A method for the production of a titanium-based current collector for bipolar lead-acid batteries

By subjecting the titanium substrate to acid etching, anodizing, and electroplating, an inconsistent titanium-based bipolar current collector structure was constructed, solving the stability problem of the titanium substrate in lead-acid batteries. This resulted in a current collector with high stability and long lifespan, thus improving battery performance.

CN122417902APending Publication Date: 2026-07-17JILIN UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
JILIN UNIVERSITY
Filing Date
2026-03-24
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Titanium-based bipolar current collectors in lead-acid batteries suffer from passivation, corrosion, severe hydrogen evolution side reactions, and poor bonding with active materials, resulting in a short stability period.

Method used

After acid etching, anodizing, and annealing, a copper layer is electroplated on one side of the titanium substrate, and a lead or lead-tin alloy layer is electroplated on the other side to construct a high-roughness TiO2-TiN layer to enhance stability. This also blocks the electrolyte on the negative electrode side, forming an inconsistent titanium-based bipolar current collector structure.

Benefits of technology

It improves the interfacial stability and lifespan of titanium-based bipolar current collectors, reduces the amount of inactive materials, increases the energy density and power density of lead-acid batteries, and reduces the amount of heavy metal lead used.

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Abstract

本发明公开了一种用于双极性铅酸电池的钛基集流体的制备方法,其通过在钛基体表面原位构筑高粗糙度导电氮化钛掺杂二氧化钛层,退火后作为钛 / 氮化钛掺杂二氧化钛复合基底;再于其一面电镀铜层后复镀铅或铅锡合金层(用于负极侧),另一面直接电镀铅或铅锡合金层(用于正极侧),即得目标集流体。氮化钛掺杂二氧化钛层可抑制钛基体钝化并通过机械互锁强化正极侧界面稳定性;负极侧铜层阻隔电解液防止钛腐蚀,铅或铅锡合金层则增强与铅膏的结合力。该集流体双极两侧界面稳定性优异,与铅膏结合牢固,可解决钛基集流体稳定性差的问题,助力长寿命、高比能双极性铅酸电池开发。
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