Preparation method of high-purity food-grade fulvic acid

By employing organic acid extraction, hollow fiber filtration, vacuum distillation, and heterogeneous membrane electrodialysis processes, combined with online detection parameter control, the problem of low purity in fulvic acid extraction has been solved, enabling the preparation and recycling of high-purity fulvic acid that meets food and pharmaceutical grade requirements.

CN122404359APending Publication Date: 2026-07-17QINGDAO AGRI UNIV
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Patent Information

Application Number
CN202610501902.6
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-04-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies make it difficult to extract high-purity fulvic acid from weathered coal or lignite, resulting in problems such as low product purity, easy leaching of heavy metals, high acid and alkali consumption, high wastewater salinity, heavy environmental burden, and difficulty in meeting food and drug safety requirements.

Method used

The technology route combines organic acid extraction, hollow fiber filtration, first vacuum distillation, resolution, heterogeneous membrane electrodialysis, and second vacuum distillation. The extraction control module dynamically determines and adjusts the process based on online detection parameters such as pH and conductivity, forming a closed-loop resource cascade utilization process.

Benefits of technology

It achieves efficient extraction and purification of fulvic acid under mild conditions, obtaining high-purity fulvic acid product with a fulvic acid content of greater than or equal to 95%, reducing the introduction of inorganic salts and heavy metal impurities, reducing material consumption and waste emissions, and possessing value for green manufacturing and industrial applications.

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Abstract

本发明提供了一种高纯食药级黄腐酸的制备方法,该方法以风化煤或褐煤为原料,采用有机酸提取、中空纤维过滤、两次减压蒸馏及异相膜电渗析耦合工艺,在密闭容器和管道系统中完成制备。提取过程中,对提取液的酸碱度、电导率及二百五十四纳米、四百六十五纳米、六百六十五纳米吸光度进行在线检测,计算颜色比值、趋势提取增益参数和微扰差分响应参数,识别提取平台期,并通过补酸微扰或搅拌微扰实现自动调控,从而控制继续提取、补酸、调整搅拌或结束提取。该方法可提高提取过程的智能化和稳定性,实现酸液和水的循环利用,降低杂质含量与能耗,获得黄腐酸含量大于或等于百分之九十五的高纯产品。
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Citation Information

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