ANHYDROUS HAIR TREATMENT COMPOSITION comprising a cationic surfactant and a fatty alcohol
The anhydrous hair treatment composition with cationic surfactants and fatty alcohols addresses the limitations of traditional conditioners by forming a lamellar structure for efficient oil deposition, achieving hydration and frizz control without residue buildup.
Patent Information
- Application Number
- FR2024009413
- Authority / Receiving Office
- FR · FR
- Patent Type
- Utility models
- Current Assignee / Owner
- Filing Date
- 2024-09-05
- Publication Date
- 2026-03-06
- Estimated Expiration
- 2034-09-05
AI Technical Summary
Existing hair care products, particularly those containing silicones, often lead to residue buildup, moisture barrier formation, and eventual dryness and damage, while failing to provide long-lasting hydration and frizz control without weighing down the hair.
An anhydrous hair treatment composition comprising cationic surfactants and fatty alcohols, which forms a lamellar structure upon contact with water, efficiently depositing oils and active ingredients onto the hair, providing hydration and frizz control without greasiness.
The composition moisturizes and softens hair, treats split ends, and controls frizz, leaving hair feeling light and soft with a natural shine, without the drawbacks of traditional conditioners.
Abstract
Description
Title of the invention: ANHYDROUS HAIR TREATMENT COMPOSITION comprising a cationic surfactant and a fatty alcohol SCOPE OF DISCLOSURE
[0001] This disclosure relates to anhydrous hair treatment compositions comprising cationic surfactants and fatty alcohols, and methods of treating hair with the compositions. The compositions and methods are useful for smoothing hair, treating split ends, and controlling frizz. BACKGROUND
[0002] Many consumers wish to use cosmetic and care compositions that improve the appearance of hair, for example, by changing the color, style, and / or shape of the hair and / or by imparting various cosmetic properties to the hair, such as shine and revitalization. Hair can become dry or damaged for various reasons, for example, exposure to the elements, poor nutrition, mechanical treatments (e.g., brushing), styling treatments using chemicals, dyes, heat, nutrients, etc. Even cleansing products tend to remove the hair's natural oils, causing dryness and potentially leading to a dull appearance and split ends. People with curly hair may also face additional challenges when caring for their hair.Curly hair tangles more easily and can be more difficult to style.
[0003] Environmental factors, such as salt water, sunlight, and heat, as well as chemical treatments, are also known to damage hair. Various types of chemical treatments include, for example, hair bleaching and coloring, perms, perming products, and straightening treatments. These chemical treatments change the appearance of hair by altering its physical structure, which inevitably causes some degree of hair damage. Damaged hair is characterized by unnatural changes in the protein structure of individual hair strands or shafts. The damage results in split ends, dry, straw-like hair, hair that breaks easily, and hair that is frizzy and difficult to style. Since the visible part of the hair is dead, it cannot regenerate itself.
[0004] Many over-the-counter and salon treatments are intended to repair damaged hair. Silicones, for example, are used to provide lubrication and shine. Silicones work by coating the cuticle, the outermost layer of the hair fiber. Silicones are often found in conditioners because they increase slip, help retain moisture, and leave hair feeling soft. The increased slip makes detangling easier. Silicones are also used for their anti-frizz properties because they can form a coating on the hair that resists moisture, which causes frizz. However, silicones can build up on the hair and leave a residue that is difficult to wash out. Ultimately, the residue prevents moisture from being absorbed into the hair, leading to dryness and damage over time.Furthermore, silicones can weigh down hair, especially fine hair, causing it to lose volume and elasticity.
[0005] Products that condition hair include rinse-out conditioners, leave-in conditioners, deep conditioning treatments, and co-wash conditioners. Rinse-out conditioners are the most common type of conditioning product. They are applied after shampooing and rinsed out before drying and styling. Rinse-out conditioners typically remain on the hair for only a few minutes before being rinsed out, but they are suitable for most hair types and can be used daily or as needed.
[0006] Leave-in conditioners are usually applied to the hair after shampooing and are not rinsed out. They remain on the hair during drying and styling and are designed to provide long-lasting moisture and nourishment, making them a popular choice for dry or damaged hair. Leave-in conditioners can also offer additional benefits such as heat protection, frizz control, and detangling. They are especially useful for people who frequently style their hair or who need extra moisture throughout the day.
[0007] All-in-one shampoos / conditioners, also called "co-wash" or "conditioning shampoos," attempt to combine the cleansing benefits of a shampoo with the conditioning properties of a conditioner. They cleanse the hair while simultaneously conditioning it, making for a convenient and simplified hair care routine. Cleansing compositions, such as shampoos, are designed to remove sebum, oil, and debris from the hair, which is the opposite of conditioning. Many conditioning products are designed to deliver oil and other conditioning agents to the hair. In addition, shampoos Effective conditioners cause the hair cuticle to open, which helps release and remove debris. Effective conditioners, on the other hand, are designed to close the cuticle to prevent moisture release and provide extra protection for the hair. A single product cannot both open and close the cuticle simultaneously.
[0008] Conditioning products on the market come in various forms, such as solutions, lotions, creams, sprays, oils, and even aerosols. Regardless of the form, consumers are looking for lightweight products that do not weigh down the hair or leave it with a greasy or oily texture. Conditioned hair should have a natural, healthy appearance, a pleasant shine, and a natural flow. Ideal conditioning products moisturize the hair, provide protection against heat and other environmental damage, and control frizz and flyaways.
[0009] The formulation of environmentally friendly cosmetic products, designed and developed with environmental considerations in mind, is also becoming a major objective in an effort to address global challenges. It is therefore essential to offer more sustainable compositions, preparation processes, and ingredients to meet these environmental concerns. In this context, it is important to develop new cosmetic compositions with a lower carbon footprint, particularly by promoting the use of renewable raw materials and / or materials with a high naturalness index and / or materials of natural origin, and more specifically, materials of plant origin, while reducing the use of petrochemical-derived compounds. DISCLOSURE SUMMARY
[0010] This disclosure relates to an anhydrous hair treatment composition that instantly provides hair with softness, hydration, and other conditioning benefits. The composition includes castor oil, one or more cationic surfactants, and one or more fatty alcohols. Fatty alcohols behave as nonionic surfactants due to their amphipathic nature. Notably, despite the presence of both cationic surfactants and fatty alcohols, the composition is not an emulsion; rather, it is a homogeneous and transparent solution in which the cationic surfactants and fatty alcohols are solubilized.
[0011] Surfactants have a polar head and an oily tail. In emulsions, water and other polar organic compounds form an aqueous phase that interacts with the polar heads of the surfactants. Fatty compounds such as oils create a hydrophobic phase of the emulsion that interacts with the oily tails of the surfactants. In the absence of water, monoalcohols having 1 to 6 carbon atoms, glycols Polyols, containing 1 to 6 carbon atoms, and / or other polyols with 1 to 6 carbon atoms are typically used to incorporate surfactants into oils. The inventors have remarkably discovered a unique formulation that effectively solubilizes both cationic surfactants and fatty alcohols, resulting in a clear solution that moisturizes, softens hair, treats split ends, and controls frizz when used with water.
[0012] The composition of an anhydrous hair treatment typically includes: a. one or more vegetable oils, in which one or more of the vegetable oils is castor oil in an amount of at least 10% by weight, relative to the total weight of the anhydrous hair treatment composition; b. one or more cationic surfactants; c. one or more fatty alcohols; and d. optionally, one or more sensory-active agents;
[0013] all percentages by weight are based on a total weight of the composition.
[0014] Upon contact with water, the anhydrous hair treatment composition undergoes a transformation into a structured lamellar arrangement. Cationic surfactants and fatty alcohols assemble at the oil-water interface, positioning their hydrophobic tails toward the oil and their hydrophilic heads toward the water molecules. This molecular alignment forms bilayers, or lamellae, efficiently trapping and transporting oil droplets within these layers onto the hair during application. When applied to wet or damp hair, the presence of water triggers the development of the lamellar structure. Consequently, the oil droplets are deposited on the hair surface. Unlike conventional conditioners that use oils, cationic surfactants, and fatty alcohols for conditioning, the unique lamellar mechanism formed with the anhydrous hair treatment composition when used with water ensures a more efficient and thorough deposition process.This formula effectively deposits substantial amounts of oil, cationic surfactants, and other active ingredients onto the hair. Unlike other water-based conditioning products, hair treated with this anhydrous hair treatment formula is moisturized without becoming sticky, greasy, or weighed down. It leaves hair feeling light and soft with a natural shine and a healthy appearance.
[0015] Preferably, the anhydrous hair treatment composition is free or essentially free of monoalcohols having from 1 to 6 carbon atoms and polyhydric alcohols having from 1 to 6 carbon atoms. In addition, the anhydrous hair treatment composition is also preferably free or essentially free of alpha-hydroxy acid esters. The anhydrous hair treatment composition may further or alternatively be free or essentially free of acetal and ketals having 10 carbon atoms or fewer. A non-limiting example of a ketal having 10 carbon atoms or fewer is isopropylidene glycerol. In a preferred embodiment, the anhydrous hair treatment composition is free from or substantially free from isopropylidene glycerol.
[0016] The anhydrous hair treatment composition includes castor oil, typically in an amount of about 10% by weight or more. In addition to castor oil, the composition optionally includes one or more additional vegetable oils. In various embodiments, it is preferable to include one or more vegetable oils in addition to castor oil. Non-exhaustive examples of additional vegetable oils include peanut oil, amaranth seed oil, apricot oil, argan oil, avocado oil, babassu oil, cottonseed oil, borage seed oil, camelina oil, camellia oil, safflower oil, peanut oil, pomegranate seed oil, grapefruit seed oil, hemp oil, hazelnut oil, elderberry oil, currant seed oil, jojoba oil, flaxseed oil, macadamia nut oil, corn oil, almond oil,almond oil, Manila oil, evening primrose oil, olive oil, palm oil, palm kernel oil, Brazil nut oil, pecan oil, peach kernel oil, rapeseed oil, rosehip oil, sea buckthorn fruit oil, sea buckthorn kernel oil, sesame oil, soybean oil, sunflower oil, grapeseed oil, walnut oil, wild rose oil, and / or wheat germ oil. Additional vegetable oils that are particularly beneficial include coconut oil, soybean oil, avocado oil, peanut oil, apricot oil, argan oil, avocado oil, babassu oil, cottonseed oil, camelina oil, camellia oil, safflower oil, and peanut oil. Preferred additional oils include coconut oil and / or soybean oil. Coconut oil is especially preferred.
[0017] Cationic surfactants include, but are not limited to, quaternary ammonium surfactants and amidoamine surfactants. Non-limiting examples of quaternary ammonium surfactants include cetrimonium chloride, steartrimonium chloride, behentrimonium chloride, behentrimonium methosulfate, behenamidopropyltrimonium methosulfate, stearamidopropyltrimonium chloride, arachidtrimonium chloride, distearyldimonium chloride, dicetyldimonium chloride, and tricetylmonium chloride. Non-limiting examples of amidoamines include oleamidopropyl dimethylamine, linoleamidopropyl dimethylamine, isostearamidopropyl dimethylamine, oleyl hydroxyethyl imidazoline, stearamidopropyldimethylamine, behenamidopropyldimethylamine, behenamidopropyldiethylamine, behenamidoethyldiethylamine, behenamidoethyldimethylamine, rarachidamidopropyldimethylamine, arachidamidopropyldiethylamine, rarachidamidoethyldiethylamine and rarachidamidoethyldimethylamine.
[0018] Non-limiting examples of fatty alcohols include branched or linear fatty alcohols, and saturated or unsaturated fatty alcohols, which may be liquid or solid fatty alcohols. Non-limiting examples of solid fatty alcohols include stearyl alcohol, cetyl alcohol, cetearyl alcohol, myristyl alcohol, behenyl alcohol, or arachidyl alcohol. Non-limiting examples of liquid fatty alcohols include isostearyl alcohol, oleyl alcohol, octyldodecanol, linoleyl alcohol, linolenylic alcohol, lauryl alcohol, 2-hexyldecanol, 2-heptyldecanol, enanthic alcohol (1-heptanol), caprylic alcohol (1-octanol), pelargonic alcohol (1-nonanol), or capric alcohol (1-decanol). In a preferred embodiment, the anhydrous hair treatment composition includes one or more solid fatty alcohols and one or more liquid fatty alcohols.
[0019] The anhydrous hair treatment composition optionally includes one or more polymeric oil thickening agents and / or one or more cationic revitalizing polymers. Non-limiting examples of polymeric oil thickening agents include a VP / hexadecene copolymer, a trimethylpentanediol / adipic acid / glycerin crosslinked polymer, an ethylene / propylene / styrene copolymer, a butylene / ethylene / styrene copolymer, a VP / eicosene copolymer, a bis-dioctadecylamide / ethylenediamine dimer dilinoleic acid copolymer, a cetearyl dimethicone crosslinked polymer, a hydrogenated C6-20 poly(olefin), an HDI / trimethylol hexyllactone crosslinked polymer, a dimethicone / vinyl dimethicone crosslinked polymer, or a vinyl dimethicone / methicone silsesquioxane crosslinked polymer.In various embodiments, preferred polymeric oil thickening agents include hydrogenated poly(C6-20 olefin) and crosslinked HDI / trimethylol hexyllactone polymer.
[0020] The anhydrous hair treatment composition optionally includes one or more sensory-active agents. Non-limiting examples of sensory-active agents include essential oils, cooling agents, terpenes, and terpenoids.
[0021] Non-limiting examples of essential oils include lavender oil, geranium oil, juniper berry oil, bay leaf oil, lemon oil, mandarin oil, orange oil, wormwood oil, African bluegrass oil, ajowan oil, anethi oil, angelica root oil, star anise oil, wild arborvitae oil, mugwort oil, asafoetida oil, Australian lemon balm oil, basil oil, benzoin oil, Calabrian bergamot oil, betel leaf oil, birch oil, birch tar oil, blackcurrant seed oil, blood orange oil, buchu oil, cabreuva oil, cade oil, cajeput oil, calamus root oil, camphor oil, cananga oil, caraway oil, cardamom oil, carrot oil, cassia oil, cedar leaf oil, Atlas cedarwood oil, Chinese cedarwood oil, Himalayan cedarwood oil, Texas cedarwood oil, Virginia cedarwood oil, celery seed oil, German chamomile oil, Moroccan chamomile oil, Roman chamomile oil, chaulmoogra oil, goosefoot oil, chili seed oil, cinnamon bark oil, cinnamon leaf oil, citral oil, Ceylon citronella oil, clary sage oil, clementine oil, clove bud oil, clove leaf oil, cognac oil, copaiba oil, coriander oil, costus root oil, coffee oil, cumin oil, turmeric oil, curry oil,Australian blue cypress oil, French cypriol oil, davana oil, dill seed oil, dill oil, elemi oil, emu oil, eucalyptus oil, bitter fennel oil, fenugreek oil, balsam fir oil, fir needle oil, organic flaxseed oil, frankincense oil, garlic oil, galbanum oil, ginger oil, palmarosa oil, gaia oil, pink grapefruit oil, white grapefruit oil, guaiac wood oil, helichrysum oil, horseradish oil, hyadacheim oil, hyssop oil, jamarosa root oil Himalayan wild oil, karanj seed oil, kanuka oil, katrafay oil, lime oil, kunzea oil, kukui oil, lantana oil, bay leaf oil, lemongrass oil, lemon eucalyptus oil, lemon myrtle oil, 5 times lemon oil, lican oil, lime oilLitsea cubeba oil, lovage leaf oil, mace oil, mandarin oil, manuka oil, marjoram oil, lemon balm leaf oil, liquid menthol oil, mullein oil, myrrh oil, myrtle oil, neem oil, neroli oil, Australian nerolina oil, niaouli oil, noni oil, nutmeg oil, oat oil, onion oil, opoponax oil, bitter orange oil, sweet orange oil, oregano oil, 5 times orange oil, palmarosa oil, parsley oil, patchouli oil, pennyroyal mint oil, pepper oil, mint oil peppermint oil, Peruvian balsam oil, petitgrain oil, chili leaf oil, long-leaf pine oil, Scots pine oil, commercial pine oil, pomegranate oil, Siam wood oil, wild ravensara oil, Australian rosalina oil, rose geranium oil, rosemary oil,rosewood oil, rue oil, Dalmatian sage oil, sandalwood oil, savine oil, mountain savory oil, sea buckthorn oil, spearmint oil, spikenard oil, spruce oil, sugandh kokila oil, sumac oil, marigold oil, mandarin oil, annual tansy oil, tarragon oil, 5 times mandarin oil, tea tree oil, tea tree oil, lemon, thyme oil, tolu balsam oil, turmeric oil, valerian root oil, vanilla oil 10 times, vetiver oil, wintergreen oil, wild verbena oil, wormwood oil, yarrow oil and ylang ylang oil.
[0022] Non-limiting examples of cooling agents include menthol, glycerol menthone acetal, menthyl lactate, menthyl-3-carboxylic acid N-ethylamide, 2-isopropyl-N-2,3-trimethylbutanamide, 3-menthoxypropane-1,2-diol, 2-hydroxyethylmenthyl carbonate, 2-hydroxypropylmenthyl carbonate, and isopulegol. Menthol and / or menthol derivatives are particularly useful.
[0023] Non-limiting examples of terpenes and terpenoids include menthol, myrcene, limonene, linalool, humulene, terpinolene, camphene, terpineol, beta-caryophylene, 1,8-cineole, anisole, anethole, eugenol, thymol, borneol, citronellol, isomenthol, camphor, camphene, carvone, geraniol, menthone, pulegone, α-pinene, β-pinene, α-3-pinene, sabinene, α-terpinene, β-bisabolene, trans-α-bergamotene, nerol, neral, cedrol, cedrene, thujopsene, methyl thujate, and acid thujic.
[0024] The anhydrous hair treatment composition optionally includes one or more emollients, for example one or more fatty ethers, fatty esters, fatty carbonates and / or propylene glycol esters of fatty acids.
[0025] Non-limiting examples of fatty esters include coco-caprylate / caprate, coco-caprylate, coco-caprate, jojoba esters, isopropyl jojobate, ethyl macadamiaate, isoamyl laurate, heptyl undecylenate, methylheptyl isostearate, isostearyl isostearate, glyceryl ricinoleate, isostearyl palmitate, myristyle myristate, octyldodecyl myristate, octyldodecyl hydroxystearate, butyl myristate, ethylhexyl cocoate, ethylhexyl palmitate, ethylhexyl stearate, butyl stearate, decyl oleate, isocetyl behenate, isocetyl myristate, isocetyl palmitate, isocetyl stearate, isodecyl oleate, isopropyl isostearate, isopropyl myristate, isopropyl palmitate, oleyl oleate, propylene glycol laurate, octyldodecyl erucate, C12-C13 alkyl lactate, C12-C15 alkyl lactate, isostearyl lactate, glycereth-5 lactate,lauryl lactate, myristyle lactate, oleyl lactate, laureth-2 benzoate, Cl2-C15 alkyl benzoate, C12-C15 pareth-3 benzoate, dipropylene glycol benzoate, isodecyl salicylate, C12-C15 alkyl salicylate, tridecyl salicylate, ethylhexyl isononanoate, cetyl ethylhexanoate, isononyl isononanoate, isodecyl ethylhexanoate, isodecyl isononanoate, tridecyl ethylhexanoate, isotridecyl isononanoate, isostearyl isononanoate, cetearyl isononanoate, laureth-2 ethylhexanoate, cetearyl ethylhexanoate, neopentanoate, isodecyl, isostearyl neopentanoate, myristyle neopentanoate, isostearyl behenate, octyldodecyl neopentanoate and tridecyl neopentanoate.
[0026] Non-limiting examples of fatty ethers include dicaprylyl ether, didecyl ether, dimyristyl ether, distearyl ether and dilauryl ether.
[0027] Non-limiting examples of fatty carbonates include C14-15 dialkyl carbonate, dicaprylyl carbonate, diethyl carbonate, dihexyl carbonate, diethylhexyl carbonate, dimethoxyphenyl phenyloxoethyl ethyl carbonate, dimethyl carbonate, dipropyl carbonate, dipropylheptyl carbonate and dioctyl carbonate.
[0028] The anhydrous hair treatment composition optionally includes one or more polymeric oil thickening agents and / or one or more cationic revitalizing polymers. Non-limiting examples of polymeric oil thickening agents include a VP / hexadecene copolymer, a trimethylpentanediol / adipic acid / glycerin crosslinked polymer, an ethylene / propylene / styrene copolymer, a butylene / ethylene / styrene copolymer, a VP / eicosene copolymer, a bis-dioctadecylamide / ethylenediamine dimer dilinoleic acid copolymer, a cetearyl dimethicone crosslinked polymer, a hydrogenated C6-20 poly(olefin), an HDI / trimethylol hexyllactone crosslinked polymer, a dimethicone / vinyl dimethicone crosslinked polymer, and a vinyl dimethicone / methicone silsesquioxane crosslinked polymer.In various embodiments, preferred polymeric oil thickening agents include hydrogenated poly(C6-20 olefin) and crosslinked HDI / trimethylol hexyllactone polymer.
[0029] The anhydrous hair treatment composition optionally includes one or more miscellaneous ingredients. Non-limiting examples of miscellaneous ingredients include preservatives, perfumes, chelating agents, antioxidants, flavonoids, vitamins, botanical extracts, UV filtering agents, proteins, protein hydrolysates, protein isolates, fillers, and compositional colorants.
[0030] The anhydrous hair treatment composition is useful in hair treatment processes, for example, hair conditioning processes, hair straightening processes, and / or hair styling processes. The anhydrous hair treatment composition can be formulated and used as a leave-in product or formulated and used as a rinse-out product. Preferably, however, the anhydrous hair treatment composition is a leave-in product that is applied to the hair, for example, wet or damp hair. After application to wet or damp hair, the anhydrous hair treatment composition is allowed to dry naturally or can be force-dried, for example, with a hairdryer. The anhydrous hair treatment composition is used in hair revitalization processes, hair hydration, frizz control, adding shine and improving the appearance and feel of hair. DETAILED DESCRIPTION OF THE DISCLOSURE
[0031] This case relates to an anhydrous hair treatment composition that provides softness, hydration, and conditioning benefits to the hair, and to hair treatment processes using the anhydrous hair treatment composition. The anhydrous hair treatment composition is typically used as a leave-in product but is also useful as a rinse-out product. The anhydrous hair treatment composition moisturizes the hair, reduces or prevents frizz, improves curl definition, and imparts softness and shine to the hair. The anhydrous hair treatment composition typically includes: a. about 10 to about 95% by weight of one or more vegetable oils, in which one or more of the vegetable oils is castor oil in an amount of at least 10% by weight; b. approximately 0.1 to approximately 10% by weight of one or more cationic surfactants; c. approximately 0.1 to approximately 10% by weight of one or more fatty alcohols; and d. Optionally, approximately 0.1 to approximately 5% by weight of one or more agents sensorially active;
[0032] in which all percentages by weight are based on a total weight of the composition.
[0033] Preferably, the anhydrous hair treatment composition is free or essentially free of monoalcohols having from 1 to 6 carbon atoms and free or essentially free of polyhydric alcohols having from 1 to 6 carbon atoms. In addition, in various embodiments, the anhydrous hair treatment composition is further, or alternatively, free or essentially free of alpha-hydroxy acid esters. The anhydrous hair treatment composition may further, or alternatively, be essentially free of acetals and ketals having 10 carbon atoms or fewer. A non-limiting example of a ketal having 10 carbon atoms or fewer is isopropylidene glycerol. In a preferred embodiment, the anhydrous hair treatment composition is free or essentially free of isopropylidene glycerol. a. Vegetable oils#
[0034] The anhydrous hair treatment composition includes one or more vegetable oils, provided that one or more of the vegetable oils is castor oil (also known as "castor seed oil") in a quantity at least 10% by weight, relative to the total weight of the anhydrous hair treatment composition. For the purposes of this disclosure, vegetable oils are oils derived from plants that are liquid at room temperature (25°C, 1 atm) or can be solubilized with other vegetable oils and exist in liquid form at room temperature. For example, coconut oil may be solid at room temperature, but if solubilized in castor oil, it exists in liquid form at room temperature. Vegetable oils are derived from various plant sources, such as nuts, almonds, grape seeds, olives, and avocados. For example, coconut oil is extracted from the pulp, olive oil from the fruit, and jojoba oil from the seed. Vegetable oils are typically obtained by pressing, which can be either cold or hot.Cold pressing involves pressing the plant to extract the oil without raising the temperature above 40°C. Hot pressing involves heating the plant, which increases the oil yield but can alter its quality.
[0035] For the purposes of this disclosure, the term "vegetable oil" does not include essential oils, and the term "essential oil" does not include vegetable oils, even though essential oils are obtained from plants. In cases where dual use exists such that a particular oil can be interpreted as both a vegetable oil and an essential oil, a single oil cannot serve simultaneously as both a vegetable oil and an essential oil in the composition of an anhydrous hair treatment.
[0036] The total amount of one or more vegetable oils in the anhydrous hair treatment composition will vary but is typically from about 10 to about 95% by weight, relative to the total weight of the anhydrous hair treatment compositions. In other embodiments, the composition of the anhydrous hair treatment includes approximately 10 to approximately 90% by weight, approximately 10 to approximately 80% by weight, approximately 10 to approximately 70% by weight, approximately 10 to approximately 65% by weight, approximately 20 to approximately 95% by weight, approximately 20 to approximately 90% by weight, approximately 20 to approximately 80% by weight, approximately 20 to approximately 70% by weight, approximately 20 to approximately 65% by weight, approximately 35 to approximately 95% by weight, approximately 35 to approximately 90% by weight, approximately 35 to approximately 80% by weight, approximately 35 to approximately 70% by weight, approximately 35 to approximately 65% by weight, approximately 35 to approximately 55% by weight, approximately 35 to approximately 50% by weight, approximately 35 to approximately 45% by weight, approximately 40 to approximately 75% by weight,approximately 40 to approximately 65% by weight, approximately 40 to approximately 55% by weight, approximately 45 to approximately 75% by weight, approximately 45 to approximately 65% by weight, approximately 45 to approximately 55% by weight, approximately 50 to approximately 75% by weight, approximately 50 to approximately 70% by weight, approximately 50 to approximately 65% by weight, approximately 50 to approximately 60% by weight, approximately 55 to approximately 75% by weight, approximately 55 to approximately 70% by weight, or approximately 55 to approximately 65% by weight, of one or more vegetable oils, relative to the total weight of the anhydrous hair treatment composition. Preferably, the anhydrous composition includes from about 10 to about 70% by weight, more preferably from about 45 to about 65% by weight, and even more preferably from about 50 to about 65% by weight of one or more vegetable oils, relative to the total weight of the hair treatment composition. (a)(i) Castor oil
[0037] Castor oil is a vegetable oil pressed from castor beans. It is a colorless or pale yellow liquid with a boiling point of about 313 °C (595 °F) and a density of about 0.961 g / cm³. It comprises a mixture of triglycerides in which about 90% of the fatty acids are ricinoleates. Oleic acid and linoleic acid are other important components. Thus, castor oil is well known as a source of ricinoleic acid, an 18-carbon monounsaturated fatty acid. Among fatty acids, ricinoleic acid is unusual in that it has a hydroxyl functional group on the twelfth carbon atom. This functional group makes ricinoleic acid (and castor oil) more polar than many other oils.
[0038] The anhydrous hair treatment composition typically includes a substantial amount of castor oil, preferably at least 10% by weight or more of castor oil, relative to the total weight of the anhydrous hair treatment composition. For example, the anhydrous hair treatment composition may include approximately 10 to approximately 95% by weight of castor oil, relative to the total weight of the anhydrous hair treatment composition. In other embodiments, the anhydrous hair treatment composition includes approximately 10 to approximately 55% by weight, approximately 10 to approximately 50% by weight, approximately 10 to approximately 45% by weight, approximately 10 to approximately 40% by weight, approximately 10 to approximately 37.5% by weight, approximately 15 to approximately 55% by weight, approximately 15 to approximately 50% by weight, approximately 15 to approximately 45% by weight, approximately 15 to approximately 40% by weight, approximately 15 to approximately 37.5% by weight, approximately 20 to approximately 55% by weight,from approximately 20 to approximately 50% by weight, from approximately 20 to approximately 45% by weight, from approximately 20 to approximately 40% by weight, from approximately 20 to approximately 37.5% by weight, from approximately 25 to approximately 55% by weight, from approximately 25 to approximately 50% by weight, from approximately 25 to approximately 45% by weight, from approximately 25 to approximately 40% by weight, from approximately 25 to approximately 37.5% by weight, from approximately 30 to approximately 60% by weight, from approximately 30 to approximately 55% by weight, from approximately 30 to approximately 50% by weight, from approximately 30 to approximately 45% by weight, from approximately 30 to approximately 40% by weight, from approximately 30 to approximately 37.5% by weight, from approximately 35 to approximately 55% by weight, from approximately 35 to approximately 50% by weight, approximately 35 to approximately 45% by weight, or approximately 35 to approximately 40% by weight of castor oil, relative to the total weight of the composition of, anhydrous hair treatment. The composition of anhydrous hair treatment preferably includes about 10 to about 80% by weight, more preferably about 15 to about 60% by weight, and even more preferably about 25 to about 50% by weight of castor oil, relative to the total weight of the composition of anhydrous hair treatment.
[0039] (a)(ii) Additional vegetable oils (other than castor oil)
[0040] As mentioned above, the anhydrous hair treatment composition preferably includes one or more additional vegetable oils (other than castor oil), i.e. the anhydrous hair treatment composition includes two or more (or a plurality of) vegetable oils, provided that one of the two or more (or a plurality of) vegetable oils is castor oil. Non-exhaustive examples of additional vegetable oils include coconut oil, peanut oil, amaranth seed oil, apricot oil, argan oil, avocado oil, babassu oil, cottonseed oil, borage seed oil, camelina oil, camellia oil, safflower oil, peanut oil, pomegranate seed oil, grapefruit seed oil, hemp oil, hazelnut oil, elderberry oil, currant seed oil, jojoba oil, flaxseed oil, macadamia nut oil,corn oil, almond oil, almond oil, Manila oil, evening primrose oil, olive oil, palm oil, palm kernel oil, Brazil nut oil, pecan nut oil, peach kernel oil, rapeseed oil, rosehip oil, sea buckthorn fruit oil, sea buckthorn kernel oil, sesame oil, soybean oil, sunflower oil, grapeseed oil, walnut oil, wild rose oil and wheat germ oil. In a preferred embodiment, the anhydrous hair treatment composition includes castor oil and one or more additional vegetable oils selected from coconut oil, soybean oil, avocado oil, peanut oil, apricot oil, argan oil, avocado oil, babassu oil, cottonseed oil, camelina oil, camellia oil, safflower oil, and peanut oil, preferably coconut oil and / or soybean oil.
[0041] In a preferred embodiment, the anhydrous hair treatment composition includes castor oil and one or more additional vegetable oils selected from coconut oil and soybean oil. In a preferred embodiment, the hair treatment composition includes castor oil and coconut oil. In yet another preferred embodiment, the anhydrous hair treatment composition includes castor oil, coconut oil, and soybean oil, and optionally one or more other vegetable oils (other than castor oil, coconut oil, and soybean oil).
[0042] The total amount of one or more additional vegetable oils (other than castor oil) will vary but is typically about 1 to about 45% by weight, relative to the total weight of the anhydrous hair treatment composition. In other embodiments, the anhydrous hair treatment composition includes approximately 1 to approximately 35% by weight, approximately 1 to approximately 25% by weight, approximately 1 to approximately 20% by weight, approximately 1 to approximately 15% by weight, approximately 5 to approximately 45% by weight, approximately 5 to approximately 35% by weight, approximately 5 to approximately 25% by weight, approximately 5 to approximately 20% by weight, approximately 5 to approximately 15% by weight, approximately 10 to approximately 45% by weight, approximately 10 to approximately 35% by weight, approximately 10 to approximately 25% by weight, approximately 10 to approximately 20% by weight, approximately 10 to approximately 15% by weight, approximately 15 to approximately 45% by weight, approximately 15 to approximately 35% by weight. weight, approximately 15 to approximately 25% by weight,of about 20 to about 45% by weight, of about 20 to about 35% by weight, of about 20 to about 20% by weight, or of about 20 to about 25% by weight of one or more additional vegetable oils (other than castor oil), relative to the total weight of the anhydrous hair treatment composition. In preferred embodiments, the anhydrous hair treatment composition includes from about 1 to about 35% by weight, more preferably from about 5 to about 30% by weight, and even more preferably from about 10 to about 25% by weight of one or more additional vegetable oils (other than castor oil), relative to the total weight of the anhydrous hair treatment composition. (a)(iii) Coconut oil,
[0043] In various embodiments, one or more of the additional vegetable oils (other than castor oil) is coconut oil. Coconut oil is extracted from the kernel of coconuts harvested from coconut palms and is rich in saturated fats. Coconut oil provides a variety of benefits to hair. For example, it moisturizes dry and damaged hair, reduces frizz, and protects hair from damage caused by styling. It can be used safely on most hair types. It is rich in fatty acids (especially lauric acid) that promote healthy hair. Therefore, in addition to castor oil, it may be beneficial to also include coconut oil in the composition of an anhydrous hair treatment.
[0044] The total amount of coconut oil in the hair treatment composition, if present, will vary, but is typically from about 1 to about 20% by weight, relative to the total weight of the anhydrous hair treatment composition. In other embodiments, the anhydrous hair treatment composition includes from about 1 to about 18% by weight, from about 1 to about 15% by weight, from about 1 to about 12% by weight, from about 1 to about 10% by weight, from about 2 to about 20% by weight, from about 2 to about 18% by weight, from about 2 to about 15% by weight, from about 2 to about 12% by weight, from about 2 to about 10% by weight, from about 5 to about 20% by weight, from about 5 to about 18% by weight, from about 5 to about 15% by weight, from about 5 to about 12% by weight, from about 8 to about 20% by weight, from about 8 to about 18% by weight, from about 8 to about 15% by weight, or from about 8 to about 12% by weight, relative to the total weight of the anhydrous hair treatment composition. Preferably, the anhydrous hair treatment composition includes from about 2 to about 18% by weight, more preferably from about 5 to about 15% by weight, and even more preferably from about 6 to about 14% by weight of coconut oil, relative to the total weight of the anhydrous hair treatment composition.
[0045] In a preferred embodiment, the anhydrous composition includes castor oil, coconut oil, and optionally one or more additional vegetable oils. In particular, the anhydrous hair treatment composition may include:
[0046] (a)(i) about 5% to about 75% by weight, preferably about 30% to about 50% in weight, more preferably about 30 to about 45% by weight, and even more preferably about 35 to about 45% by weight of castor oil;
[0047] (a)(ii) about 1 to about 25% by weight, preferably about 2 to about 18% by weight, more preferably about 5 to about 15% by weight, and even more preferably about 6 to about 14% by weight of coconut oil; and
[0048] (a)(iii) optionally, about 1 to about 20% by weight, preferably about 2 to about 18% by weight, more preferably about 5 to about 15% by weight, and even more preferably about 6 to about 14% by weight of one or more other vegetable oils (other than castor oil and coconut oil), for example, one or more other vegetable oils selected from soybean oil, avocado oil, peanut oil, apricot oil, argan oil, avocado oil, babassu oil, cottonseed oil, camelina oil, camellia oil, safflower oil and peanut oil, preferably coconut oil and / or soybean oil. (b) Cationic surfactants
[0049] For the purposes of this disclosure, the term "cationic surfactant" means a surfactant that carries one or more permanent positive charges or one or more functional groups that are cationizable, for example, on the basis of pH. Quaternary ammonium surfactants have one or more permanent positive charges. Amidoamine surfactants are cationizable.
[0050] Non-limiting examples of cationic surfactants include cetrimonium chloride, stearimonium chloride, behentrimonium chloride, behentrimonium methosulfate, behenamidopropyltrimonium methosulfate, stearamidopropyltrimonium chloride, arachidtrimonium chloride, distearyldimonium chloride, dicetyldimonium chloride, tricetylmonium chloride, oleamidopropyl dimethylamine, linoleamidopropyl dimethylamine, isostearamidopropyl dimethylamine, oleyl hydroxyethyl imidazoline, stearamidopropyldimethylamine, behenamidopropyldimethylamine, behenamidopropyldiethylamine, behenamidoethyldiethylamine, behenamidoethyldimethylamine, arachidamidopropyldimethylamine, arachidamidopropyldiethylamine, arachidamidoethyldiethylamine, brassicamidopropyldimethylamine, lauramidopropyl dimethylamine, myristamidopropyl dimethylamine, dilinoleamidopropyl dimethylamine and palmitamidopropyl dimethylamine.
[0051] In various embodiments, one or more cationic surfactants are preferably chosen from quaternary ammonium compounds. Non-limiting examples of quaternary ammonium compounds include cetrimonium chloride, steartrimonium chloride, behentrimonium chloride, behentrimonium methosulfate, behenamidopropyltrimonium methosulfate, stearamidopropyltrimonium chloride, arachidtrimonium chloride, distearyldimonium chloride, dicetyldimonium chloride, and tricetylmonium chloride.
[0052] In various embodiments, one or more cationic surfactants are preferably chosen from among the amidoamine surfactants. Non-limiting examples of amidoamine surfactants include oleamidopropyl dimethylamine, linoleamidopropyl dimethylamine, isostearamidopropyl dimethylamine, oleyl hydroxyethyl imidazoline, stearamidopropyl dimethylamine, behenamidopropyl dimethylamine, behenamidopropyl diethylamine, behenamidoethyl diethylamine, behenamidoethyl dimethylamine, arachidamidopropyl dimethylamine, arachidamidopropyl diethylamine, arachidamidoethyl diethylamine, and arachidamidoethyl dimethylamine.
[0053] In other embodiments, the one or more cationic surfactants are preferably chosen from cetrimonium chloride, behentrimonium chloride, behentrimonium methosulfate and stearamidopropyl dimethylamine.
[0054] In a preferred embodiment, at least one or more of the cationic surfactants is an amidoamine surfactant. In other embodiments, all or more of the cationic surfactants are chosen from among the amidoamine surfactants. Non-limiting examples of preferred amidoamine surfactants include oleamidopropyl dimethylamine, stearamidopropyl dimethylamine, isostearamidopropyl dimethylamine, stearamidoethyl dimethylamine, lauramidopropyl dimethylamine, myristamidopropyl dimethylamine, behenamidopropyl dimethylamine, dilinoleamidopropyl dimethylamine, palmitamidopropyl dimethylamine, ricinoleamidopropyl dimethylamine, sojamidopropyl dimethylamine, and bleamidopropyl germ. dimethylamine, toumesolamidopropyl dimethylamine seed, amandamidopropyl dimethylamine, avocadoamidopropyl dimethylamine, babassuamidopropyl dimethylamine, cocamidopropyl dimethylamine, visonamidopropyl dimethylamine, avoinamidopropyl dimethylamine, sesamamidopropyl dimethylamine, suifamidopropyl dimethylamine, brassicamidopropyl dimethylamine, olivamidopropyl dimethylamine and stearamidoethyldiethylamine.
[0055] The total amount of one or more cationic surfactants in the anhydrous hair treatment composition will vary but is typically about 0.1 to about 10% by weight, relative to the total weight of the anhydrous hair treatment composition. In other embodiments, the anhydrous hair treatment composition includes approximately 0.1 to approximately 8% by weight, approximately 0.1 to approximately 6% by weight, approximately 0.1 to approximately 5% by weight, approximately 0.1 to approximately 3% by weight, approximately 0.5 to approximately 10% by weight, approximately 0.5 to approximately 8% by weight, approximately 0.5 to approximately 6% by weight, approximately 0.5 to approximately 5% by weight, approximately 0.5 to approximately 3% by weight, approximately 1 to approximately 10% by weight, approximately 1 to approximately 8% by weight, approximately 1 to approximately 6% by weight, approximately 1 to approximately 5% by weight, or approximately 1 to approximately 3% by weight of one or more cationic surfactants, relative to the total weight of the anhydrous hair treatment composition.Preferably, the anhydrous hair treatment composition includes about 0.1 to about 10% by weight, more preferably about 0.5 to about 8% by weight, even more preferably about 0.8 to about 5% by weight, and even more preferably about 1 to about 3% by weight of one or more cationic surfactants, relative to the total weight of the anhydrous hair treatment composition. (c) Fatty alcohols
[0056] The term "fatty alcohol" refers to an alcohol comprising at least one hydroxyl group (OH), and comprising at least 8 carbon atoms, and which is neither oxyalkylated (in particular, neither oxyethylated nor oxypropylated), nor glycerolated. Fatty alcohols may be represented by: R-OH, where R designates a saturated (alkyl) or unsaturated (alkenyl) group, linear or branched, comprising from 8 to 40 carbon atoms, preferably 10 to 30 carbon atoms, more preferably 12 to 24 carbon atoms, and even more preferably 14 to 22 carbon atoms. Fatty alcohols may be liquid or solid.
[0057] The total amount of one or more fatty alcohols in the anhydrous hair treatment composition will vary but is typically from about 0.1 to about 15% by weight, relative to the total weight of the anhydrous hair treatment composition. In other embodiments, the anhydrous hair treatment composition includes from about 0.1 to about 12% by weight, from about 0.1 to about 10% by weight, about 0.1 to about 8% by weight, about 0.5 to about 15% by weight, about 0.5 to about 12% by weight, about 0.5 to about 10% by weight, about 0.5 to about 8% by weight, about 1 to about 15% by weight, about 1 to about 12% by weight, about 1 to about 10% by weight, about 1 to about 8% by weight, about 2 to about 15% by weight, about 2 to about 12% by weight, about 2 to about 10% by weight or about 2 to about 8% by weight, about 4 to about 15% by weight, about 4 to about 12% by weight, about 4 to about 10% by weight or about 4 to about 8% by weight of one or more fatty alcohols, relative to the total weight of the anhydrous hair treatment composition.Preferably, the anhydrous hair treatment composition includes about 0.1 to about 15% by weight, more preferably about 1 to about 12% by weight, even more preferably about 2 to about 10% by weight, and even more preferably about 4 to about 8% by weight of one or more fatty alcohols, relative to the total weight of the anhydrous hair treatment composition.
[0058] In various embodiments, it is preferable that the anhydrous hair treatment composition include at least one solid fatty alcohol. The term "solid fatty alcohol" refers to a fatty alcohol having a melting point above 27 °C at atmospheric pressure (1.013 x 10⁵ Pa). For the purposes of this disclosure, the melting point corresponds to the temperature of the most endothermic peak observed on the thermal analysis (differential scanning calorimetry or DSC) as described in ISO 11357-3; 1999. The melting point can be measured using a differential scanning calorimeter (DSC), for example, the calorimeter sold under the name "MDSC 2920" by TA Instruments.
[0059] Non-limiting examples of solid fatty alcohols include myristyl alcohol (1-tetradecanol), cetyl alcohol (1-hexadecanol), stearyl alcohol (1-octadecanol), arachidyl alcohol (1-eicosanol), behenyl alcohol (1-docosanol), lignoceryl alcohol (1-tetracosanol), ceryl alcohol (1-hexacosanol), montanyyl alcohol (1-octacosanol), and myricyl alcohol (1-triacontanol). In a preferred embodiment, one or more of the solid fatty alcohols are selected from myristyl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, and mixtures thereof, such as cetostearyl alcohol and cetearyl alcohol. Preferably, the cosmetic composition includes one or more solid fatty alcohols selected from cetyl alcohol, myristyl alcohol, stearyl alcohol and behenyl alcohol, preferably the solid fatty alcohol is cetyl alcohol, myristyl alcohol, behenyl alcohol and cetearyl alcohol.
[0060] The total quantity of one or more solid fatty alcohols, if present, in the anhydrous hair treatment composition will vary but is typically about 0.1 to approximately 10% by weight, relative to the total weight of the anhydrous hair treatment composition. In other embodiments, the anhydrous hair treatment composition includes approximately 0.1 to approximately 8% by weight, approximately 0.1 to approximately 6% by weight, approximately 0.2 to approximately 10% by weight, approximately 0.2 to approximately 8% by weight, approximately 0.2 to approximately 6% by weight, approximately 0.5 to approximately 10% by weight, approximately 0.5 to approximately 8% by weight, approximately 0.5 to approximately 6% by weight, approximately 1 to approximately 10% by weight, approximately 1 to approximately 8% by weight, approximately 1 to approximately 6% by weight, approximately 2 to approximately 10% by weight, approximately 2 to approximately 8% by weight, approximately 2 to approximately 6% by weight, approximately 3 to approximately 10% by weight, approximately 3 to approximately 8% by weight, or about 3 to about 6% by weight, relative to the total weight of the anhydrous hair treatment composition.Preferably, the anhydrous hair treatment composition includes from about 0.1 to about 10% by weight, more preferably from about 1 to about 8% by weight, more preferably from about 2 to about 8% by weight, and even more preferably from about 2 to about 6% by weight of one or more solid fatty alcohols.
[0061] In some cases, it is preferable for the anhydrous hair treatment composition to include at least one liquid fatty alcohol. The term "liquid fatty alcohol" refers to a fatty alcohol having a melting point of 27 °C or less at atmospheric pressure (1.013 x 10⁵ Pa). For the purposes of this disclosure, the melting point corresponds to the temperature of the most endothermic peak observed on the thermal analysis (differential scanning calorimetry or DSC) as described in ISO 11357-3; 1999. The melting point can be measured using a differential scanning calorimeter (DSC), for example, the calorimeter sold under the name "MDSC 2920" by TA Instruments.
[0062] Liquid fatty alcohols, in particular those with the C10-C34 structure, preferably have branched carbon chains and / or one or more, preferably 1 to 3 double bonds. They are preferably branched and / or unsaturated (C=C double bond) and contain 12 to 40 carbon atoms.
[0063] Liquid fatty alcohols may be represented by: R-OH, where R denotes a C12-C24 branched alkyl group or an alkenyl group (comprising at least one C=C double bond in C12-C24), R optionally being substituted by one or more hydroxyl groups. Preferably, the liquid fatty alcohol is a branched saturated alcohol. Preferably, R does not contain a hydroxyl group. These include oleic alcohol, oleyic alcohol, linoleic alcohol, linolenic alcohol, isocetyl alcohol, isostearyl alcohol, 2-octyl-l-dodecanol, 2-butyloctanol, 2-hexyl-l-decanol, 2-decyl-l-tetradecanol, and 2-tetradecyl-l-cetanol. Preferably, the liquid fatty alcohol is 2-octyl-l-dodecanol. Preferably, one or Several liquid fatty alcohols are chosen from among 2-octyldodecanol, isostearyl alcohol, 2-hexyldecanol, 2-butyloctanol, 2-undecylpentadecanol, linoleyl alcohol, linolenylic alcohol, undecylenyl alcohol, isostearyl alcohol, lanolinic alcohol, oleyl alcohol, hexadecyl alcohol, octyldodecanol alcohol, linoleyl alcohol, linolenylic alcohol, lauryl alcohol and arachidyl alcohol.
[0064] The total amount of one or more liquid fatty alcohols, if present, in the anhydrous hair treatment composition will vary but is typically about 0.1 to about 10% by weight, relative to the total weight of the anhydrous hair treatment composition.In other embodiments, the anhydrous hair treatment composition includes approximately 0.1 to approximately 8% by weight, approximately 0.1 to approximately 6% by weight, approximately 0.1 to approximately 5% by weight, approximately 0.1 to approximately 4% by weight, approximately 0.5 to approximately 10% by weight, approximately 0.5 to approximately 8% by weight, approximately 0.5 to approximately 6% by weight, approximately 0.5 to approximately 5% by weight, approximately 0.5 to approximately 4% by weight, approximately 1 to approximately 10% by weight, approximately 1 to approximately 8% by weight, approximately 1 to approximately 6% by weight, approximately 1 to approximately 5% by weight, or approximately 1 to approximately 4% by weight of one or more liquid fatty alcohols, relative to the total weight of the anhydrous hair treatment composition.Preferably, the anhydrous hair treatment composition includes about 0.1 to about 10% by weight, preferably about 0.5 to about 8% by weight, more preferably about 0.5 to about 6% by weight, and even more preferably about 1 to about 4% by weight of one or more liquid fatty alcohols, relative to the total weight of the anhydrous hair treatment composition.
[0065] In a preferred embodiment, the anhydrous hair treatment composition includes a combination of one or more solid fatty alcohols and one or more liquid fatty alcohols. For example, the combination of one or more solid fatty alcohols and one or more liquid fatty alcohols comprises, consists essentially of, or consists of:
[0066] (i) about 0.1 to about 12% by weight, preferably about 0.5 to about 10% by weight, more preferably about 1 to about 8% by weight, and even more preferably about 2 to about 6% by weight of one or more solid fatty alcohols selected from stearyl alcohol, cetyl alcohol, cetearyl alcohol, myristyl alcohol and behenyl alcohol; and
[0067] (ii) about 0.1 to about 10% by weight, preferably about 0.2 to about 8% by weight, more preferably about 0.5 to about 6% by weight, and even more preferably about 1 to about 5% by weight of one or more liquid fatty alcohols selected from isostearyl alcohol, oleyl alcohol, octyldodecanol, linoleyl alcohol, linolenylic alcohol, lauryl alcohol, caprylic alcohol and capric alcohol.
[0068] Ratio between solid fatty alcohols and liquid fatty alcohols
[0069] In cases where the anhydrous hair treatment composition includes a combination of one or more solid fatty alcohols and one or more liquid fatty alcohols, the weight ratio between the one or more solid fatty alcohols and the one or more liquid fatty alcohols will vary. Nevertheless, the weight ratio is typically from about 10:1 to about 1:5 (solid fatty alcohols : liquid fatty alcohols).In other embodiments, the weight ratio between the one or more solid fatty alcohols and the one or more liquid fatty alcohols is approximately 10:1 to approximately 1:2, approximately 8:1 to approximately 1:2, approximately 6:1 to approximately 1:2, approximately 5:1 to approximately 1:2, approximately 10:1 to approximately 1:1, approximately 8:1 to approximately 1:1, approximately 6:1 to approximately 1:1, approximately 5:1 to approximately 1:1, approximately 10:1 to approximately 1.5:1, approximately 8:1 to approximately 1.5:1, approximately 6:1 to approximately 1.5:1, approximately 5:1 to approximately 1.5:1, approximately 10:1 to approximately 1.8:1, approximately 8:1 to approximately 1.8:1, from about 6:1 to about 1.8:1 or from about 5:1 to about 1.8:1. In another preferred embodiment, the total amount of one or more solid fatty alcohols is greater than or equal to the total amount of one or more liquid fatty alcohols.Preferably, the weight ratio between one or more solid fatty alcohols and one or more liquid fatty alcohols is about 10:1 to about 1:2, more preferably about 8:1 to about 1:1, and even more preferably about 6:1 to about 1.2:1. Ratio between (b) and (c)
[0070] The one or more cationic surfactants of (b) and the one or more fatty alcohols of (c) are in a weight ratio that will vary. Nevertheless, the weight ratio between (b) and (c) can be from about 1:12 to about 2:1 ((b):(c)). In other embodiments, the weight ratio between (b) and (c) is approximately 1:12 to approximately 2:1, approximately 1:12 to approximately 1:1, approximately 1:12 to approximately 1:2, approximately 1:12 to approximately 1:4, approximately 1:12 to approximately 1:5, approximately 1:10 to 2:1, approximately 1:10 to 1:1, approximately 1:10 to 1:2, approximately 1:10 to 1:3, approximately 1:10 to 1:4, approximately 1:10 to 1:5, approximately 1:8 to 2:1, approximately 1:8 to 1:1, approximately 1:8 to 2:1, approximately 1:8 to 3:1, approximately 1:8 to 1:4, from about 1:8 to 1:5, from about 1:7 to about 2:1, from about 1:7 to about 1:1, from about 1:7 to about 1:2 or from about 1:7 to about 1:4.Preferably, the weight ratio between (b) and (c) is preferably about 1:12 to about 1:1, preferably about 1:10 to about 1:2, more preferably about 1:8 to about 1:4. (d) Sensory-active agents.
[0071] A sensory-active agent is a substance or compound that provides or causes an individual (a human) to experience a sensation, for example a sensation on the skin, a pleasant odor and / or a pleasant taste. Non-limiting examples include essential oils, cooling agents, warming agents, terpenes, and terpenoids. There is dual use between essential oils, cooling agents, warming agents, and terpenes and / or terpenoids. For example, menthol can be supplied as an essential oil, is a cooling agent, and is a terpene. In cases where dual use exists, only one substance or compound will be interpreted as an essential oil, a cooling agent, a warming agent, a terpene, and / or a terpenoid. A single substance or compound does not act simultaneously as more than one essential oil, cooling agent, warming agent, or terpene and / or terpenoid.For example, when menthol is included in an anhydrous hair treatment composition, menthol is interpreted as an essential oil if it is included or added as an essential oil, or menthol serves as a cooling agent or terpene.
[0072] The total amount of one or more sensorially active agents in the anhydrous hair treatment composition, if present, will vary but is typically about 0.05 to about 8% by weight, relative to the total weight of the anhydrous hair treatment composition. In other embodiments, the anhydrous hair treatment composition includes approximately 0.05 to approximately 5% by weight, approximately 0.5 to approximately 4% by weight, approximately 0.5 to approximately 3% by weight, approximately 0.1 to approximately 5% by weight, approximately 0.1 to approximately 4% by weight, approximately 0.1 to approximately 3% by weight, approximately 0.5 to approximately 5% by weight, approximately 0.5 to approximately 4% by weight, approximately 0.5 to approximately 3% by weight, approximately 1 to approximately 5% by weight, approximately 1 to approximately 4% by weight, or approximately 1 to approximately 3% by weight of one or more cooling agents, relative to the total weight of the anhydrous hair treatment composition.Preferably, the anhydrous hair treatment composition includes from about 0.05 to about 5% by weight, more preferably from about 0.1 to about 4% by weight, and even more preferably from about 0.5 to about 3% by weight of one or more sensory-active agents, relative to the total weight of the anhydrous hair treatment composition. (d)(i) Essential oils
[0073] The composition of an anhydrous hair treatment may include one or more essential oils. Essential oils are concentrated liquid extracts of aromatic plants, typically in the form of volatile oils containing compounds that give the plants their characteristic scents and therapeutic properties. Distillation involves passing steam through the plant, causing the aromatic compounds to evaporate. The steam is then cooled and condensed, separating the essential oil from the water. Essential oils are derived from different parts of the plants, such as the flowers, leaves, bark, and roots. or fruits. For example, lavender essential oil is extracted from the flowers, lemon essential oil from the peel, and ginger essential oil from the rhizome. Essential oils have a unique chemical composition that can vary within the same plant species, or from one plant to another.
[0074] For the purposes of this disclosure, the term "essential oil" is used in accordance with the European Pharmacopoeia; and essential oils can be identified and characterized according to Do et al., Proposal for a standardised method for the identification of essential oils by HPTLC, Pharmeur. Bio. Sci. Notes. 2021; 2021: 157-166 (PMID: 34751647), which are incorporated herein in their entirety by reference. Essential oils are of plant origin and can therefore fall within the broad spectrum of vegetable oils, but can be considered a specific and unique type of vegetable oil. For the purposes of this disclosure, the term "vegetable oil" does not include essential oils, and the term "essential oil" does not include vegetable oils, even though essential oils are obtained from plants. In cases where dual use could exist such that a particular oil could be interpreted as both a vegetable oil and an essential oil, a single oil cannot serve simultaneously as both a vegetable oil and an essential oil in the composition of an anhydrous hair treatment.
[0075] Non-limiting examples of essential oils include lavender oil, geranium oil, juniper berry oil, bay leaf oil, lemon oil, mandarin oil, orange oil, wormwood oil, African bluegrass oil, ajowan oil, anethi oil, angelica root oil, star anise oil, wild arborvitae oil, mugwort oil, asafoetida oil, Australian lemon balm oil, basil oil, benzoin oil, Calabrian bergamot oil, betel leaf oil, birch oil, birch tar oil, blackcurrant seed oil, blood orange oil, Buchu oil, cabreuva oil, cade oil, cajeput oil, calamus root oil, camphor oil, cananga oil, caraway oil, cardamom oil, carrot oil, cassia oil, cedar leaf oil, Atlas cedarwood oil,Chinese cedarwood oil, Himalayan cedarwood oil, Texas cedarwood oil, Virginia cedarwood oil, celery seed oil, German chamomile oil, Moroccan chamomile oil, Roman chamomile oil, chaulmoogra oil, goosefoot oil, chili seed oil, cinnamon bark oil, cinnamon leaf oil, citral oil, Ceylon lemongrass oil, clary sage oil, clementine oil, clove bud oil, clove leaf oil, cognac oil, copaiba oil, coriander oil, costus root oil, coffee oil, cumin oil, turmeric oil, curry oil, Australian blue cypress oil, French cypriol oil, oil of, davana, dill seed oil, dill oil, elemi oil, emu oil, eucalyptus oil, bitter fennel oil, fenugreek oil, balsam fir oil, fir needle oil, organic flaxseed oil, frankincense oil, garlic oil, galbanum oil, ginger oil, palmarosa oil, gaia oil, pink grapefruit oil, white grapefruit oil, guaiac wood oil, helichrysum oil, horseradish oil, hyadacheim oil, hyssop oil, jamarosa root oil, Himalayan wild oil, karanj seed oil, oil of kanuka, katrafay oil, lime oil, kunzea oil, kukui oil, lantana oil, bay leaf oil, lemongrass oil, lemon eucalyptus oil, lemon myrtle oil, 5 times lemon oil, lican oil, lime oil, litsea cubeba oil, lovage leaf oil, mace oil,mandarin oil, manuka oil, marjoram oil, lemon balm leaf oil, liquid menthol oil, mullein oil, myrrh oil, myrtle oil, neem oil, neroli oil, Australian nerolina oil, niaouli oil, noni oil, nutmeg oil, oat oil, onion oil, opoponax oil, bitter orange oil, sweet orange oil, oregano oil, 5 times orange oil, palmarosa oil, parsley oil, patchouli oil, pennyroyal mint oil, pepper oil, peppermint oil, Peruvian balsam oil, petitgrain oil, chili leaf oil, Long-leaf pine oil, Scots pine oil, commercial pine oil, pomegranate oil, Siam wood oil, wild ravensara oil, Australian rosalina oil, rose geranium oil, rosemary oil, rosewood oil, rue oil, Dalmatian sage oil,Sandalwood oil, savine oil, mountain savory oil, sea buckthorn oil, spearmint oil, spikenard oil, spruce oil, sugandh kokila oil, sumac oil, marigold oil, mandarin oil, annual tansy oil, tarragon oil, mandarin oil (5 times), tea tree oil, lemon tea oil, thyme oil, tolu balsam oil, turmeric oil, valerian root oil, vanilla oil (10 times), vetiver oil, wintergreen oil, wild verbena oil, wormwood oil, yarrow oil, and ylang-ylang oil.
[0076] In a preferred embodiment, the anhydrous hair treatment composition includes at least one essential oil selected from lavender, peppermint, rosemary, tea tree, Roman chamomile, bergamot, jasmine, ylang-ylang, eucalyptus, geranium, patchouli, lemon, frankincense, lemongrass, cedarwood and grapefruit.
[0077] The total quantity of one or more essential oils in the anhydrous hair treatment composition will vary but is typically from about 0.01 to about 5% by weight, relative to the total weight of the anhydrous hair treatment composition. In other embodiments, the hair treatment composition anhydrous includes approximately 0.01 to approximately 4% by weight, approximately 0.01 to approximately 3% by weight, approximately 0.01 to approximately 2% by weight, approximately 0.05 to approximately 5% by weight, approximately 0.05 to approximately 4% by weight, approximately 0.05 to approximately 3% by weight, approximately 0.05 to approximately 2% by weight, approximately 0.1 to approximately 5% by weight, approximately 0.1 to approximately 4% by weight, approximately 0.1 to approximately 3% by weight, approximately 0.1 to approximately 2% by weight, approximately 0.5 to approximately 5% by weight, approximately 0.5 to approximately 4% by weight, approximately 0.5 to approximately 3% by weight, or approximately 0.5 to approximately 2% by weight of one or more essential oils, relative to the total weight of the anhydrous hair treatment composition.Preferably, the anhydrous hair treatment composition includes about 0.05 to about 5% by weight, more preferably about 0.1 to about 4% by weight, and even more preferably about 0.5 to about 3% by weight of one or more essential oils, relative to the total weight of the anhydrous hair treatment composition. (d)(ii) Cooling agents
[0078] The composition of an anhydrous hair treatment may include one or more cooling agents. As its name suggests, a cooling agent is a substance or compound that imparts or makes a sensation of cooling to an individual (a human being). Non-limiting examples of cooling agents include menthol, N-ethyl-p-menthyl-3-carboxiamide, cubebol, isopulegol, 3-(L-menthoxy)propane-1,2-diol, cis / trans-p-menthane-3,8-diol, 3-(L-menthoxy)-2-methylpropane-1,2-diol, 2-[2-(p-menthan-3-yloxy)ethoxy]ethanol, menthoxyethanol, (1R,2R,4R)-l-(2-hydroxy-4-methylcyclohexyl)ethenone, (1R,2R,5R)-N-ethyl-5-methyl-2-(prop-l-en-2-yl)cyclohexanecarboxamide, N-(3-hydroxy-4-methoxyphenyl)-2-isopropyl-5,5-dimethyl-cyclohexanecarboxamide, the N-[4-(cyanomethyl)phenyl]-2-isopropyl-5,5-dimethyl-cyclohexanecarboxamide, N-(2-hydroxy-2-phenylethyl)-2-isopropyl-5,5-dimethyl-cyclohexane-l-carboxamide, L-menthol lactate, (-)-menthyl ethylene glycol carbonate, (-)-menthone 1,2-glycerol ketal, D / L-menthone 1,2-glycerol ketal, (-)-menthyl 1-propylene glycol carbonate, (-)-menthyl 2-propylene glycol carbonate, D / L-menthyl 1-propylene glycol carbonate, D / L-menthyl 2-propylene glycol carbonate, (1R,2S,5R)-N-(4-methoxyphenyl)-5-methyl-2-(l-methylethyl)cyclohexanecarboxamide, menthyl ethylamido oxalate, (E)-3-benzo[l,3]dioxol-5-yl-N,N-diphenyl-2-propenamide, 3,4-methylenedioxycinnamic acid, N,N-diphenylamide, N,N-dimethyl (-)-menthyl succinimide, (lR,2S,5R)-N-(4-(carbamoylmethyl)phenyl)-menthylcarboxamide, (-)-menthyl pyrrolidone carboxylate, L-phenylephrine p-menthane carboxamide, (1R,2S,5R)-N-(4-(cyanomethyl)-phenyl)menthylcarboxamide, (1R,2S,5R)-N-(2-(pyridin-2-yl)ethyl)menthylcarboxamide, 6-isopropyl-3,9-dimethyl-1,4-dioxaspiro[4.5]decan-2-one, (1R,2R,4S)-dihydroumbellulol, N-ethyl-p-menthane-3-carboxamide, 2-isopropyl-N,2,3-trimethylbutyramide, ethyl 3-(p-menthane-3-carboxamido)acetate, N-ethyl-2,2-düsopropylbutanamide, N-(l,l-dimethyl-2-hydroxyethyl)-2,2-dimethylbutanamide, N-cyclopropyl-5-methyl-2-isopropyl-cyclohexanecarbonecarboxamide, (-)-menthyl acetoacetate, (-)-menthyl succinate, (-)-menthyl (S)-3-hydroxybutarate, (-)-menthyl glutarate, l-[2-hydroxyphenyl]-4-[2-nitrophenyl]-l,2,3,6-tetrahydropyrimidine-2-one, di-(-)-menthyl glutarate, N-(2-hydroxyethyl)-2,3-dimethyl-2-isopropylbutanamide and peppermint oil.In a preferred embodiment, the anhydrous hair treatment composition includes peppermint oil and menthol.
[0079] The total amount of one or more cooling agents, if present, will vary, but is typically about 0.01 to about 5% by weight, relative to the total weight of the anhydrous hair treatment composition.In other embodiments, the anhydrous hair treatment composition includes approximately 0.01 to approximately 4% by weight, approximately 0.01 to approximately 3% by weight, approximately 0.01 to approximately 2% by weight, approximately 0.05 to approximately 5% by weight, approximately 0.05 to approximately 4% by weight, approximately 0.05 to approximately 3% by weight, approximately 0.05 to approximately 2% by weight, approximately 0.1 to approximately 5% by weight, approximately 0.1 to approximately 4% by weight, approximately 0.1 to approximately 3% by weight, approximately 0.1 to approximately 2% by weight, approximately 0.5 to approximately 5% by weight, approximately 0.5 to approximately 4% by weight, approximately 0.5 to approximately 3% by weight, or approximately 0.5 to approximately 2 % by weight of one or more cooling agents, relative to the total weight of the anhydrous hair treatment composition.Preferably, the anhydrous hair treatment composition includes about 0.05 to about 5% by weight, more preferably about 0.1 to about 4% by weight, and even more preferably about 0.5 to about 3% by weight of one or more cooling agents, relative to the total weight of the anhydrous hair treatment composition. (d)(iii) Heating agents
[0080] The composition of an anhydrous hair treatment may include one or more warming agents. As its name suggests, a "warming agent" is a substance or compound that provides or causes a sensation of warmth to an individual (a human being). Non-limiting examples of warming agents include vanillyl ethyl ether, vanillyl propyl ether, vanillin propylene glycol acetal, ethyl vanillin propylene glycol acetal, capsaicin, gingerol, vanillyl butyl ether, 4-(l-menthoxymethyl)-2-phenyl-l,3-dioxolane, 4-(l-menthoxymethyl)- 2-(3',4'-dihydroxyphenyl)-1,3-dioxolane, 4-(1-menthoxymethyl)-2-(2'-hydroxy-3'-methoxyphenyl)-1,3-dioxolane, 4-(1-menthoxymethyl)-2-(4'-methoxyphenyl)-1,3-dioxolane, 4-(1-menthoxymethyl)-2-(3',4'-methylenedioxyphenyl)-1,3-dioxolane, black pepper extract, cinnamaldehyde, piperine, chili pepper oil, cayenne pepper oleoresin, capsicum oleoresin, ginger oleoresin, nonyl vanillylamide, 4-(l-menthoxy-methyl)-2-(3'-methoxy-4'-hydroxyphenyl)-l,3-dioxolane, vanillin-l,2-hexylene glycol acetal, vanillin-1,2-butylene glycol acetal, vanillin-l-butoxyglycerol acetal, ethyl vanillin, ethyl vanillyl alcohol (3-ethoxy-4-hydroxybenzyl alcohol), ethyl homovanillate and vanillyl isopropyl ether.
[0081] In a preferred embodiment, the anhydrous hair treatment composition includes at least one heating agent selected from vanillyl ethyl ether, vanillyl propyl ether, vanillin propylene glycol acetal, ethyl vanillin propylene glycol acetal, capsaicin, gingerol, vanillyl butyl ether, 4-(l-menthoxymethyl)-2-phenyl-l,3-dioxolane, 4-(l-menthoxymethyl)-2-(3',4'-dihydroxyphenyl)-1,3-dioxolane, 4-(l-menthoxymethyl)-2-(2'-hydroxy-3'-methoxyphenyl)-l,3-dioxolane, 4-(l-menthoxymethyl)-2-(4'-methoxyphenyl)-l,3-dioxolane, 4-(l-menthoxymethyl)-2-(3',4'-methylenedioxyphenyl)-l,3-dioxolane, black pepper extract, cinnamaldehyde, piperine, chili pepper oil, cayenne pepper oleoresin, capsicum oleoresin, ginger oleoresin, nonyl vanillylamide, 4-(l-menthoxymethyl)-2-(3'-methoxy-4'-hydroxyphenyl)-l,3-dioxolane, vanillin-1,2-hexylene glycol acetal, vanillin-1,2-butylene glycol acetal,Vanillin-1-acetal butoxyglycerol, ethyl vanillin, ethyl vanillyl alcohol (3-ethoxy-4-hydroxybenzyl alcohol), ethyl homovanillate, and vanillyl isopropyl ether.
[0082] The total amount of one or more heating agents, if any, will vary, but is typically about 0.01 to about 5% by weight, relative to the total weight of the anhydrous hair treatment composition. In other embodiments, the anhydrous hair treatment composition includes approximately 0.01 to approximately 4% by weight, approximately 0.01 to approximately 3% by weight, approximately 0.01 to approximately 2% by weight, approximately 0.05 to approximately 5% by weight, approximately 0.05 to approximately 4% by weight, approximately 0.05 to approximately 3% by weight, approximately 0.05 to approximately 2% by weight, approximately 0.1 to approximately 5% by weight, approximately 0.1 to approximately 4% by weight, approximately 0.1 to approximately 3% by weight, approximately 0.1 to approximately 2% by weight, approximately 0.5 to approximately 5% by weight, approximately 0.5 to approximately 4% by weight, approximately 0.5 to approximately 3% by weight, or approximately 0.5 to approximately 2% by weight of one or more heating agents, relative to the total weight of the anhydrous hair treatment composition.Preferably, the composition of anhydrous hair treatment includes about 0.05 to about 5% by weight, more preferably about 0.1 to about 4% by weight, and even more. more preferably from about 0.5 to about 3% by weight of one or more heating agents, relative to the total weight of the anhydrous hair treatment composition. (d)(vi) Terpenes / Terpenoids
[0083] The composition of anhydrous hair treatment may include one or more terpenes and / or terpenoids. Terpenes are simple hydrocarbons, while terpenoids are a modified family of terpenes with various functional groups and a displaced or deleted oxidized methyl group. Depending on the number of carbon motifs, terpenoids are classified as monoterpenes, sesquiterpenes, diterpenes, sesterpenes, and triterpenes.Non-limiting examples of terpenes and terpenes include menthol, myrcene, limonene, linalool, humulene, terpinolene, camphene, terpineol, beta-caryophylene, 1,8-cineole, anisole, anethole, eugenol, thymol, bomeol, citronellol, isomenthol, camphor, camphene, carvone, geraniol, menthone, pulegone, α-pinene, 3-pinene, sabinene, α-terpinene, 3-bisabolene, trans-α-bergamotene, nerol, neral, cedrol, cedrene, thujopsene, methyl thujate, and thujic acid.
[0084] The total amount of one or more terpenes and / or terpenoids, if present, will vary, but is typically about 0.01 to about 5% by weight, relative to the total weight of the anhydrous hair treatment composition.In other embodiments, the anhydrous hair treatment composition includes approximately 0.01 to approximately 4% by weight, approximately 0.01 to approximately 3% by weight, approximately 0.01 to approximately 2% by weight, approximately 0.05 to approximately 5% by weight, approximately 0.05 to approximately 4% by weight, approximately 0.05 to approximately 3% by weight, approximately 0.05 to approximately 2% by weight, approximately 0.1 to approximately 5% by weight, approximately 0.1 to approximately 4% by weight, approximately 0.1 to approximately 3% by weight, approximately 0.1 to approximately 2% by weight, approximately 0.5 to approximately 5% by weight, approximately 0.5 to approximately 4% by weight, approximately 0.5 to approximately 3% by weight, or approximately 0.5 to approximately 2% by weight of one or more terpenes and / or terpenoids, relative to the total weight of the composition. anhydrous hair treatment.Preferably, the anhydrous hair treatment composition includes about 0.05 to about 5% by weight, more preferably about 0.1 to about 4% by weight, and even more preferably about 0.5 to about 3% by weight of one or more terpenes and / or terpenoids, relative to the total weight of the anhydrous hair treatment composition. (e) Emollients
[0085] Anhydrous hair treatment compositions may optionally include one or more emollients. Emollients are substances that help to soothe, soften, and increase the moisture levels of the hair and skin. Non-limiting examples of emollients include fatty ethers, fatty esters and fatty carbonates, and caprylic / capric triglyceride. The anhydrous hair treatment composition includes one or more emollients, provided that one or more of the emollients is a caprylic / capric triglyceride, typically in an amount of approximately 5% by weight or more, relative to the total weight of the anhydrous hair treatment composition.
[0086] The total amount of one or more emollients, if present, will vary, but is typically about 1 to about 55% by weight, relative to the total weight of the anhydrous hair treatment composition. In other embodiments, the anhydrous hair treatment composition includes approximately 1 to approximately 50% by weight, approximately 1 to approximately 40% by weight, approximately 1 to approximately 35% by weight, approximately 5 to approximately 55% by weight, approximately 5 to approximately 50% by weight, approximately 5 to approximately 40% by weight, approximately 5 to approximately 35% by weight, approximately 10 to approximately 55% by weight, approximately 10 to approximately 50% by weight, approximately 10 to approximately 40% by weight, approximately 10 to approximately 35% by weight, approximately 20 to approximately 55% by weight, approximately 20 to approximately 50% by weight, approximately 20 to approximately 45% by weight, approximately 20 to approximately 40% by weight, and approximately 25 to approximately 55% by weight. % by weight, from approximately 25 to approximately 50% by weight, from approximately 25 to approximately 45% by weight,of about 25 to about 40% by weight, of about 30 to about 55% by weight, of about 30 to about 50% by weight, of about 30 to about 45% by weight, of about 30 to about 40% by weight, of about 35 to about 55% by weight, of about 35 to about 50% by weight, of about 35 to about 45% by weight, or of about 35 to about 40% by weight of one or more emollients, relative to the total weight of the anhydrous hair treatment composition. Preferably, the anhydrous hair treatment composition includes from about 1 to about 55% by weight, more preferably from about 10 to about 50% by weight, and even more preferably from about 20 to about 45% by weight of one or more emollients relative to the total weight of the anhydrous hair treatment composition.
[0087] Non-limiting examples of fatty esters, fatty ethers, fatty carbonates and caprylic / capric triglyceride are provided below. (e)(i) Fatty ethers
[0088] The anhydrous hair treatment composition may optionally include one or more fatty ethers. The fatty ethers may be monoalkyl or dialkyl fatty ethers, and are optionally polyalkoxylated, for example, polyethoxylated or polypropoxylated. At least one alkyl group of the fatty ethers preferably has a carbon length of at least 4 carbons, preferably at least 6 carbons, and may be saturated or unsaturated, linear or branched, and optionally substituted, for example, by one or more hydroxyl groups. For example, at least one of the The alkyl group may be saturated or unsaturated, linear or branched in C4-C26, C6-C26, or C6-C24, optionally substituted, for example, by one or more hydroxyl groups. Preferably, the total number of carbon atoms in the fatty ether is greater than or equal to 10. In other embodiments, the total number of carbon atoms in the fatty ether is greater than 12, more preferably greater than 14. In a preferred embodiment, the fatty ether is a dialkyl ether of formula Ri ORi, in which Ri represents a C4-C24 alkyl group, preferably a C6-C20 alkyl group, more preferably a C6-Ci8 alkyl group, and even more preferably a C6-Ci2 alkyl group. Non-limiting examples of such fatty dialkyl ethers include dihexyl ether, dioctyl ether, diethylhexyl ether, dioctyl ether, dodecyl ether, and dicaprylyl ether.
[0089] Non-limiting examples of suitable polyoxyethylene fatty ethers include polyoxyethylene cetyl / stearyl ether, polyoxyethylene cholesterol ether, polyoxyethylene laurate or dilaurate, polyoxyethylene stearate or distearate, and polyoxyethylene lauryl or stearyl ether, wherein the polyoxyethylene head group ranges from about 2 to about 100 groups. In some embodiments, the polyoxyethylene fatty ethers include polyoxyethylene stearyl ether, polyoxyethylene myristyl ether, and polyoxyethylene lauryl ether having from about 3 to about 10 oxyethylene units.
[0090] In a preferred embodiment, at least one or more fatty ethers are selected from a dialkyl fatty ether chosen from dicaprylyl ether, didecyl ether, dimyristyl ether, distearyl ether, dilauryl ether, dihexyl ether, dioctyl ether, diethylhexyl ether, dioctyl ether, and dodecyl ether. In a preferred embodiment, at least one or more fatty ethers is a dicaprylyl ether.
[0091] The total amount of one or more fatty ethers, if present, will vary, but is typically about 1 to about 20% by weight, relative to the total weight of the anhydrous hair treatment composition. In other embodiments, the anhydrous hair treatment composition includes about 1 to about 18% by weight, about 1 to about 15% by weight, about 1 to about 12% by weight, about 2 to about 20% by weight, about 2 to about 18% by weight, about 2 to about 15% by weight, about 2 to about 12% by weight, about 5 to about 20% by weight, about 5 to about 18% by weight, about 5 to about 15% by weight, about 5 to about 12% by weight, about 8 to about 20%, about 8 to about 18%, about 8 to about 15%, or about 8 to about 12% of one or more fatty ethers, relative to the total weight of the anhydrous hair treatment composition.Preferably, the composition of anhydrous hair treatment includes about 2 to about 18% by weight, more preferably about 4 to . about 16% by weight, and even more preferably about 6 to about 14% by weight of one or more fatty ethers, relative to the total weight of the anhydrous hair treatment composition. (e)(ii) Fatty esters
[0092] The anhydrous hair treatment composition may optionally include one or more fatty esters. Non-limiting examples of fatty esters include dicarboxylic acid fatty esters, monocarboxylic acid fatty esters, propylene glycol esters of fatty acids,
[0093] Non-limiting examples of fatty acid dicarboxylic acid esters include those of formula R3OOCR2COOR3, which can be obtained from the esterification of a dicarboxylic acid (=HOOC-R2COOH) and a monoalcohol (R3-OH). R2 represents an alkylene group at C2-10, preferably an alkylene group at C4-8, which optionally includes at least one OH group. R3 represents an alkyl group at C2-14, preferably an alkyl group at C2-8. The dicarboxylic acid may include at least one OH group. Non-limiting examples of dicarboxylic acids comprising hydroxyl groups are tartaric acid, pentaric acid, and 3-hydroxyglutaric acid.Non-limiting examples of suitable alcohols (R3-OH) include ethanol, propanol, isopropanol, butanol, hexanol, octanol, 2-ethylhexanol, nonanol, isononanol, decanol, isodecanol, dodecanol, and isododecanol, preferably chosen from the group consisting of ethanol, isopropanol, butanol, and 2-ethylhexanol. Preferred alcohols include ethanol, propanol, isopropanol, and butanol.
[0094] Non-limiting examples of fatty acid esters of monocarboxylic acid include aliphatic monoesters of formula R4COOR5, which can be obtained from an esterification of a carboxylic acid (=R4-COOH) and a monoalcohol (R5-OH). Represents a C4 alkyl group, preferably a C6 alkyl group. i8. R5 represents a C8-2o alkyl group, preferably a Cx 16 alkyl group, more preferably a Cio ie- alkyl group. Non-limiting examples of suitable carboxylic acids include capronic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, 3,5,5-trimethylhexanoic acid, isononanoic acid, lauric acid, myristic acid, palmitic acid, stearic acid, and arachidonic acid.Non-limiting examples of suitable alcohols (R5-OH) include octanol, 2-ethylhexanol, nonanol, isononanol, decanol, isodecanol, dodecanol, isododecanol, tridecanol, iso-tridecanol, and cetearyl alcohol. Non-limiting examples of fatty esters with the formula R4COOR5 include ethylhexyl cocoate, ethylhexyl palmitate, isotridecyl myristate, isotridecyl isononanoate, isodecyl ethylhexanoate, and isononanoate. isodecyl, isodecyl octanoate, isodecyl neopentanoate and cetearyl isononanoate.
[0095] Non-limiting examples of propylene glycol fatty acid esters include propylene glycol esters of medium-chain fatty acids (fatty acids having 6 to 12 carbon atoms), such as propylene glycol dicaprylate / dicaprate, propylene glycol dipelargonate, and propylene glycol dilaurate. A preferred propylene glycol fatty acid ester is propylene glycol dicaprylate / dicaprate. The term "propylene glycol dicaprylate / dicaprate" is understood by those skilled in the art to refer to a combination containing propylene glycol dicaprylate, propylene glycol dicaprylate-caprate, and propylene glycol dicaprate, which may vary in the ratio of these components. An example of a commercially available form of propylene glycol dicaprylate / dicaprate is CAPTEX® 200, available from Abitec Corp. (Columbus, OH, United States).
[0096] In a preferred embodiment, one or more fatty esters are selected from cetyl palmitate, cetyl stearate, cetyl esters, myristyle myristate, myristyle stearate, cetyl myristate, stearyl stearate, glyceryl stearate, propylene glycol dicaprylate / dicaprate, cetearyl ethylhexanoate, isopropyl isostearate, n-propyl myristate, isopropyl myristate, hexyl laurate, hexadecyl isostearate, hexyldecyl laurate, hexyldecyl octanoate, n-propyl palmitate and isopropyl palmitate.
[0097] The anhydrous hair treatment composition may preferably include one or more liquid fatty esters. The term "liquid fatty ester" refers to an ester that is liquid at room temperature and atmospheric pressure (25 °C, 1 atm) and that comprises in its structure at least one hydrocarbon chain containing at least 6 carbon atoms. Preferably, it has a melting point less than or equal to approximately 10 °C.
[0098] Liquid fatty esters may be esters of monoalcohols or polyols with monocarboxylic or polycarboxylic acids, at least one of the alcohols and / or acids comprising at least one hydrocarbon chain containing at least 6 carbon atoms. Liquid fatty esters include esters of a fatty acid (at least 6 carbon atoms) and a monoalcohol, more particularly esters of a mono-fatty acid and a monoalcohol. Preferably, at least one of the alcohols and / or acids is branched. Preferably, the alcohol and / or acid are saturated, and preferably both are saturated. Furthermore, the liquid fatty ester is preferably not oxyalkylated.
[0099] Liquid fatty esters include those of formula R6-COOR7, in which: R6 denotes a linear or branched, saturated or unsaturated hydrocarbon-based radical, Optionally mono- or polyhydroxylated, containing from 5 to 31 carbon atoms, preferably from 7 to 21 carbon atoms, and more preferably from 8 to 20; and R7 designates a linear or branched, saturated or unsaturated, optionally mono- or polyhydroxylated hydrocarbon-based radical containing from 1 to 20 carbon atoms. Preferably, R6 designates a linear or branched (saturated) alkyl radical containing from 6 to 22 carbon atoms, in particular from 8 to 20 carbon atoms, and more preferably from 8 to 16 carbon atoms. Preferably, R7 designates a linear (saturated) alkyl radical containing from 1 to 4 carbon atoms or a branched (saturated) alkyl radical containing from 2 to 20 carbon atoms, in particular from 4 to 20 carbon atoms. More preferably, R7 designates a branched saturated alkyl radical containing 4 to 12 carbon atoms.
[0100] Non-limiting examples of preferred liquid fatty esters include ethyl laurate, butyl laurate, hexyl laurate, isohexyl laurate, isopropyl laurate, methyl myristate, ethyl myristate, butyl myristate, isobutyl myristate, isopropyl myristate, 2-octyldodecyl myristate, 2-ethylhexyl monococoate (or octyl monococoate), ethyl palmitate, isopropyl palmitate, isobutyl palmitate, 2-ethylhexyl palmitate (or octyl palmitate), butyl stearate, isopropyl stearate, isopropyl isostearate, stearate isobutyl, isocetyl stearate, isostearyl isostearate, isopropyl isostearate, 2-ethylhexyl stearate (or octyl stearate), 2-ethylhexyl hydroxystearate (or octyl hydroxystearate), decyl oleate, isononyl isononanoate, tridecyl neopentanoate, isocetyl neopentanoate, isostearyl neopentanoate,octyldodecyl neopentanoate and isoarachidyl neopentanoate.
[0101] Preferably, one or more liquid fatty esters are selected from isopropyl myristate, methyl myristate, ethyl myristate, butyl myristate, isobutyl myristate, 2-octyldodecyl myristate, 2-ethylhexyl monococoate (or octyl monococoate), ethyl palmitate, isopropyl palmitate, isobutyl palmitate, 2-ethylhexyl palmitate (or octyl palmitate), butyl stearate, isopropyl stearate, isobutyl stearate, isocetyl stearate, isostearyl isostearate, isopropyl isostearate, stearate of 2-ethylhexyl (or octyl stearate), isononyl isononanoate, 2-ethylhexyl hydroxystearate (or octyl hydroxystearate) and decyl oleate.Preferably, one or more liquid fatty esters are chosen from butyl stearate, isopropyl stearate, isopropyl isostearate, isobutyl stearate, isocetyl stearate, isostearyl isostearate, isopropyl isostearate, 2-ethylhexyl stearate (or octyl stearate), hydroxystearate. 2-ethylhexyl (or octyl hydroxy stearate), decyl oleate, isononyl isononanoate, isopropyl myristate, isononyl isononanoate and isopropyl palmitate.
[0102] The total amount of one or more fatty esters, if present, will vary, but is typically about 1 to about 20% by weight, relative to the total weight of the anhydrous hair treatment composition. In other embodiments, the anhydrous hair treatment composition includes approximately 1 to approximately 18% by weight, approximately 1 to approximately 15% by weight, approximately 1 to approximately 12% by weight, approximately 2 to approximately 20% by weight, approximately 2 to approximately 18% by weight, approximately 2 to approximately 15% by weight, approximately 2 to approximately 12% by weight, approximately 5 to approximately 20% by weight, approximately 5 to approximately 18% by weight, approximately 5 to approximately 15% by weight, approximately 5 to approximately 12% by weight, approximately 8 to approximately 20%, approximately 8 to approximately 18%, approximately 8 to approximately 15%, or approximately 8 to approximately 12% of one or more fatty esters, relative to the total weight of the anhydrous hair treatment composition.Preferably, the anhydrous hair treatment composition includes about 2 to about 18% by weight, more preferably about 4 to about 16% by weight, and even more preferably about 6 to about 14% by weight of one or more fatty esters, relative to the total weight of the anhydrous hair treatment composition. (e)(iii) Fatty carbonates
[0103] The anhydrous hair treatment composition may optionally include one or more fatty carbonates. Fatty carbonates are also known as "fatty carbonate esters." For the purposes of this disclosure, fatty carbonates (or fatty carbonate esters) are distinct from the "fatty esters" mentioned above. A fatty carbonate is a carbonate fraction accompanied by one or two alkyl groups having at least 6 carbon atoms. Fatty carbonates may be represented by the formula R8O(C=O)OR9, in which R8 and R9 are either linear or branched, saturated or unsaturated alkyl chains, and at least one of R8 and R9 is an alkyl group having at least 6 carbon atoms.For example, R8 and R9 independently have 1 to 30 carbon atoms, preferably 2 to 28 carbon atoms, more preferably 4 to 24 carbon atoms, or even more preferably 6 to 22 carbon atoms, provided that at least one of R8 and R9 is an alkyl group having at least 6 carbon atoms. Preferably, the one or more fatty carbonates are chosen from C14-15 dialkyl carbonate, dicaprylyl carbonate, dipentyl carbonate, dimyristyle carbonate, diethylhexyl carbonate, dipropylheptyl carbonate, and other carbonates. didodecyl, ethyldodecyl carbonate, diheptyl carbonate, didecyl carbonate and didodecyl carbonate.
[0104] In a preferred embodiment, the anhydrous hair treatment composition includes dicaprylyl carbonate.
[0105] The total amount of one or more fatty carbonates in the anhydrous hair treatment composition, if present, will vary but is typically about 1 to about 20% by weight, relative to the total weight of the anhydrous hair treatment composition.In other embodiments, the anhydrous hair treatment composition includes approximately 1 to approximately 15% by weight, approximately 1 to approximately 12% by weight, approximately 1 to approximately 10% by weight, approximately 1 to approximately 8% by weight, approximately 2 to approximately 20% by weight, approximately 2 to approximately 15% by weight, approximately 2 to approximately 12% by weight, approximately 2 to approximately 10% by weight, approximately 2 to approximately 8% by weight, approximately 4 to approximately 20% by weight, approximately 4 to approximately 15% by weight, approximately 4 to approximately 12% by weight, approximately 4 to approximately 10% by weight, approximately 4 to approximately 8% by weight, approximately 5 to approximately 20% by weight, approximately 5 to approximately 15% by weight, approximately 5 to approximately 10% by weight. % by weight or about 5 to about 10% by weight of one or more fatty carbonates, relative to the total weight of the anhydrous hair treatment composition.Preferably, the anhydrous hair treatment composition includes from about 1 to about 18% by weight, more preferably from about 2 to about 15% by weight, and even more preferably from about 4 to about 10% by weight of one or more fatty carbonates, relative to the total weight of the anhydrous hair treatment composition. (e)(iv) Caprylic / capric triglyceride.
[0106] Anhydrous hair treatment compositions may optionally include caprylic / capric triglyceride. Caprylic / capric triglyceride is a clear, odorless liquid derived from coconut oil and glycerin. The total amount of caprylic / capric triglyceride in the anhydrous hair treatment composition, if present, will vary but is typically from about 1 to about 25% by weight, relative to the total weight of the anhydrous hair treatment composition.In other embodiments, the anhydrous hair treatment composition includes approximately 1 to approximately 20% by weight, approximately 1 to approximately 18% by weight, approximately 1 to approximately 15% by weight, approximately 1 to approximately 12% by weight, approximately 1 to approximately 10% by weight, approximately 1 to approximately 8% by weight, approximately 1 to approximately 5% by weight, approximately 5 to approximately 20% by weight, approximately 5 to approximately 18% by weight, approximately 5 to approximately 15% by weight, approximately 5 to approximately 12% by weight, approximately 8 to approximately 25% by weight, approximately 8 to approximately 20% by weight, approximately 8 to approximately 18% by weight, approximately 8 to approximately 15% by weight, or approximately 8 to approximately 12% by weight of triglycerides caprylic / capric, relative to the total weight of the . anhydrous hair treatment composition. In a preferred embodiment, the anhydrous hair treatment composition includes from about 1 to about 25% by weight, preferably from about 5 to about 25% by weight, and more preferably from about 8 to about 12% by weight, relative to the total weight of the anhydrous hair treatment composition.
[0107] In a preferred embodiment, the anhydrous hair treatment composition includes a plurality of emollients, wherein the plurality of emollients comprises, consists essentially of, or consists of one or more fatty ethers, one or more fatty esters, one or more fatty carbonates, and / or caprylic / capric triglyceride. For example, the plurality of emollients may comprise, consist essentially of, or consist of:
[0108] (e)(i) optionally, about 1 to about 18% by weight, more preferably about 2 to about 16% by weight, and even more preferably about 6 to about 14% by weight, of one or more fatty ethers, preferably one or more fatty dialkyl ethers, more preferably wherein the one or more fatty dialkyl ethers are selected from dicaprylyl ether, didecyl ether, dimyristyl ether, distearyl ether, dilauryl ether, dihexyl ether, dioctyl ether, diethylhexyl ether or dioctyl ether, dodecyl ether, wherein dicaprylyl ether is particularly preferred; and / or
[0109] (e)(ii) optionally, about 1 to about 18% by weight, more preferably approximately 2 to approximately 16% by weight, and even more preferably approximately 6 to approximately 14% by weight, of one or more fatty esters, preferably selected from ethyl laurate, butyl laurate, hexyl laurate, isohexyl laurate, isopropyl laurate, methyl myristate, ethyl myristate, butyl myristate, isobutyl myristate, isopropyl myristate, 2-octyldodecyl myristate, 2-ethylhexyl monococoate (or octyl monococoate), ethyl palmitate, isopropyl palmitate, isobutyl palmitate, 2-ethylhexyl palmitate (or octyl palmitate), butyl stearate, stearate isopropyl, isopropyl isostearate, isobutyl stearate, isocetyl stearate, isostearyl isostearate, isopropyl isostearate, 2-ethylhexyl stearate (or octyl stearate), 2-ethylhexyl hydroxystearate (or octyl hydroxystearate), decyl oleate, isononyl isononanoate,tridecyl neopentanoate, isocetyl neopentanoate, isostearyl neopentanoate, octyldodecyl neopentanoate, and isoarachidyl neopentanoate, in which isopropyl isostearate is particularly preferred; and / or,
[0110] (e)(iii) optionally, about 1 to about 18% by weight, more preferably about 2 to about 15% by weight, and even more preferably about 4 to about 10% by weight of one or more fatty carbonates, preferably one or more fatty carbonates selected from C14-15 dialkyl carbonate, dicaprylyl carbonate, dipentyl carbonate, dimyristyle carbonate, diethylhexyl carbonate, dipropylheptyl carbonate, didodecyl carbonate, ethyldodecyl carbonate, diheptyl carbonate, didecyl carbonate or didodecyl carbonate, in which dicaprylyl carbonate is particularly preferred.
[0111] (e)(iv) optionally, about 1 to about 20% by weight, preferably about 5 to about 18% by weight, and more preferably about 8 to about 15% by weight of caprylic / capric triglyceride. (f) Miscellaneous ingredients
[0112] The anhydrous hair treatment composition optionally includes one or more miscellaneous ingredients. Miscellaneous ingredients are ingredients that are compatible with the anhydrous hair treatment composition and do not disrupt or materially affect the fundamental and innovative properties of the anhydrous hair treatment composition. Miscellaneous ingredients commonly used in cosmetics and hair care products are known in the art. Non-limiting examples include preservatives, perfumes, pH adjusters, salts, chelating agents, buffers, antioxidants, flavonoids, vitamins, botanical extracts, UV filtering agents, proteins, protein hydrolysates, emollients, humectants, hydrotropes, fillers (e.g., organic or inorganic, such as talc, calcium carbonate, dextrin, silica, etc.).), pearlescent agents, compositional colorants, etc.
[0113] In the context of this disclosure, a "composition colorant" is a compound that colors the composition but does not have an appreciable coloring effect on hair. In other words, the composition colorant is included to give the composition color for aesthetic purposes but is not intended to impart coloring properties to hair. Hair gels, for example, may come in a variety of different colors (e.g., light blue, light pink, etc.), but applying the hair gel to the hair does not visibly change the hair color.
[0114] In addition to the non-exhaustive list of miscellaneous ingredients presented above, components described as optional throughout this disclosure may be characterized as miscellaneous ingredients if they are not expressly presented as a required component of the anhydrous hair treatment composition. Thus, the term "miscellaneous ingredient" is understood as a general term representing additional components that may optionally be present in quantities designated for miscellaneous ingredients.
[0115] The total amount of miscellaneous ingredients in the anhydrous hair treatment composition, if present, will vary. However, the anhydrous hair treatment composition typically includes from about 0.01 to about 10% by weight of one or more miscellaneous ingredients, relative to the total weight of the anhydrous hair treatment composition. In other embodiments, the anhydrous hair treatment composition includes from about 0.01 to about 8% by weight, from about 0.01 to about 5% by weight, from about 0.01 to about 3% by weight, from about 0.1 to about 10% by weight, from about 0.1 to about 8% by weight, from about 0.1 to about 5% by weight, from about 0.1 to about 3% by weight, from about 1 to about 10% by weight, from about 1 to about 8% by weight, or about 1 to about 5% by weight or about 1 to about 3% by weight of one or more miscellaneous ingredients, relative to the total weight of the anhydrous hair treatment composition. Polymeric oil thickening agents
[0116] The anhydrous hair treatment composition optionally includes one or more polymeric oil-thickening agents. Similarly, in various embodiments, the anhydrous hair treatment composition is free or substantially free of polymeric oil-thickening agents. The term "polymeric oil-thickening agent" refers to a polymer that, when combined with other components of the anhydrous hair treatment composition, causes the anhydrous hair treatment composition to thicken. Non-limiting examples of oil-thickening agents include polymers and copolymers, gums, and polyethylenes. Non-polymeric oil-thickening agents may optionally be included in the anhydrous hair treatment compositions, but they are not required.Non-limiting examples of non-polymer oil-thickening agents include organo-clays, silica, and silica dimethyl silylate. In various embodiments, the anhydrous hair treatment composition is preferably free or substantially free of non-polymer oil-thickening agents. In other embodiments, in addition to one or more polymeric oil-thickening agents, the anhydrous hair treatment composition preferably includes one or more non-polymer oil-thickening agents.
[0117] Polymeric oil thickening agents include, for example, a hydrophobic polymer that is a reaction product of a natural or food-grade oil and an acrylate or methacrylate polymer, preferably a methacrylate polymer. The natural or food-grade oil may be a drying or semi-drying oil. Non-limiting examples include linseed oil, sunflower oil, tung oil, fish oil, cottonseed oil, and soybean oil. The methacrylate polymer may be formed from monomers of Methacrylate, for example, monomers selected from isobutyl methacrylate, methyl methacrylate, ethyl methacrylate, and n-butyl methacrylate. In a preferred embodiment, the hydrophobic polymer is formed from a natural or food-grade oil and an isobutyl methacrylate polymer. For example, the hydrophobic polymer may be the reaction product of approximately 72 to 77 parts by weight of the natural or food-grade oil and approximately 23 to 28 parts by weight of a methacrylate polymer. More specifically, the hydrophobic polymer may be the reaction product of linseed oil and poly(isobutyl methacrylate) in a suitable solvent, such as, for example, 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate.Preferably, the reaction product is formed from about 72 to about 77% linseed oil and about 23 to about 28% isobutyl methacrylate polymer in a suitable solvent, such as 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate, which is poly(isobutyl methacrylate / linseed oil).
[0118] The one or more polymeric oil thickening agents may include amorphous polymers formed by polymerization of an olefin. The olefin may be an ethylenically unsaturated elastomer monomer. Examples of olefins include, but are not limited to, ethylenic carbide monomers, for example those comprising one or two ethylenic unsaturations, comprising 2 to 5 carbon atoms, such as ethylene, propylene, butadiene, or isoprene.
[0119] The one or more polymeric oil thickening agents may include polycondensation products of the polyamide type resulting from the condensation between (a) at least one acid selected from dicarboxylic acids comprising at least 32 carbon atoms, such as dimeric fatty acids and (b) alkylenediamines, such as ethylenediamine, wherein the polymeric polyamide comprises at least one terminal carboxylic acid group esterified or amidated with at least one monoalcohol or monoamine comprising 12 to 30 linear, saturated carbon atoms, for example ethylenediamine / stearyl dilinoleate copolymers such as that marketed under the name Uniclear 100 VG® by Arizona Chemical.
[0120] Non-limiting examples of polymeric oil thickening agents include a C10-30 alkyl polyacrylate, a VP / hexadecene copolymer, a trimethylpentanediol / adipic acid / glycerin crosslinked polymer, an ethylene / propylene / styrene copolymer, a butylene / ethylene / styrene copolymer, a VP / eicosene copolymer, a bis-dioctadecylamide dimer dilinoleic acid / ethylenediamine copolymer, a cetearyl dimethicone crosslinked polymer, a hydrogenated C6-20 poly(olefin), an HDI / trimethylol hexyllactone crosslinked polymer, a dimethicone / vinyl dimethicone crosslinked polymer, and a vinyl dimethicone / methicone silsesquioxane crosslinked polymer. In various embodiments, Preferred polymeric oil thickening agents include hydrogenated poly(C6-20 olefin), crosslinked HDI / trimethylol hexyllactone polymer, and poly(isobutyl methacrylate / linseed oil). A combination of hydrogenated poly(C6-20 olefin) and crosslinked HDI / trimethylol hexyllactone polymer is a particularly preferred polymeric oil thickening agent.
[0121] The total amount of one or more polymeric oil thickening agents in the anhydrous hair treatment composition, if present, will vary but is typically about 0.05 to about 5% by weight, relative to the total weight of the anhydrous hair treatment composition.In other embodiments, the anhydrous hair treatment composition includes approximately 0.05 to approximately 4% by weight, approximately 0.05 to approximately 3% by weight, approximately 0.05 to approximately 2% by weight, approximately 0.05 to approximately 1% by weight, approximately 0.1 to approximately 5% by weight, approximately 0.1 to approximately 4% by weight, approximately 0.1 to approximately 3% by weight, approximately 0.1 to approximately 2% by weight, approximately 0.1 to approximately 1% by weight, approximately 0.2 to approximately 5% by weight, approximately 0.2 to approximately 4% by weight, approximately 0.2 to approximately 3% by weight, approximately 0.2 to approximately 1% of one or more polymeric oil thickening agents, relative to the total weight of the anhydrous hair treatment composition.Preferably, the anhydrous hair treatment composition includes about 0.05 to about 5% by weight, more preferably about 0.05 to about 3% by weight, and even more preferably about 0.1 to about 2% by weight of one or more polymeric oil-based thickening agents, relative to the total weight of the anhydrous hair treatment composition. Hair treatment processes
[0122] As its name suggests, anhydrous hair treatment composition is particularly useful in hair processing, especially for human hair. Anhydrous hair treatment composition is useful both as a rinse-out product and as a leave-in product. A "rinse-out" product refers to a composition that is removed by rinsing and / or washing the hair with water after or during application of the composition to the hair, and before drying and / or styling the hair. At least a portion of the composition is removed from the hair during rinsing and / or washing. A "leave-in" product refers to a composition that is not removed by rinsing and / or washing the hair after or during application of the composition to the hair. The composition remains on the hair during drying and / or throughout styling.
[0123] Processes of using the anhydrous hair treatment composition include hair care processes, hair revitalization processes, hair hydration processes, hair smoothing processes, hair frizz reduction processes, and processes for improving the Hair shine. The processes include applying an effective amount of the anhydrous hair treatment composition to the hair. For example, the anhydrous hair treatment composition may be applied to hair in need of conditioning, hair in need of hydration, hair in need of smoothing, hair prone to frizz or suffering from frizz, hair in need of shine, or any combination thereof. Furthermore, in a preferred embodiment, the anhydrous hair treatment composition is applied to damaged hair, for example, damaged hair in need of strengthening, hydration, conditioning, smoothing, and / or frizz control.
[0124] In a preferred embodiment, the anhydrous hair treatment composition is applied to wet or damp hair, for example, freshly washed and optionally conditioned hair. After rinsing out shampoo and optionally rinsing out conditioner, while the hair remains wet or damp, an effective amount of the anhydrous hair treatment composition is applied to the wet or damp hair. During application, the anhydrous hair treatment composition may be distributed by massaging, combing, or otherwise spreading over all of the hair and scalp. Preferably, the anhydrous hair treatment composition is distributed over all of the hair, including the ends.Once the anhydrous hair treatment composition has been distributed throughout the hair, it can be removed by rinsing the hair, or the hair can be washed with shampoo and optionally treated with conditioner. In this embodiment, the anhydrous hair treatment composition is a rinse-off product. Before rinsing the anhydrous hair treatment composition from the hair or washing the hair with shampoo, the anhydrous hair treatment composition is preferably left on the hair for a period, for example, from about 30 seconds to about 30 minutes. The period can also be from about 1 minute to about 30 minutes, from about 1 minute to about 15 minutes, from about 1 minute to about 10 minutes, from about 1 minute to about 5 minutes, or from about 5 minutes to about 15 minutes.
[0125] Preferably, the anhydrous hair treatment composition is not removed by rinsing or washing the hair but is applied as a leave-in product. After distributing the anhydrous hair treatment composition on wet or damp hair, the anhydrous hair treatment composition is not removed by rinsing or washing the hair. Instead, the hair to which the anhydrous hair treatment composition has been applied is allowed to dry, or it is forcefully dried, for example with a hairdryer, and the hair is styled. Alternatively, the hair can be styled while still wet or damp, and dried later. Preferred modes of implementation
[0126] In a preferred embodiment, the anhydrous hair treatment composition includes, consists essentially of, or consists of: a. about 10 to about 95% by weight, preferably about 40 to about 65% by weight, more preferably about 50 to about 65% by weight of a plurality of vegetable oils, wherein the plurality of vegetable oils comprises:
[0127] at least 10% by weight, preferably at least 25% by weight or more, preferably about 25% to about 55% by weight, more preferably about 30% to about 50% by weight of castor oil, and even more preferably about 35% to about 45% by weight of castor oil,
[0128] of coconut oil, preferably wherein the coconut oil is in an amount of about 1 to about 40% by weight, more preferably about 5 to about 30% by weight, and even more preferably about 5 to about 15% by weight, and
[0129] optionally, one or more other vegetable oils (other than castor oil and coconut oil), preferably in an amount of about 1 to about 30% by weight, more preferably about 2 to about 20% by weight, and even more preferably about 5 to about 15% by weight; a. about 0.1 to about 10% by weight, preferably about 0.5 to about 6% by weight, more preferably about 1 to about 4% by weight of one or more cationic surfactants, wherein the one or more cationic surfactants are preferably selected from quaternary ammonium surfactants and amidoamine surfactants, wherein the one or more cationic surfactants are preferably selected from one or more amidoamine surfactants, wherein the one or more amidoamine surfactants are preferably selected from oleamidopropyl dimethylamine, linoleamidopropyl dimethylamine, isostearamidopropyl dimethylamine, oleyl hydroxyethyl imidazoline, stearamidopropyl dimethylamine, behenamidopropyl dimethylamine, behenamidopropyl diethylamine, behenamidoethyl diethylamine, behenamidoethyl dimethylamine, arachidamidopropyl dimethylamine, arachidamidopropyldiethylamine and arachidamidoethyldiethylamine, arachidamidoethyldimethylamine,more preferably in which one or more amidoamine surfactants comprise or consist of stearamidopropyl dimethylamine; b. about 0.1 to about 12% by weight, preferably about 0.5 to about 10% by weight, more preferably about 1 to about 8% by weight, and even more preferably about 3 to about 8% by weight of one or more fatty alcohols, wherein preferably the one or more fatty alcohols are selected from fatty alcohols having from 12 to 34 carbon atoms and are branched or linear and saturated or unsaturated, wherein more preferably the anhydrous hair treatment composition includes a plurality of fatty alcohols, wherein preferably the plurality of fatty alcohols includes one or more solid fatty alcohols and one or more liquid fatty alcohols, in which
[0130] one or more solid fatty alcohols are selected from stearyl alcohol, cetyl alcohol, cetearyl alcohol, myristyl alcohol, behenyl alcohol and arachidyl alcohol;
[0131] one or more liquid fatty alcohols selected from isostearyl alcohol, oleyl alcohol, octyldodecanol, linoleyl alcohol, linolenylic alcohol, lauryl alcohol, 2-hexyldecanol, 2-heptyldecanol, enanthic alcohol, caprylic alcohol, pelargonic alcohol and capric alcohol; a. optionally, about 0.01 to about 5% by weight, preferably about 0.05 to about 4% by weight, more preferably about 0.1 to about 4% by weight of one or more sensory-active agents, wherein the one or more sensory-active agents are preferably selected from essential oils, cooling agents, warming agents, terpenes and terpenoids; b. optionally, about 1 to about 55% by weight, preferably about 15 to about 50% by weight, more preferably about 20 to about 50% by weight, even more preferably about 25 to about 45% by weight of one or more emollients, wherein the one or more emollients are preferably selected from fatty ethers, fatty esters, fatty carbonates, propylene glycol esters of fatty acids and caprylic / capric triglyceride; and c. optionally, about 0.01 to about 10% by weight, preferably about 0.1 to 8% by weight, and more preferably about 1 to about 5% by weight of one or more miscellaneous ingredients, wherein the one or more miscellaneous ingredients are preferably selected from preservatives, perfumes, chelating agents, antioxidants, flavonoids, vitamins, botanical extracts, UV filtering agents, proteins, protein hydrolysates, protein isolates, fillers and compositional colorants;
[0132] in which all percentages by weight are based on a total weight of the composition.
[0133] The anhydrous hair treatment composition is preferably a homogeneous and transparent solution. Furthermore, the anhydrous hair treatment composition preferably forms a lamellar structure when brought into contact with water.
[0134] In another preferred embodiment, the anhydrous hair treatment composition comprises, consists essentially of, or consists of: a. about 10 to about 95% by weight, preferably about 40 to about 65% by weight, more preferably about 50 to about 65% by weight of a plurality of vegetable oils, wherein the plurality of vegetable oils comprises:
[0135] at least 10% by weight, preferably at least 25% by weight or more, preferably about 25% to about 55% by weight, more preferably about 30% to about 50% by weight of castor oil, and even more preferably about 35% to about 45% by weight of castor oil,
[0136] of coconut oil, preferably wherein the coconut oil is in an amount of about 1 to about 40% by weight, more preferably about 5 to about 30% by weight, and even more preferably about 5 to about 15% by weight, and
[0137] optionally, one or more other vegetable oils (other than castor oil and coconut oil), preferably in an amount of about 1 to about 30% by weight, more preferably about 2 to about 20% by weight, and even more preferably about 5 to about 15% by weight, preferably in which the other vegetable oil is soybean oil; a. about 0.1 to about 10% by weight, preferably about 0.5 to about 6% by weight, more preferably about 1 to about 4% by weight of one or more cationic surfactants, wherein the one or more cationic surfactants are preferably selected from quaternary ammonium surfactants and amidoamine surfactants, wherein the one or more cationic surfactants are preferably selected from one or more amidoamine surfactants, wherein the one or more amidoamine surfactants are preferably selected from oleamidopropyl dimethylamine, linoleamidopropyl dimethylamine, isostearamidopropyl dimethylamine, oleyl hydroxyethyl imidazoline, stearamidopropyl dimethylamine, behenamidopropyl dimethylamine, behenamidopropyl diethylamine, behenamidoethyl diethylamine, behenamidoethyl dimethylamine, arachidamidopropyl dimethylamine, arachidamidopropyldiethylamine and arachidamidoethyldiethylamine, arachidamidoethyldimethylamine,more preferentially in which the , one or more amidoamine surfactants include or consist of stearamidopropyl dimethylamine; b. about 0.1 to about 12% by weight, preferably about 0.5 to about 10% by weight, more preferably about 1 to about 8% by weight, and even more preferably about 3 to about 8% by weight of one or more fatty alcohols, wherein preferably the one or more fatty alcohols are selected from fatty alcohols having from 12 to 34 carbon atoms and are branched or linear and saturated or unsaturated, wherein more preferably the anhydrous hair treatment composition includes a plurality of fatty alcohols, wherein preferably the plurality of fatty alcohols includes one or more solid fatty alcohols and one or more liquid fatty alcohols, in which
[0138] one or more solid fatty alcohols are chosen from stearyl alcohol, cetyl alcohol, cetearyl alcohol, myristyl alcohol, behenyl alcohol and arachidyl alcohol;
[0139] one or more liquid fatty alcohols selected from isostearyl alcohol, oleyl alcohol, octyldodecanol, linoleyl alcohol, linolenylic alcohol, lauryl alcohol, 2-hexyldecanol, 2-heptyldecanol, enanthic alcohol, caprylic alcohol, pelargonic alcohol and capric alcohol; a. optionally, about 0.01 to about 5% by weight, preferably about 0.05 to about 4% by weight, more preferably about 0.1 to about 4% by weight of one or more sensory-active agents, wherein the one or more sensory-active agents are preferably selected from essential oils, cooling agents, warming agents, terpenes and terpenoids; b. about 20 to about 50% by weight, preferably about 25 to about 45% by weight, more preferably about 30 to about 45% by weight of a plurality of emollients, wherein the plurality of emollients comprises:
[0140] Optionally, about 2 to about 18% by weight, more preferably about 4 to about 16% by weight, and even more preferably about 6 to about 14% by weight of one or more fatty ethers, wherein the one or more fatty ethers are preferably selected from fatty dialkyl ethers, more preferably, wherein the one or more fatty dialkyl ethers are selected from dicaprylyl ether, didecyl ether, dimyristyl ether, distearyl ether, dilauryl ether, dihexyl ether, dioctyl ether, diethylhexyl ether, dioctyl ether and dodecyl ether, wherein dicaprylyl ether is particularly preferred;
[0141] optionally, about 2 to about 18% by weight, more preferably about 4 to about 16% by weight, and even more preferably about 6 to about 14% by weight weight of one or more fatty esters, wherein the one or more fatty esters are preferably selected from ethyl laurate, butyl laurate, hexyl laurate, isohexyl laurate, isopropyl laurate, methyl myristate, ethyl myristate, butyl myristate, isobutyl myristate, isopropyl myristate, 2-octyldodecyl myristate, 2-ethylhexyl monococoate (or octyl monococoate), ethyl palmitate, isopropyl palmitate, isobutyl palmitate, 2-ethylhexyl palmitate (or octyl palmitate), butyl stearate, isopropyl stearate, isopropyl isostearate, the isobutyl stearate, isocetyl stearate, isostearyl isostearate, isopropyl isostearate, 2-ethylhexyl stearate (or octyl stearate), 2-ethylhexyl hydroxystearate (or octyl hydroxystearate), decyl oleate, isononyl isononanoate, tridecyl neopentanoate, isocetyl neopentanoate,isostearyl neopentanoate, octyldodecyl neopentanoate, octyl neopentanoate and octyl neopentanoate, in which isopropyl isostearate is particularly preferred;
[0142] optionally, about 1 to about 18% by weight, more preferably about 2 to about 15% by weight, and even more preferably about 4 to about 10% by weight of one or more fatty carbonates, preferably wherein the one or more fatty carbonates are selected from C14-15 dialkyl carbonate, dicaprylyl carbonate, dipentyl carbonate, dimyristyle carbonate, diethylhexyl carbonate, dipropylheptyl carbonate, didodecyl carbonate, ethyldodecyl carbonate, diheptyl carbonate, didecyl carbonate or didodecyl carbonate, wherein dicaprylyl carbonate is particularly preferred; and
[0143] optionally, about 1 to about 20% by weight, preferably about 5 to about 20% by weight, more preferably about 6 to about 15% by weight, and even more preferably about 8 to about 12% by weight of caprylic / capric triglyceride; a. optionally, about 0.01 to about 10% by weight, preferably about 0.1 to 8% by weight, more preferably about 1 to about 5% by weight of one or more miscellaneous ingredients, wherein the one or more miscellaneous ingredients are preferably selected from preservatives, perfumes, chelating agents, antioxidants, flavonoids, vitamins, botanical extracts, UV filtering agents, proteins, protein hydrolysates, protein isolates, fillers or compositional colorants;
[0144] in which all percentages by weight are based on a total weight of the composition.
[0145] The anhydrous hair treatment composition is preferably a homogeneous and transparent solution. Furthermore, the anhydrous hair treatment composition preferably forms a lamellar structure when brought into contact with water.
[0146] In another preferred embodiment, the anhydrous hair treatment composition comprises, consists essentially of, or consists of: a. about 10 to about 90% by weight, preferably about 35 to about 70% by weight, more preferably about 40 to about 65% by weight, and more preferably about 50 to about 65% by weight of a plurality of vegetable oils, wherein the plurality of vegetable oils comprises:
[0147] at least 10% by weight, preferably about 15 to about 90% by weight, more preferably about 25 to about 55% by weight, even more preferably about 30 to about 50% by weight, and even more preferably about 35 to about 45% by weight of castor oil,
[0148] about 1 to about 40% by weight, more preferably about 5 to about 30% by weight, and even more preferably about 5 to about 15% by weight of coconut oil, and
[0149] optionally, one or more other vegetable oils (other than castor oil and coconut oil), preferably in an amount of about 1 to about 30% by weight, more preferably about 2 to about 20% by weight, and even more preferably about 5 to about 15% by weight, wherein one or more of the other vegetable oils are preferably selected from peanut oil, amaranth seed oil, apricot oil, argan oil, avocado oil, babassu oil, cottonseed oil, borage seed oil, camelina oil, camellia oil, safflower oil, peanut oil, pomegranate seed oil, grapefruit seed oil, hemp oil, hazelnut oil, elderberry seed oil, currant seed oil, jojoba oil, flaxseed oil, macadamia nut oil, corn oil, almond oil, Manila oil, evening primrose oil,olive oil, palm oil, palm kernel oil, Brazil nut oil, pecan oil, peach kernel oil, rapeseed oil, rosehip oil, sea buckthorn fruit oil, sea buckthorn kernel oil, sesame oil, soybean oil, sunflower oil, grapeseed oil, walnut oil, wild rose oil, or wheat germ oil, of which soybean oil is particularly preferred; a. about 0.1 to about 10% by weight, preferably about 0.5 to about 6% by weight, more preferably about 1 to about 4% by weight of one or more cationic surfactants, wherein the one or more cationic surfactants are preferably selected from quaternary ammonium surfactants and amidoamine surfactants, in wherein the one or more cationic surfactants are preferably selected from one or more amidoamine surfactants, wherein the one or more amidoamine surfactants are preferably selected from oleamidopropyl dimethylamine, linoleamidopropyl dimethylamine, isostearamidopropyl dimethylamine, oleyl hydroxyethyl imidazoline, stearamidopropyldimethylamine, behenamidopropyldimethylamine, behenamidopropyldiethylamine, behenamidoethyldiethylamine, behenamidoethyldimethylamine, arachidamidopropyldimethylamine, arachidamidopropyldiethylamine, arachidamidoethyldiethylamine or arachidamidoethyldimethylamine, more preferably wherein the one or more amidoamine surfactants comprise or consist of stearamidopropyl dimethylamine; b. about 0.1 to about 12% by weight, preferably about 0.5 to about 10% by weight, more preferably about 1 to about 8% by weight, and even more preferably about 3 to about 8% by weight of one or more fatty alcohols, wherein preferably the one or more fatty alcohols are selected from fatty alcohols having from 12 to 34 carbon atoms and are branched or linear and saturated or unsaturated, wherein more preferably the anhydrous hair treatment composition includes a plurality of fatty alcohols, wherein preferably the plurality of fatty alcohols includes one or more solid fatty alcohols and one or more liquid fatty alcohols, in which
[0150] one or more solid fatty alcohols are selected from stearyl alcohol, cetyl alcohol, cetearyl alcohol, myristyl alcohol, behenyl alcohol and arachidyl alcohol;
[0151] one or more liquid fatty alcohols selected from isostearyl alcohol, oleyl alcohol, octyldodecanol, linoleyl alcohol, linolenylic alcohol, lauryl alcohol, 2-hexyldecanol, 2-heptyldecanol, enanthic alcohol, caprylic alcohol, pelargonic alcohol and capric alcohol; a. Optionally, about 0.01 to about 5% by weight, preferably about 0.05 to about 4% by weight, more preferably about 0.1 to about 4% by weight of one or more sensory-active agents, wherein the one or more sensory-active agents are preferably selected from essential oils, cooling agents, warming agents, terpenes or terpenoids,
[0152] wherein one or more essential oils are selected from lavender oil, geranium oil, juniper berry oil, laurel oil, lemon oil, mandarin oil, orange oil, wormwood oil, bluegrass oil African, ajowan oil, anéthi oil, angelica root oil, star anise oil, wild arborvitae oil, mugwort oil, asafoetida oil, Australian lemon balm oil, basil oil, benzoin oil, Calabrian bergamot oil, betel leaf oil, birch oil, birch tar oil, blackcurrant seed oil, blood orange oil, buchu oil, cabreuva oil, cade oil, cajeput oil, calamus root oil, camphor oil, cananga oil, caraway oil, cardamom oil, carrot oil, cassia oil, leaf oil cedarwood oil, Atlas cedarwood oil, Chinese cedarwood oil, Himalayan cedarwood oil, Texas cedarwood oil, Virginia cedarwood oil, celery seed oil, German chamomile oil, Moroccan chamomile oil, Roman chamomile oil, chaulmoogra oil,goosefoot oil, chili seed oil, cinnamon bark oil, cinnamon leaf oil, citral oil, Ceylon lemongrass oil, clary sage oil, clementine oil, clove bud oil, clove leaf oil, cognac oil, copaiba oil, coriander oil, costus root oil, coffee oil, cumin oil, turmeric oil, curry oil, Australian blue cypress oil, French cypriol oil, davana oil, dill seed oil, dill oil, elemi oil, emu oil, eucalyptus oil, bitter fennel oil, oil of fenugreek, balsam fir oil, fir needle oil, organic flaxseed oil, frankincense oil, garlic oil, galbanum oil, ginger oil, palmarosa oil, gaia oil, pink grapefruit oil, white grapefruit oil, guaiac wood oil, helichrysum oil,horseradish oil, hyacinth oil, hyssop oil, jamarosa root oil, Himalayan wild oil, karanj seed oil, kanuka oil, katrafay oil, lime oil, kunzea oil, kukui oil, lantana oil, bay leaf oil, lemongrass oil, lemon eucalyptus oil, lemon myrtle oil, 5 times lemon oil, lican oil, lime oil, litsea cubeba oil, lovage leaf oil, mace oil, mandarin oil, manuka oil, marjoram oil, lemon balm leaf oil, liquid menthol oil, mullein oil, myrrh oil, myrtle oil, neem oil, neroli oil, Australian nerolina oil, niaouli oil, noni oil, nutmeg oil, oat oil, onion oil, opoponax oil, bitter orange oil, sweet orange oil, oregano oil, orange oil 5 times,palmarosa oil, parsley oil, patchouli oil, pennyroyal mint oil, pepper oil, peppermint oil, Peruvian balsam oil, petitgrain oil, chili leaf oil, long-leaf pine oil, Scots pine oil, commercial pine oil, pomegranate oil, Siam wood oil, wild ravensara oil, Australian rosalina oil, rose geranium oil, oil, rosemary oil, rosewood oil, rue oil, Dalmatian sage oil, sandalwood oil, savine oil, mountain savory oil, sea buckthorn oil, spearmint oil, spikenard oil, spruce oil, sugandh kokila oil, sumac oil, marigold oil, mandarin oil, annual tansy oil, tarragon oil, mandarin oil (5 times), tea tree oil, lemon tea oil, thyme oil, tolu balsam oil, turmeric oil, valerian root oil, vanilla oil (10 times), vetiver oil, wintergreen oil, wild verbena oil absinthe, yarrow oil and ylang-ylang oil, in which more preferably, one or more essential oils are chosen from lavender oil, peppermint oil, rosemary oil, tea tree oil, Roman chamomile oil, bergamot oil, jasmine oil,ylang-ylang oil, eucalyptus oil, geranium oil, patchouli oil, lemon oil, frankincense oil, citronella oil, cedarwood oil, or grapefruit oil, and
[0153] wherein one or more cooling agents are selected from menthol, N-ethyl-p-menthyl-3-carboxiamide, cubebol, isopulegol, 3-(L-menthoxy)propane-1,2-diol, cis / trans-p-menthane-3,8-diol, 3-(L-menthoxy)-2-methylpropane-1,2-diol, 2-[2-(p-menthan-3-yloxy)ethoxy]ethanol, menthoxyethanol, (1R,2R,4R)-l-(2-hydroxy-4-methylcyclohexyl)ethenone, (1R,2R,5R)-N-ethyl-5-methyl-2-(prop-l-en-2-yl)cyclohexanecarboxamide, N-(3-hydroxy-4-methoxyphenyl)-2-isopropyl-5,5-dimethyl-cyclohexanecarboxamide, N-[4-(cyanomethyl)phenyl]-2-isopropyl-5,5-dimethyl-cyclohexanecarboxamide, N-(2-hydroxy-2-phenylethyl)-2-isopropyl-5,5-dimethyl-cyclohexane-l-carboxamide, L-menthol lactate, (-)-menthyl ethylene glycol carbonate, (-)-menthone 1,2-glycerol ketal, D / L-menthone 1,2-glycerol ketal, (-)-menthyl 1-propylene glycol carbonate, (-)-menthyl 2-propylene glycol carbonate, D / L-menthyl 1-propylene glycol carbonate,D / L-menthyl 2-propylene glycol carbonate, (1R,2S,5R)-N-(4-methoxyphenyl)-5-methyl-2-(l-methylethyl)cyclohexanecarboxamide, menthyl ethylamido oxalate, (E)-3-benzo[l,3]dioxol-5-yl-N,N-diphenyl-2-propenamide, 3,4-methylenedioxycinnamic acid, N,N-diphenylamide, N,N-dimethyl (-)-menthyl succinimide, (1R,2S,5R)-N-(4-(carbamoylmethyl)phenyl)-menthylcarboxamide, (-)-menthylpyrrolidone carboxylate, L-phenylephrine p-menthane carboxamide, (lR,2S,5R)-N-(4-(cyanomethyl)-phenyl)menthylcarboxamide, (1R,2S,5R)-N-(2-(pyridin-2-yl)ethyl)menthylcarboxamide, 6-isopropyl-3,9-dimethyl-1,4-dioxaspiro[4.5]decan-2-one, (lR,2R,4S)-dihydroumbellulol, N-ethyl-p-menthane-3-carboxamide, 2-isopropyl-N,2,3-trimethylbutyramide, ethyl 3-(p-menthane-3-carboxamido)acetate, N-ethyl-2,2-diisopropylbutanamide, N-(l,l- , dimethyl-2-hydroxyethyl)-2,2-dimethylbutanamide, N-cyclopropyl-5-methyl-2-isopropyl-cyclohexanecarbonecarboxamide, (-)-menthyl acetoacetate, (-)-menthyl succinate, (-)-menthyl (S)-3-hydroxybutarate, (-)-menthyl glutarate, l-[2-hydroxyphenyl]-4-[2-nitrophenyl]-l,2,3,6-tetrahydropyrimidine-2-one, di-(-)-menthyl glutarate or N-(2-hydroxyethyl)-2,3-dimethyl-2-isopropylbutanamide, preferably wherein one or more of the refrigerants include menthol; a. Optionally, about 1 to about 55% by weight, preferably about 20 to about 50% by weight, more preferably about 25 to about 45% by weight, and even more preferably about 30 to about 45% by weight of a plurality of emollients, wherein the plurality of emollients comprises:
[0154] about 1 to about 20% by weight, preferably about 2 to about 18% by weight, more preferably about 4 to about 16% by weight, and even more preferably about 6 to about 14% by weight of one or more fatty ethers, wherein the one or more fatty ethers are preferably selected from fatty dialkyl ethers, more preferably, wherein the one or more fatty dialkyl ethers are selected from dicaprylyl ether, didecyl ether, dimyristyl ether, distearyl ether, dilauryl ether, dihexyl ether, dioctyl ether, diethylhexyl ether, dioctyl ether or dodecyl ether, wherein dicaprylyl ether is particularly preferred;
[0155] about 1 to about 20% by weight, preferably about 2 to about 18% by weight, more preferably about 4 to about 16% by weight, and even more preferably about 6 to about 14% by weight of one or more fatty esters, wherein the one or more fatty esters are preferably selected from ethyl laurate, butyl laurate, hexyl laurate, isohexyl laurate, isopropyl laurate, methyl myristate, ethyl myristate, butyl myristate, isobutyl myristate, isopropyl myristate, 2-octyldodecyl myristate, 2-ethylhexyl monococoate (or octyl monococoate), ethyl palmitate, isopropyl palmitate, palmitate isobutyl, 2-ethylhexyl palmitate (or octyl palmitate), butyl stearate, isopropyl stearate, isopropyl isostearate, isobutyl stearate, isocetyl stearate, isostearyl isostearate, isopropyl isostearate,2-Ethylhexyl stearate (or octyl stearate), 2-Ethylhexyl hydroxystearate (or octyl hydroxystearate), decyl oleate, isononyl isononanoate, tridecyl neopentanoate, isocetyl neopentanoate, isostearyl neopentanoate, octyldodecyl neopentanoate, and isoarachidyl neopentanoate, in which isopropyl isostearate is particularly preferred; and,
[0156] about 1 to about 18% by weight, more preferably about 2 to about 15% by weight, and even more preferably about 4 to about 10% by weight of one or more fatty carbonates, preferably wherein the one or more fatty carbonates are selected from C14-15 dialkyl carbonate, dicaprylyl carbonate, dipentyl carbonate, dimyristyle carbonate, diethylhexyl carbonate, dipropylheptyl carbonate, didodecyl carbonate, ethyldodecyl carbonate, diheptyl carbonate, didecyl carbonate or didodecyl carbonate, wherein dicaprylyl carbonate is particularly preferred;
[0157] optionally, about 1 to about 25% by weight, preferably about 5 to about 20% by weight, more preferably about 6 to about 15% by weight, and even more preferably about 8 to about 12% by weight of caprylic / capric triglyceride; and a. optionally, about 0.01 to about 10% by weight, preferably about 0.1 to 8% by weight, more preferably about 1 to about 5% by weight of one or more miscellaneous ingredients, wherein the one or more miscellaneous ingredients are preferably selected from preservatives, perfumes, chelating agents, antioxidants, flavonoids, vitamins, botanical extracts, UV filtering agents, proteins, protein hydrolysates, protein isolates, fillers or compositional colorants;
[0158] in which all percentages by weight are based on a total weight of the composition.
[0159] The anhydrous hair treatment composition is preferably a homogeneous and transparent solution. Furthermore, the anhydrous hair treatment composition preferably forms a lamellar structure when brought into contact with water. Preferred exclusions
[0160] The anhydrous hair treatment composition does not require silicones, including amino-functionalized silicones. Therefore, in a preferred embodiment, the anhydrous hair treatment composition is free or essentially free of silicones, including amino-functionalized silicones.
[0161] The anhydrous hair treatment composition does not require cationic polymers. Therefore, in a preferred embodiment, the anhydrous hair treatment composition is free or essentially free of cationic polymers. In other embodiments, however, it may be useful to include one or more cationic polymers.
[0162] The anhydrous hair treatment composition is preferably free or substantially free of anionic surfactants, non-ionic surfactants (other than fatty alcohols) and / or amphoteric surfactants. In one embodiment, the anhydrous hair treatment composition is free or substantially free of anionic surfactants. In another embodiment, the anhydrous hair treatment composition is free or essentially free of nonionic surfactants (other than fatty alcohols). In various embodiments, the anhydrous hair treatment composition is free or essentially free of amphoteric surfactants. EXAMPLES
[0163] Various changes can be made to the above compositions and processes without departing from the scope of the invention. Accordingly, it is intended that all disclosure in the above description and in the examples given below is illustrative and not limiting. Example 1 Inventive compositions
[0164] [Tables 1] AB (a) Vegetable oil CASTOR OIL 33.8 32 SOYBEAN OIL 11.7 COCONUT OIL 9 10 SUNFLOWER SEED OIL 20 Total (a) 54.5 62 (b) Cationic surfactant STEARAMIDOPROPYL DIMETHYLAMINE 1.2 1.2 Total (b) 1.2 1.2 (c) Fatty alcohols Solids CETEARYL ALCOHOL 3 3 MYRISTYL ALCOHOL 2.1 1.8 CETYL ALCOHOL 0.06 Liquids OLEYL ALCOHOL 1 1 ISOSTEARYL ALCOHOL 1 LAURYL ALCOHOL 0.7 Ratio of solid fatty acids to liquid fatty acids 1.9:1 4.8:1 Total (c) 7.8 5.8 Ratio (b):(c) 1:6.5 1:4,8 (d) Sensory active agents Scented oils ROSEMARY LEAF OIL, LAVENDER OIL AND PEPPERMINT OIL 0.8 Terpenoid MENTHOL 1.1 (e) Emollients Triglyceride CAPRYLIC / CAPRIC TRIGLYCERIDE 9 Fatty ester ISOPROPYL ISOSTEARATE 9 Fatty carbonate DICAPRYLYL ETHER CARBONATE 6.7 15 Fatty ether DICAPRYLYL ETHER 9 15 (f) Miscellaneous* < 5 <5
[0165] * Preservatives (tocopherol), perfumes, composition colorants, UV filters, etc. Example 2 Comparative composition
[0166] Inventive Composition A of Example 1 was compared to a popular commercial reference product (Trade Reference No. 1), known for its excellent conditioning, smoothing, and anti-frizz properties. Trade Reference No. 1, like Inventive Composition A, is an oil-based product. However, it lacks cationic surfactants and fatty alcohols. The ingredients of the product Trade Reference No. 1 are listed below.
[0167] Glycine soybean oil, Ricinus communis (castor) seed oil, Rosmarinus Officinalis (rosemary) leaf oil, Simmondsia Chinensis (jojoba) seed oil, Mentha Piperita (peppermint) oil, Eucalyptus Globulus (eucalyptus) leaf oil, menthol, Melaleuca Altemifolia (tea tree) leaf oil, Cocos nucifera (coconut) oil, Equisetum Arvense (horsetail) extract, Aloe Barbadensis leaf extract, Lavandula Angustifolia (lavender) oil, Triticum Vulgare (wheat) germ oil, Carthamus Tinctorius (safflower) seed oil, Oenothera Biennis (evening primrose) oil, Vitis Vinifera (grape) seed oil, benzyl nicotinate, Prunus oil Amygdalus Dulcis (sweet almond), Oryza Sativa (rice) bran oil, tocopheryl acetate, biotin, Arctium Lappa (burdock) root extract, glycerin, Apium Graveolens (celery) seed extract, retinyl palmitate, cholecalciferol (vitamin D),Ascorbic acid, Ocimum, Basilicum (basil) oil, Pogostemon Cablin (pachouli) oil, Salicinalis Officinalis (sage) oil, silica, Urtica Dioica (nettle) extract.
[0168] After shampooing a volunteer's hair, excess water was squeezed out and the hair was towel-dried. While still damp, equal amounts of Inventive Composition A and Commercial Reference No. 1 were applied to opposite sides of the volunteer's hair. Both compositions were distributed evenly throughout the hair from roots to tips. An expert evaluator then assessed the attributes of the treated hair. Without rinsing the hair composition, the hair was dried with a hairdryer. After the hair was completely dry, the same expert re-evaluated the attributes of the treated hair. The results are presented in the table below.
[0169] [Tables2] Inventive A Reference No. 1 Wet Attributes: Significantly easier to distribute More volume Significantly more curl definition and evenness Less frizz Significantly smoother More frizzy ends More curl elongation Dry feel Dry Attributes: More curl definition and evenness More coated More frizz control Drier and frizzier Significantly smoother No sealed ends Better glide Significantly more shine Better sealed ends Rougher texture Sharper transformation Example 3 Comparative composition
[0170] Inventive Composition B of Example 1 was compared to a popular commercial reference product (Commercial Reference No. 2), known for its excellent conditioning, smoothing, and anti-frizz properties. Commercial Reference No. 2, like Inventive Composition A, is an oil-based product. However, it lacks cationic surfactants and fatty alcohols. The ingredients of Commercial Reference No. 2 are listed below.
[0171] Refined sunflower oil, refined olive oil, virgin jojoba oil, refined coconut oil, alpha-tocopherol concentrate (vitamin E), castor oil, black cumin oil, polymerized linseed oil and perfume.
[0172] After shampooing a volunteer's hair, excess water was squeezed out and the hair was towel-dried. While still damp, equal amounts of Inventive Composition A and Commercial Reference No. 2 were applied to opposite sides of the volunteer's hair. Both compositions were distributed evenly throughout the hair from roots to tips. An expert evaluator then assessed the attributes of the treated hair. Without rinsing the hair composition, the hair was dried using a hairdryer. After the hair was completely dry, the same expert re-evaluated the attributes of the treated hair. The results are presented in the table below.
[0173] [Tables3] Inventive A Reference No. 2 Wet Attributes Significantly easier to distribute More localized Significantly more curl definition and consistency Less frizz Significantly smoother Uneven curls Uniform volume Dry feel Dry Attributes Smoother Dry feel and appearance Uniform shape More frizz Shinier Good end coating More sealed ends Feels warmer during the first blow-dry Softer
[0174] The preceding disclosure illustrates and describes embodiments of the invention. The disclosure shows and describes only preferred embodiments, but it is understood that the invention is usable in various other combinations, modifications, and environments, and that it may undergo changes or modifications in the scope of the inventive concepts as expressed herein, depending on the teachings above and / or the skills or knowledge of the relevant art. The embodiments described herein are further intended to explain the best known embodiments of the applicant and to enable others skilled in the art to use the disclosure. Accordingly, the description is not intended to limit the invention.
[0175] As used herein, the terms "comprising," "having," and "including" (or "comprise," "have," and "include") are used in their broad, non-limiting sense. The phrase "consisting essentially of" limits the scope of a claim to the materials or steps specified and to those which do not materially affect the basic and innovative features of the claimed invention.
[0176] The terms "a", "an", "the" and "the" are understood to encompass both the plural and the singular.
[0177] Thus, the expression "one of their mixtures" or "one of their combinations" also refers to "their mixtures" or "their combinations." Throughout the disclosure, the expression "one of their combinations" may be used following a list of elements, as shown in the following example where the letters A through F represent the elements: "one or more elements selected from the group consisting of A, B, C, D, E, F, and one of their combinations." The expression "one of their combinations" does not require that the combination include all of the elements A, B, C, D, E, and F (although all of the elements A, B, C, D, E, and F may be included). Rather, it indicates that a combination of any two or more of the elements A, B, C, D, E, and F may be included. In other words, it is equivalent to the expression "one or more elements chosen from the group consisting of A, B, C, D, E, F, and a combination of any two of A, B, C, D, E and F or more".
[0178] Similarly, the expression "one of its (their) salts" also refers to "its (their) salts." Thus, when the disclosure refers to "an element chosen from the group consisting of A, B, C, D, E, F, one of their salts, and one of their combinations," it indicates that one or more of A, B, C, D, and F may be included, that one or more of a salt of A, a salt of B, a salt of C, a salt of D, a salt of E, and a salt of F may be included, or that a mixture of any two of A, B, C, D, E, F, a salt of A, a salt of B, a salt of C, a salt of D, a salt of E, and a salt of F may be included.
[0179] The term "anhydrous" as used herein refers to a substantial absence of water. An "anhydrous" composition, including the anhydrous hair treatment composition of this disclosure, comprises less than 5% by weight of water, preferably less than 3% by weight of water, more preferably less than 2% by weight of water. The anhydrous hair treatment composition may comprise less than 1% by weight of water, less than 0.5% by weight of water, or less than 0.1% by weight of water.
[0180] The surfactants referred to throughout the disclosure may include those having a counterion such as bromide, chloride, fluoride, hydroxide, nitrate, acetate, benzoate, or sulfate. This list of counterions, however, is not exhaustive.
[0181] The expression "one or more" means "at least one" and therefore includes individual components as well as mixtures / combinations.
[0182] The term “plurality” means “more than one” or “two or more”.
[0183] Except in operational examples, or unless otherwise indicated, all numbers expressing quantities of ingredients and / or reaction conditions may in all cases be modified by the term "approximately", meaning to within + / - 10% of the stated number. For example, a quantity of "approximately 1 by weight" may include a quantity as low as 0.90% by weight or as high as 1.1. Similarly, a quantity of "approximately 50" may include a quantity as low as 45% by weight and as high as 55% by weight.
[0184] Some of the various categories of ingredients identified for the anhydrous hair treatment composition may have dual function. In cases where dual function may exist and the anhydrous hair treatment composition includes two (or more than two) dual components, a dual component shall not represent more than one claimed component. For example, menthol may be interpreted as both a "cooling agent" and a "terpene." If a claimed anhydrous hair treatment composition includes both a cooling agent and a terpene, the menthol in the anhydrous hair treatment composition shall serve only as a cooling agent or only as a terpene. Menthol may not simultaneously serve as both a cooling agent and a terpene.
[0185] All percentages, parts and ratios herein are based on the total weight of the compositions of the present invention, unless otherwise stated.
[0186] All ranges and values disclosed herein are inclusive and combinable. For example, any value or point described herein that falls within a range described herein can serve as a minimum or maximum value for deducing a subrange, and so on. Furthermore, all ranges provided are intended to include each specific range within the given ranges, and a combination of intermediate subranges within the given ranges. Thus, a range of 1 to 5 specifically includes 1, 2, 3, 4, and 5, as well as subranges such as 2 to 5, 3 to 5, 2 to 3, 2 to 4, 1 to 4, and so on.
[0187] A "rinse-off" product refers to a composition that is removed by rinsing and / or washing the hair with water after or during the application of the composition to the hair, and before drying and / or styling the hair. At least a portion of the composition is removed from the hair during rinsing and / or washing.
[0188] A "leave-in" product refers to a composition that is not removed by rinsing and / or washing the hair after or during the application of the composition to the hair. The composition remains on the hair during drying and / or throughout styling.
[0189] All components presented positively in this disclosure may be excluded negatively from the claims and the compositions and processes described throughout the disclosure. In other words, the cleaning compositions of the present disclosure may be free or substantially free of one or more of the components presented positively in this disclosure for possible inclusion in cleaning compositions.
[0190] The expression "substantially free" or "essentially free" as used herein means that the specific material may be present in small quantities that do not materially affect the basic and innovative features of the claimed invention. For example, less than 1% by weight of a specific material may be added to a composition, relative to the total weight of the composition (provided that an amount of 1% by weight or less does not materially affect the basic and innovative features of the claimed invention). Similarly, where a composition is essentially free of a particular element, the composition may include 1% by weight or less, 0.5% by weight or less, 0.1% by weight or less, 0.05% by weight or less, or 0.01% by weight or less, or no amount of the specified material.For example, if a composition is "substantially free" or "essentially free" of ethanol, the composition may optionally include ethanol in an amount of up to 1% by weight, relative to the total weight of the composition, provided that 1% by weight does not materially affect the basic and innovative characteristics of the composition. In addition, the composition may optionally include 0.5% by weight or less, 0.1% by weight or less, 0.05% by weight or less, 0.01% by weight or less, or no ethanol at all.
Claims
Demands
1. An anhydrous hair treatment composition comprising: (a) about 10 to about 95% by weight of one or more vegetable oils, wherein one or more of the vegetable oils is castor oil, in an amount of at least 10% by weight; (b) about 0.1 to about 10% by weight of one or more cationic surfactants; (c) about 0.1 to about 10% by weight of one or more fatty alcohols; and (d) optionally, about 0.1 to about 5% by weight of one or more sensory-active agents; wherein the composition is substantially free from monoalcohols having 1 to 6 carbon atoms, polyhydric alcohols having 1 to 6 carbon atoms, and alpha-hydroxy acid esters; and all percentages by weight are based on the total weight of the composition.
2. An anhydrous hair treatment composition according to claim 1, wherein the composition forms a lamellar structure when brought into contact with water.
3. An anhydrous hair treatment composition according to claim 1 or 2, wherein the composition further comprises, in addition to castor oil, one or more vegetable oils selected from coconut oil, peanut oil, amaranth seed oil, apricot oil, argan oil, avocado oil, babassu oil, cottonseed oil, borage seed oil, camelina oil, camellia oil, safflower oil, peanut oil, pomegranate seed oil, grapefruit seed oil, hemp oil, hazelnut oil, elderberry seed oil, gooseberry seed oil, jojoba oil, linseed oil, macadamia nut oil, corn oil, almond oil, Manila oil, evening primrose oil, olive oil, palm oil, palm kernel oil, Brazil nut oil, pecan nut oil, peach kernel oil, rapeseed oil, rosehip oil,Sea buckthorn fruit oil, sea buckthorn kernel oil, sesame oil, soybean oil, sunflower oil, grapeseed oil, walnut oil, wild rose oil, or wheat germ oil.
4. Anhydrous hair treatment composition according to any one of claims 1 to 3, wherein one or more of the vegetable oils is coconut oil.
5. Anhydrous hair treatment composition according to any one of claims 1 to 4, wherein (b) and (c) are in a weight ratio of about 1:12 to about 2:1 ((b):(c)).
6. Anhydrous hair treatment composition according to any one of claims 1 to 5, wherein one or more cationic surfactants are selected from quaternary ammonium surfactants and amidoamine surfactants.
7. Anhydrous hair treatment composition according to any one of claims 1 to 6, wherein one or more cationic surfactants are selected from oleamidopropyl dimethylamine, linoleamidopropyl dimethylamine, isostearamidopropyl dimethylamine, oleyl hydroxyethyl imidazoline, stearamidopropyldimethylamine, behenamidopropyldimethylamine, behenamidopropyldiethylamine, behenamidoethyldiethylamine, behenamidoethyldimethylamine, arachidamidopropyldimethylamine, arachidamidopropyldiethylamine, arachidamidoethyldiethylamine or arachidamidoethyldimethylamine.
8. Anhydrous hair treatment composition according to any one of claims 1 to 7, wherein one or more fatty alcohols are selected from fatty alcohols having 12 to 34 carbon atoms and are branched or linear, and saturated or unsaturated.
9. Anhydrous hair treatment composition according to any one of claims 1 to 8, wherein the composition further comprises one or more emollients selected from fatty ethers, fatty esters, fatty carbonates, propylene glycol esters of fatty acids and caprylic / capric triglyceride.
10. A hair treatment method comprising applying to the hair the anhydrous hair treatment composition of any one of claims 1 to 9.