COMPOSITION COMPRISING AN EXTRACT OF TARAXACUM OFFICINALE
The composition enhances oligosaccharide penetration from Taraxacum Officinale extract into skin using glycol and polyglyceryl monoester, improving skin radiance and texture, and offering a sustainable cosmetic solution.
Patent Information
- Application Number
- FR2023010244
- Authority / Receiving Office
- FR · FR
- Patent Type
- Utility models
- Current Assignee / Owner
- Filing Date
- 2023-09-27
- Publication Date
- 2025-10-17
- Estimated Expiration
- 2033-09-27
AI Technical Summary
Existing cosmetic compositions do not effectively enhance the penetration of oligosaccharides from Taraxacum Officinale extracts into keratinous substances like skin, and lack sustainable ingredients to reduce environmental impact.
A composition comprising Taraxacum Officinale extract, glycol, and polyglyceryl monoester of fatty acid, with specific ratios to enhance oligosaccharide penetration and improve skin radiance, tone, and texture, while using renewable and natural ingredients.
The composition increases oligosaccharide absorption into the skin, enhancing skin lightening and anti-pollution effects, and provides a more sustainable cosmetic solution.
Abstract
Description
Title of the invention: COMPOSITION COMPRISING AN EXTRACT OF TARAXACUM OFFICINALE Technical field
[0001] The present invention relates to a composition including an extract of Taraxacum Officinale, as well as a cosmetic method using the composition. STATE OF THE ART
[0002] The formulation of environmentally friendly cosmetic products, which are designed and developed with environmental issues in mind, is becoming a major objective in an effort to address global challenges.
[0003] It is therefore essential to provide more sustainable compositions, preparation processes and ingredients to address these environmental concerns.
[0004] In this context, it is important to develop new cosmetic compositions with a better carbon footprint, in particular by promoting the use of renewable raw materials and / or materials with a good naturalness index and / or materials of natural origin and, more particularly, materials of plant origin while reducing the use of compounds of petrochemical origin.
[0005] It is known that an extract of Taraxacum Officinale (dandelion) has certain useful functions for cosmetic applications. For example, JP-A-2016-88939 discloses that a dandelion extract can promote the generation of hyaluronic acid in the skin.
[0006] US-A-2017 / 0049692 discloses that Taraxacum Officinale includes fructan, and that a Taraxacum Officinale extract can reduce the buildup of oxidized proteins from environmental pollution, trapping them and, once removed, leaving an improved skin tone, complexion and texture.
[0007] WO 2001 / 66079 discloses a lotion (Example 6) including a herbal extract obtained from a mixture of plants including dandelion. DISCLOSURE OF THE INVENTION
[0008] There is a need for a composition which includes a Taraxacum Officinale extract and which can promote the effects on a keratinous substance, such as skin, provided by the Taraxacum Officinale extract, in particular those provided by the active ingredient included in the Taraxacum Officinale extract.
[0009] Thus, an objective of the present invention is to provide a composition which can promote the penetration of an oligosaccharide in a Taraxacum Officinale extract into a keratinous substance such as the skin.
[0010] The above object of the present invention can be achieved by a composition, preferably a cosmetic composition, and more preferably a cosmetic composition for the skin, comprising: a. at least one extract of Taraxacum Officinale; b. at least one glycol; and c. at least one polyglyceryl monoester of fatty acid, [0011 ] in which
[0012] the amount of the fatty acid polyglyceryl monoester of point (c) is greater than 0.2% by weight relative to the total weight of the composition.
[0013] The amount of the Taraxacum Officinale extract(s) of point (a) in the composition according to the present invention may be from 0.01% to 5% by weight, preferably from 0.05% to 3% by weight, and more preferably from 0.1% to 1% by weight, relative to the total weight of the composition.
[0014] The glycol of point (b) may be selected from the group consisting of propylene glycol, pentylene glycol and mixtures thereof.
[0015] The amount of the glycol(s) of point (b) in the composition according to the present invention may be from 0.1% to 20% by weight, preferably from 0.5% to 15% by weight, and more preferably from 1% to 10% by weight, relative to the total weight of the composition.
[0016] The fatty acid polyglyceryl monoester of point (c) may comprise 2 to 4 glycerol units.
[0017] The amount of the fatty acid polyglyceryl monoester(s) of point (c) in the composition according to the present invention may be from 0.3% to 10% by weight, preferably from 0.5% to 5% by weight, and more preferably from 1% to 3% by weight, relative to the total weight of the composition.
[0018] The composition according to the present invention may further comprise (d) water, preferably in an amount of 50% to 95% by weight, more preferably 60% to 93% by weight, and even more preferably 70% to 90% by weight, relative to the total weight of the composition.
[0019] The composition according to the present invention may further comprise (e) at least one oil.
[0020] The oil of point (e) can be selected from ester oils.
[0021] The amount of the oil(s) of point (e) in the composition according to the present invention may be from 0.01% to 10% by weight, preferably from 0.05% to 5% by weight, and more preferably from 0.1% to 1% by weight, relative to the total weight of the composition.
[0022] The composition according to the present invention may further comprise (f) at least one anionic surfactant.
[0023] The anionic surfactant of point (f) may be selected from surfactants amino acids.
[0024] The amount of the anionic surfactant(s) of point (f) in the composition according to the present invention may be from 0.01% to 10% by weight, preferably from 0.05% to 5% by weight, and more preferably from 0.1% to 1% by weight, relative to the total weight of the composition.
[0025] The present invention also relates to a cosmetic process for a keratinous substance such as the skin, comprising: applying the composition according to the present invention to the keratinous substance.
[0026] The present invention also relates to a use of a combination of
[0027] (b) at least one glycol; and
[0028] (c) at least one polyglyceryl monoester of fatty acid,
[0029] in a composition comprising
[0030] (a) at least one extract of Taraxacum Officinale;
[0031] in which
[0032] the amount of the polyglyceryl monoester of fatty acid of point (c) is greater than 0.2% by weight relative to the total weight of the composition
[0033] in order to enhance the penetration of an oligosaccharide in the Taraxacum Officinale extract of point (a) into a keratinous substance such as the skin. Best mode for carrying out the invention
[0034] After careful research, the inventors have discovered that it is possible to provide a composition which can promote the absorption of the oligosaccharide in an extract of Taraxacum Officinale into a keratinous substance such as the skin.
[0035] Thus, the composition according to the present invention comprises: a. at least one extract of Taraxacum Officinale; b. at least one glycol; and c. at least one polyglyceryl monoester of fatty acid,
[0036] wherein
[0037] the amount of the fatty acid polyglyceryl monoester of point (c) is greater than 0.2% by weight relative to the total weight of the composition.
[0038] The Taraxacum Officinale (dandelion) extract of point (a), preferably a Taraxacum Officinale rhizome or root extract, includes an oligosaccharide such as oligofructan. The oligofructan may be linear or branched. The linear oligofructan may be based on inulin and levan. The branched fructan may be based on graminans. The oligosaccharide such as oligofructan may have a degree of polymerization of 2 to 26.
[0039] The composition according to the present invention can increase the amount of oligosaccharide, such as oligofructan, penetrating into a keratinous substance. such as skin. In particular, the composition according to the present invention can enhance the absorption through the skin or skin penetration of the oligosaccharide included in the Taraxacum Officinale extract, preferably a rhizome or root extract of Taraxacum Officinale.
[0040] The increased amount of oligosaccharide absorbed by a keratinous substance such as skin can enhance the cosmetic effects, on the keratinous substance such as skin, provided by the oligosaccharide.
[0041] An extract of Taraxacum Officinale is known to improve skin radiance, tone and texture. Therefore, the composition according to the present invention can provide enhanced improving effects on skin radiance, tone and texture. In addition, the composition according to the present invention can enhance the skin lightening effects provided by the extract of Taraxacum Officinale.
[0042] In addition, an extract of Taraxacum Officinale is known to function as an anti-pollution agent or free radical scavenger (antioxidant). Therefore, the composition according to the present invention can provide enhanced protection of a keratinous substance such as skin against environmental pollution or oxidation.
[0043] Accordingly, the composition according to the present invention can provide enhanced skin care effects, particularly enhanced skin lightening effects.
[0044] Hereinafter, the present invention will be explained in more detail. [Composition]
[0045] (Extract of Taxacum Officinale)
[0046] The composition according to the present invention comprises (a) at least one Taraxacum Officinale extract. Two or more Taraxacum Officinale extracts may be used in combination. Thus, a single type of Taraxacum Officinale extract or a combination of different types of Taraxacum Officinale extracts may be used.
[0047] Taraxacum Officinale, i.e. dandelion, is a perennial flowering herb of the dandelion genus in the Asteraceae family (syn. Compositae). Dandelion is well known for its yellow flower heads that develop into round balls of numerous silvery tufted fruits that disperse in the wind. Examples of Taraxacum Officinale that can be used include those that are commercially available and cultivated or collected from the wild.
[0048] The Taraxacum Officinale extract of point (a), preferably a Taraxacum Officinale rhizome or root extract, may include an oligosaccharide such as oligofructan. The oligofructan may be linear or branched. The linear oligofructan may be based on inulin and levan. The branched oligofructan may be based on graminans. The oligosaccharide such as oligofructan may have a degree of polyme- rization from 2 to 26.
[0049] The Taraxacum Officinale extract of point (a) can be obtained from natural plants or plant tissue cultures of Taraxacum Officinale cells.
[0050] The Taraxacum Officinale extract of point (a) can be obtained by extraction of Taraxacum Officinale, and preferably from the rhizome or root of Taraxacum Officinale.
[0051] The term "extract" herein includes an extract in any form, such as a liquid or a powder, which can be obtained by any extraction process. The extract can be obtained by an extraction process, with or without dilution, purification or drying. Specifically, the Taraxacum Officinale extract of point (a) can be produced and used in the form of a dried powder after extraction.
[0052] The extraction method for producing the Taraxacum Officinale extract of item (a) is not particularly limited, and the extraction may be carried out according to a method commonly used in the art. Non-limiting examples of the extraction method include a hydrothermal extraction method, an ultrasonic extraction method, a filtration method, a reflux extraction method, and the like. These extraction methods may be carried out alone, or two or more methods may be used in combination. Furthermore, in order to obtain a high-purity extract, the extract may be extracted one or more times by the same method.
[0053] The type of solvent used to produce the Taraxacum Officinale extract of item (a) is not particularly limited, and any solvent known in the art may be used. For example, one or more solvents selected from the group consisting of water, alcohols having 1 to 4 carbon atoms, and a mixture thereof may be used. More specifically, a mixture of water and ethanol may be used as the extraction solvent.
[0054] The Taraxacum Officinale extract of item (a), preferably a Taraxacum Officinale rhizome or root extract, can improve the brightness, tone and texture of a keratinous substance such as skin. Therefore, the Taraxacum Officinale extract of item (a), preferably the Taraxacum Officinale rhizome or root extract, can provide skin-lightening effects.
[0055] In addition, (a) the Taraxacum Officinale extract, preferably a Taraxacum Officinale rhizome or root extract, can function as an anti-pollution agent or free radical scavenger (antioxidant), and therefore, it can protect a keratinous substance such as skin against environmental pollution or oxidation.
[0056] As the Taraxacum Officinale extract of point (a), preferably a rhizome or root extract of Taraxacum Officinale, a commercial product, such as Apolluskin® sold by Silab in France, can be used.
[0057] The amount of the Taraxacum Officinale extract(s) of point (a) in the composition according to the present invention may be 0.01% by weight or more, preferably 0.05% by weight or more, and more preferably 0.1% by weight or more, relative to the total weight of the composition.
[0058] The amount of the Taraxacum Officinale extract(s) of point (a) in the composition according to the present invention may be 5% by weight or less, preferably 3% by weight or less, and more preferably 1% by weight or less, relative to the total weight of the composition.
[0059] The amount of the Taraxacum Officinale extract(s) of point (a) in the composition according to the present invention may be from 0.01% to 5% by weight, preferably from 0.05% to 3% by weight, and more preferably from 0.1% to 1% by weight, relative to the total weight of the composition.
[0060] (Glycol)
[0061] The composition according to the present invention comprises (b) at least one glycol. Two or more glycols may be used in combination. Thus, a single type of glycol or a combination of different types of glycols may be used.
[0062] The glycol of point (b) can be selected from aliphatic hydrocarbons having 2 hydroxy groups.
[0063] It may be preferable that the glycol of point (b) is selected from linear or branched, saturated or unsaturated aliphatic hydrocarbons having 2 hydroxy groups. The glycol of point (b) may or may not have at least one substituent selected from halogen atoms such as fluorine, chlorine and bromine atoms.
[0064] The glycol of point (b) may have at least one heteroatom in the backbone thereof. The heteroatom is preferably selected from O, N and S. Preferably, the heteroatom is O.
[0065] Examples of the glycol of item (b) include C3-C6 glycols such as propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, diethylene glycol, dipropylene glycol and a mixture thereof.
[0066] It is preferable that the glycol of point (b) is selected from the group consisting of propylene glycol, pentylene glycol and a mixture thereof.
[0067] It is preferable that the glycol of point (b) is pentylene glycol.
[0068] The quantity of the glycol(s) of point (b) in the composition according to the present invention may be 0.1% by weight or more, preferably 0.5% by weight or more, and more preferably 1% by weight or more, relative to the total weight of the composition.
[0069] The amount of the glycol(s) of point (b) in the composition according to the present invention may be 20% by weight or less, preferably 15% by weight or less, and more preferably 10% by weight or less, relative to the total weight of the composition.
[0070] The amount of the glycol(s) of point (b) in the composition according to the present invention may be from 0.1% to 20% by weight, preferably from 0.5% to 15% by weight, and more preferably from 1% to 10% by weight, relative to the total weight of the composition.
[0071] (Polyglyceryl monoester of fatty acid)
[0072] The composition according to the present invention comprises (c) at least one polyglyceryl fatty acid monoester. Two or more polyglyceryl fatty acid monoesters may be used in combination. Thus, a single type of polyglyceryl fatty acid monoester or a combination of different types of polyglyceryl fatty acid monoesters may be used.
[0073] It is preferable that the fatty acid polyglyceryl monoester of item (c) has a polyglycerol moiety derived from 2 to 8 glycerols, more preferably from 2 to 6 glycerols, and even more preferably from 2 to 4 glycerols.
[0074] The polyglyceryl fatty acid monoester of point (c) may have an HLB (Hydrophilic Lipophilic Balance) value of 7.0 to 16.0, preferably 8.0 to 15.0, and more preferably 9.0 to 14.0. If two or more polyglyceryl fatty acid monoesters are used, the HLB value is determined by the weighted average of the HLB values of all the polyglyceryl fatty acid monoesters.
[0075] The polyglyceryl monoester of fatty acid of point (c) may be selected from monoesters of a saturated or unsaturated acid, comprising from 4 to 22 carbon atoms, preferably from 6 to 20 carbon atoms, and more preferably from 8 to 18 carbon atoms, such as lauric acid, oleic acid, stearic acid, isostearic acid, capric acid, caprylic acid and myristic acid.
[0076] The amount of the polyglyceryl monoester(s) of fatty acid of point (c) in the composition according to the present invention is 0.2% by weight relative to the total weight of the composition.
[0077] The amount of the fatty acid polyglyceryl monoester(s) of point (c) in the composition according to the present invention may be 0.3% by weight or more, preferably 0.5% by weight or more, and more preferably 1% by weight or more, relative to the total weight of the composition.
[0078] The amount of the fatty acid polyglyceryl monoester(s) of point (c) in the composition according to the present invention may be 10% by weight or less, preferably 5% by weight or less, and more preferably 3% by weight or less, relative to the total weight of the composition.
[0079] The amount of the fatty acid polyglyceryl monoester(s) of point (c) in the composition according to the present invention may range from 0.3% to 10% by weight, preferably from 0.5% to 5% by weight, more preferably from 1% to 3% by weight. weight, relative to the total weight of the composition.
[0080] It is preferable that the composition according to the present invention comprises at least two polyglyceryl fatty acid monoesters, as first and second polyglyceryl fatty acid monoesters.
[0081] First monoester of polyglyceryl fatty acid:
[0082] The first fatty acid polyglyceryl monoester may have an HLB value of more than 8.0 and less than 17.0, preferably 8.5 to 16.0, and more preferably 9.0 to 15.0.
[0083] It is preferable that the first fatty acid polyglyceryl monoester comprises 2 to 4 glycerol units.
[0084] The fatty acid for the fatty acid moiety of the first fatty acid polyglyceryl monoester may comprise 12 or fewer carbon atoms, preferably 11 or fewer carbon atoms, and more preferably 10 or fewer carbon atoms. The fatty acid for the fatty acid moiety of the first fatty acid polyglyceryl monoester may comprise 4 or more carbon atoms, preferably 6 or more carbon atoms, and more preferably 8 or more carbon atoms. The fatty acid for the fatty acid moiety of the first fatty acid polyglyceryl monoester may have from 4 to 12 carbon atoms, preferably from 6 to 11 carbon atoms, and more preferably from 8 to 10 carbon atoms.
[0085] The fatty acid for the fatty acid moiety of the fatty acid polyglyceryl monoester may be saturated or unsaturated, and may be selected from caprylic acid, capric acid, and lauric acid.
[0086] The first fatty acid polyglyceryl monoester may be selected from the group consisting of PG2 caprate (HLB: 9.5), PG4 caprylate (HLB: 14), PG4 laurate (HLB: about 14), PG4 caprate (HLB: 14), PG5 myristate (HLB: 15.4), PG5 stearate (HLB: 15), PG6 caprylate (HLB: 14.6), PG6 caprate (HLB: 13.1), PG6 laurate (HLB: 14.1), PG10 laurate (HLB: 15.2), PG10 myristate (HLB: 14.9), PG10 stearate (HLB: 14.1), PG10 isostearate (HLB: 13.7), PG10 oleate (HLB: 13.0), PG10 cocoate (HLB: 16), and a mixture thereof.
[0087] It is preferred that the first fatty acid polyglyceryl monoester be selected from the group consisting of PG2 caprate (HLB: 9.5), PG4 caprylate (HLB: 14), PG4 laurate (HLB: about 14), PG4 caprate (HLB: 14), and a mixture thereof.
[0088] The amount of the first fatty acid polyglyceryl monoester in the composition according to the present invention may be 0.1% by weight or more, preferably 0.2% by weight or more, and more preferably 0.3% by weight or more, relative to the total weight of the composition.
[0089] The amount of the first fatty acid polyglyceryl monoester in the composition according to the present invention may be 5% by weight or less, preferably 4% by weight or less, and more preferably 3% by weight or less, relative to the total weight of the composition.
[0090] The amount of the first fatty acid polyglyceryl monoester in the composition according to the present invention may range from 0.1% to 6% by weight, preferably from 0.2% to 4% by weight, and more preferably from 0.3% to 2% by weight, relative to the total weight of the composition.
[0091] Second monoester of polyglyceryl fatty acid:
[0092] The second fatty acid polyglyceryl monoester may have an HLB value of 4.0 to 8.0, preferably 4.5 to 7.5, and more preferably 5.0 to 7.0.
[0093] It is preferable that the second fatty acid polyglyceryl monoester comprises 2 to 4 glycerol units, preferably 2 or 3 glycerol units, and more preferably 2 glycerol units.
[0094] The fatty acid for the fatty acid moiety of the second fatty acid polyglyceryl monoester may comprise 14 or more carbon atoms, preferably 16 or more carbon atoms, and more preferably 18 or more carbon atoms. The fatty acid for the fatty acid moiety of the second fatty acid polyglyceryl monoester may comprise 24 or fewer carbon atoms, preferably 22 or fewer carbon atoms, and more preferably 20 or fewer carbon atoms. The fatty acid for the fatty acid moiety of the second fatty acid polyglyceryl monoester may have from 14 to 24, preferably from 16 to 22, and more preferably from 18 to 20 carbon atoms.
[0095] The fatty acid for the fatty acid moiety of the second fatty acid polyglyceryl monoester may be saturated or unsaturated, and may be selected from myristic acid, stearic acid, isostearic acid, and oleic acid.
[0096] The second fatty acid polyglyceryl monoester may be selected from the group consisting of PG2 stearate (HLB: 5.0), PG2 isostearate (HLB: 5.5), PG2 oleate (HLB: 7), and a mixture thereof.
[0097] The amount of the second fatty acid polyglyceryl monoester in the composition according to the present invention may be 0.01% by weight or more, preferably 0.05% by weight or more, and more preferably 0.1% by weight or more, relative to the total weight of the composition.
[0098] The amount of the second fatty acid polyglyceryl monoester in the composition according to the present invention may be 10% by weight or less, preferably 5% by weight or less, and more preferably 1% by weight or less, relative to the total weight of the composition.
[0099] The amount of the second fatty acid polyglyceryl monoester in the composition according to the present invention may range from 0.01% to 10% by weight, preferably 0.05% to 5% by weight, more preferably 0.1% to 1% by weight, relative to the total weight of the composition.
[0100] (Water)
[0101] The composition according to the present invention may comprise (d) water.
[0102] The water of point (d) may constitute an aqueous phase which may be, for example, a continuous phase in the composition according to the present invention.
[0103] The amount of water of point (d) may be 50% by weight or more, preferably 60% by weight or more, and more preferably 70% by weight or more, relative to the total weight of the composition.
[0104] The amount of water of point (d) may be 95% by weight or less, preferably 93% by weight or less, and more preferably 90% by weight or less, relative to the total weight of the composition.
[0105] The amount of water of point (d) may be from 50% to 95% by weight, preferably from 60% to 93% by weight, and more preferably from 70% to 90% by weight, relative to the total weight of the composition.
[0106] (Oil)
[0107] The composition according to the present invention may comprise (e) at least one oil. Two or more oils may be used in combination. Thus, a single type of oil or a combination of different types of oils may be used.
[0108] Herein, the term "oil" means a fatty compound or substance which is in the form of a liquid or a paste (not solid) at room temperature (25°C) under atmospheric pressure (760 mmHg). As oils, those generally used in cosmetics can be used alone or in combination. These oils can be volatile or non-volatile.
[0109] The oil of point (e) may constitute a fatty phase which may be, for example, discontinuous phases or dispersed phases in the composition according to the present invention.
[0110] The oil of item (e) may be a non-polar oil such as a hydrocarbon oil, a silicone oil or the like; a polar oil such as an oil of vegetable or animal origin and an ester oil or an ether oil; or a mixture thereof.
[0111] The oil of point (e) may be selected from the group consisting of oils of vegetable or animal origin, synthetic oils, silicone oils, hydrocarbon oils and fatty alcohols.
[0112] As examples of vegetable oils, mention may be made, for example, of linseed oil, camellia oil, macadamia nut oil, corn oil, mink oil, olive oil, avocado oil, sasanqua oil, castor oil, safflower oil, jojoba oil, sunflower oil, almond oil, rapeseed oil, sesame oil, soybean, peanut oil, and mixtures thereof.
[0113] Examples of animal oils include squalene and squalane, for example.
[0114] Examples of synthetic oils include alkane oils such as isododecane and isohexadecane, ester oils, ether oils, and artificial triglycerides.
[0115] The ester oils are preferably liquid esters of linear or branched C1-C26 saturated or unsaturated aliphatic monoacids or polyacids and linear or branched C1-C26 saturated or unsaturated aliphatic monoalcohols or polyalcohols, the total number of carbon atoms of the esters being greater than or equal to 10.
[0116] Preferably, for the monoalcohol esters, at least one of the alcohol and the acid from which the esters of the present invention are derived is branched.
[0117] Among the monoesters of monoacids and monoalcohols, mention may be made of ethyl palmitate, ethylhexyl palmitate, isopropyl palmitate, dicaprylyl carbonate, alkyl myristates such as isopropyl myristate or ethyl myristate, isocetyl stearate, 2-ethylhexyl isonanoate, isononyl isonanoate, isodecyl neopentanoate and isostearyl neopentanoate.
[0118] Esters of C4-C22 dicarboxylic or tricarboxylic acids and C1-C22 alcohols, and esters of monocarboxylic, dicarboxylic or tricarboxylic acids and C4-C26 dihydroxy, trihydroxy, tetrahydroxy or pentahydroxy non-sugar alcohols may also be used.
[0119] Mention may in particular be made of: diethyl sebacate; isopropyl lauroyl sarcosinate; diisopropyl sebacate; bis(2-ethylhexyl) sebacate; dii-isopropyl adipate; di-n-propyl adipate; dioctyl adipate; bis(2-ethylhexyl) adipate; diisostearyl adipate; bis(2-ethylhexyl) maleate; triisopropyl citrate; triisocetyl citrate; triisostearyl citrate; glyceryl trilactate; glyceryl trioctanoate; trioctyldodecyl citrate; trioleyl citrate; neopentyl glycol diheptanoate; diethylene glycol diisononanoate.
[0120] As ester oils, esters and diesters of sugars of C6-C30 and preferably C12-C22 fatty acids can be used. It is recalled that the term "sugar" designates compounds based on oxygen-bearing hydrocarbons containing several alcohol functions, with or without aldehyde or ketone functions, and which comprise at least 4 carbon atoms. These sugars can be monosaccharides, oligosaccharides or polysaccharides.
[0121] Examples of suitable sugars which may be mentioned include sucrose, glucose, galactose, ribose, fucose, maltose, fructose, mannose, arabinose, xylose and lactose and derivatives thereof, including alkyl derivatives, such as methyl derivatives, for example methylglucose.
[0122] The sugar esters of fatty acids may be chosen in particular from the group consisting of the esters or mixtures of esters of sugars described above and of linear or branched, saturated or unsaturated fatty acids in C6-C30 and preferably in C12-C22. If they are unsaturated, these compounds may have one to three conjugated or unconjugated carbon-carbon double bonds.
[0123] The esters according to this variant may also be selected from monoesters, diesters, triesters, tetraesters and polyesters, and mixtures thereof.
[0124] These esters may be, for example, oleates, laurates, palmitates, myristates, behenates, cocoates, stearates, linoleates, linolenates, caprates and arachidonates, or mixtures thereof such as, in particular, mixed esters of oleopahnitate, oleostearate and palmitostearate, as well as pentaerythrityl tetraethyl hexanoate.
[0125] More particularly, monoesters and diesters are used, and in particular monooleates or dioleates, stearates, behenates, oleopalmitates, linoleates, linolenates and oleostearates of sucrose, glucose or methylglucose.
[0126] An example that may be mentioned is the product sold under the name Glucate® DO by the company Amerchol, which is a methylglucose dioleate.
[0127] Examples of preferable ester oils include, for example, diisopropyl adipate, dioctyl adipate, 2-ethylhexyl hexanoate, ethyl laurate, cetyl octanoate, octyldodecyl octanoate, isodecyl neopentanoate, myristyl propionate, 2-ethylhexyl 2-ethylhexanoate, 2-ethylhexyl octanate, 2-ethylhexyl caprylate / caprate, methyl palmitate, ethyl palmitate, isopropyl palmitate, dicaprylyl carbonate, isopropyl lauroyl sarcosinate, isononyl isonanoate, ethylhexyl palmitate, isohexyl laurate, hexyl laurate, isocetyl stearate, isopropyl isostearate, isopropyl myristate, isodecyl oleate, glyceryl tri(2-ethylhexanoate), pentaerythrithyl tetra(2-ethylhexanoate), 2-ethylhexyl succinate, diethyl sebacate and mixtures thereof.
[0128] Examples of artificial triglycerides include, for example, capryl caprylyl glycerides, glyceryl trimyristate, glyceryl tripalmitate, glyceryl trilinolenate, glyceryl trilaurate, glyceryl tricaprate, glyceryl tri-caprylate, glyceryl tri(caprate / caprylate) and glyceryl tri(caprate / caprylate / linolenate).
[0129] As examples of silicone oils, mention may be made, for example, of linear organopolysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, methylhydrogenpolysiloxane and the like; cyclic organopolysiloxanes such as cyclohexasiloxane, octamethylcyclotetrasiloxane, decamethylcyclopenta- siloxane, dodecamethylcyclohexasiloxane, and the like; and mixtures thereof.
[0130] Preferably, the silicone oil is selected from liquid polydialkylsiloxanes, including liquid polydimethylsiloxanes (PDMS) and liquid polyorganosiloxanes comprising at least one aryl group.
[0131] These silicone oils may also be organomodified. The organomodified silicones that may be used in accordance with the present invention are silicone oils as defined above and comprise in their structure one or more organofunctional groups attached via a hydrocarbon-based group.
[0132] Organopolysiloxanes are further defined in Chemistry and Technology of Silicones (1968) by Walter Noll, Academie Press. They may be volatile or non-volatile.
[0133] When they are volatile, the silicones are more particularly chosen from those having a boiling point between 60°C and 260°C, and even more particularly from:
[0134] (i) cyclic polydialkylsiloxanes comprising from 3 to 7 and preferably from 4 to 5 silicon atoms. These include, for example, octamethylcyclotetrasiloxane sold in particular under the name Volatile Silicone® 7207 by Union Carbide or Silbione® 70045 V2 by Rhodia, decamethylcyclopentasiloxane sold under the name Volatile Silicone® 7158 by Union Carbide, Silbione® 70045 V5 by Rhodia, and dodecame-ethylcyclopentasiloxane sold under the name Silsoft 1217 by Momentive Performance Materials, and mixtures thereof. Mention may also be made of cyclocopolymers of the dimethylsiloxane / methylalkylsiloxane type, such as Silicone Volatile® FZ 3109 sold by the company Union Carbide, of formula: with o" ■ — S' ~ O — and with: — Sî - O — I Ï ch3
[0135] Mention may also be made of mixtures of cyclic polydialkylsiloxanes with organosilicon compounds, such as the mixture of octamethylcyclotetrasiloxane and tetramethylsilylpentaerythritol (50 / 50) and the mixture of octamethylcyclotetrasiloxane and oxy-1,1'-bis(2,2,2',2',3,3'-hexatrimethylsilyloxy)neopentane; and
[0136] (ii) linear volatile polydialkylsiloxanes containing 2 to 9 silicon atoms and having a viscosity less than or equal to 5 x 10 6m2 / s at 25 °C. An example is deca-methyltetrasiloxane sold in particular under the name SH 200 by the company Toray Silicone. Silicones belonging to this category are also described in the article published in Cosmetics and Toiletries, Vol. 91, Jan. 76, pp. 27-32, Todd & Byers, Volatile Silicone Fluids for Cosmetics. The viscosity of silicones is measured at 25°C according to ASTM 445 Appendix C.
[0137] Non-volatile polydialkylsiloxanes may also be used. These non-volatile silicones are more particularly chosen from polydialkylsiloxanes, among which mention may mainly be made of polydimethylsiloxanes containing trimethylsilyl end groups.
[0138] Among these polydialkylsiloxanes, the following commercial products may be mentioned, in a non-limiting manner: • Silbione® oils from the 47 and 70 047 ranges or Mirasil® oils sold by Rhodia, for example oil 70 047 V 500 000; • oils from the Mirasil® range sold by the company Rhodia; • Dow Corning 200 series oils, such as DC200 having a viscosity of 60,000 mm2 / s; and • Viscasil® oils from General Electric and certain oils from the SF range (SF 96, SF 18) from General Electric.
[0139] Mention may also be made of polydimethylsiloxanes containing dimethylsilanol end groups known as dimethiconol (CTFA), such as the oils of the 48 range from the company Rhodia.
[0140] Among the silicones containing aryl groups, mention may be made of polydiaryl-siloxanes, in particular polydiphenylsiloxanes and polyalkylarylsiloxanes such as phenyl silicone oil.
[0141] The phenyl silicone oil can be chosen from phenyl silicones of the following formula:
[0142] in which - Ri to Rio are, independently of each other, radicals based on saturated or unsaturated, linear, cyclic or branched C1-C30 hydrocarbons, preferably radicals based on C1-C12 hydrocarbons, and more preferably radicals based on C1-C6 hydrocarbons, in particular methyl, ethyl, propyl or butyl radicals, and - m, n, p and q are, independently of each other, integers from 0 to 900 inclusive, preferably from 0 to 500 inclusive, and more preferably from 0 to 100 inclusive, provided that the sum n+m+q is other than 0.
[0143] Examples that may be mentioned include products sold under the following names: • Silbione® oils from the 70 641 range from Rhodia; • oils from the Rhodorsil® 70 633 and 763 ranges from Rhodia; • Dow Corning 556 Cosmetic Grade Fluid oil from Dow Corning; • Bayer's PK range of silicones, such as the PK20 product; and - certain oils from the General Electric SF range, such as SF 1023, SF 1154, SF 1250 and SF 1265.
[0144] As phenyl silicone oil, phenyl trimethicone (R1 to R10 are methyl;p, qetn = 0;m=l in the above formula) is preferable.
[0145] Organomodified liquid silicones may in particular contain poly-ethyleneoxy and / or polypropyleneoxy groups. Mention may thus be made of the KF-6017 silicone proposed by Shin-Etsu, and the Silwet® L722 and L77 oils from the company Union Carbide.
[0146] The hydrocarbon oils can be chosen from: • linear or branched, optionally cyclic, lower alkanes of C6-C16. Examples that may be mentioned include hexane, undecane, dodecane, tridecane and isoparaffins, for example isohexadecane, isododecane and isodecane; and • linear or branched hydrocarbons containing more than 16 carbon atoms, such as liquid paraffins, liquid petroleum jelly, hydrogenated polydecenes and polyisobutenes such as Parleam® and squalane.
[0147] As preferable examples of hydrocarbon oils, mention may be made, for example, of linear or branched hydrocarbons such as isohexadecane, isododecane, squalane, mineral oil (e.g., liquid paraffin), paraffin, petrolatum or vaseline, naphthalenes, and the like; hydrogenated polyisobutene, isoeicosane and decene / butene copolymers; and mixtures thereof.
[0148] The term "fatty" in fatty alcohol means the inclusion of a relatively large number of carbon atoms. Thus, alcohols that have 4 or more, preferably 6 or more, and more preferably 12 or more carbon atoms are encompassed within the scope of fatty alcohols. The fatty alcohol may be saturated or unsaturated. The fatty alcohol may be linear or branched.
[0149] The fatty alcohol may have the structure R-OH wherein R is selected from saturated or unsaturated, linear or branched radicals containing from 4 to 40 carbon atoms, preferably from 6 to 30 carbon atoms, and more preferably from 12 to 20 carbon atoms. In at least one embodiment, R may be selected from C12-C20 alkyl and C12-C20 alkenyl groups. R may or may not be substituted by at least one hydroxyl group.
[0150] Examples of the fatty alcohol include lauryl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, behenyl alcohol, undecylenyl alcohol, myristyl alcohol, octyldodecanol, hexyldecanol, oleyl alcohol, linoleyl alcohol, palmitoleyl alcohol, arachidonyl alcohol, erucyl alcohol and mixtures thereof.
[0151] It is preferable that the fatty alcohol is a saturated fatty alcohol.
[0152] Thus, the fatty alcohol may be selected from saturated or unsaturated, linear or branched C6-C30 alcohols, preferably saturated, linear or branched C6-C30 alcohols, and more preferably saturated, linear or branched C12-C20 alcohols.
[0153] The term "saturated fatty alcohol" herein refers to an alcohol having a long aliphatic saturated carbon chain. It is preferable that the saturated fatty alcohol is selected from any linear or branched saturated C6-C30 fatty alcohol. Among the linear or branched saturated C6-C30 fatty alcohols, linear or branched saturated C12-C20 fatty alcohols may be preferably used. Any linear or branched saturated C16-C20 fatty alcohol may be preferably used. Branched C16-C20 fatty alcohols may be used even more preferably.
[0154] Examples of saturated fatty alcohols include lauryl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, behenyl alcohol, undecylenyl alcohol, myristyl alcohol, octyldodecanol, hexyldecanol, and mixtures thereof. In one embodiment, cetyl alcohol, stearyl alcohol, octyldodecanol, hexyldecanol, or a mixture thereof (e.g., cetearyl alcohol), as well as behenyl alcohol, may be used as the saturated fatty alcohol.
[0155] According to at least one embodiment, the fatty alcohol used in the composition according to the present invention is preferably chosen from cetyl alcohol, octyldodecanol, hexyldecanol and mixtures thereof.
[0156] It is also preferable that the oil of point (e) is chosen from oils with a molecular weight of less than 600 g / mol.
[0157] Preferably, the oil of point (f) has a low molecular weight such as less than 600 g / mol, selected from ester oils having a short (CrCi2) hydrocarbon chain or chains (for example, isopropyl lauroyl sarcosinate, isopropyl myristate, isopropyl palmitate, isononyl isononanoate and ethylhexyl palmitate), silicone oils (for example, volatile silicones such as cyclohexasiloxane), hydrocarbon oils (for example, isododecane, isohexadecane and squalane), branched and / or unsaturated (Ci2-C30) fatty alcohol oils such as octylodecanol and oleyl alcohol, and ether oils such as di- caprylyl ether.
[0158] It is preferable that the oil of point (e) is selected from polar oils. It is preferable that the oil of point (e) is selected from ester oils.
[0159] The amount of the oil(s) of point (e) in the composition according to the present invention may be 0.01% by weight or more, preferably 0.05% by weight or more, and more preferably 0.1% by weight or more, relative to the total weight of the composition.
[0160] The amount of the oil(s) of point (e) in the composition according to the present invention may be 10% by weight or less, preferably 5% by weight or less, and more preferably 1% by weight or less, relative to the total weight of the composition.
[0161] The amount of the oil(s) of point (e) in the composition according to the present invention may be from 0.01% to 10% by weight, preferably from 0.05% to 5% by weight, and more preferably from 0.1% to 1% by weight, relative to the total weight of the composition.
[0162] (Anionic surfactant)
[0163] The composition according to the present invention may comprise (f) at least one anionic surfactant. Only one type of nonionic surfactant of point (f) may be used, but two or more different types of nonionic surfactants of point (f) may be used in combination.
[0164] It is preferable that the anionic surfactant of point (f) is selected from amino acid surfactants.
[0165] The amino acid surfactant is an anionic surfactant based on an amino acid or derivatives thereof. Typically, the amino acid surfactant is an anionic surfactant comprising at least one amino moiety and at least one carboxylic acid moiety that is in the form of a carboxylate. The amino acid surfactant may have two or more amino moieties and / or two or more carboxylic acid moieties that are in the form of carboxylates.
[0166] The amino acid surfactant may preferably be selected from amino acid derivatives. The amino acid derivative may more preferably be selected from salts of amino acids and N-acylated amino acids, for example alkali metal salts and alkaline earth metal salts of amino acids and N-acylated amino acids, such as sodium salts, potassium salts, magnesium salts and calcium salts of amino acids and N-acylated amino acids.
[0167] The acyl group that forms the N-acyl moiety of the amino acid derivatives may be a C1-C30 acyl group, preferably a C6-C28 acyl group and, more preferably, a C12-C24 acyl group.
[0168] The amino acid surfactant may even more preferably be se selected from the group consisting of glutamates, N-acylated glutamates, aspartates, N-acylated aspartates and salts thereof.
[0169] Examples of the amino acid surfactant include, but are not limited to: • sarcosinates, such as N-acyl sarcosinates (salts), for example, sodium lauroyl sarcosinate, sold under the name Nikkol Sarcosinate™ LN by Nikko Chemicals or sold under the name Pureact™ LSR by Innospec Performance Chemicals Europe Limited; sodium myristoyl sarcosinate, sold under the name Nikkol Sarcosinate™ MN by Nikko Chemicals; sodium palmitoyl sarcosinate, sold under the name Nikkol Sarcosinate™ PN by Nikko Chemicals; and sodium cocoyl sarcosinate, sold under the name Nikkol Sarcosinate™ CN-30 by Nikko Chemicals; • alaninates, such as N-acyl alaninates (salts), for example sodium N-lauroyl-N-methylamidopropionate, sold under the name Sodium Nikkol AlaninateTM LN 30 by Nikko Chemicals or sold under the name Alanone® ALE by Kawaken; sodium cocoyl alaninates, sold under the name Amilite® ACS-12 by Ajinomoto; and triethanolamine N-lauroyl-N-methylalanine, sold under the name Alanone® ALTA by Kawaken; • glutamates, such as N-acyl glutamates (salts), for example, sodium stearoyl glutamate, sold under the name Eumulgin® SR by BASF Japan; sodium lauroyl glutamate, sold under the name Plantapon® Amino SLG-P by BASF Japan; triethanolamine monococoyl glutamate, sold under the name Amisoft® CT-12 by Ajinomoto; triethanolamine lauroyl glutamate, sold under the name Amisoft® LT-12 by Ajinomoto; and disodium stearoyl glutamate, sold under the name Amisoft® HS-21P by Ajinomoto; • aspartates, such as N-acyl aspartates (salts), for example, disodium N-lauroyl aspartate, sold under the name AminoFoamer® FLMS-P1 by Asahi Kasei; and a mixture of triethanolamine N-lauroyl aspartate and triethanolamine N-myristoyl aspartate, sold under the name AminoFoamer® FCMT-L by Asahi Kasei; and • glycinates, such as N-acyl glycinates (salts), for example sodium N-cocoyl glycinate, sold under the name Amilite® GCS-12K; and potassium N-cocoyl glycinate, sold under the name Amilite® GCK-12K by Ajinomoto.
[0170] It is preferable that the anionic surfactant of point (f) is selected from the group consisting of sarcosinates, N-acyl sarcosinate, and salts thereof.
[0171] It is more preferable that the anionic surfactant of point (f) is sodium N-acylated sarcosinate, in particular sodium cocoyl sarcosinate.
[0172] The amount of the anionic surfactant of point (f) in the composition according to the present invention may be 0.01% by weight or more, preferably 0.05% by weight or more, and more preferably 0.1% by weight or more, relative to the total weight of the composition.
[0173] The amount of the anionic surfactant(s) of point (f) in the composition according to the present invention may be 10% by weight or less, preferably 5% by weight or less, and more preferably 1% by weight or less, relative to the total weight of the composition.
[0174] The amount of the anionic surfactant(s) of point (f) in the composition according to the present invention may range from 0.01% to 10% by weight, preferably from 0.05% to 5% by weight, more preferably from 0.1% to 1% by weight, relative to the total weight of the composition.
[0175] (Optional ingredient)
[0176] The composition according to the present invention may comprise, in addition to the above-mentioned ingredients, one or more optional ingredients typically employed in cosmetics, in particular one or more optional ingredients selected from cationic and amphoteric surfactants; nonionic surfactants other than the polyglyceryl monoesters of fatty acid of point (c); hydrophilic or lipophilic thickeners, derived, for example, from synthetic polymers; volatile or non-volatile organic solvents; cationic, anionic and amphoteric polymers; silicones and silicone derivatives other than the oil of point (e); natural extracts derived from animals or plants other than the Taraxacum Officinale extract of point (a) or the oil of point (e); waxes; and the like, within a range which does not impair the effects of the present invention.
[0177] The composition according to the present invention may comprise the above optional ingredient(s) in an amount of 0.01% to 30% by weight, preferably 0.05% to 20% by weight, and more preferably 0.1% to 10% by weight, relative to the total weight of the composition.
[0178] [Preparation]
[0179] The composition according to the present invention can be prepared by mixing the essential ingredients as explained above, and the optional ingredient(s), if necessary, as explained above.
[0180] The method and means for mixing the above essential and optional ingredients are not limited. Any conventional method and means can be used for mixing the above essential and optional ingredients to prepare the composition according to the present invention.
[0181] The composition according to the present invention can be prepared by simple or easy mixing with a conventional mixing means such as an agitator and a homogenizer. In addition, heating may not be necessary. Therefore, the method for preparing the composition according to the present invention can be environmentally friendly. [Cosmetic application]
[0182] The composition according to the present invention may be intended to be used as a cosmetic composition. Thus, the cosmetic composition according to the present invention may be intended to be applied to a keratinous substance. Keratinous substance herein refers to a material containing keratin as a main constituent, and examples thereof include skin, scalp, lips, hair or body hair and the like. Thus, it is preferable that the cosmetic composition according to the present invention is used for a cosmetic method for a keratinous substance, in particular the skin.
[0183] Thus, the cosmetic composition according to the present invention may be a cosmetic composition for the skin, preferably a skin care composition or a skin makeup composition, and more preferably a skin care composition. [Shape]
[0184] The composition according to the present invention may be present in any form.
[0185] If the composition according to the present invention includes (d) water and (e) oil, the water of point (d) can form an aqueous phase and the oil of point (e) can form fatty phases, and the fatty phases can be dispersed in the aqueous phase. Thus, the aqueous phase can function as a continuous phase, and the fatty phase can function as a dispersed phase. In other words, the composition according to the present invention can be in the form of an O / W dispersion such as an O / W emulsion. If the composition according to the present invention is of the O / W type, it can provide a feeling of freshness due to the water of point (d) which forms the external phase thereof. [Cosmetic process and use]
[0186] The present invention also relates to a cosmetic method for a keratinous substance such as the skin, comprising the application of the composition according to the present invention to the keratinous substance.
[0187] The cosmetic process here designates a non-therapeutic cosmetic care process for a keratinous substance such as the skin.
[0188] The cosmetic method according to the present invention can provide a keratinous substance such as skin with an increased amount of oligosaccharide, such as oligofructan, included in an extract of Taraxacum Officinale, preferably a extract of rhizome or root of Taraxacum Officinale, in the composition according to the present invention.
[0189] Thus, the cosmetic method according to the present invention can provide improved cosmetic effects, on a keratinous substance such as skin, based on an increased amount of the oligosaccharide, such as oligofructan, penetrating into the skin.
[0190] An extract of Taraxacum Officinale, preferably an extract of Taraxacum Officinale rhizome or root, is known to improve skin radiance, tone, and texture. Therefore, the cosmetic method according to the present invention can provide improved skin radiance, tone, and texture. Furthermore, the cosmetic method according to the present invention can effectively lighten the skin.
[0191] In addition, an extract of Taraxacum Officinale, preferably an extract of rhizome or root of Taraxacum Officinale, is known to function as an antipollution agent or free radical scavenger (antioxidant). Therefore, the cosmetic method according to the present invention can effectively protect a keratinous substance such as skin against environmental pollution or oxidation.
[0192] The present invention also relates to a use of a combination of
[0193] (b) at least one glycol; and
[0194] (c) at least one polyglyceryl monoester of fatty acid,
[0195] in a composition comprising
[0196] (a) at least one extract of Taraxacum Officinale, preferably a rhizome extract or Taraxacum Officinale root;
[0197] in which
[0198] the amount of the polyglyceryl monoester of fatty acid of point (c) is greater than 0.2% by weight relative to the total weight of the composition
[0199] in order to enhance the penetration of an oligosaccharide in the Taraxacum Officinale extract of point (a), preferably a Taraxacum Officinale rhizome or root extract, into a keratinous substance such as the skin.
[0200] The present invention also relates to a use of a combination of
[0201] (b) at least one glycol; and
[0202] (c) at least one polyglyceryl monoester of fatty acid,
[0203] in a composition comprising
[0204] (a) at least one extract of Taraxacum Officinale, preferably a rhizome extract or Taraxacum Officinale root;
[0205] in which
[0206] the amount of the polyglyceryl monoester of fatty acid of point (c) is greater than 0.2% by weight relative to the total weight of the composition
[0207] in order to enhance the cosmetic effects on the skin, such as the skin lightening effects, provided by the Taraxacum Officinale extract of point (a), preferably an extract of the rhizome or root of Taraxacum Officinale.
[0208] The above composition may comprise any of (d) water, (e) at least one oil and (f) at least one anionic surfactant.
[0209] The above explanations regarding the Taraxacum Officinale extract of point (a), the fatty acid polyglyceryl monoester of point (b) and the glycol of point (c), as well as the optional ingredients such as the water of point (d), the oil of point (e) and the anionic surfactant of point (f), can be applied to those of the above use. EXAMPLES
[0210] The present invention will be described in more detail by means of examples. However, they should not be construed as limiting the scope of the present invention. Examples 1 to 6 and comparative examples 1 to 9 [0211 ] [Preparation]
[0212] Each of the compositions according to Examples 1 to 6 and Comparative Examples 1 to 9 was prepared by mixing the ingredients shown in Tables 1 to 2. The numerical values of the amounts of ingredients shown in Tables 1 to 2 are all based on "% by weight" of raw materials.
[0213] [Tables 1] Ex. 1 Ex. 2 Ex. 3 Ex. 4 Ex. 5 Ex. 6 Water qsp 100 qsp 100 qsp 100 qsp 100 qsp 100 Caprylyl Glycol 0.3 0.3 0.3 0.3 0.3 0.3 Arginine 0.3 0.3 0.3 0.3 0.3 0.3 Citric Acid 0.1 0.1 0.1 0.1 0.1 0.1 Sodium Cocoyl Sarcosinate 0.2 0.2 0.2 0.2 0.2 0.2 Isopropyl Myristate 0.8 0.8 0.8 0.8 0.8 0.8 Taraxacum Officinale Root / Rhizome Extract 0.5 0.5 0.5 0.5 0.5 0.5 Polyglyceryl-2 Oleate 0.5 0.5 0.5 0.5 0.5 0.5 Polyglyceryl-4 Caprate 1.2 1.2 1.2 1.2 1.2 1.2 Pentylene Glycol 10 5 3 - - - Propylene Glycol - - - 10 5 3 Xanthan Gum 0.3 0.3 0.3 0.3 0.3 0.3 Absorbance (400 nm) 3.73 2.91 1.98 3.10 2.44 1.70
[0214] [Tables2] Ex. comp. 1 Ex. comp. 2 Ex. comp. 3 Ex. comp. 4 Ex. comp. 5 Ex. comp. 6 Ex. comp. 7 Ex. comp. 8 Ex. comp. 9 Water qs 100 qs 100 qs 100 qs 100 qs 100 qs 100 qs 100 qs 100 qs 100 Caprylyl Glycol 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Arginine 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Citric acid 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Sodium cocoyl sar-cosinate 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Myristate isopropyl 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 Taraxacum Officinale Root / Rhizome Extract 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Polyglyceryl-2 Oleate 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.1 - Polyglyceryl-4 Caprate 1.2 1.2 1.2 1.2 1.2 1.2 1.2 0.1 - Pentylene Glycol - - - - - - - 10 10 Glycerin 10 5 3 - - - - - - Ethanol - - - 10 5 3 - - - Xanthan Gum 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Absorbance (400 nm) 0.08 0.46 0.38 0.58 0.69 0.54 0.63 1.08 0.40 [Assessment]
[0215] (Absorbance)
[0216] The penetration test experiments were carried out in a Franz diffusion cell (Hanson) with a Strat-M membrane (Millipore, diameter of 15 mm). This equipment consisted of a donor part and a receiver part, with the Strat-M membrane sandwiched between the donor and receiver parts. The receiver part with a predetermined volume was filled with a receiver solution (0.25 wt% Tween 80 / deionized water) maintained at a temperature of 32 °C, which was continuously stirred with a small magnetic bar. Each of the compositions according to Examples 1 to 6 and Comparative Examples 1 to 9 was spread with a spatula onto the membrane of the donor part in an amount of 30 mg / cm2. After 5 hours, 200 µl of receiver solution was removed from the receiver part, while supplying the same amount of a new receiver solution to the receiver part to maintain the same penetration conditions.
[0217] The amount of oligosaccharides in the receptor solution was determined using a phenol sulfuric acid method: 150 µl of the collected receptor solution was mixed with 750 µl of sulfuric acid for 15 minutes at 90 °C and then with 150 µl of a 5% by weight phenol solution for 5 minutes at room temperature (25 °C). The oligosaccharides were converted into a brown substance composed of a UV-absorbing chromophore. The UV absorption at 400 nm of the reacted receptor solution was measured using a spectrophotometer. The UV absorption was an indication of the amount of oligosaccharides in the receptor solution.
[0218] The results are shown in the row titled “Absorbance (400 nm)” in Tables 1 and 2.
[0219] (Summary)
[0220] Comparison of Examples 1 to 6 and Comparative Example 7 demonstrates that the use of glycols significantly enhanced the skin penetration of oligosaccharides compared to the absence of use of glycols.
[0221] Comparison of Examples 1 to 3 and Examples 4 to 6, respectively, demonstrates that the use of pentylene glycol can better enhance the skin penetration of oligosaccharides compared to the use of propylene glycol.
[0222] Comparison of Comparative Examples 1 to 6 and Comparative Example 7 demonstrates that the use of polyvalent (trivalent) alcohol or monovalent alcohol did not enhance the skin penetration of oligosaccharides compared to the absence of use of polyvalent (trivalent) alcohol or monovalent alcohol.
[0223] Comparison of Comparative Example 8 and Comparative Example 7 demonstrates that the joint use of 0.2% by weight of polyglyceryl fatty acid monoesters is insufficient to significantly enhance the skin penetration of oligosaccharides, even if glycol is used.
[0224] Comparison of Comparative Example 9 and Comparative Example 7 demonstrates that the absence of use of polyglyceryl monoesters of fatty acid did not enhance the skin penetration of oligosaccharides, even if glycol is used.
Claims
Claims
1. Composition, preferably cosmetic composition, and more preferably cosmetic composition for the skin, comprising: (a) at least one extract of Taraxacum Officinale; (b) at least one glycol; and (c) at least one fatty acid polyglyceryl monoester, wherein the amount of the fatty acid polyglyceryl monoester of point (c) is greater than 0.2% by weight relative to the total weight of the composition.
2. A composition according to claim 1, wherein the amount of the Taraxacum Officinale extract(s) of type (a) in the composition is from 0.01% to 5% by weight, preferably from 0.05% to 3% by weight, and more preferably from 0.1% to 1% by weight, relative to the total weight of the composition.
3. The composition of claim 1 or 2, wherein the glycol of point (b) is selected from the group consisting of propylene glycol, pentylene glycol, and mixtures thereof.
4. A composition according to any one of claims 1 to 4, wherein the fatty acid polyglyceryl monoester of point (c) comprises 2 to 4 glycerol units.
5. A composition according to any one of claims 1 to 4, wherein the composition further comprises (e) at least one oil.
6. A composition according to claim 5, wherein the oil of type (e) is selected from ester oils.
7. A composition according to any one of claims 1 to 6, wherein the composition further comprises (f) at least one anionic surfactant.
8. Composition according to claim 7, in which the anionic surfactant (f) is selected from amino acid surfactants.
9. A cosmetic process for a keratinous substance such as skin, comprising applying the cosmetic composition according to any one of claims 1 to 8 to the keratinous substance.
10. Use of a combination of (b) at least one glycol; and (c) at least one fatty acid polyglyceryl monoester, in a composition comprising (a) at least one Taraxacum Officinale extract; in which the amount of the fatty acid polyglyceryl monoester of point (c) is greater than 0.2% by weight relative to the total weight of the composition in order to enhance the penetration of an oligosaccharide in the Taraxacum Officinale extract of point (a) into a keratinous substance such as the skin.