A fine-particle tungsten carbide powder with a high bulk specific gravity for cemented carbide rods and a method for preparing the same

By employing a dry process route of compaction, carbonization, and airflow pulverization, along with a specific ternary composite inhibitor system, the problem of achieving both particle size and bulk density of ultrafine tungsten carbide powder has been solved, enabling the industrial production of high-performance cemented carbide rods.

CN122403455APending Publication Date: 2026-07-17GANZHOU GRAND SEA W & MO GRP CO LTD
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Patent Information

Application Number
CN202610551468.2
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-04-24
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies struggle to prepare tungsten carbide powder that combines submicron-level ultrafine grains, high bulk density, high chemical purity, and good toughness. Traditional processes suffer from problems such as difficulty in achieving both particle size and bulk density, high oxygen content, and uncontrolled carbon balance.

Method used

A dry process route of compaction densification carbonization and air jet milling is adopted, combined with a specific ternary composite inhibitor system. High-pressure densification pre-agglomeration and air jet shaping are used to prepare high-ratio fine-particle tungsten carbide powder, avoiding the introduction of organic forming agents and achieving low oxygen and low carbon residue.

Benefits of technology

The prepared tungsten carbide powder has submicron-level ultrafine particle size, high bulk density and high tap density, which significantly improves flowability and formability, and significantly enhances the strength and toughness of the alloy, making it suitable for the production of high-performance cemented carbide rods.

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Abstract

本发明涉及碳化钨生产技术领域,公开了一种硬质合金棒材用大松比细颗粒碳化钨粉及其制备方法。本发明采用先压坯致密化碳化然后气流粉碎最后机械整形的干法工艺路线,通过高压压制预制高致密结块,结合气流粉碎与机械整形的协同处理,在保证亚微米级细粒度的同时,有效消除了颗粒尖角,显著提升了粉末的松装密度与流动性;全干法流程避免了有机杂质引入,实现了极高的化学纯度。配合优选的三元复合抑制剂体系,在抑制晶粒长大的同时兼顾了合金强韧性,极适于高性能硬质合金棒材的制备。所制备的碳化钨粉的费氏粒度为0.60~0.80μm,松装密度为3.40~3.80g / cm³,振实密度≥5.20g / cm³,氧含量≤0.15%。
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