A high-temperature-resistant low-dielectric composite material with a multiphase interpenetrating network structure and a preparation method thereof

By constructing a high-temperature resistant, low-dielectric composite material with a multi-level interpenetrating network structure of "sea-island-bridge", the balance problem of existing materials in terms of dielectric properties, heat resistance and toughness has been solved. This has achieved a synergistic improvement in low dielectric loss, high heat resistance, high toughness and low moisture absorption, meeting the needs of high-frequency communication and computing fields.

CN122404897APending Publication Date: 2026-07-17SHANGHAI MINGQIAN IND CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SHANGHAI MINGQIAN IND CO LTD
Filing Date
2026-05-06
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polymer materials struggle to achieve a balance among several mutually restrictive key performance indicators, such as low dielectric loss, high heat resistance, high toughness, low moisture absorption, and good processability, thus failing to meet the high-frequency and high-speed requirements of fields such as fifth-generation and sixth-generation mobile communication technologies, millimeter-wave radar, satellite communication, and high-performance computing.

Method used

High-temperature resistant, low-dielectric composite material with a multi-interpenetrating network structure is adopted. Through the "sea-island-bridge" multi-level interpenetrating network structure, a chemical bond-driven three-dimensional integrated network is constructed using components such as maleic anhydride-grafted polyphenylene ether, thermoplastic polyimide prepolymer, surface-amined aramid pulp, and 4,4'-diphenylmethane bismaleimide, so as to achieve synergistic enhancement of the performance of each component.

Benefits of technology

It achieves a synergistic improvement in low dielectric loss, high heat resistance, high toughness and low moisture absorption. The material maintains low and stable dielectric properties in high temperature and high humidity environments, thereby improving signal integrity, power efficiency and reliability.

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Abstract

本申请涉及一种具有多相互穿网络结构的耐高温低介电复合材料及其制备方法,涉及高性能高分子复合材料技术领域,其包括马来酸酐接枝聚苯醚,热塑性聚酰亚胺预聚体,表面胺基化芳纶浆粕,4,4’‑二苯甲烷双马来酰亚胺,催化剂,助剂,N‑甲基吡咯烷酮。以4,4’‑二苯甲烷双马来酰亚胺为桥梁前驱体,通过其与表面胺基化芳纶浆粕、马来酸酐接枝聚苯醚及热塑性聚酰亚胺预聚体之间发生的分步、可控化学反应,在材料内部原位形成了强韧的界面桥接相,形成的“海‑岛‑桥”多级互穿网络独特结构将各组分牢固键合为一体,实现低介电损耗、高耐热、高韧性及低吸湿性等关键性能的协同提升。
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