X-Y-Z-CrZr series light-weight refractory high-entropy alloy with excellent high-temperature mechanical properties

By employing multi-component ratios and a high-entropy solid solution strengthening mechanism, a lightweight refractory high-entropy alloy based on XYZ-CrZr was prepared. This solved the problems of insufficient strength and thermal softening of lightweight refractory high-entropy alloys at high temperatures, achieving both high-temperature softening resistance and lightweight properties, making it suitable for aerospace and nuclear energy equipment.

CN122406071APending Publication Date: 2026-07-17HEFEI UNIV OF TECH
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
HEFEI UNIV OF TECH
Filing Date
2026-05-31
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing lightweight refractory high-entropy alloys have insufficient strength at high temperatures, exhibit significant thermal softening, and have poor overall performance matching between high and low temperatures. They are difficult to adapt to complex operating conditions requiring long-term service at extreme high temperatures, and their high material density limits their application in aerospace and other fields.

Method used

By rationally combining multiple elements such as aluminum, manganese, molybdenum, titanium, vanadium, chromium, and zirconium, and employing high-entropy solid solution strengthening and fine grain strengthening mechanisms, the microstructure of the alloy is optimized to prepare XYZ-CrZr-based lightweight refractory high-entropy alloys. Low-density metal elements are introduced to improve high-temperature mechanical properties and resistance to thermal softening.

Benefits of technology

It achieves excellent yield strength in a wide temperature range of 600℃ to 1200℃. The alloy has both low density and high temperature resistance to softening, making it suitable for extreme high temperature service scenarios and improving the performance and lightweight level of aerospace and nuclear energy equipment.

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Abstract

本发明公开一种高温力学性能优良的X‑Y‑Z‑CrZr系轻质难熔高熵合金,合金组元包含钛、钒、铬、锆、锰、铌、钼及轻质铝元素,整体密度低于8g / cm3,兼具轻量化特质与优良高温强度、抗热软化性能,其中:Al‑V‑Ti‑Cr‑Zr系合金密度约5g / cm3,600℃、800℃最高屈服强度分别达1561.1MPa、1163.5MPa;Mn‑V‑Ti‑Cr‑Zr系合金密度约6g / cm3,1000℃、1200℃最高屈服强度分别为760.17MPa、251.55MPa,有效兼顾密度与高温力学性能;Mo‑Nb‑V‑Cr‑Zr、Mo‑Nb‑Ti‑Cr‑Zr系金密度处于7~8g / cm3区间,1000℃、1200℃最高屈服强度可达1571.50MPa、818.80MPa,高温承载能力进一步提升。
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