Remediation material for degrading organic contaminated soil by coupling manganese dioxide loaded biochar with chlorine dioxide and preparation method and remediation method of remediation material

By leveraging the synergistic effect of manganese dioxide-loaded biochar and chlorine dioxide, the problem of the difficulty in degrading polycyclic aromatic hydrocarbons in traditional methods has been solved, achieving efficient and economical soil remediation results.

CN120790137APending Publication Date: 2025-10-17SHANGHAI INST OF TECH
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Patent Information

Application Number
CN202510859251.3
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-06-25
Publication Date
2025-10-17

AI Technical Summary

Technical Problem

Existing technologies are insufficient for efficiently degrading polycyclic aromatic hydrocarbons in organically polluted soils, especially in aging soils where oxidants are difficult to effectively degrade. Furthermore, traditional remediation methods are characterized by high costs, soil toxicity, or low efficiency.

Method used

A remediation material using manganese dioxide-supported biochar coupled with chlorine dioxide is employed. Biochar provides a large number of active sites and a high specific surface area, while manganese dioxide nanoclusters activate chlorine dioxide to generate free radicals, thereby achieving efficient oxidative degradation of polycyclic aromatic hydrocarbons.

Benefits of technology

It significantly improves the degradation efficiency of polycyclic aromatic hydrocarbons, reduces the amount of oxidant used, and minimizes the negative impact on soil. It has the advantages of low cost, short cycle, and wide applicability.

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Abstract

The invention relates to a remediation material for degrading organic contaminated soil by coupling manganese dioxide loaded biochar with chlorine dioxide and a preparation method and a remediation method of the remediation material, and belongs to the technical field of soil remediation, the remediation material comprises a biochar carrier and manganese dioxide nanoclusters loaded on the biochar carrier. Compared with the prior art, the manganese dioxide loaded biochar catalyst has excellent physical and chemical properties, the high specific surface area and the porous structure of the biochar provide a large number of active sites for MnO2 nanoparticles, and meanwhile, the adsorption performance of the biochar can effectively shorten the distance between the catalyst and pollutants and improve the reaction efficiency.
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