3% during the rice tillering stage. Use 15L of water per acre, with three replicates per treatment, each replicate covering 40 square meters. Do not survey the initial insect population before application. Observe leaf curling 7 days after application. 20 days after application, survey 25 rice plants in each plot to calculate the control effect.

[0091] Leaf curl rate (%) = (Number of curled leaves surveyed / Total number of leaves surveyed) × 100 Control efficacy (%) = (Leaf curling rate in the control area after application - Leaf curling rate in the treated area after application) / Leaf curling rate in the control area × 100

[0092] The experimental results showed that the insecticidal compositions listed in Table 12 had good control efficacy against rice stem borer, with leaf curling rates of less than 11% in all treatments and control efficacy ranging from 69.71% to 78.91%. No adverse effects were observed on rice plants during the experiment.

[0093] Example 12: Field control efficacy of the insecticidal composition against the tea green leafhopper.

[0094] The experiment was conducted in Yangkou Tea Garden, Qingdao, Shandong Province. The experimental plot area was 40 square meters, and the experiment was repeated 4 times. The water consumption was 15L per mu. Fixed points were set up in the plot. The number of nymphs on 50 tender leaves was used as the baseline population. The population number was investigated 7 days after the application of the pesticide. The population reduction rate and control effect were calculated.

[0095] Insect population reduction rate (%) = (Insect population base - Insect population after application) / Initial population before the experiment × 100 Control efficacy (%) = (Pest population reduction rate of pesticide treatment - Pest population reduction rate of blank control area) / (100 - Pest population reduction rate of blank control area) × 100

[0096] The experimental results showed that the different insecticidal compositions listed in Table 13 had good control effects on the tea green leafhopper, with a reduction rate of over 70% 7 days after application and a control effect of 79.95%-84.19%. Furthermore, during the experiment, none of the compositions caused phytotoxicity to tea leaves or adverse effects on beneficial organisms.

[0097] Example 13: Field control efficacy of the insecticidal composition against Tetranychus carmineus.

[0098] The experiment was conducted in an eggplant plantation in Jimo, Qingdao, Shandong Province, where fertilizer and water conditions were good. Eggplants were grown outdoors, and plots were randomly arranged, each 20 square meters in size. Each treatment was replicated three times, and the pesticide was applied once. Twenty leaves were collected from each plot to count the number of mites (including adults and nymphs). A survey was conducted 7 days after application to calculate the control effect.

[0099] Mite reduction rate (%) = (Insect population size - Mite population size after application) / Initial population size before the experiment × 100 Control efficacy (%) = (mite reduction rate in pesticide-treated area - mite reduction rate in blank control area) / (100 - mite reduction rate in blank control area) × 100

[0100] The experimental results showed that the different insecticidal compositions listed in Table 14 had good control efficacy against the carmine spider mite, with a control efficacy of 65.53%-70.19% seven days after application. Furthermore, the insecticidal compositions had no effect on eggplant growth and were harmless to beneficial organisms.

[0101] Formulation preparation examples The insecticidal composition of the present invention can be prepared according to methods known to those skilled in the art.

[0102] When the insecticidal composition is prepared into a suspension, in addition to the active component, it also contains adjuvants such as dispersant 1% to 8% (preferably 2% to 7%), wetting agent 2% to 7% (preferably 2% to 4%), thickener 0% to 10% (preferably 1% to 5%), preservative 0% to 10% (preferably 1% to 2%), defoamer 1% to 10% (0.5% to 1%), antifreeze 1% to 10% (2% to 5%), and carrier deionized water to make up the balance.

[0103] Example 14: 51% A·Avermectin (50:1) suspension components: 50% A, 1% avermectin, 2.5% alkyl naphthalene sulfonic acid condensate anionic sulfonate, 1.5% silica, 0.5% xanthan gum, 5% ethylene glycol, 0.2% sodium benzoate, 0.5% organosilicon, deionized water to make up the balance.

[0104] Example 15: 15% A·pyriproxyl ether (2:1) suspension component content: 10% A, 5% pyriproxyl ether, 5% alkyl naphthalene sulfonic acid condensate anionic sulfonate, 0.5% organosilicon, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% silica, 9% ethylene glycol, 0.2% sodium benzoate, deionized water to make up the balance.

[0105] Example 16: 10% A·tebufenozide (1:1) suspension component content: 5% A, 5% tebufenozide, 0.6% xanthan gum, 4% alkyl naphthalene sulfonic acid condensate anion sulfonate, 0.5% organosilicon, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% silica, 8% ethylene glycol, 0.2% sodium benzoate, deionized water to make up the balance.

[0106] Example 17: Component content of 15%A·diflubenzuron (1:2) suspension: 5%A, 10%diflubenzuron, 5%FS3000, 1%TXC, 0.2%xanthan gum, 1% magnesium aluminum silicate, 4% ethylene glycol, 0.2%BIT, 0.3% organosilicon, deionized water to make up the balance.

[0107] Example 18: Component content of 21% A·diflubenzuron (20:1) suspension: 20% A, 1% diflubenzuron, 2% FS3000, 5% TXC, 0.2% xanthan gum, 1% magnesium aluminum silicate, 5% ethylene glycol, 0.2% BIT, 0.4% organosilicon, deionized water to make up the balance.

[0108] Example 19: Component content of 53%A·acetamiprid (50:3) suspension: 50%A, 3% acetamiprid, 4%FS3000, 1%TXC, 0.5% xanthan gum, 1% magnesium aluminum silicate, 5% ethylene glycol, 0.2% 1,2-benzisothiazolin-3-one, 0.3% Silwet806, deionized water to make up the balance.

[0109] Example 20: 15% A·flupyridine (2:1) suspension concentrate components: 10% A, 5% flonicamid, 4% sodium salt of alkyl naphthalene sulfonic acid condensate, 2% Morwet EFW, 0.5% xanthan gum, 1% magnesium aluminum silicate, 5% ethylene glycol, 0.2% 1,2-benzisothiazolin-3-one, 0.3% organosilicon, deionized water to make up the balance.

[0110] Example 21: 26% A·flupyridine (25:1) suspension concentrate component content: 25% A, 1% flonicamid, 0.6% xanthan gum, 4% alkyl naphthalene sulfonic acid condensate anion sulfonate, 0.5% organosilicon, 2% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% silica, 9% ethylene glycol, 0.2% sodium benzoate, deionized water to make up the balance.

[0111] Example 22: 53% A·flupyridine (50:3) suspension concentrate component content: 50% A, 3% flonicamid, 2% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% xanthan gum, 6% ethylene glycol, 3% alkyl naphthalene sulfonic acid condensate anion sulfonate, 1% organosilicon, 2% silica, 0.2% sodium benzoate, deionized water to make up the balance.

[0112] Example 23: 10% A·fluoxetine (1:1) suspension concentrate components: 5% A, 5% flonicamid, 3% alkyl naphthalene sulfonic acid condensate anion sulfonate, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% silica, 0.2% xanthan gum, 5% ethylene glycol, 0.2% sodium benzoate, 0.5% organosilicon, deionized water to make up the balance.

[0113] Example 24: 21% A·Fluoridium Urea (20:1) suspending agent components: 20% A, 1% Fluoridium Urea, 4% Alkyl Naphthalene Sulfonic Acid Condensate Anionic Sulfonate, 0.3% Xanthan Gum, 2% Alkylphenol Polyoxyethylene Polyether Formaldehyde Condensate Sulfate, 0.5% Organosilicon, 1.5% Silica, 6% Ethylene Glycol, 0.2% Sodium Benzoate, Deionized Water to make up the balance.

[0114] Example 25: 15% A·methoxyfenozide (2:1) suspension concentrate components: 10% A, 5% methoxyfenozide, 4% alkyl naphthalene sulfonic acid condensate anion sulfonate, 1% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% silica, 0.2% xanthan gum, 6% ethylene glycol, 0.2% sodium benzoate, 0.5% organosilicon, deionized water to make up the balance.

[0115] Example 26: Component content of 50.2% A·pyridaben (250:1) suspension: 50% A, 0.2% pyridaben, 4% alkyl naphthalene sulfonic acid condensate anionic sulfonate, 0.5% organosilicon, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% silica, 9% ethylene glycol, 0.2% sodium benzoate, 0.5% deionized water to make up the balance.

[0116] Example 27: 22% A·Biphenylhydrazine ester (10:1) suspension component content: 20% A, 2% Biphenylhydrazine ester, 5.5% Alkyl naphthalene sulfonic acid condensate anionic sulfonate, 0.5% Xanthan gum, 0.5% Organosilicon, 4% Ethylene glycol, 2% Alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1.5% Silica, 0.2% Sodium benzoate, deionized water to make up the balance.

[0117] Example 28: 20.04% A·Bifenthrin (500:1) suspension concentrate component content: 20% A, 0.04% Bifenthrin, 4% FS3000, 1% TXC, 0.18% Xanthan Gum, 1.1% Magnesium Aluminum Silicate, 5% Ethylene Glycol, 0.2% BIT, 0.3% Silwet806 synergist, deionized water to make up the balance.

[0118] Example 29: 51% A·spirotetramat (50:1) suspension concentrate component content: 50% A, 1% spirotetramat, 0.6% gelatin, 4% alkyl naphthalene sulfonic acid condensate anion sulfonate, 0.5% organosilicon, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% silica, 12% ethylene glycol, 0.2% sodium benzoate, deionized water to make up the balance.

[0119] Example 30: 21% A·trifluoromethylpyridine (20:1) suspension concentrate component content: 20% A, 1% trifluoromethylpyridine, 4% alkyl naphthalene sulfonic acid condensate anion sulfonate, 0.5% organosilicon, 2% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% silica, 12% ethylene glycol, 0.2% potassium sorbate, 1.5% deionized water to make up the balance.

[0120] Example 31: 20% A·carbendazim (4:1) suspension concentrate component content: 16% A, 4% carbendazim, 4% alkyl naphthalene sulfonic acid condensate anion sulfonate, 0.3% xanthan gum, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 0.5% organosilicon, 1.5% silica, 6% ethylene glycol, 0.2% potassium sorbate, deionized water to make up the balance.

[0121] Example 32: 21%A·chlorfenapyr (20:1) suspending agent components: 20%A, 1%chlorfenapyr, 2% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1% xanthan gum, 6% ethylene glycol, 3% alkyl naphthalene sulfonic acid condensate anion sulfonate, 1% organosilicon, 2% silica, 0.2% sodium benzoate, deionized water to make up the balance.

[0122] Example 33: Component content of 15%A·Diflubenzuron (1:2) suspension: 5%A, 10%Diflubenzuron, 4% Alkylnaphthalene sulfonic acid condensate anionic sulfonate, 0.3% Xanthan gum, 1.5% Alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 0.5% Organosilicon, 1.5% Silica, 6% Ethylene glycol, 0.2% Potassium sorbate, deionized water to make up the balance.

[0123] Example 34: 22% A·Diflubenzuron (10:1) suspension concentrate component content: 20% A, 2% Diflubenzuron, 4% Alkylnaphthalene sulfonic acid condensate anion sulfonate, 0.3% Xanthan gum, 1.5% Alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 1.5% fumed silica, 6% N, 0.2% potassium sorbate, 1% deionized water to make up the balance.

[0124] Example 35: 18% A·Ethoxyxazole (5:1) suspension components: 15% A, 3% etoxazole, 4% alkyl naphthalene sulfonic acid condensate anion sulfonate, 0.3% xanthan gum, 1.5% alkylphenol polyoxyethylene polyether formaldehyde condensate sulfate, 0.5% organosilicon, 1.5% silica, 6% N-methylpyrrolidone, 0.2% sodium benzoate, deionized water to make up the balance.

[0125] Example 36: 14%A·Isoprocarb (2:5) suspending agent components: 4%A, 10% isoprocarb, 4%FS3000, 1%TXC, 0.18% xanthan gum, 1% magnesium aluminum silicate, 5% ethylene glycol, 0.2% BIT, 0.3% Silwet806 synergist, deionized water to make up the balance.

[0126] Example 37: Component content of 22%A·Indoxacarb (10:1) suspension: 20%A, 2%Indoxacarb, 3%Urea-formaldehyde resin, 4%0201B emulsifier, 15%S200# solvent, 15%SP682, 12%SP3262, 5% gelatin, 0.2% ethylene glycol, deionized water to make up the balance.

[0127] Example 38: 21%A·Indoxacarb (20:1) suspension concentrate component content: 20%A, 1%Indoxacarb, 2% Agricultural Emulsifier 600, 8% Xylene, 2% SP~682, 6% SP~326, 4% Magnesium Aluminum Silicate, deionized water to make up the balance; Example 39: 10% A·acetamiprid (1:1) suspension concentrate components: 5% A, 5% acetamiprid, 3% urea-formaldehyde resin, 4% 0201B emulsifier, 5% S200# solvent, 7% SP3262, 5% xanthan gum, 0.2% ethylene glycol, deionized water to make up the balance.

[0128] Example 40: Component content of 20.2% A·azithion (100:1) suspension: 20% A, 0.2% azithion, 2% urea-formaldehyde resin, 5% 0201B emulsifier, 4% agricultural emulsion 600, 4% xylene, 10% SPSC29, 3% gelatin, 0.5% ethylene glycol, deionized water to make up the balance.

[0129] When the insecticidal composition is prepared into water-dispersible granules, in addition to the active component, it also contains 1% to 10% (preferably 3% to 7%) of adjuvant dispersant, 1% to 10% (preferably 3% to 7%) of wetting agent, 0.5% to 10% (preferably 1% to 5%) of disintegrant, 0.5% to 10% (preferably 1% to 5%) of binder, and filler to make up the balance.

[0130] Example 41: Formulation of 22% A·Imidacloprid (10:1) water dispersible granules: 20% A, 2% imidacloprid, 3% lignin sulfonate, 4% ammonium sulfate, corn starch to make up the balance.

[0131] Example 42: Formulation of 53%A·Imidacloprid (50:3) water dispersible granules: 50%A, 3% imidacloprid, 5% lignin sulfonate, 5% sodium benzoate, 1% ammonium sulfate, corn starch to make up the balance.

[0132] Example 43: Formulation of 15% A·pymetrozine (2:1) water-dispersible granules: 10% A, 5% pymetrozine, 1% sodium alkylnaphthalene sulfonate, 3% ammonium sulfate, corn starch to make up the balance.

[0133] Example 44: Formulation of 18% A·pymetrozine (5:1) water-dispersible granules: 15% A, 3% pymetrozine, 3% naphthalene sulfonate, 3.5% sodium benzoate, corn starch to make up the balance.

[0134] Example 45: Formulation of 22% A·fipronil (10:1) water dispersible granules: 20% A, 2% fipronil, 4% lignin sulfonate, 4% sodium benzoate, corn starch to make up the balance.

[0135] Example 46: Formulation of 21% A·fipronil (20:1) water-dispersible granules: 20% A, 1% fipronil, 2% sodium alkylnaphthalene sulfonate, 4% sodium benzoate, 1% ammonium sulfate, corn starch to make up the balance.

[0136] Example 47: Formulation of 10.01%A·flufenican (1000:1) water-dispersible granules: 10%A, 0.01%flufenican, 1.5% sodium naphthalenesulfonate, 2% sodium benzoate, 1% ammonium sulfate, corn starch to make up the balance.

[0137] Example 48: Formulation of 40.2% A·Abamectin (200:1) water-dispersible granules: 40% A, 0.2% Abamectin, 5% Sodium Alkyl Naphthalene Sulfonate, 5% Sodium Benzoate, 1% Ammonium Sulfate, corn starch to make up the balance.

[0138] Example 49: Formulation of 20.2% A·chlorantraniliprole (100:1) water dispersible granules: 20% A, 0.2% chlorantraniliprole, 2% lignin sulfonate, 4% ammonium sulfate, corn starch to make up the balance.

[0139] Example 50: Formulation of 51%A·chlorantraniliprole (50:1) water dispersible granules: 50%A, 1% chlorantraniliprole, 5% sodium alkylnaphthalene sulfonate, 6% ammonium sulfate, corn starch to make up the balance.

[0140] Example 51: Formulation of 10% A·thiamethoxam (1:1) water-dispersible granules: 5% A, 5% thiamethoxam, 2% lignin sulfonate, 2% ammonium sulfate, corn starch to make up the balance.

[0141] Example 52: Formulation of 22%A·lufenuron (10:1) water dispersible granules: 20%A, 2% lufenuron, 4% lignin sulfonate, 4% ammonium sulfate, corn starch to make up the balance.

[0142] Example 53: Formulation of 51%A·Ethyl spinosad (50:1) water dispersible granules: 50%A, 1% ethyl spinosad, 6% sodium alkyl naphthalene sulfonate, 7% sodium benzoate, corn starch to make up the balance.

[0143] When an insecticidal composition is prepared into an emulsifiable concentrate, in addition to the active ingredient, it also contains 1% to 20% (2% to 10%) of adjuvant emulsifier and the remainder of solvent.

[0144] Example 52: Formulation of 21%A·propargyl bromophos (2:1) emulsifiable concentrate: 20%A, 1% propargyl bromophos, 10% alkylphenyl polyethyl ether, rapeseed oil to make up the balance.

[0145] Example 53: Formulation of 21%A·propargyl (2:5) emulsifiable concentrate: 20%A, 1% propargyl, 10% agricultural emulsion 0204, and rapeseed oil to make up the balance.

[0146] Example 54: Formulation of 51%A·propargyl bromophos (50:1) emulsifiable concentrate: 50%A, 1% propargyl bromophos, 20% alkylphenyl polyethyl ether, rapeseed oil to make up the balance.

[0147] Example 55: Formulation of 22%A·Butadiene (10:1) emulsifiable concentrate: 20%A, 2%butadiene, 10% agricultural emulsion 0204, rapeseed oil to make up the balance.

[0148] Example 56: Formulation of 18%A·Butadiene (5:1) emulsifiable concentrate: 15%A, 3% Butadiene, 6% Agricultural Emulsion 0204, rapeseed oil to make up the balance.

[0149] Example 57: Formulation of 41%A·flufenoxuron (40:1) emulsifiable concentrate: 40%A, 1%flufenoxuron, 15% agricultural emulsion 0204, rapeseed oil to make up the balance.

[0150] Example 58: Formulation of 20% A·triazophos (4:1) emulsifiable concentrate: 16% A, 4% triazophos, 7% alkylphenyl polyethyl ether, rapeseed oil to make up the balance.

[0151] When the insecticidal composition is prepared into a wettable powder, in addition to the active ingredient, it also contains 1% to 10% (3% to 7%) of adjuvant dispersant, 1% to 10% (preferably 3% to 7%) of wetting agent, and filler to make up the balance.

[0152] Example 59: Formulation of 52%A·High-efficiency cyhalothrin (50:2) wettable powder: 50%A, 2% high-efficiency cyhalothrin, 2% sodium dodecylbenzene sulfonate, 10% silica, 7% sodium lignosulfonate, and light calcium carbonate to make up the balance.

[0153] Example 60: Formulation of 20% A·acetamiprid (4:1) wettable powder: 16% A, 4% acetamiprid, 3% sodium dodecylbenzene sulfonate, 15% silica, 6% sodium lignosulfonate, and light calcium carbonate to make up the balance.

Claims

1. A pesticide composition containing a pyrazole carboxamide insecticide, comprising component A and component B, wherein component A is Dimpropyridaz and component B is at least one active compound selected from the groups B1-B17; B1 carbamates: benzothiocarb, carbofuran, propoxur, carbofuran, oxadiazon, imidacloprid, furazolidone, methyl thiocarb, carbofuran, pymetrozine, methomyl, thiamethoxam, aldicarb, aldicarb, ethylbenzylcarbide, isopropylcarb, sec-butylcarbide, azoxystrobin, fenvalerate, methylbenzyl, methamidophos, methamidophos, methamidophos, methamidophos, methamidophos, methamidophos, methamidophos; B2 Organophosphates: Ammonium sulfadiazine, Phosphate, Fenthion, Benzoate, Phosphamidon, Pyrazophos, Propyrazophos, Propyrazophos, Phosphamidon, Pyrazazin, Dichlorvos, Dichlorvos, Chlorpyrifos, Parathion, Diazinon, Dibromophos, Phosphamidon, Methamidophos, Phosphamidon, Methylpyridinium phosphate, Methyl chlorpyrifos, Methyl parathion, Methyl glutamic acid, Methyl pyrimidinium phosphate, Methyl demeton-methyl, Methyl ethion, Monocrotophos, Quinalphos, Dimethoate, Phosphamidon, Thiophanate-methyl Phosphorus oxychloride, malathion, ethoprophos, chlorpyrifos, triazophos, fenitrothion, chlorpyrifos, dimethoate, methamidophos, methamidophos, terbufos, chlorpyrifos, phorate, phosmet, sulfonylurea, dimethoate, phorate, ethyl glutathione, ethion, acephate, methyl pyrazophos, isofenphos, phosmet, phosmet, phosmet, ethyl bromide, bromophenylenephos, pyrimiphos, trisulfite, propionyl, pyrifluquinazon, isofenphos, isoprothiolane, chlorpyrifos, chlorpyrifos; B3 Pyrethroids: s-cypermethrin, θ-cypermethrin, β-cypermethrin, deltamethrin, tetraflufenoxam, DDT, benzalkonium chloride, dichlorvos, allethrin, pyrethrin, lambda-cyhalothrin, flufenoxuron, flufenoxuron, cypermethrin, imidacloprid, thiamethoxam, flufenoxuron, deltamethrin, lambda-cyhalothrin, deltamethrin, trifluralin, flufenoxuron, cyhalothrin, pyrethroid, deltamethrin, methoxyfenozide, deltamethrin, cypermethrin, deltamethrin, deltamethrin, deltamethrin, deltamethrin, deltamethrin, deltamethrin, deltamethrin, deltamethrin, deltamethrin, deltamethrin, deltamethrin, deltamethrin Cypermethrin, cypermethrin, methoxybenzoxyfenozide, high-efficiency cyhalothrin, bifenthrin, cypermethrin, permethrin, cypermethrin, fenvalerate, fenvalerate, fenvalerate, propargite, propargite, thiamethoxam, trifluralin, bio-benzoxyfenozide, bio-allethrin, high-efficiency cyhalothrin, cyclopentylpyrethrin, cypermethrin, tetrafluorobenzylpyrethrin, tetrafluoromethrin, tetrabromopyrethrin, fenvalerate, bromopyrethrin, deltamethrin, cypermethrin, cypermethrin, pyrethrin, pyrethrin, pyrethrin, pyrethrin, pyrethrin; B4 neonicotinoids: imidacloprid, acetamiprid, dinotefuran, flonicamid, thiamethoxam, thiamethoxam, acetamiprid, nicotine, trifluralin, nitenthiamethoxam, chlorothiazoline; B5 Benzoylurea: Diflubenzuron, Polyflubenzuron, Flufenoxuron, Flufenoxuron, Flufenoxuron, Flufenoxuron, Flufenoxuron, Lufenuron, Diflubenzuron, Chlorflufenoxuron, Flufenoxuron, Flufenoxuron, Flufenoxuron; B6 juvenile hormone mimics: phenoxycarb, pyriproxyfen, acetamiprid, acetamiprid ethyl ester, acetamiprid ester, acetamiprid ether, acetamiprid thiocyanate; B7 nereistoxin analogs: chlorfenapyr, chlorfenapyr, chlorfenapyr dicarboxylic acid, pyridaben hydrochloride; B8 insecticides: Rapimidone, Emamectin methylaminoazine; B9 biological substances, hormones or pheromones: azadirachtin, Bacillus species, Beauveria bassiana species, Metarhizium anisopliae species, Paecilomyces species, Bacillus thuringiensis, Verticillium species; B10 pyrazoles: tebufenozide, fipronil, acetamiprid, thiophanate-methyl, flupyrazole; B11 oxadiazines: indoxacarb; B12 organochlorine compounds: lindane, chlordane, thiodine; B13 diamides: flubendiamide, broflanilide, flubendiamide, fluchlorfenapyr; B14 dihydrazides: tebufenozide, cyclotebufenozide, methoxyfenozide, chlorfenapyr; Other heterocyclic compounds in B15: pyridaben, pyrifluquinazon, pymetrozine, pyridaben, flonicamid, acetamiprid, chlorantraniliprole, cyclopyridaben, pyrimethanil, trifluralin; B16 Bio-based Insecticide: Spinosad; B17 acaricides: Acaricides such as fenpropathrin, fenpropathrin, fenpropathrin, pyridaben, sulfadiazine, bifenazate, micaben, propargite, thiamethoxam, trichlorfon, trichlorfon sulfone, fenpropathrin, bromodifen, difenoconazole, spirotetramat, spirodiclofen, quinacrine, pyridaben, pyridaben, flufenoxuron, pyrimethanil, thiamethoxam, tetradifon, ivermectin, etoxazole, diflubenzuron, cyprodinil, fenbutatin, tricyclic tin, triazole tin.

2. The pesticide composition according to claim 1, characterized in that... At least one component B of the composition is selected from B1 carbamates: carbofuran, thiocarbofuran, pirimicarb, carbofuran, styrax, isopropylcarbamide, sec-butylcarbamide, pirimicarb; B2 organophosphates: propoxur, propoxur, chlorpyrifos, triazophos, phoxim, chlorpyrifos; B3 Pyrethroids: s-cypermethrin, β-cypermethrin, tetraflufenoxam, pyrethrin, lambda-cyhalothrin, cyhalothrin, bifenthrin, cyhalothrin, lambda-cyhalothrin, lambda-cyhalothrin; B4 neonicotinoids: imidacloprid, acetamiprid, dinotefuran, flonicamid, thiamethoxam, thiamethoxam, acetamiprid, trifluralin; B5 benzoylurea: diflubenzuron, flufenoxuron, flufenoxuron, flufenoxuron, flufenoxuron, lufenuron, diflubenzuron; B6 juvenile hormone mimics: pyriproxyfen, acetamiprid; B7 Nerein analogues: chlorfenapyr, chlorfenapyr dicarboxylic acid, pyridaben hydrochloride; B9 biological substances, hormones, or pheromones: Bacillus thuringiensis, Verticillium species; B10 pyrazoles: tebufenozide, fipronil, acetamiprid; B11 oxadiazines: indoxacarb; B12 organochlorine compounds: chlordane; B13 diamides: flubendiamide, broflanilide, flubendiamide, fluchlorfenapyr; B14 dihydrazides: tebufenozide, cyclotebufenozide, methoxyfenozide, chlorfenapyr; Other heterocyclic compounds in B15: pymetrozine, tebufenozide, fipronil, acetamiprid, flonicamid, oxadiazon, brofenoxam, trifluralin; B16 Bio-based Insecticide: Spinosad; B17 acaricides: abamectin, pyridaben, bifenazate, propargite, thiamethoxam, spirotetramat, spirodiclofen, pyridaben, etoxazole, diflubenzuron, and cyprodinil.

3. The pesticide composition according to claim 1, characterized in that... At least one component B of the composition is selected from pyriproxyfen, imidacloprid, pymetrozine, profenofos, tebufenozide, diflubenzuron, tebufenozide, acetamiprid, dinotefuran, flufenoxuron, flufenoxuron, flufenoxuron, flufenoxuron, flufenoxuron, lambda-cyhalothrin, methoxyfenozide, cypermethrin, pirimicarb, bifenazate, bifenthrin, spirotetramat, propargite, thiamethoxam, thiamethoxam, trifluralin, trifluralin, triazophos, cartap, chlorfenapyr, lufenuron, diflubenzuron, acetamiprid, etoxazole, isoprocarb, indoxacarb, acetamiprid, and acetamiprid.

4. The pesticide composition according to claim 1, characterized in that... The weight ratio of component A to component B is 0.1:100 to 100:0.1, preferably 1:12 to 100:0.1, and more preferably 1:4 to 100:

1.

5. The pesticide composition according to any one of claims 1-3, characterized in that, The mass ratios of active ingredient A to pyriproxyfen are 1:2 to 2:1; the mass ratio of active ingredient A to imidacloprid is 2:5 to 50:1; the mass ratio of active ingredient A to pymetrozine is 5:2 to 10:1; the mass ratio of active ingredient A to profenofos is 1:1 to 50:1; the mass ratio of active ingredient A to tebufenozide is 1:4 to 1:1; the mass ratio of active ingredient A to diflubenzuron is 1:8 to 1:2; the mass ratio of active ingredient A to tebufenozide is 5:2 to 10:1; the mass ratio of active ingredient A to fenflurfen is 5:1 to 20:1; the mass ratio of active ingredient A to acetamiprid is 25:3 to 100:3; and the mass ratio of active ingredient A to dinotefuran is 1:5 to 20:

1. The mass ratio of component A to flufenoxuron is 1:12 to 1:4; the mass ratio of active component A to flonicamid is 1:5 to 50:1; the mass ratio of active component A to flonicamid is 2:5 to 2:1; the mass ratio of active component A to flonicamid is 10:1 to 50:1; the mass ratio of active component A to flufenoxuron is 10:1 to 40:1; the mass ratio of active component A to lambda-cyhalothrin is 25:4 to 25:1; the mass ratio of active component A to methoxyfenozide is 1:2 to 2:1; the mass ratio of active component A to cypermethrin is 25:0.2 to 50:0.1; the mass ratio of active component A to pirimicarb is 5:2 to 10:1; and the mass ratio of active component A to bifenazate is... The mass ratios of active components are as follows: 5:2 to 10:1; 2:1 to 100:0.1; 25:2 to 50:1; 5:2 to 10:1; 1:2 to 20:1; 5:1 to 20:1; 4:1 to 50:1; 5:1 to 20:1; 1:1 to 20:1; 1:1 to 4:1; 1:1 to 4:1; and 1:1 to 4:

1. The mass ratios of active component A and chlorfenapyr are 5:1 to 20:1; the mass ratios of active component A and lufenuron are 5:2 to 10:1; the mass ratios of active component A and diflubenzuron are 1:4 to 10:1; the mass ratios of active component A and acetamiprid are 2:1 to 20:1; the mass ratios of active component A and acetamiprid are 2:1 to 10:1; the mass ratios of active component A and etoxazole are 25:1 to 100:1; the mass ratios of active component A and isoprocarb are 2:5 to 5:2; the mass ratios of active component A and indoxacarb are 5:2 to 50:1; the mass ratios of active component A and azoxystrobin are 1:2 to 2:1; and the mass ratios of active component A and azoxystrobin are 25:1 to 100:

1.

6. The pesticide composition according to claim 1, characterized in that... The total weight of component A and component B accounts for 1% to 90% of the total composition, preferably 10% to 70%.

7. The pesticide composition according to claim 1, characterized in that... The pesticide composition also contains pesticide adjuvants and carriers.

8. A pesticide composition containing any one of the pyrazole carbamide insecticides as described in any one of claims 1-7 can be used in a method of therapeutically or preventively controlling pests.

9. The method according to claim 8, characterized in that, The pesticide composition can be applied to seeds, plants, and / or fruits through seed treatment, foliar application, or drip irrigation.

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