Aqueous lubricant for metalworking

Abstract

The invention relates to a lubricant composition comprising water and: - 0.05% to 40% by weight of polyalkylene glycol,- 0.001% to 15% by weight of non-ionic surfactant(s), 0.001% to 30% by weight of at least one cellulose compound, relative to the total weight of the lubricating composition. The invention also relates to the use of the lubricant composition according to the invention for metalworking.

Description

[0001] DESCRIPTION

[0002] TITLE: AQUEOUS LUBRICANT FOR METALWORKING

[0003] TECHNICAL FIELD OF THE INVENTION

[0004] The present invention relates to the field of lubricating compositions, and more particularly to lubricating compositions used in metalworking processes, in particular for machining (turning, milling, drilling, sawing, threading among others), forming, cutting, stamping or even rolling of metal parts. In particular, the present invention relates to water-based lubricating compositions.

[0005] STATE OF THE ART

[0006] Lubricating compositions, also called "lubricants", are commonly used in mechanical systems to reduce friction between parts and thus protect them against wear. In addition to wear phenomena, friction can oppose the relative movement of the parts in contact and induce energy losses that are detrimental to optimal operation of the mechanical system.

[0007] Lubricants are used for a wide range of applications, from the lubrication of combustion vehicle engines to the lubrication of equipment used for machining operations, commonly known as metalworking, particularly for metal deformation operations.

[0008] Metalworking generally refers to the implementation of mechanical or metallurgical processes, both diversified and more specialized, which can be defined as shaping, cutting or joining processes. It can also concern any mechanical transformation of metal, such as machining (turning, milling, drilling, sawing, threading among others), forming, cutting, stamping or even rolling.

[0009] Metalworking operations particularly require the use of lubricating compositions, with the aim of reducing friction forces between the metal parts in contact and preventing their premature wear, while advantageously ensuring cooling of the latter.

[0010] These lubricating compositions, dedicated to lubrication in metal machining processes, are also commonly referred to as “metalworking compositions or fluids”, “machining lubricants or fluids” or “cutting lubricants or fluids”.

[0011] Conventionally, the lubricant formulations used for such machining operations are lubricants composed mainly of one or more base oils,

[0012] 1

[0013] 6086079v2 which are generally associated with additives dedicated to boosting the lubricating performance of base oils, such as friction modifier additives.

[0014] Generally speaking, these lubricating formulations are classified according to the type of oil they incorporate. Thus:

[0015] - Mineral fluids, non-renewable, are those comprising mineral oils, such as paraffinic, aromatic or naphthenic oils, in their basic formulation;

[0016] - Renewable fluids, of plant or animal origin, are those comprising vegetable or animal oils or fats in their basic formulation;

[0017] - Mineral fluids of synthetic origin are those comprising mineral oils or chemically modified petrochemical derivatives, in their basic formulation such as, for example, polyalphaolefins, polyalkylene glycols and hydrogenated mineral oils;

[0018] - Renewable fluids of synthetic origin are those comprising chemically modified vegetable or animal oils, in their basic formulation such as, for example, vegetable oil esters, sulphated, oxidised, esterified vegetable oils or even sulphated animal oils.

[0019] Some formulations, called mixed, include a mixture of the oils listed above in their basic formulation. The best known are called semi-synthetic oils and correspond to a mixture of synthetic and mineral oils.

[0020] However, the use of oils or greases in lubricating compositions for metalworking has several disadvantages. In particular, oil-based lubricants generally have low resistance to microbial attack, poor cooling properties, or a negative impact on the working environment, health, or safety.

[0021] Emulsion lubricants, comprising an aqueous phase added to an oily phase, have been developed. However, these lubricants have poor stability, partly due to water hardness and / or salinity.

[0022] In order to solve the problems associated with the implementation of oil-based lubricant formulations in metalworking applications, water-based compositions have shown some interest. These formulations generally include water, supplemented with various water-soluble additives to ensure the tribological properties required for lubricants, particularly in terms of friction reduction and protection of parts against wear.

[0023] 2

[0024] 6086079v2 As an example, we can cite document FR 3 124 800 which describes aqueous lubricating compositions comprising at least one polyalkylene glycol and at least one galactomannan polysaccharide.

[0025] Unfortunately, the use of aqueous lubricants for metalworking applications has a major disadvantage related to the formation of so-called "gummy residues".

[0026] These gummy residues appear after machining operations. Once the machining equipment is stopped, the lubricant, subject to ambient dehydration, is likely to lead to the formation of salts which, combined with the polymers present in the lubricant, can form relatively viscous and insoluble residues in the aqueous phase, referred to as "gummy residues".

[0027] Gummy residues adhere to the tool walls and can cause the machining tool to jam, generally requiring unwanted maintenance operations on the machine.

[0028] Thus, there remains a need for an aqueous lubricating composition for metalworking that produces little or no gummy residue, while maintaining or even improving the tribological properties of the lubricant, particularly in terms of anti-wear and extreme pressure properties.

[0029] The present invention aims precisely to meet this need.

[0030] SUMMARY OF THE INVENTION

[0031] The invention relates to a lubricating composition comprising water and: from 0.05 to 40% by weight of polyalkylene glycol, from 0.001 to 15% by weight of non-ionic surfactant(s), from 0.001 to 30% by weight of at least one cellulose compound, relative to the total weight of the lubricating composition.

[0032] Preferably, the lubricating composition further comprises at least one anti-corrosion system comprising at least one acid and at least one base, at least one base preferably being chosen from amines, advantageously from alkanolamines.

[0033] According to one embodiment, the composition is a ready-to-use composition comprising water and: from 0.05 to 15% by weight, preferably from 0.05 to 10% by weight, preferably from 0.1 to 5% by weight, of polyalkylene glycol, from 0.001 to 5% by weight, preferably from 0.002 to 1% by weight, preferably from 0.002 to 0.5% by weight, of non-ionic surfactant(s),

[0034] 3

[0035] 6086079v2 from 0.005 to 5% by weight, preferably from 0.005 to 1% by weight, preferably from 0.005 to 0.5% by weight, of at least one cellulose compound, relative to the total weight of the lubricating composition.

[0036] According to one embodiment, the composition being a concentrated composition comprising water and: from 0.5 to 20% by weight, preferably from 1 to 20% by weight, preferably from 2 to 15% by weight, of polyalkylene glycol, from 0.01 to 10% by weight, preferably from 0.05 to 1% by weight, preferably from 0.05 to 0.5% by weight, of non-ionic surfactant(s), from 0.05 to 10% by weight, preferably from 0.05 to 5% by weight, preferably from 0.1 to 1% by weight, of at least one cellulose compound, relative to the total weight of the lubricating composition.

[0037] Preferably, said at least one cellulose compound is chosen from alkylcelluloses, dialkylcelluloses, hydroxyalkylcelluloses, carboxyalkylcelluloses, and mixtures thereof, preferably from hydroxyalkylcelluloses, advantageously said at least one cellulose compound is a hydroxyethylcellulose.

[0038] Preferably, the polyalkylene glycol(s) are chosen from poly(ethylene glycol), poly(propylene glycol), copolymers comprising ethylene oxide units and propylene oxide units, and mixtures thereof, preferably from block copolymers comprising ethylene oxide units and propylene oxide units and mixtures thereof, more preferably from ethylene oxide-propylene oxide diblock copolymers and propylene oxide-ethylene oxide-propylene oxide triblock copolymers and mixtures thereof.

[0039] Preferably, at least one polyalkylene glycol of the lubricating composition, preferably all the polyalkylene glycols of the lubricating composition, has one or more of the following characteristics:

[0040] - a molecular mass ranging from 500 to 10000 g / mol, preferably from 800 to 5000 g / mol, more preferably from 900 to 3000 g / mol, and / or

[0041] - a viscosity at 40°C ranging from 10 to 1000 mm 2 / s, preferably 15 to 500 mm 2 / s, preferably from 20 to 400 mm 2 / s.

[0042] Preferably, at least one non-ionic surfactant, preferably all non-ionic surfactants, has one or more of the following characteristics:

[0043] - at least one surfactant has a hydrophilic-lipophilic balance (HLB) ranging from 7 to 17, and / or

[0044] 4

[0045] 6086079v2 - at least one surfactant has a molar mass ranging from 130 to 850 g / mol, preferably from 140 to 700 g / mol, more preferably from 150 to 500 g / mol, and / or

[0046] - at least one surfactant is chosen from alkoxylated fatty alcohols, sorbitan esters, alkylpolyglycosides, and mixtures thereof, preferably from alkoxylated fatty alcohols, more preferably from ethoxylated and / or propoxylated fatty alcohols.

[0047] According to one embodiment, the composition is a ready-to-use composition comprising: from 0.05 to 15% by weight, preferably from 0.05 to 10% by weight, preferably from 0.1 to 5% by weight, of polyalkylene glycol, from 0.001 to 5% by weight, preferably from 0.002 to 1% by weight, preferably from 0.002 to 0.5% by weight, of non-ionic surfactant(s), from 0.005 to 5% by weight, preferably from 0.005 to 1% by weight, preferably from 0.005 to 0.5% by weight, of cellulose compound(s), at least 60% by weight of water, preferably at least 70% by weight of water, preferably at least 80% by weight of water, optionally: o from 0.01 to 10% by weight, preferably from 0.01 to 5% by weight, preferably from 0.05 to 5% by weight, of aliphatic acid(s), and o from 0.01 to 10% by weight, preferably from 0.01 to 5% by weight, preferably from 0.05 to 5% by weight, of base(s), relative to the total weight of the lubricating composition.

[0048] According to one embodiment, the composition is a ready-to-use composition comprising water and: from 0.1 to 5% by weight of PAGs chosen from copolymers comprising ethylene oxide units and propylene oxide units, the PAGs having a molecular mass ranging from 900 to 3000 g / mol, from 0.002 to 0.5% by weight of alkoxylated fatty alcohols chosen from ethoxylated fatty alcohols, ethoxylated and proproxylated fatty alcohols and their mixture, said alkoxylated fatty alcohols having a molar mass ranging from 100 to 850 g / mol, from 0.005 to 0.5% by weight of hydroxyalkylcellulose where the alkyls have from 1 to 8 carbon atoms, from 0.05 to 10% by weight of aliphatic acid(s) comprising from 4 to 15 carbon atoms, and from 0.05 to 10% by weight of alkanolamine(s) chosen from monoethanolamine, diethanolamine, triethanolamine, diglycolamine, mono-

[0049] 5

[0050] 6086079v2 isopropanolamine, diisopropanolamine, triisopropanolamine, methyldiethanol amine, 2-amino-2-ethyl-1,3-propanediol, 2-amino-2-methyl-1-propanol and mixtures thereof, relative to the total weight of the lubricating composition.

[0051] According to one embodiment, the composition is a concentrated composition comprising: from 0.5 to 20% by weight, preferably from 1 to 20% by weight, preferably from 2 to 15% by weight, of polyalkylene glycol, from 0.01 to 10% by weight, preferably from 0.05 to 1% by weight, preferably from 0.05 to 0.5% by weight, of non-ionic surfactant(s), from 0.05 to 10% by weight, preferably from 0.05 to 5% by weight, preferably from 0.1 to 1% by weight, of cellulose compound(s), at least 40% by weight of water, preferably at least 50% of water, optionally: i. from 0.5 to 20% by weight, preferably from 0.5 to 15% by weight, preferably from 1 to 15% by weight, of aliphatic acid(s), and ii. from 0.5 to 25% by weight, preferably from 0.5 to 20% by weight, preferably from 1 to 20% by weight, of base(s), relative to the total weight of the lubricating composition.

[0052] According to one embodiment, the composition is a concentrated composition comprising water and: from 2 to 15% by weight of PAGs chosen from copolymers comprising ethylene oxide units and propylene oxide units, the PAGs having a molecular mass ranging from 900 to 3000 g / mol, from 0.05 to 0.5% by weight of alkoxylated fatty alcohols chosen from ethoxylated fatty alcohols, ethoxylated and proproxylated fatty alcohols and their mixture, said alkoxylated fatty alcohols having a molar mass ranging from 100 to 850 g / mol, from 0.1 to 1% by weight of hydroxyalkylcellulose where the alkyls have from 1 to 8 carbon atoms, from 1 to 20% by weight of aliphatic acid(s) comprising from 4 to 15 carbon atoms, and from 2 to 30% by weight of alkanolamine(s) chosen from monoethanolamine, diethanolamine, triethanolamine, diglycolamine, monoisopropanolamine, diisopropanolamine, triisopropanolamine, methyldiethanolamine, 2-amino-2-ethyl-1,3-propanediol,2-amino-2-methyl-1-propanol and mixtures thereof, relative to the total weight of the lubricating composition.,

[0053] 6

[0054] 6086079v2 Preferably, the composition has a mass ratio between the PAG(s), the non-ionic surfactant(s) and the cellulose compound(s) ranging from 3-10 / 0.01-1 / 0.1-1, preferably from 5-9 / 0.05-0.5 / 0.2-0.8.

[0055] The invention also relates to the use of the lubricating composition according to the invention, as a fluid for metalworking, in particular for machining (turning, milling, drilling, sawing, threading among others), forming, cutting, stamping or even rolling of metal parts, the metal preferably being steel.

[0056] The invention also relates to the use of the lubricating composition according to the invention for improving the eco-performance of a process comprising at least one metalworking step, in which the eco-performance is chosen from: reducing the energy consumed for implementing the process, increasing the productivity of the process, improving the safety of the operators of the process, the eco-performance being in particular chosen from improving the safety of the operators of the process.

[0057] The invention makes it possible to provide a multi-service lubricating composition since it can be implemented on different types of metal surfaces, in particular aluminum surfaces and steel surfaces but more particularly steel surfaces.

[0058] The lubricating composition according to the invention makes it possible to limit the formation of viscous residues. However, these viscous or gummy residues can accumulate on machining tools and can form a polymeric film that is difficult to remove. The lubricating composition according to the invention makes it possible to limit the formation of these deposits but also makes it possible to facilitate the redissolution of these gummy residues.

[0059] Furthermore, the lubricating composition according to the invention has excellent anti-wear properties.

[0060] The invention also makes it possible to provide a lubricating composition having a good toxicological profile and a low impact on the environment.

[0061] The invention makes it possible to provide a lubricating composition which does not generate oil deposits on the ground, which increases operator safety and thus improves the eco-design profile of the composition.

[0062] DETAILED DESCRIPTION OF THE INVENTION

[0063] The invention relates to a lubricating composition comprising water and:

[0064] 7

[0065] 6086079v2 from 0.05 to 40% by weight, preferably from 0.1 to 30% by weight, preferably from 0.1 to 20% by weight, of polyalkylene glycol, from 0.001 to 15% by weight, preferably from 0.002 to 10% by weight, preferably from 0.002 to 1% by weight, of non-ionic surfactant(s), from 0.001 to 30% by weight, preferably from 0.005 to 10% by weight, preferably from 0.005 to 2% by weight, of at least one cellulose compound, relative to the total weight of the lubricating composition.

[0066] In the context of the invention, the polyalkylene glycol is different from the non-ionic surfactant.

[0067] The lubricating composition according to the invention may be a ready-to-use composition or a concentrated composition, also called a composition to be diluted.

[0068] Indeed, the lubricating composition according to the invention can be diluted with the addition of water before being used as a metalworking fluid. For example, the concentrated composition can be diluted with a dilution rate ranging from 3 to 30%, or even from 5 to 20%. This is therefore a dilution rate expressed by volume.

[0069] When the composition is ready for use, it can be used directly as a metalworking fluid, without the need for dilution.

[0070] When the composition is a ready-to-use composition, it preferably comprises water and: from 0.05 to 15% by weight, preferably from 0.05 to 10% by weight, preferably from 0.1 to 5% by weight, of polyalkylene glycol, from 0.001 to 5% by weight, preferably from 0.002 to 1% by weight, preferably from 0.002 to 0.5% by weight, of non-ionic surfactant(s), from 0.005 to 5% by weight, preferably from 0.005 to 1% by weight, preferably from 0.005 to 0.5% by weight, of at least one cellulose compound, relative to the total weight of the lubricating composition.

[0071] According to one embodiment, when the composition is a ready-to-use composition, it comprises: from 0.05 to 15% by weight, preferably from 0.05 to 10% by weight, preferably from 0.1 to 5% by weight, of polyalkylene glycol, from 0.001 to 5% by weight, preferably from 0.002 to 1% by weight, preferably from 0.002 to 0.5% by weight, of non-ionic surfactant(s), from 0.005 to 5% by weight, preferably from 0.005 to 1% by weight, preferably from 0.005 to 0.5% by weight, of at least one cellulose compound,

[0072] 8

[0073] 6086079v2 at least 60% by weight of water, preferably at least 70% by weight of water, preferably at least 80% by weight of water, optionally: o from 0.01 to 10% by weight, preferably from 0.01 to 5% by weight, preferably from 0.05 to 5% by weight, of aliphatic acid(s), and o from 0.01 to 15% by weight, preferably from 0.01 to 10% by weight, preferably from 0.05 to 5% by weight, of base(s), relative to the total weight of the lubricating composition.

[0074] When the composition is a composition to be diluted (concentrated), it preferably comprises water and: from 0.5 to 20% by weight, preferably from 1 to 20% by weight, preferably from 2 to 15% by weight, of polyalkylene glycol, from 0.01 to 10% by weight, preferably from 0.05 to 1% by weight, preferably from 0.05 to 0.5% by weight, of non-ionic surfactant(s), from 0.05 to 10% by weight, preferably from 0.05 to 5% by weight, preferably from 0.1 to 1% by weight, of at least one cellulose compound, relative to the total weight of the lubricating composition.

[0075] According to one embodiment, when the composition is a composition to be diluted (concentrated), it comprises: from 0.5 to 20% by weight, preferably from 1 to 20% by weight, preferably from 2 to 15% by weight, of polyalkylene glycol, from 0.01 to 10% by weight, preferably from 0.05 to 1% by weight, preferably from 0.05 to 0.5% by weight, of non-ionic surfactant(s), from 0.05 to 10% by weight, preferably from 0.05 to 5% by weight, preferably from 0.1 to 1% by weight, of at least one cellulose compound, at least 30% by weight of water, preferably at least 40% by weight of water, preferably at least 45% by weight of water, optionally: o from 0.5 to 20% by weight, preferably 0.5 to 15% by weight, preferably 1 to 15% by weight, of aliphatic acid(s), and o 0.5 to 25% by weight, preferably 0.5 to 20% by weight, preferably 1 to 20% by weight, of base(s), relative to the total weight of the lubricating composition.

[0076] 9

[0077] 6086079v2 According to a particular embodiment, the mass ratio between the proportions of PAG, non-ionic surfactant(s) and cellulose compound(s) ranges from 3-10 / 0.01-1 / 0.1-1, preferably from 5-9 / 0.05-0.5 / 0.2-0.8.

[0078] Polyalkylene glycol (PAG)

[0079] The lubricating composition according to the invention comprises at least one PAG. The PAG may be a polymer or a copolymer. When it is a copolymer, it may be a random copolymer or a block copolymer.

[0080] According to one embodiment, the PAG(s) of the lubricating composition according to the invention are chosen from PAGs comprising alkylene oxide units comprising from 2 to 12 carbon atoms, preferably from 2 to 8 carbon atoms, more preferably from 2 to 4 carbon atoms.

[0081] Typically, in the context of the present invention, if the PAG comprises a terminal group of hydroxyl type (-OH) and a terminal group of alkyl type, then said terminal group of alkyl type comprises from 1 to 5 carbon atoms.

[0082] According to one embodiment, the PAG(s) used in the lubricating composition according to the invention corresponds to formula (I):

[0083] R-(OA) Z OR' (I) in which:

[0084] R and R' represent, independently of one another, a hydrogen atom or alkyl group, linear or branched, comprising from 1 to 5 carbon atoms;

[0085] A, all identical or different, represents an alkyl group, linear or branched, comprising from 2 to 8 carbon atoms; z represents an integer greater than or equal to 2, preferably an integer greater than or equal to 4.

[0086] According to one embodiment, the PAG(s) of the lubricating composition according to the invention are chosen from poly(ethylene glycol) (PEG), poly(propylene glycol) (PPG), copolymers comprising ethylene oxide units and propylene oxide units, and mixtures thereof, preferably from block copolymers comprising ethylene oxide units and propylene oxide units and mixtures thereof, more preferably from ethylene oxide-propylene oxide diblock copolymers, propylene oxide-ethylene oxide-propylene oxide triblock copolymers, ethylene oxide-propylene oxide-ethylene oxide triblock copolymers, and mixtures thereof.

[0087] 10

[0088] 6086079v2 By "copolymers comprising ethylene oxide units and propylene oxide units" within the meaning of the present invention, is meant copolymers comprising at least units resulting from the polymerization of ethylene glycol and at least units resulting from the polymerization of propylene glycol. These polymers may be, for example, block copolymers or random copolymers.

[0089] For the purposes of the present invention, the term "block copolymers comprising ethylene oxide units and propylene oxide units" means copolymers comprising at least one block resulting from the polymerization of ethylene glycol and at least one block resulting from the polymerization of propylene glycol. They may then be called PEG / PPG.

[0090] For the purposes of the present invention, the term "ethylene oxide-propylene oxide diblock copolymers" means copolymers consisting of two blocks, one block resulting from the polymerization of ethylene glycol and one block resulting from the polymerization of propylene glycol. They can then be called PEG-PPG.

[0091] For the purposes of the present invention, the term "propylene oxide-ethylene oxide-propylene oxide triblock copolymers" means copolymers consisting of three blocks, sequenced, one block resulting from the polymerization of propylene glycol, one block resulting from the polymerization of ethylene glycol and one block resulting from the polymerization of propylene glycol (in this order). They can then be called PPG-PEG-PPG.

[0092] For the purposes of the present invention, the term "ethylene oxide-propylene oxide-ethylene oxide triblock copolymers" means copolymers consisting of three blocks, sequenced, one block resulting from the polymerization of ethylene glycol, one block resulting from the polymerization of propylene glycol and one block resulting from the polymerization of ethylene glycol (in this order). They can then be called PEG-PPG-PEG.

[0093] The PAG(s) used in the invention may optionally comprise alkyl end groups, for example chosen from linear or branched alkyl groups comprising from 1 to 8 carbon atoms, preferably from 1 to 5 carbon atoms.

[0094] According to a particular embodiment, the composition comprises at least one PAG having an alkyl terminal group having from 1 to 5 carbon atoms and a hydroxyl terminal group.

[0095] According to one embodiment, the PAG(s) used in the lubricating composition according to the invention corresponds to one of formulas (II) to (V):

[0096] R-(OCH2CH2)x(OCH2CH(CH3))yOR' (II);

[0097] R-(OCH2CH(CH3))y(OCH2CH2)xOR' (III);

[0098] R-(OCH2CH(CH3))y(OCH2CH2)x(OCH2CH(CH3))y'OR' (IV);

[0099] R-(OCH2CH2)x(OCH2CH(CH3))y(OCH2CH2)x'OR' (V); in which:

[0100] 11

[0101] 6086079v2 R and R' represent, independently of each other, a hydrogen atom or a saturated, linear or branched alkyl group comprising from 1 to 5 carbon atoms; x and x', identical or different, represent an integer greater than or equal to 2, preferably greater than or equal to 4, y and y', identical or different, represent an integer greater than or equal to 2.

[0102] Preferably, in the compounds of formula (II), (III), (IV) or (V) according to the invention, x, x', y and y' are, independently of one another, an integer ranging from 2 to 30, preferably from 4 to 25, advantageously from 6 to 20.

[0103] Preferably, in formula (IV), x is an integer ranging from 2 to 30, preferably from 4 to 25, advantageously from 6 to 20, and the sum y+y' ranges from 8 to 45, preferably from 12 to 40, more preferably from 20 to 35.

[0104] Preferably, in formula (V), y is an integer ranging from 2 to 30, preferably from 4 to 25, advantageously from 6 to 20, and the sum x+x' ranges from 8 to 45, preferably from 12 to 40, more preferably from 20 to 35.

[0105] According to one embodiment, each PAG included in the lubricating composition according to the invention has a molecular mass ranging from 500 to 10,000 g / mol, preferably from 700 to 5,000 g / mol, more preferably from 900 to 3,000 g / mol, or even from 900 to 1,500 g / mol.

[0106] The molar mass of PAGs can be determined according to any method well known to those skilled in the art, for example by size exclusion chromatography.

[0107] According to one embodiment, each PAG included in the lubricating composition according to the invention has a viscosity at 40°C ranging from 8 to 1000 mm 2 / s, preferably 10 to 500 mm 2 / s, preferably from 10 to 400 mm 2 / s.

[0108] Viscosity at 40°C can be measured according to ASTM D7042.

[0109] According to one embodiment, each PAG included in the lubricating composition according to the invention has a pour point below 0°C, preferably below -15°C, more preferably below -20°C.

[0110] Pour point can be measured according to ISO 3016.

[0111] According to one embodiment, each PAG included in the lubricating composition according to the invention has a cloud point ranging from 10 to 120°C, preferably from 20 to 110°C, more preferably from 40 to 100°C.

[0112] The cloud point can be measured according to standard NF EN 1890.

[0113] 12

[0114] 6086079v2 The PAG(s) represent from 0.05 to 40% by weight, preferably from 0.1 to 30% by weight, preferably from 0.2 to 20% by weight, of the total weight of the lubricating composition (reduced to 100% by weight).

[0115] PAGs are commercially available products.

[0116] Non-ionic surfactant(s)

[0117] The composition according to the invention comprises at least one non-ionic surfactant.

[0118] According to one embodiment, the non-ionic surfactant has a hydrophilic-lipophilic balance (HLB) ranging from 7 to 17.

[0119] In the context of the present invention, HLB can for example be measured according to the Griffin method.

[0120] According to one embodiment, the surfactant(s) is (are) chosen from alkoxylated fatty alcohols, sorbitan esters, alkylpolyglycosides, preferably from alkoxylated fatty alcohols, the alkoxylated fatty alcohols preferably being ethoxylated and / or propoxylated fatty alcohols. According to one embodiment, the ethoxylated and / or propoxylated fatty alcohols are chosen from ethoxylated and propoxylated fatty alcohols.

[0121] In the context of the present invention, the expression "alkoxylated fatty alcohol" designates an alcohol comprising an alkyl chain and alkoxy units, for example ethoxy units (-CH2CH2O-) and / or propoxy units (-CH2CH2CH2O- or CH3CH(CH3)O-). The alkyl chain may be linear or branched and may comprise, for example, from 6 to 28 carbon atoms or from 7 to 22 carbon atoms.

[0122] In the context of the present invention, alkoxylated fatty alcohols are different from PAGs.

[0123] Sorbitan esters may include sorbitan monoesters, sorbitan diesters, or sorbitan triesters. Non-limiting examples of sorbitan esters include sorbitan monolaurate, sorbitan monooleate, sorbitan monostearate, sorbitan trioleate, and sorbitan tristearate.

[0124] Alkylpolyglycosides can, for example, contain alkyl chains with 6 to 20 carbon atoms.

[0125] Preferably, at least one non-ionic surfactant used in the invention is chosen from alkoxylated fatty alcohols, in particular ethoxylated and / or propoxylated fatty alcohols. According to one embodiment, all the non-ionic surfactants of the lubricating composition according to the invention are chosen from alkoxylated fatty alcohols.

[0126] 13

[0127] 6086079v2 Typically, the alkoxylated fatty alcohols of the lubricating composition are in the form of a mixture of fatty alcohols comprising a distribution of compounds which differ in the number of alkoxylated units.

[0128] According to one embodiment, each alkoxylated fatty alcohol comprises from 1 to 20 alkoxylated units, preferably from 1 to 15 alkoxylated units, the alkoxylated units preferably being chosen from ethoxylated units, propoxylated units and their mixture.

[0129] According to a preferred embodiment, the alkoxylated fatty alcohols used in the lubricating composition according to the invention comprise ethoxylated units, optionally in combination with propoxylated units. Indeed, the ethoxylated units will provide good solubility in water.

[0130] According to one embodiment, each alkoxylated fatty alcohol comprises an aliphatic hydrocarbon chain comprising from 7 to 22 carbon atoms, preferably from 12 to 20 carbon atoms.

[0131] The lubricating composition according to the invention may comprise a mixture of alkoxylated fatty alcohols in which the alkoxylated fatty alcohols differ from each other by the length of the hydrocarbon chain. According to this embodiment, the hydrocarbon chain, preferably of alkyl type, comprises from 6 to 18 carbon atoms, preferably from 6 to 14 carbon atoms.

[0132] According to a preferred embodiment, the molar mass of the alkoxylated fatty alcohols ranges from 130 to 850 g / mol, preferably from 140 to 700 g / mol, more preferably from 150 to 500 g / mol.

[0133] The non-ionic surfactants represent from 0.001 to 15% by weight, preferably from 0.002 to 10% by weight, of the total weight of the lubricating composition (reduced to 100% by weight).

[0134] Nonionic surfactants, particularly alkoxylated fatty alcohols, are commercially available products.

[0135] Cellulosic compound

[0136] The lubricating composition according to the invention comprises at least one cellulose compound.

[0137] Preferably, the cellulose compound is chosen from alkylcelluloses, dialkylcelluloses, hydroxyalkylcelluloses, carboxyalkylcelluloses, and mixtures thereof, preferably from hydroxyalkylcelluloses, advantageously said at least one cellulose compound is a hydroxyethylcellulose.

[0138] For the purposes of the present invention, a hydroxyalkylcellulose is distinguished from a carboxyalkylcellulose in particular in that the carboxyalkylcellulose comprises at least one carboxyl function -COOH.

[0139] 14

[0140] 6086079v2 In the context of the cellulose compound used in the invention, advantageously the alkyl groups possibly present have from 1 to 8 carbon atoms, more preferably from 1 to 4 carbon atoms.

[0141] Advantageously, the lubricating composition comprises hydroxyethylcellulose (HEC) as a cellulose compound.

[0142] According to one embodiment, at least one cellulosic compound of the lubricating composition, preferably all the cellulosic compounds of the lubricating composition, has a weight-average molecular mass of at least 700,000 Da, preferably ranging from 700,000 to 2,000,000 Da.

[0143] The weight-average molecular mass of cellulose compounds can be measured by gel permeation chromatography (GPC).

[0144] The cellulose compound(s) represent from 0.005 to 5% by weight, preferably from 0.005 to 3% by weight, preferably from 0.01 to 1% by weight, of the total weight of the lubricating composition (reduced to 100% by weight).

[0145] Cellulosic compounds are commercially available and will advantageously be chosen from water-soluble compounds.

[0146] The inventors have in fact discovered that a composition comprising both a PAG, a non-ionic surfactant and a cellulose compound makes it possible to obtain a composition having improved lubrication properties, in particular this combination makes it possible to obtain a reduction in the capacity to form residues during washing.

[0147] Acid-base anti-corrosion system

[0148] The lubricating composition according to the invention advantageously comprises an acid-base anti-corrosion system.

[0149] When implemented, the anti-corrosion system of the lubricating composition according to the present invention comprises at least one acid and at least one base.

[0150] Among the acids that may be mentioned are aliphatic monocarboxylic acids, in particular having from 4 to 15 carbon atoms, for example octanoic acid, isononanoic acid, neodecanoic acid, aliphatic dicarboxylic acids having from 4 to 15 carbon atoms, for example decanedioic acid (sebacic acid), undecanedioic acid, dodecanedioic acid, isononanedioic acid, and mixtures thereof.

[0151] 15

[0152] 6086079v2 By “aliphatic acid”, for the purposes of the present invention, is meant an acid not comprising an aromatic group, and advantageously comprising only carbon, hydrogen and oxygen atoms.

[0153] Preferably, at least one acid of the anti-corrosion system is a saturated acid.

[0154] Preferably, at least one acid of the anti-corrosion system implemented in the invention consists of carbon, hydrogen and oxygen atoms.

[0155] Preferably, at least one acid is a monoacid. Monoacids in particular help to reduce staining.

[0156] Among the bases can be mentioned amines, in particular alkanolamines and amino alcohols, potash and sodium hydroxide. The base(s) may be chosen from potash, sodium hydroxide, and ethanolamines, such as monoethanolamine (MEA), diethanolamine (DEA), methyldiethanolamine (MDEA), triethanolamine (TEA), diglycolamine (DGA), isopropanolamines, such as monoisopropanolamine (MIPA), diisopropanolamine (DIPA) and triisopropanolamine (TIPA), ethylene amines, such as ethylenediamine (EDA), diethylenetriamine (DETA), triethylenetetramine (TETA) and tetraethylenepentamine (TEPA), cyclamines, such as cyclohexylamine, 2-amino-2-ethyl-1,3-propanediol, 2-amino-2-methyl-1-propanol and mixtures thereof.

[0157] According to one embodiment, the base(s) are chosen from monoethanolamine (MEA), diethanolamine (DEA), methyldiethanolamine (MDEA), triethanolamine (TEA), diglycolamine (DGA), isopropanolamines, such as monoisopropanolamine (MIPA), diisopropanolamine (DIPA) and triisopropanolamine (TIPA), ethylene amines, such as ethylenediamine (EDA), diethylenetriamine (DETA), triethylenetetramine (TETA) and tetraethylenepentamine (TEPA), cyclamines, such as cyclohexylamine, 2-amino-2-ethyl-1,3-propanediol, 2-amino-2-methyl-1-propanol and mixtures thereof.

[0158] According to one embodiment, the lubricating composition comprises: from 0.01 to 20% by weight, preferably from 0.05 to 15% by weight, preferably from 0.05 to 15% by weight, of acid(s), and from 0.01 to 25% by weight, preferably from 0.01 to 20% by weight, preferably from 0.05 to 20% by weight, of base(s), relative to the total weight of the lubricating composition.

[0159] According to one embodiment, the lubricating composition comprises: from 0.01 to 20% by weight, preferably from 0.05 to 15% by weight, preferably from 0.05 to 15% by weight, of aliphatic carboxylic acid(s), and

[0160] 16

[0161] 6086079v2 from 0.01 to 25% by weight, preferably from 0.01 to 20% by weight, preferably from 0.05 to 20% by weight, of amine(s), relative to the total weight of the lubricating composition.

[0162] According to a preferred embodiment, the lubricating composition comprises: from 0.01 to 20% by weight, preferably from 0.05 to 15% by weight, preferably from 0.05 to 15% by weight, of aliphatic carboxylic acid(s), at least one acid being advantageously a monocarboxylic acid having from 4 to 15 carbon atoms and at least one acid being advantageously a dicarboxylic acid having from 4 to 15 carbon atoms and from 0.01 to 25% by weight, preferably from 0.01 to 20% by weight, preferably from 0.05 to 20% by weight, of alkanolamine(s), at least one alkanolamine being advantageously chosen from monoethanolamine (MEA), diethanolamine (DEA), methyldiethanolamine (MDEA), triethanolamine (TEA), diglycolamine (DGA) isopropanolamines, such as monoisopropanolamine (MIPA), diisopropanolamine (DIPA) and triisopropanolamine (TIPA), and mixtures thereof, based on the total weight of the lubricating composition.

[0163] According to one embodiment, the acid / base mass ratio of the anti-corrosion system ranges from 0.1 to 2, preferably from 0.2 to 1, more preferably from 0.3 to 0.8.

[0164] Preferably, the anti-corrosion system is chosen so as to maintain the pH of the lubricating composition at an alkaline pH, i.e. a pH ranging from 8 to 11, preferably from 8 to 10.

[0165] When implemented, the acid-base anti-corrosion system represents from 0.1 to 30% by weight, preferably from 0.5 to 30% by weight, preferably from 1 to 30% by weight, of the total weight of the lubricating composition (reduced to 100% by weight).

[0166] Lubricating composition

[0167] The lubricating composition according to the invention is an aqueous lubricating composition. Water may represent from 30 to 99.99% by weight of the total weight of the lubricating composition.

[0168] When the composition is a ready-to-use composition, the water preferably represents from 60 to 99.99% by weight, preferably from 70 to 99% by weight, of the total weight of the lubricating composition.

[0169] 17

[0170] 6086079v2 When the composition is a concentrated composition (to be diluted), the water preferably represents from 30 to 90% by weight, preferably from 40 to 80% by weight, of the total weight of the lubricating composition.

[0171] The lubricating composition according to the invention may further comprise at least one additive chosen from the additives conventionally used by those skilled in the art in lubricating compositions for metalworking, preferably at least one additive chosen from anti-foams, biocides, wetting agents, friction modifiers, antifreeze additives, anti-corrosion agents other than acid-base systems, and their mixture.

[0172] According to one embodiment, the lubricating composition according to the invention further comprises at least one additive chosen from anti-foams, anti-corrosion agents of the benzotriazole or tolyltriazole type, and biocides, alone or as a mixture, preferably in a total amount ranging from 0.01 to 15% by weight, preferably from 0.05 to 10% by weight, relative to the total weight of the lubricating composition.

[0173] Advantageously, the lubricating composition according to the invention does not contain boron compounds.

[0174] Advantageously, the lubricating composition according to the invention does not comprise polyvinylpyrrolidone polymers.

[0175] According to one embodiment, the viscosity at 40°C of the ready-to-use lubricating composition ranges from 1 to 20 mm 2 / s, preferably 1.5 to 5 mm 2 / s.

[0176] According to one embodiment, the viscosity at 40°C of the concentrated composition ranges from 50 to 120 mm 2 / s, preferably 60 to 100 mm 2 / s.

[0177] The viscosity at 40°C of the lubricating composition can be measured according to ASTM D7042.

[0178] According to one embodiment, the lubricating composition according to the invention comprises water and:

[0179] - from 0.05 to 40% by weight, preferably from 0.1 to 30% by weight, of PAG comprising alkylene oxide units comprising from 2 to 8 carbon atoms, preferably from 2 to 4 carbon atoms,

[0180] - from 0.001 to 15% by weight, preferably from 0.002 to 10% by weight, preferably from 0.002 to 1% by weight, of non-ionic surfactants having an HLB ranging from 7 to 17,

[0181] - from 0.005 to 10% by weight, preferably from 0.005 to 5% by weight, preferably from 0.005 to 1% by weight, of cellulose compound(s),

[0182] 18

[0183] 6086079v2 relative to the total weight of the lubricating composition.

[0184] According to one embodiment, the lubricating composition according to the invention comprises water and:

[0185] - from 0.05 to 40% by weight, preferably from 0.1 to 30% by weight, preferably from 0.15 to 15% by weight, of PAG comprising alkylene oxide units comprising from 2 to 8 carbon atoms, preferably from 2 to 4 carbon atoms,

[0186] - from 0.001 to 15% by weight, preferably from 0.002 to 10% by weight, from 0.002 to 1% by weight, of non-ionic surfactants having an HLB ranging from 7 to 17 and chosen from ethoxylated and / or propoxylated fatty alcohols,

[0187] - from 0.001 to 10% by weight, preferably from 0.005 to 5% by weight, preferably from 0.005 to 1% by weight, of cellulose compound(s), relative to the total weight of the lubricating composition.

[0188] According to one embodiment, the lubricating composition according to the invention comprises water and:

[0189] - from 0.05 to 40% by weight, preferably from 0.1 to 30% by weight, preferably from 0.15 to 15% by weight, of PAG chosen from copolymers comprising ethylene oxide units and propylene oxide units,

[0190] - from 0.001 to 15% by weight, preferably from 0.002 to 10% by weight, from 0.002 to 1% by weight, of non-ionic surfactants having an HLB ranging from 7 to 17 and chosen from ethoxylated and / or propoxylated fatty alcohols,

[0191] - from 0.001 to 10% by weight, preferably from 0.005 to 5% by weight, preferably from 0.005 to 1% by weight, of cellulose compound(s) chosen from hydroxyalkylcelluloses where the alkyl groups contain from 1 to 4 carbon atoms, relative to the total weight of the lubricating composition.

[0192] According to one embodiment, the lubricating composition according to the invention comprises water and:

[0193] - from 0.05 to 40% by weight, preferably from 0.1 to 30% by weight, preferably from 0.15 to 15% by weight, of PAG(s) chosen from copolymers comprising ethylene oxide units and propylene oxide units, the PAG(s) having a molecular mass ranging from 900 to 3000 g / mol,

[0194] - from 0.001 to 15% by weight, preferably from 0.002 to 10% by weight, from 0.002 to 1% by weight, of non-ionic surfactants having an HLB ranging from 7 to 17 and chosen

[0195] 19

[0196] 6086079v2 among ethoxylated and / or propoxylated fatty alcohols, said alkoxylated fatty alcohols having a molar mass ranging from 100 to 850 g / mol,

[0197] - from 0.001 to 10% by weight, preferably from 0.005 to 5% by weight, preferably from 0.005 to 1% by weight, of cellulose compound(s) chosen from hydroxyalkylcelluloses where the alkyl groups contain from 1 to 4 carbon atoms, relative to the total weight of the lubricating composition.

[0198] According to one embodiment, the lubricating composition according to the invention comprises water and:

[0199] - from 0.05 to 40% by weight, preferably from 0.1 to 30% by weight, preferably from 0.15 to 15% by weight, of PAG(s) chosen from copolymers comprising ethylene oxide units and propylene oxide units, the PAG(s) having a molecular mass ranging from 900 to 3000 g / mol,

[0200] - from 0.001 to 15% by weight, preferably from 0.002 to 10% by weight, from 0.002 to 1% by weight, of non-ionic surfactants having an HLB ranging from 7 to 17 and chosen from ethoxylated and / or propoxylated fatty alcohols, said alkoxylated fatty alcohols having a molar mass ranging from 100 to 850 g / mol,

[0201] - from 0.001 to 10% by weight, preferably from 0.005 to 5% by weight, preferably from 0.005 to 1% by weight, of cellulose compound(s) chosen from hydroxyalkylcelluloses where the alkyl groups contain from 1 to 4 carbon atoms,

[0202] - at least 30% by weight of water, preferably at least 40% by weight of water, preferably at least 45% by weight of water,

[0203] - optionally: o from 0.01 to 10% by weight, preferably from 0.01 to 5% by weight, preferably from 0.05 to 5% by weight, of acid(s), and o from 0.01 to 10% by weight, preferably from 0.01 to 5% by weight, preferably from 0.05 to 5% by weight, of base(s), relative to the total weight of the lubricating composition.

[0204] According to one embodiment, the lubricating composition according to the invention comprises water and:

[0205] - from 0.05 to 40% by weight, preferably from 0.1 to 30% by weight, preferably from 0.15 to 15% by weight, of PAG(s) chosen from copolymers comprising ethylene oxide units and propylene oxide units, the PAG(s) having a molecular mass ranging from 900 to 1500 g / mol,

[0206] 20

[0207] 6086079v2 - from 0.001 to 15% by weight, preferably from 0.002 to 10% by weight, from 0.002 to 1% by weight, of non-ionic surfactants having an HLB ranging from 7 to 17 and chosen from ethoxylated and / or propoxylated fatty alcohols, said alkoxylated fatty alcohols having a molar mass ranging from 100 to 850 g / mol,

[0208] - from 0.001 to 10% by weight, preferably from 0.005 to 5% by weight, preferably from 0.005 to 1% by weight, of cellulose compound(s) chosen from hydroxyalkylcelluloses where the alkyl groups contain from 1 to 4 carbon atoms,

[0209] - at least 30% by weight of water, preferably at least 40% by weight of water, preferably at least 45% by weight of water,

[0210] - optionally: o from 0.01 to 20% by weight, preferably from 0.01 to 15% by weight, preferably from 0.05 to 15% by weight, of aliphatic acid(s) comprising from 4 to 15 carbon atoms, and o from 0.01 to 25% by weight, preferably from 0.01 to 20% by weight, preferably from 0.05 to 20% by weight, of alkanolamine(s), relative to the total weight of the lubricating composition.

[0211] According to one embodiment, when the composition is a ready-to-use composition, it comprises: from 0.05 to 15% by weight, preferably from 0.05 to 10% by weight, preferably from 0.1 to 5% by weight, of PAG chosen from copolymers comprising ethylene oxide units and propylene oxide units, from 0.001 to 5% by weight, preferably from 0.002 to 1% by weight, preferably from 0.002 to 0.5% by weight, of non-ionic surfactant(s) having an HLB ranging from 7 to 17 and chosen from ethoxylated and / or propoxylated fatty alcohols, from 0.005 to 5% by weight, preferably from 0.005 to 1% by weight, preferably from 0.005 to 0.5% by weight, of cellulose compound(s) chosen from hydroxyalkylcelluloses where the alkyl groups contain from 1 to 4 carbon atoms, at least 60% by weight of water, preferably at least 70% by weight of water, preferably at least 80% by weight of water, optionally: o from 0.01 to 10% by weight, preferably from 0.01 to 5% by weight, preferably from 0,05 to 5% by weight, of aliphatic acid(s), and o from 0.01 to 15% by weight, preferably from 0.01 to 10% by weight, preferably from 0.05 to 5% by weight, of alkanolamine(s),

[0212] 21

[0213] 6086079v2 relative to the total weight of the lubricating composition.

[0214] According to one embodiment, when the composition is a composition to be diluted (concentrated), it comprises: from 0.5 to 20% by weight, preferably from 1 to 20% by weight, preferably from 2 to 15% by weight, of PAG chosen from copolymers comprising ethylene oxide units and propylene oxide units, from 0.01 to 10% by weight, preferably from 0.05 to 1% by weight, preferably from 0.05 to 0.5% by weight, of non-ionic surfactant(s) having an HLB ranging from 7 to 17 and chosen from ethoxylated and / or propoxylated fatty alcohols, from 0.05 to 10% by weight, preferably from 0.05 to 5% by weight, preferably from 0.1 to 1% by weight, of compound(s) cellulose(s) chosen from hydroxyalkylcelluloses where the alkyl groups contain from 1 to 4 carbon atoms, at least 30% by weight of water, preferably at least 40% by weight of water, preferably at least 45% by weight of water, optionally: o from 0.5 to 20% by weight, preferably from 0.5 to 15% by weight,preferably from 1 to 15% by weight of aliphatic acid(s), and o from 0.5 to 25% by weight, preferably from 0.5 to 20% by weight, preferably from 1 to 20% by weight, of alkanolamine(s), relative to the total weight of the lubricating composition.,

[0215] According to one embodiment, when the composition is a ready-to-use composition, it comprises: from 0.05 to 15% by weight, preferably from 0.05 to 10% by weight, preferably from 0.1 to 5% by weight, of PAG chosen from copolymers comprising ethylene oxide units and propylene oxide units, the PAG(s) having a molecular mass ranging from 900 to 1500 g / mol, from 0.001 to 5% by weight, preferably from 0.002 to 1% by weight, preferably from 0.002 to 0.5% by weight, of non-ionic surfactant(s) having an HLB ranging from 7 to 17 and chosen from ethoxylated and / or propoxylated fatty alcohols, said alkoxylated fatty alcohols having a molar mass ranging from 100 to 850 g / mol, from 0.005 to 5% by weight, preferably from 0.005 to 1% by weight, preferably from 0.005 to 0.5% by weight, of cellulose compound(s) chosen from hydroxyalkylcelluloses where the alkyl groups contain from 1 to 4 carbon atoms,

[0216] 22

[0217] 6086079v2 at least 60% by weight of water, preferably at least 70% by weight of water, preferably at least 80% by weight of water, optionally: o from 0.01 to 10% by weight, preferably from 0.01 to 5% by weight, preferably from 0.05 to 5% by weight, of aliphatic acid(s), and o from 0.01 to 15% by weight, preferably from 0.01 to 10% by weight, preferably from 0.05 to 5% by weight, of alkanolamine(s), relative to the total weight of the lubricating composition.

[0218] According to one embodiment, when the composition is a composition to be diluted (concentrated), it comprises: from 0.5 to 20% by weight, preferably from 1 to 20% by weight, preferably from 2 to 15% by weight, of PAG chosen from copolymers comprising ethylene oxide units and propylene oxide units, the PAG(s) having a molecular mass ranging from 900 to 1500 g / mol, from 0.01 to 10% by weight, preferably from 0.05 to 1% by weight, preferably from 0.05 to 0.5% by weight, of non-ionic surfactant(s) having an HLB ranging from 7 to 17 and chosen from ethoxylated and / or propoxylated fatty alcohols, said alkoxylated fatty alcohols having a molar mass ranging from 100 to 850 g / mol, from 0.05 to 10% by weight, preferably from 0.05 to 5% by weight, preferably from 0.1 to 1% by weight, of cellulose compound(s) chosen from hydroxyalkylcelluloses where the alkyl groups contain from 1 to 4 carbon atoms, at least 30% by weight of water,preferably at least 40% by weight of water, preferably at least 45% by weight of water, optionally: o from 0.5 to 20% by weight, preferably from 0.5 to 15% by weight, preferably from 1 to 15% by weight, of aliphatic acid(s), and o from 0.5 to 25% by weight, preferably from 0.5 to 20% by weight, preferably from 1 to 20% by weight, of alkanolamine(s), relative to the total weight of the lubricating composition.,

[0219] Preferably, the lubricating composition according to the invention is in the form of a solution. Indeed, the ingredients of the lubricating composition are preferably soluble or solubilized in water.

[0220] 23

[0221] 6086079v2 For the purposes of the present invention, a “solution” is distinguished from an emulsion or a dispersion which may contain several phases or which may contain non-solubilized particles.

[0222] According to one embodiment, the aqueous lubricating composition according to the invention is not an emulsion.

[0223] The lubricating composition according to the invention can be prepared by simply mixing the ingredients, according to any methods known to those skilled in the art to obtain a solution.

[0224] Applications

[0225] The invention also relates to the use of the lubricating composition according to the invention, as a fluid for metalworking, in particular for machining (turning, milling, drilling, sawing, threading among others), forming, cutting, stamping or even rolling of metal parts, typically steel parts, in particular stainless steel.

[0226] It should be noted that the lubricating composition will be advantageously diluted with water before its use as a fluid for metalworking.

[0227] The present invention also relates to a method for lubricating at least one metal surface of a metal part, in particular aluminum or steel, comprising bringing the lubricating composition into contact with said metal surface.

[0228] Preferably, the metal surface is a steel surface.

[0229] It should be noted that the lubrication process may comprise a step of diluting the lubricating composition with water before the step of bringing the lubricating composition (thus diluted) into contact with said metal surface.

[0230] The invention also relates to a metalworking method, comprising at least one metalworking step, preferably chosen from a machining, forming, cutting, stamping or rolling step, carried out on a metal part coated on at least part of its surface with the lubricating composition according to the invention.

[0231] Preferably, the metalworking method comprises at least one preliminary step of lubricating at least a portion of said metal surface, comprising contacting the lubricating composition with at least a portion of said metal surface.

[0232] 24

[0233] 6086079v2 The inventors have in fact discovered that a composition comprising both a PAG, a non-ionic surfactant and a cellulose compound makes it possible to obtain a composition having improved lubricity properties, in particular this association makes it possible to obtain an improved capacity to be eliminated after the metalworking step.

[0234] The PAG(s) used in the aforementioned use may have one or more of the characteristics and preferences described above in the context of the lubricating composition according to the invention.

[0235] The non-ionic surfactant(s) used in the aforementioned use may have one or more of the characteristics and preferences described above in the context of the lubricating composition according to the invention.

[0236] The cellulose compound(s) used in the aforementioned use may have one or more of the characteristics and preferences described above in the context of the lubricating composition according to the invention.

[0237] The lubricating composition resulting from the aforementioned use may have one or more of the characteristics and preferences described above in the context of the lubricating composition according to the invention.

[0238] The invention also relates to the use of the lubricating composition according to the invention for improving the eco-performance of a process comprising at least one metalworking step, in which the eco-performance is chosen from: reducing the energy consumed for implementing the process, increasing the productivity of the process, improving the safety of the operators of the process, the eco-performance being in particular chosen from improving the safety of the operators of the process.

[0239] The metalworking stage may include machining (turning, milling, drilling, sawing, threading among others), forming, cutting, stamping or even rolling of metal parts, the metal preferably being steel.

[0240] In other words, the lubricating composition according to the invention makes it possible to reduce the environmental impact of a process comprising at least one metalworking step.

[0241] EXAMPLES

[0242] 25

[0243] 6086079v2 In the remainder of this description, examples are given for the purpose of illustrating the present invention and are not intended in any way to limit its scope.

[0244] Example 1: Preparation of lubricating compositions

[0245] Two lubricating compositions were prepared. The following ingredients were used: PAG1 denotes a poly(alkylene glycol) comprising ethylene oxide (EO) and propylene oxide (PO) units in an EO / PO ratio of about 1 / 1, PAG1 being terminated with a butyl group at one end and a hydroxyl group at the other end, PAG1 having a molecular weight in the range of 900 to 1500 g / mol.

[0246] TA1 denotes ethoxylated and propoxylated fatty alcohol with an HLB of 12.

[0247] HEC denotes a hydroxyethylcellulose having a weight average molecular weight ranging from 700,000 to 1,500,000 Da. alkanolamine denotes one or more alkanolamines chosen from monoethanolamine (MEA), diethanolamine (DEA), triethanolamine (TEA), diglycolamine (DGA), monoisopropanolamine (MIPA), diisopropanolamine (DI PA), triisopropanolamine (Tl PA), methyldiethanolamine (MDEA), 2-amino-2-ethyl-1,3-propanediol, 2-amino-2-methyl-1-propanol and mixtures thereof. acids denotes a mixture comprising at least two acids chosen from 08-011 aliphatic monoacids, 08-011 aliphatic diacids, aromatic polyacids. additive package means a mixture of additives conventionally used in lubricating compositions for metalworking, including in particular an antifoam, a biocide and a benzotriazole type anticorrosion agent.

[0248] Table 1 gives details of the compositions tested; the percentages are percentages by weight relative to the total weight of the composition.

[0249] [Table 1]

[0250] 6086079v2

[0251] Example 2: Evaluation of the formation of viscous residues

[0252] In this example, the ability of the compositions described in Example 1 to form viscous residues was compared.

[0253] For this test, the composition in Table 1 was diluted in water to 8%.

[0254] The test protocol is as follows with the following successive steps:

[0255] - initial :

[0256] • Pour 10 ml of dilution (8% TH40) into a cup

[0257] • Evaporate to constant weight 80°C (1 h 45)

[0258] - 1 er washing:

[0259] • Pour into a cup with dry extract (SE) of the initial, 10 ml of 8% TH40 dilution

[0260] • Wait 15 minutes in static mode (no mixing)

[0261] • Drain the excess

[0262] • Evaporate for 15 min at 80°C

[0263] Repeat this step N times until a significant residue is obtained on the reference formula according to the protocol below:

[0264] - N wash:

[0265] • Pour into a cup with ES of N-1 wash, 10 ml of 8% TH40 dilution

[0266] • Wait 15 minutes in static mode (no mixing)

[0267] • Drain the excess

[0268] • Evaporate for 15 min at 80°C

[0269] Once you have obtained this residue, proceed as follows:

[0270] Tl

[0271] 6086079v2 - pure water wash:

[0272] • Pour 10 ml of osmosis water into the cup with the ES from the Nth wash.

[0273] • Wait 15 minutes in static mode (no mixing)

[0274] • Drain the excess

[0275] • Evaporate for 15 min at 80°C

[0276] It was observed that after the final washing with pure water, for the comparative compositions CC1 and CC2, residues of polymers and minerals were still present in the cup whereas for the compositions according to the invention Cl 1 and CI2, no residue remained, the cup was clean.

[0277] As the results of this example show, the lubricating composition according to the invention makes it possible to avoid the formation of residues, in particular viscous residues of the dry polymer type (whitish deposit), during washing taking place after the metalworking step.

[0278] Example 3: Evaluation of anti-wear properties

[0279] The compositions described in Example 1 were evaluated in a 4-ball type anti-wear test.

[0280] For this test, the composition in Table 1 was diluted in water to 8%.

[0281] The anti-wear properties of lubricating compositions are evaluated by the 4-ball test according to the ASTM D2783 standard adapted with the following parameters:

[0282] - speed close to 1500 rpm,

[0283] - room temperature, approximately 20°C,

[0284] - 1 minute charging time.

[0285] The extreme pressure measurement is carried out by rotating a stainless steel ball on three stainless steel balls held stationary, the 4 balls being entirely covered with a film of lubricant. A load is applied to the balls and gradually increased (every minute according to the above parameters) until the balls weld together. The balls are changed before each increase in load.

[0286] The wear diameter in mm is shown in Table 2 for a load of 100 kg, 120 kg and 140 kg.

[0287] [Table 2]

[0288] 28

[0289] 6086079v2

[0290] As shown by the results in Table 2, the composition according to the invention Cl 1 has a smaller wear diameter and a higher weld load and therefore better anti-wear properties than the composition outside the invention CC1. Similarly, the composition according to the invention CI2 has a smaller wear diameter and a higher weld load and therefore better anti-wear properties than the composition outside the invention CC2. Thus, with the same cellulose content, the composition according to the invention makes it possible to improve the anti-wear properties.

[0291] 29

[0292] 6086079v2

Claims

CLAIMS 1. Lubricating composition comprising water and: from 0.05 to 40% by weight of polyalkylene glycol, from 0.001 to 15% by weight of non-ionic surfactant(s), from 0.001 to 30% by weight of at least one cellulose compound, relative to the total weight of the lubricating composition.

2. Lubricating composition according to claim 1, further comprising at least one anti-corrosion system comprising at least one acid and at least one base, at least one base preferably being chosen from amines, advantageously from alkanolamines.

3. Lubricating composition according to any one of claims 1 to 2, said composition being a ready-to-use composition comprising water and: from 0.05 to 15% by weight, preferably from 0.05 to 10% by weight, preferably from 0.1 to 5% by weight, of polyalkylene glycol, from 0.001 to 5% by weight, preferably from 0.002 to 1% by weight, preferably from 0.002 to 0.5% by weight, of non-ionic surfactant(s), from 0.005 to 5% by weight, preferably from 0.005 to 1% by weight, preferably from 0.005 to 0.5% by weight, of at least one cellulose compound, relative to the total weight of the lubricating composition.

4. Lubricating composition according to any one of claims 1 to 2, said composition being a concentrated composition comprising water and: from 0.5 to 20% by weight, preferably from 1 to 20% by weight, preferably from 2 to 15% by weight, of polyalkylene glycol, from 0.01 to 10% by weight, preferably from 0.05 to 1% by weight, preferably from 0.05 to 0.5% by weight, of non-ionic surfactant(s), from 0.05 to 10% by weight, preferably from 0.05 to 5% by weight, preferably from 0.1 to 1% by weight, of at least one cellulose compound, relative to the total weight of the lubricating composition.

5. Lubricating composition according to any one of claims 1 to 4, in which said at least one cellulose compound is chosen from alkylcelluloses, dialkylcelluloses, hydroxyalkylcelluloses, carboxyalkylcelluloses, and their 30 6086079v2 mixtures, preferably among hydroxyalkylcelluloses, advantageously said at least one cellulose compound is a hydroxyethylcellulose.

6. Lubricating composition according to any one of claims 1 to 5, in which the polyalkylene glycol(s) are chosen from poly(ethylene glycol), poly(propylene glycol), copolymers comprising ethylene oxide units and propylene oxide units, and mixtures thereof, preferably from block copolymers comprising ethylene oxide units and propylene oxide units and mixtures thereof, more preferably from ethylene oxide-propylene oxide diblock copolymers and propylene oxide-ethylene oxide-propylene oxide triblock copolymers and mixtures thereof.

7. Lubricating composition according to any one of claims 1 to 6, wherein at least one polyalkylene glycol of the lubricating composition, preferably all the polyalkylene glycols of the lubricating composition, has one or more of the following characteristics: - a molecular mass ranging from 500 to 10000 g / mol, preferably from 800 to 5000 g / mol, more preferably from 900 to 3000 g / mol, and / or - a viscosity at 40°C ranging from 10 to 1000 mm 2 / s, preferably 15 to 500 mm 2 / s, preferably from 20 to 400 mm 2 / s.

8. Lubricating composition according to any one of claims 1 to 7, in which at least one non-ionic surfactant, preferably all non-ionic surfactants, has one or more of the following characteristics: - at least one surfactant has a hydrophilic-lipophilic balance (HLB) ranging from 7 to 17, and / or - at least one surfactant has a molar mass ranging from 130 to 850 g / mol, preferably from 140 to 700 g / mol, more preferably from 150 to 500 g / mol, and / or - at least one surfactant is chosen from alkoxylated fatty alcohols, sorbitan esters, alkylpolyglycosides, and mixtures thereof, preferably from alkoxylated fatty alcohols, more preferably from ethoxylated and / or propoxylated fatty alcohols.

9. Lubricating composition according to any one of claims 1 to 3 and 5 to 8, said composition being a ready-to-use composition comprising: from 0.05 to 15% by weight, preferably from 0.05 to 10% by weight, preferably from 0.1 to 5% by weight, of polyalkylene glycol, 31 6086079v2 from 0.001 to 5% by weight, preferably from 0.002 to 1% by weight, preferably from 0.002 to 0.5% by weight, of non-ionic surfactant(s), from 0.005 to 5% by weight, preferably from 0.005 to 1% by weight, preferably from 0.005 to 0.5% by weight, of cellulose compound(s), at least 60% by weight of water, preferably at least 70% by weight of water, preferably at least 80% by weight of water, optionally: o from 0.01 to 10% by weight, preferably from 0.01 to 5% by weight, preferably from 0.05 to 5% by weight, of aliphatic acid(s), and o from 0.01 to 10% by weight, preferably 0.01 to 5% by weight, preferably 0.05 to 5% by weight, of base(s), relative to the total weight of the lubricating composition.

10. Lubricating composition according to any one of claims 1 to 3 and 5 to 9, said composition being a ready-to-use composition comprising water and: from 0.1 to 5% by weight of PAGs chosen from copolymers comprising ethylene oxide units and propylene oxide units, the PAGs having a molecular mass ranging from 900 to 3000 g / mol, from 0.002 to 0.5% by weight of alkoxylated fatty alcohols chosen from ethoxylated fatty alcohols, ethoxylated and proproxylated fatty alcohols and their mixture, said alkoxylated fatty alcohols having a molar mass ranging from 100 to 850 g / mol, from 0.005 to 0.5% by weight of hydroxyalkylcellulose where the alkyls have from 1 to 8 carbon atoms, from 0.05 to 10% by weight of aliphatic acid(s) containing from 4 to 15 carbon atoms, and from 0.05 to 10% by weight of alkanolamine(s) chosen from monoethanolamine, diethanolamine, triethanolamine, diglycolamine, monoisopropanolamine, diisopropanolamine,triisopropanolamine, methyldiethanol amine, 2-amino-2-ethyl-1,3-propanediol, 2-amino-2-methyl-1-propanol and mixtures thereof, relative to the total weight of the lubricating composition., 11. Lubricating composition according to any one of claims 1 to 2 and 4 to 8, said composition being a concentrated composition comprising: from 0.5 to 20% by weight, preferably from 1 to 20% by weight, preferably from 2 to 15% by weight, of polyalkylene glycol, 32 6086079v2 from 0.01 to 10% by weight, preferably from 0.05 to 1% by weight, preferably from 0.05 to 0.5% by weight, of non-ionic surfactant(s), from 0.05 to 10% by weight, preferably from 0.05 to 5% by weight, preferably from 0.1 to 1% by weight, of cellulose compound(s), at least 40% by weight of water, preferably at least 50% of water, optionally: i. from 0.5 to 20% by weight, preferably from 0.5 to 15% by weight, preferably from 1 to 15% by weight, of aliphatic acid(s), and ii. from 0.5 to 25% by weight, preferably from 0.5 to 20% by weight, preferably from 1 to 20% by weight, of base(s), relative to the total weight of the lubricating composition.

12. Lubricating composition according to any one of claims 1 to 2 and 4 to 8 or 11, said composition being a concentrated composition comprising water and: from 2 to 15% by weight of PAGs chosen from copolymers comprising ethylene oxide units and propylene oxide units, the PAGs having a molecular mass ranging from 900 to 3000 g / mol, from 0.05 to 0.5% by weight of alkoxylated fatty alcohols chosen from ethoxylated fatty alcohols, ethoxylated and proproxylated fatty alcohols and their mixture, said alkoxylated fatty alcohols having a molar mass ranging from 100 to 850 g / mol, from 0.1 to 1% by weight of hydroxyalkylcellulose where the alkyls have from 1 to 8 carbon atoms, from 1 to 20% by weight of acid(s) aliphatic(s) comprising from 4 to 15 carbon atoms, and from 2 to 30% by weight of alkanolamine(s) chosen from monoethanolamine, diethanolamine, triethanolamine, diglycolamine, monoisopropanolamine, diisopropanolamine, triisopropanolamine,methyldiethanol amine, 2-amino-2-ethyl-1,3-propanediol, 2-amino-2-methyl-1-propanol and mixtures thereof, relative to the total weight of the lubricating composition., 13. Lubricating composition according to any one of claims 1 to 12, having a mass ratio between the PAG(s), the non-ionic surfactant(s) and the cellulose compound(s) ranging from 3-10 / 0.01-1 / 0.1-1, preferably from 5-9 / 0.05-0.5 / 0.2-0.

8. 6086079v2 14. Use of the lubricating composition according to any one of claims 1 to 13, as a fluid for metalworking, in particular for machining, forming, cutting, stamping or rolling of metal parts, the metal preferably being steel.

15. Use of a lubricating composition according to any one of claims 1 to 13, for improving the eco-performance of a process comprising at least one metalworking step, in which the eco-performance is chosen from: reduction of the energy consumed for the implementation of the process, - increase in the productivity of the process, improvement of the safety of the operators of the process, preferably from improvement of the safety of the operators of the process. 6086079v2

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