Container comprising transparent laundry fragrance enhancer composition

By using a combination of ethoxylated triglycerides and beads in a transparent laundry fragrance enhancer to form a cross-linked polymer network, the stability problem of the transparent liquid fragrance enhancer in recycled resin bottles is solved, achieving a transparent and stable fragrance delivery effect.

CN121712876APending Publication Date: 2026-03-20UNILEVER IP HLDG BV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2024-06-06
Publication Date
2026-03-20

AI Technical Summary

Technical Problem

Existing transparent liquid fragrance enhancers have stability issues in recycled resin bottles, making it difficult to meet consumers' demands for transparency and stability.

Method used

A transparent laundry fragrance enhancer composition comprising fragrance, ethoxylated triglycerides, and a specific ratio of beads is used to improve the stability and transparency of the composition by forming a network using cross-linked polymers.

Benefits of technology

This technology enables the composition to maintain transparency and stability in recycled resin bottles, meeting consumer demand for transparent and efficient fragrance delivery.

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Abstract

A container comprising a transparent laundry fragrance enhancer composition, wherein the transparent laundry fragrance enhancer composition comprises: a perfume and ethoxylated triglyceride; and wherein the container comprises from 25 to 100% by weight of post consumer regenerated resin.
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Description

Technical Field

[0001] This invention relates to transparent liquid fragrance enhancers. Background Technology

[0002] In addition to any detergent or fabric conditioner, fragrance enhancers are used during the laundry process to deliver a scent. Fragrance enhancers allow consumers to customize their fragrance experience during laundry. Consumers can choose the fragrance and the amount of product to be added. This avoids overusing products like fabric conditioners to increase fragrance delivery. Consumers also expect transparent products, as transparency signals that the product is free of high levels of chemicals. There is a demand for transparent liquid fragrance enhancers; however, transparent formulations offered in recycled resin bottles present stability issues. Summary of the Invention

[0003] Research has found that careful selection of nonionic surfactants can improve the stability of transparent fragrance enhancers in post-consumer recycled resin bottles.

[0004] Therefore, in one aspect of the invention, a container comprising a transparent laundry fragrance enhancer composition is provided, wherein the transparent laundry fragrance enhancer composition comprises: a) Spices; and b) Ethoxylated triglycerides; The container contains 25 to 100% by weight of post-consumer recycled resin. Detailed Implementation

[0005] By reading the following detailed description and the appended claims, those skilled in the art will be able to clearly understand the invention and other aspects, features, and advantages. For the avoidance of doubt, any feature of one aspect of the invention may be used in any other aspect of the invention. The word “comprising” is intended to mean “including” but does not necessarily mean “consisting of” or “made of”. In other words, the listed steps or options are not exhaustive. It should be noted that the examples given in the following specification are intended to illustrate the invention and not to limit the invention to these embodiments themselves. Similarly, unless otherwise stated, all percentages are by weight. Except as otherwise expressly stated in operational examples and comparisons, all figures in this specification representing amounts of material or reaction conditions, physical properties of materials, and / or uses should be understood to be modified with the word “about”. Numerical ranges expressed in “from x to y” format should be understood to include both x and y. When multiple preferred ranges for a particular feature are described in “from x to y” format, it should be understood that all ranges combining different endpoints are also considered.

[0006] Composition The compositions described herein are transparent. For purposes of the present application, transparency is measured by percent transmittance. The percent transmittance of the formulation is from 60 to 100%, more preferably from 60 to 100%, more preferably from 70 to 100%, most preferably from 80 to 90%. Percent transmittance is measured at 25°C, can be suitably measured using a Turbiscan® LAB, available from Formulation Scientific Instruments, at a wavelength of 880 nm, equipped with glass vials having a diameter of 25 mm and a height of 55 mm. The transparent formulation can include a dye to color the formulation, but the dye preferably does not affect the transparency of the formulation.

[0007] The compositions include a perfume. The compositions preferably include from 0.1 to 20% by weight of the composition of a perfume, more preferably from 0.5 to 10% by weight of the composition of a perfume. Many examples of suitable perfumes can be found in the CTFA (Cosmetic, Toiletry and Fragrance Association) 1992 International Buyers Guide, published by CFTA Publications, and the OPD 1993 Chemicals Buyers Directory 80th Annual Edition, published by Schnell Publishing Co.

[0008] A variety of perfume ingredients are typically present in a free oil perfume composition. In the compositions for use in the present application, it is contemplated that there are three or more, preferably four or more, more preferably five or more, most preferably six or more.

[0009] The compositions described herein include an ethoxylated triglyceride. The compositions preferably include from 1 to 30% by weight of the composition of an ethoxylated triglyceride, more preferably from 2 to 25% by weight of the composition of an ethoxylated triglyceride, most preferably from 4 to 20% by weight of the composition of an ethoxylated triglyceride.

[0010] The triglyceride can be any suitable triglyceride. Preferably, the triglyceride is fully saturated. Full saturation can be naturally occurring or can be achieved by hydrogenation. Preferably, the triglyceride chains include alcohol groups. Preferred sources of triglycerides are plant oils and combinations thereof. Preferably, the triglyceride is derived from oils of almond, argan, babassu, borage, camelina, canola, castor, chia, cherry, coconut, corn, cottonseed, coffee, cuphea ( Cuphea viscosissima ), flax (linseed), grape, hepar, jatropha, jojoba, lesquerellaLesquerella fendleri Moringa oleifera

[0011] The ethoxylated triglyceride preferably has a degree of ethoxylation of 6 to 100 moles, more preferably 12 to 80 moles, even more preferably 20 to 60 moles. Most preferably, the ethoxylated triglyceride has a degree of ethoxylation of about 40 moles (i.e. 35 to 45 moles).

[0012] Most preferably, the ethoxylated triglyceride comprises PEG-40 hydrogenated castor oil. The ethoxylated triglyceride can increase the transparency of the formulation. Preferably, the ratio of perfume to ethoxylated triglyceride is 1 : 1 to 1 : 15, more preferably 1 : 2 to 1 : 10.

[0013] The composition described herein preferably comprises a bead having a diameter of 50 μιη to 2000 μιη. The composition comprises 0.001 to 10 wt% of the bead by weight of the composition, preferably 0.005 to 5 wt% of the bead, more preferably 0.01 to 2 wt% of the bead by weight of the composition.

[0014] The bead can be made of any suitable material. The bead preferably has a structure formed of an inorganic material, a plant-based solid or wax, a polymeric material, or a combination thereof.

[0015] Inorganic materials include materials such as clays (e.g. bentonite), silicates (e.g. sodium or potassium silicate), carbonates (e.g. calcium carbonate), or materials containing calcium, phosphorus, potassium, sodium, chlorine, magnesium, iron, or zinc. Preferably, the inorganic material is selected from clays, silicates, carbonates, and combinations thereof.

[0016] Plant-based solids are taken from hard materials in plants, such as the pit in fruits or the shell of nuts. The plant-based solid is preferably selected from olive pits, almond shells, peach pits, pistachio shells, avocado shells, apricot pits, argan shells, walnut shells, jojoba seeds, oats, bamboo, loofah, strawberry seeds, raspberry seeds, blackberry seeds, and combinations thereof. The plant solids can be ground to a suitable particle size. Plant-based waxes, such as beads made from hydrogenated plant oils such as hydrogenated jojoba oil or hydrogenated castor oil, suitable examples of beads formed from plant-based waxes are available from Vantage.

[0017] ​​The polymeric material comprises any polymer capable of forming a bead having a diameter of from 50 μιη to 2000 μιη. Preferably, the polymer is a polysaccharide. The polysaccharide is preferably selected from cellulose (including microcrystalline cellulose, carboxymethyl cellulose and other cellulose ethers, hydroxyethyl cellulose and hydroxypropyl cellulose), guar gum, agar agar, carrageenan, alginate, pectin, hemicellulose, alginate, locust bean gum, starch, gelatin, xanthan gum and combinations thereof. More preferably, the polysaccharide comprises cellulose (including microcrystalline cellulose, carboxymethyl cellulose and other cellulose ethers, hydroxyethyl cellulose and hydroxypropyl cellulose) and combinations thereof. Preferably, the bead comprises from 10 to 100 wt% of the polysaccharide based on the weight of the bead, more preferably from 15 to 95 wt% of the polysaccharide based on the weight of the bead, most preferably from 25 to 90 wt% of the polysaccharide based on the weight of the bead.

[0018] In addition to the inorganic material, plant-based solid or wax or polymeric material, the bead can comprise a sugar, sugar alcohol or combination thereof. Suitable sugars or sugar alcohols include lactose, sucrose, dextrose, mannitol, xylitol, sorbitol, isomalt, lactitol, erythritol and combinations thereof. The bead preferably comprises from 5 to 80 wt% of the sugar, sugar alcohol or combination thereof based on the weight of the bead, more preferably from 10 to 70 wt%, most preferably from 15 to 60 wt%.

[0019] The bead can preferably comprise an optical enhancer, preferably a pearlescer, pigment, dye and combinations thereof. The optical enhancer should not adhere to the fabric, it is used to enhance the aesthetics of the bead. It is particularly preferred for mineral or polymeric beads.

[0020] The bead can primarily consist of the inorganic material, plant-based solid or wax, or polymeric material, optionally further comprising a small amount of optical enhancer. Alternatively, the bead can primarily consist of the inorganic material, plant-based solid or wax, or polymeric material together with a sugar and / or sugar alcohol, optionally further comprising a small amount of optical enhancer.

[0021] Alternatively, when the bead is a mineral or polymeric based bead, it can comprise a benefit agent, preferably a benefit agent selected from: a perfume, a perfume microcapsule, an oil, a silicone, a plant extract, a fabric care ingredient, a vitamin, an enzyme, a shading dye, an antibacterial agent, a deodorising or odour control agent, a fabric softening agent, an insect repellent, a shading or hueing dye, a fabric dye, a soil release agent, a sunscreen agent and combinations thereof. Preferably, the bead comprises a hydrophobic benefit agent, for example a perfume. When present, the bead preferably comprises from 0.01 to 50 wt% of the benefit agent based on the weight of the bead, more preferably from 1 to 40 wt% of the benefit agent, even more preferably from 4 to 30 wt% of the benefit agent, most preferably from 6 to 25 wt% of the benefit agent based on the weight of the bead.

[0022] The beads can be prepared by mixing all raw material components, preferably in powder form. Water and / or other aqueous components are then added to the powder, mixed to form lumps, and then granulated. The wet granules are dried to reduce their moisture content. Conventional drying methods, such as air drying, spray drying, belt drying, freeze drying, drum drying, or flash drying, can be used to dry the lumps.

[0023] An example of commercially available polysaccharide beads is Unispheres®, purchased from Givaudan.

[0024] The compositions described herein preferably comprise a network-forming polymer. The network-forming polymer is a crosslinked polymer. The polymer may be crosslinked prior to addition to the composition, or may be crosslinked in the formulation, or may be crosslinked prior to addition to the composition and further crosslinked in the formulation. Preferably, the polymer is crosslinked prior to addition to the composition and further crosslinked in the composition.

[0025] The compositions described herein preferably contain 0.05 to 5% by weight of a network-forming polymer, more preferably 0.01 to 2% by weight of a network-forming polymer.

[0026] The polymer forming the network can be a synthetic, natural, or modified natural polymer (e.g., microfibrillated cellulose, which can be derived from bacteria, fungi, or plants, including wood).

[0027] The polymer forming the network can be cationic or anionic, or it can be neutral. Preferably, the polymer forming the network is anionic or neutral, and most preferably anionic.

[0028] The synthesized network-forming polymers may include polycarboxylates (esters), polyacrylates, hydrophobically modified ethoxylated carbamates, hydrophobically modified nonionic polyols, acrylic polymers, polyamino acids, polyuronic acids, polyethylene sulfonic acid, polyolefin dicarboxylic acids, and mixtures thereof. Polycarboxylate (ester) polymers may include polyacrylates, polymethacrylates, or mixtures thereof. Polyacrylates may, for example, include unsaturated mono- or dicarbonic acid (carboxylic acid) and (meth)acrylic acid at C1-C... 30Copolymers of alkyl esters. The term "acrylic polymers" means homopolymers or copolymers comprising at least acrylic acid or methacrylic acid as monomer. Polysaccharide acids include homopolymers or copolymers of these sugar acids. The term "polyvinylsulfonic acids" includes homopolymers or copolymers comprising vinylsulfonic acid as monomer. Within the scope of the present invention, the term "polyolefinic dicarboxylic acids" includes for example homopolymers or copolymers comprising maleic acid or fumaric acid as monomer. Suitable polymers are commercially available under the trade name Acusol from Dow, and under the trade name Carbopol Aqua 30 or Carbopol aqua CC. from Lubrizol.

[0029] The natural network-forming polymer is preferably a polysaccharide. Suitable polysaccharides are selected from the group consisting of pectin, alginate, arabinogalactan (gum arabic), carrageenan, gellan gum, locust bean gum, xanthan gum, guar gum, and mixtures thereof. The modified natural polymer is preferably a modified polysaccharide. Suitable modified polysaccharides can include hydroxyethylcellulose, hydrophobically modified hydroxyethylcellulose, carboxymethylcellulose, and mixtures thereof.

[0030] Preferably, the network-forming polymer is selected from the group consisting of polyacrylates, polysaccharides, polysaccharide derivatives, or combinations thereof. Preferably, the network-forming polymer is anionic. Preferably, the network-forming polymer is hydrophobically modified.

[0031] Particularly preferred polyacrylates include HASE polymers selected from crosslinked copolymers prepared by polymerizing a monomer mixture comprising: (i) 5 to 85%, more preferably 25 to 70%, most preferably 35 to 65%, of a nonionic monomer (based on the total weight of the monomer mixture); (ii) 5 to 85%, more preferably 25 to 70%, most preferably 35 to 65%, of an anionic or anionizable monomer (based on the total weight of the monomer mixture); (iii) 0.5 to 35%, more preferably 1 to 25%, of a hydrophobic monomer (based on the total weight of the monomer mixture), the hydrophobic monomer having an ethylenically unsaturated moiety (for addition polymerization with other monomers in the mixture) and a hydrophobic moiety; (iv) optionally 0.001 to 5%, preferably 0.01 to 0.1%, of a polyethylenically unsaturated copolymerizable monomer effective for crosslinking (based on the total weight of the monomer mixture).

[0032] The nonionic monomer (i) is suitably selected from the group consisting of C1-C8 alkyl esters and C2-C8 hydroxyalkyl esters of acrylic acid and methacrylic acid. Preferred are ethyl acrylate, methyl acrylate, and butyl acrylate.

[0033] The anionic or anionizable monomer (ii) is suitably selected from acrylic acid, methacrylic acid, crotonic acid, 2-acrylamido-2-methyl-1-propanesulfonic acid, vinylsulfonic acid sodium salt, itaconic acid, fumaric acid, maleic acid, itaconic acid monomethyl ester, fumaric acid monomethyl ester, fumaric acid monobutyl ester, and maleic anhydride. Preferred are acrylic acid and methacrylic acid.

[0034] In one suitable hydrophobic monomer (iii), the hydrophobic moiety consists of a homopolymer, random copolymer, or block copolymer chain of repeating units selected from C1-C 22 alkyl acrylate, C1-C 22 alkyl methacrylate, methacrylic acid, acrylic acid, or combinations thereof. Examples of such units include methyl methacrylate, ethyl methacrylate, butyl methacrylate, ethylhexyl methacrylate, stearyl methacrylate, and mixtures thereof. One of the units is left at the end of the chain as the ethylenically unsaturated moiety for addition polymerization with other monomers in the mixture. Such hydrophobic monomers are often referred to as "macromonomers" and can be prepared by catalytic chain transfer (CCT) methods using catalysts effective for achieving CCT, such as cobalt porphyrins and cobalt oximes. The macromonomers desirably have a number average molecular weight (Mn, as determined by liquid permeation chromatography) of from about 200 to about 50,000, preferably from about 400 to about 10,000, most preferably from about 500 to about 3,000. Examples of preferred macromonomers include polymethyl methacrylate / poly(methacrylic acid), polymethyl methacrylate, poly(butyl methacrylate), poly(ethylhexyl methacrylate), and combinations thereof. Another suitable hydrophobic monomer (iii) includes a polyoxyalkylene moiety between the ethylenically unsaturated moiety and the hydrophobic moiety. Such hydrophobic monomers are sometimes referred to as "surfmers" and can generally be prepared by acid-catalyzed condensation reactions of commercially available nonionic polyoxyalkylene surfactant alcohols with acrylic acid, methacrylic acid, crotonic acid, maleic acid, fumaric acid, itaconic acid, or aconitic acid. Examples of preferred surfactants include C8-C 30 alkylated polyethoxylated (meth)acrylates (i.e., methacrylate and / or acrylate esters) in which the polyethoxylated moiety comprises from about 5 to about 100, preferably from about 10 to about 80, more preferably from about 15 to about 60 ethylene oxide (EO) units, such as C 18 H 37 (EO) 2O (meth)acrylate and C 12 H 25 (EO) 23 methacrylate.

[0035] The crosslinking comonomer (iv) can suitably be selected from diallyl phthalate, divinyl benzene, allyl methacrylate, trimethylolpropane triacrylate, ethylene glycol diacrylate or ethylene glycol dimethacrylate; 1,6-hexanediol diacrylate or 1,6-hexanediol dimethacrylate; and diallyl benzene.

[0036] Particularly preferred polysaccharides include cellulose and xanthan gum. Particularly preferred polysaccharide derivatives include hydroxyethyl cellulose, hydrophobically modified hydroxyethyl cellulose, carboxymethyl cellulose and mixtures thereof.

[0037] The network-forming polymer preferably has a weight average molecular weight (Mw) of from about 30,000 g / mol to about 10,000,000 g / mol, for example from about 30,000 to about 500,000 g / mol, more typically from 50,000 g / mol to 500,000 g / mol. The molecular weight can be determined by physical properties such as intrinsic viscosity or spectrophotometric analysis such as light scattering.

[0038] The composition can comprise a single species of network-forming polymer, or can comprise a mixture of different polymers to provide optimum performance.

[0039] The composition described herein preferably comprises an alcohol ethoxylate. The composition preferably comprises from 1 to 30 wt% of an alcohol ethoxylate, more preferably from 2 to 25 wt% of an alcohol ethoxylate, most preferably from 4 to 20 wt% of an alcohol ethoxylate.

[0040] The alcohol ethoxylate has the formula: RO(CH2CH2O) x H R represents a fatty alcohol chain. Preferably, R is saturated. Preferably, R = C8to C 24 fatty alcohol, more preferably, R = C 10 to C 22 fatty alcohol, even more preferably, R = C 12 to C 20 fatty alcohol, most preferably, R = C 16 to C 18 fatty alcohol. In other words, preferably, the alcohol ethoxylate comprises C8to C 24 fatty alcohol, more preferably comprises C 10 to C 22 fatty alcohol, most preferably, R = C 16 to C 18 fatty alcohol.

[0041] x represents the degree of ethoxylation. Preferably, x is from 5 to 100, more preferably from 10 to 80, even more preferably from 12 to 60, most preferably from 15 to 40. In other words, preferably, the alcohol ethoxylate comprises from 5 to 100 ethoxy groups, more preferably from 12 to 60 ethoxy groups, most preferably from 15 to 40 ethoxy groups.

[0042] Most preferably, the alcohol ethoxylate comprises R = C 16 to C 18 a fatty alcohol, and x = 25. A suitable commercially available material is available under the trade name Lutensol AT25 from BASF.

[0043] When the composition is used with a fabric conditioner, the alcohol ethoxylate prevents residue in the rinse drawer.

[0044] The composition described herein preferably comprises both an ethoxylated triglyceride and an alcohol ethoxylate. The ratio of ethoxylated triglyceride to alcohol ethoxylate is preferably from 1 : 2 to 2 : 1, more preferably from 2 : 3 to 3 : 2.

[0045] The pH of the composition described herein is preferably from 4 to 9. The composition can comprise a pH adjusting agent to achieve the desired pH. A suitable acidic pH adjusting agent is hydrochloric acid. A suitable basic pH adjusting agent is triethanolamine.

[0046] The composition described herein preferably comprises a benefit agent. Benefit agents are known to those skilled in the art to impart benefits to fabrics. Such ingredients include: perfumes, perfume carriers, antibacterial agents, deodorizing or malodour control agents, fabric softening agents, insect repellents, shading or hueing dyes, fabric dyes, hydrotropes, anti-redeposition agents, soil release agents, anti-wrinkling agents, antioxidants, sunscreens, anti-static agents, chelants, and ironing aids.

[0047] The composition described herein preferably further comprises a preservative. Suitable preservatives include isothiazolinones, organic acids, alcohols, or combinations thereof. In particular, the preservative is preferably selected from the group consisting of benzisothiazolinone (BIT), methylisothiazolinone (MIT), lactic acid, citric acid, sodium benzoate, sodium citrate, itaconic acid, potassium sorbate, anisic acid, phenoxyethanol, propylene glycol, and combinations thereof. Certain preservatives can require a pH adjusting agent to maintain an optimal pH.

[0048] The composition described herein preferably can further comprise a dye to color the composition. Such dyes are used to color the composition, but do not attach to the fabric. Such dyes are available under the trade name Liquitint from Milliken.

[0049] The compositions described herein preferably can comprise a chelating agent. It will be appreciated that the chelating agent can prevent the composition from yellowing. This is particularly important for transparent formulations. An example of a suitable chelating agent is available under the trade name Dequest 2010 or 2066.

[0050] The compositions described herein are fragrance boost compositions. The aim is to provide additional perfume to the laundry process, rather than to provide cleaning or conditioning benefits. Thus, the compositions preferably comprise from 0 to 7 wt% of a cationic surfactant, an anionic surfactant or a mixture thereof, based on the weight of the composition. More preferably, the compositions comprise from 0 to 4 wt% of a cationic surfactant, an anionic surfactant or a mixture thereof, based on the weight of the composition; even more preferably from 0 to 2 wt% and most preferably from 0 to 1 wt% of a cationic surfactant, an anionic surfactant or a mixture thereof, based on the weight of the composition.

[0051] The compositions of the present application preferably comprise water. Preferably, the compositions comprise greater than 50 wt% water, more preferably at least 60 wt% water, based on the weight of the composition. A suitable upper limit is preferably 98 wt% of the composition.

[0052] The compositions described herein can be prepared by any suitable method. Preferably, when perfume and ethoxylated triglyceride are both present, these ingredients are pre-mixed before being added to the main mix. Preferably, the water used for the main mix is heated to 30 to 70°C, more preferably 40 to 60°C, before any other ingredients are added.

[0053] The compositions described herein can be used at any stage of the laundry process to deliver a benefit agent to the laundry process. Preferably, the compositions are used in the rinse stage. The compositions can be used with a fabric conditioner or can be used alone. Preferably, the compositions are used with a fabric conditioner. In one aspect of the present application, there is provided a method wherein the compositions described herein are added to the rinse stage of the laundry process. Preferably, the compositions are added to the rinse stage of the laundry process in addition to a fabric conditioner. In one aspect of the present application, there is provided the use of the compositions described herein to provide a fragrance to the rinse stage of the laundry process.

[0054] Packaging The compositions described herein are packaged or contained in a container wherein the container comprises from 25 to 100 wt% post-consumer recycled resin, based on the weight of the container.

[0055] Within the scope of the present application, the term "post-consumer recycled resin (PCR)" generally refers to plastic that is collected, sorted, cleaned and reprocessed into pellets through established post-consumer recycling channels.

[0056] PCR is preferably made from mechanically recycled plastics, typically packaging plastics, see Mechanical Recycling of Packaging Plastics: A Review, Z. O. G. Schyns,; M. P. Shaver Macromol. Rapid. Commun. 2021, 42, 2000415.

[0057] Types of post-consumer recycled resins include: recycled high-density polyethylene (HDPE), recycled polypropylene (PP), recycled low-density polyethylene (LDPE), recycled medium-density polyethylene, and recycled polyethylene terephthalate (PET).

[0058] Preferably, the post-consumer recycled resin is selected from recycled polyethylene terephthalate (PET), recycled polypropylene (PP), or a combination thereof. More preferably, the post-consumer recycled resin is transparent, most preferably the post-consumer recycled resin is transparent PET. The transparency of the post-consumer recycled resin is measured by the “haze” of the material. Haze is measured as the percentage of incident light that is scattered by the plastic sample at more than 2.5°. Haze is measured as a percentage, with lower values indicating higher transparency. Haze can be measured using ASTM D1003. The post-consumer recycled resin has a haze % of 0 to 15%, more preferably 0 to 10%, even more preferably 0 to 5%, most preferably 0 to 2.5%.

[0059] The container is preferably a bottle with a cap. The container is preferably blow molded. Blow molding involves making a parison or preform and placing and clamping it in a mold. Air is introduced into the parison / preform, causing it to expand, thus filling the space within the mold. Once the plastic has sufficiently hardened, the mold is opened and the formed article is removed.

[0060] Preferably, the container comprises 30 to 100% PCR, more preferably 50 to 100% and even more preferably 75 to 100% PCR, most preferably comprises 95 to 100% PCR.

[0061] The container can be made of a multi-layer material. This material can comprise multiple layers (more than one layer) of the same post-consumer recycled resin, or it can comprise multiple layers (more than one layer) of different post-consumer recycled resins, or it can comprise a mixture of at least one layer of post-consumer recycled resin and at least one layer of virgin resin. When a layer of virgin resin is used, preferably this material does not come into contact with the composition, i.e. the layer of post-consumer recycled resin is the innermost layer of the bottle, directly in contact with the composition.

[0062] Example Table 1: Example composition

[0063] The composition can be prepared by premixing the perfume and ethoxylated triglyceride. Water is then heated to 50°C and the preservative, alcohol ethoxylate, premix, polymer and pH adjuster are added. The pH is checked and adjusted to 7.6. Finally the mixture is cooled to room temperature.

Claims

1. A container comprising a transparent laundry fragrance enhancer composition, wherein the transparent laundry fragrance enhancer composition comprises: a) Spices; and b) Ethoxylated triglycerides; The container contains 25 to 100% by weight of post-consumer recycled resin. The light transmittance of the transparent laundry fragrance enhancer composition is 60 to 100%.

2. The container comprising a transparent laundry fragrance enhancer composition according to claim 1, wherein the composition comprises 1 to 30% by weight of ethoxylated triglycerides based on the weight of the composition.

3. The container comprising a transparent laundry fragrance enhancer composition according to any one of the preceding claims, wherein the triglycerides are fully saturated.

4. A container comprising a transparent laundry fragrance enhancer composition according to any one of the preceding claims, wherein the triglyceride has a degree of ethoxylation of 6 to 100 moles.

5. A container comprising a transparent laundry fragrance enhancer composition according to any one of the preceding claims, wherein the ethoxylated triglyceride comprises PEG-40 hydrogenated castor oil.

6. A container comprising a transparent laundry fragrance enhancer composition according to any one of the preceding claims, wherein the composition comprises 0.1 to 20% by weight of fragrance based on the weight of the composition.

7. A container comprising a transparent laundry fragrance enhancer composition according to any one of the preceding claims, wherein the composition further comprises beads having a diameter of 50 μm to 2000 μm.

8. The container comprising a transparent laundry fragrance enhancer composition according to claim 7, wherein the beads have a structure formed of inorganic materials, plant-based solids or waxes, polymeric materials or combinations thereof.

9. A container comprising a transparent laundry fragrance enhancer composition according to any one of the preceding claims, wherein the composition comprises a polymer forming a network.

10. A container comprising a transparent laundry fragrance enhancer composition according to any one of the preceding claims, wherein the composition comprises an alcohol ethoxylate.

11. A container comprising a transparent laundry fragrance enhancer composition according to any one of the preceding claims, wherein the post-consumer recycled resin comprises recycled polyethylene terephthalate (PET), recycled polypropylene (PP), or a combination thereof.

12. A container comprising a transparent laundry fragrance enhancer composition according to any of the preceding claims, wherein the post-consumer recycled resin is transparent and the haze % of the post-consumer recycled resin is 0 to 15% as measured by ASTM D1003.

13. A container comprising a transparent laundry fragrance enhancer composition according to any one of the preceding claims, wherein the post-consumer recycled resin is transparent recycled polyethylene terephthalate (PET).