Bipolar pulsing device, preparation apparatus and preparation method of chloroauric acid

CN122466489BActive Publication Date: 2026-08-28SUZHOU UNIV SPECIAL CHEM SHIJI IND CO
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Patent Information

Application Number
CN202610960665.X
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2026-06-30
Publication Date
2026-08-28
Estimated Expiration
2046-06-30

AI Technical Summary

Technical Problem

[0005]为此,本发明的目的在于克服在电化学法制备氯金酸过程中,阳极钝化导致氯金酸收率下降的问题,提供一种双向脉冲装置、氯金酸的制备设备以及制备方法,在采用高氯离子浓度、低pH的电解液体系进行氯金酸电解制备时,能够有效抑制阳极钝化,从而即使采用纯度较低的金阳极,也能获得更高的氯金酸收率和电流效率

Benefits of technology

[0019]本发明所述的双向脉冲装置,通过结合双向泵以及具有渐缩段和稳流段的喷嘴,不仅能够形成用于冲刷目标区域(例如电极表面)层流,冲刷清理电极表面的附着物,还能在电极表面附近形成指向喷嘴的抽吸流场,引导被冲刷下来的金物种离开电极表面,以防止其再次吸附在电极表面。因此,基于具有双向脉冲装置的电解设备制备氯金酸时,能抑制阳极钝化,进而获得更高的收率和电流效率。

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Abstract

The present application relates to the technical field of fluid pulse, and discloses a bidirectional pulse device, a preparation device and a preparation method of chloroauric acid. The bidirectional pulse device is used for forming bidirectional pulse laminar flow. The preparation device of chloroauric acid comprises the bidirectional pulse device. The preparation method of chloroauric acid is realized based on the preparation device. The preparation method of chloroauric acid comprises a cyclic step executed multiple times. The cyclic step comprises a forward electrolysis step and a reverse disturbance step, and the reverse disturbance step comprises a flushing sub-step and a back-suction sub-step. The bidirectional pulse device, the preparation device and the preparation method can effectively inhibit anode passivation when electrolytic preparation of chloroauric acid is carried out by using an electrolyte system with high chloride ion concentration and low pH, so that higher chloroauric acid yield and current efficiency can be obtained even if a gold anode with lower purity is used.
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