An ultra-low oligomer content bio-based nylon 5x resin and method of making the same

By employing a multi-stage heating, gradient vacuum, and inert gas micro-flow process, the problem of high oligomer content in bio-based nylon 5X resin was solved, resulting in high-performance, low-moisture-content, and narrow-molecular-weight-distribution bio-based nylon 5X resin suitable for high-end fibers and engineering plastics.

CN122404698APending Publication Date: 2026-07-17NANJING NANLI NEW MATERIALS CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
NANJING NANLI NEW MATERIALS CO LTD
Filing Date
2026-05-06
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The existing bio-based nylon 5X resin has an excessively high oligomer content, which leads to a decline in mechanical properties and insufficient long-term stability, making it difficult to meet the stringent requirements of high-end fibers and engineering plastics.

Method used

By employing a multi-stage heating, gradient vacuum, and inert gas micro-flow process, and by gradually controlling the temperature and vacuum level, combined with physical removal using inert gas micro-flow, the oligomer content is significantly reduced, thus preparing bio-based nylon 5X resin with ultra-low oligomer content.

Benefits of technology

It significantly reduces oligomer content, improves the mechanical properties and durability of materials, meets the performance requirements of high-end fibers and engineering plastics, and is also green and sustainable.

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Abstract

本发明公开了一种超低寡聚物含量的生物基尼龙5X树脂及其制备方法,所述树脂的寡聚物含量为0.1‑0.3 wt%,所述寡聚物包括环状二聚体和线性低聚物。其制备方法主要是采用多级升温与梯度真空协同工艺进行缩聚反应,并辅以惰性气体微气流强化脱挥,能够有效抑制寡聚物的生成。本发明所得生物基尼龙5X树脂寡聚物含量显著降低,产品纯度高,并且具有低熔融指数、窄分子量分布、低含水率以及优异机械强度,能够满足高端工程塑料与纤维领域对材料性能一致性与长期耐久性的苛刻要求。
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