TWO-STEP CLEANING PROCESS

Abstract

TWO-STEP CLEANSING PROCESS A two-step process for removing makeup from the skin is described. The process includes applying a first anhydrous composition to the skin on which makeup is present, and then applying a second anhydrous composition to the skin on which both the makeup and the first anhydrous composition are present. The first anhydrous composition includes: (a) a hydrophobic polymer formed as a reaction product of a natural or food-grade oil and a methacrylate or acrylate polymer; (b) one or more solvents capable of solubilizing the hydrophobic polymer of (a); and (c) optionally, one or more alkanes. The second anhydrous composition includes one or more nonpolar oils in which the hydrophobic polymer of the first anhydrous composition is insoluble. Figure for abstract: none

Description

[0137] (i)(c) optionally, about 1 to about 30% by weight, preferably about 5 to about 25% by weight, more preferably about 10 to about 20% by weight of one or more alkanes chosen from isododecane, isodecane, isohexadecane, n-heptane, n-octane, n-nonane, n-decane, n-undecane, n-dodecane, n-tetradecane, n-tridecane, n-tetradecane, n-pentadecane, or mixtures thereof, and even more preferably, at least one of the one or more alkanes is isododecane;

[0138] (i)(d) optionally, one or more oil thickening agents, wherein, where appropriate, the one or more oil thickening agents are preferably selected from polymers, gums, organoclays, polyethylenes, silica, or combinations thereof, wherein, where appropriate, they may be present in an amount of from about 0.01 to about 10% by weight, preferably from about 0.1 to about 5% by weight, more preferably from about 0.5 to about 4% by weight,

[0139] (i)(e) optionally, one or more miscellaneous ingredients, preferably in which the one or more miscellaneous ingredients, if any, are selected from preservatives, fragrances, pH adjusters, salts, chelating agents, buffers, antioxidants, flavonoids, vitamins, botanical extracts, UV filtering agents, proteins, protein hydrolysates and / or isolates, fillers (e.g., organic and / or inorganic fillers such as talc, calcium carbonate, silica, etc.) composition colorants, wherein if any, they are preferably present in an amount of about 0.1 to about 15% by weight, more preferably about 0.5 to about 10% by weight, more preferably about 1 to about 6% by weight;

[0140] wherein all weight percentages of (i) are based on a total weight of the first anhydrous composition; i. applying a second anhydrous composition to the skin on which the makeup and the first anhydrous composition are present, the second anhydrous composition comprising, consisting essentially of, or consisting of:

[0141] (ü)(a) about 50 to about 100% by weight, preferably about 60 to about 99% by weight, more preferably about 75 to about 95% by weight of one or more non-polar oils in which the hydrophobic polymer of (i)(a) is not soluble, wherein, preferably, the one or more non-polar oils are selected from squalane, isoparaffin (C12-C14), cycloparaffin, polydecene, polydimethylsiloxane, squalene, hydrogenated polyisobutene, isohexadecane, mineral oil, isoeicosane, ethoxydiglycol oleate, decyl olivate, or mixtures thereof, wherein, even more preferably, at least one of the one or more non-polar oils is squalane;

[0142] (ü)(b) optionally, one or more oil thickening agents, wherein, where appropriate, the one or more oil thickening agents are preferably chosen from polymers, gums, organoclays, polyethylenes, silica, or combinations thereof, wherein, where appropriate, they may be present in an amount of from about 0.01 to about 10% by weight, preferably from about 0.1 to about 5% by weight, more preferably from about 0.5 to about 4% by weight,

[0143] (ii)(c) optionally, one or more solid fatty compounds, wherein, where appropriate where appropriate, they may be present in an amount of about 0.01 to about 20% by weight, preferably about 0.1 to about 15% by weight, more preferably about 1 to about 10% by weight, wherein, preferably, at least one of the one or more solid fatty compounds is a wax, for example, one or more waxes selected from candelilla wax, carnauba wax, castor wax, beeswax, lanolin wax, ozokerite wax, microcrystalline wax, sunflower wax, tribehenin, or mixtures thereof;

[0144] (ii)(d) optionally, one or more miscellaneous ingredients, preferably in wherein the one or more miscellaneous ingredients, if any, are selected from preservatives, fragrances, pH adjusters, salts, chelating agents, buffers, antioxidants, flavonoids, vitamins, botanical extracts, UV filtering agents, proteins, protein hydrolysates and / or isolates, fillers (e.g., organic and / or inorganic fillers such as talc, calcium carbonate, silica, etc.) composition colorants, wherein if any, they are preferably present in an amount of about 0.1 to about 15% by weight, more preferably about 0.5 to about 10% by weight, more preferably about 1 to about 6% by weight.

[0145] wherein all weight percentages of (ii) are based on the total weight of the second anhydrous composition.

[0146] The first anhydrous composition, the second anhydrous composition, or both the first anhydrous composition and the second anhydrous composition may be transparent or translucent. EXAMPLES

[0147] An implementation of the present disclosure is provided by means of the following examples. These examples serve to illustrate the technology without being limiting in nature. Example 1 Solubility tests

[0148] Tests were conducted to establish the solubility of MycelX® in various solvent mixtures of polycitronellol acetate and squalane. To determine how solvent mixtures influence the solubility of MycelX®, MycelX® was initially dissolved in polycitronellol acetate to form a clear solution. Squalane was then added to the solution in varying amounts to assess how the addition of a non-polar oil influences the solubility of the MycelX®. When polycitronellol acetate and squalane were combined in a weight ratio of 80 / 20 (MycelX®:squalane), MycelX® was soluble in all quantities tested, i.e., 30% by weight, 40% by weight, 50% by weight, and 60% by weight. When polycitronellol acetate and squalane were combined in a weight ratio of 65:35 (polycitronellol acetate:squalane), the combination solubilized 10% by weight of MycelX® but only partially solubilized 20% by weight of MycelX®. At 20% by weight of MycelX®, the mixture became cloudy (loss of transparency), indicating a degree of precipitation. At 30 and 40% by weight of MycelX®, the MycelX® precipitated, resulting in a cloudy, yellow mixture, which contained MycelX® particles. The results are summarized in the table below.

[0149] [Tables4] Solubility of MycelX ® MycelX® / Squalane ratio (% by weight) 80 / 20 65 / 35 50 / 50 15 / 85 MYCE LEX® (% by weight) 60 Soluble 50 Soluble Not soluble 40 Soluble Not soluble Not soluble Not soluble 30 Soluble Not soluble Not soluble Not soluble 20 Partially soluble Not soluble Not soluble 10 Soluble Not soluble Example 2 Scrubbing studies

[0150] Different compositions were prepared and studied to determine their exfoliating properties compared to a commercial facial exfoliating cleanser, used as a standard product. The compositions are presented in the following table.

[0151] [Tables5] First Inventive Comparative Anhydrous Composition Standard ABCE MycelX®1 28.6 * Polymethyl methacrylate 28.6 Linseed oil 28.6 Polycitronellol acetate 57.1 57.1 57.1 Isododecane 14.3 14.3 14.3

[0152] 'Reaction product of linseed oil and isobutyl methacrylate polymer'

[0153] * The commercial standard product has the following list of ingredients:

[0154] Aqua / Water, Glycerin, Dicocodimonium Chloride, Carbomer, Steartrimonium Bromide, Isopropyl Alcohol, Dipotassium Glycyrrhizate, Allantoin, Citric Acid, Malic Acid, Lactic Acid, Sodium Hyaluronate, Aloe Barbadensis Leaf Extract, Punica Granatum Pericarp Extract, Soluble Collagen, Placental Protein, Fucus Vesiculosus Extract, Clematis Vitalba Leaf Extract, Spiraea Ulmaria Flower Extract, Equisetum Arvense (Horsetail) Extract, Hedera Helix (Virginia Creeper) Extract, Butylene Glycol, Phenoxyphenol, Fragrance; Parfum; Aroma, CI 16255; ACID RED 18.

[0155] Approximately 2 μL of matte ink long-lasting makeup (red) was applied evenly onto white supplare substrates (2x2 inches) and dried in a chamber at 37°C for approximately 1 hour, or until dry. After drying, approximately 2 μL of inventive composition A, comparative composition B, comparative composition C (control), and the commercial standard were pipetted to separate the dried makeup samples and rubbed with a fingertip over the makeup in a circular motion ten times. After waiting approximately 10 seconds, approximately 2 μL of squalane (second anhydrous composition) was then pipetted onto the makeup samples and rubbed with a fiber over the makeup in a circular motion ten times. Upon application of the squalane to the makeup sample treated with inventive composition A, the makeup coagulated and peeled off the supplare substrate.Makeup samples treated with Comparative Compositions B, Comparative Composition C, and Commercial Standard E did not coagulate or peel from the supplare substrate upon application of squalane. In addition, water was added on top of Standard E, but it exhibited little peeling. Example 3 Makeup removal studies

[0156] Various compositions were prepared and studied to determine their ability to remove makeup compared to a standard commercial makeup remover product. compositions are presented in the following table. Inventive composition A, comparative compositions B and C, and commercial standard product E are identical to those tested in Example 2.

[0157] [Tableauxô] First Inventive Comparative Anhydrous Composition Standard ABCDE MycelX®1 28.6 * Polymethyl methacrylate 28.6 Linseed oil 28.6 Polybutene 58.6 Polycitronellol acetate 57.1 57.1 57.1 57.1 Isododecane 14.3 14.3 14.3 14.3

[0158] 'Reaction product of linseed oil and isobutyl methacrylate polymer'

[0159] * The commercial standard product has the following list of ingredients:

[0160] Aqua / Water, Cyclopentasiloxane, Isohexadecane, Sodium Chloride, Poloxamer 184, Hexylene Glycol, Dipotassium Phosphate, Benzyl Alcohol, Potassium Phosphate, Quaternium-15, Benzalkonium Chloride, Parfum / Fragrance, Citronellol, Geraniol.

[0161] Approximately 20 μL of matte ink long-lasting makeup (red) was uniformly applied to black supplare substrates (1.25 x 1.25 inches) and dried in a chamber at 37°C for approximately 1 hour or until dry. After drying, approximately 20 μL of inventive composition A, comparative composition B, comparative composition C (control), comparative composition D, and commercial standard product E were pipetted to separate dried makeup samples and rubbed onto the makeup in a circular motion ten times. After a waiting time of approximately 10 seconds, approximately 20 μL of squalane (second anhydrous composition) was then pipetted onto the makeup samples and rubbed with a finger onto the makeup in a circular motion ten times.For the sample treated with the commercial standard product, instead of squalane, approximately 20 additional pL of the commercial standard product was reapplied in the second step. The samples were then wiped with a cotton swab under controlled pressure using a pressure sensor to control the pressure at a force of approximately 500 grams. The L*a*b* values ​​were . measured using a Datacolor 600TM Spectraflash spectrometer. The percentage of makeup removal was calculated according to the following formula. Each sample was run in triplicate and the results were averaged.

[0162] % Elimination = (a* (after) - a* (before) ) / (a* (before) - a* (substrate) )

[0163] [Tables?] % Elimination (L*a*b*) Inventive Comparative Standard ABCDE 84.4 76 61.7 66.0 75.1

[0164] The results show that inventive composition A removed the highest percentage of long-lasting makeup, even more than the commercial gold standard. Example 4 Makeup removal studies

[0165] Various compositions were prepared and studied to determine their makeup removal capacity compared to a commercial standard makeup removal product. The compositions are presented in the following table. Inventive composition A and commercial standard product E are identical to those studied in Examples 2 and 3.

[0166] [Tables8] First Comparative Inventive Anhydrous Composition AFGE Standard MycelX®1 28.6 * Polycitronellol acetate 57.1 Caprylic / capric triglycerides 57.1 Isopropyl myristate 57.1 Isododecane 14.3 14.3 14.3

[0167] 'Reaction product of linseed oil and isobutyl methacrylate polymer'

[0168] * The commercial standard product has the following list of ingredients:

[0169] Aqua / Water, Cyclopentasiloxane, Isohexadecane, Sodium Chloride, Poloxamer 184, Hexylene Glycol, Dipotassium Phosphate, Benzyl Alcohol, Potassium Phosphate, Quaternium-15, Benzalkonium Chloride, Parfum / Fragrance, Citronellol, Geraniol.

[0170] Approximately 20 μL of matte ink long-lasting makeup (red) was applied evenly onto black supplare substrates (1.25x1.25 inches) and dried in a chamber at 37°C for approximately 1 hour, or until dry. After drying, approximately 20 μL of inventive compositions A-D or commercial standard product E was pipetted to separate the dried makeup samples and rubbed onto the makeup with a finger in a circular motion ten times. After waiting approximately 10 seconds, approximately 20 μL of squalane (second anhydrous composition) was then pipetted onto the makeup samples. For the sample treated with the commercial standard product instead of squalane, approximately an additional 20 μL of the commercial standard product was re-pipetted in the second step. The samples were then wiped with a cotton swab under controlled pressure using a SWIFT Tool in the green zone.L*a*b* values ​​were measured using a Datacolor 600™ Spectraflash spectrometer. The percentage of makeup removal was calculated according to the following formula. Each composition was tested in triplicate and the results were averaged.

[0171] % Elimination = (a* (after) - a* (before) ) / (a* (before) - a* (substrate) )

[0172] [Tables9] % Elimination (L*a*b*) Inventive Standard AFGE 84.4 40.5 63.8 75.1

[0173] The results show that inventive composition A removed significantly more long-lasting makeup, even more than the commercial gold standard. Example 5 Smear test

[0174] Various compositions were prepared and studied to determine their performance using a smudge test against a commercial makeup remover standard product. The compositions are shown in the following table. Inventive composition A, comparative composition C and the commercial standard product are identical to those studied in Examples 2-4.

[0175] [TableauxlO] First Inventive Comparative Standard Anhydrous Composition ACE MycelX®1 28.6 * Linseed oil 28.6 Polycitronellol acetate 57.1 57.1 Isododecane 14.3 14.3

[0176] 'Reaction product of linseed oil and isobutyl methacrylate polymer'

[0177] * The commercial standard product has the following list of ingredients:

[0178] Aqua / Water, Cyclopentasiloxane, Isohexadecane, Sodium Chloride, Poloxamer 184, Hexylene Glycol, Dipotassium Phosphate, Benzyl Alcohol, Potassium Phosphate, Quaternium-15, Benzalkonium Chloride, Parfum / Fragrance, Citronellol, Geraniol.

[0179] Two commercially available waterproof and long-lasting mascaras were used in the tests, Mascara 1 and Mascara 2. The mascara products were applied fifteen times to eyelash samples. The eyelash samples were then placed on top of a white supplar. Approximately 4 μL of inventive composition A or commercial standard product E was pipetted onto eyelash samples treated with Mascara 1 and separately approximately 4 μL of inventive composition A and comparative compositions C were pipetted onto eyelash samples treated with Mascara 2. The eyelash samples were rubbed by hand ten times from left to right and then rubbed ten times back and forth. After rubbing, approximately 4 μL of squalane was pipetted onto the eyelash samples treated with inventive composition A and comparative composition C.For the eyelash samples treated with the commercial standard product, instead of squalane, approximately 4 additional µL of the commercial standard product was reapplied in the second step. Again, the eyelash samples were rubbed by hand ten times from left to right, then rubbed ten times back and forth. A round cotton pad was placed under the attachment of a texture analyzer (Stable Micro System). A pressure of 150 g was applied to the eyelash samples and the eyelash samples were rubbed with the cotton pad for a duration of 5 seconds. The L*a*b* values ​​were measured using a VeriVide DigiEye® Imaging System and the L values ​​were compared. The higher the L value, the lighter / whiter the sample. Each composition was tested in triplicate and the results were averaged. Is this correct?

[0180] [Tableauxll] % elimination Mascara 1 Inventive Stallion AE 77.2 + 2.9 63.4 + 6.7

[0181] [Tablesl2] % removal Mascara 2 Inventive Comparative AC 86.0+1.5 79.4+1.1

[0182] The results show that the inventive composition A removes significantly more long-lasting makeup than the commercial standard and the comparative composition C.

[0183] The foregoing description illustrates and describes the disclosure. Furthermore, the disclosure shows and describes only the preferred embodiments. However, as mentioned above, it is to be understood that it is capable of use in various other combinations, modifications, and environments and is capable of changes or modifications within the scope of the inventive concepts as expressed herein, consistent with the above teachings and / or the skill or knowledge of the relevant art. The embodiments described herein are further intended to explain the best modes known to the applicant and to enable others skilled in the art to use the disclosure in such or other embodiments and with the various modifications required by the particular applications or uses thereof. Accordingly, the description is not intended to limit the invention to the form disclosed herein.

[0184] As used herein, the terms "comprising," "having," and "including" are used in their broad and non-limiting sense.

[0185] Thus, the phrase "a mixture thereof" also relates to "mixtures thereof." Throughout the disclosure, the phrase "a mixture thereof" is used, after a list of elements as shown in the following example where the letters A to F represent the elements: "one or more elements selected from the group consisting of A, B, C, D, E, F, and a mixture thereof." The phrase "a mixture thereof" does not require that the mixture include all of A, B, C, D, E, and F (although all of A, B, C, D, E, and F may be included). Rather, it indicates that a mixture of two or more of A, B, C, D, E, and F may be included. In other words, it is equivalent to the phrase "one or more elements selected from the group consisting of A, B, C, D, E, F, and a mixture of two or more of A, B, C, D, E, and F."

[0186] Similarly, the expression "a salt thereof" also relates to "salts thereof". Thus, when the disclosure refers to "an element selected from the group consisting of A, B, C, D, E, F, a salt thereof, and a mixture thereof", it indicates that one or more of A, B, C, D and F may be included, one or more of a salt of A, a salt of B, a salt of C, a salt of D, a salt of E and a salt of F may be included, or a mixture of any two of A, B, C, D, E, F, a salt of A, a salt of B, a salt of C, a salt of D, a salt of E and a salt of F may be included.

[0187] Salts referred to throughout the disclosure may include salts having a counterion such as an alkali metal, alkaline earth metal, or ammonium counterion. This list of counterions, however, is not limiting. Suitable counterions for the components described herein are known in the art.

[0188] The term "transparent" with respect to a transparent composition indicates that the composition has a transmittance of at least 80% at a wavelength of 600 nm, measured, for example, using a Lambda 40 UV-visible spectrometer. The compositions may have, for example, a transmittance of at least 80%, at least 90%, or at least 95% at a wavelength of 600 nm, measured, for example, using a Lambda 40 UV-visible spectrometer. The term "clear" is interchangeable with the term "transparent" for the purposes of this disclosure.

[0189] The term "translucent" in relation to a translucent composition indicates that the composition has a transmittance of at least 50% at a wavelength of 600 nm, measured for example using a Lambda 40 UV-visible spectrometer.

[0190] All percentages, parts and ratios herein are based on the total weight of the compositions of the present invention, unless otherwise indicated.

[0191] Some of the various categories of components identified may overlap. In such cases where an overlap may exist and the composition includes both components (or the composition includes more than two overlapping components), an overlapping compound does not represent more than one component. For example, some compounds may be considered both an oily solvent and a surfactant. If a particular composition includes both an oily component and a surfactant, a single compound will serve solely as the oily component or solely as the surfactant (the single compound does not simultaneously serve as both the oily component and the surfactant).

[0192] All ranges and values ​​disclosed herein are inclusive and combinable. For example, any value or point described herein that falls within a range described herein may serve as a minimum or maximum value to derive a subrange, etc.

[0193] The term "substantially free" or "essentially free" as used herein means that there is less than about 2% by weight of a specific material added to a composition, based on the total weight of the compositions. However, the compositions may include less than about 1% by weight, less than about 0.5% by weight, less than about 0.1% by weight, or none of the specified material. For example, if a composition is essentially free of compound X, the composition includes less than 2% by weight of compound X, or less than 1% by weight of compound X, or less than 0.5% by weight of compound X, or less than 0.1% by weight of compound X, or is free of compound X.

[0194] Any components positively presented in the present disclosure may be negatively excluded from the claims, for example, a claimed composition may be "free", "essentially free" (or "substantially free") of one or more components that are positively presented in the present disclosure.

Claims

Claims

1. A method of removing makeup from the skin, comprising: (i) applying a first anhydrous composition to skin on which makeup is present, the first anhydrous composition comprising: (a) a hydrophobic polymer formed as a reaction product of a natural or food-derived oil and a methacrylate or acrylate polymer; preferably wherein the hydrophobic polymer is the reaction product of about 50 to about 85 parts by weight of the natural or food-derived oil and about 15 to about 50 parts by weight of the methacrylate or acrylate polymer; more preferably wherein the hydrophobic polymer is a reaction product of linseed oil and poly(isobutyl methacrylate); (b) one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a); and (c) optionally, one or more alkanes;(ii) applying a second anhydrous composition to the skin on which the makeup and the first anhydrous composition are present, the second anhydrous composition comprising: a. one or more non-polar oils in which the hydrophobic polymer of (i)(a) is not soluble.;

2. The method of claim 1, wherein the one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a) have a dispersion component (D), a polar component (P) and a hydrogen bonding component (H), and a distance (Ra) of less than or equal to 13.4 MPa0.5 according to Hansen solubility parameters, wherein the distance (Ra) is defined by the formula (I): Ra-^D-üf + ^- / ^ + ( / / -7 / / ® wherein -Di is 16.8 MPa0'5, - Pi is 4.8 MPa0'5, and - 7 / 1 is 13.0 MPa0'5, preferably wherein at least one of the one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a) is selected from polycitronellol acetate, caprylic / capric triglyceride, isododecane, isohexadecane, tetradecane, isopropyl myristate, isopropyl alcohol, octyldodecanol, phenoxyethanol, castor oil, or mixtures thereof.

3. The method of claims 1 or 2, wherein the first anhydrous composition comprises: (a) about 10 to about 40 weight percent of the hydrophobic polymer; (b) about 45 to about 75 weight percent of the one or more solvents capable of solubilizing the hydrophobic polymer of (i)(a); and (c) about 1 to about 25 weight percent of the one or more alkanes; wherein all weight percentages are based on a total weight of the first anhydrous composition.

4. A method according to any one of the preceding claims, wherein the first anhydrous composition comprises the one or more alkanes and the one or more alkanes are selected from C6-C16 alkanes, preferably wherein the one or more alkanes are selected from isododecane, isodecane, isohexadecane, n-heptane, n-octane, n-nonane, n-decane, n-undecane, n-dodecane, n-tetradecane, n-tridecane, n-tetradecane, n-pentadecane, or mixtures thereof.

5. A method according to any preceding claim, wherein the first anhydrous composition comprises: (a) about 10 to about 40 weight percent of the hydrophobic polymer; (b) about 45 to about 75 weight percent of polycitronellol acetate; and (c) about 1 to about 25 weight percent of isododecane; wherein all weight percentages are based on a total weight of the first anhydrous composition.

6. A method according to any preceding claim, wherein the one or more non-polar oils in which the hydrophobic polymer of (i)(a) is not soluble are selected from squalane, isoparaffin (C12-C14), cycloparaffin, polydecene, polydimethylsiloxane, squalene, hydrogenated polyisobutene, isohexadecane, mineral oil, isoeicosane, ethoxydiglycol oleate, decyl olivate, or mixtures thereof.

7. A method according to any preceding claim, wherein the second anhydrous composition further comprises one or more oil thickening agents, for example one or more oil thickening agents selected from polymers, gums, organoclays, polyethylenes, silica, or mixtures thereof, more preferably wherein the one or more oil thickening agents are selected from acrylate copolymer, hectorite gel, guar gum, cellulose gum, Caesalpinia Spinosa gum, gum arabic, starch, silica, silica dimethyl silylate, behenate, glyceryl dibehenate, behenyl behenate, or mixtures thereof.

8. A method according to any preceding claim, wherein the second anhydrous composition further comprises one or more solid fatty compounds, wherein preferably the one or more solid fatty compounds are selected from waxes and solid fatty alcohols, for example, candelilla wax, carnauba wax, castor wax, beeswax, lanolin wax, ozokerite wax, microcrystalline wax, sunflower wax, tribehenin, cetyl alcohol, stearyl alcohol, cetearyl alcohol, lanolin alcohol, or mixtures thereof.

9. A method according to any preceding claim, wherein the second anhydrous composition comprises: a. about 70 to about 99.9% by weight of the one or more non-polar oils in which the hydrophobic polymer of (i)(a) is not soluble; b. optionally, about 1 to about 15% by weight of one or more oil thickening agents; and c. optionally, about 1 to about 15% by weight of one or more waxes; wherein all weight percentages are based on a total weight of the second anhydrous composition.

10. A method of removing makeup from skin, comprising: (i) applying a first anhydrous composition to skin on which makeup is present, the first anhydrous composition comprising: (a) about 10 to about 40% by weight of a hydrophobic polymer that is a reaction product of linseed oil and poly(isobutyl methacrylate); (b) about 45 to about 75% by weight of polycitronellol acetate; and (c) about 1 to about 25% by weight of isododecane; wherein all weight percentages of (i) are based on a total weight of the first anhydrous composition, and wherein preferably the first anhydrous composition is transparent; and (ii) applying a second anhydrous composition to the skin on which the makeup and the first anhydrous composition are present, the second anhydrous composition comprising: (a) about 70 to 95% by weight of one or more non-polar oils in which the hydrophobic polymer of (i)(a) is not soluble; (b) optionally, about 1 to about 15% by weight of one or more oil thickening agents; and (c) optionally, from about 1 to about 15% by weight of one or more waxes; wherein all weight percentages of (ii) are based on a total weight of the second anhydrous composition.