Plasma-assisted zif-8 modified carbon fibers and methods of making and using the same

By using a plasma-assisted ZIF-8 modification method, oxygen-containing functional groups were introduced onto the surface of carbon fibers and ZIF-8 nanocrystalline layers were grown in situ. This solved the problem of weak bonding between carbon fibers and resin/ceramic matrices, and achieved simultaneous improvement in interfacial bonding strength and mechanical properties.

CN122406534APending Publication Date: 2026-07-17XI'AN POLYTECHNIC UNIVERSITY
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
XI'AN POLYTECHNIC UNIVERSITY
Filing Date
2026-05-28
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies struggle to achieve efficient interfacial bonding between carbon fibers and resin/ceramic matrices without compromising the strength of the carbon fiber itself, and single modification methods are insufficient to simultaneously improve interfacial bonding strength and mechanical properties.

Method used

A plasma-assisted ZIF-8 modification method was adopted, in which oxygen-containing functional groups were introduced into the carbon fiber surface through oxygen plasma activation treatment, and ZIF-8 nanocrystalline layers were grown in situ on the carbon fiber to form a multi-level synergistic modification interface structure, thereby enhancing the interfacial bonding strength and mechanical interlocking effect.

Benefits of technology

It significantly improves the surface roughness and activity of carbon fiber, enhances the interfacial bonding strength, improves the overall mechanical properties of composite materials, and maintains the bulk strength of carbon fiber.

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Abstract

本发明公开了等离子体协同ZIF‑8改性碳纤维及其制备方法,包括将碳纤维基体浸入丙酮溶液中去除表面上浆剂,然后置于氧气氛围下进行等离子体活化处理,得到表面富含含氧官能团的活化碳纤维,最后依次浸入硝酸锌甲醇溶液和2‑甲基咪唑甲醇溶液,室温静置反应,获得等离子体协同 ZIF‑8改性的碳纤维材料。本发明还公开了等离子体协同ZIF‑8改性碳纤维的应用方法,包括将所述改性碳纤维与树脂 / 陶瓷基体复合,制成碳纤维增强复合材料。本发明利用氧等离子体的刻蚀与活化作用,在碳纤维表面构建丰富的含氧官能团,为ZIF‑8提供充足的化学锚定位点,解决了传统 ZIF‑8直接负载时易团聚、分布不均、结合不牢固的问题。
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