Polynuclear diimine ligand compounds, polynuclear diimine catalysts, and methods of making and using the same

CN122167308APending Publication Date: 2026-06-09合肥中科科乐新材料有限责任公司

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
合肥中科科乐新材料有限责任公司
Filing Date
2026-02-14
Publication Date
2026-06-09

AI Technical Summary

Technical Problem

Traditional mononuclear diimine nickel catalysts have limitations in terms of thermal stability, branching degree control, and catalyst life, making it difficult to meet the performance requirements of high-end polyolefin materials.

Method used

Polynuclear diimine ligand compounds and polynuclear diimine catalysts were designed to enhance thermal stability and reactivity through the synergistic effect of multiple metal centers, enabling precise control of polymer branching degree. Specific substituent groups were used to regulate catalyst performance.

Benefits of technology

It significantly improves the thermal stability and reactivity of the catalyst, enabling it to maintain high catalytic performance under high temperature conditions, achieve efficient synthesis of branched polyethylene, and meet the performance requirements of high-end polyolefin materials.

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Abstract

The present disclosure provides a polynuclear diimine ligand compound, a polynuclear diimine catalyst and a preparation method and application thereof, and belongs to the technical field of polyolefins. The polynuclear diimine ligand compound has a structure as shown in formula (I), wherein R1 and R2 are each independently selected from hydrogen, methyl, ethyl, C3-C8 isomerized alkyl, benzhydryl, methoxy, 4-tert-butylphenyl and biphenyl; and R3 is selected from hydrogen, methyl, ethyl, methoxy, C3-C8 isomerized alkyl, halogen and nitro. Formula (I).
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