Composition comprising at least one (C1-C6) alkyl acrylic acid polymer, hyaluronic acid and a hydrophilic gelling agent

Abstract

Composition comprising at least one (C1-C6)alkyl acrylic acid polymer, hyaluronic acid, and a hydrophilic gelling agent. The present invention relates to a composition, particularly a cosmetic one, comprising at least one polymer derived from (C1-C6)alkyl acrylic acid or one of its salts, less than 0.15% by weight relative to the total weight of the composition, hyaluronic acid and / or one of its salts, and at least one hydrophilic gelling agent distinct from the polymer derived from (C1-C6)alkyl acrylic acid or one of its salts and from hyaluronic acid and / or its salts. It also relates to a cosmetic treatment method for skincare, particularly for oily skin, comprising the application of a cosmetic composition according to the invention. Figure for abstract: none

Description

Title of the invention: Composition comprising at least one (CrC6)alkyl acrylic acid polymer, hyaluronic acid and a hydrophilic gelling agent

[0001] The present invention relates to a composition, particularly a cosmetic one, comprising at least one polymer derived from (C1-C6)alkyl acrylic acid or one of its salts, less than 0.15% by weight relative to the total weight of the hyaluronic acid composition and / or one of its salts, and at least one hydrophilic gelling agent distinct from the polymer derived from (C1-C6)alkyl acrylic acid or one of its salts and from the hyaluronic acid and / or its salts. It also relates to a cosmetic treatment method for skincare, particularly for oily skin, comprising the application of a cosmetic composition according to the invention.

[0002] Sebum normally acts as a moisturizing agent for the epidermis. It is the natural product of the sebaceous gland, which is an extension of the pilosebaceous unit. It is essentially a more or less complex mixture of lipids. Typically, the sebaceous gland produces squalene, triglycerides, aliphatic waxes, cholesterol waxes, and possibly free cholesterol.

[0003] Hyperseborrheic oily skin is characterized by excessive secretion and excretion of sebum. Classically, a sebum level exceeding 200 pg / cm² measured on the forehead is considered characteristic of such oily skin. This type of skin is also often associated with poor desquamation, a shiny complexion, and / or a thick skin texture, i.e., manifestations perceived as skin imperfections or aesthetic disorders.

[0004] Skin shine is generally linked to a significant secretion of sebum, but can also be linked to sweat, result from physical activity or climatic conditions (heat, humidity); it can also be due to the combination of the two phenomena (sebum and sweat).

[0005] In addition to the active ingredients that prevent and / or treat this significant sebum secretion, compositions are sought that have an appearance that is consistent with the purpose for which this composition is used by the consumer.

[0006] Thus, a composition with minimal shine, a granite / sorbet appearance and a gliding effect on application to the skin is highly sought after by users, especially those with combination or oily skin, as it gives a perception of lightness and freshness while ensuring a certain comfort during application.

[0007] There is therefore a need for cosmetic compositions, particularly those adapted to oily or oily-prone skin, that have good sensory properties, namely a minimal shine (i.e. very slightly shiny) and a granite / sorbet appearance while maintaining a smooth effect when applied to the skin.

[0008] The Applicant has now discovered that a composition comprising at least one polymer derived from (Ci-C6)alkyl acrylic acid, hyaluronic acid or one of its salts in a certain content and at least one hydrophilic gelling agent distinct from the polymer derived from (Ci-C6)alkyl acrylic acid and hyaluronic acid, exhibits both minimal shine, a granite / sorbet-like appearance and a good glide effect when applied to the skin.

[0009] Thus, the object of the invention is a composition, in particular a cosmetic one, comprising:

[0010] i) at least one polymer derived from (Ci-C6)alkyl acrylic acid or one of its salts, comprising a repetition of formula units (I):

[0011] [Chem.l]

[0012] formula (I) in which:

[0013] * R1 and R2, whether identical or different, represent a hydrogen atom or a (Ci-C6)alkyl group such as methyl, preferably R1 and R2 represent a hydrogen atom,

[0014] * M+ represents a cationic counterion, preferably an alkali metal, alkaline- earthy or ammonium, more preferably M+ represents an alkali metal such as sodium;

[0015] ii) less than 0.15% by weight relative to the total weight of composition, of hyaluronic acid and / or one of its salts, and

[0016] iii) at least one hydrophilic gelling agent distinct from the polymer derived from (Cl-C6)alkyl acrylic acid or one of its salts and hyaluronic acid and / or its salts.

[0017] Such a composition according to the invention is advantageous in several respects: it gives the user a perception of freshness and lightness upon application due to its minimal shine (i.e. very slightly shiny) and its granite appearance (like finely crushed ice), while maintaining a certain comfort thanks to a gliding effect when applied to the skin.

[0018] For the purposes of this invention, "granite" describes an appearance with a slightly grainy, frosted effect. A granite appearance is synonymous with a frosted texture; a "frosted texture" is understood to be a composition with a sorbet-like appearance that melts on the skin upon application. Such a frosted texture is characterized, in particular, by the presence of agglomerates distributed homogeneously throughout the composition.

[0019] The granite effect and minimal gloss of the composition according to the invention are visual characteristics of the composition, which can in particular be evaluated in its container such as a jar, and are particularly interesting in the context of compositions intended for the treatment of oily skin, because they give the consumer the perception of a light and fresh texture.

[0020] The gliding effect of the composition according to the invention can be evaluated by determining the number of turns that can be made on the skin during a defined time, for example the number of turns for 15 seconds after application of the composition to the skin.

[0021] Advantageously, the composition according to the invention has a viscosity of less than 40 Pa.s, preferably a viscosity of 20 to 40 Pa.s, more preferably of 25 to 40 Pa.s, even better of 30 to 40 Pa.s.

[0022] The viscosity measurement is carried out at 30°C, using an Ametek Brookfield HADV2T viscometer equipped with a No. 6 wheel such as the reference HA-6, the measurement being carried out after 1 minute of rotation of the wheel within the composition (time at the end of which a stabilization of the viscosity and the rotation speed of the wheel is observed), at a speed of 10 revolutions / min (rpm).

[0023] The invention also relates to a cosmetic treatment method for skin care, in particular oily skin, comprising the application of a cosmetic composition according to the invention.

[0024] For the purposes of the present invention, and unless otherwise indicated:

[0025] By "polymer(s)" we mean one or more homopolymer(s) (i.e. resulting from the polymerization of identical synthons), one or more copolymer(s) (i.e. resulting from the polymerization of different synthons), or their mixtures i.e. homopolymers and copolymers.

[0026] By "(C j -C 6 )alkyl group", we mean a saturated hydrocarbon radical, linear or branched, in Ci-C6, preferably in Ci-C4.

[0027] By "cationic counter-ion" is meant a cation or a cationic group from an organic or mineral base salt counterbalancing the anionic charge of the ingredients of formula (!') or (II'); more particularly the cationic counter-ion is chosen from alkali metals such as sodium, potassium, preferably Na+; alkaline earth metals such as calcium; ammonium (R)4N+ with R, identical or different, represents a hydrogen atom or a (Ci-C6)alkyl group optionally substituted by one or more hydroxy groups, preferably R represents a hydrogen atom or a (Ci-C4)alkyl group such as methyl.

[0028] The term “composition comprising a physiologically acceptable medium” means a composition comprising a medium compatible with the skin.

[0029] The term "skin" refers to all the skin on the human body, and preferably includes the skin of the face, scalp, décolletage, neck, arms and forearms, or even more preferably, the skin of the face, particularly the forehead, nose, cheeks, chin, and around the eyes. Preferably, the skin concerned according to the invention is oily skin, i.e., skin with an excess of sebum. (Cl-C6)alkyl acrylic acid polymer

[0030] The composition of the invention comprises i) one or more polymer(s) derived from (Ci-C6)alkyl acrylic acid or one of its salts, as defined above.

[0031] Preferably, the polymer(s) i) is / are chosen from homopolymers.

[0032] According to another embodiment of the invention, the polymer(s) of i) is / are chosen from among the copolymers.

[0033] According to a particular embodiment of the invention, the polymer(s) i) comprise a repetition of formula units (I) and formula unit(s) (II):

[0034] -[CH(R')-C(R2)(COO M+)]-(I) and -[CH(R')-C(R2)(COOH)]- (II)

[0035] formulas (I) and (II) in which R 1 and R 2, and M + are such as defined previously.

[0036] According to a particular embodiment of the invention, the polymer(s) i) comprise a repetition of formula units (I) and formula unit(s) (II):

[0037] -[CH(R')-C(R2)(COO M+)]y-(I) and -[CH(R1)-C(R2)(COOH)]z- (II)

[0038] formulas (I) and (II) in which R 1 and R 2, and M + are as defined above, and

[0039] * y represents an integer greater than or equal to 2;

[0040] * z is zero, or represents a number greater than zero; preferably y > z.

[0041] According to a particular embodiment, the polymer(s) i) of the invention consists of a repetition of unit of formula (I) and formula (II).

[0042] According to a preferred embodiment of the invention, the polymer(s) i) of the invention comprise (preferably consist of) a repetition of units of formula (I) and formula (II) in which the molar number of units of formula (I) is greater than or equal to the molar number of units of formula (II), preferably the molar number of units of formula (I) is greater than the molar number of units of formula (II).

[0043] According to a particular embodiment, the polymer(s) i) of the invention comprise (preferably consist of) a repetition of unitless formula units (I) (II).

[0044] According to another particular embodiment, the polymer(s) of the invention i) comprise (preferably consist of) a repetition of units of formula (I) and of formula (II) in which the molar number of units of formula (II) is greater than the molar number of units of formula (I).

[0045] The neutralized polymer(s) i) may be totally or partially neutralized. Preferably, the polymer(s) i) is / are partially neutralized, preferably by a metal salt, more preferably by an alkali metal salt, and even more preferably by a sodium salt.

[0046] According to a particular embodiment, in the polymer(s) of the invention, the molar ratio of the neutralized parts (units of formula (I)) to the non-neutralized parts (units of formula (II)) is at least 10%, particularly at least 20%, more particularly at least 30%, even more particularly at least 40%, or even at least 50% and / or particularly at most 90%, more particularly at most 80%, even more particularly at most 70%, better at most 60%.

[0047] According to a particular embodiment of the invention, the composition comprises one or more polymer(s) i) as defined above comprising (preferably consisting of) a repetition of formula units (I) and unit units (II) in which R1 and R2 represent a hydrogen atom or a (Ci-C4)alkyl group such as methyl, preferably a hydrogen atom.

[0048] According to a particular embodiment of the invention, the composition comprises one or more polymer(s) i) as defined above in which M+ represents a cationic counter-ion selected from an alkali metal, alkaline earth metal and ammonium, preferably M+ represents an alkali metal such as sodium.

[0049] In particular, the polymer(s) i) as defined above is / are chosen from among the "superabsorbents", i.e. the polymer(s) is / are capable of absorbing at least 20 times its / their weight in water (i.e. at least 20 grams of water absorbed per gram of superabsorbent polymer - the water absorbance characteristics being defined at room temperature, 25 °C, and atmospheric pressure (1 atm.) with distilled water), more particularly at least 50 times its / their weight in water, more particularly capable of absorbing at least 80 times its / their weight in water, preferably the polymer(s) of formula (I) is / are capable of absorbing at least 100 times its / their weight in water.

[0050] The water-absorbing capacity of the polymer(s) can be determined, for example, by dispersing 5 grams (g) of polymer(s) in 150 g of water and waiting 5 minutes (min.) to 30 min., such as 20 min., filtering the solution through a 150 mm filter in 20 min and weighing the unabsorbed water.

[0051] According to a particular embodiment of the present invention, the polymer(s) i) as defined above may have a water absorption capacity of 10 g or more, preferably 20 g or more, and more preferably 50 g or more, and / or 2,000 g or less, preferably 1,500 g or less, and more preferably 1,000 g or less, relative to 1 g of the polymer at 25 °C and 1 atm.

[0052] The polymer(s) of the invention i) as defined above is / are particularly derived from the polymerization of:

[0053] a) several monomers, identical (in which case they will be homopolymers) or different (in which case they will be copolymers), chosen from:

[0054] - (alkyl)acrylic acids of the following formula (II') HC(R 1 )=C(R 2 )-C(O)OH,

[0055] - the salts of the following formula (I') HC(R 1 )=C(R 2 )-C(O)O ' M + and

[0056] - mixtures of monomers (I') and (II'), as well as their optical isomers, and / or geometric isomers,

[0057] it being understood that in formulas (I') and (II'), R1, R2 and M+ are as defined previously;

[0058] b) in the presence of a polymerization initiator (UV-initiator) to lead to polymers of formula (I) as defined above.

[0059] According to a particular embodiment of the invention, the polymer(s) of the invention i) as defined above is / are obtained from the polymerization of monomers of formula (II'), said polymer(s) then being neutralized by the use of at least one alkaline agent, preferably the alkaline agent is inorganic, in particular chosen from alkali or alkaline-earth metal hydroxides such as soda, potash, alkali or alkaline-earth metal (bi)carbonates, preferably chosen from sodium (bi)carbonate and soda, more preferably soda.

[0060] Preferably R1 represents a hydrogen atom, R2 represents a hydrogen atom or an (Ci-C4)alkyl group such as methyl, more preferably R2 represents a hydrogen atom; and M+ preferably represents an alkali metal such as sodium or potassium, more preferably sodium.

[0061] In addition, the polymer(s) i) as defined above and the monomers (!') and / or (II') is / are capable of crosslinking in the presence of one or more crosslinking agent(s), said agent(s) may be applied, for example, by spraying, to the surface of said polymer(s), said polymer(s) being more particularly in the form of particles.

[0062] The polymer(s) of i) as defined above may be in the form of particles.

[0063] The polymer(s) i) as defined above is / are preferably in the form of particles and preferably spherical. The average size of the primary particles as D50 (particularly non-hydrated particles) of the polymer(s) i) as defined above is not particularly limited, is generally 0.1 µm or more, preferably 0.5 µm or more, and more preferably 1 µm or more, and / or is 200 µm or less, preferably 100 µm or less, more preferably 50 µm or less.

[0064] The term "D50" here designates the particle size for which 50% of the particle volume, based on the total particle volume, has a particle size less than or equal to D50.

[0065] The D50 value can be determined by laser diffraction, for example using a laser diffraction particle size distribution analyzer, such as the Mastersizer 2000 from Malvem Corp.

[0066] The polymer(s) i) as defined may be soluble in water, the polymer(s) i) being able to be included in the aqueous phase, including water, of the composition according to the present invention.

[0067] According to one embodiment of the invention, once hydrated, said particles swell into soft particles having an average diameter inclusively between 10 µm and 300 µm, more particularly between 20 µm and 200 µm, and even more particularly between 40 µm and 150 µm. The particle sizes correspond to the primary particle sizes.

[0068] According to a particular embodiment of the invention, the particles of the polymer(s) i) is / are not swollen and have / have an average particle size (average diameter) of between 2 µm and 10 µm, particularly between 4 µm and 50 µm, more particularly between 5 µm and 30 µm, preferably between 10 µm and 20 µm. The particle sizes correspond to the primary particle sizes.

[0069] The polymer(s) i) as defined above is / are preferably crosslinked, and more preferably in the form of particles.

[0070] In a preferred embodiment, the polymer(s) i) as defined above is / are chosen from among the crosslinked homopolymers.

[0071] Among the preferred polymers i) of the invention, one can mention alkali, alkaline earth or ammonium metal polyacrylates, preferably alkali or alkaline earth metal polyacrylates, more preferably alkali metal polyacrylates such as sodium acrylates, for example that sold under the name of AQUPEC in particular AQUPEC MG N40R, crosslinked and partially neutralized and also called sodium carbomer (or "sodium carbomer" or carbopol), more particularly the polymer(s) i) is / are chosen from among the carbomers, preferably S carbomer or sodium carbomer.

[0072] The quantity in the composition of polymer(s) i) as defined above is particularly at least 0.5% by weight, more particularly at least 0.7% by weight, and more preferably at least 1% by weight relative to the total weight of the composition.

[0073] The quantity in the composition of polymer(s) i) as defined above is particularly at most 10% by weight, preferably at most 5% by weight, and more preferably at most 3% by weight, relative to the total weight of the composition.

[0074] Particularly the quantity in the composition of polymer(s) i) such as defined above shall be from 0.5% to 5% by weight, preferably from 0.7% to 4% by weight, and more preferably from 1% to 3% by weight, better from 1% to 2% relative to the total weight of the composition. Hyaluronic acid and / or one of its salts

[0075] The composition according to the invention also comprises hyaluronic acid and / or one of its salts ii), in a content less than or equal to 0.15% by weight relative to the total weight of the composition.

[0076] Hyaluronic acid belongs to the glycosaminoglycan (GAG) family.

[0077] GAGs are linear chains composed of repeating basic disaccharides that always contain a hexosamine (glucosamine or galactosamine) and another sugar (glucuronic acid, iduronic acid, or galactose). The glucosamine is either N-sulfated or N-acetylated. In contrast, the galactosamine is always N-acetylated. Furthermore, there may be O-linked sulfates on the hexosamine, iduronic acid, and galactose.

[0078] Hyaluronic acid or hyaluronan (HA) is the main GAG of the dermis, the latter containing half of the HA in the body.

[0079] It is a polysaccharide of disaccharides themselves composed of D-glucuronic acid and N-acetylglucosamine, linked together by alternating beta-1,4 and beta-1,3 glycosidic bonds. It plays an important role in the hydration and elasticity of the skin.

[0080] Examples of hyaluronic acid salts include potassium hyaluronate and sodium hyaluronate.

[0081] Preferably, sodium hyaluronate will be used according to the invention.

[0082] In particular, sodium hyaluronate with a molecular weight of 1,100,000 Daltons, marketed by the company SOLIANCE under the name CRISTALHYAL®, may be used in the composition of the invention.

[0083] Hyaluronic acid or one of its salts, or mixtures thereof, may be present in the composition according to the invention in an amount less than 0.13%. weight (of dry matter) and preferably at least 0.0001% by weight (of dry matter) relative to the total weight of the composition.

[0084] In a preferred embodiment, hyaluronic acid or one of its salts or mixtures is present in the composition according to the invention in an amount ranging from 0.0001% to 0.15% by weight (dry matter) relative to the total weight of the composition, preferably ranging from 0.01% to 0.13% by weight (dry matter), even better ranging from 0.05% to 0.12% by weight (dry matter) relative to the total weight of the composition. Hydrophilic gelling agent

[0085] The composition according to the invention comprises at least one hydrophilic gelling agent iii). It may preferably comprise a mixture of several hydrophilic gelling agents.

[0086] Of course, the hydrophilic gelling agent iii) is distinct from the polymer derived from (Cl-C6)alkyl acrylic acid or one of its salts i) and also distinct from hyaluronic acid and / or its salts ii).

[0087] Advantageously, the composition according to the invention comprises at least one hydrophilic gelling agent selected from sulfonic group polymers, polysaccharides and mixtures thereof.

[0088] The hydrophilic gelling agent(s) may be present in the composition according to the invention in a content ranging from 0.01% to 5%, and preferably from 0.1% to 3%, and even more preferably from 0.1% to 1% by weight relative to the total weight of said composition.

[0089] Polymer with a sulfonic group

[0090] By "sulfonic group polymer" is meant a polymer of poly(2-acrylamido 2-methylpropane sulfonic acid), their salts or mixtures thereof, preferably a homo- or copolymer of a monomer with a sulfonic group, their salts or mixtures thereof.

[0091] These are water-soluble polymers, dispersible in water or inflatable in water. These polymers used according to the invention are homo- or copolymers that can be obtained from at least one monomer with ethylenic unsaturation and a sulfonic group, which may be in free form or partially or totally neutralized.

[0092] Preferably, the sulfonic group polymers used according to the invention can be partially or completely neutralized by a mineral base (such as sodium hydroxide, potassium hydroxide, or aqueous ammonia) or an organic base such as mono-, di-, or triethanolamine, aminomethylpropanediol, N-methylglucamine, or basic amino acids such as arginine or lysine, or mixtures of these compounds. They are generally neutralized. In the present invention, the term "neutralized" is intended to designate polymers that have been completely or almost completely neutralized, that is, neutralized to at least 90%.

[0093] The sulfonic group polymers used in the composition of the invention generally have a number average molecular mass ranging from 1000 to 20,000,000 g / mol, preferably ranging from 20,000 to 5,000,000, and even more preferably from 100,000 to 1,500,000 g / mol.

[0094] Monomers with a sulfonic group are selected in particular from vinylsulfonic acid, styrenesulfonic acid, (meth)acrylamido-(Cl-C22)alkylsulfonic acids, N-(Cl-C22)alkyl-(meth)acrylamido-(Cl-C22)-alkylsulfonic acids such as undecyl-acrylamido-methane-sulfonic acid, as well as their partially or totally neutralized forms, and their mixtures.

[0095] According to a preferred embodiment of the invention, the sulfonic group monomers are selected from (meth)acrylamido(Cl-C22)alkylsulfonic acids such as, for example, acrylamido-methane-sulfonic acid, acrylamido-ethane-sulfonic acid, acrylamido-propane-sulfonic acid, 2-acrylamido-2-methylpropane-sulfonic acid, 2-methacrylamido-2-methylpropane-sulfonic acid, 2-acrylamido-n-butane-sulfonic acid, 2-acrylamido-2,4,4-trimethylpentane-sulfonic acid, 2-methacrylamido-dodecyl-sulfonic acid, 2-acrylamido-2,6-dimethyl-3-heptane-sulfonic acid, as well as their partially or totally neutralized forms, and mixtures thereof.

[0096] These polymers according to the invention can be crosslinked or non-crosslinked.

[0097] When polymers are crosslinked, the crosslinking agents can be chosen from among the olefinic polyunsaturated compounds commonly used for crosslinking polymers obtained by radical polymerization.

[0098] Examples of crosslinking agents include divinylbenzene, diallyl ether, dipropylene glycol diallyl ether, polyglycol diallyl ether, triethylene glycol divinyl ether, hydroquinone diallyl ether, ethylene glycol di(meth)acrylate, tetraethylene glycol di(meth)acrylate, trimethylolpropane triacrylate, methylenebisacrylamide, methylenebismethacrylamide, triallylamine, triallyl cyanurate, diallyl maleate, tetraallylethylenediamine, tetraallyloxyethane, trimethylolpropane diallyl ether, allyl(meth)acrylate, allyl ethers of alcohols, as well as allylic esters of phosphoric acid derivatives and / or vinylphosphonic acid derivatives, or mixtures of these compounds. According to a preferred embodiment of the invention, the crosslinking agent is chosen from methylene-bis-acrylamide, allyl methacrylate or trimethylol propane triacrylate (TMPTA).

[0099] The degree of crosslinking generally varies from 0.01 to 10% by mole, and more particularly from 0.2 to 2% by mole, relative to the polymer.

[0100] Preferably, the sulfonic group polymer is chosen from homo- and copolymers of 2-acrylamido-2-methylpropane sulfonic acid, their salts and mixtures thereof.

[0101] Even more preferably, the sulfonic group polymer is chosen from among the homopolymers of 2-acrylamido-2-methylpropane sulfonic acid, their salts and mixtures thereof.

[0102] The particularly preferred 2-acrylamido 2-methylpropane sulfonic acid homopolymers comprise, randomly distributed, motifs of the following general formula (III):

[0103] [Chem.2] (III)

[0104] in which X+ designates a proton, an alkali metal cation, an alkaline earth cation or the ammonium ion, at most 10 mol% of the X+ cations being H+ protons;

[0105] and crosslinking motifs from at least one monomer having at least two olefinic double bonds.

[0106] The homopolymers used according to the invention and more particularly preferred comprise from 90 to 99.9% by weight and preferably from 98 to 99.5% by weight of formula (III) motifs, and from 0.01 to 10% by weight, preferably from 0.2 to 2% by weight of crosslinking motifs, the proportions by weight being defined in relation to the total weight of the polymer.

[0107] Preferred homopolymers of this type are selected from polymers, crosslinked or not, of sodium 2-acrylamido-2-methyl propane sulfonate such as that used in the commercial product SIMULGEL 800 (CTFA name: Sodium Polyacryloyldimethyl Taurate), or crosslinked polymers of ammonium 2-acrylamido-2-methyl propane sulfonate (INCI name: AMMONIUM POLYACRYLDIMEHYLTAURAMIDE) such as the product sold under the trade name HOSTACERIN AMPS® by the Clariant company.

[0108] Preferred 2-acrylamido-2-methylpropanesulfonic acid copolymers are selected from:

[0109] - copolymers of 2-acrylamido-2-methylpropane sulfonic acid and acrylamide, for example of the SEPIGEL or SIMULGEL type marketed in particular by the company SEPPIC. As non-limiting examples of such copolymers, we can cite for example the crosslinked anionic acrylamide / 2-acrylamido 2-methylpropane sulfonic acid copolymers, in the form of an O / W emulsion, such as those marketed under the name Sepigel 305 (INCI name: polyacrylamide (and) C13-14 isoparaffin (and) laureth-7) and under the name Simulgel 600 (INCI name: acrylamide / sodium acryloyldimethyltaurate copolymer (and) isohexadecane (and) polysorbate 80) by the company SEPPIC;

[0110] - copolymers of 2-acrylamido 2-methylpropanesulfonic acid and vinylpyrrolidone or vinylformamide such as that used in the commercial product sold under the name ARISTOFLEX AVC® by the company CLARIANT (CTFA name: AMMONIUM ACRYLOYLDIMETHYLTAURATE / VP COPOLYMER) but neutralized by sodium hydroxide or potassium hydroxide;

[0111] - 2-acrylamido-2-methylpropanesulfonic acid and acrylate copolymers sodium, such as for example the 2-acrylamido 2-methylpropane sulfonic acid / sodium acrylate copolymer such as that used in the commercial product sold under the name SIMULGEL EG® by the company SEPPIC or under the trade name SEPINOV EM under (CTFA name: HYDROXYETHYL ACRYLATE / SODIUM ACRYLOYLDIMETHYL TAURATE COPOLYMER);

[0112] - 2-acrylamido 2-methylpropanesulfonic acid copolymers and of hydroxyethyl acrylate, such as for example the 2-acrylamido 2-methylpropane sulfonic acid / hydroxyethyl acrylate copolymer such as that used in the commercial product sold under the name SIMULGEL NS® by the company SEPPIC (CTFA name: HYDROXYETHYL ACRYLATE / SODIUM ACRYLOYLDIMETHYLTAURATE COPOLYMER (AND) SQUALANE (AND) POLYSORBATE 60) or such as the product marketed under the name SODIUM ACRYLAMIDO-2-METHYL PROPANE SULFONATE / HYDROXYETHYLACRYLATE such as the commercial product SEPINOV EMT 10 (INCI name: HYDROXYETHYL ACRYLATE / SODIUM ACRYLOYLDIMETHYL TAURATE COPOLYMER);

[0113] - 2-acrylamido 2-methylpropanesulfonic acid copolymers and of cetearyl ethoxylated methacrylate, possibly cross-linked, such as Aristoflex® HMS, which bears the name of 2-acrylamido 2-methylpropane sulfonic acid / cetearyl ethoxylated methacrylate (25 EO) 80 / 20 copolymer, cross-linked by trimethylolpropane triacrylate (TMPTA) or Ammonium Acryloyldimethyltaurate / Steareth-25 methacrylate crosspolymer in INCI name;

[0114] - and their mixtures.

[0115] Preferably, the sulfonic group polymer is a crosslinked homopolymer of ammonium 2-acrylamido-2-methyl propane sulfonate (INCI name: AMMONIUM POLYACRYLDIMEHYLTAURAMIDE) such as the product sold under the trade name HOSTACERIN AMPS® by Clariant.

[0116] Polysaccharide

[0117] Generally, the polysaccharides according to the invention can be chosen from polysaccharides produced by microorganisms; polysaccharides isolated from algae and polysaccharides from higher plants, such as homogeneous polysaccharides, in particular celluloses and their derivatives or fructans, heterogeneous polysaccharides such as gum arabic, galactomannans, glucomannans, pectins, and their derivatives.

[0118] In particular, the polysaccharides may be selected from fructans, gellans, glucans, amylose, amylopectin, glycogen, pullulan, dextran, celluloses and their derivatives, in particular methylcelluloses, hydroxyalkylcelluloses, ethylhydroxyethylcelluloses and carboxymethylcelluloses, mannans, xylans, lignins, arabans, galactans, galacturonans, alginate-based compounds, chitin, chitosan, glucuronoxylans, arabinoxylans, xyloglucans, glucomannans, pectic acids and pectins, arabinogalactans, carrageenans, agars, gum arabic, tragacanth gum, ghatti gum, karaya gum, gums of carob, galactomannans such as guar gum and their non-ionic derivatives, particularly hydroxypropyl guar, and ionic biopolysaccharide gums of microbial origin,in particular scleroglucan or xanthan gums, or polysaccharides comprising fucose, galactose and galacturonic acid units such as biosaccharide gum-1, mucopolysaccharides, and in particular chondroitin sulfate and mixtures thereof.

[0119] Advantageously, a composition according to the invention comprises, as a hydrophilic gelling agent, at least one polysaccharide selected from carrageenans, in particular kappa-carrageenan, gellan gum, agar-agar, xanthan gum, alginate-based compounds, in particular sodium alginate, sceroglucan gum, guar gum, inulin, pullulan and mixtures thereof.

[0120] These polysaccharides can be chemically modified, in particular by urea, urethane groups, or by hydrolysis, oxidation, esterification, etherification, sulfation, phosphatation, amination, amidation, alkylation, or several of these modifications.

[0121] The derivatives obtained can be anionic, cationic, amphoteric or non-ionic.

[0122] Advantageously, the polysaccharides can be selected from carrageenans, in particular kappa-carrageenan, gellan gum, agar-agar, xanthan gum, alginate-based compounds, in particular sodium alginate, sceroglucan gum, guar gum, inulin, pullulan and mixtures thereof.

[0123] Generally speaking, compounds of this type, usable in the present invention, are chosen from those described in particular in "Encyclopedia of Chemical Technology, Kirk-Othmer, Third Edition, 1982, volume 3, pp. 896-900, and volume 15, pp. 439-458", in "Polymers in Nature, by EA McGREGOR and CT GREENWOOD, Editions John Wiley & Sons, Chapter 6, pp. 240-328, 1980", in the work by Robert L. DAVIDSON entitled "Handbook of Water soluble gums and resins" published by McGraw Hill Book Company (1980) and in Industrial Gums "Polysaccharides and their Derivatives, Edited by Roy L. WHISTLER, Second Edition, Edition Academie Press Inc.".

[0124] According to a preferred method, the polysaccharide is selected from xanthan gum, alginate-based compounds, in particular sodium alginate, sceroglucan gum, guar gum and mixtures thereof.

[0125] According to a preferred embodiment, the polysaccharide is xanthan gum.

[0126] Xanthan gums have a molecular weight of between 1,000,000 g / mol and 50,000,000 g / mol and a viscosity of between 0.6 and 1.65 Pa.s for an aqueous composition containing 1% xanthan gum (measured at 25 °C using a Brookfield viscometer, type LVT at 60 revolutions per minute).

[0127] Xanthan gums are represented for example by the products sold under the names Rhodicare by the company RHODIA CHIMIE, under the name SATIAXANE™ by the company Cargill Texturizing Solutions (for the food, cosmetic and pharmaceutical industries), under the name NOVAXAN™ by the company ADM, and under the names Kelzan® and Keltrol® by the company CP-Kelco.

[0128] In a preferred embodiment, the composition according to the invention comprises at least one hydrophilic gelling agent iii) selected from sulfonic group polymers, polysaccharides, and mixtures thereof. In a preferred embodiment, the composition according to the invention comprises at least one hydrophilic gelling agent selected from a crosslinked homopolymer of ammonium 2-acrylamido-2-methylpropane sulfonate, xanthan gum, and mixtures thereof. Physiologically acceptable environment

[0129] In addition to the compounds indicated above, the composition according to the invention comprises a physiologically acceptable medium.

[0130] The physiologically acceptable medium is generally adapted to the nature of the support on which the composition is to be applied, as well as to the appearance in which the composition is to be packaged.

[0131] The cosmetic compositions of the invention are preferably in the form of an O / W emulsion.

[0132] The physiologically acceptable medium may include water and optionally one or more solvent(s) miscible with water.

[0133] According to a preferred embodiment, the compositions of the invention comprise at least 20% by weight of water, in particular at least 40% by weight of water relative to the total weight of said composition.

[0134] Preferably, the composition according to the invention has a water content ranging from 20% to 95% by weight, even better from 40% to 90% by weight relative to the total weight of the composition.

[0135] A suitable water for the invention may be a floral water such as cornflower water and / or a mineral water such as VITTEL water, VICHY water or LA ROCHE POSAY water and / or a thermal water.

[0136] Among the water-miscible organics (at room temperature 25°C) one or more cosmetically acceptable organic solvents may be mentioned, which may be alcohols: in particular monovalent alcohols such as ethyl alcohol, propanediol, isopropyl alcohol, benzyl alcohol and phenylethyl alcohol; diols such as ethylene glycol, propylene glycol, butylene glycol and pentylene glycol; and ethers such as monomethyl, monoethyl and monobutyl ethers of ethylene glycol, monomethyl, monoethyl and monobutyl ethers of propylene glycol, and monomethyl, monoethyl and monobutyl ethers of butylene glycol, and glycerin.

[0137] The water-miscible organic solvent(s) may be present in a concentration of 0.01% to 30% by weight, preferably 0.1% to 20% by weight and more preferably 1% to 15% by weight, relative to the total weight of the composition.

[0138] The composition according to the invention may also include any water-soluble or water-dispersible compound such as film-forming polymers, surfactants and mixtures thereof.

[0139] The composition according to the invention may also include at least one fatty substance such as one or more oil(s).

[0140] The term "oil" refers to any fatty substance in liquid form at ambient temperature (20-25°C) and atmospheric pressure. These oils may be of vegetable, mineral, or synthetic origin.

[0141] Examples of oils that can be used in the composition of the invention include: - hydrocarbon oils, particularly those of vegetable origin; - synthetic esters and ethers, particularly of fatty acids, such as oils with formulas R1COOR2 and R1OR2 in which RI represents the remainder of a fatty acid containing 8 to 29 carbon atoms, and R2 represents a hydrocarbon chain, branched or unbranched, containing 3 to 30 carbon atoms; - linear or branched hydrocarbons, of mineral or synthetic origin; - fatty alcohols having from 8 to 26 carbon atoms; - partially hydrocarbon and / or silicone-based fluorinated oils; - silicone oils; - their mixtures.

[0142] The term hydrocarbon oil in the list of oils cited above means any oil consisting mainly of carbon and hydrogen atoms, and possibly ester, ether, fluorinated, carboxylic acid and / or alcohol groups.

[0143] According to a preferred embodiment of the invention, the composition used in the context of the invention is a water-in-oil (W / O) or oil-in-water (O / W) emulsion, preferably oil-in-water (O / W). The proportion of fatty substances in the emulsion can range from 1 to 90% by weight, and preferably from 1 to 60% by weight relative to the total weight of the composition.

[0144] The composition may include at least one emulsifier. Emulsions generally contain at least one emulsifier selected from amphoteric, anionic, cationic, or nonionic emulsifiers, used alone or in mixtures, and optionally a co-emulsifier. The emulsifiers are chosen appropriately depending on the emulsion to be obtained (W / O or W / O).

[0145] The emulsifier and co-emulsifier are generally present in the composition, in a proportion ranging from 0.05 to 5% by weight, and preferably from 0.07 to 3% by weight relative to the total weight of the composition.

[0146] It is preferable that the composition according to the present invention has a pH of 4.5 or more, and more preferably of 5 or more.

[0147] It is preferable that the composition according to the present invention has a pH of 7.0 or less, and more preferably of 6.5 or less.

[0148] It is preferable that the composition according to the present invention has a pH of 4.5 to 6.5, and more preferably of 5.5 to 6.5.

[0149] The pH of the composition means the pH of the aqueous phase of the composition according to the present invention. Additives

[0150] A cosmetic composition according to the invention may also further comprise any additive commonly used in the field concerned, for example selected from gums distinct from compounds iii), resins, dispersing agents, essential oils, preservatives, perfumes, antiseptic agents, UV-protecting agents, cosmetic actives, sequestrants, fillers and mixtures thereof.

[0151] It is part of the routine operations of a person skilled in the art to adjust the nature and quantity of additives present in compositions according to the invention, so that the cosmetic properties and the desired stability properties of the latter are not affected.

[0152] Preferably, the composition according to the invention further comprises at least one cosmetic active ingredient. By "cosmetic active ingredient" is meant a compound that can be incorporated into a cosmetic composition to produce an effect on keratinous materials, whether this effect is immediate or produced by repeated applications.Examples of cosmetic active ingredients include colored or non-colored, fluorescent or non-fluorescent chromophores, such as those derived from optical brighteners, or chromophores from UVA and / or UVB filters; anti-aging active ingredients; and active ingredients designed to benefit the skin, such as those that act on the skin barrier function, anti-acne agents, deodorants, antiperspirants, exfoliating agents, antioxidants, moisturizers, sebum regulators, anti-shine agents, anti-pollution agents, antimicrobial or bactericidal agents, anti-dandruff agents, and fragrances. Preferably, the cosmetic active ingredient is an agent that helps prevent and / or treat oily skin, preferably chosen from among anti-acne agents, sebum regulators, and anti-shine agents.Preferably, such an agent for preventing and / or treating oily skin is chosen from silica, particularly in the form of microspheres, glycyrrhizic acid and its salts such as dipotassium glycyrrhizate, and mixtures thereof.

[0153] The composition according to the invention may comprise glycyrrhizic acid and / or one of its salts, such as dipotassium glycyrrhizate. "Salt" means a salt formed with an inorganic or organic base. Examples of salts include the ammonium salt of glycyrrhizic acid and dipotassium glycyrrhizate. Preferably, the salt of glycyrrhizic acid according to the invention is dipotassium glycyrrhizate. Glycyrrhizic acid or (3[3,20[3]-20-carboxy-ll-oxo-30-norolean-12-en-3-yl 2-O-[3-D-glucopyranuronosyl-alpha-D-glucopyranosiduronic acid is a heteroside, the aglycone part of which (an acidic terpene) is linked to an acidic sugar dimer of glucuronic acid.

[0154] It corresponds to formula (VI) below: , œœ(VI)

[0155] Dipotassium glycyrrhizate corresponds to the formula (VII) below: (VII)

[0156] Preferably, such an active ingredient chosen from silica, in particular in the form of microspheres, glycyrrhizic acid and its salts such as dipotassium glycyrrhizate, and mixtures thereof, is used at a concentration of 0.01% to 2%, preferably 0.05% to 1.5% and even more preferably 0.1% to 1% relative to the total weight of the composition.

[0157] Preferably, the composition according to the invention comprises niacinamide or one of its derivatives.

[0158] According to the invention, niacinamide has the following structure: (H)

[0159] By "niacinamide derivative" is preferably understood to mean a compound in which the amide group of niacinamide is secondary or tertiary, preferably substituted by one or two alkyl groups independently selected from C1-C4 alkyl groups and / or in which at least one hydrogen atom of the pyridine group is replaced by a C1-C4 alkyl group.

[0160] Preferably, the compound chosen from among niacinamide and its derivatives is niacinamide. For example, the product Niacinamide PC® marketed by DSM NUTRITIONAL PRODUCTS may be cited.

[0161] Preferably, the composition comprises from 0.1% to 20% by weight of the compound selected from niacinamide and its derivatives relative to the total weight of the composition, preferably from 0.5% to 15% by weight, preferably from 0.8% to 10% by weight.

[0162] The composition used according to the invention can be presented in all the galenic forms normally used in the cosmetic field.

[0163] It may be in particular in the form of a gelled aqueous or hydroalcoholic solution, an oil-in-water or water-in-oil or multiple gelled emulsion, or even in the form of a serum or a paste. It may have a paste-like consistency, or be more or less fluid.

[0164] Thus, the composition may include all the constituents usually employed in the envisaged topical application and administration.

[0165] A composition according to the invention may advantageously be in the form of an emulsion, in particular obtained by dispersing an aqueous phase in an oily phase (W / O) or an oily phase in an aqueous phase (W / O), of a semi-liquid consistency such as milk, or of a soft, semi-solid consistency such as cream or gel, or even of a multiple emulsion (W / O / O or W / O / O). These compositions are prepared according to conventional methods.

[0166] Preferably, the composition according to the invention is applied topically, i.e. on the surface of the skin in question.

[0167] The compositions according to the invention can be applied directly to the skin.

[0168] The composition may or may not be rinsed off after being applied to the skin. Applications

[0169] The cosmetic compositions covered by the invention may be facial or body care products.

[0170] The compositions according to the invention are cosmetic compositions intended for skin care, in particular for oily skin. These compositions are therefore intended to be applied to the skin.

[0171] According to another of its objects, the present invention also relates to a cosmetic treatment method for skin care, in particular oily skin, comprising the application of a cosmetic composition according to the invention.

[0172] By “treatment” we mean a non-therapeutic treatment capable of producing an aesthetic effect without preventing or correcting a pathological dysfunction of the skin.

[0173] The invention will be illustrated in the following non-limiting examples. Unless otherwise stated, percentages are expressed as a percentage of the total weight of the composition (% w / w).

[0174] The compositions are prepared according to the usual methods of formulating cosmetic compositions.

[0175] Example: Evaluation of the gloss / matte finish of a composition according to the invention (Cl) and comparative compositions (CCI 1, CC2 * and CC31)

[0176] The Cl formulations according to the invention and comparative CCI* to CC3* are as follows:

[0177] [Tables] Ingredient (% w / w) Cl CCI * CC2 * CC3 * NaOH 0.07 0.07 0.07 0.07 NIACINAMIDE 2.00 2.00 2.00 2.00 GLYCERYL ISOSTEARATE 0.10 0.10 0.10 0.10 Salicylic Acid 0.20 0.20 0.20 0.20 Ethanol 5.00 5.00 5.00 5.00 SODIUM HYALURONATE 0.10 - 0.30 0.10 GLYCERIN 7.29 7.29 7.29 7.29 Xanthan Gum (Kelt roi CG-T from CP Kelco) 0.20 0.20 0.20 0.20 Antioxidant 0.20 0.20 0.20 0.20 AMMONIUM POLYACRY LOYLDIMETHYL TAURA TE (Hostacerin AMPS from Clarian t) 1.25 SILICA 0.50 0.50 0.50 0.50 TRISODIUM ETHYLENEDI AMINE DISUCCINATE 0.27 0.27 0.27 0.27 Preservative Qs Qs Qs Qs SQUALANE 1.00 1.00 1.00 1.00 BIOSACCHARIDE GUM-1 (FUCOGEL POWDERdeS OLABIA) 0.10 0.10 0.10 0.10 Salts 0.01 0.01 0.01 0.01 BUTYLENE GLYCOL 1.60 1.60 1.60 1.60 CAPRYLYL GLYCOL 0.30 0.30 0.30 0.30 SODIUM CARBOMER (A QUPEC MG N401R from SU MITOMO SEIKA) 1.25 1.25 1.25 - Citric acid 0.05 0.05 0.05 0.05 Water qs. 100 qs. 100 qs. 100 qs. 100 Evaluation Protocol

[0178] The above compositions were evaluated by a panel of 10 people, with the naked eye, in their primary container (i.e. in the form of a jar).

[0179] A scoring based on the glossiness on a scale of 0 to 5, "0": less glossy to "5": more glossy, and based on the texture + I- granite of each of the compositions Cl, CCI*, CC2* and CC3*, was carried out. Results

[0180] The results are as follows:

[0181] [Tables2] Formulas Cl CCI * CC2 * CC3 * Formula shine (average obtained from 10 people; score from 0 to 5) 1.2 0.1 3.0 5.0 Granite / sorbet texture of the formula (++) (+++) (+) (-) No granite texture Slippery on application (+) (-) No slipperiness (++) (+++) Conclusion = ACCEPT TABLE = = = NO AC NO AC NO N AC ACCEPTABLE ACCEPTABLE ACCEPTABLE THE THE THE Conclusion#:

[0182] Composition Cl according to the invention is that which has a low shine (= high matte finish) while having a granite / sorbet texture, which corresponds to the characteristics sought by consumers, particularly in the context of compositions for the prevention and / or treatment of oily skin, because they give a light / fresh texture sensation.

Claims

Demands

1. Composition, especially cosmetic, comprising: i) at least one polymer derived from (Ci-C6)alkyl acrylic acid or one of its salts, comprising a repetition of formula units (I): [Chem.l] formula (I) in which: * R1 and R2, identical or different, represent a hydrogen atom or a (Ci-C6)alkyl group such as methyl, preferably R1 and R2 represent a hydrogen atom, * M+ represents a cationic counterion, preferably an alkali metal, alkaline earth metal or ammonium, more preferably M+ represents an alkali metal such as sodium; ii) less than 0.15% by weight relative to the total weight of composition, of hyaluronic acid and / or one of its salts, and iii) at least one hydrophilic gelling agent distinct from the polymer derived from (Cl-C6)alkyl acrylic acid or one of its salts and hyaluronic acid and / or its salts.

2. Composition according to claim 1, wherein the (Ci-C6)alkyl acrylic acid polymer or one of its salts i) comprises a repetition of formula units (I) and formula unit(s) (II): -[CH(R')-C(R2)(COO M+)]-(I) and -[CH(R')-C(R2)(COOH)]- (II) formulas (I) and (II) wherein R 1 and R 2, and M + are as defined in claim 1.

3. Composition according to claim 1 or 2, wherein the (Ci-C6)alkyl acrylic acid polymer or one of its salts i) comprises a repetition of formula units (I) and formula unit(s) (II): -[CH(R')-C(R2)(COO M+)]y-(I) and -[CH(R1)-C(R2)(COOH)]z- (II) formulas (I) and (II) wherein R1 and R2, and M+ are as defined above, and * y represents an integer greater than or equal to 2; * z is zero, or represents a number greater than zero; preferably y > z.

4. Composition according to any one of the preceding claims, wherein the (Ci-C6)alkyl acrylic acid polymer or any one of its salts i) comprises, preferably consisting of, a repetition of units of formula (I) and unit (II) in which R1 and R2 represent a hydrogen atom or a (Ci-C4)alkyl group such as methyl, preferably a hydrogen atom.

5. Composition according to any one of the preceding claims, wherein the (Ci-C6)alkyl acrylic acid polymer or one of its salts (i) is selected from alkali metal, alkaline earth or ammonium polyacrylates, preferably alkali metal or alkaline earth polyacrylates, more preferably sodium acrylates, more particularly carbomers, preferably S-carbomer or sodium carbomer.

6. Composition according to any one of the preceding claims, wherein the (Ci-C6)alkyl acrylic acid polymer or one of its salts (i) is present in an amount of at least 0.5% by weight, more particularly at least 0.7% by weight, and more preferably at least 1% by weight relative to the total weight of the composition, and / or at most 10% by weight, preferably at most 5% by weight, and more preferably at most 3% by weight relative to the total weight of the composition; preferably from 0.5% to 5% by weight, preferably from 0.7% to 4% by weight, more preferably from 1% to 3% by weight, better from 1% to 2% relative to the total weight of the composition.

7. Composition according to any one of the preceding claims, wherein the hyaluronic acid salt is selected from potassium hyaluronate and sodium hyaluronate, preferably sodium hyaluronate.

8. Composition according to any one of the preceding claims, wherein hyaluronic acid or one of its salts ii) is present in an amount less than 0.13% by weight of dry matter and preferably of at least 0.0001% by weight of dry matter relative to the total weight of the composition; preferably from 0.0001% to 0.15% by weight of dry matter relative to the total weight of the composition, preferably from 0.001% to 0.13% by weight of dry matter, even better from 0.05% to 0.12% by weight of dry matter relative to the total weight of the composition.

9. Composition according to any one of the preceding claims, wherein the hydrophilic gelling agent iii) is selected from sulfonic group polymers, polysaccharides and mixtures thereof.

10. Composition according to any one of the preceding claims, wherein the hydrophilic gelling agent iii) is present in a content ranging from 0.01% to 5%, and preferably from 0.1% to 3%, and even more preferably from 0.1% to 1% by weight relative to the total weight of said composition.

11. Composition according to any one of the preceding claims, wherein the hydrophilic gelling agent iii) is a sulfonic group polymer selected from homopolymers of 2-acrylamido-2-methylpropane sulfonic acid, copolymers of 2-acrylamido-2-methylpropane sulfonic acid and acrylamide, copolymers of 2-acrylamido-2-methylpropane sulfonic acid and vinylpyrrolidone or vinylformamide, copolymers of 2-acrylamido-2-methylpropane sulfonic acid and sodium acrylate, copolymers of 2-acrylamido-2-methylpropane sulfonic acid and hydroxyethyl acrylate, copolymers of 2-acrylamido-2-methylpropane sulfonic acid and cetearyl methacrylate ethoxylated optionally crosslinked, their salts and mixtures thereof.

12. A composition according to any one of the preceding claims, wherein the hydrophilic gelling agent iii) is a polysaccharide selected from fructans, gellans, glucans, amylose, amylopectin, glycogen, pullulan, dextran, celluloses and their derivatives, in particular methylcelluloses, hydroxyalkylcelluloses, ethylhydroxyethylcelluloses and carboxymethylcelluloses, mannans, xylans, lignins, arabans, galactans, galacturonans, alginate compounds, chitin, chitosan, glucuronoxylans, arabinoxylans, xyloglucans, glucomannans, pectic acids and pectins, arabinogalactans, carrageenans, agars, gum arabic, gums Tragacanth, Ghatti gums, Karaya gums, carob gums, galactomannans such as guar gums and their non-ionic derivatives, in particular hydroxypropyl guar, and ionic derivatives,microbial biopolysaccharide gums, in particular scleroglucan or xanthan gums, or polysaccharides comprising fucose, galactose and galacturonic acid units, mucopolysaccharides, and in particular chondroitin sulfate and mixtures thereof; preferably selected from xanthan gum, alginate-based compounds, in particular sodium alginate, sceroglucan gum, guar gum and mixtures thereof, preferably xanthan gum.

13. Composition according to any one of the preceding claims, comprising a physiologically acceptable medium comprising water and optionally one or more water-miscible solvent(s), and optionally at least one fatty substance such as one or more oil(s).

14. Composition according to any one of the preceding claims, further comprising at least one cosmetic active ingredient which is an agent for preventing and / or treating oily skin, preferably selected from anti-acne active ingredients, sebum-regulating active ingredients and active ingredients for limiting skin shine, preferably selected from silica, in particular in the form of microspheres, glycyrrhizic acid and its salts such as dipotassium glycyrrhizate, and mixtures thereof.

15. A cosmetic treatment method for the non-therapeutic care of the skin, in particular oily skin, comprising the application of a cosmetic composition according to any one of the preceding claims.