Dimethyl sulfoxide wastewater treatment equipment
By adopting a structure with a lamp tube installed inside a transparent plate and a water pump circulation system in the wastewater treatment equipment, combined with a dosing system, the problems of uneven catalysis and low degradation efficiency in the treatment of dimethyl sulfoxide wastewater are solved, and the photocatalytic effect of rapid removal and uniform mixing is achieved.
Patent Information
- Application Number
- CN202422717868.5
- Authority / Receiving Office
- CN · China
- Patent Type
- Utility models(China)
- Current Assignee / Owner
- Filing Date
- 2024-11-08
- Publication Date
- 2025-10-10
- Estimated Expiration
- 2034-11-08
AI Technical Summary
In the existing technology, the biodegradability of dimethyl sulfoxide wastewater is poor, and the biochemical treatment method has the problems of secondary pollution and low degradation efficiency. The photocatalytic method has uneven catalytic effect, with good surface effect and poor internal effect.
A wastewater treatment equipment is designed. It adopts a structure with a lamp tube inside a transparent plate. A water pump is used to circulate the mixed liquid and evenly irradiate it with light. Combined with a dosing system of sodium hydroxide, hydrogen peroxide and ferrous sulfate, it realizes all-round photocatalysis.
The rapid removal of dimethyl sulfoxide in wastewater is achieved, the photocatalytic effect is enhanced, and the uniform mixing of the mixed liquid is ensured, thereby improving the treatment efficiency.
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Figure CN223422472U_ABST
Abstract
Description
Technical Field
[0001] The utility model belongs to the technical field of wastewater treatment, in particular to a dimethyl sulfoxide wastewater treatment device. Background Art
[0002] Dimethyl sulfoxide (DMSO) is a sulfur-containing organic compound with the molecular formula (CH3)2SO. It is a colorless, odorless, transparent liquid at room temperature and is hygroscopic and flammable. It is highly polar, has a high boiling point, is thermally stable, is aprotic, and is miscible with water. It is soluble in most organic compounds, including ethanol, propanol, benzene, and chloroform, earning it the nickname "universal solvent."
[0003] The production of dimethyl sulfoxide (DMSO) generates wastewater, which has poor biodegradability and is difficult to directly treat using conventional biological methods. Treatment methods for DMSO wastewater primarily include photocatalytic oxidation and biochemical methods. In the biochemical method, anaerobic degradation of DMSO by highly efficient bacteria produces a certain amount of sulfur-containing volatiles, causing secondary pollution. Aerobic degradation of DMSO also presents challenges such as long degradation times and low removal rates.
[0004] When using the existing photocatalytic method, a lamp is often installed on the top of the reaction tank. Therefore, it can only have a good catalytic effect on the surface of the wastewater, while the internal water receives less light and has a poor catalytic effect. Utility Model Content
[0005] The utility model provides a dimethyl sulfoxide wastewater treatment device, which is used to solve the defects in the prior art.
[0006] The utility model is achieved through the following technical solutions:
[0007] A dimethyl sulfoxide wastewater treatment device comprises a wastewater treatment tank, wherein the upper portion of the wastewater treatment tank is sequentially connected with a sodium hydroxide dosing pipe, a hydrogen peroxide dosing pipe, a ferrous sulfate dosing pipe and a water inlet pipe, the lower portion of the wastewater treatment tank is connected with a water pump, the water outlet end of the water pump is connected with one end of a circulation pipe, the other end of the circulation pipe passes through the wastewater treatment tank and extends upward, bends downward above the wastewater treatment tank and passes into the wastewater treatment tank, a plurality of parallel transparent plates are arranged in the wastewater treatment tank, the length of the transparent plates is less than the length of the wastewater treatment tank, and the back surfaces of two adjacent transparent plates are fixedly connected to the inner wall of the wastewater treatment tank, a lamp is arranged in the transparent plates, and the lower portion of the wastewater treatment tank is connected with a sewage pipe controlled by a valve.
[0008] When the present application is in use, dimethyl sulfoxide wastewater enters the wastewater treatment tank through the water inlet pipe, and then sodium hydroxide, hydrogen peroxide and ferrous sulfate are injected into the wastewater treatment tank and the water pump is started. The water pump draws the mixed water into the circulation pipe and flows down from the upper part of the wastewater treatment tank through the circulation pipe and falls on the corresponding transparent plate. Since a lamp tube is provided in the transparent plate, the mixed water can be better photocatalyzed, thereby accelerating the reaction and quickly removing the dimethyl sulfoxide in the dimethyl sulfoxide wastewater. The water pump circulates to pump up the mixed water and drop it from the transparent plate, which not only increases the contact time of the mixed water with light, so that all the mixed water can be illuminated by light, better realizing photocatalysis, but also can achieve better mixing of the various components in the mixed water.
[0009] Preferably, the opposite ends of the glass plate extend out of the wastewater treatment tank and are sealed at the exit. The glass plate is transversely provided with a groove, and a rectangular frame is slidably fitted within the groove. The lamp tubes are arranged in multiple rows and are detachably fixed within the rectangular frame. The rectangular frame slides within the groove, allowing for easy removal from the groove, thereby facilitating repair of damaged lamp tubes.
[0010] Preferably, the inner walls of both sides of the groove are provided with sliding grooves, the rectangular frame is slidably fitted in the sliding grooves, and the lamps located in the rectangular frame are connected in parallel. The parallel connection of the lamps ensures that even if one of the lamps is damaged, it will not affect the normal operation of the other lamps.
[0011] Preferably, the transparent plate includes a cleaning plate and a fixed plate, the fixed plate is fixedly arranged on the wastewater treatment tank, the cleaning plate is located in the wastewater treatment tank, the groove extends to the cleaning plate through the fixed plate, an annular plate is sleeved on the relative edges of the cleaning plate and the fixed plate, the opposite surfaces of the two annular plates are fixedly connected with a sealing gasket, the two annular plates are fixedly connected by bolts, the upper part of the wastewater treatment tank closes the lid, and the sodium hydroxide dosing pipe, the hydrogen peroxide dosing pipe, the ferrous sulfate dosing pipe and the water inlet pipe are arranged on the lid. When performing wastewater treatment, the lid is opened and the bolts are rotated to remove the cleaning plate from the fixed plate, thereby cleaning the cleaning plate, ensuring its transparent state, and facilitating better photocatalysis. The sealing gasket plays a sealing role to prevent water from entering through the gap between the cleaning plate and the fixed plate.
[0012] The beneficial effects of the present invention are as follows: the use of the present application can utilize a water pump to circulate water and flow it to the transparent plate to be illuminated, so that all mixed water can be illuminated, achieving a better catalytic effect and achieving better mixing of the various components in the mixed water. BRIEF DESCRIPTION OF THE DRAWINGS
[0013] In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the following is a brief introduction to the drawings required for use in the embodiments or the description of the prior art. Obviously, the drawings described below are some embodiments of the present invention. For ordinary technicians in this field, other drawings can be obtained based on these drawings without paying any creative labor.
[0014] Figure 1 It is a structural diagram of the utility model;
[0015] Figure 2 It is a schematic diagram of the structure of the lamp tube in the rectangular frame.
[0016] As shown in the figure:
[0017] 1. Wastewater treatment tank, 2. Sodium hydroxide dosing pipe, 3. Hydrogen peroxide dosing pipe, 4. Ferrous sulfate dosing pipe, 5. Water inlet pipe, 6. Water pump, 7. Circulation pipe, 8. Transparent plate, 9. Lamp tube, 10. Rectangular frame, 81. Cleaning plate, 82. Fixed plate. DETAILED DESCRIPTION
[0018] To make the purpose, technical solutions, and advantages of the embodiments of the present invention more clear, the technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the drawings in the embodiments of the present invention. Obviously, the embodiments described are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without making creative efforts shall fall within the scope of protection of the present invention.
[0019] A dimethyl sulfoxide wastewater treatment device, such as Figure 1 and Figure 2 As shown, it includes a wastewater treatment tank 1, the upper part of which is connected in sequence to a sodium hydroxide dosing pipe 2, a hydrogen peroxide dosing pipe 3, a ferrous sulfate dosing pipe 4, and a water inlet pipe 5. The lower part of the wastewater treatment tank 1 is connected to a water pump 6, the outlet end of the water pump 6 is connected to one end of a circulation pipe 7, the other end of the circulation pipe 7 passes through the wastewater treatment tank 1 and extends upward, bends downward above the wastewater treatment tank 1 and passes into the wastewater treatment tank 1. Several parallel transparent plates 8 are provided in the wastewater treatment tank 1. The length of the transparent plates 8 is shorter than that of the wastewater treatment tank 1, and the back surfaces of two adjacent transparent plates 8 are fixedly connected to the inner wall of the wastewater treatment tank 1. A lamp 9 is provided in the transparent plates 8. The lower part of the wastewater treatment tank 1 is connected to a sewage pipe controlled by a valve.
[0020] When the present application is in use, the dimethyl sulfoxide wastewater enters the wastewater treatment tank 1 through the water inlet pipe 5, and then sodium hydroxide, hydrogen peroxide and ferrous sulfate are injected into the wastewater treatment tank 1 and the water pump 6 is started. The water pump 6 draws the mixed water into the circulation pipe 7 and flows down from the upper part of the wastewater treatment tank 1 through the circulation pipe 7 and falls on the corresponding transparent plate 8. Since a lamp tube 9 is provided in the transparent plate 8, the mixed water can be better photocatalyzed, thereby accelerating the reaction and quickly removing the dimethyl sulfoxide in the dimethyl sulfoxide wastewater. The water pump 6 circulates to pump up the mixed water and drop it from the transparent plate 8, which not only increases the contact time of the mixed water with light, so that all the mixed water can be illuminated by light, better realizing photocatalysis, but also can achieve better mixing of the various components in the mixed water.
[0021] The opposite ends of the glass plate extend through the wastewater treatment tank 1 and are sealed at the exit. A transverse groove is defined in the glass plate, into which a rectangular frame 10 slidably fits. Specifically, the inner walls of the groove are defined with sliding grooves, into which the rectangular frame 10 slidably fits. Multiple rows of light tubes 9 are removably fixed within the rectangular frame 10. The rectangular frame 10 slides within the groove, allowing for easy removal and repair of damaged light tubes 9. The light tubes 9 within the rectangular frame 10 are connected in parallel.
[0022] The parallel connection of the lamp tubes 9 can ensure that even if one of the lamp tubes 9 is damaged, it will not affect the normal operation of the other lamp tubes 9.
[0023] Transparent plate 8 comprises cleaning plate 81 and fixed plate 82, fixed plate 82 is fixedly arranged on wastewater treatment tank 1, cleaning plate 81 is located in wastewater treatment tank 1, groove extends to cleaning plate 81 through fixed plate 82, cleaning plate 81 and fixed plate 82 are sleeved with annular plates at the relative edges, the opposite surfaces of the two annular plates are fixedly connected with sealing gaskets, and the two annular plates are fixedly connected by bolts. The upper part of wastewater treatment tank 1 is closed by lid, and sodium hydroxide dosing pipe 2, hydrogen peroxide dosing pipe 3, ferrous sulfate dosing pipe 4 and water inlet pipe 5 are arranged on the lid. When carrying out wastewater treatment, open the lid and rotate the bolts, cleaning plate 81 can be removed from fixed plate 82, thereby cleaning cleaning plate 81, ensure its transparent state, conveniently and better carry out photocatalysis. And sealing gasket then plays a sealing role, prevents water from flowing through the gap between cleaning plate 81 and fixed plate 82 and entering.
[0024] The use of the present application can utilize the water pump 6 to circulate the water and flow it to the transparent plate 8 to be illuminated, so that all the mixed water can be illuminated, achieving a better catalytic effect and achieving better mixing of the various components in the mixed water.
[0025] Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention, rather than to limit it. Although the present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that they can still modify the technical solutions described in the aforementioned embodiments, or make equivalent replacements for some of the technical features therein. However, these modifications or replacements do not deviate the essence of the corresponding technical solutions from the spirit and scope of the technical solutions of the various embodiments of the present invention.
Claims
1. A dimethyl sulfoxide wastewater treatment equipment, characterized in that: The utility model comprises a wastewater treatment tank, the upper part of which is connected in sequence with a sodium hydroxide dosing pipe, a hydrogen peroxide dosing pipe, a ferrous sulfate dosing pipe and a water inlet pipe, the lower part of the wastewater treatment tank is connected with a water pump, the water outlet end of the water pump is connected with one end of a circulation pipe, the other end of the circulation pipe passes through the wastewater treatment tank and extends upward and bends downward above the wastewater treatment tank to pass into the wastewater treatment tank, a plurality of parallel transparent plates are arranged in the wastewater treatment tank, the length of the transparent plates is less than the length of the wastewater treatment tank and the back surfaces of two adjacent transparent plates are fixedly connected to the inner wall of the wastewater treatment tank, a lamp is arranged in the transparent plate, and the lower part of the wastewater treatment tank is connected with a sewage pipe controlled by a valve.
2. The dimethyl sulfoxide wastewater treatment equipment according to claim 1, characterized in that: The opposite ends of the glass plate pass through the wastewater treatment tank and the passing point is sealed. The glass plate is horizontally provided with a groove, and a rectangular frame is slidably fitted in the groove. The lamp tubes are arranged in multiple rows and are detachably fixed in the rectangular frame.
3. The dimethyl sulfoxide wastewater treatment equipment according to claim 2, characterized in that: Slide grooves are provided on the inner walls of both sides of the groove, the rectangular frame is slidably fitted in the slide grooves, and the lamp tubes located in the rectangular frame are connected in parallel.
4. The dimethyl sulfoxide wastewater treatment equipment according to claim 1, characterized in that: The transparent plate includes a cleaning plate and a fixed plate. The fixed plate is fixedly arranged on the wastewater treatment tank. The cleaning plate is located in the wastewater treatment tank. The groove extends to the cleaning plate through the fixed plate. An annular plate is sleeved on the opposite edges of the cleaning plate and the fixed plate. The opposite surfaces of the two annular plates are fixedly connected with sealing gaskets. The two annular plates are fixedly connected by bolts. The upper part of the wastewater treatment tank closes the lid. The sodium hydroxide dosing pipe, the hydrogen peroxide dosing pipe, the ferrous sulfate dosing pipe and the water inlet pipe are arranged on the lid.