Method for recycling waste lithium iron phosphate based on three-dimensional conductive network and composite material

By introducing nano-lithium iron phosphate powder to construct a three-dimensional conductive network, the problems of lithium compensation, structural reorganization and conductivity improvement of waste lithium iron phosphate were solved, and high-performance recycled lithium iron phosphate composite materials were realized.

CN122403404APending Publication Date: 2026-07-17HUNAN HAPPY TIMES NEW ENERGY CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
HUNAN HAPPY TIMES NEW ENERGY CO LTD
Filing Date
2026-05-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies cannot simultaneously and efficiently solve the problems of lithium compensation, structural restructuring, and conductivity improvement in waste lithium iron phosphate, resulting in limited stability of recycled materials under long-term cycling.

Method used

By introducing nano-lithium iron phosphate powder with specified average particle size and specific surface area, and utilizing the synergistic effect generated during heat treatment, a three-dimensional conductive network is constructed to achieve comprehensive repair of waste lithium iron phosphate powder.

Benefits of technology

It significantly improves the electrochemical and physical properties of regenerated lithium iron phosphate composite cathode materials, including high discharge capacity, excellent rate performance, good low-temperature performance, and long-term cycle stability.

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Abstract

本发明提供一种基于三维导电网络的废旧磷酸铁锂再生方法及复合材料,包括:步骤S1,将废旧磷酸铁锂粉体、纳米磷酸铁锂粉体、碳源前驱体和碳酸锂按照质量比100:(3‑15):(1‑8):(1‑10)混合均匀,得到混合物料;步骤S2,将所述混合物料在惰性气氛或还原性气氛保护下,于550℃~750℃进行高温热处理;步骤S3,对高温热处理后的产物进行冷却处理、粉碎和过筛,得到复合材料。本发明通过引入指定平均粒径和比表面积的纳米磷酸铁锂粉体,利用其在热处理过程中产生的独特且不可分割的协同效应,实现对废旧磷酸铁锂粉体从体相到表面的全面修复,获取具有创新微观结构的高性能的再生磷酸铁锂复合正极材料。
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