A water conditioner and its preparation method and application

Abstract

The present application belongs to the technical field of water body additive, and provides a water body regulator, a preparation method and application thereof. The water body regulator of the present application combines inorganic composite peroxide bridge system with synergistic mediation system and photosynthetic irritation system, which have different functional active sites, to form a system in which various active ingredients coexist in the form of mainly biomimetic non-free radical singlet oxygen and free radical cluster synergy in the aquaculture water body. The oxygen hole site content in the synergistic mediation system and the whole abiotic phase system of the aquaculture water body determine the high content of biomimetic non-free radical singlet oxygen. The double-track mediation of free radical cluster and biomimetic non-free radical singlet oxygen and the high content of biomimetic non-free radical singlet oxygen can realize the purification treatment of leftover feed, organic pollutants, pathogenic microorganisms and toxic phase in the aquaculture water body, accelerate the realization of six-phase balance of the aquaculture water body, safe aquaculture, and ensure the green health of aquatic products.

Description

Technical Field

[0001] This invention relates to the field of water additives, and in particular to a water conditioner, its preparation method, and its application. Background Technology

[0002] Aquaculture is the fastest-growing sector of animal food production. Water is the core resource in aquaculture, and maintaining its quality is crucial. Micropollutants (MPs) can enter aquaculture through anthropogenic addition or influent, potentially causing harmful effects such as endocrine disorders and antibiotic resistance, negatively impacting farmed fish. Furthermore, the discharge of aquaculture wastewater into the environment can lead to waterway deterioration. In this sense, implementing environmentally responsible measures at aquaculture farms is essential for protecting ecosystems and human health.

[0003] With the rapid development of aquaculture in my country, its proportion in the overall aquaculture industry is constantly increasing. Due to expanding market demand, the stocking density of aquaculture farmers is also continuously increasing. Increased stocking density accelerates water quality aging and deterioration. Water quality indicators such as ammonia nitrogen, nitrite, hydrogen sulfide, and dissolved oxygen are difficult to control. Coupled with weather changes, such as rain and storms, fluctuations in water temperature and salinity cause osmotic pressure imbalances, stress, and decreased immunity in farmed animals, making them susceptible to outbreaks of pathogens and resulting in aquaculture failure. Previously, aquaculture farmers heavily relied on antibiotics for disease prevention and control. However, the overuse of antibiotics further accelerates water quality deterioration, causing secondary stress to farmed animals, making disease control even more difficult, and easily leading to outbreaks of mortality and affecting animal quality. Therefore, timely water quality control, sterilization, detoxification, and immune enhancement to increase the success rate of aquaculture have become crucial issues for the sustainable development of the aquaculture industry.

[0004] Currently, existing technologies disclose the use of potassium persulfate (PMS) to treat aquaculture water, but PMS treatment has a weak ability to decompose toxins in aquaculture water. Summary of the Invention

[0005] In view of this, the purpose of this invention is to provide a water conditioner, its preparation method, and its application. The water conditioner provided by this invention has a strong ability to decompose toxins in water.

[0006] To achieve the above-mentioned objectives, the present invention provides the following technical solution:

[0007] This invention provides a water conditioner comprising the following components by mass percentage:

[0008] Inorganic composite peroxygen bridge system 20%–90%, synergistic mediation system 0.05%–2%, comprehensive balance system 6%–25%, photosynthetic stimulation system 2%–20%, stabilization system 1%–25%;

[0009] The inorganic composite peroxy bridge system includes a first component and a second component. The first component includes a sodium sulfate-hydrogen peroxide-sodium chloride adduct, a sodium citrate-hydrogen peroxide-sodium chloride adduct, or a sodium phosphate-hydrogen peroxide-sodium chloride adduct. The second component includes one or more of potassium peroxymonosulfate, calcium peroxide, sodium persulfate, and sodium perborate.

[0010] The synergistic mediating system comprises the following components by mass percentage: 10%–20% magnesium valproate, 20%–30% manganese oxide, and 50%–70% rare earth oxides;

[0011] The integrated balance system includes one or more of the following: calcium sulfate, magnesium sulfate, calcium formate, potassium phosphate, sodium pyrophosphate, sodium silicate, and sodium sulfate.

[0012] The photosynthetic irritation system includes one or more of titanium dioxide, sodium percarbonate, and magnesium oxide;

[0013] The stabilizing system includes one or more of potassium diformate, citric acid, malic acid, aminosulfonic acid, and succinic acid.

[0014] Preferably, the water conditioner comprises the following components by mass percentage: 65% inorganic composite peroxy-bridging system, 0.1% synergistic mediating system, 12% comprehensive balancing system, 12.9% photosynthetic irritation system, and 10% stabilizing system.

[0015] Preferably, in the inorganic composite peroxy bridge system, the mass ratio of the first component to the second component is 7-9:4-6.

[0016] Preferably, in the synergistic mediation system, the rare earth oxide includes one or more of neodymium oxide, samarium oxide, europium oxide, ytterbium oxide, praseodymium oxide, and gadolinium oxide.

[0017] Preferably, the integrated balance system includes magnesium sulfate, calcium formate, and potassium phosphate; the mass ratio of magnesium sulfate, calcium formate, and potassium phosphate is 2-4:1-3:0.5-1.5.

[0018] Preferably, the photosynthetic irritation system comprises titanium dioxide, sodium percarbonate, and magnesium oxide; in the photosynthetic irritation system, the mass ratio of titanium dioxide, sodium percarbonate, and magnesium oxide is 56-60:48-52:17-22.

[0019] Preferably, the stabilizing system comprises potassium diformate, citric acid, and aminosulfonic acid; in the stabilizing system, the mass ratio of potassium diformate, citric acid, and aminosulfonic acid is 2-4:1-3:4-6.

[0020] This invention also provides a method for preparing the water conditioner described in the above technical solution, comprising the following steps:

[0021] The water conditioner is obtained by mixing the inorganic composite peroxy-bridge system, the synergistic mediation system, the comprehensive balance system, the photosynthetic stimulation system, and the stabilization system.

[0022] The present invention also provides the application of the water conditioner described in the above technical solution in aquaculture water.

[0023] Preferably, the dosage of the water conditioner is 0.3–5 g / m³. 3 .

[0024] This invention provides a water conditioning agent.

[0025] The water conditioner of this invention combines an inorganic composite peroxy-bridge system with different functional activation sites, a synergistic mediating system, and a photosynthetic stimulation system. In aquaculture water, this forms a system dominated by biomimetic non-free radical singlet oxygen and free radical clusters (SO4). - CO3 - ·、(·OH),(·Cl),(HO2·),(RCOO·),(superoxide anion radical: O 2- This system is a coexistence of multiple active ingredients with the synergistic effect of free radicals. The content of oxygen cavitation sites and the entire abiotic phase of the aquaculture water body, synergistically mediated by these free radicals, determines the high content of biomimetic non-free radical singlet oxygen. The dual-track mediation of free radical clusters and biomimetic non-free radical singlet oxygen, along with its high content, enables the purification of residual feed, organic pollutants, pathogenic microorganisms, and toxic phases in the aquaculture water body. This accelerates the achievement of balance in the six phases of the aquaculture water body (bacterial, algal, planktonic, ionic, microbial, and toxic phases), ensuring safe aquaculture and guaranteeing the green and healthy aquatic products. Specifically:

[0026] (1) Eliminate and inhibit bacteria, fungi, viruses and insects in the water, maintain a low concentration that does not cause disease, and effectively balance the aquaculture water.

[0027] (2) Enhance decomposers: decompose ammonia nitrogen, nitrite, hydrogen sulfide and organic pollutants, and repay the large amount of oxygen debt generated at the bottom of the pool; prevent microorganisms from being overloaded.

[0028] (3) Promote producers: Make full use of the nutrients produced by the degradation of organic pollutants to achieve production balance regulation of bacterial, algal and planktonic phases and eliminate the accumulation of harmful substances.

[0029] (4) Retaining Consumers: The biomimetic design of singlet oxygen forms a large number of ecological nano-singlet oxygen microbubbles in the aquaculture water. These microbubbles remain on the oxygen bridges of hydrated cells for extended periods (more than half an hour), forming microbubble air-float bodies carrying relaxation energy (biophoton energy). These microbubble air-float bodies are distributed throughout the water body, promoting water health. After absorbing the energy, fish and shrimp improve their immunity and reduce mortality; at the same time, they promote growth and development, increase weight, improve meat quality, enhance protein safety, and increase yield.

[0030] (5) The design incorporates a variety of active ingredients, including free radicals and singlet oxygen, with a focus on ecological disease prevention. It is broadly applicable to bacteria, fungi, viruses, chlamydia, mycoplasma, etc., without the need for antibiotics or halogen preparations, thus ensuring the safety of aquatic food.

[0031] (6) Balance and increase the beneficial trace mineral elements in the water. The product degradation produces sodium, potassium, calcium and magnesium ions, which are essential for aquaculture water. It also synergistically mediates the degradation of trace mineral elements such as zinc, manganese, neodymium and ytterbium, which promote the growth of aquatic animals.

[0032] (7) Application environment: It can eliminate, detoxify, and balance the six phases of water quality throughout the entire aquaculture process, providing health care throughout the entire process with one agent, ensuring safe detoxification and green aquaculture. Detailed Implementation

[0033] This invention provides a water conditioner comprising the following components by mass percentage:

[0034] Inorganic composite peroxygen bridge system 20%–90%, synergistic mediation system 0.05%–2%, comprehensive balance system 6%–25%, photosynthetic stimulation system 2%–20%, stabilization system 1%–25%;

[0035] The inorganic composite peroxy bridge system includes a first component and a second component. The first component includes a sodium sulfate-hydrogen peroxide-sodium chloride adduct, a sodium citrate-hydrogen peroxide-sodium chloride adduct, or a sodium phosphate-hydrogen peroxide-sodium chloride adduct. The second component includes one or more of potassium peroxymonosulfate, calcium peroxide, sodium persulfate, and sodium perborate.

[0036] The synergistic mediating system comprises the following components by mass percentage: 10%–20% magnesium valproate, 20%–30% manganese oxide, and 50%–70% rare earth oxides;

[0037] The integrated balance system includes one or more of the following: calcium sulfate, magnesium sulfate, calcium formate, potassium phosphate, sodium pyrophosphate, sodium silicate, and sodium sulfate.

[0038] The photosynthetic irritation system includes one or more of titanium dioxide, sodium percarbonate, and magnesium oxide;

[0039] The stabilizing system includes one or more of potassium diformate, citric acid, malic acid, aminosulfonic acid, and succinic acid.

[0040] Unless otherwise specified, the raw materials used in this invention are preferably commercially available products.

[0041] The water conditioner provided by this invention comprises an inorganic composite peroxy-bridge system at a mass percentage of 20% to 90%, preferably 40% to 70%, more preferably 50% to 65%, and specifically preferably 20%, 25%, 30%, 35%, 40%, 45%, 50%, 55%, 60%, 65%, or 70%. In this invention, the inorganic composite peroxy-bridge system comprises a first component and a second component, the mass ratio of which is preferably 7-9:4-6, more preferably 8:5. In this invention, the first component comprises a sodium sulfate-hydrogen peroxide-sodium chloride adduct, a sodium citrate-hydrogen peroxide-sodium chloride adduct, or a sodium phosphate-hydrogen peroxide-sodium chloride adduct, preferably a sodium citrate-hydrogen peroxide-sodium chloride adduct. In this invention, the second component comprises one or more of potassium peroxymonosulfate, calcium peroxide, sodium persulfate, and sodium perborate, preferably potassium peroxymonosulfate. In this invention, the particle size of the first and second components is independently preferably 60-120 mesh. In this invention, the moisture content of the components of the inorganic composite peroxy bridge system is preferably ≤0.2%. In a specific embodiment of this invention, the inorganic composite peroxy bridge system preferably comprises a sodium citrate-hydrogen peroxide-sodium chloride adduct and potassium peroxymonosulfate, and the mass ratio of the sodium citrate-hydrogen peroxide-sodium chloride adduct to potassium peroxymonosulfate is preferably 8:5. In this invention, the inorganic composite peroxy bridge system can provide free radical clusters and singlet oxygen sources.

[0042] Based on the mass percentage of the inorganic composite peroxy-bridge system, the water conditioner provided by this invention includes a synergistic mediating system at a mass percentage of 0.05% to 2%, specifically preferably 0.05%, 0.1%, 0.15%, 0.2%, 0.5%, 1%, 1.5%, or 2%. In this invention, the synergistic mediating system comprises the following components at mass percentages: magnesium valproate 10-20%, manganese oxide 20-30%, and rare earth oxides 50-70%, preferably comprising the following components at mass percentages: magnesium valproate 15%, manganese oxide 25%, and rare earth oxides 60%. In this invention, the rare earth oxides preferably include neodymium oxide (Nd₂O₃), samarium oxide (Sm₂O₃), europium oxide (Eu₂O₃), ytterbium oxide (Yb₂O₃), and praseodymium oxide (Pr₆O₃). 11The system comprises one or more of gadolinium oxide (Gd₂O₃), more preferably neodymium oxide (Nd₂O₃). In this invention, the particle size of the components of the synergistic mediating system is independently preferably 60–120 mesh. In this invention, the moisture content of the components of the synergistic mediating system is independently preferably ≤0.2%. In this invention, the synergistic mediating system is capable of synergistically mediating the generation of free radical clusters and singlet oxygen.

[0043] Based on the mass percentage of the inorganic composite peroxy-bridge system, the water conditioner provided by this invention comprises a comprehensive balancing system with a mass percentage of 6% to 25%, preferably 10% to 20%, and specifically preferably 6%, 8%, 10%, 12%, 15%, 18%, 20%, 22%, or 25%. In this invention, the comprehensive balancing system comprises one or more of calcium sulfate, magnesium sulfate, calcium formate, potassium phosphate, sodium pyrophosphate, sodium silicate, and sodium sulfate, preferably including magnesium sulfate, calcium formate, and potassium phosphate. In this invention, the mass ratio of magnesium sulfate, calcium formate, and potassium phosphate in the comprehensive balancing system is preferably 2–4:1–3:0.5–1.5, more preferably 3:2:1. In this invention, the particle size of the components of the comprehensive balancing system is independently preferably 60–120 mesh. In this invention, the moisture content of the components of the comprehensive balancing system is independently preferably ≤0.2%. In this invention, the comprehensive balancing system can balance the stability of the product.

[0044] Based on the mass percentage of the inorganic composite peroxy-bridge system, the water conditioner provided by this invention includes a photosynthetic irritation system at a mass percentage of 2% to 20%, preferably 5% to 15%, and specifically preferably 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 12.9%, 13%, 14%, 15%, 16%, 17%, 18%, 19%, or 20%. In this invention, the photosynthetic irritation system includes one or more of titanium dioxide, sodium percarbonate, and magnesium oxide, preferably including titanium dioxide, sodium percarbonate, and magnesium oxide. In this invention, the mass ratio of titanium dioxide, sodium percarbonate, and magnesium oxide in the photosynthetic irritation system is preferably 40–70:48–70:17–30, more preferably 58:50:21, 70:60:30, or 40:70:20. In this invention, the particle size of the components of the photosynthetic stimulating system is preferably 60-120 mesh. In this invention, the moisture content of the components of the photosynthetic stimulating system is preferably ≤0.2%. In this invention, the photosynthetic stimulating system can enhance photosynthesis in aquaculture water.

[0045] Based on the mass percentage of the inorganic composite peroxy-bridge system, the water conditioner provided by this invention includes a stabilizing system at a mass percentage of 1% to 25%, preferably 5% to 20%, more preferably 10% to 15%, and specifically preferably 1%, 5%, 6.95%, 10%, 15%, 15.8%, 16%, 20%, or 25%. In this invention, the stabilizing system includes one or more of potassium diformate, citric acid, malic acid, sulfamic acid, and succinic acid, preferably including potassium diformate, citric acid, and sulfamic acid. In this invention, the mass ratio of potassium diformate, citric acid, and sulfamic acid in the stabilizing system is preferably 2-4:1-3:4-6, more preferably 3:2:5. In this invention, the particle size of the components of the stabilizing system is independently preferably 60-120 mesh. In this invention, the moisture content of the components of the stabilizing system is independently preferably ≤0.2%. In this invention, the stabilizing system can stabilize the pH value of the product and enhance storage and transportation safety.

[0046] In one specific embodiment of the present invention, the water conditioner preferably comprises the following components by mass percentage: 65% inorganic composite peroxy-bridging system, 0.1% synergistic mediating system, 12% comprehensive balancing system, 12.9% photosynthetic irritation system, and 10% stabilizing system.

[0047] In one specific embodiment of the present invention, the water conditioner preferably comprises the following components by mass percentage: 50% inorganic composite peroxy-bridging system, 0.2% synergistic mediating system, 18% comprehensive balancing system, 16% photosynthetic irritation system, and 15.8% stabilizing system.

[0048] In one specific embodiment of the present invention, the water conditioner preferably comprises the following components by mass percentage: 70% inorganic composite peroxy-bridging system, 0.05% synergistic mediating system, 10% comprehensive balancing system, 13% photosynthetic irritation system, and 6.95% stabilizing system.

[0049] This invention utilizes an inorganic composite peroxy-bridge system with different functional activation sites, a composite synergistic mediation system, and a photosynthetic stimulation system to form a biomimetic non-radical singlet oxygen-dominant free radical cluster (SO₄²⁻) in aquaculture water. 4- ·、CO 3- ·、(·OH),(·Cl),(HO2·),(RCOO·),(superoxide anion radical: O 2- A system in which multiple active ingredients coexist synergistically with free radicals.

[0050] In this invention, biomimetic non-radical singlet oxygen ( 1 O2 is a molecular oxygen in an excited state, which reacts with superoxide radicals (O2). 2- ), hydroxyl radical (·OH), sulfate radical (SO₄)4- Similar to free radicals such as ·), it is chemically active, has strong oxidizing power, and high reactivity. 1 O2 can selectively degrade electron-rich pollutants (including organic olefins, pharmaceuticals, and hormones); it is also an important factor that causes cell membrane damage and promotes apoptosis. 1 O2 can undergo oxidation reactions with many biomolecules, including DNA, lipids, free amino acids, and proteins. 1 O2 can also penetrate mitochondrial membranes or nucleic acids, causing DNA damage. 1 O2 can undergo oxidation reactions with residues of cysteine, histidine, tryptophan, methionine, and tyrosine. 1 O2 can also cause proteins to lose their function, causing intramolecular or intermolecular cross-linking of enzyme protein molecules, leading to changes in protein conformation and loss of activity. Importantly... 1 O2 oxidation does not produce toxic or harmful byproducts. Therefore, 1 O2 plays a crucial role in enzyme reactions, cell division, phagocytosis and sterilization, chemical poisoning, environmental pollution, and organic synthesis. Meanwhile, non-radical oxidation processes are more resistant to water body disturbances, meaning they are less affected by water pH and coexisting substances (inorganic anions and natural organic matter). Furthermore, non-radical oxidation processes have higher oxidant utilization efficiency, which can reduce the cost of water treatment technologies. In addition, plants absorb light quanta as an energy source during photosynthesis, forming active oxygen molecules... 1 O2, but 1 O2 existed for only about a thousandth of a second before immediately releasing quantum energy and reverting to its normal triplet state of oxygen, because 1 O2 has higher energy than triplet oxygen (O3p). The released photons (energy) are absorbed by water vapor in the air and retained briefly (about half an hour) on the oxygen bridges of hydrated cells. This energy is then reabsorbed into the human body through respiration, promoting cellular oxygen utilization and enhancing metabolism. All living organisms contain free radicals and singlet oxygen. Controlled free radicals and singlet oxygen are beneficial to organisms. Therefore, both free radicals and non-free radical singlet oxygen can help transfer energy to maintain life, kill bacteria and parasites, and participate in toxin elimination.

[0051] The water conditioner of this invention lowers the acidity of the internal environment of fish and shrimp, causing bacterial metabolic disorders and even lysis and death, indirectly reducing the number of harmful bacteria. Based on the principle of "resistance" and "resistance reduction," it improves feeding, digestibility, and weight gain. The water conditioner of this invention is halogen-free, with low toxicity and strong shock resistance; it is suitable for both shock-related applications and preventative balance throughout the entire aquaculture process; it does not produce carcinogenic halogenated hydrocarbons such as halothanes; it is environmentally friendly and produces no secondary toxins. The water conditioner of this invention has a high reactive oxygen species (ROS) content of 3.0-4.0% and a redox potential of 2.5-4.5V, which is crucial for the six-phase balance of aquaculture water. Free radicals also exist in the human body; controlled free radicals are beneficial to humans, fish, and shrimp; they can help transfer energy to maintain vitality, kill bacteria and parasites, and participate in toxin elimination. Singlet oxygen selectively inhibits pathogenic bacteria, fungi, viruses, and insects; selectively decomposes toxic substances; biomimetic water mist bubbles exhibit strong stress resistance, active pooling energy, and enhanced immunity and internal oxygen respiration. Free radical clusters (SO₄²⁻) 4- ·、CO 3- ·、(·OH),(·Cl),(HO2·),(RCOO·),(superoxide anion radical: O 2- This water conditioner contains more than 10 high-energy, highly active ingredients, including free radicals, which can rapidly inhibit pathogenic microorganisms and insects; improve the bottom and detoxify algal toxins, hydrogen sulfide, ammonia nitrogen, and nitrite; mineralize toxic organic matter; balance bacterial and algal communities; and convert itself into beneficial trace elements and small-molecule organic acids; and enhance dissolved oxygen and its utilization rate. The water conditioner of this invention also enhances photosynthesis, promotes the growth of bacterial and algal communities, inhibits and regulates the reproduction of pathogenic microorganisms, improves the immunity of fish and shrimp, increases lactone synthesis to improve yield, and promotes the balance of the six phases (biomass, microbiome, and tertiary phase).

[0052] This invention also provides a method for preparing the water conditioner described in the above technical solution, comprising the following steps:

[0053] The water conditioner is obtained by mixing the inorganic composite peroxy-bridge system, the synergistic mediation system, the comprehensive balance system, the photosynthetic stimulation system, and the stabilization system.

[0054] In this invention, the mixing is preferably carried out on a mixer, and the mixing time is preferably 0.2 to 1.0 h.

[0055] The present invention also provides the application of the water conditioner described in the above technical solution in aquaculture water.

[0056] In this invention, the preferred dosage of the water conditioning agent is 0.3–5 mg / m³. 3 .

[0057] The following detailed description of the water conditioner, its preparation method, and its application provided by the present invention, with reference to specific embodiments, should not be construed as limiting the scope of protection of the present invention.

[0058] In the examples, the particle size of each material was 60-120 mesh, and the moisture content was ≤0.2%.

[0059] Example 1

[0060] A water conditioner comprises the following components by mass percentage: 65% inorganic composite peroxy-bridge system (wherein, the first component is a sodium citrate-hydrogen peroxide-sodium chloride adduct, the second component is potassium monopersulfate, and the mass ratio of the first component to the second component is 8:5), 0.1% synergistic mediating system (the synergistic mediating system comprises the following components by mass percentage: 15% magnesium valproate, 25% manganese oxide, and 60% rare earth oxide, wherein the rare earth oxide is neodymium oxide (Nd₂O₃), 12% comprehensive balancing system (wherein, the comprehensive balancing system comprises magnesium sulfate, calcium formate, and potassium phosphate, and the mass ratio of magnesium sulfate, calcium formate, and potassium phosphate is 3:2:1), 12.9% photosynthetic irritation system (comprising 5.8% titanium dioxide, 5% sodium percarbonate, and 2.1% magnesium oxide), and 10% stabilizing system (comprising potassium diformate, citric acid, and sulfamic acid, and the mass ratio of potassium diformate, citric acid, and sulfamic acid is 3:2:5).

[0061] An inorganic composite peroxy-bridge system, a synergistic mediation system, a comprehensive balancing system, a photosynthetic irritation system, and a stabilizing system are mixed to obtain a water conditioner.

[0062] Application Example 1

[0063] The water conditioner from Example 1 was applied at a concentration of 1.5 ppm (i.e., 1.5 mg / m³) based on the weight of the aquaculture water. 3 The water conditioner was evenly applied to the tilapia rearing pond at a ratio of 1:1, once every 7 days. The experimental temperature was controlled at 23–26℃, the stocking density was approximately 20 kg / m³, and the tilapia were healthy and of similar weight (approximately 0.6 kg / fish). The treatment results for two consecutive weeks in the fourth month are shown in Table 1. The control group did not use the water conditioner from Example 1.

[0064] Table 1. Effects of water phases in tilapia farming

[0065]

[0066] As can be seen from Table 1, this regulator can stabilize the pH and dissolved oxygen in tilapia aquaculture water, mineralize and degrade toxic and harmful organic matter such as ammonia nitrogen, nitrite and uneaten feed, and balance the aquaculture water.

[0067] Application Example 2

[0068] The water conditioner from Example 1 was applied at a concentration of 2.0 ppm (i.e., 2.0 mg / m³) based on the weight of the aquaculture water. 3 The water conditioner was evenly distributed into the Chinese soft-shelled turtle rearing pond at a ratio of 1:1, once every 15 days. The experimental temperature was controlled at 26-30℃, and the stocking density was approximately 40 turtles / cubic meter. The turtles were healthy and of similar weight, approximately 0.5 kg / turtle. The results of two consecutive treatments after 7 months are shown in Table 2. The control group did not use the water conditioner from Example 1.

[0069] Table 2. Aquatic Phase Effects of Chinese Soft-shelled Turtle Farming

[0070]

[0071] As can be seen from Table 2, this regulator can stabilize the pH and dissolved oxygen in the water used for Chinese soft-shelled turtle farming, mineralize and degrade toxic and harmful organic matter such as ammonia nitrogen, nitrite, and uneaten feed, and balance the water body.

[0072] Application Example 3

[0073] The water conditioner from Example 1 was applied at a dosage of 0.8 ppm (0.8 mg / m³) based on the weight of the aquaculture water. 3 The solution was first prepared in the specified proportions and then evenly sprinkled into the Litopenaeus vannamei shrimp culture ponds, once every 7 days. The experimental temperature was controlled at 27-31℃, and the culture density was approximately 220 shrimp / cubic meter. The results after two consecutive weeks of treatment at 3 months are shown in Table 3. The control group did not use the water conditioner in Example 1.

[0074] Table 3. Aquatic Phase Effects in Litopenaeus vannamei Culture

[0075]

[0076] As can be seen from Table 3, this regulator can stabilize the pH and dissolved oxygen in the water used for Litopenaeus vannamei farming, mineralize and degrade toxic and harmful organic matter such as ammonia nitrogen, nitrite and uneaten feed, and balance the water.

[0077] Example 2

[0078] A water conditioning agent comprises the following components in weight percentage: 50% inorganic composite peroxy-bridge system (wherein, the first component is a sodium citrate-hydrogen peroxide-sodium chloride adduct, the second component is potassium monopersulfate, and the mass ratio of the first component to the second component is 8:5), 0.2% synergistic mediating system (the synergistic mediating system comprises the following components in weight percentage: 15% magnesium valproate, 25% manganese oxide, and 60% rare earth oxide, the rare earth oxide being samarium oxide Sm2O3), 18% comprehensive balancing system (wherein, the comprehensive balancing system comprises magnesium sulfate, calcium formate, and potassium phosphate, and the mass ratio of magnesium sulfate, calcium formate, and potassium phosphate is 3:2:1); 16% photosynthetic irritation system (comprising 7% titanium dioxide, 6% sodium percarbonate, and 3% magnesium oxide); and 15.8% stabilizing system (comprising potassium diformate, citric acid, and sulfamic acid, and the mass ratio of potassium diformate, citric acid, and sulfamic acid is 3:2:5).

[0079] An inorganic composite peroxy-bridge system, a synergistic mediation system, a comprehensive balancing system, a photosynthetic irritation system, and a stabilizing system are mixed to obtain a water conditioner.

[0080] Application Example 4

[0081] The water conditioner from Example 2 was applied at a concentration of 2.0 ppm (i.e., 2.0 mg / m³) based on the weight of the aquaculture water. 3 The water conditioner was evenly distributed into the Chinese soft-shelled turtle rearing pond at a ratio of 1:1, once every 15 days. The experimental temperature was controlled at 26-30℃, and the stocking density was approximately 40 turtles / cubic meter. The turtles were healthy and of similar weight, approximately 0.5 kg / turtle. The results of two consecutive treatments after 7 months are shown in Table 4. The control group did not use the water conditioner from Example 2.

[0082] Table 4. Aquatic Phase Effects of Chinese Soft-shelled Turtle Farming

[0083]

[0084] As can be seen from Table 4, this regulator can stabilize the pH and dissolved oxygen in the water used for Chinese soft-shelled turtle farming, mineralize and degrade toxic and harmful organic matter such as ammonia nitrogen, nitrite and uneaten feed, and balance the water body.

[0085] Example 3

[0086] A water conditioner comprises the following components by mass percentage: 70% inorganic composite peroxy-bridge system (wherein, the first component is a sodium citrate-hydrogen peroxide-sodium chloride adduct, the second component is potassium monopersulfate, and the mass ratio of the first component to the second component is 8:5), 0.05% synergistic mediating system (the synergistic mediating system comprises the following components by mass percentage: 15% magnesium valproate, 25% manganese oxide, and 60% rare earth oxide, the rare earth oxide being neodymium oxide (Nd₂O₃)), 10% comprehensive balancing system (wherein, the comprehensive balancing system comprises magnesium sulfate, calcium formate, and potassium phosphate, and the mass ratio of magnesium sulfate, calcium formate, and potassium phosphate is 3:2:1); 13% photosynthetic irritation system (comprising 4% titanium dioxide, 7% sodium percarbonate, and 2% magnesium oxide); and 6.95% stabilizing system (comprising potassium diformate, citric acid, and sulfamic acid, and the mass ratio of potassium diformate, citric acid, and sulfamic acid is 3:2:5).

[0087] An inorganic composite peroxy-bridge system, a synergistic mediation system, a comprehensive balancing system, a photosynthetic irritation system, and a stabilizing system are mixed to obtain a water conditioner.

[0088] Application Example 5

[0089] The water conditioner from Example 3 was applied at a dosage of 0.8 ppm (0.8 mg / m³) based on the weight of the aquaculture water. 3 The solution was first prepared in the specified proportions and then evenly sprinkled into the Litopenaeus vannamei shrimp culture ponds, once every 7 days. The experimental temperature was controlled at 27-31℃, and the culture density was approximately 220 shrimp / cubic meter. The results after two consecutive weeks of treatment at 3 months are shown in Table 5. The control group did not use the water conditioner in Example 3.

[0090] Table 5. Aquatic Phase Effects in Litopenaeus vannamei Culture

[0091]

[0092] As can be seen from Table 5, this regulator can stabilize the pH and dissolved oxygen in the water used for Litopenaeus vannamei farming, mineralize and degrade toxic and harmful organic matter such as ammonia nitrogen, nitrite and uneaten feed, and balance the water.

[0093] The above description is only a preferred embodiment of the present invention. It should be noted that for those skilled in the art, several improvements and modifications can be made without departing from the principle of the present invention, and these improvements and modifications should also be considered within the scope of protection of the present invention.

Claims

1. A water conditioner, characterized in that, The components include the following percentages by mass: Inorganic composite peroxygen bridge system 20%–90%, synergistic mediation system 0.05%–2%, comprehensive balance system 6%–25%, photosynthetic stimulation system 2%–20%, stabilization system 1%–25%; The inorganic composite peroxy bridge system includes a first component and a second component. The first component includes a sodium sulfate-hydrogen peroxide-sodium chloride adduct, a sodium citrate-hydrogen peroxide-sodium chloride adduct, or a sodium phosphate-hydrogen peroxide-sodium chloride adduct. The second component includes one or more of potassium peroxymonosulfate, calcium peroxide, sodium persulfate, and sodium perborate. The synergistic mediating system comprises the following components by mass percentage: 10%–20% magnesium valproate, 20%–30% manganese oxide, and 50%–70% rare earth oxides; The integrated balance system includes one or more of the following: calcium sulfate, magnesium sulfate, calcium formate, potassium phosphate, sodium pyrophosphate, sodium silicate, and sodium sulfate. The photosynthetic irritation system includes one or more of titanium dioxide, sodium percarbonate, and magnesium oxide; The stabilizing system includes one or more of potassium diformate, citric acid, malic acid, aminosulfonic acid, and succinic acid.

2. The water conditioner according to claim 1, characterized in that, It comprises the following components by weight percentage: 65% inorganic composite peroxy-bridge system, 0.1% synergistic mediating system, 12% comprehensive balancing system, 12.9% photosynthetic irritation system, and 10% stabilizing system.

3. The water conditioner according to claim 1 or 2, characterized in that, In the inorganic composite peroxy bridge system, the mass ratio of the first component to the second component is 7-9:4-6.

4. The water conditioner according to claim 1 or 2, characterized in that, In the synergistic mediation system, the rare earth oxides include one or more of neodymium oxide, samarium oxide, europium oxide, ytterbium oxide, praseodymium oxide, and gadolinium oxide.

5. The water conditioner according to claim 1 or 2, characterized in that, The integrated balance system includes magnesium sulfate, calcium formate, and potassium phosphate; in the integrated balance system, the mass ratio of magnesium sulfate, calcium formate, and potassium phosphate is 2-4:1-3:0.5-1.

5.

6. The water conditioner according to claim 1 or 2, characterized in that, The photosynthetic irritation system includes titanium dioxide, sodium percarbonate, and magnesium oxide; the mass ratio of titanium dioxide, sodium percarbonate, and magnesium oxide in the photosynthetic irritation system is 56-60:48-52:17-22.

7. The water conditioner according to claim 1 or 2, characterized in that, The stabilizing system comprises potassium diformate, citric acid, and aminosulfonic acid; the mass ratio of potassium diformate, citric acid, and aminosulfonic acid in the stabilizing system is 2-4:1-3:4-6.

8. The method for preparing the water conditioner according to any one of claims 1 to 7, characterized in that, Includes the following steps: The water conditioner is obtained by mixing the inorganic composite peroxy-bridge system, the synergistic mediation system, the comprehensive balance system, the photosynthetic stimulation system, and the stabilization system.

9. The application of the water conditioner according to any one of claims 1 to 7 in aquaculture water.

10. The application according to claim 9, characterized in that, The dosage of the water conditioner is 0.3–5 mg / m³. 3 .

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