A method for solvent-mediated assisted hot-press growth of high-quality thickness-controllable perovskite quasi-single crystal thin films

By using a solvent-mediated assisted hot pressing growth method, the problems of numerous defects in polycrystalline films and complex preparation of single-crystal films in perovskite thin film fabrication have been solved. This method enables the growth of quasi-single-crystal thin films with low defect density and high carrier transport, thus promoting the industrialization of perovskite optoelectronic devices.

CN122406355APending Publication Date: 2026-07-17SHANDONG UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SHANDONG UNIV
Filing Date
2026-04-27
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Among the existing perovskite thin film preparation technologies, polycrystalline thin films have many defects and low efficiency, while single-crystal thin films are complex to prepare and difficult to integrate on a large scale, making it difficult to balance high performance and process feasibility.

Method used

A solvent-mediated assisted hot-pressing growth method is adopted to induce secondary rearrangement and growth of powder film grains by utilizing the synergistic effect of solvent, temperature and pressure in a confined space, thereby forming a quasi-single-crystal thin film with low defect density.

Benefits of technology

It has achieved the growth of high-quality, thickness-controllable quasi-single-crystal thin films, which have excellent carrier transport performance and large-area fabrication capabilities, thus improving the performance and stability of optoelectronic devices.

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Abstract

本发明提供了一种溶剂介导辅助热压生长高质量厚度可控钙钛矿准单晶薄膜的方法。该方法包括步骤:将钙钛矿前驱体粉末加入有机溶剂中,进行搅拌,得到钙钛矿前驱体过饱和浆料;将所得过饱和浆料在亲水衬底上制备薄膜,经预退火处理,得到钙钛矿前驱体多晶薄膜;在所得钙钛矿前驱体多晶薄膜上面覆盖疏水抛光衬底,使用柔性薄膜缠绕固定后,在亲水衬底背面贴合加热元件,之后置于氟胶垫片之间,并用法兰密封形成密封法兰元件;将所得密封法兰元件转移至密封的高等静压反应釜中,进行溶剂介导辅助热压处理,经冷却,得到钙钛矿准单晶薄膜。本发明的方法可以制备出具有低缺陷密度、高载流子输运性质的厚度可控的钙钛矿准单晶薄膜。
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