Aqueous composite sizing agent, method for producing the same, method for surface treatment of reinforcing fibers, and composite material

By utilizing a water-based composite sizing agent preparation method, bisphenol E cyanate prepolymer and nanoparticles are covalently bonded and mechanically interlocked, solving the problems of insufficient heat resistance and environmental pollution of existing sizing agents and improving the performance of composite materials.

CN122406532APending Publication Date: 2026-07-17JIANGSU ZHONGFU SHENYING CARBON FIBER ENG CENT CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
JIANGSU ZHONGFU SHENYING CARBON FIBER ENG CENT CO LTD
Filing Date
2026-05-25
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing sizing agents have insufficient heat resistance, making it difficult to match high-performance resin matrices and causing serious environmental pollution. Traditional sizing agents have high viscosity and are brittle, resulting in limited improvement in the interlaminar shear strength of composite materials.

Method used

An aqueous composite sizing agent containing bisphenol E cyanate prepolymer, polyethersulfone, inorganic nanoparticles, nonionic emulsifier, and anionic emulsifier is used to prepare an O/W type emulsion via a reverse emulsification method. This emulsion is then used to treat the surface of the reinforcing fiber, forming an interfacial reinforcement mechanism involving covalent bonding and mechanical interlocking.

Benefits of technology

It improves the heat resistance and interlaminar shear strength of composite materials, enhances interfacial bonding, reduces environmental pollution, and meets the matching requirements of high-performance resin matrices.

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Abstract

本发明涉及增强纤维表面处理技术领域,具体而言,涉及水性复合上浆剂及其制备方法、增强纤维的表面处理方法和复合材料。以质量百分比计,水性复合上浆剂包括15‑25%双酚E型氰酸酯预聚体、3‑8%聚醚砜、0.5‑2%无机纳米粒子、2‑5%非离子型乳化剂、0.5‑2%阴离子型乳化剂、0.025‑0.1%催化剂、其余量为水。该上浆剂解决现有上浆剂耐热性不足、与高性能树脂基体匹配性差、环境污染严重等问题。
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