A method of bonding an age-resistant polytetrafluoroethylene-rubber

By forming an activation layer on the surface of polytetrafluoroethylene (PTFE) and reacting it with the adhesive to form chemical bonds such as urethane groups and amide groups, the problems of low bonding strength and poor aging resistance between PTFE and rubber are solved, achieving a bonding effect with high strength and aging resistance.

CN122405162APending Publication Date: 2026-07-17SHANDONG NON METALLIC MATERIAL RESEARCH INSTITUTE

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SHANDONG NON METALLIC MATERIAL RESEARCH INSTITUTE
Filing Date
2026-06-08
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The bonding strength between polytetrafluoroethylene and rubber is low and the aging resistance is poor. Existing methods cannot meet the requirements for bonding strength and aging resistance.

Method used

An activation layer is formed on the surface of polytetrafluoroethylene (PTFE) treated with sodium naphthalene by mixing toluene-2,4-diisocyanate (TDI) and epoxy resin E51. The PTFE is then bonded to the rubber by hot pressing with an adhesive. The isocyanate groups in TDI react with the active groups on the PTFE surface to form chemical bonds such as urethane groups and amide groups.

Benefits of technology

It significantly improves the bonding strength between PTFE and rubber, and maintains high bonding strength after long-term aging, thus enhancing the aging resistance of the bonding interface.

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Abstract

本发明属于高分子材料粘接技术领域,具体涉及一种耐老化聚四氟乙烯‑橡胶的粘接方法,主要利用甲苯‑2,4‑二异氰酸酯(TDI)与环氧树脂E51混合液在经钠萘处理剂处理过的聚四氟乙烯表面形成活化层,再经胶黏剂与橡胶进行热压粘接。该方法适用于多种橡胶粘接,且粘接强度高,经长时间老化后依然能够保持较高的粘接强度。
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