Method for recycling and preparing lithium iron phosphate from waste lithium iron phosphate positive electrode material

By employing steps such as roasting, acid leaching, nanofiltration membrane separation, and oxalic acid precipitation, the problems of lengthy processes and reagent consumption in the recycling of waste lithium iron phosphate have been solved. This has enabled efficient and low-cost full-component recovery and regenerated lithium iron phosphate preparation, improving product purity and membrane module lifespan.

CN122403403APending Publication Date: 2026-07-17GEM CO LTD +3

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
GEM CO LTD
Filing Date
2026-05-09
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing waste lithium iron phosphate recycling technologies suffer from problems such as lengthy processes, high reagent consumption, severe lithium loss, low product purity, and membrane module contamination, making it difficult to achieve stable industrial operation and efficient resource utilization.

Method used

By employing steps such as calcination, acid leaching, acid-resistant nanofiltration membrane separation, impurity removal, and oxalic acid precipitation, and through precise control of leaching conditions and separation parameters, efficient separation of Fe2+ and Li+/H2PO4- is achieved, avoiding lengthy steps and consumption of acid and alkali reagents, preventing Fe2+ oxidation, and synthesizing regenerated lithium iron phosphate cathode materials.

Benefits of technology

It achieves efficient recovery of lithium, iron, and phosphorus, with product purity reaching battery-grade standards, reducing the generation of waste, extending the life of membrane modules, realizing closed-loop regeneration of all components, and reducing costs.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明涉及一种废旧磷酸铁锂正极材料回收制备磷酸铁锂的方法,所述方法包括:废旧磷酸铁锂正极材料在保护气氛中焙烧,脱除粘结剂与导电剂,分离得到集流体与废旧磷酸铁锂粉体;酸浸所述废旧磷酸铁锂粉体,固液分离,得到酸浸液;调节酸浸液的pH值为1.8~2.5,使用耐酸纳滤膜进行膜分离,得到透过液与截留液;所述透过液经第一除杂与蒸发结晶,得到磷酸二氢锂;所述截留液经第二除杂与草酸沉淀,得到二水草酸亚铁;所述磷酸二氢锂、二水草酸亚铁与碳源混合,所得混合料经过干燥、预烧与烧结,得到再生磷酸铁锂。本发明提供的方法流程短、试剂消耗低、回收率高、产品纯度好,有利于工业化生产。
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