Herbicide / safener combination based on safeners from the class of substituted [(1,5-diphenyl-1h-1,2,4-triazol-3-yl)oxy]acetic acids and their salts

Abstract

The present invention relates to combinations comprising one or more components (A) active as safener and one or more herbicidally active compounds (component (B)), wherein component (A) represents one or more compounds of general formula (I) or agrochemically compatible salts thereof, and component (B) represents one or more herbicides. The application further relates to a method and to the use of the herbicide / safener combinations of the invention for control of harmful plants or for growth regulation.

Description

[0001] BCS221028-Ausland Dr. ML - 1 - B ayer AGHerbicide / safener combinations based on safeners from the class of substituted [(1,5-diphenyl-1H-1,2,4-triazol-3-yl)oxy]acetic acids and salts thereof 5 Description The invention lies in the technical field of crop protection agents which can be used against undesired plant growth in cultivated land, for seed preparation or in plant crops 10 and which contain a combination of at least one safener (A) and at least one herbicide (B), where the safener (A) corresponds to one or more substituted [(1,5-diphenyl-1H-1,2,4-triazol-3-yl)oxy]acetic acids of the general formula (I) and / or their agrochemically acceptable salts (= component (A)). The effectiveness of known herbicides against weeds is at a high level, but generally depends on the application rate, the particular preparation form, the weed spectrum, the weeds to be controlled, the climatic and soil conditions, etc., but above all also on crop compatibility. One possibility for improving the application profile of a herbicide can be the combination 20 of a safener with one or more herbicidal active ingredients which contribute the desired additional properties. However, the combined use of several active ingredients not infrequently leads to phenomena of physical and biological incompatibility, e.g. insufficient stability in a co-formulation, decomposition of an active ingredient or antagonism between the active ingredients, or the safeners have a limited range of action which only protects the 25 crop against one herbicide but not against all components in the case of combined applications of several herbicides. Safeners, also called antidotes, with different chemical structures have been known for around 70 years. It is also known that they differ significantly in terms of their protective functions, 30 i.e.i.e., their use is limited to selected herbicides and / or the crops to be protected. In addition, it is required that a selected herbicide / safener combination does not adversely affect the herbicidal efficacy with respect to the weeds to be controlled. [(1,5-Diphenyl-1H-1,2,4-triazol-3-yl)oxy]acetic acid derivatives and their salts are known from the PCT-35 application with the application number PCT / EP2020 / 083167 (WO2021 / 105101). BCS221028-Ausland Dr. ML - 2 - It has now been found that compounds from the class of substituted [(1,5-Diphenyl-1H-1,2,4-triazol-3-yl)oxy]acetic acids can be used extremely effectively to protect various crops when applying one or more herbicides [component (B)] of different chemical structures. 5 The herbicide / safener combinations according to the invention act together in a particularly advantageous manner, e.g.when used to combat undesirable plant growth in crops such as wheat (durum and soft wheat), maize, soybeans, sugar beet, sugar cane, cotton, rice, beans (such as, for example, bush beans and horse beans), flax, barley, oats, rye, triticale, potatoes, and sorghum. The present invention thus relates to combinations comprising one or more safener-active components (A) and one or more herbicidally active compounds as component (B), where (A) represents one or more compounds of the general formula (I) or their agrochemically acceptable salts. and wherein 20 (R 1 ) n •-Phenyl for the group •L en Q-1.1 to Q-1.53 • • . BCS221028-Abroad Dr. ML - 3 - 0 0 0 0 0 0 0 0 0 0 0 . 0 0 0 0 0 0 0 0 0 0 0 BCS221028-Abroad Dr. ML - 4 - 0 * 0 0 0 5 . stands, and (R 2 ) m-Phenyl for groups Q-2.1 to Q-2.53 5 • 0 0 0 0 0 0 0 0 0 BCS221028-Abroad Dr. ML • - 5 - • BCS221028-Abroad Dr. ML - 6 - 0 0 . stands, R 3 stands for hydrogen, 5 and R 4für Wasserstoff, Methyl, Ethyl, n-Propyl, i-Propyl, n-Butyl, n-Pentyl, Phenyl, Benzyl, CH2(4-Cl-Ph), CH2(4-F-Ph), CH2(4-OMe-Ph), 2-Methoxyethyl, Tetrahydrofuran-2-yl-10 methyl, Tetrahydrofuran-3-yl-methyl, Tetrahydropyran-2-yl-methyl, Tetrahydropyran-3-yl- methyl, Tetrahydropyran-4-yl-methyl, Methylpropionat-3-yl, Ethylpropionat-3-yl, Methylacetat-2-yl, Ethylacetat-2-yl, Methylpivalat-2-yl, Ethylpivalat-3-yl, Methyl-2- methylpropanoat-3-yl, Methyl-2,2-dimethylpropanoat-3-yl, Ethyl-2-methylpropanoat-3-yl, Methyl-2-propanoat-2-yl, Ethyl-2-propanoat-2-yl, Methyl-acetat-2yl, Ethyl-acetat-2yl, 15 Methyl-1-methylcyclopropancarboxylat-2yl, Ethyl-1-methylcyclopropan-carboxylat-2yl, 2-(Dimethylamino)ethyl, Oxetan-3-yl, (3-Methyloxetan-3-yl)methyl, 2,2,2-Trifluorethyl, 2,2-Difluorethyl, 2-Fluorethyl, 2,2,3,3,3-Pentafluorpropyl, Cyclopropylmethyl, 1- Cyclopropyl-ethyl, (1-Methyl-cyclopropyl)-methyl, (2,2-Dichlorcyclopropyl)-methyl, (2,2- Dimethyl-cyclopropyl)-methyl, Allyl,Propargyl (Prop-2-yn-1-yl), 2-Chloroprop-2-en-1-yl, 3- 20 Phenylprop-2-yn-1-yl, 3,3-Dichloroprop-2-en-1-yl, 3,3-Dichloro-2-fluoro-prop-2-en-1-yl, Methylprop-2-yn-1-yl, 2-Methylprop-2-en-1-yl, But-2-en-1-yl, But-3-en-1-yl, But-2-yn-1-yl, But-3-yn-1-yl, 4-chloro-but-2-yn-1-yl, 3-methyl-but-2-en-1-yl, 3-methyl-but-1-en-1-yl, 1-(2E)-1-methylbut-2-en-1-yl, (E)-Pent-3-en-2-yl or (Z)-pent-3-en-2-yl, cyclobutylmethyl, cyclopentylmethyl, cyclohexylmethyl, heptan-2-yl, isobutyl, 1,3-dioxolan-2-ylmethyl or 1-ethyl-5-methyl-1-pyrazol-4-methyl, and (B) one or more herbicides [component (B)] from the group of herbicidal active ingredients with the general formula (II), A bedeutet N oder CY, X bedeutet Nitro, Halogen, Cyano, Formyl, Rhodano, (C1-C6)-Alkyl, Halogen-(C1-C6)-alkyl, (C2- C6)-Alkenyl, Halogen-(C2-C6)-alkenyl, (C2-C6)-Alkinyl, Halogen-(C3-C6)-alkinyl, (C3-C6)-Cycloalkyl, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Halogen-(C3-C6)-cycloalkyl-(C1-C6)- alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, NR 1 C(O)N(R 1 )2, OC(O)N(R 1 )2, C(O)NR 1 OR 1 , OR 1 , OCOR 1 , OSO2R 2 , S(O) n R 2 , SO2OR 1 , SO2N(R 1 )2, NR 1 SO2R 2 , NR 1 COR 1 , (C1-C6)- Alkyl-S(O) n R 2 , (C1-C6)-Alkyl-OR 1 , (C1-C6)-Alkyl-OCOR 1 , (C1-C6)-Alkyl-OSO2R 2 , (C1-C6)-Alkyl- CO2R 1 , (C1-C6)-Alkyl-SO2OR 1 , (C1-C6)-Alkyl-CON(R 1)2, (C1-C6)-Alkyl-SO2N(R 1 )2, (C1-C6)-Alkyl- NR 1 COR 1 , (C1-C6)-Alkyl-NR 1 SO2R 2 , NR 1 R 2 , P(O)(OR 5 )2, CH2P(O)(OR 5 )2, (C1-C6)-Alkyl-Heteroaryl, (C1-C6)-Alkyl-Heterocyclyl, wobei die beiden letztgenannten Reste jeweils durch s Reste aus der Gruppe bestehend aus Halogen, (C1-C6)-Alkyl, Halogen-(C1-C6)-alkyl, S(O)n-(C1-C6)-Alkyl, (C1-C6)- Alkoxy und Halogen-(C1-C6)-alkoxy substituiert sind, und wobei Heterocyclyl n Oxogruppen trägt, Y bedeutet Wasserstoff, Nitro, Halogen, Cyano, Rhodano, (C1-C6)-Alkyl, Halogen-(C1-C6)-alkyl, (C2-C6)-Alkenyl, Halogen-(C2-C6)-alkenyl, (C2-C6)-Alkinyl, Halogen-(C2-C6)-alkinyl, (C3-C6)- Cycloalkyl, (C3-C6)-Cycloalkenyl, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Halogen-(C3-C6)-cycloalkyl-(C1-C6)-alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, NR 1 C(O)N(R1 )2, OC(O)N(R 1 )2, CO(NOR 1 )R 1 , NR 1 SO2R 2 , NR 1 COR 1 , OR 1 , OSO2R 2 , S(O)nR 2 , SO2OR 1 , SO2N(R 1 )2, (C1-C6)-Alkyl-S(O)nR 2 , (C1-C6)-Alkyl-OR 1 , (C1-C6)-Alkyl-OCOR 1 , (C1-C6)-Alkyl-OSO2R 2 , (C1-C6)-Alkyl-CO2R 1 , (C1-C6)-Alkyl-CN, (C1-C6)-Alkyl-SO2OR 1 , (C1-C6)-Alkyl-CON(R 1 )2, (C1-C6)- Alkyl-SO2N(R 1 )2, (C1-C6)-Alkyl-NR 1 COR 1 , (C1-C6)-Alkyl-NR 1 SO2R 2 , N(R 1 )2, P(O)(OR 5 )2, CH2P(O)(OR 5)2, (C1-C6)-Alkyl-Phenyl, (C1-C6)-Alkyl-Heteroaryl, (C1-C6)-Alkyl-Heterocyclyl, Phenyl, Heteroaryl oder Heterocyclyl, wobei die sechs letztgenannten Reste jeweils durch s Reste aus der Gruppe bestehend aus Halogen, Nitro, Cyano, (C1-C6)-Alkyl, Halogen-(C1-C6)-alkyl, (C3-C6)- Cycloalkyl, S(O)n-(C1-C6)-Alkyl, (C1-C6)-Alkoxy, Halogen-(C1-C6)-alkoxy, (C1-C6)-Alkoxy-(C1-C4)- alkyl und Cyanomethyl substituiert sind, und wobei Heterocyclyl n Oxogruppen trägt, Z bedeutet Halogen, Cyano, Rhodano, Halogen-(C1-C6)-alkyl, (C2-C6)-Alkenyl, Halogen-(C2-C6)- alkenyl, (C2-C6)-Alkinyl, Halogen-(C2-C6)-alkinyl, (C3-C6)-Cycloalkyl, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Halogen-(C3-C6)-cycloalkyl-(C1-C6)-alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, NR 1 C(O)N(R 1 )2, OC(O)N(R 1 )2, C(O)NR 1 OR 1 , OSO2R 2 , S(O) n R 2 , SO2OR1 , SO2N(R 1 )2, NR 1 SO2R 2 , NR 1 COR 1 , (C1-C6)-alkyl-S(O) n R 2 , (C1-C6)-alkyl-OR 1 , (C1-C6)-alkyl-OCOR 1 , (C1-C6)-alkyl-OSO2R 2 , (C1-C6)-alkyl-CO2R 1 , (C1-C6)-alkyl-SO2OR 1 , (C1-C6)-alkyl-CON(R 1 )2, (C1-C6)-alkyl-SO2N(R 1 )2, (C1-C6)-alkyl-NR 1 COR 1 , (C1-C6)-alkyl-NR 1 SO2R 2 , N(R 1 )2, P(O)(OR 5 )2, heteroaryl, heterocyclyl or phenyl, where the last three radicals are each substituted by s radicals from the group consisting of halogen, nitro, cyano, (C1-C6)-alkyl, halogen-(C1-C6)-alkyl, (C3-C6)-cycloalkyl, S(O)n-(C1-C6)-alkyl, (C1-C6)-alkoxy or halogen-(C1-C6)-alkoxy, and where heterocyclyl carries n oxo groups, or Z can also be hydrogen, (C1-C6)-alkyl or (C1-C6)-alkoxy if Y is the radical S(O)nR 2R is (C1-C8)-alkyl, halogen-(C1-C8)-alkyl, (C2-C8)-alkenyl, halogen-(C2-C8)-alkenyl, (C2-C8)-alkynyl, halogen-(C2-C8)-alkynyl, where these six radicals mentioned above are each substituted by s radicals from the group consisting of hydroxy, nitro, cyano, SiR 5 3, PO(OR 5 )2, S(O)n-(C1-C6)-alkyl, S(O)n-(C1-C6)-haloalkyl, (C1-C6)-alkoxy, halogen-(C1-C6)-alkoxy, N(R 3 )2, COR 3 , COOR 3 , OCOR 3 , NR 3 COR 3 , NR 3 SO2R 4, O(C1-C2)-alkyl-(C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl, heteroaryl, heterocyclyl, phenyl, where the last three radicals are each substituted by s radicals from the group consisting of methyl, ethyl, methoxy, trifluoromethyl, cyano and halogen, and where heterocyclyl carries n oxo groups, or R is each substituted by s radicals from the group consisting of halogen, nitro, cyano, (C1-C6)-alkyl, halogen-(C1-C6)-alkyl, (C3-C6)-cycloalkyl, S(O)n-(C1-C6)-alkyl, (C1-C6)-alkoxy, halogen-(C1-C6)-alkoxy and (C1-C6)-alkoxy-(C1-C4)-alkyl (C3–C7)-cycloalkyl, heteroaryl, heterocyclyl or phenyl, where heterocyclyl carries n oxo groups, R 1bedeutet Wasserstoff, (C1-C6)-Alkyl, (C1-C6)-Halogenalkyl, (C2-C6)-Alkenyl, (C2-C6)- Halogenalkenyl, (C2-C6)-Alkinyl, (C2-C6)-Halogenalkinyl, (C3-C6)-Cycloalkyl, (C3-C6)-Cycloalkenyl, (C3-C6)-Halogencycloalkyl, (C1-C6)-Alkyl-(C3-C6)-cycloalkyl, (C1-C6)-Alkyl-O-(C1-C6)-alkyl, (C3-C6)- Cycloalkyl-(C1-C6)-alkyl, Phenyl, Phenyl-(C1-C6)-alkyl, Heteroaryl, (C1-C6)-Alkyl-Heteroaryl, Heterocycl, (C1-C6)-Alkyl-Heterocyclyl, (C1-C6)-Alkyl-O-Heteroaryl, (C1-C6)-Alkyl-O-Heterocyclyl, (C1-C6)-Alkyl-NR 3 -Heteroaryl oder (C1-C6)-Alkyl-NR 3 -Heterocyclyl wobei die 21 letztgenannten Reste jeweils durch s Reste aus der Gruppe bestehend aus Cyano, Nitro, Rhodano, OR 3 , S(O) n R 4 , N(R 3 )2, NR 3 OR 3 , COR 3 , OCOR 3 , SCOR 4 , NR 3 COR 3 , NR 3 SO2R 4, CO2R 3 , COSR 4 , CON(R 3)2und (C1-C4)- Alkoxy-(C2-C6)-alkoxycarbonyl substituiert sind, und wobei Heterocyclyl n Oxogruppen trägt, R 2 bedeutet (C1-C6)-Alkyl, (C1-C6)-Halogenalkyl, (C2-C6)-Alkenyl, (C2-C6)-Halogenalkenyl, (C2- C6)-Alkinyl, (C2-C6)-Halogenalkinyl, (C3-C6)-Cycloalkyl, (C3-C6)-Cycloalkenyl, (C3-C6)- Halogencycloalkyl, (C1-C6)-Alkyl-O-(C1-C6)-alkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Phenyl, Phenyl- (C1-C6)-alkyl, Heteroaryl, (C1-C6)-Alkyl-Heteroaryl, Heterocyclyl, (C1-C6)-Alkyl-Heterocyclyl, (C1-C6)- Alkyl-O-Heteroaryl, (C1-C6)-Alkyl-O-Heterocyclyl, (C1-C6)-Alkyl-NR 3 -Heteroaryl oder (C1-C6)-Alkyl- NR 3 -Heterocyclyl, wobei die 21 letztgenannten Reste jeweils durch s Reste aus der Gruppe bestehend aus Cyano, Halogen, Nitro, Rhodano, OR 3 , S(O)nR 4 , N(R 3 )2, NR 3 OR 3 , COR 3 , OCOR 3 , SCOR 4 , NR 3 COR 3 , NR 3 SO2R 4 , CO2R 3 , COSR4 , CON(R 3 )2 und (C1-C4)-Alkoxy-(C2-C6)-alkoxycarbonyl substituiert sind, und wobei Heterocyclyl n Oxogruppen trägt, R 3 bedeutet Wasserstoff, (C1-C6)-Alkyl, (C2-C6)-Alkenyl, (C2-C6)-Alkinyl, (C3-C6)-Cycloalkyl, (C3- C6)-Cycloalkyl-(C1-C6)-alkyl oder Phenyl, R 4 bedeutet (C1-C6)-Alkyl, (C2-C6)-Alkenyl, (C2-C6)-Alkinyl, (C3-C6)-Cycloalkyl, (C3-C6)- Cycloalkyl-(C1-C6)-alkyl oder Phenyl, R 5means (C1-C4)alkyl, n means 0, 1 or 2, s means 0, 1, 2 or 3. The herbicidal active ingredients of the formula (I) are known, for example, from WO 2012 / 028579 A1, WO 2013 / 064458 A1, WO 2013 / 174845 A1, WO 2016 / 001075 A1, WO 2016 / 001073 A1, WO 2018 / 202535 A1, WO 2019 / 025540 A1, WO 2021 / 204665 A1 and WO 2021 / 204666 A1. In the following, only the neutral compound is mentioned, thus encompassing all existing forms as listed, unless a specific form of the active ingredient is relevant in a particular context, such as in the table examples below for biological activity. The herbicide / safener combinations according to the invention may contain further components, e.g.other active ingredients against harmful organisms such as harmful plants, plant-harming animals or plant-harming fungi, in particular active ingredients from the group of herbicides, other than the herbicides listed under B, fungicides, insecticides, acaricides, nematicides and miticides and related substances, or also other types of plant protection active ingredients (e.g. resistance inducers), crop-protecting active ingredients (safeners, antidotes, other than component (A)), plant growth regulators and / or additives and / or formulation aids commonly used in plant protection. The components can be formulated and applied together (ready-made formulation) or they can be formulated separately and applied together, e.g. in a tank mix or in sequential application. The individual safeners of the general formula (I) contained as component (A) are also referred to below as compounds (A), active ingredients (A), components (A) or safeners (A).Accordingly, the individual herbicidal active ingredients contained as component (B) are also referred to below as compounds (B), active ingredients (B), components (B), herbicides (B) or compounds of the formula (II). An advantageous property of the combination of safeners (A) and herbicides (B) according to the invention is that safeners (A) and herbicides (B) are compatible with one another, i.e. they can be used together without significant chemical incompatibilities between the safener (A) and / or the herbicides (B) occurring, which could lead to decomposition of the safener (A) or the herbicide(s) (B). This favorable compatibility also extends to the biological properties of the active ingredients when used in combination. Thus, antagonistic effects are generally not observed when controlling weeds with the herbicide / safener combinations according to the invention.The following definitions apply in formula (I) for compounds of the safeners (A) and in formula (II) for compounds of the herbicides (B) and all subsequent formulas: The compounds of formula (I) or (II) can exist as stereoisomers depending on the nature and linkage of the substituents. If, for example, one or more asymmetrically substituted carbon atoms and / or sulfoxides are present, enantiomers and diastereomers can occur. Stereoisomers can be obtained from the mixtures obtained during production by customary separation methods, for example by chromatographic separation processes. Stereoisomers can also be selectively prepared by using stereoselective reactions using optically active starting materials and / or auxiliaries. The invention also relates to all stereoisomers and mixtures thereof which are encompassed by formula (I) or (II) but are not specifically defined.For the sake of simplicity, however, reference is always made below to compounds of formula (I) or (II), although both the pure compounds and, where appropriate, mixtures with varying proportions of isomeric compounds are meant. Depending on the nature of the substituents defined above, the compounds of formula (I) or (II) exhibit acidic properties and can form salts, optionally also internal salts or adducts, with inorganic or organic bases or with metal ions. If the compounds of formula (I) or (II) carry hydroxyl, carboxyl, or other groups that induce acidic properties, these compounds can be reacted with bases to form salts.Suitable bases include, for example, hydroxides, carbonates, bicarbonates of alkali and alkaline earth metals, in particular those of sodium, potassium, magnesium and calcium, as well as ammonia, primary, secondary and tertiary amines with (C1-C4) alkyl groups, mono-, di- and trialkanolamines of (C1-C4) alkanols, choline and chlorocholine, and organic amines such as trialkylamines, morpholine, piperidine or pyridine. These salts are compounds in which the acidic hydrogen is replaced by a cation suitable for agriculture, for example metal salts, in particular alkali metal salts or alkaline earth metal salts, in particular sodium and potassium salts, or ammonium salts, salts with organic amines or quaternary ammonium salts, for example with cations of the formula [N. wherein R to R''' each independently represent an organic radical, in particular alkyl, aryl, aralkyl or alkylaryl. Alkylsulfonium and alkylsulfoxonium salts, such as (C1-C4)-trialkylsulfonium and (C1-C4)-trialkylsulfoxonium salts, are also suitable. The compounds of formula (I) or (II) can form salts by addition of a suitable inorganic or organic acid, such as, for example, mineral acids such as HCl, HBr, H2SO4, H3PO4 or HNO3, or organic acids, e.g. carboxylic acids such as formic acid, acetic acid, propionic acid, oxalic acid, lactic acid or salicylic acid or sulfonic acids such as, for example, p-toluenesulfonic acid, to a basic group, such as, for example, amino, alkylamino, dialkylamino, piperidino, morpholino or pyridino. These salts then contain the conjugate base of the acid as an anion. Suitable substituents in deprotonated form, such asSulfonic acids or carboxylic acids, can form internal salts with protonatable groups, such as amino groups. If a group is polysubstituted by radicals, this means that this group is substituted by one or more of the same or different radicals mentioned. Preferred, particularly preferred and very particularly preferred meanings are described below for the individual safeners (A) and the herbicides (B). If the compounds can form tautomers by hydrogen shift which would not be structurally covered by the general formula (A), these tautomers are nevertheless encompassed by the definition of the compounds of the general formula (A) according to the invention, unless a specific tautomer is the subject of consideration.For example, many carbonyl compounds can exist in both the keto and the enol form, both forms being encompassed by the definition of a compound of general formula (A). The compounds of general formula (I) can exist as stereoisomers depending on the type and linkage of the substituents. The possible stereoisomers defined by their specific spatial form, such as enantiomers, diastereomers, Z and E isomers, are all encompassed by general formula (I). If, for example, one or more alkenyl groups are present, diastereomers (Z and E isomers) can occur. If, for example, one or more asymmetric carbon atoms are present, enantiomers and diastereomers can occur. Stereoisomers can be obtained from the mixtures obtained during production using conventional separation methods. Chromatographic separation can be carried out on an analytical scale to determine the enantiomeric excess or the enantiomeric concentration.of the diastereomeric excess, as well as on a preparative scale for the production of test samples for biological testing. Stereoisomers can also be prepared selectively by using stereoselective reactions using optically active starting materials and / or auxiliaries. The invention thus also relates to all stereoisomers encompassed by the general formula (I) but not indicated with their specific stereoform, as well as mixtures thereof. If the compounds are obtained as solids, purification can also be carried out by recrystallization or digestion. If individual compounds of the general formula (I) cannot be satisfactorily obtained by the routes described below, they can be prepared by derivatization of other compounds of the general formula (I).Suitable methods for the isolation, purification, and stereoisomer separation of compounds of general formula (I) include methods generally known to the person skilled in the art from analogous cases, e.g., physical processes such as crystallization, chromatography, especially column chromatography and HPLC (high-pressure liquid chromatography), distillation, optionally under reduced pressure, extraction, and other processes. Any remaining mixtures can generally be separated by chromatographic separation, e.g., on chiral solid phases. For preparative quantities or on an industrial scale, processes such as crystallization, e.g., of diastereomeric salts, which can be obtained from the diastereomer mixtures with optically active acids and, if acidic groups are present, with optically active bases, are suitable.In a first embodiment of the present invention, the herbicide / safener combination according to the invention contains, in addition to at least one component (B) as defined above, preferably a compound [component A] of the general formula (I) or its agronomically acceptable salts [safener (A)] according to Table 1. Table 1: IUPAC names and the structural formulas of the preferred compounds of the formula (I) (safener (A)). The compounds of the formula (I) are known from the international application with the application number PCT / EP2020 / 083167 (WO2021 / 105101) and can be prepared by the processes described therein. The application rates of the herbicides (B) are in the range from 20 to 400 g of active ingredient per hectare (hereinafter g ai / ha), preferably 40 to 200 g ai / ha, in particular 40 to 100 g ai / ha), and of the safener (A) in the range from 1 to 1000 g ai / ha, preferably from 10 to 500 g ai / ha, in particular from 20 to 200 g / ha of active ingredient. Particularly preferred safeners (A) for the purposes of the present invention are the compounds with the numbers A1, A3 and A5, according to Table 1 above. As combination partner (B) [= component (B) orHerbicides (B)] are in principle all active ingredients of subgroups (B1) to (B11) suitable, the designation of the herbicidal active ingredients largely being based on the “common name” (in English spelling) according to the reference “The Pesticide Manual” 14th Ed., British Crop Protection Council 2006, abbreviated “PM” or the chemical name according to the usual nomenclature (IUPAC or Chemical Abstracts). However, some herbicides (B) have surprisingly proven to be particularly good combination partners with the safeners (A). The preferred and particularly preferred herbicides (B) are listed below as further embodiments of the present invention. In a second embodiment of the present invention, the herbicidal active ingredients of the formula (II) are preferred. worin, A bedeutet N oder CY, X bedeutet Halogen, (C1-C6)-Alkyl, Halogen-(C1-C6)-alkyl, (C2-C6)-Alkenyl, Halogen-(C2-C6)- alkenyl, (C2-C6)-Alkinyl, Halogen-(C3-C6)-alkinyl, (C3-C6)-Cycloalkyl, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Halogen-(C3-C6)-cycloalkyl-(C1-C6)-alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, OC(O)N(R 1 )2, C(O)NR 1 OR 1 , OR 1 , OCOR 1 , OSO2R 2 , S(O) n R 2 , NR 1 SO2R 2 , NR 1 COR 1 , (C1-C6)-Alkyl-S(O) n R 2 , (C1-C6)-Alkyl-OR 1 , (C1-C6)-Alkyl-OCOR 1 , (C1-C6)-Alkyl-OSO2R 2 , (C1-C6)-Alkyl-CO2R 1 , (C1-C6)-Alkyl-SO2OR 1 , (C1-C6)-Alkyl-CON(R 1 )2, (C1-C6)-Alkyl-SO2N(R 1 )2, (C1- C6)-Alkyl-NR 1 COR 1 , (C1-C6)-Alkyl-NR 1 SO2R2 , Y bedeutet Wasserstoff, Halogen, Cyano, (C1-C6)-Alkyl, Halogen-(C1-C6)-alkyl, (C2-C6)-Alkenyl, Halogen-(C2-C6)-alkenyl, (C2-C6)-Alkinyl, Halogen-(C2-C6)-alkinyl, (C3-C6)-Cycloalkyl, (C3-C6)- Cycloalkenyl, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Halogen-(C3-C6)- cycloalkyl-(C1-C6)-alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, NR 1 C(O)N(R 1 )2, OC(O)N(R 1 )2, CO(NOR 1 )R 1 , NR 1 SO2R 2 , NR 1 COR 1 , OR 1 , OSO2R 2 , S(O)nR 2 , SO2OR 1 , SO2N(R 1 )2, (C1- C6)-Alkyl-S(O)nR 2 , (C1-C6)-Alkyl-OR 1 , (C1-C6)-Alkyl-OCOR 1 , (C1-C6)-Alkyl-OSO2R 2 , (C1-C6)-Alkyl- CO2R 1 , (C1-C6)-Alkyl-CN, (C1-C6)-Alkyl-SO2OR 1 , (C1-C6)-Alkyl-CON(R 1 )2, (C1-C6)-Alkyl-SO2N(R 1)2, (C1-C6)-Alkyl-NR 1 COR 1 , (C1-C6)-Alkyl-NR 1 SO2R 2 , N(R 1 )2, Heterocyclyl, wobei Heterocyclyl n Oxogruppen tragen kann Z bedeutet Halogen, Halogen-(C1-C6)-alkyl, (C2-C6)-Alkenyl, Halogen-(C2-C6)-alkenyl, (C2-C6)- Alkinyl, Halogen-(C2-C6)-alkinyl, (C3-C6)-Cycloalkyl, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-Cycloalkyl- (C1-C6)-alkyl, Halogen-(C3-C6)-cycloalkyl-(C1-C6)-alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, NR 1 C(O)N(R 1 )2, OC(O)N(R 1 )2, C(O)NR 1 OR 1 , OSO2R 2 , S(O)nR 2 , SO2OR 1 , SO2N(R 1 )2, NR 1 SO2R 2 , NR 1 COR 1 , (C1-C6)-Alkyl-S(O)nR 2 , (C1-C6)-Alkyl-OR 1 , (C1-C6)-Alkyl-OCOR 1 , (C1-C6)- Alkyl-OSO2R 2 , (C1-C6)-Alkyl-CO2R 1 , (C1-C6)-Alkyl-SO2OR 1, (C1-C6)-Alkyl-CON(R 1 )2, (C1-C6)-Alkyl- SO2N(R 1 )2, (C1-C6)-Alkyl-NR 1 COR 1 , (C1-C6)-Alkyl-NR 1 SO2R 2 , N(R 1 )2, Z kann auch Wasserstoff, (C1-C6)-Alkyl oder (C1-C6)-Alkoxy bedeuten, falls Y für den Rest S(O)nR 2 steht, R bedeutet (C1–C8)-Alkyl, Halogen-(C1–C8)-alkyl, (C2-C8)-Alkenyl, Halogen-(C2-C8)-alkenyl, (C2- C8)-Alkinyl, Halogen-(C2-C8)-alkinyl, (C3-C6)-Cycloalkyl, Phenyl, R 1 bedeutet Wasserstoff, (C1-C6)-Alkyl, (C1-C6)-Halogenalkyl, (C2-C6)-Alkenyl, (C2-C6)- Halogenalkenyl, (C2-C6)-Alkinyl, (C2-C6)-Halogenalkinyl, (C3-C6)-Cycloalkyl, (C3-C6)-Cycloalkenyl, (C3-C6)-Halogencycloalkyl, (C1-C6)-Alkyl-O-(C1-C6)-alkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Phenyl, Phenyl-(C1-C6)-alkyl, Heteroaryl, (C1-C6)-Alkyl-Heteroaryl, Heterocyclyl, wobei (C3-C6)-Cycloalkyl mit s Resten (C1-C6)-Alkyl substituiert sein kann, R 2bedeutet (C1-C6)-Alkyl, (C1-C6)-Halogenalkyl, (C2-C6)-Alkenyl, (C2-C6)-Halogenalkenyl, (C2- C6)-Alkinyl, (C2-C6)-Halogenalkinyl, (C3-C6)-Cycloalkyl, (C3-C6)-Cycloalkenyl, (C3-C6)- Halogencycloalkyl, (C1-C6)-Alkyl-O-(C1-C6)-alkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Phenyl, n bedeutet 0, 1 oder 2, s bedeutet 0, 1, 2 oder 3. In einer dritten Ausführungsform der vorliegenden Erfindung sind die herbiziden Wirkstoffe der Formel (II) bevorzugt, worin, A bedeutet CY, X bedeutet Halogen, (C1-C6)-Alkyl, Halogen-(C1-C6)-alkyl, (C2-C6)-Alkenyl, Halogen-(C2-C6)- alkenyl, (C2-C6)-Alkinyl, Halogen-(C3-C6)-alkinyl, (C3-C6)-Cycloalkyl, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Halogen-(C3-C6)-cycloalkyl-(C1-C6)-alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, OC(O)N(R 1 )2, C(O)NR 1 OR 1 , OR 1 , OCOR 1 , OSO2R 2 , S(O)nR 2 , NR1 SO2R 2 , NR 1 COR 1 , (C1-C6)-Alkyl-S(O)nR 2 , (C1-C6)-Alkyl-OR 1 , (C1-C6)-Alkyl-OCOR 1 , (C1-C6)-Alkyl-OSO2R 2 , (C1-C6)-Alkyl-CO2R 1 , (C1-C6)-Alkyl-SO2OR 1 , (C1-C6)-Alkyl-CON(R 1 )2, (C1-C6)-Alkyl-SO2N(R 1 )2, (C1- C6)-Alkyl-NR 1 COR 1 , (C1-C6)-Alkyl-NR 1 SO2R 2 , Y bedeutet Wasserstoff, Halogen, Cyano, (C1-C6)-Alkyl, Halogen-(C1-C6)-alkyl, (C2-C6)-Alkenyl, Halogen-(C2-C6)-alkenyl, (C2-C6)-Alkinyl, Halogen-(C2-C6)-alkinyl, (C3-C6)-Cycloalkyl, (C3-C6)- Cycloalkenyl, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Halogen-(C3-C6)- cycloalkyl-(C1-C6)-alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, NR 1 C(O)N(R 1 )2, OC(O)N(R 1 )2, CO(NOR 1 )R 1 , NR 1 SO2R 2 , NR1 COR 1 , OR 1 , OSO2R 2 , S(O)nR 2 , SO2OR 1 , SO2N(R 1 )2, (C1- C6)-Alkyl-S(O)nR 2 , (C1-C6)-Alkyl-OR 1 , (C1-C6)-Alkyl-OCOR 1 , (C1-C6)-Alkyl-OSO2R 2 , (C1-C6)-Alkyl- CO2R 1 , (C1-C6)-Alkyl-CN, (C1-C6)-Alkyl-SO2OR 1 , (C1-C6)-Alkyl-CON(R 1 )2, (C1-C6)-Alkyl-SO2N(R 1 )2, (C1-C6)-Alkyl-NR 1 COR 1 , (C1-C6)-Alkyl-NR 1 SO2R 2 , N(R 1 )2, Heterocyclyl, wobei Heterocyclyl n Oxogruppen tragen kann, Z bedeutet Halogen, Halogen-(C1-C6)-alkyl, (C2-C6)-Alkenyl, Halogen-(C2-C6)-alkenyl, (C2-C6)- Alkinyl, Halogen-(C2-C6)-alkinyl, (C3-C6)-Cycloalkyl, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-Cycloalkyl- (C1-C6)-alkyl, Halogen-(C3-C6)-cycloalkyl-(C1-C6)-alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, NR 1 C(O)N(R 1)2, OC(O)N(R 1 )2, C(O)NR 1 OR 1 , OSO2R 2 , S(O) n R 2 , SO2OR 1 , SO2N(R 1 )2, NR 1 SO2R 2 , NR 1 COR 1 , (C1-C6)-Alkyl-S(O) n R 2 , (C1-C6)-Alkyl-OR 1 , (C1-C6)-Alkyl-OCOR 1 , (C1-C6)- Alkyl-OSO2R 2 , (C1-C6)-Alkyl-CO2R 1 , (C1-C6)-Alkyl-SO2OR 1 , (C1-C6)-Alkyl-CON(R 1 )2, (C1-C6)-Alkyl- SO2N(R 1 )2, (C1-C6)-Alkyl-NR 1 COR 1 , (C1-C6)-Alkyl-NR 1 SO2R 2 , N(R 1 )2, Z kann auch Wasserstoff, (C1-C6)-Alkyl oder (C1-C6)-Alkoxy bedeuten, falls Y für den Rest S(O)nR 2 steht, R bedeutet (C1–C8)-Alkyl, Halogen-(C1–C8)-alkyl, (C2-C8)-Alkenyl, Halogen-(C2-C8)-alkenyl, (C2- C8)-Alkinyl, Halogen-(C2-C8)-alkinyl, (C3-C6)-Cycloalkyl, Phenyl, R 1bedeutet Wasserstoff, (C1-C6)-Alkyl, (C1-C6)-Halogenalkyl, (C2-C6)-Alkenyl, (C2-C6)- Halogenalkenyl, (C2-C6)-Alkinyl, (C2-C6)-Halogenalkinyl, (C3-C6)-Cycloalkyl, (C3-C6)-Cycloalkenyl, (C3-C6)-Halogencycloalkyl, (C1-C6)-Alkyl-O-(C1-C6)-alkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Phenyl, Phenyl-(C1-C6)-alkyl, Heteroaryl, (C1-C6)-Alkyl-Heteroaryl, Heterocyclyl, wobei (C3-C6)-Cycloalkyl mit s Resten (C1-C6)-Alkyl substituiert sein kann, R 2 bedeutet (C1-C6)-Alkyl, (C1-C6)-Halogenalkyl, (C2-C6)-Alkenyl, (C2-C6)-Halogenalkenyl, (C2- C6)-Alkinyl, (C2-C6)-Halogenalkinyl, (C3-C6)-Cycloalkyl, (C3-C6)-Cycloalkenyl, (C3-C6)- Halogencycloalkyl, (C1-C6)-Alkyl-O-(C1-C6)-alkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Phenyl, n bedeutet 0, 1 oder 2, s bedeutet 0, 1, 2 oder 3. In einer vierten Ausführungsform der vorliegenden Erfindung sind die herbiziden Wirkstoffe der Formel (II) bevorzugt, worin, A bedeutet CY, X bedeutet Halogen, (C1-C6)-Alkyl, (C1-C6)-Alkyl-OR 1, Y means S(O) n R 2 , OR 1 , (C1-C6)-alkyl-OR 1 , COR 1 , C(O)N(R 1 )2, heterocyclyl, where heterocyclyl may carry n oxo groups, Z is halogen, halogen-(C1-C6)-alkyl, (C3-C6)-cycloalkyl, S(O) n R 2 , Z can also be (C1-C6)-alkyl if Y is the radical S(O) n R 2 R is (C1–C8)-alkyl, R 1 means (C1-C6)-alkyl, (C3-C6)-cycloalkyl, (C1-C6)-haloalkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl, where (C3-C6)-cycloalkyl can be substituted with s radicals (C1-C6)-alkyl, R 2 means (C1-C6)-alkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl, (C3-C6)-cycloalkyl, (C1-C6)-alkyl-O-(C1-C6)-alkyl, n means 0, 1 or 2, s means 0, 1, 2 or 3. In a fifth embodiment of the present invention, the herbicidally active compounds of the formula (II) are preferred, wherein, A is CY, X is halogen, (C1-C6)-alkyl, (C1-C6)-alkyl-OR 1, Y bedeutet Methylsulfanyl, Methylsulfinyl, Methylsulfonyl, Ethylsulfanyl, Ethylsulfinyl, Ethylsulfonyl, Methylaminocarbonyl, Ethylaminocarbonyl, Cyclopropylaminocarbonyl, Isopropylaminocarbonyl, Cyclopropylmethylaminocarbonyl, Dimethylaminocarbonyl, Methylcarbonyl, Ethylcarbonyl, Cyclopropylcarbonyl, Methoxymethyl, Ethoxymethyl, Methoxy, Ethoxy, Cyclopropyloxy, Cyclopropylmethoxy, Z bedeutet Halogen, Halogen-(C1-C6)-alkyl, R 2 (O)nS, (C3-C6)-Cycloalkyl, Z kann auch (C1-C6)-Alkyl bedeuten, falls Y für die Reste Methylsulfinyl, Methylsulfanyl, Methylsulfonyl, Ethylsulfinyl, Ethylsulfanyl, Ethylsulfonyl, Cyclopropylmethylsulfinyl, Cyclopropylmethylsulfanyl, Cyclopropylmethylsulfonyl steht, R 1 bedeutet (C1-C6)-Alkyl, R 2means (C1-C6)-alkyl, n means 0, 1 or 2. In a sixth embodiment of the present invention, the herbicidal active compounds of the formula (II) listed in Table 2 below, in which A is CY, are preferred. The abbreviations used therein mean: Et = Ethyl Me = Methyl n-Pr = n-Propyl i-Pr = Isopropyl c-Pr = Cyclopropyl Table 2: - Within the scope of the present invention, it is possible to combine the individual preferred and particularly preferred compounds with one another as desired. This means that herbicidal compositions comprising safeners (A), one or more compounds of general formula (I) or their agrochemically acceptable salts [component (A)], and (B) one or more herbicides [component (B)] are encompassed by the present invention, in which any disclosed, preferred, and particularly preferred embodiments as listed above can be combined with one another. Some binary combinations comprising a compound (A) of general formula (I) acting as a safener or its agrochemically acceptable salts [safener (A)], and a herbicide (B) have surprisingly proven particularly advantageous at the time of application. These are listed in Table 3 below. Table 3: Higher-order herbicide / safener combinations from the aforementioned binary combinations are also possible according to the invention, for example by using the same safener and blending two binary combinations, which are mentioned below in connection with this specific safener. Furthermore, the herbicide / safener combinations according to the invention can be used together with other active ingredients such as fungicides, insecticides, acaricides, etc. and / or plant growth regulators or adjuvants from the group of additives customary in crop protection, such as adjuvants and formulation aids. Their application forms, such as formulations or tank mixes, represent herbicidal compositions (compositions). The invention therefore also relates to the herbicide / safener combinations which can be combined with additives customary in crop protection, such as adjuvants and formulation aids.and optionally further plant protection active ingredients. The invention also relates to the use of, or the application method using, the herbicide / safener combinations according to the invention as herbicides and plant growth regulators, preferably as herbicides and plant growth regulators with a synergistically effective content of the respective herbicide combination contained. For the active ingredients from group (B), the application rate is preferably in the range from 20 to 400 g ai / ha, in particular in the range from 40 to 200 g / ha, and most preferably in the range from 40 to 100 g ai / ha. The ratios (A):(B) based on the weight are, depending on the effective application rates, generally in the range from 1:400 to 500:1, preferably in the range from 1:100 to 100:1.particularly preferably in the range of 1:40 to 20:1. The quantities stated are application rates (g ai / ha = grams of active substance per hectare) and thus also define the quantitative ratios in a co-formulation, a premix, a tank mix, or a sequential application of the combined active ingredients. The herbicide / safener combinations according to the invention can contain further components, e.g. other active ingredients against harmful organisms such as harmful plants, plant-harming animals, or plant-harming fungi, in particular active ingredients from the group of fungicides, insecticides, acaricides, nematicides, miticides, and related substances. Fungicidal compounds that can be used in conjunction with the herbicide / safener combinations according to the invention are preferably commercially available active ingredients, for example (analogous to the herbicides, the compounds are generally referred to by their common names),hier in der üblichen englischen Schreibweise): 1) Inhibitoren der Ergosterol-Biosynthese, beispielsweise Cyproconazol, Difenoconazol, Epoxiconazol, Fenhexamid, Fenpropidin, Fenpropimorph, Fenpyrazamin, Fluquinconazol, Flutriafol, Imazalil, Imazalil Sulfat, Ipconazol, Metconazol, Myclobutanil, Paclobutrazol, Prochloraz, Propiconazol, Prothioconazol, Pyrisoxazol, Spiroxamin, Tebuconazol, Tetraconazol, Triadimenol, Tridemorph, Triticonazol, (1R,2S,5S)-5-(4-Chlorbenzyl)-2-(chlormethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclo-pentanol, (1S,2R,5R)-5-(4-Chlorbenzyl)-2-(chlormethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol, (2R)-2-(1-Chlorcyclopropyl)-4-[(1R)-2,2-dichlorcyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (2R)- 2-(1-Chlorcyclopropyl)-4-[(1S)-2,2-dichlorcyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (2R)-2-[4- (4-Chlorphenoxy)-2-(trifluormethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (2S)-2-(1-Chlorcyclo- propyl)-4-[(1R)-2,2-dichlorcyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (2S)-2-(1-Chlorcyclo- propyl)-4-[(1S)-2,2-dichlorcyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (2S)-2-[4-(4-Chlorphen- oxy)-2-(trifluormethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (R)-[3-(4-Chlor-2-fluorphenyl)-5- (2,4-difluorphenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (S)-[3-(4-Chlor-2-fluorphenyl)-5-(2,4- difluorphenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, [3-(4-Chlor-2-fluorphenyl)-5-(2,4-difluor- phenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, 1-({(2R,4S)-2-[2-Chlor-4-(4-chlorphenoxy)phenyl]-4- methyl-1,3-dioxolan-2-yl}methyl)-1H-1,2,4-triazol, 1-({(2S,4S)-2-[2-Chlor-4-(4-chlorphenoxy)phenyl]- 4-methyl-1,3-dioxolan-2-yl}methyl)-1H-1,2,4-triazol, 1-{[3-(2-Chlorphenyl)-2-(2,4-difluor- phenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl-thiocyanat, 1-{[rel(2R,3R)-3-(2-Chlorphenyl)-2-(2,4- difluorphenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl-thiocyanat, 1-{[rel(2R,3S)-3-(2-Chlorphenyl)- 2-(2,4-difluorphenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl-thiocyanat, 2-[(2R,4R,5R)-1-(2,4- Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazol-3-thion, 2- [(2R,4R,5S)-1-(2,4-Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazol- 3-thion, 2-[(2R,4S,5R)-1-(2,4-Dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H- 1,2,4-triazol-3-thion, 2-[(2R,4S,5S)-1-(2,4-Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4- dihydro-3H-1,2,4-triazol-3-thion, 2-[(2S,4R,5R)-1-(2,4-Dichlorphenyl)-5-hydroxy-2,6,6- trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazol-3-thion, 2-[(2S,4R,5S)-1-(2,4-Dichlorphenyl)-5- hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazol-3-thion, 2-[(2S,4S,5R)-1-(2,4- Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazol-3-thion, 2- [(2S,4S,5S)-1-(2,4-Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazol- 3-thion, 2-[1-(2,4-Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazol- 3-thion, 2-[2-Chlor-4-(2,4-dichlorophenoxy)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, 2-[2-Chlor-4- (4-chlorphenoxy)phenyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, 2-[4-(4-Chlorphenoxy)-2-(trifluormethyl)- phenyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, 2-[4-(4-Chlorphenoxy)-2-(trifluormethyl)phenyl]-1-(1H- 1,2,4-triazol-1-yl)pentan-2-ol, 2-[4-(4-Chlorphenoxy)-2-(trifluormethyl)phenyl]-1-(1H-1,2,4-triazol-1- yl)propan-2-ol, 2-{[3-(2-Chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4- triazol-3-thion, 2-{[rel(2R,3R)-3-(2-Chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl]methyl}-2,4- dihydro-3H-1,2,4-triazol-3-thion, 2-{[rel(2R,3S)-3-(2-Chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2- yl]methyl}-2,4-dihydro-3H-1,2,4-triazol-3-thion, 5-(4-Chlorbenzyl)-2-(chlormethyl)-2-methyl-1-(1H- 1,2,4-triazol-1-ylmethyl)cyclopentanol, 5-(Allylsulfanyl)-1-{[3-(2-chlorphenyl)-2-(2,4- difluorphenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol, 5-(Allylsulfanyl)-1-{[rel(2R,3R)-3-(2-chlorphenyl)- 2-(2,4-difluorphenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol, 5-(Allylsulfanyl)-1-{[rel(2R,3S)-3-(2- chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol, N'-(2,5-Dimethyl-4-{[3- (1,1,2,2-tetrafluorethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamid, N'-(2,5-Dimethyl- 4-{[3-(2,2,2-trifluorethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamid, N'-(2,5- Dimethyl-4-{[3-(2,2,3,3-tetrafluorpropoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamid, N'-(2,5-Dimethyl-4-{[3-(pentafluorethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamid, N'-(2,5-Dimethyl-4-{3-[(1,1,2,2-tetrafluorethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N- methylimidoformamid, N'-(2,5-Dimethyl-4-{3-[(2,2,2-trifluorethyl)sulfanyl]phenoxy}phenyl)-N-ethyl- N-methylimidoformamid, N'-(2,5-Dimethyl-4-{3-[(2,2,3,3-tetrafluorpropyl)sulfanyl]phenoxy}phenyl)- N-ethyl-N-methylimidoformamid, N'-(2,5-Dimethyl-4-{3-[(pentafluorethyl)sulfanyl]phenoxy}phenyl)- N-ethyl-N-methylimidoformamid, N'-(2,5-Dimethyl-4-phenoxyphenyl)-N-ethyl-N- methylimidoformamid, N'-(4-{[3-(Difluormethoxy)phenyl]sulfanyl}-2,5-dimethylphenyl)-N-ethyl-N- methylimidoformamid, N'-(4-{3-[(Difluormethyl)sulfanyl]phenoxy}-2,5-dimethylphenyl)-N-ethyl-N- methylimidoformamid, N'-[5-Brom-6-(2,3-dihydro-1H-inden-2-yloxy)-2-methylpyridin-3-yl]-N-ethyl- N-methylimidoformamid, N'-{4-[(4,5-Dichlor-1,3-thiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N- methylimidoformamid, N'-{5-Brom-6-[(1R)-1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N- ethyl-N-methylimidoformamid, N'-{5-Brom-6-[(1S)-1-(3,5-difluorphenyl)ethoxy]-2-methylpyridin-3- yl}-N-ethyl-N-methylimidoformamid, N'-{5-Brom-6-[(cis-4-isopropylcyclohexyl)oxy]-2- methylpyridin-3-yl}-N-ethyl-N-methylimidoformamid, N'-{5-Brom-6-[(trans-4- isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamid, N'-{5-Bromo-6-[1- (3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamide, Mefentrifluconazole, Ipfentrifluconazole. 2) Inhibitors of the respiratory chain at complex I or II, for example benzovindiflupyr, bixafen, boscalid, carboxin, fluopyram, flutolanil, fluxapyroxad, furametpyr, isofetamid, isopyrazam (anti-epimeric enantiomer 1R,4S,9S), isopyrazam (anti-epimeric enantiomer 1S,4R,9R), isopyrazam (anti-epimeric racemate 1RS,4SR,9SR), isopyrazam (mixture of syn-epimeric racemate 1RS,4SR,9RS and anti-epimeric racemate 1RS,4SR,9SR), isopyrazam (syn-epimeric enantiomer 1R,4S,9R), (2.015) isopyrazam (syn-epimeric enantiomer 1S,4R,9S), isopyrazam (syn-epimeric racemate 1RS,4SR,9RS), Penflufen, Penthiopyrad, Pydiflumetofen, Pyraziflumid, Sedaxane, 1,3-Dimethyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1H-pyrazol-4-carboxamid, 1,3-Dimethyl-N-[(3R)-1,1,3- trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazol-4-carboxamide, 1,3-Dimethyl-N-[(3S)-1,1,3-trimethyl- 2,3-dihydro-1H-inden-4-yl]-1H-pyrazol-4-carboxamid, 1-Methyl-3-(trifluormethyl)-N-[2'- (trifluormethyl)biphenyl-2-yl]-1H-pyrazol-4-carboxamid, 2-Fluor-6-(trifluoromethyl)-N-(1,1,3- trimethyl-2,3-dihydro-1H-inden-4-yl)benzamid, 3-(Difluormethyl)-1-methyl-N-(1,1,3-trimethyl-2,3- dihydro-1H-inden-4-yl)-1H-pyrazol-4-carboxamid, 3-(Difluormethyl)-1-methyl-N-[(3R)-1,1,3- trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazol-4-carboxamid, 3-(Difluormethyl)-1-methyl-N-[(3S)- 1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazol-4-carboxamid, (2.030) 3-(Difluormethyl)-N-(7- fluor-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1-methyl-1H-pyrazol-4-carboxamid, 3-(Difluor- methyl)-N-[(3R)-7-fluor-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazol-4- carboxamid, 3-(Difluoromethyl)-N-[(3S)-7-fluor-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl- 1H-pyrazol-4-carboxamid, 5,8-Difluor-N-[2-(2-fluor-4-{[4-(trifluormethyl)pyridin-2- yl]oxy}phenyl)ethyl]quinazolin-4-amin,N-(2-Cyclopentyl-5-fluorbenzyl)-N-cyclopropyl-3- (difluormethyl)-5-fluor-1-methyl-1H-pyrazol-4-carboxamid, N-(2-tert-Butyl-5-methylbenzyl)-N- cyclopropyl-3-(difluormethyl)-5-fluor-1-methyl-1H-pyrazol-4-carboxamid, N-(2-tert-Butylbenzyl)-N- cyclopropyl-3-(difluormethyl)-5-fluor-1-methyl-1H-pyrazol-4-carboxamid, N-(5-Chlor-2-ethylbenzyl)- N-cyclopropyl-3-(difluormethyl)-5-fluor-1-methyl-1H-pyrazol-4-carboxamid, N-(5-Chlor-2- isopropylbenzyl)-N-cyclopropyl-3-(difluormethyl)-5-fluor-1-methyl-1H-pyrazol-4-carboxamid, (2.039) N-[(1R,4S)-9-(Dichlormethylen)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-(difluormethyl)-1- methyl-1H-pyrazol-4-carboxamid, N-[(1S,4R)-9-(Dichlormethylen)-1,2,3,4-tetrahydro-1,4- methanonaphthalen-5-yl]-3-(difluormethyl)-1-methyl-1H-pyrazol-4-carboxamid, N-[1-(2,4- Dichlorphenyl)-1-methoxypropan-2-yl]-3-(difluormethyl)-1-methyl-1H-pyrazol-4-carboxamid, N-[2- Chlor-6-(trifluormethyl)benzyl]-N-cyclopropyl-3-(difluormethyl)-5-fluor-1-methyl-1H-pyrazol-4- carboxamid,N-[3-Chlor-2-fluor-6-(trifluormethyl)benzyl]-N-cyclopropyl-3-(difluormethyl)-5-fluor-1- methyl-1H-pyrazol-4-carboxamid, N-[5-Chlor-2-(trifluormethyl)benzyl]-N-cyclopropyl-3- (difluormethyl)-5-fluor-1-methyl-1H-pyrazol-4-carboxamid, N-Cyclopropyl-3-(difluormethyl)-5-fluor- 1-methyl-N-[5-methyl-2-(trifluormethyl)benzyl]-1H-pyrazol-4-carboxamid, N-Cyclopropyl-3- (difluormethyl)-5-fluor-N-(2-fluor-6-isopropylbenzyl)-1-methyl-1H-pyrazol-4-carboxamid, N- Cyclopropyl-3-(difluormethyl)-5-fluor-N-(2-isopropyl-5-methylbenzyl)-1-methyl-1H-pyrazol-4- carboxamid, N-Cyclopropyl-3-(difluormethyl)-5-fluor-N-(2-isopropylbenzyl)-1-methyl-1H-pyrazol-4- carbothioamid, N-Cyclopropyl-3-(difluoromethyl)-5-fluor-N-(2-isopropylbenzyl)-1-methyl-1H-pyrazol- 4-carboxamid, N-Cyclopropyl-3-(difluormethyl)-5-fluor-N-(5-fluor-2-isopropylbenzyl)-1-methyl-1H- pyrazol-4-carboxamid, N-Cyclopropyl-3-(difluormethyl)-N-(2-ethyl-4,5-dimethylbenzyl)-5-fluor-1- methyl-1H-pyrazol-4-carboxamid,N-Cyclopropyl-3-(difluormethyl)-N-(2-ethyl-5-fluorbenzyl)-5-fluor- 1-methyl-1H-pyrazol-4-carboxamid, N-Cyclopropyl-3-(difluormethyl)-N-(2-ethyl-5-methylbenzyl)-5- fluor-1-methyl-1H-pyrazole-4-carboxamid, N-Cyclopropyl-N-(2-cyclopropyl-5-fluorbenzyl)-3- (difluormethyl)-5-fluor-1-methyl-1H-pyrazole-4-carboxamid, N-Cyclopropyl-N-(2-cyclopropyl-5- methylbenzyl)-3-(difluormethyl)-5-fluor-1-methyl-1H-pyrazole-4-carboxamid, N-Cyclopropyl-N-(2- cyclopropylbenzyl)-3-(difluormethyl)-5-fluor-1-methyl-1H-pyrazole-4-carboxamid. 3) Inhibitoren der Atmungskette am Komplex III, beispielsweise Ametoctradin, Amisulbrom, Azoxystrobin, Coumethoxystrobin, Coumoxystrobin, Cyazofamid, Dimoxystrobin, Enoxastrobin, Famoxadon, Fenamidon, Flufenoxystrobin, Fluoxastrobin, Kresoxim-Methyl, Metominostrobin, Orysastrobin, Picoxystrobin, Pyraclostrobin, Pyrametostrobin, Pyraoxystrobin,Trifloxystrobin (3.021) (2E)-2-{2-[({[(1E)-1-(3-{[(E)-1-Fluor-2-phenylvinyl]oxy}phenyl)ethyliden]amino}oxy)methyl]- phenyl}-2-(methoxyimino)-N-methylacetamid, (2E,3Z)-5-{[1-(4-Chlorphenyl)-1H-pyrazol-3-yl]oxy}-2- (methoxyimino)-N,3-dimethylpent-3-enamid, (2R)-2-{2-[(2,5-Dimethylphenoxy)methyl]phenyl}-2- methoxy-N-methylacetamid, (2S)-2-{2-[(2,5-Dimethylphenoxy)methyl]phenyl}-2-methoxy-N- methylacetamid, (3S,6S,7R,8R)-8-Benzyl-3-[({3-[(isobutyryloxy)methoxy]-4-methoxypyridin-2- yl}carbonyl)amino]-6-methyl-4,9-dioxo-1,5-dioxonan-7-yl-2-methylpropanoat, 2-{2-[(2,5- Dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamid, N-(3-Ethyl-3,5,5- trimethylcyclohexyl)-3-formamido-2-hydroxybenzamid, (2E,3Z)-5-{[1-(4-Chlor-2-fluorphenyl)-1H- pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamid, Methyl {5-[3-(2,4-dimethylphenyl)- 1H-pyrazol-1-yl]-2-methylbenzyl}carbamate. 4) Inhibitoren der Mitose und Zellteilung, beispielsweise Carbendazim, Diethofencarb, Ethaboxam, Fluopicolid,Pencycuron, Thiabendazol, Thiophanat-Methyl, Zoxamid, 3-Chlor-4-(2,6-difluorphenyl)-6- methyl-5-phenylpyridazin, 3-Chlor-5-(4-chlorphenyl)-4-(2,6-difluorphenyl)-6-methylpyridazin, 3- Chlor-5-(6-chlorpyridin-3-yl)-6-methyl-4-(2,4,6-trifluorphenyl)pyridazin, 4-(2-Brom-4-fluorphenyl)-N- (2,6-difluorphenyl)-1,3-dimethyl-1H-pyrazol-5-amin, 4-(2-Brom-4-fluorphenyl)-N-(2-brom-6- fluorphenyl)-1,3-dimethyl-1H-pyrazol-5-amin, 4-(2-Brom-4-fluorphenyl)-N-(2-bromphenyl)-1,3- dimethyl-1H-pyrazol-5-amin, 4-(2-Brom-4-fluorphenyl)-N-(2-chlor-6-fluorphenyl)-1,3-dimethyl-1H- pyrazol-5-amin, (4.016) 4-(2-Brom-4-fluorphenyl)-N-(2-chlorphenyl)-1,3-dimethyl-1H-pyrazol-5-amin, 4-(2-Brom-4-fluorphenyl)-N-(2-fluorphenyl)-1,3-dimethyl-1H-pyrazol-5-amin, 4-(2-Chlor-4- fluorphenyl)-N-(2,6-difluorphenyl)-1,3-dimethyl-1H-pyrazol-5-amin, 4-(2-Chlor-4-fluorphenyl)-N-(2- chlor-6-fluorphenyl)-1,3-dimethyl-1H-pyrazol-5-amin, 4-(2-Chlor-4-fluorphenyl)-N-(2-chlorphenyl)- 1,3-dimethyl-1H-pyrazol-5-amin,4-(2-Chloro-4-fluorophenyl)-N-(2-fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine, 4-(4-Chlorophenyl)-5-(2,6-difluorophenyl)-3,6-dimethylpyridazine, N-(2-Bromo-6- fluorophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine, N-(2-bromophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine, N-(4-chloro-2,6-difluorophenyl)-4-(2-chloro-4-fluoro- phenyl)-1,3-dimethyl-1H-pyrazole-5-amine. 5) Compounds capable of multi-site activity, for example Bordeaux mixture, captafol, captan, chlorothalonil, copper hydroxide, copper naphthenate, copper oxide, copper oxychloride, copper(2+) sulfate, dithianon, dodine, folpet, mancozeb, maneb, metiram, zinc metiram, copper oxine, propineb, sulfur and sulfur preparations including calcium polysulfide, thiram, zineb, ziram, 6-ethyl-5,7-dioxo-6,7-dihydro-5H-pyrrolo[3',4':5,6][1,4]dithiino[2,3-c][1,2]thiazole-3-carbonitrile. 6) Compounds capable of eliciting host defenses, for example acibenzolar-S-methyl, isotianil,Probenazole, tiadinil. 7) Inhibitors of amino acid and / or protein biosynthesis, for example, cyprodinil, kasugamycin, kasugamycin hydrochloride hydrate, oxytetracycline, pyrimethanil, 3-(5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl)quinoline. (8) Inhibitors of ATP production, for example, silthiofam. 9) Inhibitors of cell wall synthesis, for example, benthiavalicarb, dimethomorph, flumorph, iprovalicarb, mandipropamid, pyrimorph, valifenalate, (2E)-3-(4-tert-butylphenyl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)prop-2-en-1-one, (2Z)-3-(4-tert-butylphenyl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)prop-2-en-1-one. 10) Inhibitors of lipid and membrane synthesis, for example, propamocarb, propamocarb hydrochloride, tolclofos-methyl. 11) Inhibitors of melanin biosynthesis, for example, tricyclazole, 2,2,2-trifluoroethyl-{3-methyl-1-[(4-methylbenzoyl)amino]butan-2-yl}carbamate. 12) Inhibitors of nucleic acid synthesis, for example, benalaxyl, benalaxyl-M (kiralaxyl),Metalaxyl, Metalaxyl-M (Mefenoxam). 13) Signal transduction inhibitors, for example, fludioxonil, iprodione, procymidone, proquinazid, quinoxyfen, vinclozolin. 14) Compounds that can act as uncouplers, for example, fluazinam, meptyldinocap. 15) Other compounds, for example abscisic acid, benthiazole, bethoxazine, capsimycin, carvone, quinomethionate, cufraneb, cyflufenamid, cymoxanil, cyprosulfamide, flutianil, fosetyl aluminum, fosetyl calcium, fosetyl sodium, methyl isothiocyanate, metrafenone, mildiomycin, natamycin, nickel dimethyldithiocarbamate, nitrothal isopropyl, oxamocarb, oxathiapiprolin, oxyfenthiin, pentachlorophenol and salts, phosphonic acid and its salts, propamocarb fosetylate, pyriofenone (chlazafenone), tebufloquin, tecloftalam, tolnifanide, 1-(4-{4-[(5R)-5-(2,6-difluorophenyl)-4,5- dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone, 1-(4-{4-[(5S)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2- yl}piperidin-1-yl)-2-[5-methyl-3-(trifluormethyl)-1H-pyrazol-1-yl]ethanon, 2-(6-Benzylpyridin-2- yl)quinazolin, 2,6-Dimethyl-1H,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetron, 2-[3,5- Bis(difluormethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-(prop-2-in-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol- 3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanon, 2-[3,5-Bis(difluormethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2- chlor-6-(prop-2-in-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1- yl]ethanon, 2-[3,5-Bis(difluormethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-fluor-6-(prop-2-in-1- yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanon, 2-[6-(3-Fluor-4- methoxyphenyl)-5-methylpyridin-2-yl]quinazolin, 2-{(5R)-3-[2-(1-{[3,5-Bis(difluormethyl)-1H- pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorphenyl methanesulfonat, 2-{(5S)-3-[2-(1-{[3,5-Bis(difluormethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3- thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorphenyl methanesulfonat, 2-{2-[(7,8-Difluor-2- methylquinolin-3-yl)oxy]-6-fluorphenyl}propan-2-ol, 2-{2-Fluor-6-[(8-fluor-2-methylquinolin-3- yl)oxy]phenyl}propan-2-ol, 2-{3-[2-(1-{[3,5-Bis(difluormethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)- 1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorphenyl-methansulfonat, 2-{3-[2-(1-{[3,5- Bis(difluormethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5- yl}phenyl methanesulfonat, 2-Phenylphenol und deren Salze, 3-(4,4,5-Trifluor-3,3-dimethyl-3,4- dihydroisoquinolin-1-yl)quinolin, 3-(4,4-Difluor-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)quinolin, 4- Amino-5-fluorpyrimidin-2-ol (Tautomere Form: 4-Amino-5-fluorpyrimidin-2(1H)-on), 4-Oxo-4-[(2- phenylethyl)amino]buttersäure, 5-Amino-1,3,4-thiadiazol-2-thiol, 5-Chlor-N'-phenyl-N'-(prop-2-yn-1- yl)thiophen-2-sulfonohydrazid,5-Fluor-2-[(4-fluorbenzyl)oxy]pyrimidin-4-amin, 5-Fluor-2-[(4- methylbenzyl)oxy]pyrimidin-4-amin, 9-Fluor-2,2-dimethyl-5-(quinolin-3-yl)-2,3-dihydro-1,4- benzoxazepin, But-3-yn-1-yl-{6-[({[(Z)-(1-methyl-1H-tetrazol-5-yl)(phenyl)methylen]amino}oxy)- methyl]pyridin-2-yl}carbamat, Ethyl-(2Z)-3-amino-2-cyano-3-phenylacrylat, Phenazin-1-carbonsäure, Propyl 3,4,5-trihydroxybenzoat, Quinolin-8-ol, Quinolin-8-ol sulfat (2:1), tert-Butyl {6-[({[(1-methyl- 1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamat, 5-Fluor-4-imino-3- methyl-1)sulfonyl]-3,4-dihydropyrimidin-2(1H)-one. Bevorzugte Fungizide sind ausgewählt aus der Gruppe bestehend aus Benalaxyl, Bitertanol, Bromuconazol, Captafol, Carbendazim, Carpropamid, Cyazofamid, Cyproconazol, Diethofencarb, Edifenphos, Fenpropimorph, Fentine, Fluquinconazol, Fosetyl, Fluoroimide, Folpet, Iminoctadine, Iprodionem, Iprovalicarb, Kasugamycin, Maneb, Nabam, Pencycuron, Prochloraz, Propamocarb, Propineb, Pyrimethanil, Sprioxamine,Quintozene, Tebuconazole, Tolylfluanid, Triadimefon, Triadimenol, Trifloxystrobin, Zineb. Insecticidal, acaricidal, nematicidal, miticidal and related active ingredients are, for example (analogous to herbicides and fungicides, the compounds are referred to by their common names where possible, here in the usual English notation): (1) Acetylcholinesterase (AChE) inhibitors, preferably carbamates selected from alanycarb, aldicarb, bendiocarb, benfuracarb, butocarboxim, butoxycarboxim, carbaryl, carbofuran, carbosulfan, ethiofencarb, fenobucarb, formetanate, furathiocarb, isoprocarb, methiocarb, methomyl, metolcarb, oxamyl, pirimicarb, propoxur, thiodicarb, thiofanox, triazamate, trimethacarb, XMC and xylylcarb, or organophosphates selected from acephate, azamethiphos, azinphos-ethyl, azinphos-methyl, cadusafos, chlorethoxyfos, Chlorfenvinphos, Chlormephos, Chlorpyrifos-methyl, Coumaphos, Cyanophos, Demeton-S-methyl, Diazinon, Dichlorvos / DDVP, Dicrotophos, Dimethoate,Dimethylvinphos, Disulfoton, EPN, Ethion, Ethoprophos, Famphur, Fenamiphos, Fenitrothion, Fenthion, Fosthiazate, Heptenophos, Imicyafos, Isofenphos, Isopropyl-O-(methoxyaminothio-phosphoryl) salicylate, Isoxathion, Malathion, Mecarbam, Methamidophos, Methidathion, Mevinphos, Monocrotophos, Naled, Omethoate, Oxydemeton-methyl, Parathion-methyl, Phenthoate, Phorate, Phosalon, Phosmet, Phosphamidone, Phoxim, Pirimiphos-methyl, Profenofos, Propetamphos, Prothiofos, Pyraclofos, Pyridaphenthion, Quinalphos, Sulfotep, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphos, Thiometon, Triazophos, Triclorfon, and Vamidothion. (2) GABA-gated chloride channel blockers, preferably cyclodiene organochlorines selected from chlordane and endosulfan, or phenylpyrazoles (fiproles) selected from ethiprole and fipronil. (3) Sodium channel modulators, preferably pyrethroids selected from acrinathrin, allethrin, d-cis-trans-allethrin, d-trans-allethrin, bifenthrin, bioallethrin,Bioallethrin-S-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(1R)-trans isomer], deltamethrin, empenthrin [(EZ)-(1R) isomer], esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, tau-fluvalinate, halfenprox, imiprothrin, kadethrin, momfluorothrin, permethrin, phenothrin [(1R)-trans isomer], prallethrin, pyrethrins (pyrethrum), Resmethrin, silafluofen, tefluthrin, tetramethrin, tetramethrin [(1R)-isomer], tralomethrin and transfluthrin, or DDT or methoxychlor. (4) Competitive modulators of the nicotinic acetylcholine receptor (nAChR), preferably neonicotinoids selected from acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam, or nicotine, or sufoximines selected from sulfoxaflor,or butenolides selected from flupyradifurone. (5) Allosteric modulators of the nicotinic acetylcholine receptor (nAChR), preferably spinosyns selected from spinetoram and spinosad. (6) Allosteric modulators of the glutamate-dependent chloride channel (GluCl), preferably avermectins / milbemycins selected from abamectin, emamectin benzoate, lepimectin and milbemectin. (7) Juvenile hormone mimetics, preferably juvenile hormone analogues selected from hydroprene, kinoprene and methoprene, or fenoxycarb or pyriproxyfen. (8) Various non-specific (multi-site) inhibitors, preferably alkyl halides selected from methyl bromide and other alkyl halides, or chloropicrin or sulfuryl fluoride or borax or tartar emetic or methyl isocyanate generators selected from diazomet and metam. (9) TRPV channel modulators of chordotonal organs selected from pymetrozine and pyrifluquinazone. (10) Mite growth inhibitors selected from clofentezine, hexythiazox,Diflovidazine and etoxazole. (11) Microbial disruptors of the insect intestinal membrane selected from Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis and Bt plant proteins selected from Cry1Ab, Cry1Ac, Cry1Fa, Cry1A.105, Cry2Ab, VIP3A, mCry3A, Cry3Ab, Cry3Bb and Cry34Ab1 / 35Ab1. (12) Inhibitors of mitochondrial ATP synthase, preferably ATP disruptors selected from diafenthiuron, or organotin compounds selected from azocyclotin, cyhexatin and fenbutatin oxide, or propargite or tetradifon. (13) Uncouplers of oxidative phosphorylation by disrupting the proton gradient selected from chlorfenapyr, DNOC, and sulfluramide. (14) Blockers of the nicotinic acetylcholine receptor channel selected from bensultap, cartap hydrochloride, thiocyclam, and thiosultap sodium. (15) Inhibitors of chitin biosynthesis, type 0.selected from bistriflurone, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron, and triflumuron. (16) Chitin biosynthesis type 1 inhibitors selected from buprofezin. (17) Moulting disruptor (particularly in dipterans) selected from cyromazine. (18) Ecdysone receptor agonists selected from chromafenozide, halofenozide, methoxyfenozide, and tebufenozide. (19) Octopamine receptor agonists selected from amitraz. (20) Mitochondrial complex III electron transport inhibitors selected from hydramethylnon, acequinocyl, and fluacrypyrim. (21) Mitochondrial complex I electron transport inhibitors, preferably METI acaricides selected from fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad, and tolfenpyrad, or rotenone (Derris). (22) Voltage-dependent sodium channel blockers selected from indoxacarb and metaflumizone. (23) Acetyl-CoA carboxylase inhibitors.preferably tetronic and tetramic acid derivatives selected from spirodiclofen, spiromesifen, and spirotetramat. (24) Inhibitors of mitochondrial complex IV electron transport, preferably phosphines selected from aluminum phosphide, calcium phosphide, phosphine, and zinc phosphide, or cyanides selected from calcium cyanide, potassium cyanide, and sodium cyanide. (25) Inhibitors of mitochondrial complex II electron transport, preferably beta-ketonitrile derivatives selected from cyenopyrafen and cyflumetofen, or carboxanilides selected from pyflubumide. (28) Ryanodine receptor modulators, preferably diamides selected from chlorantraniliprole, cyantraniliprole, and flubendiamide. (29) Modulators of chordotonal organs (with undefined target structure) selected from flonicamid. (30) further active ingredients selected from Acynonapyr, Afidopyropen, Afoxolaner, Azadirachtin, Benclothiaz, Benzoximate, Benzpyrimoxane, Bifenazate, Broflanilide, Bromopropylate, Quinomethionate, Chloroprallethrin, Cryolite,Cyclaniliprol, cycloxaprid, cyhalodiamide, dicloromezotiaz, dicofol, epsilon-metofluthrin, epsilon-momfluthrin, flometoquin, fluazaindolizin, fluensulfone, flufenerim, flufenoxystrobin, flufiprole, fluhexafone, fluopyram, flupyrimin, fluralaner, fluxametamide, Fufenozide, Guadipyr, Heptafluthrin, Imidaclothiz, Iprodione, kappa-Bifenthrin, kappa-Tefluthrin, Lotilaner, Meperfluthrin, Oxazosulfyl, Paichongding, Pyridalyl, Pyrifluquinazone, Pyriminostrobin, Spirobudiclofen, Spiropidion, Tetramethylfluthrin, Tetraniliprole, Tetrachlorantraniliprole, Tigolaner, tioxazafen, thiofluoximate, Triflumezopyrim and iodomethane; furthermore, preparations based on Bacillus firmus (I-1582, BioNeem, Votivo), as well as the following compounds: 1-{2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}-3-(trifluoromethyl)-1H-1,2,4-triazol-5-amine (known from WO2006 / 043635) (CAS 885026-50-6), {1'-[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]-5-fluorospiro[indole- 3,4'-piperidin]-1(2H)-yl}(2-chloropyridin-4-yl)methanone (known from WO2003 / 106457) (CAS 637360-23-7), 2-chloro-N-[2-{1-[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]piperidin-4-yl}-4-(trifluoromethyl)phenyl]isonicotinamide (known from WO2006 / 003494) (CAS 872999-66-1), 3-(4-chloro-2,6-dimethylphenyl)-4-hydroxy-8-methoxy-1,8-diazaspiro[4.5]dec-3-en-2-one (known from WO 2010052161) (CAS 1225292-17-0), 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-2-oxo-1,8-diazaspiro[4.5]dec-3-en-4-yl ethyl carbonate (known from EP 2647626) (CAS-1440516-42-6), 4-(but-2-yn-1-yloxy)-6-(3,5-dimethylpiperidin-1-yl)-5-fluoropyrimidine (known from WO2004 / 099160) (CAS 792914-58-0), PF1364 (known from JP2010 / 018586) (CAS Reg. No. 1204776-60-2), (3E)-3-[1-[(6- Chloro-3-pyridyl)methyl]-2-pyridylidene]-1,1,1-trifluoropropan-2-one (known from WO2013 / 144213) (CAS 1461743-15-6), N-[3-(Benzylcarbamoyl)-4-chlorophenyl]-1-methyl-3-(pentafluoroethyl)-4- (trifluoromethyl)-1H-pyrazole-5-carboxamide (known from WO2010 / 051926) (CAS 1226889-14-0),5- Brom-4-chlor-N-[4-chlor-2-methyl-6-(methylcarbamoyl)phenyl]-2-(3-chlor-2-pyridyl)pyrazol-3- carboxamid (bekannt aus CN103232431) (CAS 1449220-44-3), 4-[5-(3,5-Dichlorphenyl)-4,5-dihydro- 5-(trifluormethyl)-3-isoxazolyl]-2-methyl-N-(cis-1-oxido-3-thietanyl)benzamid, 4-[5-(3,5- Dichlorphenyl)-4,5-dihydro-5-(trifluormethyl)-3-isoxazolyl]-2-methyl-N-(trans-1-oxido-3- thietanyl)benzamid und 4-[(5S)-5-(3,5-Dichlorphenyl)-4,5-dihydro-5-(trifluormethyl)-3-isoxazolyl]-2- methyl-N-(cis-1-oxido-3-thietanyl)benzamid (bekannt aus WO 2013 / 050317 A1) (CAS 1332628-83-7), N-[3-Chlor-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluorpropyl)sulfinyl]propanamid, (+)- N-[3-Chlor-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluorpropyl)sulfinyl]propanamid und (-)-N-[3-Chlor-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluorpropyl)sulfinyl]propanamid (bekannt aus WO 2013 / 162715 A2, WO 2013 / 162716 A2, US 2014 / 0213448 A1) (CAS 1477923-37-7),5-[[(2E)-3-Chlor-2-propen-1-yl]amino]-1-[2,6-dichlor-4-(trifluormethyl)phenyl]-4- [(trifluormethyl)sulfinyl]-1H-pyrazol-3-carbonitrile (bekannt aus CN 101337937 A) (CAS 1105672-77- 2), 3-Brom-N-[4-chlor-2-methyl-6-[(methylamino)thioxomethyl]phenyl]-1-(3-chlor-2-pyridinyl)-1H- pyrazol-5-carboxamid, (Liudaibenjiaxuanan, bekannt aus CN 103109816 A) (CAS 1232543-85-9); N- [4-Chlor-2-[[(1,1-dimethylethyl)amino]carbonyl]-6-methylphenyl]-1-(3-chlor-2-pyridinyl)-3- (fluormethoxy)-1H-pyrazol-5-carboxamid (bekannt aus WO 2012 / 034403 A1) (CAS 1268277-22-0), N- [2-(5-Amino-1,3,4-thiadiazol-2-yl)-4-chlor-6-methylphenyl]-3-brom-1-(3-chlor-2-pyridinyl)-1H- pyrazol-5-carboxamid (bekannt aus WO 2011 / 085575 A1) (CAS 1233882-22-8), 4-[3-[2,6-Dichlor-4- [(3,3-dichlor-2-propen-1-yl)oxy]phenoxy]propoxy]-2-methoxy-6-(trifluormethyl)pyrimidin (bekannt aus CN 101337940 A) (CAS 1108184-52-6); (2E)- und 2(Z)-2-[2-(4-Cyanophenyl)-1-[3- (trifluormethyl)phenyl]ethyliden]-N-[4-(difluormethoxy)phenyl]hydrazincarboxamid (bekannt aus CN 101715774 A) (CAS 1232543-85-9); Cyclopropancarbonsäure-3-(2,2-dichlorethenyl)-2,2-dimethyl-4- (1H-benzimidazol-2-yl)phenylester (bekannt aus CN 103524422 A) (CAS 1542271-46-4); (4aS)-7- Chlor-2,5-dihydro-2-[[(methoxycarbonyl)[4-[(trifluormethyl)thio]phenyl]amino]carbonyl]indeno[1,2- e][1,3,4]oxadiazin-4a(3H)-carbonsäuremethylester (bekannt aus CN 102391261 A) (CAS 1370358-69- 2); 6-Desoxy-3-O-ethyl-2,4-di-O-methyl-1-[N-[4-[1-[4-(1,1,2,2,2-pentafluorethoxy)phenyl]-1H-1,2,4- triazol-3-yl]phenyl]carbamat]-α-L-mannopyranose (bekannt aus US 2014 / 0275503 A1) (CAS 1181213- 14-8); 8-(2-Cyclopropylmethoxy-4-trifluormethylphenoxy)-3-(6-trifluormethylpyridazin-3-yl)-3- azabicyclo[3.2.1]octan (CAS 1253850-56-4),(8-anti)-8-(2-Cyclopropylmethoxy-4- trifluormethylphenoxy)-3-(6-trifluormethylpyridazin-3-yl)-3-azabicyclo[3.2.1]octan (CAS 933798-27- 7), (8-syn)-8-(2-Cyclopropylmethoxy-4-trifluormethylphenoxy)-3-(6-trifluormethylpyridazin-3-yl)-3- azabicyclo[3.2.1]octan (bekannt aus WO 2007040280 A1, WO 2007040282 A1) (CAS 934001-66-8), N-[3-Chlor-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluorpropyl)thio]-propanamid (bekannt aus WO 2015 / 058021 A1, WO 2015 / 058028 A1) (CAS 1477919-27-9) und N-[4- (Aminothioxomethyl)-2-methyl-6-[(methylamino)carbonyl]phenyl]-3-bromo-1-(3-chloro-2-pyridinyl)- 1H-pyrazol-5-carboxamid (bekannt aus CN 103265527 A) (CAS 1452877-50-7), 5-(1,3-Dioxan-2-yl)-4- [[4-(trifluormethyl)phenyl]methoxy]-pyrimidin (bekannt aus WO 2013 / 115391 A1) (CAS 1449021-97- 9), 3-(4-Chlor-2,6-dimethylphenyl)-8-methoxy-1-methyl-1,8-diazaspiro[4.5]decane-2,4-dion (bekannt aus WO 2014 / 187846 A1) (CAS 1638765-58-8), 3-(4-Chlor-2,6-dimethylphenyl)-8-methoxy-1-methyl- 2-oxo-1,8-diazaspiro[4.5]dec-3-en-4-yl-carboxylic acid ethyl ester (known from WO 2010 / 066780 A1, WO 2011151146 A1) (CAS 1229023-00-0), 4-[(5S)-5-(3,5-Dichloro-4-fluorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-N-[(4R)-2-ethyl-3-oxo-4-isoxazolidinyl]-2-methyl-benzamide (known from WO 2011 / 067272, WO2013 / 050302) (CAS 1309959-62-3). Insecticides which can preferably be used together with the herbicide / safener combinations according to the invention are, for example, the following: Acetamiprid, Acrinathrin, Aldicarb, Amitraz, Acinphos-methyl, Cyfluthrin, Carbaryl, Cypermethrin, Deltamethrin, Endosulfan, Ethoprophos, Fenamiphos, Fenthion, Fipronil, Imidacloprid, Methamidophos, Methiocarb, Niclosamide, Oxydemeton-methyl, Prothiophos, Silafluofen, Thiacloprid, Thiodicarb, Tralomethrin, Triazophos, Trichlorfon, Triflumuron, Terbufos, Fonofos, Phorate, Chlorpyriphos, Carbofuran,Tefluthrin. The herbicide / safener combinations according to the invention are particularly suitable for controlling undesirable plant growth in economically important crops such as wheat (durum and soft wheat), maize, soybeans, sugar beet, sugar cane, cotton, rice, beans (such as, for example, bush beans and horse beans), flax, barley, oats, rye, triticale, potatoes, and sorghum. The herbicide / safener combinations according to the invention can be applied jointly or separately to the plants (e.g., harmful plants such as monocotyledonous or dicotyledonous weeds or undesirable crops), the seed (e.g., grains, seeds, or vegetative propagation organs such as tubers or shoot parts with buds), or the area on which the plants grow (e.g., the cultivated area). The herbicide / safener combinations can be applied pre-sowing (if appropriate also by incorporation into the soil),Pre-emergence or post-emergence applications are preferred. Application is preferably carried out using the early post-sowing pre-emergence method or the post-emergence method against weeds that have not yet emerged or have already emerged. Application can also be integrated into weed management systems with divided, multiple applications (sequential applications). Some examples of monocotyledonous and dicotyledonous weed flora that can be controlled by the herbicide / safener combinations according to the invention are given, without implying a restriction to specific species. On the monocot weed side, for example Aegilops, Agropyron, Agrostis, Alopecurus, Apera, Avena, Brachicaria, Bromus, Cynodon, Dactyloctenium, Digitaria, Echinochloa, Eleocharis, Eleusine, Eragrostis, Eriochloa, Festuca, Fimbristylis, Imperata, Ischaemum, Heteranthera, Imperata, Ischaemum, Leptochloa, Lolium, Monochoria,Panicum, Paspalum, Phalaris, Phleum, Poa, Rottboellia, Sagittaria, Scirpus, Setaria, Sorghum, Sphenoclea and Cyperus species are included in the annual group. In the case of dicotyledonous weed species, the spectrum of activity extends to species such as Abutilon, Amaranthus, Ambrosia, Anoda, Anthemis, Aphanes, Artemisia, Atriplex, Bellis, Bidens, Capsella, Carduus, Cassia, Centaurea, Chenopodium, Cirsium, Convolvulus, Datura, Desmodium, Emex, Erodium, Erysimum, Euphorbia, Galeopsis, Galinsoga, Galium, Geranium, Hibiscus, Ipomoea, Kochia, Lamium, Lepidium, Lindernia, Matricaria, Mentha, Mercurialis, Mullugo, Myosotis, Papaver, Pharbitis, Plantago, Polygonum, Portulaca, Ranunculus, Raphanus, Rorippa, Rotala, Rumex, Salsola, Senecio, Sesbania, Sida, Sinapis, Solanum, Sonchus, Sphenoclea, Stellaria, Taraxacum, Thlaspi, Trifolium, Urtica, Veronica, Viola, Xanthium. If the herbicide / safener combinations according to the invention are applied to the soil surface before germination,This either completely prevents the emergence of weed seedlings, or the weeds grow to the cotyledon stage, but then cease growth and finally die completely after three to four weeks. When the herbicide / safener combinations are applied post-emergence to the green parts of the plant, growth stops after treatment, and the weeds remain at the growth stage present at the time of application or die completely after a certain period.so that weed competition harmful to the crops is eliminated very early and sustainably. The crops, however, are not or only slightly affected in their development by the application of the herbicide / safener combination. The herbicide / safener combinations according to the invention are characterized by a rapid onset and long-lasting herbicidal effect. The rainfastness of the active ingredients in the combinations according to the invention is generally favorable. A particular advantage is that the effective dosages of components (A) and (B) used in the herbicide / safener combinations can be adjusted so low that their soil effect is optimally low. This makes their use possible not only in sensitive crops,but groundwater contamination is practically avoided. Economically important crops for the application of the herbicide / safener combinations according to the invention include, for example, dicotyledonous crops of the genera Arachis, Beta, Brassica, Cucumis, Cucurbita, Helianthus, Daucus, Glycine, Gossypium, Ipomoea, Lactuca, Linum, Lycopersicon, Nicotiana, Phaseolus, Pisum, Solanum, Vicia, or monocotyledonous crops of the genera Allium, Ananas, Asparagus, Avena, Hordeum, Oryza, Panicum, Saccharum, Secale, Sorghum, Triticale, Triticum and Zea. The herbicide / safener combinations according to the invention can preferably also be used in transgenic crops which are effective against growth substances or against herbicides which inhibit essential plant enzymes, e.g. B. Acetolactate synthases (ALS), EPSP synthases, glutamine synthases (GS), protoporphyrinogen IX oxidase (PPO), or hydroxyphenylpyruvate dioxygenases (HPPD), respectively against herbicides from the group of sulfonylureas, glyphosates,Glufosinate or benzoyl isoxazole and analogous active ingredients. The herbicide / safener combinations according to the invention can be prepared either as mixed formulations of components (A) and (B), optionally with further active ingredients, additives and / or customary formulation auxiliaries, which are then applied diluted with water in the usual way, or as so-called tank mixes by jointly diluting the separately formulated or partially separately formulated components with water. The herbicide / safener combinations according to the invention can be formulated in various ways, depending on the biological and / or chemical-physical parameters specified. General formulation options include, for example: wettable powders (WP), water-soluble powders (SP), emulsifiable concentrates (EC), water-soluble concentrates, aqueous solutions (SL),Emulsions (EW) such as oil-in-water and water-in-oil emulsions, sprayable solutions or emulsions, oil- or water-based dispersions, oil dispersions (OD), suspoemulsions, suspension concentrates (SC), oil-miscible solutions, capsule suspensions (CS), dusts (DP), seed dressings, granules for soil or broadcast application, granules (GR) in the form of microgranules, spray granules, coating granules, and adsorption granules, water-dispersible granules (WG), water-soluble granules (SG), ULV formulations, microcapsules, or waxes. The invention therefore also relates to herbicidal and plant growth regulating agents containing the herbicide / safener combinations according to the invention. The individual formulation types are known in principle and are described, for example, in: Winnacker-Küchler, "Chemische Technologie," Volume 7, C. Hanser Verlag, Munich, 4th edition, 1986; van Valkenburg, "Pesticides Formulations", Marcel Dekker NY, 1973; K. Martens, "Spray Drying Handbook", 3rd Ed.1979,G. Goodwin Ltd. London. The necessary formulation aids such as inert materials, surfactants, solvents, and other additives are also known and are described, for example, in: Watkins, "Handbook of Insecticide Dust Diluents and Carriers," 2nd Ed., Darland Books, Caldwell NJ; Hv Olphen, "Introduction to Clay Colloid Chemistry"; 2nd Ed., J. Wiley & Sons, NY; Marsden, "Solvents Guide," 2nd Ed., Interscience, NY 1963; McCutcheon's, "Detergents and Emulsifiers Annual," MC Publ. Corp., Ridegewood NJ; Sisley and Wood, "Encyclopedia of Surface Active Ingredients," Chem. Publ. Co. Inc., NY 1964; Schönfeldt, "Grenzflächenaktive Äthylenoxidaddukte," Wiss. Verlagsgesellschaft, Stuttgart 1976, Winnacker-Küchler, "Chemical Technology", Volume 7, C. Hanser Verlag Munich, 4th edition 1986. On the basis of these formulations, combinations with other pesticidally active substances, such as other herbicides, fungicides,Insecticides or other pesticides (e.g. acaricides, nematicides, molluscicides, rodenticides, aphicides, avicides, larvicides, ovicides, bactericides, virucides, etc.), as well as other safeners, fertilizers and / or growth regulators, e.g. in the form of a ready-to-use formulation or as a tank mix. Wettable powders are preparations that are evenly dispersible in water and contain, in addition to the active ingredient and a diluent or inert substance, ionic and / or non-ionic surfactants (wetting agents, dispersants), e.g., polyethoxylated alkylphenols, polyethoxylated fatty alcohols, polyethoxylated fatty amines, fatty alcohol polyglycol ether sulfates, alkanesulfonates, alkylbenzenesulfonates, sodium ligninsulfonate, sodium 2,2'-dinaphthylmethane-6,6'-disulfonate, sodium dibutylnaphthalenesulfonate, or sodium oleoylmethyltaurine. For the manufacture of the wettable powders, the herbicidal active ingredients are, for example, milled in conventional equipment such as hammer mills,The active ingredient is finely ground in fan mills and air jet mills and mixed simultaneously or subsequently with the formulation auxiliaries. Emulsifiable concentrates are produced by dissolving the active ingredient in an organic solvent, e.g., butanol, cyclohexanone, dimethylformamide, xylene, or higher-boiling aromatics or hydrocarbons, or mixtures of organic solvents, with the addition of one or more ionic and / or non-ionic surfactants (emulsifiers). Examples of emulsifiers that can be used are calcium salts of alkylarylsulfonic acid, such as calcium dodecylbenzenesulfonate, or non-ionic emulsifiers, such as fatty acid polyglycol esters, alkylaryl polyglycol ethers, fatty alcohol polyglycol ethers, propylene oxide-ethylene oxide condensation products, alkyl polyethers, and sorbitan esters, such as sorbitan fatty acid esters or polyoxyethylene sorbitan fatty acid esters. Dusts are obtained by grinding the active ingredient with finely divided solid substances, e.g. talc,natural clays, such as kaolin, bentonite, and pyrophyllite, or diatomaceous earth. Suspension concentrates can be water- or oil-based. They can be produced, for example, by wet grinding using commercially available bead mills and, if necessary, with the addition of surfactants, as already listed above for the other formulation types. Emulsions, e.g., oil-in-water emulsions (EW), can be produced, for example, using stirrers, colloid mills, and / or static mixers using aqueous organic solvents and, if necessary, surfactants, as already listed above for the other formulation types. Granules can be produced either by spraying the active ingredient onto adsorptive, granulated inert material or by applying active ingredient concentrates to the surface of carrier materials such as sand using adhesives, e.g., polyvinyl alcohol, sodium polyacrylate, or mineral oils.Kaolinite or granulated inert material. Suitable active ingredients can also be granulated in the manner customary for the production of fertilizer granules – if desired, in a mixture with fertilizers. Water-dispersible granules are generally produced by processes such as spray drying, fluidized-bed granulation, disc granulation, mixing with high-speed mixers, and extrusion without solid inert material. The agrochemical preparations generally contain 0.1 to 99% by weight, in particular 0.2 to 95% by weight, of active ingredients of components (A) and / or (B). Depending on the type of formulation, the following concentrations are usual: In wettable powders, the active ingredient concentration is, for example, about 10 to 95% by weight, the remainder to 100% by weight consisting of customary formulation components. In emulsifiable concentrates, the active ingredient concentration can be about 1 to 90% by weight.preferably 5 to 80% by weight. Dust-like formulations usually contain 5 to 20% by weight of active ingredient, sprayable solutions contain approximately 0.05 to 80, preferably 2 to 50% by weight (wt. %) of active ingredient. In granules such as dispersible granules, the active ingredient content depends partly on whether the active compound is liquid or solid and which granulation aids and fillers are used. As a rule, the content for water-dispersible granules is between 1 and 95% by weight, preferably between 10 and 80% by weight. In addition, the above-mentioned active ingredient formulations may contain the usual adhesives, wetting agents, dispersants, emulsifiers, penetration agents, preservatives, antifreeze agents, solvents, fillers, dyes, carriers, defoamers, evaporation inhibitors, and agents.which influence the pH or viscosity. For application, the formulations available in commercial form are diluted, if necessary, in the usual way, e.g., with water in the case of wettable powders, emulsifiable concentrates, dispersions, and water-dispersible granules. Dust-like preparations, soil or broadcast granules, and sprayable solutions are not usually diluted with other inert substances before application. The herbicide / safener combinations according to the invention can be applied to the plants, plant parts, plant seeds, or the cultivated area (arable soil), preferably to the green plants and plant parts and, if appropriate, additionally to the arable soil. One possible application is the joint application of the herbicide / safener combinations in the form of tank mixtures.wherein the optimally formulated concentrated formulations of the individual active ingredients are mixed together with water in a tank, and the resulting spray mixture is applied. A joint formulation of the herbicide / safener combinations according to the invention has the advantage of being easier to use, because the amounts of the components are already adjusted in the correct ratio to one another. Furthermore, the auxiliaries in the formulation can be optimally matched to one another, whereas a tank mix of different formulations can result in undesirable combinations of auxiliaries. A. General Formulation Examples a) A dust is obtained by mixing 10 parts by weight (= parts by weight) of a component (A) or (B) or a component mixture (A) + (B) (and optionally further components) and / or their salts and 90 parts by weight of talc as an inert substance, and comminuting the mixture in a hammer mill. b) A readily water-dispersible,A wettable powder is obtained by mixing 25 parts by weight of a component or a component mixture, 64 parts by weight of kaolin-containing quartz as an inert material, 10 parts by weight of potassium ligninsulfonate, and 1 part by weight of sodium oleoylmethyltaurine as a wetting and dispersing agent, and grinding the mixture in a pin-type mill. c) A dispersion concentrate that is easily dispersible in water is obtained by mixing 20 parts by weight of a component or a component mixture with 6 parts by weight of alkylphenol polyglycol ether (®Triton X 207), 3 parts by weight of isotridecanol polyglycol ether (8 EO), and 71 parts by weight of paraffinic mineral oil (boiling range, for example, approx. 255 to 277 °C) and grinding the mixture in a ball mill to a fineness of less than 5 microns. d) An emulsifiable concentrate is obtained from 15 parts by weight of a component or a mixture of components,75 parts by weight of cyclohexanone as solvent and 10 parts by weight of ethoxylated nonylphenol as emulsifier. e) Water-dispersible granules are obtained by mixing 75 parts by weight of one component of a component mixture, 10 parts by weight of calcium ligninsulfonate, 5 parts by weight of sodium lauryl sulfate, 3 parts by weight of polyvinyl alcohol, and 7 parts by weight of kaolin, grinding the mixture in a pin mill, and granulating the powder in a fluidized bed by spraying water as the granulating liquid. f) A water-dispersible granulate is also obtained by homogenising and pre-crushing 25 parts by weight of one component of a component mixture, 5 parts by weight of 2,2'-dinaphthylmethane-6,6'-disulfonic acid sodium, 2 parts by weight of oleoylmethyltauric acid sodium, 1 part by weight of polyvinyl alcohol, 17 parts by weight of calcium carbonate and 50 parts by weight of water on a colloid mill,subsequently ground in a bead mill, and the resulting suspension is atomized and dried in a spray tower using a single-component nozzle. BIOLOGICAL EXAMPLES Effect of selected herbicide / safener combinations according to the invention using the example of pest reduction on spring wheat (TRZAS): The seeds of the crops to be treated were placed in soil in plastic pots (diameter ~8 cm), covered with soil, and grown in a greenhouse under favorable conditions for germination and growth. The test plants were treated in the early leaf stage (BBCH12). The herbicides and safeners used were formulated as wettable powders (WP), mixed according to the respective specified dosage, and sprayed onto the above-ground parts of the plants as an aqueous suspension at a water application rate corresponding to 300 l / ha with the addition of a wetting agent (Mero, 1.5 l / ha). The dosage of the respective herbicides was selected such thatthat at the time of evaluation, it caused moderate, visually clearly detectable damage (min. 30%, max. 70%) in a control group of crops included in the same trial without safener treatment compared to untreated crops. After application, the plants were cultivated in a greenhouse under good growth conditions. 21 days after application, a visual assessment of the herbicide damage was carried out. The damage was visually assessed on a scale of 0-100% in comparison to untreated control plants and averaged across two replicates per treatment. Examples: 0% = no detectable effect compared to the untreated plant; 20% = the treated plant population is 20% damaged compared to the untreated control population (e.g., growth height, leaf damage, etc.); 100% = treated plants completely damaged or dead. The trials show,that damage to the crop plant spring wheat (TRZAS; cv. Triso) (= herbicide damage without safener in Table 4 below) caused by the respective herbicide (component (B)) is significantly reduced by the addition of a safener (component (A)). The safeners were each used at an application rate of 80 g / ha (Table 4):

Claims

Patent claims 1. Herbicide / safener combination containing one or more compounds effective as safeners [component (A)] and one or more herbicidally active compounds [component (B)], where component (A) is one or more compounds of the general formula (I) or their agrochemically acceptable salts, 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 000 0 0 0 0 0 0 0 0 0 0 0 stands, and (R 2 )m-Phenyl for groups Q-2.1 to Q-2.53 00 0 0 0 0 0 0 0 0 0 0 . 0 0 0 . . stands, R 3 stands for hydrogen, and R 4für Wasserstoff, Methyl, Ethyl, n-Propyl, i-Propyl, n-Butyl, n-Pentyl, Phenyl, Benzyl, CH2(4-Cl-Ph), CH2(4-F-Ph), CH2(4-OMe-Ph), 2-Methoxyethyl, Tetrahydrofuran-2-yl- methyl, Tetrahydrofuran-3-yl-methyl, Tetrahydropyran-2-yl-methyl, Tetrahydropyran-3-yl- methyl, Tetrahydropyran-4-yl-methyl, Methylpropionat-3-yl, Ethylpropionat-3-yl, Methylacetat-2-yl, Ethylacetat-2-yl, Methylpivalat-2-yl, Ethylpivalat-3-yl, Methyl-2- methylpropanoat-3-yl, Methyl-2,2-dimethylpropanoat-3-yl, Ethyl-2-methylpropanoat-3-yl, Methyl-2-propanoat-2-yl, Ethyl-2-propanoat-2-yl, Methyl-acetat-2yl, Ethyl-acetat-2yl, Methyl-1-methylcyclopropancarboxylat-2yl, Ethyl-1-methylcyclopropan-carboxylat-2yl, 2-(Dimethylamino)ethyl, Oxetan-3-yl, (3-Methyloxetan-3-yl)methyl, 2,2,2-Trifluorethyl, 2,2-Difluorethyl, 2-Fluorethyl, 2,2,3,3,3-Pentafluorpropyl, Cyclopropylmethyl, 1- Cyclopropyl-ethyl, (1-Methyl-cyclopropyl)-methyl, (2,2-Dichlorcyclopropyl)-methyl, (2,2- Dimethyl-cyclopropyl)-methyl, Allyl, Propargyl (Prop-2-in-1-yl),2-Chloroprop-2-en-1-yl, 3-Phenylprop-2-yn-1-yl, 3,3-Dichloroprop-2-en-1-yl, 3,3-Dichloro-2-fluoro-prop-2-en-1-yl, Methylprop-2-yn-1-yl, 2-Methylprop-2-en-1-yl, But-2-en-1-yl, But-3-en-1-yl, But-2-yn-1-yl, but-3-yn-1-yl, 4-chloro-but-2-yn-1-yl, 3-methyl-but-2-en-1-yl, 3-methyl-but-1-en-1-yl, 1-(2E)-1-methylbut-2-en-1-yl, (E)-pent-3-en-2-yl or (Z)-Pent-3-en-2-yl, cyclobutylmethyl, Cyclopentylmethyl, cyclohexylmethyl, heptan-2-yl, isobutyl, 1,3-dioxolan-2-ylmethyl or 1-ethyl-5-methyl-1-pyrazol-4-methyl, and (B) one or more herbicides [component (B)] from the group of herbicidal active ingredients with the general formula (II), where A is N or CY, X bedeutet Nitro, Halogen, Cyano, Formyl, Rhodano, (C1-C6)-Alkyl, Halogen-(C1-C6)-alkyl, (C2- C6)-Alkenyl, Halogen-(C2-C6)-alkenyl, (C2-C6)-Alkinyl, Halogen-(C3-C6)-alkinyl, (C3-C6)-Cycloalkyl, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Halogen-(C3-C6)-cycloalkyl-(C1-C6)- alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, NR 1 C(O)N(R 1 )2, OC(O)N(R 1 )2, C(O)NR 1 OR 1 , OR 1 , OCOR 1 , OSO2R 2 , S(O) n R 2 , SO2OR 1 , SO2N(R 1 )2, NR 1 SO2R 2 , NR 1 COR 1 , (C1-C6)- Alkyl-S(O) n R 2 , (C1-C6)-Alkyl-OR 1 , (C1-C6)-Alkyl-OCOR 1 , (C1-C6)-Alkyl-OSO2R 2 , (C1-C6)-Alkyl- CO2R 1 , (C1-C6)-Alkyl-SO2OR 1 , (C1-C6)-Alkyl-CON(R 1 )2, (C1-C6)-Alkyl-SO2N(R 1)2, (C1-C6)-Alkyl- NR 1 COR 1 , (C1-C6)-Alkyl-NR 1 SO2R 2 , NR 1 R 2 , P(O)(OR 5 )2, CH2P(O)(OR 5 )2, (C1-C6)-Alkyl-Heteroaryl, (C1-C6)-Alkyl-Heterocyclyl, wobei die beiden letztgenannten Reste jeweils durch s Reste aus der Gruppe bestehend aus Halogen, (C1-C6)-Alkyl, Halogen-(C1-C6)-alkyl, S(O)n-(C1-C6)-Alkyl, (C1-C6)- Alkoxy und Halogen-(C1-C6)-alkoxy substituiert sind, und wobei Heterocyclyl n Oxogruppen trägt, Y bedeutet Wasserstoff, Nitro, Halogen, Cyano, Rhodano, (C1-C6)-Alkyl, Halogen-(C1-C6)-alkyl, (C2-C6)-Alkenyl, Halogen-(C2-C6)-alkenyl, (C2-C6)-Alkinyl, Halogen-(C2-C6)-alkinyl, (C3-C6)- Cycloalkyl, (C3-C6)-Cycloalkenyl, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Halogen-(C3-C6)-cycloalkyl-(C1-C6)-alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, NR 1 C(O)N(R 1 )2, OC(O)N(R 1)2, CO(NOR 1 )R 1 , NR 1 SO2R 2 , NR 1 COR 1 , OR 1 , OSO2R 2 , S(O)nR 2 , SO2OR 1 , SO2N(R 1 )2, (C1-C6)-Alkyl-S(O)nR 2 , (C1-C6)-Alkyl-OR 1 , (C1-C6)-Alkyl-OCOR 1 , (C1-C6)-Alkyl-OSO2R 2 , (C1-C6)-Alkyl-CO2R 1 , (C1-C6)-Alkyl-CN, (C1-C6)-Alkyl-SO2OR 1 , (C1-C6)-Alkyl-CON(R 1 )2, (C1-C6)- Alkyl-SO2N(R 1 )2, (C1-C6)-Alkyl-NR 1 COR 1 , (C1-C6)-Alkyl-NR 1 SO2R 2 , N(R 1 )2, P(O)(OR 5 )2, CH2P(O)(OR 5)2, (C1-C6)-Alkyl-Phenyl, (C1-C6)-Alkyl-Heteroaryl, (C1-C6)-Alkyl-Heterocyclyl, Phenyl, Heteroaryl oder Heterocyclyl, wobei die sechs letztgenannten Reste jeweils durch s Reste aus der Gruppe bestehend aus Halogen, Nitro, Cyano, (C1-C6)-Alkyl, Halogen-(C1-C6)-alkyl, (C3-C6)- Cycloalkyl, S(O)n-(C1-C6)-Alkyl, (C1-C6)-Alkoxy, Halogen-(C1-C6)-alkoxy, (C1-C6)-Alkoxy-(C1-C4)- alkyl und Cyanomethyl substituiert sind, und wobei Heterocyclyl n Oxogruppen trägt, Z bedeutet Halogen, Cyano, Rhodano, Halogen-(C1-C6)-alkyl, (C2-C6)-Alkenyl, Halogen-(C2-C6)- alkenyl, (C2-C6)-Alkinyl, Halogen-(C2-C6)-alkinyl, (C3-C6)-Cycloalkyl, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Halogen-(C3-C6)-cycloalkyl-(C1-C6)-alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, NR 1 C(O)N(R 1 )2, OC(O)N(R 1 )2, C(O)NR 1 OR 1 , OSO2R 2 , S(O)nR 2 , SO2OR 1, SO2N(R 1 )2, NR 1 SO2R 2 , NR 1 COR 1 , (C1-C6)-alkyl-S(O) n R 2 , (C1-C6)-alkyl-OR 1 , (C1-C6)-alkyl-OCOR 1 , (C1-C6)-alkyl-OSO2R 2 , (C1-C6)-alkyl-CO2R 1 , (C1-C6)-alkyl-SO2OR 1 , (C1-C6)-alkyl-CON(R 1 )2, (C1-C6)-alkyl-SO2N(R 1 )2, (C1-C6)-alkyl-NR 1 COR 1 , (C1-C6)-alkyl-NR 1 SO2R 2 , N(R 1 )2, P(O)(OR 5 )2, heteroaryl, heterocyclyl or phenyl, where the last three radicals are each substituted by s radicals from the group consisting of halogen, nitro, cyano, (C1-C6)-alkyl, halogen-(C1-C6)-alkyl, (C3-C6)-cycloalkyl, S(O) n -(C1-C6)-alkyl, (C1-C6)-alkoxy or halogen-(C1-C6)-alkoxy, and wherein heterocyclyl carries n oxo groups, or Z can also be hydrogen, (C1-C6)-alkyl or (C1-C6)-alkoxy if Y is the radical S(O) n R 2R is (C1-C8)-alkyl, halogen-(C1-C8)-alkyl, (C2-C8)-alkenyl, halogen-(C2-C8)-alkenyl, (C2-C8)-alkynyl, halogen-(C2-C8)-alkynyl, where these six radicals mentioned above are each substituted by s radicals from the group consisting of hydroxy, nitro, cyano, SiR 5 3, PO(OR 5 )2, S(O) n -(C1-C6)-alkyl, S(O) n -(C1-C6)-haloalkyl, (C1-C6)-alkoxy, halogen-(C1-C6)-alkoxy, N(R 3 )2, COR 3 , COOR 3 , OCOR 3 , NR 3 COR 3 , NR 3 SO2R 4, O(C1-C2)-alkyl-(C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl, heteroaryl, heterocyclyl, phenyl, where the last three radicals are each substituted by s radicals from the group consisting of methyl, ethyl, methoxy, trifluoromethyl, cyano and halogen, and where heterocyclyl carries n oxo groups, or R is each substituted by s radicals from the group consisting of halogen, nitro, cyano, (C1-C6)-alkyl, halogen-(C1-C6)-alkyl, (C3-C6)-cycloalkyl, S(O)n-(C1-C6)-alkyl, (C1-C6)-alkoxy, halogen-(C1-C6)-alkoxy and (C1-C6)-alkoxy-(C1-C4)-alkyl (C3–C7)-cycloalkyl, heteroaryl, heterocyclyl or phenyl, where heterocyclyl carries n oxo groups, R 1bedeutet Wasserstoff, (C1-C6)-Alkyl, (C1-C6)-Halogenalkyl, (C2-C6)-Alkenyl, (C2-C6)- Halogenalkenyl, (C2-C6)-Alkinyl, (C2-C6)-Halogenalkinyl, (C3-C6)-Cycloalkyl, (C3-C6)-Cycloalkenyl, (C3-C6)-Halogencycloalkyl, (C1-C6)-Alkyl-(C3-C6)-cycloalkyl, (C1-C6)-Alkyl-O-(C1-C6)-alkyl, (C3-C6)- Cycloalkyl-(C1-C6)-alkyl, Phenyl, Phenyl-(C1-C6)-alkyl, Heteroaryl, (C1-C6)-Alkyl-Heteroaryl, Heterocycl, (C1-C6)-Alkyl-Heterocyclyl, (C1-C6)-Alkyl-O-Heteroaryl, (C1-C6)-Alkyl-O-Heterocyclyl, (C1-C6)-Alkyl-NR 3 -Heteroaryl oder (C1-C6)-Alkyl-NR 3 -Heterocyclyl wobei die 21 letztgenannten Reste jeweils durch s Reste aus der Gruppe bestehend aus Cyano, Nitro, Rhodano, OR 3 , S(O)nR 4 , N(R 3 )2, NR 3 OR 3 , COR 3 , OCOR 3 , SCOR 4 , NR 3 COR 3 , NR 3 SO2R 4, CO2R 3 , COSR 4 , CON(R 3)2 und (C1-C4)- Alkoxy-(C2-C6)-alkoxycarbonyl substituiert sind, und wobei Heterocyclyl n Oxogruppen trägt, R 2 bedeutet (C1-C6)-Alkyl, (C1-C6)-Halogenalkyl, (C2-C6)-Alkenyl, (C2-C6)-Halogenalkenyl, (C2- C6)-Alkinyl, (C2-C6)-Halogenalkinyl, (C3-C6)-Cycloalkyl, (C3-C6)-Cycloalkenyl, (C3-C6)- Halogencycloalkyl, (C1-C6)-Alkyl-O-(C1-C6)-alkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Phenyl, Phenyl- (C1-C6)-alkyl, Heteroaryl, (C1-C6)-Alkyl-Heteroaryl, Heterocyclyl, (C1-C6)-Alkyl-Heterocyclyl, (C1-C6)- Alkyl-O-Heteroaryl, (C1-C6)-Alkyl-O-Heterocyclyl, (C1-C6)-Alkyl-NR 3 -Heteroaryl oder (C1-C6)-Alkyl- NR 3 -Heterocyclyl, wobei die 21 letztgenannten Reste jeweils durch s Reste aus der Gruppe bestehend aus Cyano, Halogen, Nitro, Rhodano, OR 3 , S(O) n R 4 , N(R 3 )2, NR 3 OR 3 , COR 3 , OCOR 3 , SCOR 4 , NR 3 COR 3 , NR 3 SO2R 4 , CO2R3 , COSR 4 , CON(R 3 )2and (C1-C4)-alkoxy-(C2-C6)-alkoxycarbonyl, and wherein heterocyclyl carries n oxo groups, R 3 means hydrogen, (C1-C6)-alkyl, (C2-C6)-alkenyl, (C2-C6)-alkynyl, (C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl or phenyl, R 4 means (C1-C6)-alkyl, (C2-C6)-alkenyl, (C2-C6)-alkynyl, (C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl or phenyl, R 5 means (C1-C4)-alkyl, n means 0, 1 or 2, s means 0, 1, 2 or 3.

2. Safener / herbicide combination according to claim 1, comprising as component (A) one or more safeners from the group consisting of the compounds A1, A2, A3, A4, A5 and A6: A1 Methyl {[1,5-bis(4-chloro-2-fluorophenyl)-1H-1,2,4-triazol-3-yl]oxy}acetate A3 Methyl {[5-(4-chloro-2-fluorophenyl)-1-(2,4-difluorophenyl)-1H-1,2,4-triazol-3-yl]oxy}acetate A5 Methyl {[1-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1H-1,2,4-triazol-3-yl]oxy}acetate A6 {[1-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1H-1,2,4-triazol-3-yl]oxy}acetic acid 3. Safener / herbicide combination according to one of claims 1 or 2, containing as component (B) one or more active ingredients of the formula (II) where, A means N or CY, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl, halogen-(C3-C6)-cycloalkyl-(C1-C6)-alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, OC(O)N(R 1 )2, C(O)NR 1 OR 1 , OR 1 , OCOR 1 , OSO2R 2 , S(O)nR 2 , NR 1 SO2R 2 , NR 1COR 1 , (C1-C6)-Alkyl-S(O)nR 2 , (C1-C6)-Alkyl-OR 1 , (C1-C6)-Alkyl-OCOR 1 , (C1-C6)-Alkyl-OSO2R 2 , (C1-C6)-Alkyl-CO2R 1 , (C1-C6)-Alkyl-SO2OR 1 , (C1-C6)-Alkyl-CON(R 1 )2, (C1-C6)-Alkyl-SO2N(R 1 )2, (C1- C6)-Alkyl-NR 1 COR 1 , (C1-C6)-Alkyl-NR 1 SO2R 2 , Y bedeutet Wasserstoff, Halogen, Cyano, (C1-C6)-Alkyl, Halogen-(C1-C6)-alkyl, (C2-C6)-Alkenyl, Halogen-(C2-C6)-alkenyl, (C2-C6)-Alkinyl, Halogen-(C2-C6)-alkinyl, (C3-C6)-Cycloalkyl, (C3-C6)- Cycloalkenyl, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Halogen-(C3-C6)- cycloalkyl-(C1-C6)-alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, NR 1 C(O)N(R 1 )2, OC(O)N(R 1 )2, CO(NOR 1 )R 1 , NR 1 SO2R 2 , NR 1 COR 1 , OR 1 , OSO2R2 , S(O)nR 2 , SO2OR 1 , SO2N(R 1 )2, (C1- C6)-Alkyl-S(O)nR 2 , (C1-C6)-Alkyl-OR 1 , (C1-C6)-Alkyl-OCOR 1 , (C1-C6)-Alkyl-OSO2R 2 , (C1-C6)-Alkyl- CO2R 1 , (C1-C6)-Alkyl-CN, (C1-C6)-Alkyl-SO2OR 1 , (C1-C6)-Alkyl-CON(R 1 )2, (C1-C6)-Alkyl-SO2N(R 1 )2, (C1-C6)-Alkyl-NR 1 COR 1 , (C1-C6)-Alkyl-NR 1 SO2R 2 , N(R 1 )2, Heterocyclyl, wobei Heterocyclyl n Oxogruppen tragen kann Z bedeutet Halogen, Halogen-(C1-C6)-alkyl, (C2-C6)-Alkenyl, Halogen-(C2-C6)-alkenyl, (C2-C6)- Alkinyl, Halogen-(C2-C6)-alkinyl, (C3-C6)-Cycloalkyl, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-Cycloalkyl- (C1-C6)-alkyl, Halogen-(C3-C6)-cycloalkyl-(C1-C6)-alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, NR 1 C(O)N(R 1 )2, OC(O)N(R 1 )2, C(O)NR 1 OR1 , OSO2R 2 , S(O)nR 2 , SO2OR 1 , SO2N(R 1 )2, NR 1 SO2R 2 , NR 1 COR 1 , (C1-C6)-Alkyl-S(O) n R 2 , (C1-C6)-Alkyl-OR 1 , (C1-C6)-Alkyl-OCOR 1 , (C1-C6)- Alkyl-OSO2R 2 , (C1-C6)-Alkyl-CO2R 1 , (C1-C6)-Alkyl-SO2OR 1 , (C1-C6)-Alkyl-CON(R 1 )2, (C1-C6)-Alkyl- SO2N(R 1 )2, (C1-C6)-Alkyl-NR 1 COR 1 , (C1-C6)-Alkyl-NR 1 SO2R 2 , N(R 1 )2, Z kann auch Wasserstoff, (C1-C6)-Alkyl oder (C1-C6)-Alkoxy bedeuten, falls Y für den Rest S(O) n R 2 steht, R bedeutet (C1–C8)-Alkyl, Halogen-(C1–C8)-alkyl, (C2-C8)-Alkenyl, Halogen-(C2-C8)-alkenyl, (C2- C8)-Alkinyl, Halogen-(C2-C8)-alkinyl, (C3-C6)-Cycloalkyl, Phenyl, R 1means hydrogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C2-C6)-alkenyl, (C2-C6)-haloalkenyl, (C2-C6)-alkynyl, (C2-C6)-haloalkynyl, (C3-C6)-cycloalkyl, (C3-C6)-cycloalkenyl, (C3-C6)-halocycloalkyl, (C1-C6)-alkyl-O-(C1-C6)-alkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl, phenyl, phenyl-(C1-C6)-alkyl, heteroaryl, (C1-C6)-alkyl-heteroaryl, heterocyclyl, where (C3-C6)-cycloalkyl can be substituted with s residues (C1-C6)-alkyl, R 2 means (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C2-C6)-alkenyl, (C2-C6)-haloalkenyl, (C2-C6)-alkynyl, (C2-C6)-haloalkynyl, (C3-C6)-cycloalkyl, (C3-C6)-cycloalkenyl, (C3-C6)-halocycloalkyl, (C1-C6)-alkyl-O-(C1-C6)-alkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl, phenyl, n means 0, 1 or 2, s means 0, 1, 2 or 3.

4. Safener / herbicide combination according to one of claims 1 to 3, comprising as component (B) one or more active ingredients of the formula (II) where, A means CY, X bedeutet Halogen, (C1-C6)-Alkyl, Halogen-(C1-C6)-alkyl, (C2-C6)-Alkenyl, Halogen-(C2-C6)- alkenyl, (C2-C6)-Alkinyl, Halogen-(C3-C6)-alkinyl, (C3-C6)-Cycloalkyl, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Halogen-(C3-C6)-cycloalkyl-(C1-C6)-alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, OC(O)N(R 1 )2, C(O)NR 1 OR 1 , OR 1 , OCOR 1 , OSO2R 2 , S(O) n R 2 , NR 1 SO2R 2 , NR 1 COR 1 , (C1-C6)-Alkyl-S(O) n R 2 , (C1-C6)-Alkyl-OR 1 , (C1-C6)-Alkyl-OCOR 1 , (C1-C6)-Alkyl-OSO2R 2 , (C1-C6)-Alkyl-CO2R 1 , (C1-C6)-Alkyl-SO2OR 1 , (C1-C6)-Alkyl-CON(R 1 )2, (C1-C6)-Alkyl-SO2N(R 1 )2, (C1- C6)-Alkyl-NR 1 COR 1 , (C1-C6)-Alkyl-NR 1 SO2R 2, Y bedeutet Wasserstoff, Halogen, Cyano, (C1-C6)-Alkyl, Halogen-(C1-C6)-alkyl, (C2-C6)-Alkenyl, Halogen-(C2-C6)-alkenyl, (C2-C6)-Alkinyl, Halogen-(C2-C6)-alkinyl, (C3-C6)-Cycloalkyl, (C3-C6)- Cycloalkenyl, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Halogen-(C3-C6)- cycloalkyl-(C1-C6)-alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, NR 1 C(O)N(R 1 )2, OC(O)N(R 1 )2, CO(NOR 1 )R 1 , NR 1 SO2R 2 , NR 1 COR 1 , OR 1 , OSO2R 2 , S(O)nR 2 , SO2OR 1 , SO2N(R 1 )2, (C1- C6)-Alkyl-S(O)nR 2 , (C1-C6)-Alkyl-OR 1 , (C1-C6)-Alkyl-OCOR 1 , (C1-C6)-Alkyl-OSO2R 2 , (C1-C6)-Alkyl- CO2R 1 , (C1-C6)-Alkyl-CN, (C1-C6)-Alkyl-SO2OR 1 , (C1-C6)-Alkyl-CON(R 1 )2, (C1-C6)-Alkyl-SO2N(R 1)2, (C1-C6)-Alkyl-NR 1 COR 1 , (C1-C6)-Alkyl-NR 1 SO2R 2 , N(R 1 )2, Heterocyclyl, wobei Heterocyclyl n Oxogruppen tragen kann, Z bedeutet Halogen, Halogen-(C1-C6)-alkyl, (C2-C6)-Alkenyl, Halogen-(C2-C6)-alkenyl, (C2-C6)- Alkinyl, Halogen-(C2-C6)-alkinyl, (C3-C6)-Cycloalkyl, Halogen-(C3-C6)-cycloalkyl, (C3-C6)-Cycloalkyl- (C1-C6)-alkyl, Halogen-(C3-C6)-cycloalkyl-(C1-C6)-alkyl, COR 1 , COOR 1 , OCOOR 1 , NR 1 COOR 1 , C(O)N(R 1 )2, NR 1 C(O)N(R 1 )2, OC(O)N(R 1 )2, C(O)NR 1 OR 1 , OSO2R 2 , S(O)nR 2 , SO2OR 1 , SO2N(R 1 )2, NR 1 SO2R 2 , NR 1 COR 1 , (C1-C6)-Alkyl-S(O)nR 2 , (C1-C6)-Alkyl-OR 1 , (C1-C6)-Alkyl-OCOR 1 , (C1-C6)- Alkyl-OSO2R 2 , (C1-C6)-Alkyl-CO2R 1 , (C1-C6)-Alkyl-SO2OR 1, (C1-C6)-Alkyl-CON(R 1 )2, (C1-C6)-Alkyl- SO2N(R 1 )2, (C1-C6)-Alkyl-NR 1 COR 1 , (C1-C6)-Alkyl-NR 1 SO2R 2 , N(R 1 )2, Z kann auch Wasserstoff, (C1-C6)-Alkyl oder (C1-C6)-Alkoxy bedeuten, falls Y für den Rest S(O)nR 2 steht, R bedeutet (C1–C8)-Alkyl, Halogen-(C1–C8)-alkyl, (C2-C8)-Alkenyl, Halogen-(C2-C8)-alkenyl, (C2- C8)-Alkinyl, Halogen-(C2-C8)-alkinyl, (C3-C6)-Cycloalkyl, Phenyl, R 1 bedeutet Wasserstoff, (C1-C6)-Alkyl, (C1-C6)-Halogenalkyl, (C2-C6)-Alkenyl, (C2-C6)- Halogenalkenyl, (C2-C6)-Alkinyl, (C2-C6)-Halogenalkinyl, (C3-C6)-Cycloalkyl, (C3-C6)-Cycloalkenyl, (C3-C6)-Halogencycloalkyl, (C1-C6)-Alkyl-O-(C1-C6)-alkyl, (C3-C6)-Cycloalkyl-(C1-C6)-alkyl, Phenyl, Phenyl-(C1-C6)-alkyl, Heteroaryl, (C1-C6)-Alkyl-Heteroaryl, Heterocyclyl, wobei (C3-C6)-Cycloalkyl mit s Resten (C1-C6)-Alkyl substituiert sein kann, R 2means (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C2-C6)-alkenyl, (C2-C6)-haloalkenyl, (C2-C6)-alkynyl, (C2-C6)-haloalkynyl, (C3-C6)-cycloalkyl, (C3-C6)-cycloalkenyl, (C3-C6)-halocycloalkyl, (C1-C6)-alkyl-O-(C1-C6)-alkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl, phenyl, n means 0, 1 or 2, s means 0, 1, 2 or 3.

5. Safener / herbicide combination according to one of claims 1 to 4, comprising as component (B) one or more active ingredients of the formula (II) wherein, A is CY, X is halogen, (C1-C6)-alkyl, (C1-C6)-alkyl-OR 1 , Y means S(O)nR 2 , OR 1 , (C1-C6)-alkyl-OR 1 , COR 1 , C(O)N(R 1 )2, heterocyclyl, where heterocyclyl may carry n oxo groups, Z is halogen, halogen-(C1-C6)-alkyl, (C3-C6)-cycloalkyl, S(O)nR 2 , Z can also be (C1-C6)-alkyl if Y is the radical S(O)nR 2 R is (C1–C8)-alkyl, R 1means (C1-C6)-alkyl, (C3-C6)-cycloalkyl, (C1-C6)-haloalkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl, where (C3-C6)-cycloalkyl can be substituted with s radicals (C1-C6)-alkyl, R 2 means (C1-C6)-alkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl, (C3-C6)-cycloalkyl, (C1-C6)-alkyl-O-(C1-C6)-alkyl, n means 0, 1 or 2, s means 0, 1, 2 or 3.

6. Safener / herbicide combination according to one of claims 1 to 5, comprising as component (B) one or more active ingredients of the formula (II) wherein, A is CY, X is halogen, (C1-C6)-alkyl, (C1-C6)-alkyl-OR 1, Y bedeutet Methylsulfanyl, Methylsulfinyl, Methylsulfonyl, Ethylsulfanyl, Ethylsulfinyl, Ethylsulfonyl, Methylaminocarbonyl, Ethylaminocarbonyl, Cyclopropylaminocarbonyl, Isopropylaminocarbonyl, Cyclopropylmethylaminocarbonyl, Dimethylaminocarbonyl, Methylcarbonyl, Ethylcarbonyl, Cyclopropylcarbonyl, Methoxymethyl, Ethoxymethyl, Methoxy, Ethoxy, Cyclopropyloxy, Cyclopropylmethoxy, Z bedeutet Halogen, Halogen-(C1-C6)-alkyl, R 2 (O)nS, (C3-C6)-Cycloalkyl, Z kann auch (C1-C6)-Alkyl bedeuten, falls Y für die Reste Methylsulfinyl, Methylsulfanyl, Methylsulfonyl, Ethylsulfinyl, Ethylsulfanyl, Ethylsulfonyl, Cyclopropylmethylsulfinyl, Cyclopropylmethylsulfanyl, Cyclopropylmethylsulfonyl steht, R 1 bedeutet (C1-C6)-Alkyl, R 2means (C1-C6)-alkyl, n means 0, 1 or 2.

7. Safener / herbicide combination according to any one of claims 1 to 6, comprising as component (A) one or more active ingredients from the group of compounds A1, A3 and A5.

8. Safener / herbicide combination according to any one of claims 1 to 7, further comprising one or more additives customary in crop protection.

9. A method for protecting crops from phytotoxic side effects of a herbicide (B), characterized in that an effective amount of a safener (A) is applied before, after or simultaneously with the herbicide (B) to the plants, plant parts, plant seeds or the cultivated area, where the combination of herbicide (B) and safener (A) is defined according to any one of claims 1 to 7.

10. The method according to claim 9, characterized in that the crops are cereal plants. 11.The method according to claim 9 or 10, characterized in that the herbicides (B) are applied at a rate of 40 to 200 g / ha of active substance and in a safener (A) / herbicide (B) weight ratio of 1:400 to 500:

1.

12. Use of the safener / herbicide combination according to any one of claims 1 to 8 for controlling weeds or regulating plant growth.

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