METHOD FOR SUPPLYING KERATINOUS MATERIALS WITH A PRINTED INK DEPOSIT HAVING IMPROVED WATER RESISTANCE

Abstract

METHOD FOR SUPPLYING KERATINOUS MATERIALS WITH A PRINTED INK DEPOSIT HAVING IMPROVED WATER RESISTANCE The present invention relates to a method comprising the steps of: (i) optionally applying a makeup base composition to a keratinous material to provide a makeup base layer on the keratinous material; (ii) applying an ink composition to the makeup base layer if step (i) is performed, or to a keratinous material if step (i) is not performed, to provide an ink pattern, preferably to print an ink pattern on the makeup base layer or the keratinous material; and (iii) applying an anhydrous composition to the ink pattern, preferably to the printed ink pattern to provide a coating layer on the ink pattern, wherein the anhydrous composition comprises at least one oil-soluble film-forming agent.The method according to the present invention can produce a design with improved water resistance. Figure for the abstract: none.

Description

Title of the invention: METHOD FOR SUPPLYING KERATINOUS MATERIALS WITH A PRINTED INK DEPOSIT HAVING IMPROVED WATER RESISTANCE technical field

[0001] The present invention relates to a method for providing a keratinous material with a printed ink deposit having improved water resistance. The present invention also relates to a composition for improving the water resistance of an ink deposit printed on a keratinous material. CONTEXT OF THE INVENTION

[0002] Traditional tattooing is a process of infiltrating pigment into the dermal layer of the skin, and the initial treatment cost is also high, but it is not easy to remove because it is permanent once treated.

[0003] Recently, after the traditional tattooing procedure, henna tattoos (a process of drawing on the body using ink), water transfer stickers (a form of attaching transfer paper to the body using water) and other body paintings using ink have been proposed using various processes, such as a process of stamping a design.

[0004] Among temporary body painting processes, a skin printing process with a two-liquid skin printing ink is reported in KR101655978 B1 and KR20180057953 A.

[0005] However, there remains a need to improve the water resistance of temporary ink deposits printed on the skin. DISCLOSURE OF THE INVENTION

[0006] An objective of the present invention is to propose a new method of supplying a keratinous material with temporary printed ink deposits having improved water resistance.

[0007] The above objective of the present invention can be achieved by a new method comprising the steps of: i. optional application of a makeup base composition onto keratinous material to provide a makeup base layer on the keratinous material; ii. application of an ink composition to the makeup base layer if step (i) is performed, or to a keratinous material if step (i) is not performed, to provide an ink pattern, preferably to imprint an ink pattern onto the makeup base layer or the keratinous material; and iii. application of an anhydrous composition to the ink pattern, preferably to the printed ink pattern, to provide a coating layer on the ink pattern,

[0008] wherein the anhydrous composition comprises at least one oil-soluble film-forming agent.

[0009] The oil-soluble film-forming agent may comprise at least one silicone resin.

[0010] The silicone resin can be chosen from silsesquioxane, siloxysilicate and mixtures thereof.

[0011] The anhydrous composition may further comprise at least one oil.

[0012] The oil may comprise at least one hydrocarbon oil and / or at least one silicone oil

[0013] The oil can be volatile or non-volatile.

[0014] The oil may be present in the anhydrous composition in an amount of 10% to 70% by weight, preferably 15% to 65% by weight, and more preferably 20% to 60% by weight, relative to the total weight of the composition.

[0015] The oil-soluble film-forming agent may be present in the anhydrous composition in an amount of 1% to 30% by weight, preferably 5% to 25% by weight, and more preferably 10% to 20% by weight, relative to the total weight of the composition.

[0016] The ink composition may include at least one solvent and at least one dye.

[0017] The basic makeup composition may include at least one water-soluble polymer.

[0018] The method according to the present invention can be a method for printing a temporary tattoo on keratinous material.

[0019] The anhydrous composition may further comprise at least one silicone gum.

[0020] The anhydrous composition may further comprise at least one filler and / or one lipophilic gelling agent.

[0021] The present invention also relates to an anhydrous composition comprising at least one oil-soluble film-forming agent, for use in providing an ink pattern applied to a keratinous material with improved water resistance.

[0022] The present invention also relates to a use of the anhydrous composition according to the present invention for the formation of an ink pattern on a keratinous material with improved water resistance. DETAILED DESCRIPTION OF THE INVENTION

[0023] After diligent research, the inventors discovered that at least one oil-soluble film-forming agent can provide an ink deposit of a keratinous material with improved water resistance, and thus finalized the invention.

[0024] Thus, the process according to the present invention is a process comprising the steps of: i. optional application of a makeup base composition onto keratinous material to provide a makeup base layer on the keratinous material; ii. application of an ink composition to the makeup base layer if step (i) is performed, or to a keratinous material if step (i) is not performed, to provide an ink pattern, preferably to imprint an ink pattern onto the makeup base layer or the keratinous material; and iii. Application of an anhydrous composition to the ink pattern, preferably to the printed ink pattern. Thus, the process according to the present invention can constitute a pattern applied by the ink composition, preferably a pattern printed by the ink composition onto keratinous materials with improved water resistance.

[0025] Keratinous material herein refers to a material containing keratin as its principal constituent, and examples thereof include skin, scalp, nails, lips, hair, eyebrows, eyelashes, and the like. Preferably, keratinous material herein refers to skin, hair, eyebrows, and eyelashes. Thus, in a preferred embodiment, the process according to the present invention is a cosmetic process for supplying the skin with a printed ink having improved water resistance.

[0026] In one embodiment, the ink deposit is a temporary tattoo. Thus, the method according to the present invention can be a method for imprinting a temporary tattoo onto keratinous material. The term "temporary" here indicates that the tattoo is not permanent and can be removed, for example, by rubbing it with soapy water. This temporary tattoo imprinted by the method according to the present invention exhibits improved water resistance. Thus, it can be said that the temporary tattoo provided by the present invention can have a longer lifespan.

[0027] In a preferred embodiment, the keratinous materials include areas on which the temporary tattoo is intended to be applied, preferably to be imprinted, such as the face, body, eyebrow area, and the like. Thus, the keratinous materials can be the skin of the face, the skin of the body, and the skin and eyebrow in the eyebrow area.

[0028] The process and composition according to the present invention will be explained in more detail below. [Process]

[0029] The method according to the present invention comprises the steps of: i. optional application of a makeup base composition onto keratinous material to provide a base layer of makeup on the keratinous material; and ii. application of an ink composition to the makeup base layer if step (i) is performed, or to a keratinous material if step (i) is not performed, to provide an ink pattern, preferably to imprint an ink pattern onto the makeup base layer or the keratinous material; and iii. application of an anhydrous composition to the ink pattern, preferably to the printed ink pattern to provide a coating layer on the ink pattern.

[0030] The process according to the present invention aims to provide keratinous material, such as skin, hair, eyebrows and eyelashes, with a pattern applied by the ink composition, preferably a pattern printed by the ink composition having improved water resistance.

[0031] For the purposes of the present invention, the expression "ink pattern" is here intended to designate a drawing prepared by an ink composition. {Step (i)}

[0032] The process according to the present invention includes an optional step (i) for applying a makeup base composition to a keratinous material to provide a makeup base layer on the keratinous material.

[0033] The makeup base layer can provide the ink deposits temporarily printed by the present invention with improved resistance to streaks and abrasion.

[0034] The basic makeup composition may be in the form of aqueous compositions, loose powder, compact powder, anhydrous compositions, alcoholic compositions, semi-solid compositions, jelly or film.

[0035] The application of the makeup base composition can be carried out by any means, for example, an inkjet process, a spraying process, a drip process, or by bringing the makeup base composition into contact with the keratinous material using a finger, gauze, cotton, a sponge, a powder puff, and / or a cosmetic applicator such as a flocked applicator, an elastomeric applicator, a fiber applicator, and a comb applicator. In one embodiment of the present invention, the application of the makeup base composition can be carried out by putting in contact the base makeup composition with the keratinous material using fingers, gauze, cotton, sponge, powder puff and / or a cosmetic applicator such as a flocked applicator, an elastomeric applicator, a fiber applicator and a comb applicator.

[0036] The makeup base composition can be dried after application to form the makeup base layer. Drying can be carried out under ambient conditions for 0.1 to 120 seconds, preferably for 1 to 60 seconds. Drying can be achieved by heating the applied ink composition, or simply by maintaining the applied makeup base composition at ambient conditions. The heating temperature can range from 10°C to 110°C. The ambient conditions can be at a temperature ranging from 10°C to 40°C, particularly from 15°C to 30°C, and at atmospheric pressure (105 Pa).

[0037] The basic makeup composition may include at least one water-soluble polymer.

[0038] The water-soluble polymer included in the makeup base composition may be selected from a carboxyvinyl polymer, carboxymethylcellulose, methylcellulose, ethylcellulose, hydroxyalkylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, alkyl cellulose, polyurethane, polyurethane-acrylate copolymer, polyester urethane, polyvinylpyrrolidone, polyvinyl acetate, vinylpyrrolidone-vinyl acetate copolymer, polyvinyl alcohol, polyacrylic acid, sodium polyacrylate, acrylate polymer, acrylate copolymer, such as Polyacrylate Crosspolymer-6, partially hydrogenated polyacrylic acid, polyacrylic acid starch, sodium carmellose, carboxyvinyl polymer, N-vinylacetate amide, alkylolefinic acid, alkylolefinic acid ester copolymer, amide / acid olefinic, the amide / olefinic acid copolymer,Native gums, such as xanthan gum, and mixtures thereof.

[0039] The makeup base composition may comprise 0.1 to 30 parts by weight, preferably 1 to 15 parts by weight, of the water-soluble polymer on the basis of 100 parts by weight of the solvent in the makeup base composition.

[0040] The basic makeup composition of the present invention can be prepared by mixing the ingredients as explained above. In one embodiment of the present invention, the basic makeup composition can be prepared by stirring the solvent(s) and the water-soluble polymer(s) at 300 to 1000 rpm, preferably 400 to 600 rpm, for 20 to 40 minutes. {Step (ii)}

[0041] Step (ü) consists of applying an ink composition to the makeup base layer if step (i) is carried out, or to the keratinous material if step (i) is not carried out, to provide an ink pattern, preferably to print an ink pattern on the makeup base layer or the keratinous material.

[0042] The application of the ink composition can be carried out by any means, for example, an inkjet process, a spray process, a drip process, or by bringing the ink composition into contact with the keratinous material using a finger, stick, tip, applicator, gauze, or cotton. When the base makeup composition in powder form is used in step (i), then the application of the ink composition is preferably carried out using a powder puff, brush, or sponge.

[0043] Preferably, the application of the ink composition is carried out by an inkjet process, for example using a skin transfer printing system, such as Prinker M manufactured by Prinker.

[0044] According to one embodiment of the present invention, the ink composition is applied to all or part of the makeup base layer prepared in step (i).

[0045] The ink composition can be dried after application to form the ink layer. Drying can be carried out under ambient conditions for 0.1 to 120 seconds, preferably for 1 to 60 seconds. Drying can be achieved by heating the applied ink composition, by fanning it to dry, or simply by maintaining the applied ink composition at ambient conditions. The heating temperature can range from 10 °C to 110 °C. The ambient conditions can be at a temperature ranging from 10 °C to 40 °C, particularly from 15 °C to 30 °C, and at atmospheric pressure (10⁵ Pa).

[0046] The ink composition includes at least one dye.

[0047] The colorant used in the present invention can be chosen from dyes and pigments.

[0048] The pigments here can be white or colored particles, and mineral and / or organic. The pigments can be of any shape: platelet, spherical or oblong, regardless of the crystallographic form (for example, lamellar, cubic, hexagonal, orthorhombic, etc.)

[0049] Among the mineral pigments that may be cited are titanium dioxide, such as rutile type titanium dioxide pigment, optionally surface treated, zirconium oxide or cerium oxide, as well as zinc oxide, iron oxide (black, yellow, gold or red) or chromium oxide, manganese violet, ultramarine blue, chromium hydrate and ferric blue, and metallic powders, for example aluminum powder and copper powder.

[0050] Organic pigments may be chosen from the materials below, and their mixtures:

[0051] - carbon black,

[0052] - organic pigments of azo dyes, anthraquinone dyes, dyes indigoids, xanthene dyes, pyrene dyes, quinoline dyes, triphenylmethane dyes and fluorane dyes.

[0053] The dyes can be chosen from among water-soluble acid dyes.

[0054] For the purposes of the present invention, acid dye can also be represented as acid direct dye. For the purposes of the present invention, acid dye can also be represented as anionic dye. Thus, acid dye can also be represented as "anionic dye," "acid direct dye," and / or "anionic direct dye." A direct dye is a colored substance that does not require the use of an oxidizing agent to reveal its color.

[0055] The water-soluble acid dye can be natural and / or synthetic dyes.

[0056] The expression "natural direct dye" means any dye or dye precursor of natural origin, produced by extraction (and optionally by purification) from a plant matrix or an animal such as an insect, optionally in the presence of natural compounds such as ash or ammonia.

[0057] Natural direct dyes are not limited as long as they are acid direct dyes. Examples of natural direct dyes include quinone tinctures (such as lawsone and juglone), alizarin, purpurin, laccaic acid, carminic acid, kermesic acid, purpurogallin, protocatechaldehyde, indigoids such as indigo, sorghum, isatin, betanin, curcuminoids (such as curcumin), spinulosin, various types of chlorophyll and chlorophyllin, hematoxylin, hematein, brazilein, brazilin, safflower tinctures (such as carthamine), flavonoids (such as rutin, quercetin, catechin, epicatechin, morin, apigenidin, and sandalwood), and anthocyanins (such as apigeninidin and apigenin), carotenoids, tannins, orceins, sandalins and cochineal carmine.

[0058] The expression "synthetic direct dye" means any dye or dye precursor produced by chemical synthesis.

[0059] Synthetic direct dyes are not limited as long as they are acidic direct dyes. Examples of synthetic dyes include azo, methicillin, carbonyl, nitro(hetero)aryl, or tri(hetero)arylmethane direct dyes, alone or in mixtures.

[0060] The ink composition may comprise at least one solvent and at least one colorant

[0061] The solvent included in the ink composition is not particularly limited as long as it is a solvent commonly used in cosmetics, and preferably includes water and at least one organic solvent.

[0062] The organic solvent is not limited as long as it is an organic solvent commonly used in cosmetics, and is preferably chosen from ethyl alcohol, n-propyl alcohol, isopropyl alcohol, n-butyl alcohol, sec-butyl alcohol, isobutyl alcohol, ethyl lactate, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, butylene glycol, 1,4-butanediol, pentanediol, 1,6-hexanediol, 1,2-hexanediol, 1,2,6-hexanetriol, hexylene glycol, glycerol, glycerol ethoxylate, trimethylolpropane ethoxylate, sodium 2-methylpyrrolidone, caprylyl pyrrolidone, ethiol, diethylene glycol methyl ether, diethylene glycol ethyl ether, triethylene glycol monomethyl ether, triethylene glycol dimethyl ether, dimethyl sulfoxide, tetramethylene sulfone, thioglycol and polyethylene glycol having a weight average molecular weight of 150 to 1000, and more preferably at least one selected from diethylene glycol, glycerol,polyethylene glycol, isopropyl alcohol and butylene glycol, and more preferably at least one selected from the group consisting of glycerol, isopropyl alcohol and polyethylene glycol.

[0063] The colouring agent can be used without limitation as long as it is a component commonly used in cosmetics, and may preferably include pigments and dyes.

[0064] The ink composition may contain 0.01 to 20 parts by weight, preferably 0.1 to 15 parts by weight, of the colorant(s) on the basis of 100 parts by weight of the composition.

[0065] The ink composition of the present invention can be prepared by mixing the ingredients as explained above. In one embodiment of the present invention, the ink composition can be prepared by stirring the solvent(s), dye(s) and surfactant(s) at 100 to 500 rpm, preferably 200 to 400 rpm, for 20 to 40 minutes, preferably 25 to 35 minutes, and then filtering the mixture through a filter with a pore size of 0.1 to 0.6 µm, preferably 0.35 to 0.55 µm, to prepare the ink composition. {Step (iii)}

[0066] Step (iii) consists of applying an anhydrous composition to the pattern applied by the ink composition, preferably the pattern printed by the ink composition in step (ii), to provide a coating layer on the printed pattern.

[0067] The application of the anhydrous composition can be carried out by any means, for example an inkjet process, a spraying process, a drip process, or by bringing the ink composition into contact with the material keratinous using a finger, gauze, cotton, sponge, powder puff, cosmetic applicator such as a flocked applicator, elastomeric applicator, fiber applicator and comb applicator.

[0068] According to one embodiment of the present invention, the anhydrous composition is applied to the whole of the applied pattern, preferably printed, or to a larger part than the applied pattern, preferably printed.

[0069] The anhydrous composition can be dried after application to form the coating layer. Drying can be carried out under ambient conditions for 0.1 to 120 seconds, preferably for 1 to 60 seconds. Drying can be achieved by heating the applied anhydrous composition, or simply by maintaining the applied anhydrous composition at ambient conditions. The heating temperature can range from 10 °C to 110 °C. The ambient conditions can be at a temperature ranging from 10 °C to 40 °C, in particular from 15 °C to 30 °C and under atmospheric pressure (10⁵ Pa). In one embodiment of the present invention, there is no drying step after step (iii).

[0070] The anhydrous composition comprises at least one oil-soluble film-forming agent. (Oil-soluble film-forming agent)

[0071] The anhydrous composition comprises at least one oil-soluble film-forming agent. Only one type of oil-soluble film-forming agent may be used, but two or more different types of oil-soluble film-forming agents may be used in combination.

[0072] The expression "soluble in oil" here refers to a substance that is soluble in an oil, such as isododecane, at a concentration of at least 1% by weight, for example at least 5% by weight or 10% by weight, relative to the total weight of the oils at room temperature (25°C) and atmospheric pressure (105 Pa).

[0073] The term “film-forming” refers to a substance capable of forming, alone or in the presence of an auxiliary film-forming agent, a macroscopically continuous film that adheres to a support, the film being able to exhibit a property of water resistance.

[0074] The oil-soluble film-forming agent may be an oil-soluble film-forming polymer. For the purposes of the present invention, the term "polymer" means a compound consisting of the repetition of one or more units (these units being derived from compounds called monomers). This unit or these units are repeated at least twice and, preferably, at least three times.

[0075] The oil-soluble film-forming agent may be hydrophobic, and may thus improve or enhance the durability of the anhydrous composition with respect to water.

[0076] For the present invention, the oil-soluble film-forming agent is preferably chosen from silicone resins. - Silicone resin

[0077] Examples of silicone resins include silsesquioxane, siloxysilicate, and resins obtained by hydrosilylation. In particular, the silicone resin is selected from silsesquioxane, siloxysilicate, and mixtures thereof.

[0078] The nomenclature for silicone resin is known in the art as the "MDTQ" nomenclature, by which a silicone resin is described according to the different fractions of repeating siloxane monomers that constitute the polymer. Each letter of "MDTQ" corresponds to a different type of fraction.

[0079] The symbol "M" corresponds to the monofunctional fraction R-SiO₂. This fraction is considered monofunctional because the silicon atom shares only one oxygen atom for chain formation. The group R₁ indicates a hydrocarbon group, preferably an alkyl or aryl group, and more preferably a C₁-C₂O alkyl group, in particular a C₁-C₄ alkyl group, such as a methyl, ethyl, propyl, or butyl group. The fraction "M" can be represented by the following structure: h9c x 3 CH3

[0080] At least one of the methyl groups can be replaced so as, for example, to produce a fraction of the following formula: [R(CH3)2]SiOi / 2, as represented by the following structure: H3C x S^—Oj / 2 ch3

[0081]

[0082] where R is other than a methyl group. The symbol "D" corresponds to the difunctional fraction R'2-SiO2 / 2, in which two of the available bonds on the silicon atom are used to bind to oxygen for the formation of the polymer chain. The group R1 indicates the same thing as explained above. The "D" fraction, which is the essential component of dimethicone oils, can be represented by the following formula: Si—Oik H3C ' Cnj

[0083] The symbol “T” corresponds to the trifunctional fraction R'-SiOs^, in which three of the available bonds on the silicon atom are used to bond with oxygen for the formation of the polymer chain. The group R1 indicates the same thing as explained above. The fraction “T” can be represented by the following structure: \ O \ SI—O 1 / 2 o z L / CH S

[0084] As in fraction "M", any of the methyl groups can be replaced in "D" or "T" by an R group other than methyl.

[0085] Finally, the symbol “Q” corresponds to a tetrafunctional SiO4 / 2 fraction, where the four available bonds on the silicon atom are used to bond with oxygen for the formation of the polymer chain. The “Q” fraction can be represented by the following structure: if-—Oi / 2

[0086] As described above, in one embodiment of the present invention, the silicone resin can be selected from siloxysilicate, silsesquioxane, and a resin obtained by hydrosilylation. Any siloxysilicate, silsesquioxane, or resin obtained by hydrosilylation that acts as a film-forming polymer can be used in the anhydrous composition of the present invention. Preferably, the silicone resin is crosslinked.

[0087] According to one embodiment of the present invention, the silicone resin can be selected from substituted siloxysilicate, silsesquioxane, and resin obtained by hydrosilylation. A substituted siloxysilicate or a substituted silsesquioxane can be, for example, a siloxysilicate or a silsesquioxane in which a methyl group has been replaced by a longer carbon chain, such as an ethane, propane, or butane chain. The carbon chain can be saturated or unsaturated.

[0088] According to one embodiment of the present invention, the silicone resin can be chosen from siloxysilicate, such as MQ resins, which can substantially consist of M fractions and Q fractions. The MQ resin can be represented by the following formula:

[0089] [(R^SiOidxCSiO^y (fractions MQ)

[0090] in which x and y can have values ​​from 10 to 150, preferably from 20 to 120, more preferably from 40 to 100, and in particular from 50 to 80; and R1 indicates a hydrocarbon group, preferably an alkyl group or an aryl group, and more preferably a Ci-Cio alkyl group, in particular a Ci-C4 alkyl group, such as a methyl group.

[0091] According to another embodiment of the present invention, a siloxysilicate can be chosen from all combinations of fractions of M and Q such as, for example, [(R)3Si]x(SiO4 / 2)y, where R is chosen from a methyl group and a longer carbon chain.

[0092] In a preferred embodiment, the siloxysilicate is trimethylsiloxysilicate, which is represented by [(CH3)3SiO]x(SiO4 / 2)y in which x and y represent from 10 to 150, preferably from 20 to 120, more preferably from 40 to 100, and in particular from 50 to 80, for example, sold by the company Momentive Performance Materials under the name SR 1000 MQ Resin.

[0093] According to another embodiment of the present invention, the silicone resin can be chosen from silsesquioxane, which can substantially consist of T fractions. Silsesquioxane can be represented by the following formula:

[0094] (R'SiO3 / 2)x (fractions T),

[0095] in which xa has a value that can go up to several thousand and R1 indicates a hydrocarbon group, preferably an alkyl group or an aryl group, and more preferably a Ci-C i0 alkyl group, in particular a Ci-C 4 alkyl group, such as a methyl group.

[0096] Among silsesquioxane, alkylsilsesquioxane resins may be cited which are homopolymers and / or copolymers of silsesquioxane having an average siloxane motif of formula R2nSiO(4 n) / 2, where each R2 independently designates a hydrogen atom or an alkyl group in the form Ci-Cio, where more than 80 mol% of the R1 radicals represent an alkyl group in the form C3-CiO, and n is a number from 1.0 to 1.4, and more particularly a silsesquioxane copolymer will be used in which more than 60 mol% comprise R2SiO3 / 2 motifs in which R2 has the definition indicated above.

[0097] Preferably, the silsesquioxane resin is chosen such that R2 is a C1-C1 alkyl group, preferably a C2-C4 alkyl group, and more particularly a propyl group. A poly(propyl silsesquioxane) or t-propyl silsesquioxane resin (INCI name: Polypropylsilsesquioxane (and) Isododecane) will be used in particular, such as the product sold under the trade name Dow Corning® 670 Fluid by Dow Corning.

[0098] According to another embodiment of the present invention, the silicone resin can be chosen from MQT resins, which can substantially consist of M fractions, T fractions and Q fractions.

[0099] Thus, in another embodiment, the silicone resin is chosen from among the MQ resins, the T resins and the MQT resins.

[0100] The quantity of the oil-soluble film-forming agent(s) in the anhydrous composition according to the present invention may be 1% by weight or more, preferably 5% by weight or more, and more preferably 10% by weight or more, relative to the total weight of the composition.

[0101] The quantity of the oil-soluble film-forming agent(s) in the anhydrous composition according to the present invention may be 30% by weight or less, preferably 25% by weight or less, and, more preferably, 20% by weight or less, relative to the total weight of the composition.

[0102] The quantity of the oil-soluble film-forming agent(s) in the anhydrous composition according to the present invention can range from 1% to 30% by weight, preferably from 5% to 25% by weight, and more preferably from 10% to 20% by weight, relative to the total weight of the composition. (Optional ingredients) - Oil

[0103] The anhydrous composition may comprise at least one oil. Only one type of oil may be used, or two or more different types of oils may be used in combination.

[0104] Here, "oil" means a compound or substance which is in the form of a liquid, a paste or a solid at room temperature (25 °C) under atmospheric pressure (105 Pa).

[0105] The oil may be volatile or non-volatile.

[0106] For the purposes of the present invention, the expression "non-volatile oil" is intended to designate an oil whose vapor pressure at ambient temperature and atmospheric pressure is non-zero and less than 103 mmHg (0.13 Pa).

[0107] For the purposes of the invention, the term "volatile oil" is intended to designate any oil that is capable of evaporating upon contact with the skin in less than one hour, at room temperature and atmospheric pressure. Volatile oil is a volatile cosmetic compound that is liquid at room temperature, having in particular a non-zero vapor pressure, at room temperature and atmospheric pressure, having in particular a vapor pressure ranging from 0.13 Pa to 40,000 Pa (103 to 300 mmHg), in particular ranging from 1.3 Pa to 13,000 Pa (0.01 to 100 mmHg) and more particularly ranging from 1.3 Pa to 1300 Pa (0.01 to 10 mmHg).

[0108] In this context, volatile oil also includes an oil whose flash point ranges from -20 °C to 120 °C.

[0109] It is preferable that the oil be chosen from among hydrocarbon oils and silicone oils.

[0110] The expression "hydrocarbon oil" (or "hydrocarbon oil" or "hydrocarbon-based oil") refers to an oil formed essentially, or even composed, of carbon and hydrogen atoms, and optionally of oxygen and nitrogen atoms, and containing no silicon or fluorine atoms. It may contain alcohol, ester, ether, carboxylic acid, amine and / or amide groups.

[0111] According to a preferred embodiment, the volatile hydrocarbon oil has a flash point above 25 °C, and, even better, above 35 °C.

[0112] Volatile hydrocarbon oils may be selected from hydrocarbon oils containing 8 to 16 carbon atoms, and in particular C8-Ci6 branched alkanes (also known as isoparaffins), for example isododecane (also called 2,2,4,4,6-pentamethylheptane), isodecane and isohexadecane, and mixtures thereof.

[0113] The volatile hydrocarbon oil may also be a linear volatile alkane containing 7 to 17 carbon atoms, in particular 9 to 15 carbon atoms, and more particularly 11 to 13 carbon atoms. Examples include n-nonadecane, n-decane, n-undecane, n-dodecane, n-tridecane, n-tetradecane, n-pentadecane and n-hexadecane, and mixtures thereof.

[0114] The volatile hydrocarbon oil may preferably be selected from the group consisting of C7-10 paraffins, petrolatum, isododecane, isohexadecane, undecane, tridecane, and mixtures thereof.

[0115] The term "silicone oil" here refers to an oil comprising at least one silicon atom, and in particular at least one Si-O group, and more specifically an organopolysiloxane. Silicone oil may also be represented as a "silicone-based oil".

[0116] The volatile silicone oil may be selected from those having a boiling point between 60 °C and 260 °C, and more particularly from: i. cyclic polydialkylsiloxanes comprising 3 to 7 and preferably of 4 to 5 silicon atoms. These include, for example, octamethylcyclotetrasiloxane sold in particular under the name Volatile Silicone® 7207 by Union Carbide or Silbione® 70045 V2 by Rhodia, decamethylcyclopentasiloxane sold under the name Volatile Silicone® 7158 by Union Carbide, Silbione® 70045 V5 by Rhodia, and dodecamethylcyclopentasiloxane sold under the name Silsoft 1217 by Momentive Performance Materials, and their mixtures. We can also mention cyclocopolymers of the dimethylsiloxane / methylalkylsiloxane type, such as Silicone Volatile® FZ 3109 sold by Union Carbide, with the formula:

[0117] Other examples include mixtures of cyclic polydialkylsiloxanes with organosilicon compounds, such as the mixture of octamethylcyclotetrasiloxane and tetratrimethylsilylpentaerythritol (50 / 50) and the mixture of octamethylcyclotetrasiloxane and oxy-1,r-bis(2,2,2',2',3,3'-hexatrimethylsilyloxy)neopentane; and

[0118] (ii) linear volatile polydialkylsiloxanes containing 2 to 9 silicon atoms and having a viscosity less than or equal to 5 x 10⁶ m² / s at 25 °C. An example is decamethyltetrasiloxane, sold in particular under the name SH 200 by Toray Silicone. Silicones belonging to this category are also described in the article published in Cosmetics and Toiletries, Vol. 91, Jan. 76, pp. 27–32, Todd & Byers, Volatile Silicone Fluids for Cosmetics. The viscosity of silicones is measured at 25 °C according to ASTM 445 Annex C.

[0119] The volatile silicone oil may be chosen from cyclic silicones, preferably chosen from the group consisting of cyclopentasiloxane, cyclohexasiloxane and mixtures thereof.

[0120] Silicone oils can be organomodified. The organomodified silicones that can be used for the present invention are silicone oils as defined above and comprise in their structure one or more organofunctional groups attached via an organic group, such as a hydrocarbon group.

[0121] Examples of organomodified silicones include phenyl silicones, in particular non-volatile phenyl silicones.

[0122] Representative examples of these non-volatile phenyl silicone oils that may be mentioned include:

[0123] - phenyl silicone oils corresponding to the following formula; ? ® JRR r—Si—O | j II R-""'-Si OS j --------------- R RR j IR R--Si-------O R

[0124] formula (I) in which the R groups represent, independently of each other, a methyl or a phenyl group, provided that at least one R group represents a phenyl group. Preferably, in this formula, the phenyl silicone oil comprises at least three, for example at least four, at least five, or at least six phenyl groups,

[0125] - phenyl silicone oils corresponding to the following formula; RRR (II) R— O Si O Si * R RRR

[0126] formula (II) wherein the R groups represent, independently of each other, a methyl or a phenyl group, provided that at least one R group represents a phenyl group. Preferably, in this formula, said organopolysiloxane comprises at least three, for example at least four or at least five phenyl groups. Mixtures of the phenyl organopolysiloxanes described above may be used. Examples that may be mentioned include mixtures of triphenyl, tetraphenyl, or pentaphenyl organopolysiloxanes,

[0127] - phenyl silicone oils corresponding to the following formula; Ph Ph Ph (ni) / / / i ' 1 \ Ph M® Ph

[0128] formula (III) in which Me represents methyl, Ph represents phenyl. Such a phenyl silicone is notably manufactured by Dow Corning under the reference PH-1555 HRI or Dow Corning 555 Cosmetic Fluid (chemical name: 1,3,5-trimethyl-1,1,3,5,5-pentaphenyl trisiloxane; INCI name: trimethyl pentaphenyl trisiloxane). The Dow Corning 554 reference cosmetic fluid may also be used,

[0129] - phenyl silicone oils corresponding to the following formula; *f8 MO <iv) X—Si■■■■■■(■■■■■■ O ■■■■■■■■■■■■ gj q........... g............... K i * I. Ms.

[0130] formula (IV) in which Me represents methyl, y is between 1 and 1000, and X represents -CH2-CH(CH3)(Ph).

[0131] - phenyl silicone oils corresponding to formula (V) below; Mef Me "1 r OR (V) ML i I i Me—Si -HO—SI--KO™ Si —K~O--Su CH.L iiidri " Me'- Me L 1¾

[0132] formula (V) in which Me is methyl and Ph is phenyl, OR1 represents a -OSiMe3 group and y is 0 or ranges from 1 to 1000, and z ranges from 1 to 1000, so that the Compound (V) is a non-volatile oil. According to a first embodiment, y ranges from 1 to 1000. One can use, for example, trimethyl siloxyphenyl dimethicone, sold in particular under the reference Belsil PDM 1000 sold by the company Wacker. According to a second embodiment, y is equal to 0. One can use, for example, phenyl trimethylsiloxy trisiloxane, sold notably under the reference Dow Corning 556 Cosmetic Grade Fluid,

[0133] - phenyl silicone oils corresponding to formula (VI) below, and their mixtures; n

[0134] formula (VI) wherein:

[0135] - Ri in Rio, independently of each other, are radicals based of saturated or unsaturated, linear, cyclic or branched Ci-C30 hydrocarbons,

[0136] - m, n, p and q are, independently of each other, integers included between 0 and 900, provided that the sum m+n+q is not equal to 0; preferably, the sum m+n+q is between 1 and 100. Preferably, the sum m+n+p+q is between 1 and 900, and even better between 1 and 800. Preferably, q is equal to 0,

[0137] - the phenyl silicone oils corresponding to formula (VII) below, and their mixtures;

[0138] formula (VII) in which:

[0139] - Ri to R6, independently of each other, are radicals based of saturated or unsaturated, linear, cyclic or branched Ci-C30 hydrocarbons,

[0140] - m, n and p are, independently of each other, integers included between 0 and 100, provided that the sum n+m is between 1 and 100; preferably, Ri to R6, independently of each other, represent a saturated hydrocarbon-based radical, linear or branched in Ci-C30 and in particular in C1-C12 and in particular a methyl, ethyl, propyl or butyl radical; Ri to R6 may in particular be identical, and moreover may be a methyl radical; preferably, m = 1 or 2 or 3, and / or n = 0 and / or p = 0 or 1 may apply, in formula (VII),

[0141] - phenyl silicone oils corresponding to formula (VIII), and mixtures thereof:

[0142] formula (VIII) in which:

[0143] - R is a Ci-C30 alkyl radical, an aryl radical or an aralkyl radical,

[0144] - n is an integer from 0 to 100, and

[0145] - m is an integer from 0 to 100, provided that the sum n+m goes from 1 to 100. In particular, the radicals R of formula (VIII) and Ri at Rio defined previously may each represent a linear or branched alkyl radical, saturated or unsaturated, especially in C2-C2O, especially in C3-C16 and more particularly in C4-C10, or a monocyclic or polycyclic aryl radical in C6-C14 and especially in C10-C13, or an aryl radical whose aryl and alkyl residues are such as defined previously. Preferably, R of formula (VIII) and Ri at Ri may each represent a methyl, ethyl, propyl, isopropyl, decyl, dodecyl or octadecyl radical, or alternatively a phenyl, tolyl, benzyl or phenethyl radical. According to one embodiment, a phenyl silicone oil of formula (VIII) with a viscosity at 25 °C of between 5 and 1500 mm2 / s (i.e. 5 to 1500 cSt), and preferably with a viscosity of between 5 and 1000 mm2 / s (i.e. 5 to 1000 cSt) may be used.As formula (VIII) phenyl silicone oils, it is possible to use phenyl trimethicones such as Dow Corning DC556 (22.5 cSt), Rhône-Poulenc Silbione 70663V30 (28 cSt), or diphenyl dimethicones such as Belsil oils, including Wacker's Belsil PDM1000 (1000 cSt), Belsil PDM 200 (200 cSt), and Belsil PDM 20 (20 cSt). Values ​​in parentheses represent viscosities at 25°C.

[0146] - phenyl silicone oils corresponding to the following formula, and their mixtures:

[0147] formula (IX) wherein:

[0148] - Rb R2, R5 and R6 are, together or separately, an alkyl radical containing 1 to 6 carbon atoms,

[0149] - R3 and R4 are, together or separately, an alkyl radical containing from 1 to 6 atoms of carbon or an aryl radical,

[0150] - X is an alkyl radical containing 1 to 6 carbon atoms, a hydroxyl radical or a vinyl radical

[0151] - n and p being chosen so as to give the oil an average molecular mass in weight less than 200,000 g / mol, preferably less than 150,000 g / mol and more preferably less than 100,000 g / mol.

[0152] The phenyl silicones most particularly suitable for use in the present invention may be those corresponding to formulas (II) and in particular to formulas (III), (V) and (VIII) above.

[0153] More particularly, phenyl silicones can be selected from phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxydiphenylsiloxanes, diphenyl dimethicones, diphenylmethyldiphenyltrisiloxanes and 2-phenylethyl trimethylsiloxysilicates, and mixtures thereof.

[0154] Preferably, the average molecular weight by weight of the phenyl silicone oil used according to the present invention can range from 500 to 10,000 g / mol.

[0155] The quantity of the oil(s) in the anhydrous composition may be 10% by weight or more, preferably 15% by weight or more, and more preferably 20% by weight or more, relative to the total weight of the anhydrous composition.

[0156] The quantity of the oil(s) in the anhydrous composition may be 60% by weight or less, preferably 55% by weight or less, and more preferably 50% by weight or less, relative to the total weight of the composition.

[0157] The quantity of the oil(s) in the anhydrous composition can be from 10% to 60% by weight, preferably from 15% to 55% by weight, and more preferably from 20% to 50% by weight, relative to the total weight of the anhydrous composition. - Silicone gum

[0158] The anhydrous composition of the present invention may comprise at least one silicone gum. If two or more silicone gums are used, they may be identical or different.

[0159] The silicone gum can have a dynamic viscosity at 25 °C of 400,000 cSt or more, preferably 600,000 cSt or more, and more preferably 800,000 cSt or more.

[0160] The silicone gum may have a dynamic viscosity at 25 °C of 10,000,000 cSt or less, preferably 5,000,000 cSt or less, and more preferably 3,000,000 cSt or less.

[0161] The silicone gum can have a dynamic viscosity at 25 °C of 300,000 to 10,000,000 cSt, preferably of 500,000 to 5,000,000 cSt or less, and more preferably of 700,000 to 3,000,000 cSt.

[0162] The dynamic viscosity of silicone gum can be measured in accordance with ASTM D-445.

[0163] It may be preferable that the silicone gum not have a functional group such as an amino group.

[0164] The silicone gum may be chosen in particular from silicones of the following formula:

[0165] in which:

[0166] - RI, R2, R5 and R6 are, together or separately, an alkyl radical containing 1 to 6 carbon atoms,

[0167] - R3 and R4 are, together or separately, an alkyl radical containing from 1 to 6 atoms of carbon, a vinyl radical, an amine radical, or a hydroxyl radical,

[0168] - X is an alkyl radical containing 1 to 6 carbon atoms, a hydroxyl radical or an amine radical, and

[0169] - n and p being integers chosen such that the dynamic viscosity at 25 °C of the compound either of 400,000 cSt or more, preferably of 600,000 cSt or more, and more preferably of 800,000 cSt or more.

[0170] Examples of silicone rubbers that can be used according to the present invention include those for which:

[0171] - the substituents RI to R6 represent a methyl group, the group X represents a methoxy group, and n and p are such that the molecular weight of the polymer is 600,000 g / mol, such as the product sold under the name Mirasil C-DPDM by the company Bluestar;

[0172] - the substituents RI to R6 represent a methyl group, the group X represents a hydroxyl group, and n and p are such that the molecular weight of the polymer is 600 000 g / mol, such as the product sold under the name SGM 36 by Dow Corning; and

[0173] - dimethicones of the type (polydimethylsiloxane) (methylvinylsiloxane), such as SE63 sold by GE Bayer Silicones, poly(dimethylsiloxane)(diphenyl)(methylvinylsiloxane) copolymers, and mixtures thereof.

[0174] The molecular mass of silicone gum may be greater than 350,000 g / mol, between 350,000 and 800,000 g / mol, and preferably from 450,000 to 700,000 g / mol.

[0175] It is preferable that the silicone gum be chosen from polydimethylsiloxane gum.

[0176] The quantity of silicone gum in the anhydrous composition according to the present invention may be 1% by weight or more, preferably 3% by weight or more, and more preferably 5% by weight or more, relative to the total weight of the composition.

[0177] The quantity of silicone gum in the anhydrous composition according to the present invention may be 25% by weight or less, preferably 20% by weight or less, and more preferably 15% by weight or less, relative to the total weight of the composition.

[0178] Thus, the quantity of silicone gum in the anhydrous composition according to the present invention can be from 1% to 25% by weight, preferably from 3% to 20% by weight, and more preferably from 5% to 15% by weight, relative to the total weight of the composition. - Charge

[0179] The anhydrous composition may comprise at least one filler. If two or more fillers are used, they may be identical or different.

[0180] The term "filler" should be understood as designating mineral or synthetic particles of any shape, which are insoluble in the medium of the anhydrous composition, regardless of the temperature at which the composition is manufactured.

[0181] The charge(s) of the present invention can increase the thickness of the anhydrous layer formed by the anhydrous composition.

[0182] The charge can be of any shape, plate-like, spherical or oblong, regardless of the crystallographic form (for example lamellar, cubic, hexagonal, orthorhombic, etc.).

[0183] The filler can be an inorganic or organic powder, which may or may not be surface coated.

[0184] The average particle size of the charge is not limited, but is generally 100 µm or less, preferably 50 µm or less, and more preferably of 10 µm or less. The average particle size of the charge is 0.01 µm or more, preferably 0.05 µm or more, and most preferably 0.1 µm or more. The term "average particle size" used here represents a number-average diameter-average size that is given by the statistical particle size distribution to half the population, designated by D50. For example, the number-average diameter-average size can be measured by a laser diffraction particle size distribution analyzer, such as the Mastersizer 2000 from Malvern Corp.

[0185] As inorganic fillers, examples include talc, mica, silica, magnesium-aluminum silicate, silica aerogel, such as silica silylate, kaolin, bentone, calcium carbonate, magnesium hydrogen carbonate, hydroxyapatite, boron nitride, fluorphlogopite, sericite, calcined talc, calcined mica, calcined sericite, synthetic mica, perlite, metallic soap, bismuth oxychloride, barium sulfate, magnesium carbonate, magnesium hydrocarbonate, hydroxyapatite, hollow silica microspheres (Maprecos Silica Beads®), glass or ceramic microcapsules, and mixtures thereof, optionally subjected to hydrophilic or hydrophobic treatment. Metallic soap can be a metallic soap derived from organic carboxylic acids containing 8 to 22 carbon atoms, preferably 12 to 18 carbon atoms, for example, zinc stearate, magnesium stearate, lithium stearate, zinc laurate, or magnesium myristate.

[0186] As organic fillers, examples include acrylic polymer powders, silicone powders, polyamide powders, urethane polymer powders, tetrafluoroethylene polymer powders, polyacrylonitrile powders, poly-[3-alanine] powders, polyethylene powders, polytetrafluoroethylene powders, lauroyl lysine, starch, cellulose powder, tetrafluoroethylene polymer powders, hydrophobically modified starch, and mixtures thereof.

[0187] Examples of acrylic polymer powders include polymethyl methacrylate powders, polymethyl methacrylate / ethylene glycol dimethacrylate powders, polyallyl methacrylate / ethylene glycol dimethacrylate powders, lauryl methacrylate / ethylene glycol dimethacrylate powders, acrylate / ethylhexyl acrylate powders, and expanded hollow particles of acrylonitrile (co-)polymer, such as acrylonitrile / methacrylate / vinylidene chloride copolymer.

[0188] Examples of acrylic polymer powder include:

[0189] - crosslinked polymethyl methacrylate powder, for example "Covabead LH85" sold by LC Wackherr, or non-crosslinked polymethyl methacrylate, such as SJ Touch 1 sold by Nihon Junyaku;

[0190] - methyl methacrylate / butyl acrylate copolymer powder sold under the Sepipress M name by the company Seppic;

[0191] - methyl acrylate / ethylene copolymer powder sold under the name EMAA by Kobo Products Inc.;

[0192] - methyl methacrylate / ethylene dimethacrylate crosslinked copolymer powder glycol sold under the name Ganzpearl GMP 0820 by Ganz Chemical, under the name Techpolymer MBP-8 by Sekisui Plastics, or under the name SUNPMMA-S by Sunjin Chemical;

[0193] - polymethyl methacrylate / ethylene glycol dimethacrylate powder, by example "Dow Corning 5640 Microsponge Skin Oil Adsorber" sold by the Dow Corning company;

[0194] - methyl methacrylate / ethylene dimethacrylate crosslinked copolymer powder glycol sold under the name Ganzpearl PM 030 by the company Ganz Chemical;

[0195] - allyl polymethacrylate / ethylene glycol dimethacrylate powder, for example “Poly-Pore L200” or “Poly-Pore E200” sold by the company Amcol,

[0196] - lauryl methacrylate / ethylene glycol dimethacrylate copolymer powder, for example “Polytrap 6603” sold by Dow Corning;

[0197] - acrylate / ethylhexyl acrylate copolymer powder, for example " Techpolymer ACP-8C » sold by the company Sekisui Plastics;

[0198] - acrylonitrile / methacrylate / vinylidene chloride copolymer powder sold under the name Expancel by the company Expancel under the references 551 DE 50, 551 DE 20, 551 DE 12, 551 DE 80 and 461 DE 50.

[0199] Examples of polyurethane powders include crosslinked polyurethane powders comprising a copolymer, said copolymer comprising trimethylol hexyl lactone, for example the polymer hexamethylene diisocyanate / trimethylol hexyl lactone sold under the name Plastic Powder D-400® or Plastic Powder D-800® by the Toshiki company.

[0200] Examples of silicone powders include organopolysilsesquioxane powders, organopolysiloxane powders and silicone resin powders.

[0201] Organopolysilsesquioxane powders are preferably polymethylsilsesquioxane powders. Materials sold by Momentive Performance Materials under the trade name "TOSPEARL" and materials sold by NIKKO RICA under the names MSP-N050 and MSP-N080 are examples of such polymethylsilsesquioxane powders.

[0202] Organopolysiloxane powders can be elastomeric or non-elastomeric. It is preferable to use elastomeric organopolysiloxane powder or organopolysiloxane elastomer powder.

[0203] The elastomeric organopolysiloxane can, for example, be cross-linked and can be obtained

[0204] via a crosslinking addition reaction of diorganopolysiloxane comprising at least one hydrogen bonded to silicon and diorganopolysiloxane comprising at an ethylenically unsaturated group bonded to silicon, preferably in the presence, for example, of a platinum catalyst; or

[0205] via a dehydrogenation crosslinking condensation reaction between a diorganopolysiloxane comprising at least one terminal hydroxyl group and a diorganopolysiloxane comprising at least one silicon-bonded hydrogen, preferably in the presence, for example, of an organotin compound; or

[0206] via a condensation reaction by crosslinking of a diorganopolysiloxane comprising at least one terminal hydroxyl group and a hydrolyzable organopolysilane; or

[0207] via thermal crosslinking of an organopolysiloxane, preferably in the presence, for example, of an organoperoxide catalyst; or

[0208] via crosslinking of an organopolysiloxane by high energy radiation such as gamma rays, ultraviolet rays or an electron beam.

[0209] The organopolysiloxane elastomer powders that may be used include those sold under the names "Dow Corning 9505 Powder" and "Dow Corning 9506 Powder" by Dow Corning. These powders have the INCI name: dimethicone / vinyl dimethicone crosspolymer.

[0210] The elastomeric organopolysiloxane powder may, for example, be selected from elastomeric organopolysiloxane powders coated with silicone resin, for example, silsesquioxane resin, as described, for example, in US Patent No. 5,538,793, the contents of which are incorporated by reference. These elastomeric powders are sold under the names "KSP-100", "KSP-101", "KSP-102", "KSP-103", "KSP-104" and "KSP-105" by the Shin-Etsu company and bearing the INCI name: vinyl dimethicone / methicone silsesquioxane crosspolymer.

[0211] Other elastomeric organopolysiloxanes in the form of spherical powders may be hybrid silicone powders functionalized with fluoroalkyl groups, sold, for example, under the name "KSP-200" by the company Shin-Etsu and hybrid silicone powders functionalized with phenyl groups, sold, for example, under the name "KSP-300" by the company Shin-Etsu.

[0212] Examples of polyamide powders include those sold under the name "Orgasol" by Atochem. These polyamide powder particles are also known, based on their various physicochemical properties, as "Nylon 12" or "Nylon 6." Polyamide powders useful in the present invention may also include those sold under the name SP500 by TORAY.

[0213] Hydrophobically modified starches may be esterified starches. The expression "hydrophobically modified" means that, at least, the surface of the starches has been treated to be hydrophobic.

[0214] The esterified starch preferably used in the present invention may be selected from the group consisting of phosphorylated starch, starch acetate, oxidized starch acetate, starch laurate, sodium starch phosphate, alkyl or alkenyl succinic starch, such as calcium octenylsuccinate starch, sodium octenylsuccinate starch, aluminum octenylsuccinate starch, which is starch esterified with octenylsuccinic anhydride and its salts, for example, sold under the name "Dry Flo Plus" by AKZO NOVEL, potato starch esterified with a carboxymethyl group, sold under the name "Supramyl P 60" by Amylum, corn starch esterified with a hydroxypropyl group, sold under the name "Merigel EF6" by Amylum, corn starch esterified with dodecenylsuccinic anhydride (INCI name: CORN STARCH MODIFIED), and potato starch esterified with halogenated methylaminodipropionate acid (INCI name: POTATO STARCH MODIFIED).

[0215] Preferred fillers of the present invention include inorganic fillers, in particular spherical inorganic fillers such as silica, silica silylate, and hollow silica microspheres, and hydrophobically modified starch such as esterified starch powders, and mixtures thereof.

[0216] The quantity of the filler(s) in the anhydrous composition of the present invention may be 1% by weight or more, preferably 5% by weight or more, and more preferably 10% by weight or more, relative to the total weight of the composition.

[0217] The quantity of the filler(s) in the anhydrous composition of the present invention may be 30% by weight or less, preferably 25% by weight or less, and more preferably 20% by weight or less, relative to the total weight of the composition.

[0218] The quantity of the filler(s) in the anhydrous composition of the present invention can be from 1% to 30% by weight, preferably from 5% to 25% by weight, and more preferably from 10% to 20% by weight, relative to the total weight of the composition. - Lipophilic gelling agent

[0219] The anhydrous composition of the present invention may comprise at least one lipophilic gelling agent. If two or more lipophilic gelling agents are used, they may be identical or different.

[0220] The expression "lipophilic gelling agent" refers to an agent capable of increasing the viscosity of the anhydrous composition, resulting in an increase in the coating layer formed by the anhydrous composition.

[0221] The term “lipophilic” here refers to a substance that is soluble in an oil, such as isododecane, at a concentration of at least 1% by weight, for example of at least 5% by weight or 10% by weight, relative to the total weight of the oils at ambient temperature (25 °C) and atmospheric pressure (105 Pa).

[0222] The composition according to the present invention comprises at least one lipophilic gelling agent which is preferably particulate.

[0223] The term "particulate" lipophilic gelling agent means a lipophilic gelling agent in the form of particles or crystals (particulate or crystalline).

[0224] According to the present invention, the lipophilic gelling agent is preferably chosen from organomodified clays.

[0225] Clay refers to a material based on hydrated silicates and / or aluminosilicates, with a lamellar structure.

[0226] Clays can be natural or synthetic, and they are made lipophilic by treatment with an alkylammonium salt, such as a C22 C1O ammonium chloride, in particular stearalconium chloride or distearyldimethylammonium chloride.

[0227] They can be selected from bentonites, in particular bentonites, hectorites and montmorillonites, beidellites, saponites, nontronites, sepiolites, biotites, attapulgites, vermiculites and zeolites.

[0228] Organomodified clays may be clays treated with compounds selected in particular from quaternary and tertiary amines. Organomodified clays that may be mentioned include organomodified bentonites, such as the product sold under the name Bentone 34 by Rheox, and organomodified hectorites, such as the products sold under the names Bentone 27 and Bentone 38 by Rheox. Examples include modified clays such as modified magnesium silicate (Rheox Bentone gel VS38), modified hectorites such as hectorite modified with C22 fatty acid ammonium chloride, for example hectorite modified with distearyldimethylammonium chloride, for example the product sold under the name Bentone 38VCG by Elementis or the product sold under the name Bentone 38 CE by Rheox, or the product sold under the name Bentone Gel V5 5V by Elementis.

[0229] Lipophilic gelling agents can also be selected from hydrophobic fumed silicas, which can be obtained by modifying the silica surface via a chemical reaction that reduces the number of silanol groups, these groups being optionally replaced, in particular, by hydrophobic groups. The hydrophobic groups can be trimethylsiloxy groups, which are obtained, in particular, by treating fumed silica in the presence of hexamethyldisilazane. Silicas treated in this way are known as "Silica silylate" according to the CTFA (6th edition, 1995). They are sold, for example, under the brand names Aerosil R812® by Degussa, and Cab-O-Sil TS-530® by Cabot. The hydrophobic groups can be dimethylsilyloxy or polydimethylsiloxane groups, which are obtained, in particular, by treating fumed silica in the presence of polydimethylsiloxane or dimethyldichlorosilane. Silicas treated in this way are known as "Silica dimethyl silylate" according to the CTFA dictionary (6th edition, 1995). They are sold, for example, under the brand names Aerosil R972® and Aerosil R974® by Degussa, and CAB-O-SIL TS-610® and CAB-O-SIL TS-720® by Cabot.

[0230] Lipophilic gelling agents may also be selected from hydrophobic silica aerogels, such as the products sold under the name VM-2260 (INCI name: Silica silylate) by Dow Corning, whose particles have an average size of approximately 1000 microns and a specific surface area per unit mass ranging from 600 to 800 m² / g; other examples include aerogels sold by Cabot under the references Aerogel TLD 201, Aerogel OGD 201, Aerogel TLD 203, Enova® Aerogel MT 1100, and Enova Aerogel MT 1200.

[0231] Lipophilic gelling agents may also be selected from lipophilic polymer thickeners which may be selected from carboxyvinyl polymers such as Carbopol products (carbomers) and Pemulen products (C10-C30 acrylate / alkyl acrylate copolymer) or polymers having the INCI name "Poly C10-30 Alkyl Acrylate", such as Air Products' Intelimer® products, such as Intelimer® IPA 13-1, which is a polystearyl acrylate, or Intelimer® IPA 13-6, which is a behenyl polymer.

[0232] It may be preferable for the lipophilic gelling agent to be an organomodified clay, in particular disteardimonium hectorite.

[0233] The quantity of the lipophilic gelling agent(s) in the anhydrous composition according to the present invention may be 1% by weight or more, preferably 3% by weight or more, and more preferably 5% by weight or more, relative to the total weight of the composition.

[0234] The quantity of the lipophilic gelling agent(s) in the anhydrous composition according to the present invention may be 14% by weight or less, preferably 12% by weight or less, and, more preferably 10% by weight or less, relative to the total weight of the composition.

[0235] Thus, the quantity of the lipophilic gelling agent(s) in the anhydrous composition according to the present invention can be from 1% to 14% by weight, preferably from 3% to 12% by weight, and more preferably from 5% to 10% by weight, relative to the total weight of the composition. - Additives

[0236] The anhydrous composition may also include any other additive(s) commonly used in the field of cosmetics, chosen from, for example, solvents, resins, dispersants, surfactants, thickening agents, antioxidants, preservatives, perfumes, UV filtering agents, and mixtures thereof.

[0237] The total quantity of the additive(s) in the anhydrous composition of the present invention can be from 0.01% to 30% by weight, preferably from 0.05% to 20% by weight, and more preferably from 0.1% to 15% by weight, relative to the total weight of the composition.

[0238] The anhydrous composition of the present invention can be prepared by mixing the oil-soluble film-forming agent, as essential ingredients, with one or more other optional ingredients, as explained above.

[0239] According to a preferred embodiment, the process according to the invention is a process comprising the steps of: i. optional application of a makeup base composition onto keratinous material to provide a makeup base layer on the keratinous material; ii. application of an ink composition to the makeup base layer if step (i) is performed, or to a keratinous material if step (i) is not performed, to provide an ink pattern, preferably to imprint an ink pattern onto the makeup base layer or the keratinous material; and iii. application of an anhydrous composition to the ink pattern, preferably to the printed ink pattern, to provide a coating layer on the ink pattern,

[0240] wherein the anhydrous composition comprises, relative to the total weight of the composition, from 1% to 30% by weight of at least one oil-soluble film-forming agent selected from silicone resins.

[0241] According to a preferred embodiment, the process according to the invention is a process comprising the steps of: i. optional application of a makeup base composition onto keratinous material to provide a makeup base layer on the keratinous material; ii. application of an ink composition to the makeup base layer if step (i) is performed, or to a keratinous material if step (i) is not performed, to provide an ink pattern, preferably to imprint an ink pattern onto the makeup base layer or the keratinous material; and iii. application of an anhydrous composition to the ink pattern, preferably the printed ink pattern, to provide a coating layer on the ink pattern,

[0242] wherein the anhydrous composition comprises, relative to the total weight of the composition, 10% to 20% by weight of at least one oil-soluble film-forming agent selected from silsesquioxane, siloxysilicate and mixtures thereof. [Composition]

[0243] The present invention relates to an anhydrous composition comprising at least one oil-soluble film-forming agent, for use in providing a pattern applied by an ink composition, preferably a pattern printed by an ink composition on keratinous material with improved water resistance.

[0244] The ink deposit can be the ink layer or the printed ink as a temporary tattoo as explained above. Thus, the composition according to the present invention is the anhydrous composition as explained in the process according to the present invention above.

[0245] The composition according to the present invention can be used to improve the water resistance of the ink deposit printed on the keratinous material.

[0246] The oil-soluble film-forming agent in the anhydrous composition is the same as those described in the anhydrous composition in the process according to the present invention above. Furthermore, the anhydrous composition according to the present invention may include other optional ingredients than those described in the anhydrous composition in the process according to the present invention above. In addition, the anhydrous composition according to the present invention may be prepared as described in the anhydrous composition in the process according to the present invention above. [Use]

[0247] The present invention relates to a use of the anhydrous composition according to the present invention to provide the applied ink deposit, preferably printed on keratinous material with improved water resistance.

[0248] Thus, the present invention also relates to a use of the anhydrous composition according to the present invention to improve the water resistance of the applied ink deposit, preferably printed on keratinous material.

[0249] The use of the anhydrous composition of the present invention is as described in the process and composition according to the present invention above. EXAMPLES

[0250] The present invention will be described in more detail by means of examples. However, these examples should not be interpreted as limiting the scope of the present invention. The examples below are presented as non-limiting illustrations within the scope of the present invention. (Manufacturing procedure)

[0251] A basic makeup composition used in the examples was prepared by mixing the ingredients listed in Table 1 below until homogeneous. The numerical values ​​for the quantities of the ingredients are all based on the "% by weight" as active raw materials.

[0252] [Tables 1] Ingredients: Makeup Base Composition: Vinylpyrrolidone / Vinyl Acetate Copolymer 5, Polyacrylate-6 Crosslinked Polymer 0.5, Xanthan Gum 0.1, Ethanol 5, Caprylyl Glycol 0.3, Citric Acid 0.01, Sodium Citrate 0.03, Phenoxyethanol 0.7, Water qs 100

[0253] An ink composition used in the examples was prepared by mixing the ingredients listed in Table 2 below until homogeneous. The numerical values ​​for the quantities of the ingredients are all based on the "% by weight" as active raw materials.

[0254] [Tables2] Ingredients Ink Composition Carbon Black 4 Dipropylene glycol 10 PEG200 10 Polyethylene (20) oleyl ether 1 Water 75

[0255] Anhydrous compositions 1 and 2 were prepared by mixing the ingredients listed in Table 3 until homogeneous. The numerical values ​​for the quantities of the ingredients are all based on the "% by weight" as raw materials.

[0256] [Tables3] Ingredients Hydrogen Composition 1 Hydrogen Composition 2 Isododecane qs 100 - Trimethylsiloxysilicate 14 - Petrolatum - 72 Synthetic wax - 5 Ceresin - 10 Microcrystalline wax - 10 Pentylene glycol 1 - Caprylyl glycol 0.5 - Propylene carbonate 2.8 - 1,2-Hexanediol - 3 Dimethicone (IM est) 10.5 - Disteardimonium hectorite 8 - Silica silylate 0.5 - Aluminum octenylsuccinate starch 16 - Example 1

[0257] The basic makeup composition was poured into a plunger applicator. The ink composition was placed in a cartridge of a skin transfer printer (Prinker M, Prinker). The anhydrous composition 1 was dispensed into a dip applicator. The base makeup composition was applied to a face using a flocked tip and then dried at 25°C for 1 minute to prepare a base layer of makeup on the facial skin. The design was then printed onto the base layer of makeup with the ink composition using a skin transfer printer (Prinker M, Prinker), and the design was then dried at 25°C for 1 minute. Finally, the coating composition was applied over the printed design and dried for 1 minute to form a coating layer. All steps were performed at 25°C. Comparative Example 1

[0258] Example 1 was repeated, but anhydrous composition 2 was used instead of anhydrous composition 1. Comparative Example 2

[0259] Example 1 was repeated, but no anhydrous composition was used. Thus, in this comparative example, no coating layer was prepared. [Evaluations] (Water resistance)

[0260] Water resistance was evaluated for each of Examples 1 and 2 and Comparative Example 1. Specifically, 5 minutes after the final print, 10 mL of water was applied to each sample at a flow rate of 1 mL / s. After 5 rubs using a testing device (Rub Tester, Sketch-On), the ratio between the remaining surface area and the surface area before rubbing was measured. The evaluation was carried out according to the following criteria.

[0261] Good: more than 90% of the surface area remained.

[0262] Correct: 70 to 90% of the surface remained.

[0263] Poor: Less than 70% of the surface area remained.

[0264] The results are presented in Table 4.

[0265] [Tables4] Example 1 Example Comparison 1 Example Comparison 2 Water resistance Good Poor Poor

[0266] As shown in Table 4, the process according to the present invention using the anhydrous composition of the present invention was able to improve the water resistance of the ink deposit.

[0267] On the other hand, the process according to Comparative Example 1, which did not use an anhydrous composition of the present invention, was unable to demonstrate improved water resistance. Furthermore, the process according to Comparative Example 2, which lacked the step of applying the anhydrous composition of the present invention, was also unable to demonstrate improved water resistance.

[0268] Consequently, it can be concluded that the process according to the present invention can constitute a printed pattern with an ink composition on a keratinous material, such as a temporary tattoo, with improved water resistance.

Claims

Demands

1. A method comprising the steps of: (i) optionally applying a makeup base composition to a keratinous material to provide a makeup base layer on the keratinous material; (ii) applying an ink composition to the makeup base layer if step (i) is performed, or to a keratinous material if step (i) is not performed, to provide an ink pattern, preferably to print an ink pattern on the makeup base layer or the keratinous material; and (iii) applying an anhydrous composition to the ink pattern, preferably to the printed ink pattern to provide a coating layer on the ink pattern, wherein the anhydrous composition comprises at least one oil-soluble film-forming agent.

2. A method according to claim 1, wherein the oil-soluble film-forming agent comprises at least one silicone resin.

3. A method according to claim 2, wherein the silicone resin is selected from silsesquioxane, siloxysilicate and mixtures thereof.

4. A method according to any one of claims 1 to 3, wherein the anhydrous composition further comprises at least one oil.

5. A method according to claim 4, wherein the oil comprises at least one hydrocarbon oil and / or at least one silicone oil.

6. A method according to claim 4 or 5, wherein the oil is volatile or non-volatile.

7. A method according to any one of claims 4 to 6, wherein the oil is present in the anhydrous composition in an amount of 10% to 70% by weight, preferably 15% to 65% by weight, and more preferably 20% to 60% by weight, relative to the total weight of the composition.

8. A method according to any one of claims 1 to 7, wherein the oil-soluble film-forming agent is present in the anhydrous composition in an amount of 1% to 30% by weight, preferably 5% to 25% by weight, and more preferably 10% to 20% by weight, relative to the total weight of the composition. 34

9. A method according to any one of claims 1 to 8, wherein the makeup base composition comprises at least one water-soluble polymer.

10. An anhydrous composition comprising at least one oil-soluble film-forming agent, for use in providing an applied ink pattern, preferably printed on a keratinous material with improved water resistance.