Preparation process of graphene modified high-thermal-conductivity cool polyester fiber

By co-blending terminal amino polyamide 6 chips with carboxylated graphene microplates in a twin-screw extruder, and combining this with triphenyl phosphite inactivation and side-blowing cooling, a covalently entangled coating layer is formed. This solves the problems of inorganic phase homogenization and flow stability in the preparation of high thermal conductivity and cool-feel polyester fibers, and achieves high-performance and stable fiber production.

CN122406409APending Publication Date: 2026-07-17SHENZHEN KORADIOR FASHION LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SHENZHEN KORADIOR FASHION LTD
Filing Date
2026-05-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the preparation of high thermal conductivity and cool-feel polyester fibers, conventional mixing processes cannot achieve spatial anchoring control of inorganic phase homogenization and isotropic continuous orientation of matrix macromolecular chain segments. This leads to the inorganic filler being prone to heterogeneous phase interface slippage and melt flow instability during high-temperature and high-pressure processing, resulting in melt fracture.

Method used

By blending amino-terminated polyamide 6 chips with carboxyl-terminated graphene microplates and then performing a melt reaction in a twin-screw extruder, the end groups are deactivated by triphenyl phosphite, the shear viscosity ratio is adjusted, and a covalently entangled coating layer is formed by combining side-blowing cooling and stretching processes. This dynamically matches the rheological shear viscosity of the two phases and prevents the melt stream from breaking.

Benefits of technology

Stable preparation of graphene-modified high thermal conductivity and cool-feel polyester fiber was achieved, avoiding melt fracture, improving the thermodynamic stability and thermal conductivity of the multiphase system, and ensuring continuous extrusion and high performance of the fiber.

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Abstract

本发明涉及高性能锦纶制备工艺技术领域,公开了一种石墨烯改性高导热凉感聚酯纤维的制备工艺,包括:将聚酰胺6切片与羧基化石墨烯微片送入双螺杆挤出机熔融缩聚,注入聚酯熔体界面缩聚并加入亚磷酸三苯酯灭活,通过流道压力降换算粘度比调节加热功率,使物料经喷丝孔挤出形成细流并梯度侧吹风分段冷却固化,本发明利用两相界面的原位键合重塑共价外壳,消除异质体系流变应力集中并阻断石墨烯二次聚集,在保全二维声子网络导热效率的同时,避免纺丝细流熔体破裂,调和纤维强度与凉感指标的制约问题。
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