Preparation method of hollow double-shell znsn03 / sn02 heterojunction sensor material and application of the same in selective detection of triethylamine

Hollow double-shell ZnSnO3/SnO2 heterojunction sensor materials were prepared by co-precipitation and solvothermal reaction, which solved the problems of low specific surface area of ​​ZnSnO3 and poor selectivity of SnO2, and achieved high sensitivity and high selectivity detection of triethylamine, which is suitable for food freshness monitoring.

CN122409778APending Publication Date: 2026-07-17JINZHONG UNIV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
JINZHONG UNIV
Filing Date
2026-04-27
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing technologies, ZnSnO3 has a low specific surface area and insufficient active sites, which limits its gas-sensing performance. SnO2 has a high operating temperature and poor selectivity, making it impossible to achieve high sensitivity and high selectivity for the detection of triethylamine.

Method used

ZnSn(OH)6/SnO2・nH2O microsphere precursors were prepared by coprecipitation method. Hollow double-shell ZnSnO3/SnO2 heterojunction sensor materials were formed by solvothermal reaction and calcination, realizing the synergistic regulation of morphology and oxygen vacancies.

Benefits of technology

The prepared hollow double-shell ZnSnO3/SnO2 heterojunction sensor material exhibits high specific surface area and high oxygen vacancy concentration at low operating temperatures, and possesses rapid response, good selectivity and stability, making it suitable for highly sensitive detection of triethylamine and monitoring of food freshness.

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Abstract

The application discloses a preparation method of hollow double-shell ZnSnO3 / SnO2 heterojunction sensor material and application of the material in selective detection of triethylamine, and belongs to the technical field of gas sensors. The preparation method of the hollow double-shell ZnSnO3 / SnO2 heterojunction sensor material comprises the following steps: ZnSn(OH)6 / SnO2.nH2O microsphere precursors are prepared by using a coprecipitation method; the ZnSn(OH)6 / SnO2.nH2O microsphere precursors are added into an organic solvent to perform a solvothermal reaction, and then are calcined to obtain the hollow double-shell ZnSnO3 / SnO2 heterojunction sensor material. The hollow double-shell ZnSnO3 / SnO2 heterojunction sensor material can be used for high-response detection of triethylamine at a low working temperature, has excellent selectivity and stability, and can be used for actual monitoring application of food freshness.
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