Organic compound, light-emitting device, display device, and electronic apparatus

Abstract

Provided is an organic compound having electron injection properties and low solubility in water. Provided is an organic compound represented by general formula (G1). Note that in general formula (G1), Ar is an aromatic skeleton represented by general formula (Ar-1), L represents an alkylene group, an arylene group, or a heteroarylene group, n represents an integer of 0 to 3, m represents an integer of 1 to 4, and R1 to R12 each independently represent hydrogen or an alkyl group. In general formula (Ar-1), ring A represents a benzene ring or a naphthalene ring, ring B represents a naphthalene ring, an anthracene ring, or a phenanthrene ring, alpha represents oxygen, sulfur, carbon having a substituent, silicon having a substituent, or germanium having a substituent, and any m carbon atoms included in general formula (Ar-1) have m bonds in general formula (G1). # imgabs0 #

Claims

1. An organic compound represented by the general formula (G1). [Chemical Formula 1] (Note that in the general formula (G1), Ar is an aromatic skeleton represented by the general formula (Ar-1), L is an alkylene group having 1 to 10 carbon atoms, a substituted or unsubstituted arylene group having 6 to 30 carbon atoms, or a substituted or unsubstituted heteroarylene group having 1 to 11 carbon atoms, n represents an integer from 0 to 3, m represents an integer from 1 to 4, and R 1 to R 12 Each independently represents hydrogen (including deuterium) or an alkyl group having 1 to 10 carbon atoms. In addition, when n is 2 or more, L may be the same or different from each other, when m is 2 or more, L may be the same or different from each other, n may be the same or different from each other, and R 1 to R 12 They may be the same as or different from each other. In the general formula (Ar-1), ring A represents a benzene ring or a naphthalene ring, ring B represents a naphthalene ring, anthracene ring or a phenanthrene ring, α represents oxygen, sulfur, substituted carbon, substituted silicon or substituted germanium, and any m of the carbon atoms included in the general formula (Ar-1) have m bonds in the general formula (G1).

2. An organic compound represented by the general formula (G1). [Chemical Formula 2] (Note that in the general formula (G1), Ar is an aromatic skeleton represented by the general formula (Ar-2), L represents an alkylene group having 1 to 10 carbon atoms, a substituted or unsubstituted arylene group having 6 to 30 carbon atoms, or a substituted or unsubstituted heteroarylene group having 1 to 11 carbon atoms, n represents an integer from 0 to 3, m represents an integer from 1 to 4, and R 1 to R 12 Each independently represents hydrogen (including deuterium) or an alkyl group having 1 to 10 carbon atoms. In addition, when n is 2 or more, L may be the same or different from each other, when m is 2 or more, L may be the same or different from each other, n may be the same or different from each other, and R 1 to R 12 In the general formula (Ar-2), ring B represents a naphthalene ring, anthracene ring or phenanthrene ring, α represents oxygen, sulfur, carbon with a substituent, silicon with a substituent or germanium with a substituent, and R 21 to R 24 Each independently represents hydrogen (including deuterium), an alkyl group having 1 to 10 carbon atoms, a cycloalkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a substituted or unsubstituted heteroaryl group having 1 to 30 carbon atoms, and any m of the carbon atoms included in the general formula (Ar-2) have m bonds in the general formula (G1).

3. An organic compound represented by the general formula (G1). [Chemical Formula 3] (Note that in the general formula (G1), Ar is an aromatic skeleton represented by the general formula (Ar-3), L represents an alkylene group having 1 to 10 carbon atoms, a substituted or unsubstituted arylene group having 6 to 30 carbon atoms, or a substituted or unsubstituted heteroarylene group having 1 to 11 carbon atoms, n represents an integer from 0 to 3, m represents an integer from 1 to 4, and R 1 to R 12 Each independently represents hydrogen (including deuterium) or an alkyl group having 1 to 10 carbon atoms. In addition, when n is 2 or more, L may be the same or different from each other, when m is 2 or more, L may be the same or different from each other, n may be the same or different from each other, and R 1 to R 12 In the general formula (Ar-3), α represents oxygen, sulfur, carbon with a substituent, silicon with a substituent or germanium with a substituent, and R 21 to R 32 Any m of them represent m bonding positions in the general formula (G1), R 21 to R 32 The rest of the residues independently represent hydrogen (including deuterium), an alkyl group having 1 to 10 carbon atoms, a cycloalkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a substituted or unsubstituted heteroaryl group having 1 to 30 carbon atoms.

4. An organic compound represented by the general formula (G2). [Chemical Formula 4] (In general formula (G2), R 1 to R 12 Each independently represents hydrogen (including deuterium) or an alkyl group having 1 to 10 carbon atoms. When n is 2 or more, L may be the same or different. α represents oxygen, sulfur, carbon with a substituent, silicon with a substituent, or germanium with a substituent, and R 21 、R 23 to R 32 Each independently represents hydrogen (including deuterium), an alkyl group having 1 to 10 carbon atoms, a cycloalkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a substituted or unsubstituted heteroaryl group having 1 to 30 carbon atoms. 5 . The organic compound according to claim 1 , wherein the α is represented by the general formula (α-1). [Chemical Formula 5] (In the general formula (α-1), X represents carbon, silicon or germanium, R 33 and R 34 Each independently represents hydrogen (including deuterium), a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a cycloalkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a substituted or unsubstituted heteroaryl group having 1 to 30 carbon atoms, and * represents a bonding position.) 6. An organic compound represented by structural formula (100). [Chemical Formula 6] 7. A light-emitting device using the organic compound according to any one of claims 1 to 4 and 6.

8. A display device comprising: The light-emitting device according to claim 7; as well as transistor or substrate.

9. An electronic device comprising: The display device according to claim 8; as well as Detection unit, input unit or communication unit.

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